Henry Taube Papers SC0731SC0731
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The Beckman Center for the History of Chemistry
THE BECKMAN CENTER FOR THE HISTORY OF CHEMISTRY GERHARD HERZBERG Transcript of an Interview Conducted by M. Christine King at The National Research Council of Canada on 5 May 1986 This interview has been designated as Free Access. One may view, quote from, cite, or reproduce the oral history with the permission of CHF. Please note: Users citing this interview for purposes of publication are obliged under the terms of the Chemical Heritage Foundation Oral History Program to credit CHF using the format below: Gerhard Herzberg, interview by M. Christine King at The National Research Council of Canada, Ottawa, Canada, 5 May 1986 (Philadelphia: Chemical Heritage Foundation, Oral History Transcript # 0023). Chemical Heritage Foundation Oral History Program 315 Chestnut Street Philadelphia, Pennsylvania 19106 The Chemical Heritage Foundation (CHF) serves the community of the chemical and molecular sciences, and the wider public, by treasuring the past, educating the present, and inspiring the future. CHF maintains a world-class collection of materials that document the history and heritage of the chemical and molecular sciences, technologies, and industries; encourages research in CHF collections; and carries out a program of outreach and interpretation in order to advance an understanding of the role of the chemical and molecular sciences, technologies, and industries in shaping society. GERHARD HERZBERG 1904 Born in Hamburg, Germany on 25 December Education 1928 Dr. Ing., Darmstadt Technische Universität Professional Experience 1928-1929 Post-doctoral -
New 78 Covers
NATIONAL ACADEMY OF SCIENCES ROBERT SANDERSON MULLIKEN 1896–1986 A Biographical Memoir by R. STEPHEN BERRY Biographical Memoirs, VOLUME 78 PUBLISHED 2000 BY THE NATIONAL ACADEMY PRESS WASHINGTON, D.C. Photo credit: Photo by Harris & Ewing, Washington, D.C. ROBERT SANDERSON MULLIKEN June 7, 1896-October 31, 1986 BY R. STEPHEN BERRY OBERT S. MULLIKEN WAS a quiet, soft-spoken man, yet so R single-minded and determined in his devotion to under- standing molecules that he came to be called “Mr. Molecule.” If any single person’s ideas and teachings dominated the development of our understanding of molecular structure and spectra, it surely was Robert Mulliken. From the begin- ning of his career as an independent scientist in the mid- 1920s until he published his last scientific papers in the early 1980s, he guided an entire field through his penetrat- ing solutions of outstanding puzzles, his identification (or discovery) and analysis of the new major problems ripe for study, and his creation of a school—the Laboratory of Molecular Structure and Spectroscopy or LMSS at the University of Chicago, during its existence the most impor- tant center in the world for the study of molecules. Robert’s background led him naturally into academic sci- ence. He was born in Newburyport, Massachusetts, in a house built by his great-grandfather in about 1798. His father, Samuel Parsons Mulliken, was a professor of chemistry at MIT, which made him a daily commuter between Newburyport and Boston. Samuel Mulliken and his child- hood friend and later MIT colleague Arthur A. Noyes were 3 4 BIOGRAPHICAL MEMOIRS strong influences stirring Robert’s interests in science. -
HENRY TAUBE Department of Chemistry, Stanford University, Stanford, CA 94305
ELECTRON TRANSFER BETWEEN METAL COMPLEXES - RETROSPECTIVE Nobel lecture, 8 December, 1983 by HENRY TAUBE Department of Chemistry, Stanford University, Stanford, CA 94305 This will be an account in historical perspective of the development of part of the field of chemistry that I have been active in for most of my professional life, the field that is loosely described by the phrase “electron transfer in chemical reactions”. In the short time available to me for the preparation of this paper, I can’t hope to provide anything significant in the way of original thought. But I can add some detail to the historical record, especially on just how some of the contributions which my co-workers and I have made came about. This kind of information may have some human interest and may even have scientific interest of a kind which cannot easily be gathered from the scientific journals. For publication there, the course of discovery as it actually took place may be rewritten to invest it with a logic that it did not fully acquire until after the event. Simple electron transfer is realized only in systems such as Ne + Ne +. The + physics already becomes more complicated when we move to N 2 + N 2 for example, and with the metal ion complexes which I shall deal with, where a 2+ typical reagent is Ru(NH 3)6 , and where charge trapping by the solvent, as well as within the molecule, must be taken into account, the complexity is much greater. Still, a great deal of progress has been made by a productive interplay of experiment, qualitative ideas, and more sophisticated theory, involving many workers. -
Robert Mulliken
NATIONAL ACADEMY OF SCIENCES ROBERT SANDERSON MULLIKEN 1896–1986 A Biographical Memoir by R. STEPHEN BERRY Biographical Memoirs, VOLUME 78 PUBLISHED 2000 BY THE NATIONAL ACADEMY PRESS WASHINGTON, D.C. Photo credit: Photo by Harris & Ewing, Washington, D.C. ROBERT SANDERSON MULLIKEN June 7, 1896-October 31, 1986 BY R. STEPHEN BERRY OBERT S. MULLIKEN WAS a quiet, soft-spoken man, yet so R single-minded and determined in his devotion to under- standing molecules that he came to be called “Mr. Molecule.” If any single person’s ideas and teachings dominated the development of our understanding of molecular structure and spectra, it surely was Robert Mulliken. From the begin- ning of his career as an independent scientist in the mid- 1920s until he published his last scientific papers in the early 1980s, he guided an entire field through his penetrat- ing solutions of outstanding puzzles, his identification (or discovery) and analysis of the new major problems ripe for study, and his creation of a school—the Laboratory of Molecular Structure and Spectroscopy or LMSS at the University of Chicago, during its existence the most impor- tant center in the world for the study of molecules. Robert’s background led him naturally into academic sci- ence. He was born in Newburyport, Massachusetts, in a house built by his great-grandfather in about 1798. His father, Samuel Parsons Mulliken, was a professor of chemistry at MIT, which made him a daily commuter between Newburyport and Boston. Samuel Mulliken and his child- hood friend and later MIT colleague Arthur A. Noyes were 3 4 BIOGRAPHICAL MEMOIRS strong influences stirring Robert’s interests in science. -
Henry Taube by J
Chemical Education Today Nobel Centennial Essays A Century of Chemical Dynamics Traced through the Nobel Prizes W 1983: Henry Taube by J. Van Houten Nobel Prize in Chemistry 1983 Photo by Rudy Baum Henry Taube (1915– ) for his work on the mechanisms of electron transfer Henry Taube, shown on reactions, especially in metal complexes the cover of C&E News. This is the eighth in a series of essays (1) written in com- Reprinted with permis- memoration of the centennial of the Nobel Prize, examin- sion from Chemical & ing the history of chemical dynamics in the 20th century.W Engineering News, May 21, 1984. © As his Nobel citation (2) states, Henry Taube studied elec- Copyright 1984 Ameri- tron transfer reactions of transition metal complexes. The can Chemical Society. Nobel Prize to Taube came exactly seventy years after it was awarded to Alfred Werner (3) for developing the structural chemistry of inorganic transition metal complexes. During the entire 20th century, Taube and Werner are the only in- to Werner’s. His early mechanistic studies relied heavily on organic transition metal chemists to win a Nobel Prize.1 In isotope tracer techniques developed by George de Hevesy, the fact, many of the complexes that Taube studied were first 1943 Nobel Laureate (1d). The second of the 100 references prepared or characterized by Werner. in Taube’s Nobel lecture (6) is to a 1920 paper where de Taube’s citation (2) concludes with the statement: “There Hevesy used naturally occurring lead isotopes to follow the is no doubt that Henry Taube is one of the most creative exchange reaction between Pb2+ and Pb4+ (7). -
Walter Elsasser in Mind
NATIONAL ACADEMY OF SCIENCES W A L T E R M . E LSASSER 1904—1991 A Biographical Memoir by H A R R Y RU BIN Any opinions expressed in this memoir are those of the author(s) and do not necessarily reflect the views of the National Academy of Sciences. Biographical Memoir COPYRIGHT 1995 NATIONAL ACADEMIES PRESS WASHINGTON D.C. WALTER M. ELSASSER March 20, 1904–October 14, 1991 BY HARRY RUBIN ALTER ELSASSER WAS TRAINED as a theoretical physicist Wand made several important contributions to funda- mental problems of atomic physics, including interpreta- tion of the experiments on electron scattering by Davisson and Germer as an effect of de Broglie’s electron waves and recognition of the shell structure of atomic nuclei. Circum- stances later turned his interests to geophysics, where he had important insights about the radiative transfer of heat in the atmosphere and fathered the generally accepted dy- namo theory of the earth’s magnetism. He devoted a major part of the last fifty years of his life to developing a theory of organisms, concentrating on the basic features that dis- tinguish between living and inanimate matter, and he pro- duced four books on the subject. While his contribution to biology was not widely acknowledged, he felt it would even- tually be seen as his major scientific achievement. BACKGROUND AND YOUTH Walter was born in Mannheim, Germany, the older of two children of Maurice and Johanna Elsasser. His sister, Maria, was three years younger than him. His grandparents were prosperous Jewish merchants, but his father was a law- 103 104 BIOGRAPHICAL MEMOIRS yer who was caught up in the great wave of assimilation and both parents became nonpracticing Protestants. -
Gerhard Herzberg
The Nobel Prize in Chemistry 1971 Gerhard Herzberg Gerhard Herzberg Born: 25 December 1904, Hamburg, Germany Died: 3 March 1999, Ottawa, Canada Affiliation at the time of the award: National Research Council of Canada, Ottawa, Canada Prize motivation: "for his contributions to the knowledge of electronic structure and geometry of molecules, particularly free radicals" Field: Physical chemistry, molecular structures Information taken from The Official Website of the Nobel Prize nobelprize.org “…series of bands with complicated fine structure in the red and photographic infrared… This spectrum was analysed as that of an asymmetric top…” (1) Geometrical structure of CH2 in the three lowest states (1) Spectra and quotes from the Nobel Lecture by G. Herzberg The Nobel Prize in Physics 1918 Max Planck Max Karl Ernst Ludwig Planck Born: 23 April 1858, Kiel, Schleswig (now Germany) Died: 4 October 1947, Goettingen, West Germany Affiliation at the time of the award: Berlin University,Berlin, Germany Prize motivation: "in recognition of the services he rendered to the advancement of Physics by his discovery of energy quanta" Field: Quantum mechanics Max Planck received his Nobel Prize one year later, in 1919. Information taken from The Official Website of the Nobel Prize nobelprize.org The Nobel Prize in Physics 1922 Niels Bohr Niels Henrik David Bohr Born: 7 October 1885, Copenhagen, Denmark Died: 18 November 1962, Copenhagen, Denmark Affiliation at the time of the award: Copenhagen University, Copenhagen, Denmark Prize motivation: "for his services -
Future of Electrochemistry in Light of History and the Present Conditions
Journal of Solid State Electrochemistry (2020) 24:2089–2092 https://doi.org/10.1007/s10008-020-04585-3 FEATURE ARTICLE Future of electrochemistry in light of history and the present conditions György Inzelt1 Received: 26 March 2020 /Revised: 26 March 2020 /Accepted: 29 March 2020 / Published online: 15 April 2020 # The Author(s) 2020 General thoughts would not be financed or financed properly, the development of science and consequently that of the technology will stop or We may agree with the saying which is attributable to Niels at least will slow down. The decision makers want an imme- Bohr who said: “It is difficult to make predictions, especially diate success for the money of the taxpayers. The applied about the future.” Nevertheless, the past can give ideas in this research and especially the innovation phase needing the cap- respect and the present circumstances set the course. ital also for buildings and machines want orders of magnitude However, the great breakthroughs cannot be predicted. higher money than the grant for some thousand researchers at Without any exaggeration, we may declare that electro- the universities and institutes. chemistry has played, plays, and will play an important role The support of the basic research is not a wasted money, in the scientific and technological advancement, and conse- and it underlies the future. I would like to draw the attention to quently the quality of life of the people. We cannot imagine another important point: it is the proper education. The well- the everyday life without electricity. We have had electric prepared and competent researchers are essential for the prog- current for 220 years since Volta constructed his pile. -
OLC Denies FOIA Request for Opinion on Executive Orders
FEDERATION OF AMERICAN SCIENTISTS Board of Sponsors 1725 DeSales Street NW, 6th floor [email protected] (Partial List) Washington, DC 20036 www.fas.org *Sidney Altman Phone: (202) 546-3300 Fax: (202) 675-1010 Bruce Ames F.A.S. *Philip W. Anderson *Kenneth J. Arrow *Julius Axelrod *David Baltimore Frank von Hippel Hal Feiveson Henry C. Kelly Paul Beeson Chairman Secretary-Treasurer President *Baruj Benacerraf *Hans A. Bethe *J. Michael Bishop *Nicolaas Bloembergen *Norman Borlaug *Paul Boyer March 11, 2008 *Owen Chamberlain (202)454-4691 Morris Cohen *Stanley Cohen [email protected] Mildred Cohn *Leon N. Cooper Elizabeth Farris *E. .J. Corey Paul B. Cornely Office of Legal Counsel *James Cronin *Johann Deisenhofer Room 5515, 950 Pennsylvania Avenue, NW Carl Djerassi Ann Druyan Department of Justice *Renato Dulbecco John T. Edsall Washington, DC 20530-0001 Paul R. Ehrlich By fax: 202-514-0563 George Field *Val L. Fitch Jerome D. Frank *Jerome I. Friedman Dear Ms. Farris: *John Kenneth Galbraith *Walter Gilbert *Donald Glaser *Sheldon L. Glashow This is a request under the Freedom of Information Act. Marvin L. Goldberger *Joseph L. Goldstein *Roger C. L. Guillemin We request a copy of an Office of Legal Counsel opinion from the George *Dudley R. Herschbach *Roald Hoffmann W. Bush Administration pertaining in part to the efficacy of executive John P. Holdren *David H. Hubel orders. *Jerome Karle Nathan Keyfitz *H. Gobind Khorana *Arthur Kornberg In particular, Senator Sheldon Whitehouse stated on the Senate floor on *Edwin G. Krebs *Willis E. Lamb December 7 that he had examined an OLC opinion which included, *Leon Lederman *Edward Lewis according to his notes, the following statement or something resembling it: *William N. -
CCB 002.Pdf (1.169Mb)
DEPARTMENT OF CHEMISTRY CORNELL UNIVERSITY ITHACA, NEW YORK 14850 NE WSL. E: T TEH Issue No. 2 August 1968 The response to the first issue of the Chemistry Department Newsletter was extremely gratifying and well worth the effort put into it. As promised, the Newsletter will come out twice a year, each issue about a month before the national American Chemical Society meetings. A number of "lost11 names turned up as a result of the first issue and also some very interesting letters, parts of which have led to stories in Lauby's Recollections column. It .even generated visits by some of you. I hope all of this keeps up; we'd like to hear from and see more of you. Another result of the first Newsletter was the tremendous attendance at the Cornell Social Hour at the San Francisco meeting. While other social hours have been well attended, the one in San Francisco was pleasantly crowded. It made for renewal of many old friendships and the making of some new ones. We're hoping for an even bigger and better one at the Atlantic City meeting. There the Cornell Social Hour is scheduled for 5:30, Tuesday afternoon, September 10, in the Diamond Jim Brady Room of the Shelburne Hotel. The plans for Baker renovation are moving rapidly. The reno- vation has gone out for bid and bids are due back at about the time this Newsletter will be mailed. The contract should be signed shortly thereafter. The actual renovation will start in late August or very early September. -
FAS Asks Justice Inspector General To
FEDERATION OF AMERICAN SCIENTISTS T: 202/546-3300 1717 K Street NW #209 Washington, DC 20036 www.fas.org F: 202/675-1010 [email protected] Board of Sponsors (Partial List) * Sidney Altman October 22, 2003 * Philip W. Anderson * Kenneth J. Arrow (202)454-4691 * Julius Axelrod * David Baltimore [email protected] * Baruj Benacerraf * Paul Berg Office of the Inspector General * Hans A. Bethe * J. Michael Bishop U.S. Department of Justice * Nicolaas Bloembergen * Norman Borlaug 950 Pennsylvania Avenue, NW * Paul Boyer Ann Pitts Carter Room 4322 * Owen Chamberlain Morris Cohen Washington, DC 20530 * Stanley Cohen Mildred Cohn By fax: (202)616-9898 * Leon N. Cooper * E. J. Corey * James Cronin * Johann Deisenhofer Ann Druyan * Renato Dulbecco Dear Sir: Paul R. Ehrlich George Field * Val L. Fitch * Jerome I. Friedman I am writing to report a possible violation of law by Department of Justice (DoJ) * Robert Furchgott John Kenneth Galbraith officials involving the unauthorized withholding of information. * Riccardo Giacconi * Walter Gilbert * Donald Glaser * Sheldon L. Glashow The matter concerns a DoJ report entitled "Support for the Department in Marvin L. Goldberger * Joseph L. Goldstein Conducting an Analysis of Diversity in the Attorney Workforce" dated June 14, * Roger C. L. Guillemin * Herbert A. Hauptman 2002. A copy of the report is posted in heavily censored form here: * Dudley R. Herschbach * Roald Hoffmann John P. Holdren * David H. Hubel http://www.usdoj.gov/04foia/readingrooms/diversityanalysis.pdf * Jerome Karle Carl Kaysen * H. Gobind Khorana * Arthur Kornberg The title page of the report indicates that "All excisions are made pursuant to * Edwin G. -
Federation of American Scientists
FEDERATION OF AMERICAN SCIENTISTS T: 202/546-3300 1717 K Street NW #209 Washington, DC 20036 www.fas.org F: 202/675-1010 [email protected] Board of Sponsors (Partial List) November 12, 2001 *Sidney Altman *Philip W. Anderson Hon Tom Daschle Hon J. Dennis Hastert *Kenneth J. Arrow *Julius Axelrod Senate Majority Leader Speaker of the House *David Baltimore *Baruj Benacerraf *Hans A. Bethe *J. Michael Bishop Hon Trent Lott Hon Richard Gephardt *Nicolaas Bloembergen *Norman Borlaug Senate Minority Leader House Minority Leader *Paul Boyer Ann Pitts Carter *Owen Chamberlain In the interest of national security we urge you to deny funding for any program, project, or Morris Cohen *Stanley Cohen activity that is inconsistent with the Anti-Ballistic Missile (ABM) Treaty. The tragic events Mildred Cohn *Leon N. Cooper of September 11 eliminated any doubt that America faces security needs far more substantial *E. J. Corey *James Cronin than a technically improbable defense against a strategically improbable Third World *Johann Deisenhofer ballistic missile attack. Ann Druyan *Renato Dulbecco John T. Edsall Paul R. Ehrlich Regarding the probable threat, the September 11 attacks have dramatized what has been George Field obvious for years: A primitive ICBM, with its dubious accuracy and reliability and bearing *Val L. Fitch *Jerome I. Friedman a clear return address, is unattractive to a terrorist and a most improbable delivery system for John Kenneth Galbraith *Walter Gilbert a terrorist weapon. Devoting massive effort and expense to countering the least probable *Donald Glaser and least effective threat would be unwise. *Sheldon L. Glashow Marvin L. Goldberger *Joseph L.