Modeling the Capital and Operating Costs of Thermal Desalination

Total Page:16

File Type:pdf, Size:1020Kb

Modeling the Capital and Operating Costs of Thermal Desalination Desalination and Water Purification Research and Development Program Report No. 130 WT Cost II Modeling the Capital and Operating Costs of Thermal Desalination Processes Utilizing a Recently Developed Computer Program that Evaluates Membrane Desalting, Electrodialysis, and Ion Exchange Plants U.S. Department of the Interior Bureau of Reclamation February 2008 REPORT DOCUMENTATION PAGE Form Approved OMB No. 0704-0188 Public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing this collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing this burden to Department of Defense, Washington Headquarters Services, Directorate for Information Operations and Reports (0704-0188), 1215 Jefferson Davis Highway, Suite 1204, Arlington, VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. PLEASE DO NOT RETURN YOUR FORM TO THE ABOVE ADDRESS. T T T T T 1.T REPORT DATE (DD-MM-YYYY) 2. REPORT TYPE 3. DATES COVERED (From - To) February 2008 Final Final 4.T TITLE AND SUBTITLE 5a. CONTRACT NUMBER WT Cost II Agreement No. 04-FC-81-1038 Modeling the Capital and Operating Costs of Thermal Desalination Processes 5b. GRANT NUMBER Utilizing a Recently Developed Computer Program that Evaluates Membrane Desalting, Electrodialysis, and Ion Exchange Plants 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER Irving Moch, Jr., I. Moch and Associates, William R. Querns, Querns Engineering Services, LLD, and 5e. TASK NUMBER Darlene Steward, Boulder Research Enterprises, LLC Task F 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) 8. PERFORMING ORGANIZATION REPORT NUMBER 9. SPONSORING / MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR’S ACRONYM(S) U.S. Department of the Interior Bureau of Reclamation, 11. SPONSOR/MONITOR’S REPORT Technical Service Center NUMBER(S) ,Denver Federal Center DWPR Report No. 130 PO Box 25007, Denver CO 80225-0007 12. DISTRIBUTION / AVAILABILITY STATEMENT Available from the National Technical Information Service (NTIS), Operations Division, 5285 Port Royal Road, Springfield VA 22161 13. SUPPLEMENTARY NOTEST Report can be downloaded from Reclamation Web site: www.usbr.gov/pmts/water/publications/reports.html 14. ABSTRACT (Maximum 200 words) A water treatment cost estimating program, WTCost II©, has been developed for all commercial desalting processes involving membrane desalinations (reverse osmosis and nanofiltration), thermal evaporative desalination plants using technologies of multistage flash distillation, multieffect distillation and vapor compression (mechanical and thermal), ion exchange, and electrodialysis. These processes and their associated unit operations have been seamlessly blended into an already developed computer program called WTCost©. The thermal processes include both single purpose (production of desalted water only – power obtained from the grid) and dual-purpose (manufacture of desalinated water wherein the power is derived from a coupled powerplant) plants and, also, hybrid concepts. The program also scopes media filtration and low- pressure membranes, microfiltration and ultrafiltration. All these water treatment processes can be employed singularly or in series or parallel combinations. 15. SUBJECT TERMS Desalination, Cost Estimation, Distillation, Thermal Desalination, Construction Cost, Operation and Maintenance Cost 16. SECURITY CLASSIFICATION OF: 17. LIMITATION 18. NUMBER 19a. NAME OF RESPONSIBLE PERSONT OF ABSTRACT OF PAGES Michelle Chapman SAR 40 a. REPORT b. ABSTRACT c. THIS PAGE 19b. TELEPHONE NUMBER (include area code) UL UL UL 303-445-2264 S Standard Form 298 (Rev. 8/98) P Prescribed by ANSI Std. 239-18 Desalination and Water Purification Research and Development Program Report No. 130 WT Cost II Modeling the Capital and Operating Costs of Thermal Desalination Processes Utilizing a Recently Developed Computer Program that Evaluates Membrane Desalting, Electrodialysis, and Ion Exchange Plants: Case Study for a Seawater 20-million-gallon-per-day (MGD) Hybrid System Involving 10-MGD Multistage Flash Distillation Plus 10-MGD Reverse Osmosis Prepared for Reclamation Under Agreement No. 04-FC-81-1038 by Irving Moch, Jr., I. Moch & Associates, Inc. With William R. Querns, Querns Engineering Services, LLD Darlene Steward, Boulder Research Enterprises, LLC U.S. Department of the Interior Bureau of Reclamation Technical Service Center Water and Environmental Services Division Water Treatment Engineering Research Team Denver, Colorado February 2008 MISSION STATEMENTS The mission of the Department of the Interior is to protect and provide access to our Nation's natural and cultural heritage and honor our trust responsibilities to Indian tribes and our commitments to island communities. The mission of the Bureau of Reclamation is to manage, develop, and protect water and related resources in an environmentally and economically sound manner in the interest of the American public. Disclaimer Information contained in this report regarding commercial products or firms was supplied by those firms. It may not be used for advertising or promotional purposes and is not to be construed as an endorsement of any product or firm by the Bureau of Reclamation. The information contained in this report was developed for the Bureau of Reclamation; no warranty as to the accuracy, usefulness, or completeness is expressed or implied. Author’s Disclaimer The information contained in the WTCost II© is based on published documents, technical data, tests, and internal studies that are believed to be reliable. It is intended for use by persons having approved technical skills at their own discretion and risk. Since conditions of use are outside our control, we can assume no liability for results obtained or damages incurred through the application of the data presented. This information is not intended as a license to operate under, or a recommendation to infringe, any patent covering any material or use. Abstract A computer cost estimating program, WTCost II©, has been developed for all commercial desalting processes involving membrane desalinations (reverse osmosis and nanofiltration), thermal evaporative desalination plants using technologies of multistage flash distillation, multieffect distillation and vapor compression (mechanical and thermal), ion exchange and electrodialysis. The Bureau of Reclamation has been a sponsor. These processes and their associated unit operations have been seamlessly blended into an already developed computer program called WTCost©. The thermal processes include both single purpose (production of desalted water only - power obtained from the grid) and dual- purpose (manufacture of desalinated water wherein the power is derived from a coupled power plant) plants and, also, hybrid concepts. The program also scopes media filtration and low pressure membranes, microfiltration and ultrafiltration. All these water treatment processes can be employed singularly or in series or parallel combinations. With these water technologies on one CD ROM program, a user can now evaluate any treatment system using a standard desalination cost format. Thus, direct comparisons can be made, enabling a customer to define what are the least costly process and technology alternatives for a project tender. Further, this procedure is a teaching tool and will also enable researchers to evaluate their studies for commercial viability at any point in time. Experts have assessed the consistency and accuracy of all subsystems against recent awards and found the results to be very reasonable. The initial WTCost© program has been enhanced to cover such additional areas of currency exchanges, land acquisition, insurance, electrochlorination, and value added tax. Over 90 copies of it have been released to the domestic and international markets. Reports back have been very positive as to the program’s content and user friendliness; it has been found to provide reasonable results in comparison to past projects and in answering questions on future tenders. iii Table of Contents Page Introduction.............................................................................................. 1 Program Content ...................................................................................... 2 Technical Approach................................................................................. 3 Program Options................................................................................ 4 Comments ................................................................................. 8 Case Study for 20-mgd Plant with 10 mgd RO and 10 mgd MSF .......... 10 Program Flow..................................................................................... 11 Water Analysis................................................................................... 12 Unit Operations.................................................................................. 15 Desalting Processes................................................................... 16 Membrane Processes..........................................................
Recommended publications
  • Reverse Osmosis and Nanofiltration, Second Edition
    Reverse Osmosis and Nanofiltration AWWA MANUAL M46 Second Edition Science and Technology AWWA unites the entire water community by developing and distributing authoritative scientific and technological knowledge. Through its members, AWWA develops industry standards for products and processes that advance public health and safety. AWWA also provides quality improvement programs for water and wastewater utilities. Copyright © 2007 American Water Works Association. All Rights Reserved. Contents List of Figures, v List of Tables, ix Preface, xi Acknowledgments, xiii Chapter 1 Introduction . 1 Overview, 1 RO and NF Membrane Applications, 7 Membrane Materials and Configurations, 12 References, 18 Chapter 2 Process Design . 21 Source Water Supply, 21 Pretreatment, 26 Membrane Process Theory, 45 Rating RO and NF Elements, 51 Posttreatment, 59 References, 60 Chapter 3 Facility Design and Construction . 63 Raw Water Intake Facilities, 63 Discharge, 77 Suspended Solids and Silt Removal Facilities, 80 RO and NF Systems, 92 Hydraulic Turbochargers, 95 Posttreatment Systems, 101 Ancillary Equipment and Facilities, 107 Instrumentation and Control Systems, 110 Waste Stream Management Facilities, 116 Other Concentrate Management Alternatives, 135 Disposal Alternatives for Waste Pretreatment Filter Backwash Water, 138 General Treatment Plant Design Fundamentals, 139 Plant Site Location and Layout, 139 General Plant Layout Considerations, 139 Membrane System Layout Considerations, 140 Facility Construction and Equipment Installation, 144 General Guidelines for Equipment Installation, 144 Treatment Costs, 151 References, 162 iii Copyright © 2007 American Water Works Association. All Rights Reserved. Chapter 4 Operations and Maintenance . 165 Introduction, 165 Process Monitoring, 168 Biological Monitoring, 182 Chemical Cleaning, 183 Mechanical Integrity, 186 Instrumentation Calibration, 188 Safety, 190 Appendix A SI Equivalent Units Conversion Tables .
    [Show full text]
  • Dynamic Modeling of Multi Stage Flash (MSF) Desalination Plant
    Dynamic Modeling of Multi Stage Flash (MSF) Desalination Plant by Hala Faisal Al-Fulaij Department of Chemical Engineering University College London Supervisors: Professor David Bogle Thesis submitted for the degree of Doctor of Philosophy (Ph.D.) at University College London (UCL) July 2011 I, Hala Faisal Al-Fulaij, confirm that the work presented in this thesis is my own. Where information has been derived from other sources, I confirm that this has been indicated in the thesis. Hala F. Al-Fulaij Acknowledgments i Acknowledgments This Ph.D. was carried out between March 2007 and January 2011 at the Chemical Engineering department, University College London (UCL). This work was supervised by Professor David Bogle (UCL) and Professor Hisham Ettouney (Kuwait University). I take this opportunity to thank both of my supervisors for general guidance throughout the project and their great help, support and insight. I also thank Professor Giorgio Micale and Doctor Andrea Cipollina from University of Palermo who expended their time and made significant contribution to my knowledge especially in the computer tools field. Also, I am grateful for the love and support of my family, especially my mother, father, husband and sisters. Their patience and encouragement have given me the strength to complete my thesis study. Finally I would like to dedicate this thesis to my lovely children (Rayan, Maryam, AbdulWahab and Najat) hoping them the most of health, success, and happiness. Abstract ii Abstract The world population is increasing at a very rapid rate while the natural water resources remain constant. During the past decades industrial desalination (reverse osmosis (RO) and multistage flash desalination (MSF)) became a viable, economical, and sustainable source of fresh water throughout the world.
    [Show full text]
  • Characterization and Performance of Nanofiltration Membranes
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Covenant University Repository Environ Chem Lett (2014) 12:241–255 DOI 10.1007/s10311-014-0457-3 REVIEW Characterization and performance of nanofiltration membranes Oluranti Agboola • Jannie Maree • Richard Mbaya Received: 16 October 2013 / Accepted: 17 January 2014 / Published online: 1 February 2014 Ó Springer International Publishing Switzerland 2014 Abstract The availability of clean water has become a nanofiltration membranes. We also present a new concept critical problems facing the society due to pollution by for membrane characterization by quantitative analysis of human activities. Most regions in the world have high phase images to elucidate the macro-molecular packing at demands for clean water. Supplies for freshwater are under the membrane surface. pressure. Water reuse is a potential solution for clean water scarcity. A pressure-driven membrane process such as Keywords Nanofiltration membranes Á Membrane nanofiltration has become the main component of advanced characterizations Á Pore size Á Surface morphology Á water reuse and desalination systems. High rejection and Performance evaluation Á ImageJ software water permeability of solutes are the major characteristics that make nanofiltration membranes economically feasible for water purification. Recent advances include the pre- Introduction diction of membrane performances under different oper- ating conditions. Here, we review the characterization of Nanofiltration process is one of the most important recent nanofiltration membranes by methods such as scanning developments in the process industries. It shows performance electron microscopy, thermal gravimetric analysis, attenu- characteristics, which fall in between that of ultrafiltration ated total reflection Fourier transform infrared spectros- and reverse osmosis membranes (Mohammed and Takriff copy, and atomic force microscopy.
    [Show full text]
  • Nanofiltration (NF) Is a Pressure Driven Membrane Process
    Nanofiltration Nanofiltration (NF) is a pressure driven membrane process. Hydraulic pressure is used to overcome the feed solution’s osmotic pressure and to induce diffusion of pure water (referred to as permeate) through a semi-permeable NF membrane. The residual feed stream (referred to as retentate, concentrate, or reject) is concentrated by the process, and depending on water quality, may be suitable for further water recovery in additional downstream unit processes; otherwise, the residual stream requires disposal. NF is designed to achieve high removal of divalent and multivalent ions (e.g., calcium, magnesium, sulfate, iron, arsenic, etc.), and is occasionally referred to as membrane softening. NF may achieve moderate to low removal of monovalent ions (e.g., sodium, potassium, chloride). NF is commonly employed to remove hardness from brackish groundwater to produce potable water. Water characterized by high concentrations of calcium or magnesium and monovalent salts may be treated with NF prior to a reverse osmosis. An illustration of the process is shown below. FEED NF PERMEATE CONCENTRATE Summary of technical assessment of NF Criteria Description/Rationale Status of technology Mature and robust technology for water softening and metals removal in various sectors of the industrial and municipal water treatment sectors. Has been employed for produced water treatment. Feed water quality bins Feed water total dissolved solids concentration applicability depends on feed solution composition and may range from 500 to 12,000 mg/L. Most useful for treatment of water with high concentrations of divalent ions (e.g., magnesium, calcium, barium, sulfate), multivalent metals ions (e.g., iron, manganese), and radionuclides.
    [Show full text]
  • Forward Osmosis – a Brief Introduction
    Forward Osmosis – A Brief Introduction This paper outlines some of the aspects of Forward Osmosis process and its derivatives, with regard to key issues, concepts and some applications. By Peter G. Nicoll Forward Osmosis (FO) over the past five years has generally it is apparent that they are increasingly becoming a topic of some attracted more attention, both academically and commercially, interest. National Geographic [1] in an article in April 2010 cited it with a number of companies raising finance on the back of its as one of the three most promising new desalination technologies potential. The process exploits the natural process of osmosis, and at the last IDA World Congress in Perth, Australia in 2011, which is how plants and trees take up water from the soil – a low six papers were published on this subject. In the Journal of energy, natural process. It works by having two solutions with Membrane Science the number of papers published has seen a different concentrations (or more correctly different osmotic very significant increase over the last three years (24 in 2012), pressures) separated by a selectively permeable membrane, in the showing the increasing level of academic interest. We have also case of the plants and trees their cell walls, and ‘pure’ water flows seen the emergence of a number of commercial organisations from less concentrated solution across the membrane to dilute with significant funding to develop and exploit the technology the more concentrated solution, leaving the salts behind. The clue such as, Hydration Technology Innovations Inc, Modern Water in the potential applications is that it is widely used in nature, plc, Oasys Water Inc, Statkraft AS and Trevi Systems Inc.
    [Show full text]
  • Journal of Membrane Science 593 (2020) 117444
    Journal of Membrane Science 593 (2020) 117444 Contents lists available at ScienceDirect Journal of Membrane Science journal homepage: www.elsevier.com/locate/memsci Nanofiltration membranes with hydrophobic microfiltration substrates for robust structure stability and high water permeation flux T ∗∗ ∗ Xi Zhanga,b, Chang Liua,b, Jing Yanga,b, , Cheng-Ye Zhua,b, Lin Zhangc, Zhi-Kang Xua,b, a MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Hangzhou, 310027, China b Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, China c Key Laboratory of Biomass Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China ARTICLE INFO ABSTRACT Keywords: Traditional nanofiltration membranes (NFMs) suffer from ultrafiltration substrates with low porosity, small pore Nanofiltration membrane size and relatively poor solvent stability. Herein, NFMs have been fabricated on a series of hydrophobic polymer Microfiltration substrate microfiltration substrates to address these issues. Polyphenol-based coatings of tannic acid/diethylenetriamine Surface wettability (TA/DETA) were co-deposited on the hydrophobic substrates to improve their surface wettability and to make Water permeation flux them appropriate for interfacial polymerization. The spreading behaviors of aqueous solutions, which are of Structure stability significant importance to the formation of defect-free polyamide layers, were directly visualized by laser con- focal microscopy. The influences of TA/DETA coatings on the interfacial polymerization were further demon- strated by both dynamic molecular simulation and nanofiltration performance evaluation. The as-prepared NFMs exhibit higher water permeation flux compared with traditional ones because of the large pore size and high porosity of the microfiltration substrates, as well as the relatively low cross-linking degree of polyamide layers.
    [Show full text]
  • 1 Selectrodialysis and Bipolar Membrane
    View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by UPCommons. Portal del coneixement obert de la UPC 1 SELECTRODIALYSIS AND BIPOLAR MEMBRANE ELECTRODIALYSIS 2 COMBINATION FOR INDUSTRIAL PROCESS BRINES TREATMENT: 3 MONOVALENT-DIVALENT IONS SEPARATION AND ACID AND BASE 4 PRODUCTION 5 6 Mònica Reig1,*, César Valderrama1, Oriol Gibert1,2, José Luis Cortina1,2 7 8 1Chemical Engineering Dept., UPC-Barcelona TECH, Av. Diagonal 647, 08028 Barcelona, Spain 9 2CETAQUA Carretera d'Esplugues, 75, 08940 Cornellà de Llobregat, Spain 10 *Corresponding author: Tel.:+34 93 4016997; E-mail address: [email protected] 11 12 13 ABSTRACT 14 Chemical industries generate large amounts of wastewater rich in different chemical 15 constituents. Amongst these, salts at high concentrations are of major concern, making 16 necessary the treatment of saline effluents before discharge. Because most of these rejected 17 streams comprise a combination of more than one salt at high concentration, it is reasonable 18 to try to separate and revalorize them to promote circular economy at industry site level. For 19 this reason, ion-exchange membranes based technologies were integrated in this study: 20 selectrodialysis (SED) and electrodialysis with bipolar membranes (EDBM). Different 21 process brines composed by Na2SO4 and NaCl at different concentrations were treated first by 22 SED to separate each salt, and then by EDBM to produce base (NaOH) and acids (HCl and 23 H2SO4) from each salt. The optimum of both electrolyte nature and concentration of the SED - 2- 24 stack streams was evaluated. Results indicated that it was possible to separate Cl and SO4 25 depending on the anionic membrane, initial electrolytes and concentrations of each stream.
    [Show full text]
  • Membrane Filtration
    Membrane Filtration A membrane is a thin layer of semi-permeable material that separates substances when a driving force is applied across the membrane. Membrane processes are increasingly used for removal of bacteria, microorganisms, particulates, and natural organic material, which can impart color, tastes, and odors to water and react with disinfectants to form disinfection byproducts. As advancements are made in membrane production and module design, capital and operating costs continue to decline. The membrane processes discussed here are microfiltration (MF), ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO). MICROFILTRATION Microfiltration is loosely defined as a membrane separation process using membranes with a pore size of approximately 0.03 to 10 micronas (1 micron = 0.0001 millimeter), a molecular weight cut-off (MWCO) of greater than 1000,000 daltons and a relatively low feed water operating pressure of approximately 100 to 400 kPa (15 to 60psi) Materials removed by MF include sand, silt, clays, Giardia lamblia and Crypotosporidium cysts, algae, and some bacterial species. MF is not an absolute barrier to viruses. However, when used in combination with disinfection, MF appears to control these microorganisms in water. There is a growing emphasis on limiting the concentrations and number of chemicals that are applied during water treatment. By physically removing the pathogens, membrane filtration can significantly reduce chemical addition, such as chlorination. Another application for the technology is for removal of natural synthetic organic matter to reduce fouling potential. In its normal operation, MF removes little or no organic matter; however, when pretreatment is applied, increased removal of organic material can occur.
    [Show full text]
  • Applications of Nanotechnology in Membrane Distillation: a Review Study
    Desalination and Water Treatment 192 (2020) 61–77 www.deswater.com July doi: 10.5004/dwt.2020.25821 Applications of nanotechnology in membrane distillation: a review study Mamdouh El Haj Assada,*, Ehab Bani-Hanib, Israa Al-Sawaftaa, Salah Issaa, Abir Hmidac, Madhu Guptad, Rahman S.M. Atiqurea, Khaoula Hidouric aSustainable and Renewable Energy Engineering Department, University of Sharjah, P.O. Box: 27272, Sharjah, UAE, emails: [email protected] (M. El Haj Assad), [email protected] (I. Al-Sawafta), [email protected] (S. Issa), [email protected] (R.S.M. Atiqure) bSchool of Engineering, Australian College of Kuwait, Mishref, Kuwait, email: [email protected] (E. Bani-Hani) cNational Engineering School of Gabès, Applied Thermodynamics Research Laboratory, University of Gabès, Omar Ibn El Khattab Street, Gabès, 6029, Tunisia, emails: [email protected] (A. Hmida), [email protected] (K. Hidouri) dSchool of M.M.H. College, Ghaziabad, U.P. Resi-# 7/48 Sector-2, Rajendra Nagar, Sahibabad, Ghaziabad – 201005, India, email: [email protected] (M. Gupta) Received 27 June 2019; Accepted 10 March 2020 abstract Membrane distillation (MD) is an effective water treatment process with relatively low cost compared to conventional membrane processes. This study investigates several factors affecting the performance of the MD membrane such as fouling, porosity, pore size, mechanical stability, contact angle, salt rejection, and other physical and thermal properties. Membrane performance can be improved if membranes are manufactured using nanotechnology. This work presents a review of the application of recently discovered nanotechnology that improves the properties and enhances the performance of membranes used in water distillation processes.
    [Show full text]
  • An Attempt to Optimise the Process of Nanofiltration of Pool Water Enriched with Compounds Associated with Secretions of the Human Body †
    Proceedings An Attempt to Optimise the Process of Nanofiltration of Pool Water Enriched with Compounds Associated with Secretions of the Human Body † Edyta Łaskawiec *, Mariusz Dudziak and Joanna Wyczarska-Kokot Institute of Water and Wastewater Engineering, Faculty of Energy and Environmental Engineering, Silesian University of Technology, Konarskiego 18, 44–100 Gliwice, Poland; [email protected] (M.D.); [email protected] (J.W.-K.) * Correspondence: [email protected]; Tel.: +48-32-237-16-98 † Presented at Innovations-Sustainability-Modernity-Openness Conference (ISMO’19), Bialystok, Poland, 22–23 May 2019. Published: 14 June 2019 Abstract: This paper discusses the possibilities of purifying pool water by the process of nanofiltration. The analysis was carried out in the presence of substances analogous to the secretions of the human body. The samples of water collected from the school swimming pool was enriched with selected organic and inorganic compounds. The transport-separation properties of nanofiltration membranes were assessed. In the context of the removal of these organic compounds, the measurement of the total organic carbon concentration was of particular importance. Keywords: swimming pool water; body fluids analogues; pressure driven membrane processes 1. Introduction It is estimated that during one hour of physical activity one swimmer may excrete 50 mL of urine and 200 ml of sweat, which results in the release into the water of many organic compounds whose structures comprise nitrogen, which quickly reacts with chlorine-based disinfectants [1]. The concentration and composition of disinfection by-product (DBP) precursors classified as body fluid analogues (BFAs) are strongly correlated with the number of swimmers, their hygiene habits, and the intended use of the pool.
    [Show full text]
  • Introduction to Desalination Technologies
    Introduction to Desalination Technologies Hari J. Krishna1 Definition and brief history Desalination can be defined as any process that removes salts from water. Desalination processes may be used in municipal, industrial, or commercial applications. With improvements in technology, desalination processes are becoming cost-competitive with other methods of producing usable water for our growing needs. During World War II, it was felt that desalination technology - ‘desalting’ as it was called then - should be developed to convert saline water into usable water, where fresh water supplies were limited. Subsequently, “The Saline Water Act” was passed by Congress in 1952 to provide federal support for desalination. The U.S. Department of the Interior, through the Office of Saline Water (OSW) provided funding during the 1950s and 60s for initial development of desalination technology, and for construction of demonstration plants. Desalination is a relatively new science that has developed to a large extent during the latter half of the 20th century, and continues to undergo technological improvements even at the present time. It is interesting to note that one of the first seawater desalination demonstration plants to be built in the United States was at Freeport, Texas in 1961. Dow, in cooperation with the U.S. Department of the Interior built a 1 million gallons per day (mgd) long tube vertical distillation (LTV) plant at a cost of $1.2 million, that produced water for the City of Freeport and for Dow operations. The plant was officially opened on June 21, 1961 by then President John F. Kennedy, by pressing a button from the White House.
    [Show full text]
  • Nanofiltration and Reverse Osmosis Nanofiltration and Reverse Osmosis Contents
    CT4471 Drinking water I Dr.ir. S.G.J. Heijman nanofiltration and reverse osmosis Nanofiltration and reverse osmosis Contents 1. Introduction 2. Theory 3. Membrane modules 4. Applications 5. Design 6. Fouling control Introduction Size, µm 0.001 0.01 0.1 1.0 10 100 1000 Approximate molecular 100 200 1000 10000 20000 100000 500000 weight Viruses Bacteria Relative size of Dissolved salts Algae materials in water Metal ions Humus acids Cystes Sand Clay Silt ΔP [bar] Conventional filtration processes 0.01 Micro filtration 0.05 Treatment Ultra filtration 0.1 process Nanofiltration 5 Reverse osmosis 30 ED and EDR Metal ions Dissolved salts Viruses Bacteria Cryptosporidium Arsenic Calcium salts Contagious Giardia Salmonella Nitrate Sulfate salts Hepatitis Nitrite Magnesium salts Shigellosis Protozoa Cyanide Aluminum salts Vibrio cholera Cystes Introduction •Bacteria •Virusses •Multivalent •Monovalent salts salts Microfiltration MF + - - - Ultrafiltration + + - - UF Nanofiltration + + + - NF Reversed Osmosis + + + + RO October 16, 2007 4 Introduction Introduction • Spiral wound membrane Modules • Spiral wound membranes Introduction • Principle slow sand filtration v = 0.10 m/h d = 0.15 – 0.35 mm October 16, 2007 8 Introduction • Slow sand filtration slow sand filtration October 16, 2007 9 Introduction • Parallel MF/SSF Problems: 1. Fouling 2. Packing flux = 0.01 m/h October 16, 2007 10 Introduction • Traditional RO/NF - fouling spacers Concentrate channel Permeate channel October 16, 2007 11 Turbulent flow across membranes Introduction • Filtration process and particle size Particle size pressure MWCO flux [nm] [bar] [m3/m2·h] Micro filtration > 100 < 1 0.04 - 0.2 Ultra filtration 10 - 100 < 2 1000 - 10000 0.08 - 0.2 Nano filtration 1 - 2 5 - 10 200 - 500 0.02 - 0.08 Reverse osmosis0.2 - 1 15 - 60 100 0.01 - 0.04 MWCO = Molecular Weight Cut Off = 90% of organic molecules is removed Contents 1.
    [Show full text]