Membrane Filtration
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Reverse Osmosis and Nanofiltration, Second Edition
Reverse Osmosis and Nanofiltration AWWA MANUAL M46 Second Edition Science and Technology AWWA unites the entire water community by developing and distributing authoritative scientific and technological knowledge. Through its members, AWWA develops industry standards for products and processes that advance public health and safety. AWWA also provides quality improvement programs for water and wastewater utilities. Copyright © 2007 American Water Works Association. All Rights Reserved. Contents List of Figures, v List of Tables, ix Preface, xi Acknowledgments, xiii Chapter 1 Introduction . 1 Overview, 1 RO and NF Membrane Applications, 7 Membrane Materials and Configurations, 12 References, 18 Chapter 2 Process Design . 21 Source Water Supply, 21 Pretreatment, 26 Membrane Process Theory, 45 Rating RO and NF Elements, 51 Posttreatment, 59 References, 60 Chapter 3 Facility Design and Construction . 63 Raw Water Intake Facilities, 63 Discharge, 77 Suspended Solids and Silt Removal Facilities, 80 RO and NF Systems, 92 Hydraulic Turbochargers, 95 Posttreatment Systems, 101 Ancillary Equipment and Facilities, 107 Instrumentation and Control Systems, 110 Waste Stream Management Facilities, 116 Other Concentrate Management Alternatives, 135 Disposal Alternatives for Waste Pretreatment Filter Backwash Water, 138 General Treatment Plant Design Fundamentals, 139 Plant Site Location and Layout, 139 General Plant Layout Considerations, 139 Membrane System Layout Considerations, 140 Facility Construction and Equipment Installation, 144 General Guidelines for Equipment Installation, 144 Treatment Costs, 151 References, 162 iii Copyright © 2007 American Water Works Association. All Rights Reserved. Chapter 4 Operations and Maintenance . 165 Introduction, 165 Process Monitoring, 168 Biological Monitoring, 182 Chemical Cleaning, 183 Mechanical Integrity, 186 Instrumentation Calibration, 188 Safety, 190 Appendix A SI Equivalent Units Conversion Tables . -
Electrocoagulation Pretreatment for Microfiltration: an Innovative Combination to Enhance Water Quality and Reduce Fouling in Integrated Membrane Systems
Desalination and Water Purification Research and Development Report No. 139 Electrocoagulation Pretreatment for Microfiltration: An Innovative Combination to Enhance Water Quality and Reduce Fouling in Integrated Membrane Systems University of Houston U.S. Department of the Interior Bureau of Reclamation Technical Service Center Denver, Colorado September 2007 Form Approved REPORT DOCUMENTATION PAGE OMB No. 0704-0188 The public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information, including suggestions for reducing the burden, to Department of Defense, Washington Headquarters Services, Directorate for Information Operations and Reports (0704-0188), 1215 Jefferson Davis Highway, Suite 1204, Arlington, VA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display a currently valid OMB control number. PLEASE DO NOT RETURN YOUR FORM TO THE ABOVE ADDRESS. 2. REPORT TYPE 1. REPORT DATE (DD-MM-YYYY) 3. DATES COVERED (From - To) Final September 2007 October 2005 – September 2007 4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER Electrocoagulation Pretreatment for Microfiltration: An Innovative Combination Agreement No. 05-FC-81-1172 to Enhance Water Quality and Reduce Fouling in Integrated Membrane Systems 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER Shankar Chellam, Principal Investigator Dennis A. -
Dynamic Modeling of Multi Stage Flash (MSF) Desalination Plant
Dynamic Modeling of Multi Stage Flash (MSF) Desalination Plant by Hala Faisal Al-Fulaij Department of Chemical Engineering University College London Supervisors: Professor David Bogle Thesis submitted for the degree of Doctor of Philosophy (Ph.D.) at University College London (UCL) July 2011 I, Hala Faisal Al-Fulaij, confirm that the work presented in this thesis is my own. Where information has been derived from other sources, I confirm that this has been indicated in the thesis. Hala F. Al-Fulaij Acknowledgments i Acknowledgments This Ph.D. was carried out between March 2007 and January 2011 at the Chemical Engineering department, University College London (UCL). This work was supervised by Professor David Bogle (UCL) and Professor Hisham Ettouney (Kuwait University). I take this opportunity to thank both of my supervisors for general guidance throughout the project and their great help, support and insight. I also thank Professor Giorgio Micale and Doctor Andrea Cipollina from University of Palermo who expended their time and made significant contribution to my knowledge especially in the computer tools field. Also, I am grateful for the love and support of my family, especially my mother, father, husband and sisters. Their patience and encouragement have given me the strength to complete my thesis study. Finally I would like to dedicate this thesis to my lovely children (Rayan, Maryam, AbdulWahab and Najat) hoping them the most of health, success, and happiness. Abstract ii Abstract The world population is increasing at a very rapid rate while the natural water resources remain constant. During the past decades industrial desalination (reverse osmosis (RO) and multistage flash desalination (MSF)) became a viable, economical, and sustainable source of fresh water throughout the world. -
Circle Reverse Osmosis System
CIRCLE REVERSE OSMOSIS SYSTEM KEY FEATURES Water Saving Technology – Patented technology eliminates backpressure The RC100 conforms to common in conventional RO systems making the Circle up to 10 times more NSF/ANSI 42, 53 and efficient than existing products. 58 for the reduction of Saves You Money – Conventional RO systems waste up to 24 gallons of Aesthetic Chlorine, Taste water per every 1 gallon of filtered water produced. The Circle only wastes and Odor, Cyst, VOCs, an average of 2.1 gallons of water per 1 gallon of filtered water produced, Fluoride, Pentavalent Arsenic, Barium, Radium 226/228, Cadmium, Hexavalent saving you water and money over the life of the product!. Chromium, Trivalent Chromium, Lead, RO Filter Auto Flushing – Significantly extends life of RO filter. Copper, Selenium and TDS as verified Chrome Faucet Included – With integrated LED filter change indicator. and substantiated by test data. The RC100 conforms to NSF/ANSI 372 for Space Saving Compact Design – Integrated rapid refill tank means more low lead compliance. space under the sink. SPECIFICATIONS Product Name H2O+ Circle Reverse Osmosis Water Filtration System Model / SKU RC100 Installation Undercounter Sediment Filter, Pre-Carbon Plus Filter, Post Carbon Block Filter (RF-20): 6 months Filters & Lifespan RO Membrane Filter (RF-40): 24 months Tank Capacity 6 Liters (refills fully in less than one hour) Dimensions 9.25” (W) x 16.5” (H) x 13.75” (D) Net weight 14.6 lbs Min/Max Operating Pressure 40 psi – 120 psi (275Kpa – 827Kpa) Min/Max Water Feed Temp 41º F – 95º F (5º C – 35º C) Faucet Flow Rate 0.26 – 0.37 gallons per minute (gpm) at incoming water pressure of 20–100 psi Rated Service Flow 0.07 gallons per minute (gpm) Warranty One Year Warranty PO Box 470085, San Francisco CA, 94147–0085 brondell.com 888-542-3355. -
Sedimentation and Clarification Sedimentation Is the Next Step in Conventional Filtration Plants
Sedimentation and Clarification Sedimentation is the next step in conventional filtration plants. (Direct filtration plants omit this step.) The purpose of sedimentation is to enhance the filtration process by removing particulates. Sedimentation is the process by which suspended particles are removed from the water by means of gravity or separation. In the sedimentation process, the water passes through a relatively quiet and still basin. In these conditions, the floc particles settle to the bottom of the basin, while “clear” water passes out of the basin over an effluent baffle or weir. Figure 7-5 illustrates a typical rectangular sedimentation basin. The solids collect on the basin bottom and are removed by a mechanical “sludge collection” device. As shown in Figure 7-6, the sludge collection device scrapes the solids (sludge) to a collection point within the basin from which it is pumped to disposal or to a sludge treatment process. Sedimentation involves one or more basins, called “clarifiers.” Clarifiers are relatively large open tanks that are either circular or rectangular in shape. In properly designed clarifiers, the velocity of the water is reduced so that gravity is the predominant force acting on the water/solids suspension. The key factor in this process is speed. The rate at which a floc particle drops out of the water has to be faster than the rate at which the water flows from the tank’s inlet or slow mix end to its outlet or filtration end. The difference in specific gravity between the water and the particles causes the particles to settle to the bottom of the basin. -
Characterization and Performance of Nanofiltration Membranes
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Covenant University Repository Environ Chem Lett (2014) 12:241–255 DOI 10.1007/s10311-014-0457-3 REVIEW Characterization and performance of nanofiltration membranes Oluranti Agboola • Jannie Maree • Richard Mbaya Received: 16 October 2013 / Accepted: 17 January 2014 / Published online: 1 February 2014 Ó Springer International Publishing Switzerland 2014 Abstract The availability of clean water has become a nanofiltration membranes. We also present a new concept critical problems facing the society due to pollution by for membrane characterization by quantitative analysis of human activities. Most regions in the world have high phase images to elucidate the macro-molecular packing at demands for clean water. Supplies for freshwater are under the membrane surface. pressure. Water reuse is a potential solution for clean water scarcity. A pressure-driven membrane process such as Keywords Nanofiltration membranes Á Membrane nanofiltration has become the main component of advanced characterizations Á Pore size Á Surface morphology Á water reuse and desalination systems. High rejection and Performance evaluation Á ImageJ software water permeability of solutes are the major characteristics that make nanofiltration membranes economically feasible for water purification. Recent advances include the pre- Introduction diction of membrane performances under different oper- ating conditions. Here, we review the characterization of Nanofiltration process is one of the most important recent nanofiltration membranes by methods such as scanning developments in the process industries. It shows performance electron microscopy, thermal gravimetric analysis, attenu- characteristics, which fall in between that of ultrafiltration ated total reflection Fourier transform infrared spectros- and reverse osmosis membranes (Mohammed and Takriff copy, and atomic force microscopy. -
Troubleshooting Activated Sludge Processes Introduction
Troubleshooting Activated Sludge Processes Introduction Excess Foam High Effluent Suspended Solids High Effluent Soluble BOD or Ammonia Low effluent pH Introduction Review of the literature shows that the activated sludge process has experienced operational problems since its inception. Although they did not experience settling problems with their activated sludge, Ardern and Lockett (Ardern and Lockett, 1914a) did note increased turbidity and reduced nitrification with reduced temperatures. By the early 1920s continuous-flow systems were having to deal with the scourge of activated sludge, bulking (Ardem and Lockett, 1914b, Martin 1927) and effluent suspended solids problems. Martin (1927) also describes effluent quality problems due to toxic and/or high-organic- strength industrial wastes. Oxygen demanding materials would bleedthrough the process. More recently, Jenkins, Richard and Daigger (1993) discussed severe foaming problems in activated sludge systems. Experience shows that controlling the activated sludge process is still difficult for many plants in the United States. However, improved process control can be obtained by systematically looking at the problems and their potential causes. Once the cause is defined, control actions can be initiated to eliminate the problem. Problems associated with the activated sludge process can usually be related to four conditions (Schuyler, 1995). Any of these can occur by themselves or with any of the other conditions. The first is foam. So much foam can accumulate that it becomes a safety problem by spilling out onto walkways. It becomes a regulatory problem as it spills from clarifier surfaces into the effluent. The second, high effluent suspended solids, can be caused by many things. It is the most common problem found in activated sludge systems. -
Chemical Industry Wastewater Treatment
CHEMICAL INDUSTRY WASTEWATER TREATMENT Fayza A. Nasr\ Hala S. Doma\ Hisham S Abdel-Halim", Saber A. El-Shafai* * Water Pollution Research department, National Research Centre, Cairo, Egypt "Faculty of Engineering, Cairo University, Cairo, Egypt Abstract Treatment of chemical industrial wastewater from building and construction chemicals factory and plastic shoes manufacturing factory was investigated. The two factories discharge their wastewater into the public sewerage network. The results showed the wastewater discharged from the building and construction chemicals factory was highly contaminated with organic compounds. The average values of COD and BOD were 2912 and 150 mg02/l. Phenol concentration up to 0.3 mg/l was detected. Chemical treatment using lime aided with ferric chloride proved to be effective and produced an effluent characteristics in compliance with Egyptian permissible limits. With respect to the other factory, industrial wastewater was mixed with domestic wastewater in order to lower the organic load. The COD, BOD values after mixing reached 5239 and 2615 mg02/l. The average concentration of phenol was 0.5 mg/l. Biological treatment using activated sludge or rotating biological contactor (RBC) proved to be an effective treatment system in terms of producing an effluent characteristic within the permissible limits set by the law. Therefore, the characteristics of chemical industrial wastewater determine which treatment system to utilize. Based on laboratory results TESCE, Vol. 30, No.2 <@> December 2004 engineering design of each treatment system was developed and cost estimate prepared. Key words: chemical industry, wastewater, treatment, chemical, biological Introduction The chemical industry is of importance in terms of its impact on the environment. -
Crystallization of Oxytetracycline from Fermentation Waste Liquor: Influence of Biopolymer Impurities
Journal of Colloid and Interface Science 279 (2004) 100–108 www.elsevier.com/locate/jcis Crystallization of oxytetracycline from fermentation waste liquor: influence of biopolymer impurities Shi-zhong Li a,1, Xiao-yan Li a,∗, Dianzuo Wang b a Environmental Engineering Research Centre, Department of Civil Engineering, The University of Hong Kong, Hong Kong, China b Chinese Academy of Engineering, Beijing 100038, China Received 28 January 2004; accepted 17 June 2004 Available online 29 July 2004 Abstract Organic impurities in the fermentation broth of antibiotic production impose great difficulties in the crystallization and recovery of antibi- otics from the concentrated waste liquor. In the present laboratory study, the inhibitory effect of biopolymers on antibiotic crystallization was investigated using oxytetracycline (OTC) as the model antibiotic. Organic impurities separated from actual OTC fermentation waste liquor by ultrafiltration were dosed into a pure OTC solution at various concentrations. The results demonstrated that small organic molecules with an apparent molecular weight (AMW) of below 10,000 Da did not affect OTC crystallization significantly. However, large biopolymers, especially polysaccharides, in the fermentation waste caused severe retardation of crystal growth and considerable deterioration in the pu- rity of the OTC crystallized. Atomic force microscopy (AFM) revealed that OTC nuclei formed in the solution attached to the surfaces of large organic molecules, probably polysaccharides, instead of being surrounded by proteins as previously thought. It is proposed that the attachment of OTC nuclei to biopolymers would prevent OTC from rapid crystallization, resulting in a high OTC residue in the aqueous phase. In addition, the adsorption of OTC clusters onto biopolymers would destabilize the colloidal system of organic macromolecules and promote particle flocculation. -
Microfiltration of Cutting-Oil Emulsions Enhanced by Electrocoagulation
This article was downloaded by: [Faculty of Chemical Eng & Tech], [Krešimir Košutić] On: 30 April 2015, At: 03:13 Publisher: Taylor & Francis Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK Desalination and Water Treatment Publication details, including instructions for authors and subscription information: http://www.tandfonline.com/loi/tdwt20 Microfiltration of cutting-oil emulsions enhanced by electrocoagulation b a a b Janja Križan Milić , Emil Dražević , Krešimir Košutić & Marjana Simonič a Faculty of Chemical Engineering and Technology, Department of Physical Chemistry, University of Zagreb, Marulićev trg 19, HR-10000 Zagreb, Croatia, Tel. +385 1 459 7240 b Faculty of Chemistry and Chemical Engineering, Laboratory for Water Treatment, University of Maribor, Smetanova 17, SI-2000 Maribor, Slovenia Published online: 30 Apr 2015. Click for updates To cite this article: Janja Križan Milić, Emil Dražević, Krešimir Košutić & Marjana Simonič (2015): Microfiltration of cutting-oil emulsions enhanced by electrocoagulation, Desalination and Water Treatment, DOI: 10.1080/19443994.2015.1042067 To link to this article: http://dx.doi.org/10.1080/19443994.2015.1042067 PLEASE SCROLL DOWN FOR ARTICLE Taylor & Francis makes every effort to ensure the accuracy of all the information (the “Content”) contained in the publications on our platform. However, Taylor & Francis, our agents, and our licensors make no representations or warranties whatsoever as to the accuracy, completeness, or suitability for any purpose of the Content. Any opinions and views expressed in this publication are the opinions and views of the authors, and are not the views of or endorsed by Taylor & Francis. -
Industrial Wastewater Treatment Technologies Fitxategia
INDUSTRIAL WASTEWATER TREATMENT TECHNOLOGIES Image by Frauke Feind from Pixabay licensed under CC0 Estibaliz Saez de Camara Oleaga & Eduardo de la Torre Pascual Faculty of Engineering Bilbao (UPV/EHU) Department of Chemical and Environmental Engineering Industrial Wastewaters (IWW) means the water or liquid that carries waste from industrial or processes, if it is distinct from domestic wastewater. Desalination plant “Rambla Morales desalination plant (Almería - Spain)” by David Martínez Vicente from Flickr licensed under CC BY 2.0 IWW may result from any process or activity of industry which uses water as a reactant or for transportation of heat or materials. 2 Characteristics of wastewater from industrial sources vary with the type and the size of the facility and the on-site treatment methods, if any. Because of this variation, it is often difficult to define typical operating conditions for industrial activities. Options available for the treatment of IWW are summarized briefly in next figure. To introduce in a logical order in the description of treatment techniques, the relationship between pollutants and respective typical treatment technology is taken as reference. 1. Removal of suspended solids and insoluble liquids 2. Removal of inorganic, non-biodegradable or poorly degradable soluble content 3. Removal of biodegradable soluble content 3 Range of wastewater treatments in relation to type of contaminants. Source: BREF http://eippcb.jrc.ec.europa.eu/reference/ 4 3.1. CLASSIFICATION OF INDUSTRIAL EFFLUENTS CLASSIFICATION OF EFFLUENTS -
Particle Separation and Fractionation by Microfiltration
Particle separation and fractionation by microfiltration Promotor: Prof. Dr. Ir. R.M. Boom Hoogleraar Levensmiddelenproceskunde, Wageningen Universiteit Copromotoren: Dr. Ir. C.G.P.H. Schro¨en Universitair docent, sectie Proceskunde, Wageningen Universiteit Dr. Ir. R.G.M. van der Sman Universitair docent, sectie Proceskunde, Wageningen Universiteit Promotiecommissie: Prof. Dr. Ir. J.A.M. Kuipers Universiteit Twente Prof. Dr. Ir. M. Wessling Universiteit Twente Dr. Ir. A. van der Padt Royal Friesland Foods Prof. Dr. M.A. Cohen Stuart Wageningen Universiteit Janneke Kromkamp Particle separation and fractionation by microfiltration Scheiding en fractionering van deeltjes middels microfiltratie Proefschrift Ter verkrijging van de graad van doctor op gezag van de rector magnificus van Wageningen Universiteit, Prof.dr. M.J. Kropff, in het openbaar te verdedigen op dinsdag 6 september 2005 des namiddags te vier uur in de Aula. Particle separation and fractionation by microfiltration Janneke Kromkamp Thesis Wageningen University, The Netherlands, 2005 - with Dutch summary ISBN: 90-8504-239-9 Contents 1 Introduction 1 1.1 Membrane filtration 2 1.2 Microfiltration 2 1.3 Mass transport 5 1.4 Shear-induced diffusion 7 1.5 Research aim and outline 9 2 Lattice Boltzmann simulation of 2D and 3D non-Brownian suspensions in Couette flow 13 2.1 Introduction 14 2.2 Computer simulation method 15 2.2.1 Simulation of the fluid 15 2.2.2 Fluid-particle interactions 17 2.2.3 Accuracy of particle representation and particle-particle interactions 18 2.3 Single and pair particles