COATINGS for ARCHITECTURAL METALS Durability + Design a Collection Coatings for Architectural Metals
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Utrecht Art Supplies What Not to Use As Varnish
Utrecht Art Supplies What Not to Use as Varnish • Removable with light solvents and gentle manipulation (should not require strong solvents or hard scrubbing) • Should not fuse with, soften or dissolve completely dry paint • Resin content should be documented to aid in later cleaning and care Alkyd Alkyd-based painting mediums are great for improving paint flow, imparting gloss, increasing transparency, and promoting a tough, flexible Ask the Expert: "Lately I've been finishing my paint film, but as a top-coat, they aren't oil paintings with a coat of alkyd medium to give reversible with even very harsh solvents. A coat a shiny finish. My friend says this might not be a of alkyd is permanent, for better or worse. Also, good idea. If I can coat an acrylic painting with some alkyd mediums impart harsh glare, making gloss medium, what's the problem with using it difficult to install and light the finished work. alkyd medium on oils?" Wax A: Artists sometimes make the mistake of top- coating a painting with a medium or other Wax is sometimes used as a top-coat over material which gives a good appearance in the paintings, but it has some significant short term, but which causes problems later. shortcomings for this application. Wax remains Alkyd-based painting mediums are great for their soft indefinitely, so it doesn't impart protection intended purpose, but alkyds don't meet the against mechanical damage from handling and requirements of a picture varnish. casual contact. Wax also tends to attract and hold dust. Cold wax medium has an attractive A picture varnish should satisfy these appearance when first applied, especially when functions: buffed to a shine, but can later become • Permanently neutral in color and lackluster. -
Vinyl Toluene Modified Alkyd Resins
VINYL TOLUENE MODIFIED ALKYD RESINS VT can be used to prepare a wide variety of alkyd coating resins. In general, the base alkyd is formulated to use low cost VT to reduce the oil length of the vehicle. For example using VT with a very long-oil soya alkyd produces improved drying time and hardness. These improvements are realized without reducing the good naphtha solubility of the vehicle. OIL AND BASE ALKYD SELECTION The type of oil used in the copolymer reaction is an important variable. Variations in the chemical structure such as degree of unsaturation, type of unsaturation and degree of polymerization have an effect on the product. Copolymers prepared from heavy-bodied oils have higher viscosities, faster drying rates and greater utility for protective coatings than those based on lower viscosity oils. Conjugated oils react readily with VT to form compatible products without use of a catalyst. VT reactivity with unconjugated oils is less active and appears to be a function of the Iodine value of the oil. Use of a small amount of suitable catalyst allows production of products with good homogeneity from any of the convential drying and semi-drying oils. Copolymers of maximum hardness, toughness and flexibility can be prepared by using one of the highly reactive oils such as dehydrated castor oil. VT modified alkyd properties depend upon the base alkyd resin used. Close attention must be given to the choice of polyhydric alcohols and the average functionality of the acids in addition to the type and amount of drying oil used. Viscosity buildup, dry time and film integrity are influenced by the functionality of both the polyhydric alcohol and acid constituents. -
Kinetics of Castor Oil Alkyd Resin Polycondensation Reaction
ineering ng & E P l r a o c i c e m s e s Journal of h T C e f c h o Uzoh and Onukwuli, J Chem Eng Process Technol 2015, 6:4 l ISSN: 2157-7048 n a o n l o r g u y o J Chemical Engineering & Process Technology DOI: 10.4172/2157-7048.1000240 Research Article Article OpenOpen Access Access Kinetics of Castor Oil Alkyd Resin Polycondensation Reaction Uzoh CF* and Onukwuli OD and Madiebo Emeka Chemical Engineering Department, Faculty of Engineering Nnamdi Azikiwe University, Awka, Nigeria Abstract An appropriate kinetic law that governs some important conditions of the reaction process for dehydrated castor monoglyceride modified alkyd resin has been developed. A kinetic experiment was conducted following a standard procedure. The classical third order conversion rate model was utilized in determining the rate parameters while the viscosity-conversion model suggested by the free-volume theory was applied for the viscosity kinetics studies. The kinetic model considered for this study adequately predicts the reaction progress even beyond the actual gelation point. The effects of the system parameters on both the predicted yields and the corresponding conversion rates were documented in a well-designed sampling space implemented by statistical screening optimization paradigm. The effects of system parameters on the reaction rates further investigated based on Arrhenius equation detect a heavy mass transfer resistance during the esterification process. A detailed analysis of the response reveals a deviation from linear first order kinetics and possible transition to second and higher order kinetics in the later stages of the esterification reaction. -
Deep Textured Architectural Metals Custom Fabricated Products Contents
Deep Textured Architectural Metals Custom Fabricated Products contents 4 interior panels 6 exterior panels 8 patterns 10 panel systems 14 fabrication 15 color and tile finishes 16 finishes 18 Trim-Tex™ 19 Rigi-Grip™ 20 partitions 21 elevators 22 Rigi-Bump™ 24 sustainability 26 textured perforations 27 technical data 2 metal made better who we are As the originator and world leader of deep textured metals, Rigidized® Metals manufactures lasting impressions. We continue to explore the world of textures, finishes, forms and shapes to enhance the performance of all metals. For over seventy years our journey has allowed us to develop a one-of- a-kind expertise in how metals can be improved. Many discoveries have created imaginative products and some surprising applications. We strive to use less & give you more. A proud American manufacturer of metal products since 1940. metal made better 3 interiors Nordstrom Cafe 1HM Pattern in Copper Coastline Design Metal Made Better We make metals for interior surfaces richer with textures that reflect the glow of light. These patterned metals offer significantly more durable, longer lasting 1NA Pattern in Stainless Steel surfaces. 4 metal made better interiors Grand Junction Readiness Center Courtesy of CooverClark Architects 1NA 304 Stainless Steel Powder Coated “Brass Transparent” 6WL Column Covers metal made better 5 exteriors 6WL Pattern ZGF Architects-Twelve West, Portland, OR ZGF Architects-Twelve West, Portland, OR 6 metal made better exteriors 1UN Pattern Sherbourne Common Park, Toronto, Ontario Javits Convention Center, FXFOWLE Architects Metal Made Better Our Rigidized® Metals for exterior applications are uniquely durable, long lasting, luminescent, and visu- ally appealing. -
Architectural Metals: Cast Iron, Steel, Pressed Tin, Copper, Aluminum and Zinc
CITY OF GRANBURY Historic Preservation DESIGN GUIDELINES 10. ARCHITECTURAL METALS: CAST IRON, STEEL, PRESSED TIN, COPPER, ALUMINUM AND ZINC Evaluate the overall condition of architectural metals to determine whether more protection and maintenance may be required and if repairs are warranted. Most architectural features on Granbury's historic buildings were made of pressed tin. Most hardware on Granbury's historic buildings (before 1930) were made of brass, bronze and/or copper. Identify and Retain architectural metal features, such as columns, pilasters, soffits, cornices, capitals, window frames, awnings or stairways that are important to defining the historic character of a building, its finishes and colors. Protect and Maintain architectural metals from corrosion by providing proper drainage, preventing water from standing on horizontal surfaces or accumulating in curved, decorative features. Clean architectural metals, when necessary, to remove corrosion prior to repainting or applying other appropriate protective coatings. Do not remove historic patinas found on some metals such as copper or bronze. This will diminish the metal's historic character and may damage it. Prohibited: ¦ Removing or radically changing architectural metal features, so that, as a result, their character is diminished. ¦ Removing a major portion of the historic architectural metal from a facade instead of repairing or replacing only the portion(s) of deteriorated metal. ¦ Radically changing a metal’s type of finish, patina, historic color or accent theme. ¦ Failing to identify, evaluate and treat the causes of corrosion, like moisture from leaking roofs or flashing. ¦ Placing incompatible metals together without first providing a reliable separation material, thus causing a galvanic or corrosive reaction, and damaging the adjacent metals. -
SPECIFYING STOCK COMPONENTS for ARCHITECTURAL METAL WORK
• About the Instructor • About the Sponsor • Ask an Expert SPECIFYING STOCK COMPONENTS for ARCHITECTURAL METAL WORK Architectural Metals, Railing Systems, and Engineering Information This Online Learning Seminar is available through a professional courtesy provided by: Julius Blum & Co., Inc. P.O. Box 816 Carlstadt, NJ 07072 Toll‐Free: 800‐526‐6293 Tel: 201‐438‐4600 (local NJ) Fax: 201‐438‐6003 Email: [email protected] Web: www.juliusblum.com START ©2013 Julius Blum & Co., Inc. The material contained in this course was researched, assembled, and produced by powered by Julius Blum & Co., Inc. and remains its property. Questions or concerns about the content of this course should be directed to the program instructor. This multimedia product is the copyright of AEC Daily. ©2013 ∙ Table of Contents Slide 1of 70 • About the Instructor • About the Sponsor • Ask an Expert SPECIFYING STOCK COMPONENTS for ARCHITECTURAL METAL WORK Presented by: Julius Blum & Co., Inc. P.O. Box 816. Carlstadt, NJ 07072. Description: The course includes a discussion on: how to choose the best material for your job; available systems and their components; engineering data and the formulas to provide safe installations. To ensure the accuracy of this program material, this course is valid only when listed on AEC Daily’s Online Learning Center. Please click here to verify the status of this course. If the course is not displayed on the above page, it is no longer offered. The American Institute of Architects ∙ Course No. AEC659 ∙ This program qualifies for 1.0 LU/HSW Hour. AEC Daily Corporation is a Registered Provider with The American Institute of Architects Continuing Education Systems (AIA/CES). -
Design Guidelines September, 1999 Table of Contents
Design Guidelines September, 1999 Table of Contents I: Introduction ............................................................................................................................................................................................. 1 A. Preserving the Architectural Heritage............................................................................................................................................. 1 B. History of the Historic District Area............................................................................................................................................... 1 C. Other Areas of Historical Significance........................................................................................................................................... 2 D. Historic Preservation Commission................................................................................................................................................. 3 E. Purpose............................................................................................................................................................................................ 3 F. Scope and Jurisdiction .................................................................................................................................................................... 4 G. Certificate of Appropriateness ....................................................................................................................................................... -
Modified Alkyd Resins As the Versatile Coating Materials Derived from Vegetable Oils
Available online at www.scholarsresearchlibrary.com Scholars Research Library Archives of Applied Science Research, 2017, 9 (1):7-12 (http://scholarsresearchlibrary.com/archive.html) ISSN 097-0X CODEN (USA) AASRC9 Modified Alkyd Resins as the Versatile Coating Materials derived from Vegetable Oils A Hasnat* Natural Product and Polymer Research Laboratory, Department of Chemistry, G. F. College (Affili- ated to M J P Rohilkhand University) Shahjahanpur, U.P. India ABSTRACT Over the years efforts have been made to design eco-friendly specialty chemicals from natural renewable resources. Among different renewable resources vegetable oils obtained from various seeds spotted largely due to their unique properties, functionalities and worldwide abundant availability. In the present review article efforts have been made to highlight the inside of the alkyd resins; oldest polymeric resin derived from vegetable oils, with respect to time to time technological modifications to improve the practical utilities. In view to reduce the use of organic solvents, synthesis and application of different types of water-born alkyds were enlightened in detailed. Furthermore, utilization of nontraditional and nonconventional seed oils in the development of versatile resin also accounted which ultimately provides profitable utilization to them as well as reduces the cost of final products. Keywords: Vegetable oil, Renewable resource, Alkyd resin, Coating materials INTRODUCTION The consumer and industrial both interests in the progress of eco-friendly materials have catapulted the environmentally benign agricultural resources as feedstock for the production of valuable polymers. Over the years efforts have been made to design eco-friendly specialty chemicals from the spectrum of natural renewable resources [1-3]. -
Alkyd Polyesters Creating Performance Through Chemistry
ALKYD POLYESTERS CREATING PERFORMANCE THROUGH CHEMISTRY Measurable Building upon decades spent advancing materials Performance Benefit chemistry innovation, NatureWorks offers solutions based on lactides and lactide intermediates that help innovators within the coatings, adhesives, sealants, and elastomers (C.A.S.E.), toner and surfactant industries realize: Lactides Significant, measurable product performance benefits Optimized Faster R&D Supply Chain Polyols and Scale-Up Move through the R&D process more efficiently and with minimal risk Resins Decrease systems costs via an optimized supply chain We achieve this by coupling tunable Vercet™ lactide- based chemistries with the knowledge of scientists and engineers who understand how to dial in the full capabilities of this versatile product line. NatureWorks Performance Chemicals ALKYD POLYESTERS Using Vercet lactides as a component in your resins enables unique properties including a new way of creating low VOC Custom Solutions for Coatings solvent-borne coatings for substrates such as wood and metal. Coatings for Multiple Markets Performance Benefits Substrates • Wood • Furniture • Low viscosity alkyds for lower VOC’s • Metal • Flooring • Improved flexibility resistance - Anti-corrosion layers • Architecture • Excellent substrate adhesion - Primers • Decorative • Grain enhancement alkyd-based wood varnish • Pigmentable • Renewably-sourced building block 2 NATUREWORKS PERFORMANCE CHEMICALS 16,000 14,000 ) 12,000 .s a P m ( 10,000 C ° 3 2 8,000 @ y t i s 6,000 o sc i v 4,000 P A C 2,000 MEASURABLE0 PERFORMANCE Reference 7.5% Vercet 15% Vercet 25% Vercet Low VOC's from ReducedLactide CoatingLactide ViscosityLactide 16,000 14,000 ) 12,000 .s a P m ( 10,000 C ° 3 2 8,000 @ y t i 60% s 6,000 o Vercet Coating Incumbent Coating sc i 0% v 4,000 P A C ENHANCED GLOSS & GRAIN 2,000 0% 25% Vercet lactide (M700) coating shows 0 excellent gloss, enhanced wood grain, Reference1 7.5% Vercet 15% Vercet 25% Vercet Lactide Lactide Lactide and improved flexibility while having lower VOC's than incumbents. -
Pavement Marking Technical Manual
Pavement Marking Technical Manual This publication was produced by the Direction de l’encadrement et de l’expertise en exploitation and the Direction des matériaux d’infrastructures and edited by the Direction des normes et des documents d’ingénierie of the Ministère des Transports du Québec. The content of this publication is available on the Ministère’s website at the following address: www.transports.gouv.qc.ca. Cette publication est également disponible en français sous le titre “Manuel technique sur le marquage routier”. For more information, you can: • call 511 (in Québec) or 1 888 355-0511 (throughout North America) • consult the website of the Ministère des Transports: www.transports.gouv.qc.ca • write to the following address: Direction des communications Ministère des Transports 500, boulevard René-Lévesque Ouest, bureau 4.010 Montréal (Québec) H2Z 1W7 © Gouvernement du Québec, November 2019 ISBN 978-2-550-87234-4 (PDF) (Original edition: ISBN 978-2-550-85437-1 [PDF]) Legal deposit – 2020 Bibliothèque et Archives nationales du Québec All rights reserved for all countries. Reproduction by any means, and the translation, even in part, of this document are prohibited without the authorization of Publications du Québec. Acknowledgments The preparation of this publication was coordinated by Mélanie Beaulieu, eng., and Frédéric Boily, M. Sc., chemist. We wish to sincerely thank the following persons for their contribution: Johanne Chamberland, infographic designer, Direction des normes et des documents d’ingénierie Michaël Côté, graphic designer , Direction des normes et des documents d’ingénierie Gaétan Leclerc, M. Sc., chemist, Direction des matériaux d’infrastructures Audrée Perreault, eng., Direction de l’encadrement et de l’expertise en exploitation We also wish to thank everyone who took part, directly or indirectly, in preparing this document. -
Nelson Industrial Inc. / Architectural Metals Division / Left: 51 Astor Place, NYC
Nelson Industrial Inc. / Architectural Metals Division / http://www.nelsonii.com/arch Left: 51 Astor Place, NYC Allow us to take you on a journey through the world of metals where size, shape and sheen define style in metal expressions. Experience the unique impact of seeing intriguing geometric achievements in metal, brought to life by the experienced Nelson team. Every installation reflects the collaborative spirit that exists between Nelson and it's customers, in the ongoing creative dialogue of urban life. Ourborite™ A natural looking and very durable laminate applied to an aluminum sheet, available in over a dozen replicated wood veneers. Shown here: Light Cherry Cathedral Karri ACOUSTICS Metal Ceilings and Walls are available both non-perforated (sound reflective) and perforated (sound absorbing). Perforation patterns are limited only by the type of material and thickness chosen and available tooling. Presently Nelson offers more than fifty different perforation patterns ranging from diagonal, staggered to straight as well as round, square and oblong holes. Typically a 15 to 25% perforated open area is required for absorption values (NRC) of .70 or higher. Nelson’s standard acoustical material consists of a Black pre-laminated fleece (SoundTex®) typically bonded to the concealed face of the perforated ceiling panel. For additional sound absorbing qualities and in particular for wall panel applications due to the requirement of a minimum of 8”/200 mm of free airspace behind the perforated metal surface when applied with SoundTex, Nelson recommends filling the void within the panel with a fiberglass or mineral wool inlay in a thickness that matches the void and has a minimum density of 1.5 pounds per cu.ft. -
Alkyd Synthesis & Applications
Alkyd Synthesis & Applications Topics Introduction to Alkyds & Polymers Engineering Design Process Fluorinated Alkyd Coatings Encapsulation of Alkyds for Coatings Principles of Self Healing Polymers Self Healing Gelatin Laboratory What is an Alkyd & Why Should You Care About Them? ➢ ➢ ➢ ➢ ➢ ➢ ➢ ➢ ➢ Wait! What is a Polymer? “You act like we should know what these are.” ❖ ❖ So… What Gives These Polymers Their Specific Characteristics ❖ ❖ Ok….. So, Now I Know What A Polymer Is How Do We Make Them? ❖ ❖ ❖ ❖ Types of Alkyd Synthesis Used Monoglyceride Process ➢ Two Stage Process: 1) Transesterification 2) Direct Esterification ➢ Temperatures between 230oC and 250oC heat Catalyst Glycerol Phthalic (excess) Monoglyceride Linseed Oil Anhydride Alkyd Resin R1 -Linoleic acid R2-Oleic Acid R3- Stearic Acid Fatty Acid Process ➢ One Step process that offers better control, but at a higher cost than the Monoglyceride process. ➢ In this Process the esterification of both aliphatic and aromatic groups occurs at the same time. heat Catalyst Glycerol Phthalic Alkyd Resin Anhydride Modifying Alkyds ➢ ➢ ➢ ➢ ➢ ➢ ➢ heat Fluorinated Alkyd Resin Fluorinated Alkyd Polyol Testing Properties Measures minimum tensile stress Tests impact resistance SEM shows stratification & where atoms are Graphite Pencil Test Tests a coatings hardness Test the adhesion strength ➢ ➢ ➢ Scanning Electron Microscope- Capsule ➢ Alkyd was encapsulated in silica shell. ➢ Not all silica formed capsules ➢ Each Capsule consists of about 53%/TEOS (tetraethyl orthosilicate) and 28% Silica Shell