FLAME RETARDANTS in PRINTED CIRCUIT BOARDS Chapter 3
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Synergistic Effects of Zinc Borate and Aluminum Trihydrate on Flammability Behaviour of Aerospace Epoxy System
SYNERGISTIC EFFECTS OF ZINC BORATE AND ALUMINUM TRIHYDRATE ON FLAMMABILITY BEHAVIOUR OF AEROSPACE EPOXY SYSTEM A. De Fenzo1,2, Cristina Formicola1,2 , Mauro Zarrelli1,2*, Alberto Frache3 Michele Giordano1,2 and Giovanni Camino3 1 IMCB – Institute of Composite and Biomedical Materials, CNR – Research National Council, P E. Fermi 1, Portici 80055, ITALY 2 IMAST – Technological District on Polymeric and Composite Materials Engineering, P E. Fermi 1, Portici 80055, ITALY 3 Material Science and Chemical Engineering Dept., Polytechnic of Turin in Alessandria, Via Teresa Michel 5, 15100 Alessandria, ITALY *[email protected] SUMMARY Flame retardancy of mono-component epoxy resin, used for aerospace composites, treated with zinc borate (ZB), aluminum trihydrate (ATH) and their mixtures at different percentages have been investigated by morphological and thermal characterization. Cone calorimeter data reveal that peak HRR decreases when synergistic effects between additives occur. Keywords: Epoxy Resin; Fire retardancy; Zinc borate; Aluminum trihydrate; Cone calorimeter INTRODUCTION Zinc borate is an effective inorganic flame retardant and it possesses characteristic properties of flame retardancy (FR), smoke suppression, promoting charring, etc.[1-2] particularly important according to new fire standards. Zinc borate is commonly used as multifunctional flame retardant in combination with other halogenated or halogen-free flame retardant systems to boost FR properties [3-4]. Its efficacy depends upon the type of halogen source (aliphatic versus aromatic) and the used polymer root. The zinc borate can generally display synergistic effects with antimony oxide in fire retardancy. In the presence of aluminium trihydroxide (ATH) or magnesium hydroxide (Mg(OH)2), this synergy can be augmented significantly [5]. -
Generation of Carbon Dioxide and Mobilization of Antimony Trioxide by Fungal Decomposition of Building Materials John D
University of South Florida Scholar Commons Graduate Theses and Dissertations Graduate School 3-25-2005 Generation of Carbon Dioxide and Mobilization of Antimony Trioxide by Fungal Decomposition of Building Materials John D. Krause University of South Florida Follow this and additional works at: https://scholarcommons.usf.edu/etd Part of the American Studies Commons Scholar Commons Citation Krause, John D., "Generation of Carbon Dioxide and Mobilization of Antimony Trioxide by Fungal Decomposition of Building Materials" (2005). Graduate Theses and Dissertations. https://scholarcommons.usf.edu/etd/730 This Dissertation is brought to you for free and open access by the Graduate School at Scholar Commons. It has been accepted for inclusion in Graduate Theses and Dissertations by an authorized administrator of Scholar Commons. For more information, please contact [email protected]. Generation of Carbon Dioxide and Mobilization of Antimony Trioxide by Fungal Decomposition of Building Materials by John D. Krause A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy Department of Environmental and Occupational Health College of Public Health University of South Florida Major Professor: Yehia Y. Hammad, Sc.D. Noreen D. Poor, Ph.D. Ann C. Debaldo, Ph.D. Diane Te Strake, Ph.D. Date of Approval: March 25, 2005 Keywords: mold, mould, carbon dioxide, antimony trioxide, flame retardant © Copyright 2005, John D. Krause Dedication For their love, support, patience and understanding throughout this endeavor, I dedicate this work to my family, daughter, and most of all, my loving wife. Acknowledgements I would like to acknowledge the following individuals and companies for their assistance in this research. -
Moo3 Thickness, Thermal Annealing and Solvent Annealing Effects on Inverted and Direct Polymer Photovoltaic Solar Cells
Materials 2012, 5, 2521-2536; doi:10.3390/ma5122521 OPEN ACCESS materials ISSN 1996-1944 www.mdpi.com/journal/materials Article MoO3 Thickness, Thermal Annealing and Solvent Annealing Effects on Inverted and Direct Polymer Photovoltaic Solar Cells Sylvain Chambon 1, Lionel Derue 1, Michel Lahaye 2, Bertrand Pavageau 3, Lionel Hirsch 1 and Guillaume Wantz 1,* 1 University Bordeaux, CNRS, IMS, UMR 5218, 33400 Talence, France; E-Mails: [email protected] (S.C.); [email protected] (L.D.); [email protected] (L.H.) 2 University Bordeaux, CNRS, ICMCB, UPR 9048, 33600 Pessac, France; E-Mail: [email protected] 3 University Bordeaux, CNRS, RHODIA, LOF, UMR 5258, 33600 Pessac, France; E-Mail: [email protected] * Author to whom correspondence should be addressed; E-Mail: [email protected]; Tel.: +33-5-40-00-66-30; Fax: +33-5-40-00-66-31. Received: 1 November 2012; in revised form: 16 November 2012 / Accepted: 19 November 2012 / Published: 27 November 2012 Abstract: Several parameters of the fabrication process of inverted polymer bulk heterojunction solar cells based on titanium oxide as an electron selective layer and molybdenum oxide as a hole selective layer were tested in order to achieve efficient organic photovoltaic solar cells. Thermal annealing treatment is a common process to achieve optimum morphology, but it proved to be damageable for the performance of this kind of inverted solar cells. We demonstrate using Auger analysis combined with argon etching that diffusion of species occurs from the MoO3/Ag top layers into the active layer upon thermal annealing. -
Synthesis, Characterization, and Application of Molybdenum Oxide Nanomaterials Michael S
University of South Florida Scholar Commons Graduate Theses and Dissertations Graduate School 11-9-2017 Synthesis, Characterization, and Application of Molybdenum Oxide Nanomaterials Michael S. McCrory University of South Florida, [email protected] Follow this and additional works at: https://scholarcommons.usf.edu/etd Part of the Mechanical Engineering Commons Scholar Commons Citation McCrory, Michael S., "Synthesis, Characterization, and Application of Molybdenum Oxide Nanomaterials" (2017). Graduate Theses and Dissertations. https://scholarcommons.usf.edu/etd/7424 This Dissertation is brought to you for free and open access by the Graduate School at Scholar Commons. It has been accepted for inclusion in Graduate Theses and Dissertations by an authorized administrator of Scholar Commons. For more information, please contact [email protected]. Synthesis, Characterization, and Application of Molybdenum Oxide Nanomaterials by Michael S. McCrory A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy Department of Mechanical Engineering College of Engineering University of South Florida Co-Major Professor: Ashok Kumar, Ph.D. Co-Major Professor: Manoj K. Ram, Ph.D. Daniel Hess, Ph.D. Sylvia Thomas, Ph.D. Sagar Pandit, Ph.D. Date of Approval: November 2, 2017 Keywords: Battery, Decontamination, Photocatalyst, Adsorbent, Methylene Blue Copyright © 2017, Michael S. McCrory DEDICATION I’d like to dedicate this work to grandma, Janet, and my parents, Gail and James. Thank you for everything; the love, support, encouragement, etc. I’d also like to dedicate this work to my soon-to-be wife, Courtney. Words just cannot describe my feelings here, so I’ll simply say thank you for everything and I love you. -
Solid Phase Synthesis of Anhydrous Zinc Borate from Zinc and Boron Oxide and Utilization As a Flame Retardant in Dye and Textile
Gazi University Journal of Science GU J Sci 27(3):987-991 (2014) Solid Phase Synthesis of Anhydrous Zinc Borate from Zinc and Boron Oxide and Utilization as a Flame Retardant in Dye and Textile Barış AYAR 1, Metin GÜRÜ 2, Çetin ÇAKANYILDIRIM 3,♠ 1Hitit University, Ömer Derindere Vacational High School, 19500 Osmancık, Çorum, Turkey 2Gazi University, Eng. Faculty, Chemical Eng. Depart. 06570, Maltepe-Ankara, Turkey 3 Hitit University, Eng. Faculty, Chemical Eng. Depart. 19030 Çorum, Turkey Received:30/01/2014 Revised: 01/04/2014 Accepted:17/04/2014 ABSTRACT Durability of materials against flame and stability at high temperatures are very important in order to increase the field of use. Non-flammability is not the only requirement; these materials should not have toxic gas products during the burning, also. Anhydrous zinc borate was chosen as flame retardant due to its advantages, such as; light weight, high melting point, low thermal expansion, and intrinsic smoke suppression and corrosion resistance properties. For the synthesis, metallic zinc and anhydrous boron oxide powders were mixed in the attritor working at 600 rpm. Powder product was sintered under atmospheric conditions according to the phase change temperature that was determined by TGA-DSC analyses. Synthesized zinc borate was grinned up to nanometer size by Spex type grinder. Zinc borate was introduced in binder to decrease the flammability. The properties of the produced materials were determined and compared by LOI, TGA-DSC, SEM and oven according to the zinc borate ingredients. Key Words : Zinc borate, Pigment, Flame retardant, Flame resistant dye 1. INTRODUCTION Dyes are widespread used in our lives as a coating many cases, alumina, magnesium hydroxide, antimony material to resist corrosion [1]. -
4. Inorganic Flame Retardants. Plastics Can Be Given Flame Retardant Characteristics by Introducing Elements of Organic, Inorganic and Halogen Origin
4. Inorganic Flame Retardants. Plastics can be given flame retardant characteristics by introducing elements of organic, inorganic and halogen origin. Such elements include magnesium, aluminium, phosphorous, molybdenum, antimony, tin, chlorine and bromine. Flame retardants are added in either the manufacturing step of the polymer or the compounding step of the polymeric article. Phosphorous bromine and chlorine are usually included as some organic compound. Inorganic flame retardants are usually added together with other flame retardants to provide a more efficient flame retardant action through synergism. Halogen flame retardants usually need an addition of about 40% in order to be effective, and this affects the properties of the polymer quite negatively. Structural integrity of the polymer article is often very important, and a drastic decrease in strength and other mechanical properties is simply not acceptable. The efficiency of halogen flame retardants is often enhanced by the addition of inorganic flame retardants. A smaller mass percentage halogen flame retardant is now needed, so the adverse effect on the polymer properties is also reduced (Touval, 1993) . 4.1 Antimony Compounds The antimony compounds used for flame retardancy include antimony trioxide, antimony pentoxide and antimony-metal compounds. In 1990 in the United States alone, the use of antimony trioxide amounted to 20 000 metric tons just for the flame retardancy of plastics. Antimony oxide is readily found in nature but in very impure form. This is not suitable for 29 direct use as flame retardant, so antimony oxide is often rather produced from antimony metal. There are therefore many different grades of antimony oxide that can be used for flame retardants. -
The Development of Zinc Borate Production Process
A-PDF MERGER DEMO The Development of Zinc Borate Production Process By H.Emre ELTEPE A Dissertation Submitted to the Graduate School in Partial Fulfillment of the Requirement for the Degree of MASTER OF SCIENCE Department: Chemical Engineering Major: Chemical Engineering ø]PLU,QVWLWXWHRI7HFKQRORJ\ ø]PLU7XUNH\ November, 2004 We approve the thesis of H.Emre ELTEPE Date of Signature ………………………………………….. 21.12.2004 Prof. Dr. Devrim BALKÖSE Supervisor Department of Chemical Engineering ………………………………………….. 21.12.2004 Prof. Dr. Semra ÜLKÜ Co-Supervisor Department of Chemical Engineering ………………………………………….. 21.12.2004 Prof.Dr. Tamerkan ÖZGEN Department of Chemistry ………………………………………….. 21.12.2004 Assist.Prof.Fehime ÖZKAN Department of Chemical Engineering ………………………………………….. 21.12.2004 Assist.Prof.$\VXQ62)82ö/8 Department of Chemical Engineering ………………………………………….. 21.12.2004 Prof. Dr. Devrim BALKÖSE Head of Department ACKNOWLEDGEMENT I would like to express my deepest gratefullness to my advisors Prof. Devrim BALKÖSE and Prof. Semra ÜLKÜ for their support, guidance and sharing their valuable experiences throughout the study and the preparation of the thesis which has been a very important experience for my future carreer. I would like to state my special thanks to my friends $\NXW(5'2ö'8 Sevdiye ATAKUL, Mehmet GÖNEN, gQL] %ø562< DQG <DUNÕQ g=*$5ø3 for their help, encouragement and friendship throughout this project. I would also like to thank to Gökhan (5'2ö$1, Duygu2÷X].,/,d 0LQH%$+d(&ø and Evrim YAKUT for their help for SEM, EDX and X-RAY analyses, Burcu ALP for TGA analyses and Özlem Ça÷lar DUVARCI and Filiz ÖZMIHÇI for FTIR analysis ùHULIH ùDKLQ g=$/3 DQG %HOJLQ TUNÇEL for their help throughout the experiments. -
123. Antimony
1998:11 The Nordic Expert Group for Criteria Documentation of Health Risks from Chemicals 123. Antimony John Erik Berg Knut Skyberg Nordic Council of Ministers arbete och hälsa vetenskaplig skriftserie ISBN 91–7045–471–x ISSN 0346–7821 http://www.niwl.se/ah/ah.htm National Institute for Working Life National Institute for Working Life The National Institute for Working Life is Sweden's center for research and development on labour market, working life and work environment. Diffusion of infor- mation, training and teaching, local development and international collaboration are other important issues for the Institute. The R&D competence will be found in the following areas: Labour market and labour legislation, work organization and production technology, psychosocial working conditions, occupational medicine, allergy, effects on the nervous system, ergonomics, work environment technology and musculoskeletal disorders, chemical hazards and toxicology. A total of about 470 people work at the Institute, around 370 with research and development. The Institute’s staff includes 32 professors and in total 122 persons with a postdoctoral degree. The National Institute for Working Life has a large international collaboration in R&D, including a number of projects within the EC Framework Programme for Research and Technology Development. ARBETE OCH HÄLSA Redaktör: Anders Kjellberg Redaktionskommitté: Anders Colmsjö och Ewa Wigaeus Hjelm © Arbetslivsinstitutet & författarna 1998 Arbetslivsinstitutet, 171 84 Solna, Sverige ISBN 91–7045–471–X ISSN 0346-7821 Tryckt hos CM Gruppen Preface The Nordic Council is an intergovernmental collaborative body for the five countries, Denmark, Finland, Iceland, Norway and Sweden. One of the committees, the Nordic Senior Executive Committee for Occupational Environmental Matters, initiated a project in order to produce criteria documents to be used by the regulatory authorities in the Nordic countries as a scientific basis for the setting of national occupational exposure limits. -
Safety Data Sheet According to 1907/2006/EC, Article 31 Printing Date 17.07.2021 Revision: 14.07.2021
Page 1/6 Safety data sheet according to 1907/2006/EC, Article 31 Printing date 17.07.2021 Revision: 14.07.2021 SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Cobalt oxide-molybdenum oxide on alumina (3.5% CoO, 14% MoO3) · Item number: 27-0480 · 1.2 Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: Strem Chemicals, Inc. 7 Mulliken Way NEWBURYPORT, MA 01950 USA [email protected] · Further information obtainable from: Technical Department · 1.4 Emergency telephone number: EMERGENCY: CHEMTREC: + 1 (800) 424-9300 During normal opening times: +1 (978) 499-1600 SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 The product is not classified according to the CLP regulation. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 Void · Hazard pictograms Void · Signal word Void · Hazard statements Void · Precautionary statements P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. -
Toxicological Profile for Antimony
ANTIMONY AND COMPOUNDS 11 CHAPTER 2. HEALTH EFFECTS 2.1 INTRODUCTION The primary purpose of this chapter is to provide public health officials, physicians, toxicologists, and other interested individuals and groups with an overall perspective on the toxicology of antimony. It contains descriptions and evaluations of toxicological studies and epidemiological investigations and provides conclusions, where possible, on the relevance of toxicity and toxicokinetic data to public health. When available, mechanisms of action are discussed along with the health effects data; toxicokinetic mechanistic data are discussed in Section 3.1. A glossary and list of acronyms, abbreviations, and symbols can be found at the end of this profile. To help public health professionals and others address the needs of persons living or working near hazardous waste sites, the information in this section is organized by health effect. These data are discussed in terms of route of exposure (inhalation, oral, and dermal) and three exposure periods: acute (≤14 days), intermediate (15–364 days), and chronic (≥365 days). As discussed in Appendix B, a literature search was conducted to identify relevant studies examining health effect endpoints. Figure 2-1 provides an overview of the database of studies in humans or experimental animals included in this chapter of the profile. These studies evaluate the potential health effects associated with inhalation, oral, or dermal exposure to antimony, but may not be inclusive of the entire body of literature. A systematic review of the scientific evidence of the health effects associated with exposure to antimony was also conducted; the results of this review are presented in Appendix C. -
Hydrated Zinc Borates and Their Industrial Use
Review Hydrated Zinc Borates and Their Industrial Use David M. Schubert AvidChem LLC, Lone Tree, CO, 80124 USA; [email protected] Received: 17 June 2019; Accepted: 26 June 2019; Published: 30 June 2019 Abstract: Zinc borates are important chemical products having industrial applications as functional additives in polymers, bio-composites, paints and ceramics. Of the thirteen well documented hydrated binary zinc borates, Zn[B3O4(OH)3] (2ZnO∙3B2O3∙3H2O) is manufactured in the largest quantity and is known as an article of commerce as 2ZnO∙3B2O3∙3.5H2O. Other hydrated zinc borates in commercial use include 4ZnO∙B2O3∙H2O, 3ZnO∙3B2O3∙5H2O and 2ZnO∙3B2O3∙7H2O. The history, chemistry, and applications of these and other hydrated zinc borate phases are briefly reviewed, and outstanding problems in the field are highlighted. Keywords: borate; zinc; polymer additive; fire retardant; bio-composite 1. Introduction Zinc borates rank in the top ten boron-containing industrial chemicals in terms of global production and use [1]. Tens of thousands of tons of zinc borates are used annually in various applications utilizing their special properties. The family of binary zinc borates of general composition aZnO∙bB2O3∙cH2O, where c is >0, contains at least thirteen unique crystalline compounds; the most important these is 2ZnO∙3B2O3∙3H2O, or Zn[B3O4(OH)3], which is usually referred to in commerce as 2ZnO∙3B2O3∙3.5H2O, owing to an early error in characterization. Major applications of zinc borates include lending durability to bio-composite building materials and improving fire performance and electrical properties of polymers. Zinc borates also serve as corrosion inhibitors, fire retardants and preservatives in coatings, fluxes in ceramic bodies and glazes, hosts for scintillation compounds, and ingredients in agricultural micronutrients. -
The Radiochemistry of Molybdenum COMMITTEE on NUCLEAR SCIENCE
National Academy of Sciences National Research council s NUCLEAR SCIENCE SERIES The Radiochemistry of Molybdenum COMMITTEE ON NUCLEAR SCIENCE L. F. CURTISS, Chairman ROBLEY D. EVANS, ViceCkainna?I NationalBureau ofStandards MassachusettsInstituteofTechnology J.A. DeJUREN, Secretary WestinghouseElectricCorporation H. J. CURTIS G. G. MANOV BrookhavenNationalLaboratory Tracerlah,Inc. SAMUEL EPSTEIN W. WAYNE MEINKE CaliforniaInstituteofTechnology Universityof Michigan HERBERT GOLDSTEIN A. H. SNELL NuclearDevelopmentCorporationof Oak Ridge NationalLaboratory America E. A. UEHLING H. J. GOMBERG UniversityofWashington UniversityofMichigan D. M. VAN PATTER E. D. KLEMA BartolResearch Foundation NorthwesternUniversity ROBERT L. PLATZMAN Argonne NationalLaboratory LIA SON MEMBERS PAUL C. AEBERSOLD W. D. URRY Atomic EnerW Commission U. S.Air Force J.HOWARD McMILLEN WILLIAM E. WRIGHT NationalScienceFoundation OfficeofNavalResearch SUBCOMMITTEE ON RADIOCHEMISTRY W. WAYNE MEINICE, Chai?man EARL HYDE Universityof Mlchlgan UniversityofCalifornia(Berkeley) NATHAN BALLOU HAROLD KIRBY Navy RadiologicalDefenseLaboratory Mound Laboratory GREGORY R. CHOPPIN GEORGE LEDDICOTTE FloridaStateUniver~ity Oak Ridge NationalLaboratory GEORGE A. COWAN ELLIS P. STEINBERG Los Alsmos ScientificLshoratory Argonne NationalLaboratory ARTHUR W. FAIRHALL PETER C. STEVENSON UniversityofWashington UniversityofCalifornia(Llvermore) HARMON FINSTON LEO YAFFE Brookhaven,NationalLaboratory McGillUniversity .. The Radiochernistry d Molybdenum By E. hf.SCADDEN and N. E. BALLOU U. S.