Safety Data Sheet s3

SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

SAFETY DATA SHEET SALIGIN MPS (SODIUM METHYL PARABEN)

1.Product identifier Product name: Sodium Methyl Paraben Product code : SLM3823 EC#: 225-714-1 CAS#: 5026-62-0 EINECS#: 225-714-1 RTECS: DH2455000 Synonyms: Methylparaben, sodium salt; Benzoate, 4-oxide-, methyl, sodium salt; Benzoic acid, 4-hydroxy-, methyl ester, sodium salt; Benzoic acid, p-hydroxy-, methyl ester, sodium derivative; Methyl p-hydroxybenzoate, sodium salt; Sodium 4-(methoxycarbonyl)phenolate. Chemical Formula : C8 H7 Na O3

Structural Formula :

1.1. Relevant uses and uses advised against  It is characterized by its high solubility in cold water and is extremely effective preservatives regularly used in hair styling gels, hair care products toothpaste and oral care products.  It can be particularly useful when the heating of aqueous solution is undesirable.

 With high water solubility, it can be used in aqueous products that cannot be heated.

1.2. Details on the supplier of the SDS

SALICYLATES & CHEMICALS PVT. LTD., SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

1.3. Emergency telephone number: (EM): give the number of the company (+ working hours) and emergency number in the country of destination.

2. Hazard identification

2.1. Classification of Substance

2.1.1. Classification according to Regulation (EC) Nr 1272/2008 (CLP/GHS) Acute Tox. 2: H332 Skin Irrit. 2 : H315 Eye Irrit. 2 : H319

2.1.2. Classification according to Directive 67/548/EEC (DSD):  R22: Harmful if Swallowed

2.2. Labelling

2.2.1. Labeling according to Regulation (EC) No 1272/2008 (CLP/GHS)

Hazard pictogram:

GHS08: Health SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

Signal word:

Warning

Hazard statements: H332

GHS07: Skin and Eye

Signal word:

Warning

Hazard statements: H315,H319 Precautionary statements:

 P262: Do not get in eyes, on skin, or on clothing

2.2.2. Labeling according to Directive 67/548/EEC (DSD):

Hazard statements:

R-phrases:

 R22: Harmful if Swallowed  R36/38: Irritating to eyes and skin

Precautionary statements:

S-phrases:

 S24 – Avoid contact with skin  S25 - Avoid contact with eyes SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

2.3. Other hazards

Substance meets the criteria for PBT according to Regulation (EC) 1907/2006, Annex XIII  No

Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII:  No

2.Composition/Information on ingredients Constituents

Constituent CAS# Concentration 5026-62-0 100 % (w/w) Sodium Methyl Paraben

4. First Aid Measures

4.1. Description of first aid measures Inhalation- Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion- Rinse mouth thoroughly with water and give large amounts of milk or water to people not unconscious. Get medical attention. Skin- Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Eyes- Promptly wash eyes with plenty of water while lifting the eye lids. Contact physician if irritation persists.

4.2. Most important symptoms and effects, both acute and delayed The substance is toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage.

4.3. indication of any immediate medical attention and special treatment needed Not Available

5. Fire fighting measures Flammability of the Product: May be combustible at high temperature. SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

Products of Combustion: These products are carbon oxides (CO, CO2). Some metallic oxides. Fire Hazards in Presence of Various Substances: Extremely flammable in presence of open flames and sparks. Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

6. Accidental release measures: Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.

7. Handling and storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Keep from contact with moist air and steam.

Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

8: Exposure Controls/Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.

Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate protective gloves to prevent skin exposure. SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators: A respiratory protection program that meets OSHA’s 29 CFR Ì1910.134 and ANSI Z88.2 requirements or European

Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s use.

8.2 Exposure controls: Exposure Limits: Not available.

9. Physical and chemical properties

9.1. Information on basic physical and chemical properties

Property Results 1) odour Not Available 2) pH, concentration 9,5-10,5 solution 3) Melting / freezing point Not Available 4) Boiling point Decomposes 5) Vapour density Not applicable 6) Water solubility Soluble in cold water. 7) Auto-ignition The substance is not auto-flammable temperature 8) Molecular Weight 174.13 9) Physical State Solid. Crystals or crystalline. Plates.

10) Corrosivity Non-corrosive in presence of glass, of steel, of stainless steel(304), of stainless steel(316).

10. Stability and Reactivity SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

10.1. Reactivity No details have been found

10.2. Chemical stability Stable under normal temperatures and pressures.

10.3. Possibility of hazardous reactions Strong oxidants.

10.4. Conditions to avoid Incompatible materials, strong oxidants, exposure to moist air or water.

10.5. Incompatible materials Avoid: Contact with alkalis. Normally stable. Hygroscopic.

10.6. Hazardous decomposition products Fire or high temperatures create: Very toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

11. Toxicological Information

Acute toxicity

Product/ingredient Result Species Dose Exposure name Sodium Methyl LD50 Oral Rat 2000 NA Paraben mg/kg

Irritation/Corrosion

Skin: Slightly Hazardous Eye: Hazardous Respiratory tract: Very hazardous in case of inhalation. SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

Sensitization Skin disorders and allergies.

Germ cell mutagenicity

No biologically relevant genotoxic activity

Carcinogenicity

No experimental or epidemiological evidence exists to justify classification of sodium compounds for carcinogenic activity

Reproductive toxicity

No experimental or epidemiological evidence exists to justify classification of sodium compounds for reproductive or developmental toxicity

Specific target organ toxicity (single exposure)

No experimental or epidemiological sufficient evidence for specific target organ toxicity

Specific target organ toxicity (repeated exposure)

No experimental or epidemiological sufficient evidence for specific target organ toxicity

12. Ecological Information

12.1. Toxicity

Not available.

12.2. Persistence and biodegradability

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

12.3. Bioaccumulative potential

The products of degradation are more toxic. Decomposes and burns to form smoke, carbon monoxide and carbon dioxide. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is s potential dust explosion hazard.

12.4. Results of PBT and vPvB assessment

No information has been found

13. Disposal Considerations

Material in the elemental state should be recovered for reuse or recycling. Contact a licensed professional waste disposal service to dispose of this material. Observe all federal, state, and local environmental regulations.

14. Transport Information

DOT Classification: Not a DOT controlled material (United States). Identification: Not applicable. Special Provisions for Transport: Not applicable. IATA No information available. IMO No information available. RID/ADR No information available.

15. Regulatory Information

European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN

Risk Phrases: R 22 Harmful if swallowed. R36 Irritating to eyes Safety Phrases: S24 – Avoid contact with skin S25 - Avoid contact with eyes

Other regulatory information SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

HMIS (Hazardous Materials Identification System) Classification

2 = Moderate Hazard = Temporary or minor injury may occur 1= Slight Hazard = Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) 0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water, polymerise, decompose, condense or self react E =

NFPA (National Fire Protection Association)

2= Health Hazard = Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. 1= Flammability = Must be preheated before ignition can occur. 0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.

Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

16. Other Information  Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the factory  Create a Register for Workplace Chemicals;  Set priorities concerning the safety in the organization SALICYLATES & CHEMICALS PVT. LTD., A-25, Road No.18, I.D.A. Nacharam, Hyderabad - 500 076 – India. Tel # 91 40 27171550, 27174691 Fax # +91 40 27171249 Email : [email protected] Visit us : www.preservativesindia.com

 Create emergency plans for the assessed hazards;  Organize occupational health care and regular surveys as necessary;  Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards, and to reliably measure and/or estimate occupational exposures to chemicals when needed;  Start collecting case studies of accidents and sickness records in the enterprise to create a basis for priority measures in the control of hazards;  Involve workers in safety organizations, such as the system of Safety Representatives and Committees.  Do regular inspection using checklists made for the particular chemicals and chemical processes in use;  Mark and label all chemicals;  Keep at hand an inventory list of all chemicals handled in the place of work together with a collection of Chemical Safety Data Sheets for these chemicals;  Train workers to read and understand the Chemical Safety Information, including the health hazards and routes of exposure; train them to handle dangerous chemicals and processes with respect;  Plan, develop and choose the safe working procedures;  Reduce the number of people coming into contact with dangerous chemicals;  Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals;  Train workers to know and understand the emergency procedures;  Equip and train workers to use personal protective equipment properly after everything possible has been done to eliminate hazards by means of other methods;

Created By: ELC GROUP Contact Person momaja s.r.o. Jastin Sardhara Krakovska 9, Prague 1, 110 00 Czech Republic Tel. +420 22 491 0000 Fax. +420 22 491 0671

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall SALICYLATES & CHEMICALS PVT. LTD be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages.