Thermal Expansion of New Arsenate Minerals, Bradaczekite, Nacu4(Aso4)3, and Urusovite, Cu(Asalo5) S
ISSN 1075-7015, Geology of Ore Deposits, 2009, Vol. 51, No. 8, pp. 827–832. © Pleiades Publishing, Ltd., 2009. Original Russian Text © S.K. Filatov, D.S. Rybin, S.V. Krivovichev, L.P. Vergasova, 2009, published in Zapiski RMO (Proceedings of the Russian Mineralogical Society), 2009, Pt. CXXXVII, No. 1, pp. 136–143. MINERALOGICAL CRYSTALLOGRAPHY Thermal Expansion of New Arsenate Minerals, Bradaczekite, NaCu4(AsO4)3, and Urusovite, Cu(AsAlO5) S. K. Filatova, D. S. Rybina, S. V. Krivovicheva, and L. P. Vergasovab a Faculty of Geology, St. Petersburg State University, Universitetskaya nab. 7/9, St. Petersburg, 199034 Russia b Institute of Volcanology, Far East Division, Russian Academy of Sciences, Boulevard Piipa, 9, Petropavlovsk-Kamchatsky, 683006 Russia Received December 19, 2007 Abstract—Thermal behavior of two new exhalation copper-bearing minerals, bradaczekite and urusovite, from the Great Tolbachik Fissure Eruption (1975–1976, Kamchatka Peninsula, Russia) has been studied by X-ray thermal analysis within the range 20–700°C in air. The following major values of the thermal expansion tensor α α α α α × –6° –1 μ α ° have been calculated for urusovite: 11 = 10, 22 = b = 7, 33 = 4, V = 21 10 C , = c^ 33 = 49 and α α α × –6° –1 μ α ° bradaczekite: 11aver = 23, 22 = 8, 33aver = 6 10 C , (c^ 33) = 73 . The sharp anisotropy of thermal deformations of these minerals, absences of phase transitions, and stability of the minerals in the selected tem- perature range corresponding to conditions of their formation and alteration during the posteruption period of the volcanic activity are established. DOI: 10.1134/S1075701509080169 INTRODUCTION established that there is a synthetic analogue, NaCu4(AsO4)3, synthesized by Pertlik (1987) under The Great Tolbachik Fissure Eruption (GTFE 1975– hydrothermal conditions.
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