Kit Components 05/23/2019 Product Code Description N9306048

05/23/2019 Kit Components

Product code Description

N9306048 Replacement Cartridge Set

Components: N9306003 Hydrocarbon/Moisture-Removing Replacement Cartridge N9306004 TRAP-HI CAPACITY REPL OXYGEN N9306005 Indicating Oxygen-Removing Replacement Cartridge

Page 1/10 Safety Data Sheet acc. to OSHA HCS Printing date 05/23/2019 Review date 05/23/2019

* 1 Identification

∙ Product identifier ∙ Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge ∙ Article number N9306003 ∙ Application of the substance / the mixture Laboratory chemicals ∙ Details of the supplier of the safety data sheet ∙ Manufacturer/Supplier:

PerkinElmer, Inc. 710 Bridgeport Avenue Shelton, Connecticut 06484 USA [email protected] 203-925-4600 ∙ Emergency telephone number: CHEMTREC (within US) 800-424-9300 CHEMTREC (from outside US) +1 703-527-3887 (call collect) CHEMTREC (within AU) +(61)-290372994

* 2 Hazard(s) identification

∙ Classification of the substance or mixture

Health hazard

Carc. 1A H350 May cause cancer.

Corrosion

Eye Dam. 1 H318 Causes serious eye damage. ∙ Label elements ∙ GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ∙ Hazard pictograms GHS05, GHS08 ∙ Signal word Danger ∙ Hazard-determining components of labeling: calcium oxide Quartz (SiO2) ∙ Hazard statements H318 Causes serious eye damage. H350 May cause cancer. ∙ Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P308+P313 IF exposed or concerned: Get medical advice/attention. (Contd. on page 2) USA

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 1) P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ∙ Classification system: ∙ NFPA ratings (scale 0 - 4) Health = 3 1 Fire = 1 3 0 Reactivity = 0 ∙ HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0 ∙ Other hazards The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes. This product has been tested according to the United Nations Transport of Dangerous Goods test protocol for a “self-heating substance”. It has been specifically determined that this product does not meet the definition of a self heating substance or any other hazard class, and therefore is not a hazardous material. ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable.

* 3 Composition/information on ingredients

∙ Chemical characterization: Mixtures ∙ Description: Mixture of the substances listed below with nonhazardous additions. ∙ Hazardous components: 1344-28-1 aluminium oxide 13.9% 1305-78-8 calcium oxide Eye Dam. 1, H318 7.0% 14808-60-7 Quartz (SiO2) Carc. 1A, H350 1.7% ∙ Additional Components Carbon - non-pyrophoric 47.8% 7631-86-9 silicon dioxide, chemically prepared 22.6% 1313-59-3 SODIUM OXIDE 7.0%

* 4 First-aid measures

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 2) ∙ Most important symptoms and effects, both acute and delayed No further relevant information available. ∙ Indication of any immediate medical attention and special treatment needed No further relevant information available.

* 5 Fire-fighting measures

∙ Extinguishing media ∙ Suitable extinguishing agents: Use fire fighting measures that suit the environment. ∙ Special hazards arising from the substance or mixture No further relevant information available. ∙ Advice for firefighters ∙ Protective equipment: No special measures required.

* 6 Accidental release measures

∙ Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. ∙ Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. ∙ Methods and material for containment and cleaning up: Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. ∙ Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. ∙ Protective Action Criteria for Chemicals ∙ PAC-1: 7631-86-9 silicon dioxide, chemically prepared 18 mg/m³ 1344-28-1 aluminium oxide 15 mg/m³ 1305-78-8 calcium oxide 6 mg/m³ 1313-59-3 SODIUM OXIDE 0.5 mg/m³ 14808-60-7 Quartz (SiO2) 0.075 mg/m³ ∙ PAC-2: 7631-86-9 silicon dioxide, chemically prepared 740 mg/m³ 1344-28-1 aluminium oxide 170 mg/m³ 1305-78-8 calcium oxide 110 mg/m³ 1313-59-3 SODIUM OXIDE 5 mg/m³ 14808-60-7 Quartz (SiO2) 33 mg/m³ ∙ PAC-3: 7631-86-9 silicon dioxide, chemically prepared 4,500 mg/m³ 1344-28-1 aluminium oxide 990 mg/m³ 1305-78-8 calcium oxide 660 mg/m³ 1313-59-3 SODIUM OXIDE 50 mg/m³ (Contd. on page 4) USA

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 3) 14808-60-7 Quartz (SiO2) 200 mg/m³

* 7 Handling and storage

∙ Handling: ∙ Precautions for safe handling Thorough dedusting. Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. ∙ Information about protection against explosions and fires: Keep respiratory protective device available. ∙ Conditions for safe storage, including any incompatibilities ∙ Storage: ∙ Requirements to be met by storerooms and receptacles: No special requirements. ∙ Information about storage in one common storage facility: Not required. ∙ Further information about storage conditions: Keep receptacle tightly sealed. ∙ Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

∙ Additional information about design of technical systems: No further data; see item 7. ∙ Control parameters ∙ Components with limit values that require monitoring at the workplace: 1344-28-1 aluminium oxide PEL Long-term value: 15*; 5** mg/m³ *Total dust; ** Respirable fraction REL Long-term value: 10* 5** mg/m³ as Al*Total dust**Respirable/pyro powd./welding f. TLV Long-term value: 1* mg/m³ as Al; *as respirable fraction 1305-78-8 calcium oxide PEL Long-term value: 5 mg/m³ REL Long-term value: 2 mg/m³ TLV Long-term value: 2 mg/m³ 14808-60-7 Quartz (SiO2) PEL Long-term value: 0.05* mg/m³ *resp. dust; 30mg/m3/%SiO2+2 REL Long-term value: 0.05* mg/m³ *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m³ *as respirable fraction ∙ Additional information: The lists that were valid during the creation were used as basis. (Contd. on page 5) USA

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 4) ∙ Exposure controls ∙ Personal protective equipment: ∙ General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. ∙ Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. ∙ Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation ∙ Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. ∙ Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. ∙ Eye protection:

Tightly sealed goggles or safety glasses

* 9 Physical and chemical properties

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 5) ∙ Flash point: Not applicable. ∙ Flammability (solid, gaseous): Not determined. ∙ Ignition temperature: 370 °C (698 °F) ∙ Decomposition temperature: Not determined. ∙ Auto igniting: Product is not selfigniting. ∙ Danger of explosion: Product does not present an explosion hazard. Not determined. ∙ Explosion limits: Lower: Not determined. Upper: Not determined. ∙ Vapor pressure: Not applicable. ∙ Density: Not determined. ∙ Relative density Not determined. ∙ Vapor density Not applicable. ∙ Evaporation rate Not applicable. ∙ Solubility in / Miscibility with Water: Not miscible or difficult to mix. ∙ Partition coefficient (n-octanol/water): Not determined. ∙ Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. ∙ Solvent content: VOC content: 0.00 % Solids content: 56.0 % ∙ Other information No further relevant information available.

* 10 Stability and reactivity

∙ Reactivity No further relevant information available. ∙ Chemical stability ∙ Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. ∙ Possibility of hazardous reactions No dangerous reactions known. ∙ Conditions to avoid No further relevant information available. ∙ Incompatible materials: No further relevant information available. ∙ Hazardous decomposition products: No dangerous decomposition products known. USA (Contd. on page 7)

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 6)

* 11 Toxicological information

∙ Information on toxicological effects ∙ Acute toxicity: ∙ Primary irritant effect: ∙ on the skin: No irritant effect. ∙ on the eye: Strong irritant with the danger of severe eye injury. ∙ Sensitization: No sensitizing effects known. ∙ Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant ∙ Carcinogenic categories ∙ IARC (International Agency for Research on Cancer) 7631-86-9 silicon dioxide, chemically prepared 3 14808-60-7 Quartz (SiO2) 1 ∙ NTP (National Toxicology Program) 14808-60-7 Quartz (SiO2) K ∙ OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

* 12 Ecological information

∙ Toxicity ∙ Aquatic toxicity: No further relevant information available. ∙ Persistence and degradability No further relevant information available. ∙ Behavior in environmental systems: ∙ Bioaccumulative potential No further relevant information available. ∙ Mobility in soil No further relevant information available. ∙ Additional ecological information: ∙ General notes: Do not allow product to reach ground water, water course or sewage system, even in small quantities. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Danger to drinking water if even extremely small quantities leak into the ground. ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable. ∙ Other adverse effects No further relevant information available.

13 Disposal considerations

∙ Waste treatment methods ∙ Recommendation: Dispose of container and materials in accordance with local, regional and national regulations. (Contd. on page 8) USA

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 7) ∙ Uncleaned packagings: ∙ Recommendation: Disposal must be made according to official regulations.

* 14 Transport information

∙ UN-Number ∙ DOT, ADR, ADN, IMDG, IATA Void ∙ UN proper shipping name ∙ DOT, ADR, ADN, IMDG, IATA Void ∙ Transport hazard class(es) ∙ DOT, ADR, ADN, IMDG, IATA ∙ Class Void ∙ Packing group ∙ DOT, ADR, IMDG, IATA Void ∙ Environmental hazards: ∙ Marine pollutant: No ∙ Special precautions for user Not applicable. ∙ Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. ∙ Transport/Additional information: This product has been tested according to the United Nations Transport of Dangerous Goods test protocol for a “self-heating substance”. It has been specifically determined that this product does not meet the definition of a self heating substance or any other hazard class, and therefore is not a hazardous material. ∙ UN "Model Regulation": Non regulated according to above specifications. Void

* 15 Regulatory information ∙ Safety, health and environmental regulations/legislation specific for the substance or mixture Carbon - non-pyrophoric 47.8% 7631-86-9 silicon dioxide, chemically prepared 22.6% 1344-28-1 aluminium oxide 13.9% ∙ Sara ∙ Section 355 (extremely hazardous substances): None of the ingredients is listed. ∙ Section 313 (Specific toxic chemical listings): 1344-28-1 aluminium oxide (Contd. on page 9) USA

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 8) ∙ TSCA (Toxic Substances Control Act): All ingredients are listed. 7631-86-9 silicon dioxide, chemically prepared ACTIVE 1344-28-1 aluminium oxide ACTIVE 1305-78-8 calcium oxide ACTIVE 1313-59-3 SODIUM OXIDE ACTIVE 14808-60-7 Quartz (SiO2) ACTIVE ∙ Hazardous Air Pollutants None of the ingredients is listed. ∙ Proposition 65 ∙ Chemicals known to cause cancer: 14808-60-7 Quartz (SiO2) ∙ Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ∙ Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ∙ Chemicals known to cause developmental toxicity: None of the ingredients is listed. ∙ Cancerogenity categories ∙ EPA (Environmental Protection Agency) None of the ingredients is listed. ∙ TLV (Threshold Limit Value established by ACGIH) 1344-28-1 aluminium oxide A4 14808-60-7 Quartz (SiO2) A2 ∙ NIOSH-Ca (National Institute for Occupational Safety and Health) 14808-60-7 Quartz (SiO2) ∙ National regulations: ∙ Additional classification according to Decree on Hazardous Materials: Carcinogenic hazardous material group III (dangerous). ∙ Information about limitation of use: Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases. Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases. ∙ Water hazard class: Water hazard class 3 (Self-assessment): extremely hazardous for water. ∙ Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

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Trade name: Hydrocarbon/Moisture-Removing Replacement Cartridge

(Contd. of page 9) considered a warranty or quality specification. All materials may present unknown hazards, and should be used with caution. Although certain hazards are described, we cannot guarantee that these are the only hazards which exist. PerkinElmer shall not be held liable for any damage resulting from handling or from contact with the product. ∙ Department issuing SDS: Environmental, Health and Safety ∙ Contact: Within the USA: 1-(800)-762-4000 Outside the USA: 1-(203)-712-8488 ∙ Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Carc. 1A: Carcinogenicity – Category 1A ∙ * Data compared to the previous version altered. USA

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* 1 Identification

∙ Product identifier ∙ Trade name: TRAP-HI CAPACITY REPL OXYGEN ∙ Article number N9306004 ∙ Application of the substance / the mixture Laboratory chemicals ∙ Details of the supplier of the safety data sheet ∙ Manufacturer/Supplier:

* 2 Hazard(s) identification

∙ Classification of the substance or mixture

Flame

Self-heat. 1 H251 Self-heating: may catch fire.

Health hazard

Carc. 1A H350 May cause cancer.

Environment

Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

Eye Irrit. 2A H319 Causes serious eye irritation. ∙ Label elements ∙ GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ∙ Hazard pictograms GHS02, GHS07, GHS08, GHS09 ∙ Signal word Danger ∙ Hazard-determining components of labeling: Quartz (SiO2) (Contd. on page 2) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 1) ∙ Hazard statements H251 Self-heating: may catch fire. H319 Causes serious eye irritation. H350 May cause cancer. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. ∙ Precautionary statements P235+P410 Keep cool. Protect from sunlight. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear eye protection / face protection. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P391 Collect spillage. P407 Maintain air gap between stacks/pallets. P420 Store away from other materials. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ∙ Classification system: ∙ NFPA ratings (scale 0 - 4) Health = 2 4 Fire = 4 2 0 Reactivity = 0 ∙ HMIS-ratings (scale 0 - 4) HEALTH *2 Health = *2 FIRE 4 Fire = 4 REACTIVITY 0 Reactivity = 0 ∙ Other hazards The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes. ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable.

* 3 Composition/information on ingredients

∙ Chemical characterization: Mixtures ∙ Description: Mixture of the substances listed below with nonhazardous additions. ∙ Hazardous components: 1317-38-0 copper(II) oxide Aquatic Acute 1, H400; Aquatic Chronic 1, H410 55.0% 1344-28-1 aluminium oxide 10.0% 7782-42-5 Graphite 2.5% (Contd. on page 3) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 2) 1305-78-8 calcium oxide Eye Dam. 1, H318 2.1% 14808-60-7 Quartz (SiO2) Carc. 1A, H350 0.5% ∙ Additional Components Zinc Oxide (Non-pyrophoric) 21.0% 7631-86-9 silicon dioxide, chemically prepared 6.8% 1313-59-3 SODIUM OXIDE 2.1%

* 4 First-aid measures

∙ Description of first aid measures ∙ After inhalation: Supply fresh air; consult doctor in case of complaints. ∙ After skin contact: Generally the product does not irritate the skin. ∙ After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. ∙ After swallowing: If symptoms persist consult doctor. ∙ Most important symptoms and effects, both acute and delayed No further relevant information available. ∙ Indication of any immediate medical attention and special treatment needed No further relevant information available.

5 Fire-fighting measures

* 6 Accidental release measures

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 3) 1305-78-8 calcium oxide 6 mg/m³ 1313-59-3 SODIUM OXIDE 0.5 mg/m³ 14808-60-7 Quartz (SiO2) 0.075 mg/m³ ∙ PAC-2: 1317-38-0 copper(II) oxide 11 mg/m³ 1344-28-1 aluminium oxide 170 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 740 mg/m³ 1305-78-8 calcium oxide 110 mg/m³ 1313-59-3 SODIUM OXIDE 5 mg/m³ 14808-60-7 Quartz (SiO2) 33 mg/m³ ∙ PAC-3: 1317-38-0 copper(II) oxide 93 mg/m³ 1344-28-1 aluminium oxide 990 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 4,500 mg/m³ 1305-78-8 calcium oxide 660 mg/m³ 1313-59-3 SODIUM OXIDE 50 mg/m³ 14808-60-7 Quartz (SiO2) 200 mg/m³

* 7 Handling and storage

∙ Handling: ∙ Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. ∙ Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. ∙ Conditions for safe storage, including any incompatibilities ∙ Storage: ∙ Requirements to be met by storerooms and receptacles: No special requirements. ∙ Information about storage in one common storage facility: Not required. ∙ Further information about storage conditions: Keep receptacle tightly sealed. ∙ Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

∙ Additional information about design of technical systems: No further data; see item 7. ∙ Control parameters ∙ Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. 1344-28-1 aluminium oxide PEL Long-term value: 15*; 5** mg/m³ *Total dust; ** Respirable fraction (Contd. on page 5) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 4) REL Long-term value: 10* 5** mg/m³ as Al*Total dust**Respirable/pyro powd./welding f. TLV Long-term value: 1* mg/m³ as Al; *as respirable fraction 7782-42-5 Graphite PEL Long-term value: 15 mppcf* mg/m³ *impinger samples counted by light field techn. REL Long-term value: 2.5* mg/m³ *respirable dust TLV Long-term value: 2* mg/m³ all forms except graphite fibers;*resp. fraction 1305-78-8 calcium oxide PEL Long-term value: 5 mg/m³ REL Long-term value: 2 mg/m³ TLV Long-term value: 2 mg/m³ 14808-60-7 Quartz (SiO2) PEL Long-term value: 0.05* mg/m³ *resp. dust; 30mg/m3/%SiO2+2 REL Long-term value: 0.05* mg/m³ *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m³ *as respirable fraction ∙ Additional information: The lists that were valid during the creation were used as basis. ∙ Exposure controls ∙ Personal protective equipment: ∙ General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. ∙ Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. ∙ Protection of hands:

Protective gloves

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 5) ∙ Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. ∙ Eye protection:

Tightly sealed goggles or safety glasses

* 9 Physical and chemical properties

∙ Information on basic physical and chemical properties ∙ General Information ∙ Appearance: Form: Solid in various forms Color: According to product specification ∙ Odor: Characteristic ∙ Odor threshold: Not determined. ∙ pH-value: Not applicable. ∙ Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 2,230 °C (4,046 °F) ∙ Flash point: Not applicable. ∙ Flammability (solid, gaseous): Not determined. ∙ Ignition temperature: >370 °C (>698 °F) ∙ Decomposition temperature: Not determined. ∙ Auto igniting: Product is not selfigniting. ∙ Danger of explosion: Product does not present an explosion hazard. Not determined. ∙ Explosion limits: Lower: Not determined. Upper: Not determined. ∙ Vapor pressure: Not applicable. ∙ Density: Not determined. ∙ Relative density Not determined. ∙ Vapor density Not applicable. ∙ Evaporation rate Not applicable. ∙ Solubility in / Miscibility with Water: Not miscible or difficult to mix. ∙ Partition coefficient (n-octanol/water): Not determined. (Contd. on page 7) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 6) ∙ Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. ∙ Solvent content: VOC content: 0.00 % Solids content: 45.2 % ∙ Other information No further relevant information available.

10 Stability and reactivity

* 11 Toxicological information

∙ Information on toxicological effects ∙ Acute toxicity: ∙ Primary irritant effect: ∙ on the skin: No irritant effect. ∙ on the eye: Irritating effect. ∙ Sensitization: No sensitizing effects known. ∙ Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant ∙ Carcinogenic categories ∙ IARC (International Agency for Research on Cancer) 7631-86-9 silicon dioxide, chemically prepared 3 14808-60-7 Quartz (SiO2) 1 ∙ NTP (National Toxicology Program) 14808-60-7 Quartz (SiO2) K ∙ OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

* 12 Ecological information

∙ Toxicity ∙ Aquatic toxicity: No further relevant information available. (Contd. on page 8) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 7) ∙ Persistence and degradability No further relevant information available. ∙ Behavior in environmental systems: ∙ Bioaccumulative potential No further relevant information available. ∙ Mobility in soil No further relevant information available. ∙ Ecotoxical effects: ∙ Remark: Very toxic for fish ∙ Additional ecological information: ∙ General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable. ∙ Other adverse effects No further relevant information available.

13 Disposal considerations

∙ Waste treatment methods ∙ Recommendation: Dispose of container and materials in accordance with local, regional and national regulations. ∙ Uncleaned packagings: ∙ Recommendation: Disposal must be made according to official regulations.

* 14 Transport information

∙ UN-Number ∙ DOT, ADR, IMDG, IATA UN3190 ∙ UN proper shipping name ∙ DOT Self-heating solid, inorganic, n.o.s. (Activated copper oxide) ∙ ADR 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide), ENVIRONMENTALLY HAZARDOUS ∙ IMDG, IATA SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide) ∙ Transport hazard class(es) ∙ DOT

∙ Class 4.2 Substances liable to spontaneous combustion (Contd. on page 9) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 8) ∙ Label 4.2 ∙ ADR

∙ Class 4.2 Substances liable to spontaneous combustion ∙ IMDG, IATA

∙ Class 4.2 Substances liable to spontaneous combustion ∙ Label 4.2 ∙ Packing group ∙ DOT, ADR, IMDG, IATA II ∙ Environmental hazards: ∙ Marine pollutant: No ∙ Special marking (ADR): Symbol (fish and tree) ∙ Special precautions for user Warning: Substances liable to spontaneous combustion ∙ Stowage Category E ∙ Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. ∙ Transport/Additional information: ∙ DOT ∙ Quantity limitations On passenger aircraft/rail: 15 kg On cargo aircraft only: 50 kg ∙ ADR ∙ Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g ∙ IMDG ∙ Limited quantities (LQ) 0 ∙ Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g ∙ UN "Model Regulation": UN 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. (ACTIVATED COPPER OXIDE), 4.2, II, ENVIRONMENTALLY HAZARDOUS

USA (Contd. on page 10)

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 9)

* 15 Regulatory information ∙ Safety, health and environmental regulations/legislation specific for the substance or mixture 1317-38-0 copper(II) oxide 55.0% Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Zinc Oxide (Non-pyrophoric) 21.0% 1344-28-1 aluminium oxide 10.0% ∙ Sara ∙ Section 355 (extremely hazardous substances): None of the ingredients is listed. ∙ Section 313 (Specific toxic chemical listings): 1317-38-0 copper(II) oxide 1344-28-1 aluminium oxide ∙ TSCA (Toxic Substances Control Act): All ingredients are listed. 1317-38-0 copper(II) oxide ACTIVE 1344-28-1 aluminium oxide ACTIVE 7631-86-9 silicon dioxide, chemically prepared ACTIVE 7782-42-5 Graphite ACTIVE 1305-78-8 calcium oxide ACTIVE 1313-59-3 SODIUM OXIDE ACTIVE 14808-60-7 Quartz (SiO2) ACTIVE ∙ Hazardous Air Pollutants None of the ingredients is listed. ∙ Proposition 65 ∙ Chemicals known to cause cancer: 14808-60-7 Quartz (SiO2) ∙ Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ∙ Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ∙ Chemicals known to cause developmental toxicity: None of the ingredients is listed. ∙ Cancerogenity categories ∙ EPA (Environmental Protection Agency) None of the ingredients is listed. ∙ TLV (Threshold Limit Value established by ACGIH) 1344-28-1 aluminium oxide A4 14808-60-7 Quartz (SiO2) A2 (Contd. on page 11) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 10) ∙ NIOSH-Ca (National Institute for Occupational Safety and Health) 14808-60-7 Quartz (SiO2) ∙ National regulations: ∙ Additional classification according to Decree on Hazardous Materials: Carcinogenic hazardous material group III (dangerous). ∙ Information about limitation of use: Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases. Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases. ∙ Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. ∙ Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information Disclaimer The information provided in this Material Safety Data Sheet is based on our present knowledge, and believed to be correct at the date of publication. However, no representation is made concerning its accuracy and completeness. It is intended as guidance only, and is not to be considered a warranty or quality specification. All materials may present unknown hazards, and should be used with caution. Although certain hazards are described, we cannot guarantee that these are the only hazards which exist. PerkinElmer shall not be held liable for any damage resulting from handling or from contact with the product. ∙ Department issuing SDS: Environmental, Health and Safety ∙ Contact: Within the USA: 1-(800)-762-4000 Outside the USA: 1-(203)-712-8488 ∙ Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Self-heat. 1: Self-heating substances and mixtures – Category 1 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 (Contd. on page 12) USA

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Trade name: TRAP-HI CAPACITY REPL OXYGEN

(Contd. of page 11) Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A Carc. 1A: Carcinogenicity – Category 1A Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 ∙ * Data compared to the previous version altered. USA

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* 1 Identification

∙ Product identifier ∙ Trade name: Indicating Oxygen-Removing Replacement Cartridge ∙ Article number N9306005 ∙ Application of the substance / the mixture Laboratory chemicals ∙ Details of the supplier of the safety data sheet ∙ Manufacturer/Supplier:

* 2 Hazard(s) identification

∙ Classification of the substance or mixture

Flame

Self-heat. 1 H251 Self-heating: may catch fire.

Health hazard

Carc. 1A H350 May cause cancer.

Corrosion

Eye Dam. 1 H318 Causes serious eye damage.

Environment

Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.

Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H332 Harmful if inhaled. (Contd. on page 2) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 1) ∙ Label elements ∙ GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). ∙ Hazard pictograms GHS02, GHS05, GHS07, GHS08, GHS09 ∙ Signal word Danger ∙ Hazard-determining components of labeling: manganese dioxide Quartz (SiO2) barium oxide, obtained by calcining witherite ∙ Hazard statements H251 Self-heating: may catch fire. H302+H332 Harmful if swallowed or if inhaled. H318 Causes serious eye damage. H350 May cause cancer. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. ∙ Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P235+P410 Keep cool. Protect from sunlight. P261 Avoid breathing dust/fume/gas/mist/vapors/spray P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P330 Rinse mouth. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P308+P313 IF exposed or concerned: Get medical advice/attention. P391 Collect spillage. P407 Maintain air gap between stacks/pallets. P420 Store away from other materials. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. ∙ Classification system: ∙ NFPA ratings (scale 0 - 4) Health = 3 4 Fire = 4 3 0 Reactivity = 0 ∙ HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 4 Fire = 4 REACTIVITY 0 Reactivity = 0

(Contd. on page 3) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 2) ∙ Other hazards The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds or formaldehydes. ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable.

* 3 Composition/information on ingredients

∙ Chemical characterization: Mixtures ∙ Description: Mixture of the substances listed below with nonhazardous additions. ∙ Hazardous components: 1313-13-9 manganese dioxide 43.5% Acute Tox. 4, H302; Acute Tox. 4, H332 1317-38-0 copper(II) oxide 22.8% Aquatic Acute 1, H400; Aquatic Chronic 1, H410 14807-96-6 Talc (Mg3H2(SiO3)4) 14.0% 1344-28-1 aluminium oxide 4.0% 1305-78-8 calcium oxide 1.7% Eye Dam. 1, H318 1304-28-5 barium oxide, obtained by calcining witherite 1.0% Acute Tox. 3, H331 Acute Tox. 4, H302 14808-60-7 Quartz (SiO2) 0.3% Carc. 1A, H350 ∙ Additional Components 7631-86-9 silicon dioxide, chemically prepared 10.0% 1313-59-3 SODIUM OXIDE 1.7% Zinc Oxide (Non-pyrophoric) 1.0%

* 4 First-aid measures

∙ Description of first aid measures ∙ General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. ∙ After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. ∙ After skin contact: Generally the product does not irritate the skin. ∙ After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. ∙ After swallowing: Immediately call a doctor. ∙ Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 4) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 3) ∙ Indication of any immediate medical attention and special treatment needed No further relevant information available.

* 5 Fire-fighting measures

* 6 Accidental release measures

∙ Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. ∙ Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. ∙ Methods and material for containment and cleaning up: Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. ∙ Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. ∙ Protective Action Criteria for Chemicals ∙ PAC-1: 1313-13-9 manganese dioxide 4.7 mg/m³ 1317-38-0 copper(II) oxide 0.75 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 18 mg/m³ 1344-28-1 aluminium oxide 15 mg/m³ 1313-59-3 SODIUM OXIDE 0.5 mg/m³ 1305-78-8 calcium oxide 6 mg/m³ 1304-28-5 barium oxide, obtained by calcining witherite 1.7 mg/m³ 14808-60-7 Quartz (SiO2) 0.075 mg/m³ ∙ PAC-2: 1313-13-9 manganese dioxide 7.9 mg/m³ 1317-38-0 copper(II) oxide 11 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 740 mg/m³ 1344-28-1 aluminium oxide 170 mg/m³ 1313-59-3 SODIUM OXIDE 5 mg/m³ 1305-78-8 calcium oxide 110 mg/m³ 1304-28-5 barium oxide, obtained by calcining witherite 200 mg/m³ 14808-60-7 Quartz (SiO2) 33 mg/m³ (Contd. on page 5) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 4) ∙ PAC-3: 1313-13-9 manganese dioxide 690 mg/m³ 1317-38-0 copper(II) oxide 93 mg/m³ 7631-86-9 silicon dioxide, chemically prepared 4,500 mg/m³ 1344-28-1 aluminium oxide 990 mg/m³ 1313-59-3 SODIUM OXIDE 50 mg/m³ 1305-78-8 calcium oxide 660 mg/m³ 1304-28-5 barium oxide, obtained by calcining witherite 1,200 mg/m³ 14808-60-7 Quartz (SiO2) 200 mg/m³

* 7 Handling and storage

∙ Handling: ∙ Precautions for safe handling Thorough dedusting. Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. ∙ Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Keep respiratory protective device available. ∙ Conditions for safe storage, including any incompatibilities ∙ Storage: ∙ Requirements to be met by storerooms and receptacles: No special requirements. ∙ Information about storage in one common storage facility: Not required. ∙ Further information about storage conditions: Keep receptacle tightly sealed. ∙ Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

∙ Additional information about design of technical systems: No further data; see item 7. ∙ Control parameters ∙ Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the remaining constituent has no known exposure limits. 1313-13-9 manganese dioxide PEL Ceiling limit value: 5 mg/m³ as Mn REL Short-term value: 3 mg/m³ Long-term value: 1 mg/m³ as Mn TLV Long-term value: 0.02* 0.1** mg/m³ as Mn; *respirable **inhalable fraction (Contd. on page 6) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 5) 14807-96-6 Talc (Mg3H2(SiO3)4) PEL Long-term value: 20 mppcf ppm (containing <1% Quartz) REL Long-term value: 2* mg/m³ *respirable dust; and <1% Quartz TLV Long-term value: 2* mg/m³ *as respirable fraction; E 1344-28-1 aluminium oxide PEL Long-term value: 15*; 5** mg/m³ *Total dust; ** Respirable fraction REL Long-term value: 10* 5** mg/m³ as Al*Total dust**Respirable/pyro powd./welding f. TLV Long-term value: 1* mg/m³ as Al; *as respirable fraction 1305-78-8 calcium oxide PEL Long-term value: 5 mg/m³ REL Long-term value: 2 mg/m³ TLV Long-term value: 2 mg/m³ 1304-28-5 barium oxide, obtained by calcining witherite PEL Long-term value: 0.5 mg/m³ as Ba REL Long-term value: 0.5 mg/m³ as Ba TLV Long-term value: 0.5 mg/m³ as Ba 14808-60-7 Quartz (SiO2) PEL Long-term value: 0.05* mg/m³ *resp. dust; 30mg/m3/%SiO2+2 REL Long-term value: 0.05* mg/m³ *respirable dust; See Pocket Guide App. A TLV Long-term value: 0.025* mg/m³ *as respirable fraction ∙ Additional information: The lists that were valid during the creation were used as basis. ∙ Exposure controls ∙ Personal protective equipment: ∙ General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes. Avoid contact with the eyes and skin. (Contd. on page 7) USA

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(Contd. of page 6) ∙ Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. ∙ Protection of hands:

Protective gloves

Tightly sealed goggles or safety glasses

* 9 Physical and chemical properties

∙ Information on basic physical and chemical properties ∙ General Information ∙ Appearance: Form: Solid Color: According to product specification ∙ Odor: Characteristic ∙ Odor threshold: Not determined. ∙ pH-value: Not applicable. ∙ Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 3,600 °C (6,512 °F) ∙ Flash point: Not applicable. ∙ Flammability (solid, gaseous): Not determined. ∙ Decomposition temperature: Not determined. ∙ Auto igniting: Product is not selfigniting. ∙ Danger of explosion: Product does not present an explosion hazard. Not determined. (Contd. on page 8) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 7) ∙ Explosion limits: Lower: Not determined. Upper: Not determined. ∙ Vapor pressure: Not applicable. ∙ Density: Not determined. ∙ Relative density Not determined. ∙ Vapor density Not applicable. ∙ Evaporation rate Not applicable. ∙ Solubility in / Miscibility with Water: Not miscible or difficult to mix. ∙ Partition coefficient (n-octanol/water): Not determined. ∙ Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. ∙ Solvent content: VOC content: 0.00 % Solids content: 55.0 % ∙ Other information No further relevant information available.

* 10 Stability and reactivity

* 11 Toxicological information

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 8) ∙ Carcinogenic categories ∙ IARC (International Agency for Research on Cancer) 14807-96-6 Talc (Mg3H2(SiO3)4) 3 7631-86-9 silicon dioxide, chemically prepared 3 14808-60-7 Quartz (SiO2) 1 ∙ NTP (National Toxicology Program) 14808-60-7 Quartz (SiO2) K ∙ OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed.

* 12 Ecological information

∙ Toxicity ∙ Aquatic toxicity: No further relevant information available. ∙ Persistence and degradability No further relevant information available. ∙ Behavior in environmental systems: ∙ Bioaccumulative potential No further relevant information available. ∙ Mobility in soil No further relevant information available. ∙ Ecotoxical effects: ∙ Remark: Very toxic for fish ∙ Additional ecological information: ∙ General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms ∙ Results of PBT and vPvB assessment ∙ PBT: Not applicable. ∙ vPvB: Not applicable. ∙ Other adverse effects No further relevant information available.

* 13 Disposal considerations

* 14 Transport information

∙ UN-Number ∙ DOT, ADR, IMDG, IATA UN3190 (Contd. on page 10) USA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 9) ∙ UN proper shipping name ∙ DOT Self-heating solid, inorganic, n.o.s. (Activated copper oxide) ∙ ADR 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide), ENVIRONMENTALLY HAZARDOUS ∙ IMDG, IATA SELF-HEATING SOLID, INORGANIC, N.O.S. (Activated copper oxide) ∙ Transport hazard class(es) ∙ DOT

∙ Class 4.2 Substances liable to spontaneous combustion ∙ Label 4.2 ∙ ADR

∙ Class 4.2 Substances liable to spontaneous combustion ∙ Label 4.2 ∙ IMDG, IATA

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Trade name: Indicating Oxygen-Removing Replacement Cartridge

(Contd. of page 10)

∙ ADR ∙ Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g ∙ IMDG ∙ Limited quantities (LQ) 0 ∙ Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 500 g ∙ UN "Model Regulation": UN 3190 SELF-HEATING SOLID, INORGANIC, N.O.S. (ACTIVATED COPPER OXIDE), 4.2, II, ENVIRONMENTALLY HAZARDOUS

* 15 Regulatory information ∙ Safety, health and environmental regulations/legislation specific for the substance or mixture 1313-13-9 manganese dioxide Acute Tox. 4, H302; Acute Tox. 4, H332 43.5% 1317-38-0 copper(II) oxide Aquatic Acute 1, H400; Aquatic Chronic 1, H410 22.8% 14807-96-6 Talc (Mg3H2(SiO3)4) 14.0% ∙ Sara ∙ Section 355 (extremely hazardous substances): None of the ingredients is listed. ∙ Section 313 (Specific toxic chemical listings): 1313-13-9 manganese dioxide 1317-38-0 copper(II) oxide 1344-28-1 aluminium oxide 1304-28-5 barium oxide, obtained by calcining witherite ∙ TSCA (Toxic Substances Control Act): All ingredients are listed. 1313-13-9 manganese dioxide ACTIVE 1317-38-0 copper(II) oxide ACTIVE 14807-96-6 Talc (Mg3H2(SiO3)4) ACTIVE 7631-86-9 silicon dioxide, chemically prepared ACTIVE 1344-28-1 aluminium oxide ACTIVE 1313-59-3 SODIUM OXIDE ACTIVE 1305-78-8 calcium oxide ACTIVE 1304-28-5 barium oxide, obtained by calcining witherite ACTIVE 14808-60-7 Quartz (SiO2) ACTIVE ∙ Hazardous Air Pollutants 1313-13-9 manganese dioxide (Contd. on page 12) USA

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(Contd. of page 11) ∙ Proposition 65 ∙ Chemicals known to cause cancer: 14808-60-7 Quartz (SiO2) ∙ Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ∙ Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ∙ Chemicals known to cause developmental toxicity: None of the ingredients is listed. ∙ Cancerogenity categories ∙ EPA (Environmental Protection Agency) 1313-13-9 manganese dioxide D 1304-28-5 barium oxide, obtained by calcining witherite D, CBD(inh), NL(oral) ∙ TLV (Threshold Limit Value established by ACGIH) 14807-96-6 Talc (Mg3H2(SiO3)4) A4 1344-28-1 aluminium oxide A4 1304-28-5 barium oxide, obtained by calcining witherite A4 14808-60-7 Quartz (SiO2) A2 ∙ NIOSH-Ca (National Institute for Occupational Safety and Health) 14808-60-7 Quartz (SiO2) ∙ National regulations: ∙ Additional classification according to Decree on Hazardous Materials: Carcinogenic hazardous material group III (dangerous). ∙ Information about limitation of use: Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases. Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in this preparation. Exceptions can be made by the authorities in certain cases. ∙ Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. ∙ Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* 16 Other information Disclaimer The information provided in this Material Safety Data Sheet is based on our present knowledge, and believed to be correct at the date of publication. However, no representation is made concerning its accuracy and completeness. It is intended as guidance only, and is not to be considered a warranty or quality specification. All materials may present unknown hazards, and should be used with caution. Although certain hazards are described, we cannot guarantee that these are the only hazards which exist. PerkinElmer shall not be held liable for any damage resulting from handling or from contact with the product. ∙ Department issuing SDS: Environmental, Health and Safety (Contd. on page 13) USA

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(Contd. of page 12) ∙ Contact: Within the USA: 1-(800)-762-4000 Outside the USA: 1-(203)-712-8488 ∙ Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Self-heat. 1: Self-heating substances and mixtures – Category 1 Acute Tox. 4: Acute toxicity – Category 4 Acute Tox. 3: Acute toxicity – Category 3 Eye Dam. 1: Serious eye damage/eye irritation – Category 1 Carc. 1A: Carcinogenicity – Category 1A Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1 ∙ * Data compared to the previous version altered. USA

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