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Effect of Reaction Time on Base Hydrolysis of Methyl Benzoate

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Effect of Reaction Time on Base Hydrolysis of Methyl Benzoate EFFECT OF REACTION TIME ON BASE HYDROLYSIS OF METHYL BENZOATE ROSSIDAH SINJAANAK DAVID DARI (43864) Bachelor ofScience with Honours (Resource Chemistry) 2016 EFFECT OF REACTIONN TIME ON BASE HYDROLYSIS OF METHYL BENZOATE ROSSIDAH SINJA ANAK DAVID DARI (43864) This project paper is submitted in partial fulfillment of requirements the Degree of Bachelor of Science with honors (Program of Resource Chemistry) Faculty of Resource Science and Technology UNIVERSITI MALAYSIA SARAWAK 2016 II ,...... 7 r Acknowledgement I would like to express my deepest gratitude to the many people that helped to bring this research project to success. I want to thank, first and foremost my supervisor, Miss Yusralina bt Yusof for providing me the opportunity to taking part in this Final Year Project. I am so grateful for her help, professionalism and valuable guidance throughout this project that I do not have enough words to give my sincere appreciation. I would also like to thank all the staffs that involve in the analysis of data for this research project. Without their passionate participation and input, the analysis of data could not have successfully conducted. I am indebted to my friends who support me in this research project through the entire year. I cannot find words to express my gratitude to them in making this research project to fruition. I consider it an honor to work with all of them during this project. Last but not least, I must express my profound gratitude to my parents for providing me with unfailing support throughout my years of study and through the process of researching and writing this thesis. This thesis would not have been possible without them. Thank you. III - UNIVERSITI MALAYSIA SARAWAK Grade: ----- Please tick (..Jj Final Year Project Report lZ::] Masters ID PhD .D DECLARAnON OF ORIGINAL WORK This declaration is made on the 17th May 2012. Student's Declaration: I Rossidah Sinja anak David Dari, 43864, Faculty of Resource Science and Technology hereby declare that the work entitled, Effect of Reaction Time on Base Hydrolysis of Methyl Benzoate is my original work. I have not copied from any other students' work or from any other sources except where due reference or acknowledgement is made explicitly in the text, nor has any part been written for me by another person. \·1"''' It\ (l~ )0\\.I Date submitted Rossidah Sinja anak David Dari (43864) Supervisor's Declaration: I, Yusralina binti Yusof, hereby certify that the work entitled, Effect of Reaction Time on Acid Hydrolysis of Methyl Benzoate was prepared by the above name student, and was submitted to the "FACUL TY" as a full fulfilment for the confennent of Bachelor of Science IV with Honours (Resource Chemistry), and the aforementioned work, to the best of my knowledge, is the said student's work. Received for examination by: Date: 21 / b /.2-01 b I declare this Project/Thesis is classified as (Please tick (..Jj): CONFIDENTIAL (Contain confidential information under the Official Secret Act D 1972)* DRESTRICTED (Contains restricted information as specified by the organisation where research was done)* DOPEN ACCESS Validation of Project/Thesis I therefore duly affirmed with free consent and willingness declared that this said Project/Thesis shall be placed officially in the Centre for Academic Information Services with the abide interest and rights as follows: • This Project/Thesis is the sole legal property of Universiti Malaysia Sarawak (UNIMAS). • The Centre for Academic Information Services has the lawful right to make copies for the purpose of academic and research only not for other purposes. • The Centre for Academic Information Services has the lawful right to digitise the content to for the Local Content Database. • The Centre for Academic Information Services has the lawful right to make copies of the Project/Thesis for the academic exchange between Higher Learning Institute. v ,...... • No dispute or any claim shall arise from the student himself / herself neither third party on this ProjectlThesis once it becomes sole property ofUNIMAS. • This Projectffhesis or any material, data and information related to it shall not be distributed, published or disclosed to any party by the student except with UNIMAS permission. D Student's signature: ____. ___ _ Supervisor's signature: ~ ---+-+-'---­AfJ I ~Ji (17th May 2016) (17th M'ay 2016) Current Address: Rumah Sandah Ulu Machan 96700, Kanowit Notes: * If the ProjectlThesis is COFIDENTIAL or RESTRICTED, please attach together as annexure a letter from the organisation with the period and reasons of confidentiality and restriction. VI I ,......... Table of Content Acknowledgement ................................................................................................................... III DECLARATION OF ORIGINAL WORK ............................................................................ .IV Table of Content .................................................................................................................... VII List of Abbreviation.................................................................................................................. X List of Table.............................................................................................................................XI List of Figure ......................................................................................................................... XII Abstract.................................................................................................................................XIV 1.0 Introduction.......................................................................................................................... I 1.1 Background .......................................................................................................................... I 1.2 Problem statement ............................................................................................................ 3 1.3 Objective .......................................................................................................................... 3 2.0 Literature Review ................................................................................................................ 4 2.1 Ester.................................................................................................................................. 4 2.1.1 Methyl benzoate ........................................................................................................ 4 2.2 Benzoic acid ..................................................................................................................... 5 2.2.1. Application of benzoic acid ...................................................................................... 6 2.3 Hydrolysis ........................................................................................................................ 6 2.3.1 Base hydrolysis .......................................................................................................... 7 2.3.2 Base hydrolysis of carboxylic ester ........................................................................... 7 2.3.2 Acid hydrolysis .......................................................................................................... 8 2.3.3 Solvent effects on hydrolysis..................................................................................... 8 VII 3.0 Materials and Methods ....................................................................................................... 10 3.1 Preparation of2 M NaOH .............................................................................................. 10 3.3 Preparation of2 M HC1 .................................................................................................. 10 3.4 Base hydrolysis of methyl benzoate with solvent.. ........................................................ 10 3.5 Purification of benzoic acid ........................................................................................... 11 3.6 Preparation of sample for analysis ................................................................................. 11 3.6.1 FTIR analysis ........................................................................................................... 11 3.6.2 Melting point analysis ............................................................................................. 12 4.0 Result and Discussion ........................................................................................................ 13 4.1 Effect off reaction time on base hydrolysis ................................................................... 13 4.1.1 Comparison between the effect of reaction time on methyl benzoate by using NaOH in the presence and absence ofMeOH .................................................................. 17 4.1.2 Comparison between the effect of reaction time on base hydrolysis of methyl benzoate by using KOH in the presence and absence of MeOH...................................... 18 4.1.3 Comparison between the effect of reaction time on methyl benzoate by using NaOH and KOH in the presence ot\leOH...................................................................... 19 4.1.4 Comparison between the effect of reaction time on methyl benzoate by using NaOH and KOH in the absence of MeOH ....................................................................... 20 4.2 FTIR analysis of benzoic acid .......................................................................................
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