Tin Resources of the World
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PGM Associations in Copper-Rich Sulphide Ore of the Oktyabr Deposit, Talnakh Deposit Group, Russia Olga A. Yakovleva1, Sergey M. Kozyrev1 and Oleg I. Oleshkevich2 1Institute Gipronickel JS, St. Petersburg, Russia 2Mining and Metallurgical Company “Noril’sk Nickel” JS, Noril’sk, Russia e-mail: [email protected] The PGM assemblages of the Cu-rich 6%; the Ni content ranges 0.8 to 1.3%, and the ratio sulphide ores occurring in the western exocontact Cu/S = 0.1-0.2. zone of the Talnakh intrusion and the Kharaelakh Pyrrhotite-chalcopyrite ore occurs at the massive orebody have been studied. Eleven ore top of ore horizons. The ore-mineral content ranges samples, weighing 20 to 200 kg, were processed 50 to 60%, and pyrrhotite amount is <15%. The ore using gravity and flotation-gravity techniques. As a grades 1.1 to 1.3% Ni, and the ratio Cu/S = 0.35- result, the gravity concentrates were obtained from 0.7. the ores and flotation products. In the gravity Chalcopyrite ore occurs at the top and on concentrates, more than 20,000 PGM grains were the flanks of the orebodies. The concentration of found and identified, using light microscopy and sulphides ranges 50 to 60%, and pyrrhotite amount EPMA. The textural and chemical characteristics of is <1%; the Ni content ranges 1.3 to 3.4%, and the PGM were documented, as well as the PGM ratio Cu/S = 0.8-0.9. distribution in different size fractions. Also, the The ore types are distinctly distinguished balance of Pt, Pd and Au distribution in ores and by the PGE content which directly depends on the process products and the PGM mass portions in chalcopyrite quantity, but not on the total sulphide various ore types were calculated. -
West Coast Land Use Planning Strategy
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LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Key to Rocks & Minerals Collections
STATE OF MICHIGAN MINERALS DEPARTMENT OF NATURAL RESOURCES GEOLOGICAL SURVEY DIVISION A mineral is a rock substance occurring in nature that has a definite chemical composition, crystal form, and KEY TO ROCKS & MINERALS COLLECTIONS other distinct physical properties. A few of the minerals, such as gold and silver, occur as "free" elements, but by most minerals are chemical combinations of two or Harry O. Sorensen several elements just as plants and animals are Reprinted 1968 chemical combinations. Nearly all of the 90 or more Lansing, Michigan known elements are found in the earth's crust, but only 8 are present in proportions greater than one percent. In order of abundance the 8 most important elements Contents are: INTRODUCTION............................................................... 1 Percent composition Element Symbol MINERALS........................................................................ 1 of the earth’s crust ROCKS ............................................................................. 1 Oxygen O 46.46 IGNEOUS ROCKS ........................................................ 2 Silicon Si 27.61 SEDIMENTARY ROCKS............................................... 2 Aluminum Al 8.07 METAMORPHIC ROCKS.............................................. 2 Iron Fe 5.06 IDENTIFICATION ............................................................. 2 Calcium Ca 3.64 COLOR AND STREAK.................................................. 2 Sodium Na 2.75 LUSTER......................................................................... 2 Potassium -
The Collapse of the International Tin Agreement
CORE Metadata, citation and similar papers at core.ac.uk Provided by IDS OpenDocs The Collapse of the International Tin Agreement Michael Prest Introduction unimportant part of an international dispute which it Early on the morning of 24 October 1985 Michael only dimly understood. The field was quickly Brown,chiefexecutiveof the London Metal dominated by national governments, big banks, and in Exchange, was sitting in his office chatting to the the background the United Nations Conference on chairman of the exchange's committee, Ted Jordan. Trade and Development. The telephone range. It was Pieter de Koning, the International Tin Council's buffer stock manager and For the LME the issues were the sanctity of contract the most powerful person in the world tin market. and the preservation of the exchange. But for the other There was a brief conversation. Brown recalls:'I participants it was a matter of realpolitik, in which the turned to Ted and said "de Koning has suspended stakes were the future of international commodity trading".' agreements, the debt crisis, and relations between developing commodity producing countries and In that instant both realised that chaos threatened. industrial consumers of commodities. What originated Their immediate concern was the LME and its as a commercial dispute - the announcement by the members. They knew that around half of the LME's 27 ITC that it could not pay its debts - rapidly ring dealing members' were heavily involved with the intensified and expanded into a test case of the ability buffer stock. They also suspected that de Koning's of commodity agreements to survive in adverse careful word 'suspend' was code for defaulting on his market conditions. -
Gomposition and Occurrence of Electrum Atthe
L37 The Canadian M inerala g i st Vol.33,pp. 137-151(1995) GOMPOSITIONAND OCCURRENCEOF ELECTRUM ATTHE MORNINGSTAR DEPOSIT, SAN BERNARDINOCOUNTY, GALIFORNIA: EVIDENCEFOR REMOBILIZATION OF GOLD AND SILVER RONALD WYNN SIIEETS*, JAMES R. CRAIG em ROBERT J. BODNAR Depanmen of Geolngical Sciences, Virginin Polytechnic h stitate and Stale (Jniversity, 4A44 Dening Hall, Blacl<sburg, Virginin 24060, U.S-A,. Arsrnacr Elecfum, acanthiteand uytenbogaardtite have been examined from six depthswithin the tabular quartzt calcite sockwork and breccia-filled veins in the fault-zone-hostedMorning Star depositof the northeasternMojave Desert, Califomia. Six distinct types of electrum have been identified on the basis of minerat association,grain moryhology and composition. Two types, (1) p1'rite-hostedand (2) quartz-hostedelectrum, occur with acanthite after argentite and base-metalsulfide minerals in unoxidized portions of the orebody; the remaining forr types, (3) goethite-hostedelectrum, (4) electnrm cores, (5) electrumrims and (6) wire electrum,are associatedwith assemblagesof supergeneminerals in its oxidizedportions. Pyrite- hosted quartz-hostedand goethite-hostedelectrum range in compositionfrom 6l ta 75 utt.7oAu and have uniform textures and no zoning. In lower portions ofthe oxidized ore zone, electrum seemsto replacegoethite and occursas small grains on surfacesof the goethite.Textural evidencefavors supergeneremobilization of Au and Ag, which were depositedas electrum on or replacinggoethite. This type of electrumis identical in appearanceand compositionto prinary electrum,In the upper portions of the oxidized zone,secondary electum occursas a gold-rich rim on a core of elechum and as wire-like grains,both with acanthiteand uytenbogaardtite.Such secondaryelectrum contains from 78 to 93 wt./o Au. Textural relations and asso- ciated minerals suggestthat the primary electrum was hydrothermally depositedand partially remobilized by supergene processes. -
Pyrostilpnite Ag3sbs3 C 2001-2005 Mineral Data Publishing, Version 1
Pyrostilpnite Ag3SbS3 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals tabular {010} giving flat rhombic forms; also laths by elongation k [001], to 1 mm; as subparallel sheaflike aggregates. Twinning: On {100} with (100) as composition plane. Physical Properties: Fracture: Conchoidal. Tenacity: Somewhat flexible in thin plates. Hardness = 2 VHN = 95–115, 107 average (100 g load). D(meas.) = 5.94 D(calc.) = 5.97 Optical Properties: Transparent. Color: Hyacinth-red; lemon-yellow by transmitted light. Streak: Yellow-orange. Luster: Adamantine. Optical Class: Biaxial (+). Orientation: Y = b; X ∧ c = 8–11◦. α = Very high. β = Very high. γ = Very high. R1–R2: (400) 36.3–36.9, (420) 36.3–36.5, (440) 36.1–35.8, (460) 35.7–35.1, (480) 34.9–34.2, (500) 33.9–33.2, (520) 32.3–31.8, (540) 30.8–30.3, (560) 29.6–29.2, (580) 28.6–28.2, (600) 27.8–27.5, (620) 27.1–26.7, (640) 26.6–26.2, (660) 26.2–25.8, (680) 25.9–25.4, (700) 25.6–25.2 ◦ 0 Cell Data: Space Group: P 21/c. a = 6.84 b = 15.84 c = 6.24 β = 117 09 Z=4 X-ray Powder Pattern: Pˇr´ıbram, Czech Republic. 2.85 (100), 2.65 (50), 2.42 (50), 1.895 (50b), 1.887 (50b), 1.824 (20b), 1.813 (20b) Chemistry: (1) (2) (3) Ag 59.44 59.7 59.76 Sb 22.30 23.7 22.48 S 18.11 16.8 17.76 Total 99.85 100.2 100.00 (1) St. -
Both Pestle and Mortar Should Be Sent to a Commercial Heat Treating House to Be Carburized to a Depth of at Least $ Inch and Hardened to 62-64 Rockwell C
NOTES AND NEWS 165 Both pestle and mortar should be sent to a commercial heat treating house to be carburized to a depth of at least $ inch and hardened to 62-64 Rockwell C. It is not necessaryto harden the sleeve although it may be cyanided. After heat treating the mortar is chucked in the lathe and the diameter of the projection is ground with a tool post grinder to a tight, but re- movable, fi.t to the sleeve. The face of the projection should be ground true to the side at the same chucking. The pestle is also chucked and the diameter of the grinding end reduced about .005 inch, or a working fit in the sleeve.The face of the pestle should also be ground true with the side. A NEW LOCALITY FOR GREENOCKITE CRYSTALS IN BOLIVIA FnBoBnrco Aur,rnr,o, C ochabambo, Bol'ivia. Greenockite is a rare mineral in the Bolivian tin deposits' It has been describedonly from Llallagua by S. Gordon (1). The mineral forms coat- ings of minute red crystals, resembling vanadinite in colour, upon quartz' marcasite, cassiteriteand on the wall rock, almost always associatedwith wavellite. The crystals are exceedinglyminute, rarely measuring as much as 0.1 mm. They vary greatly in habit from pyramidal to thick tabular and prismatic. Cyclic twins are common. Gordon ascribesthe formation of the mineral to supergenesolutions. The source of the cadmium may have been from the wurtzite or sphalerite which has relaced pyrrhotite. 166 NOTESAND NEWS Recently I found a secondoccurrence of greenockite in Bolivia, which is remarkable for the larger size and the rich red colour of the crystals. -
SPANISH CEPAL Economic Commission
Distr. RESTRICTED E/CEPAL/R.249 1H January 1932 ENGLISH ORIGINAL: SPANISH C E P A L Economic Commission for Latin America LINKS OF THE TRANSNATIONAL CORPORATIONS WITH THE TIN INDUSTRY IN BOLIVIA Jan Kfiakal */ jV The author is a regional expert of the CEPAL/CTC Joint Unit on Transnational Corporations. The views expressed in this working paper are those of the author and do not necessarily reflect the views of the Organization. 81-9-2017 - 1X• • 1» - CONTENTS Page Introduction . i Part One THE INTERNATIONAL TIN INDUSTRY 5 1. Characteristics of the product 5 2. Tin mining and reserves 7 3. Sovereignty of the developing countries over their tin resources 10 4. Tin smelting and position of the main transnational corporations 15 5. Control over the world tin market 20 Part Two THE BOLIVIAN TIN INDUSTRY AND ITS LINKS WITH TRANSNATIONAL CORPORATIONS 29 1. The importance of mining and tin in the Bolivian economy 29 2. Early stage of the industry and its nationalization in 1952 . 31 3. Establishment of the Corporación Minera de Bolivia and the* postnationalization period 34 4. Continued dependence on foreign smelters 36 5. Importance of the public enterprise in tin smelting 42 6. Domestic integration of the mining and metallurgical sector (COMIBOL and ENAF) and reaction of the foreign smelters 44 7. Marketing of metal tin by ENAF 57 8. Industrialization based on tin: its limits and possibilities for increased regional co-operation 64 9. Conclusions to be drawn from the Bolivian experience 71 Annex 1 Selected Bibliography 77 Annex 2 Main clauses and technical specifications included in ENAF's tin marketing contracts 79 Annex 3 Contract between ENAF and an international sales agent . -
Tin from Myanmar – a Scenario for Applying the European Union Regu- Lation on Supply Chain Due Diligence
Commodity TopNews Fakten ● Analysen ● Wirtschaftliche Hintergrundinformationen 61 TIN FROM MYANMAR – A SCENARIO FOR APPLYING THE EUROPEAN UNION REGU- LATION ON SUPPLY CHAIN DUE DILIGENCE Christian Heimig 1, Philip Schütte 2, Gudrun Franken 2, Christoph Klein 3 Abb. 1:: Small-scale miners at the Mawchi tin mine, central Myanmar (photo: BGR). INTRODUCTION Starting from January 1, 2021, European Union including, among others, conflict financing, the (EU)-based importers of tin, tantalum and tungs- worst forms of child labor and human rights vi- ten, their ores, and gold are required to comply olations. To this end, the OECD guidance defi- with the EU regulation on supply chain due dili- nes a five-step due diligence framework, which gence (EU, 2017). The EU regulation is based on has been integrated into the EU regulation. The- the OECD due diligence guidance for responsib- se steps include establishing strong management le supply chains. The contents of this guidance systems, identifying and responding to supply provide a framework for companies to identify chain risks, carrying out independent third-party and mitigate risks in their mineral supply chains audits at certain points in the supply chain, and public reporting on due diligence implementation (OECD, 2016). 1 Formerly Federal Institute for Geosciences and Natural Resources, presently at Südwestdeutsche Salzwerke AG 2 Federal Institute for Geosciences and Natural Resources 3 Formerly Federal Institute for Geosciences and Natural Resources, presently at KPMG AG Wirtschaftsprüfungsgesellschaft 2 Commodity TopNews The US Dodd-Frank Act, enacted in 2010, al- oned experts to develop an indicative global list ready defines certain sourcing requirements for of such areas, companies remain responsible for so-called conflict minerals. -
Ag-Pb-Sb Sulfosalts and Se-Rich Mineralization of Anthony of Padua
minerals Article Ag-Pb-Sb Sulfosalts and Se-rich Mineralization of Anthony of Padua Mine near Poliˇcany—Model Example of the Mineralization of Silver Lodes in the Historic Kutná Hora Ag-Pb Ore District, Czech Republic Richard Pažout 1,*, Jiˇrí Sejkora 2 and Vladimír Šrein 3 1 Institute of Chemical Technology, Technická 5, 166 28 Prague 6, Czech Republic 2 Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, 193 00 Prague 9–Horní Poˇcernice,Czech Republic 3 Czech Geological Survey, Klárov 3, 118 21 Prague 1, Czech Republic * Correspondence: [email protected]; Tel.: +420-220444080 Received: 3 May 2019; Accepted: 6 July 2019; Published: 12 July 2019 Abstract: Significant selenium enrichment associated with selenides and previously unknown Ag-Pb-Sb, Ag-Sb and Pb-Sb sulfosalts has been discovered in hydrothermal ore veins in the Anthony of Padua mine near Poliˇcany, Kutná Hora ore district, central Bohemia, Czech Republic. The ore mineralogy and crystal chemistry of more than twenty silver minerals are studied here. Selenium mineralization is evidenced by a) the occurrence of selenium minerals, and b) significantly increased selenium contents in sulfosalts. Identified selenium minerals include aguilarite and selenides naumannite and clausthalite. The previously unknown sulfosalts from Kutná Hora are identified: Ag-excess fizélyite, fizélyite, andorite IV, andorite VI, unnamed Ag-poor Ag-Pb-Sb sulfosalts, semseyite, stephanite, polybasite, unnamed Ag-Cu-S mineral phases and uytenbogaardtite. Among the newly identified sulfides is argyrodite; germanium is a new chemical element in geochemistry of Kutná Hora. Three types of ore were recognized in the vein assemblage: the Pb-rich black ore (i) in quartz; the Ag-rich red ore (ii) in kutnohorite-quartz gangue; and the Ag-rich ore (iii) in milky quartz without sulfides.