Ice-Ocean Exchange Processes in the Jovian and Saturnian Satellites
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Modeling the Ice VI to VII Phase Transition
Modeling the Ice VI to VII Phase Transition Dawn M. King 2009 NSF/REU PROJECT Physics Department University of Notre Dame Advisor: Dr. Kathie E. Newman July 31, 2009 Abstract Ice (solid water) is found in a number of different structures as a function of temperature and pressure. This project focuses on two forms: Ice VI (space group P 42=nmc) and Ice VII (space group Pn3m). An interesting feature of the structural phase transition from VI to VII is that both structures are \self clathrate," which means that each structure has two sublattices which interpenetrate each other but do not directly bond with each other. The goal is to understand the mechanism behind the phase transition; that is, is there a way these structures distort to become the other, or does the transition occur through the breaking of bonds followed by a migration of the water molecules to the new positions? In this project we model the transition first utilizing three dimensional visualization of each structure, then we mathematically develop a common coordinate system for the two structures. The last step will be to create a phenomenological Ising-like spin model of the system to capture the energetics of the transition. It is hoped the spin model can eventually be studied using either molecular dynamics or Monte Carlo simulations. 1 Overview of Ice The known existence of many solid states of water provides insight into the complexity of condensed matter in the universe. The familiarity of ice and the existence of many structures deem ice to be interesting in the development of techniques to understand phase transitions. -
11Th International Conference on the Physics and Chemistry of Ice, PCI
11th International Conference on the Physics and Chemistry of Ice (PCI-2006) Bremerhaven, Germany, 23-28 July 2006 Abstracts _______________________________________________ Edited by Frank Wilhelms and Werner F. Kuhs Ber. Polarforsch. Meeresforsch. 549 (2007) ISSN 1618-3193 Frank Wilhelms, Alfred-Wegener-Institut für Polar- und Meeresforschung, Columbusstrasse, D-27568 Bremerhaven, Germany Werner F. Kuhs, Universität Göttingen, GZG, Abt. Kristallographie Goldschmidtstr. 1, D-37077 Göttingen, Germany Preface The 11th International Conference on the Physics and Chemistry of Ice (PCI- 2006) took place in Bremerhaven, Germany, 23-28 July 2006. It was jointly organized by the University of Göttingen and the Alfred-Wegener-Institute (AWI), the main German institution for polar research. The attendance was higher than ever with 157 scientists from 20 nations highlighting the ever increasing interest in the various frozen forms of water. As the preceding conferences PCI-2006 was organized under the auspices of an International Scientific Committee. This committee was led for many years by John W. Glen and is chaired since 2002 by Stephen H. Kirby. Professor John W. Glen was honoured during PCI-2006 for his seminal contributions to the field of ice physics and his four decades of dedicated leadership of the International Conferences on the Physics and Chemistry of Ice. The members of the International Scientific Committee preparing PCI-2006 were J.Paul Devlin, John W. Glen, Takeo Hondoh, Stephen H. Kirby, Werner F. Kuhs, Norikazu Maeno, Victor F. Petrenko, Patricia L.M. Plummer, and John S. Tse; the final program was the responsibility of Werner F. Kuhs. The oral presentations were given in the premises of the Deutsches Schiffahrtsmuseum (DSM) a few meters away from the Alfred-Wegener-Institute. -
Electromagnetism Based Atmospheric Ice Sensing Technique - a Conceptual Review
Int. Jnl. of Multiphysics Volume 6 · Number 4 · 2012 341 Electromagnetism based atmospheric ice sensing technique - A conceptual review Umair N. Mughal*, Muhammad S. Virk and M. Y. Mustafa High North Technology Center Department of Technology, Narvik University College, Narvik, Norway ABSTRACT Electromagnetic and vibrational properties of ice can be used to measure certain parameters such as ice thickness, type and icing rate. In this paper we present a review of the dielectric based measurement techniques for matter and the dielectric/spectroscopic properties of ice. Atmospheric Ice is a complex material with a variable dielectric constant, but precise calculation of this constant may form the basis for measurement of its other properties such as thickness and strength using some electromagnetic methods. Using time domain or frequency domain spectroscopic techniques, by measuring both the reflection and transmission characteristics of atmospheric ice in a particular frequency range, the desired parameters can be determined. Keywords: Atmospheric Ice, Sensor, Polar Molecule, Quantum Excitation, Spectroscopy, Dielectric 1. INTRODUCTION 1.1. ATMOSPHERIC ICING Atmospheric icing is the term used to describe the accretion of ice on structures or objects under certain conditions. This accretion can take place either due to freezing precipitation or freezing fog. It is primarily freezing fog that causes this accumulation which occurs mainly on mountaintops [16]. It depends mainly on the shape of the object, wind speed, temperature, liquid water content (amount of liquid water in a given volume of air) and droplet size distribution (conventionally known as the median volume diameter). The major effects of atmospheric icing on structure are the static ice loads, wind action on iced structure and dynamic effects. -
© Cambridge University Press Cambridge
Cambridge University Press 978-0-521-80620-6 - Creep and Fracture of Ice Erland M. Schulson and Paul Duval Index More information Index 100-year wave force, 336 friction and fracture, 289, 376 60° dislocations, 17, 82, 88 indentation failure, 345 microstructure, 45, 70, 237, 255, 273 abrasion, 337 multiscale fracture and frictional accommodation processes of basal slip, 165 sliding, 386 acoustic emission, 78, 90, 108 nested envelopes, 377 across-column cleavage cracks, 278 pressure–area relationship, 349, 352 across-column confinement, 282 S2 growth texture, 246, 273 across-column cracks, 282, 306, SHEBA faults, 371 across-column loading, 275 SHEBA stress states, 377 across-column strength, 246, 249, 275 Arctic Ocean, 1, 45, 190, 361 activation energy, 71, 84, 95, 111, 118, 131 aspect ratio, 344 activation volume, 114, 182 atmospheric ice, 219, 221, 241, 243 activity of pyramidal slip systems, 158 atmospheric icing, 31 activity of slip systems, 168 atmospheric impurities, 113 adiabatic heating, 291, 348 atomic packing factor, 9 adiabatic softening, 291 audible report, 240 affine self-consistent model, 160 avalanches, 206 air bubbles, 38 air-hydrate crystals, 37 bands, 89 albedo, 363 basal activity, 162 aligned first-year sea ice, 246 basal dislocations, 77 along-column confinement, 282 basal planes, 214, along-column confining stress, 282, basal screw dislocations, 77, 87 along-column strength, 244, 275 basal shear bands, 163 ammonia dihydrate, 181 basal slip, 18, 77, 127, 228 ammonia–water system, 186 basal slip lines, 77 amorphous forms -
Gibbs Energy of Ices III, V and VI: Wholistic Thermodynamics and Elasticity of the Water Phase Diagram to 2300 Mpa. 1. Abstract
Gibbs energy of ices III, V and VI: wholistic thermodynamics and elasticity of the water phase diagram to 2300 MPa. B. Journaux*1, J.M. Brown1, A. Pakhomova2, I. E. Collings3,4, S. Petitgirard5, P. Espinoza1, J. Ott1,6, F. Cova3,7, G. Garbarino3, M. Hanfland3 1. Abstract: Gibbs energy representations for ice III, V and VI are reported. These were constructed using new measurements of volumes at high pressure over a range of low temperatures combined with calculated vibrational energies grounded in statistical physics. The collection of representations including ice Ih and water (released as the open source “SeaFreeze” framework) allow accurate determinations of thermodynamics properties (phase boundaries, density, heat capacity, bulk modulus, thermal expansivity, chemical potentials) and seismic wave velocities over the entire range of conditions encountered in hydrospheres in our solar system (220-500K to 2300 MPa). These comprehensive representations allow exploration of the rich spectrum of thermodynamic behavior in the H2O system. Although the results are broadly applicable in science and engineering, their use in habitability analysis in water-rich planetary bodies of our solar system and beyond is particularly relevant. 2. Introduction Water is a fundamentally important molecule in scientific fields ranging from biology to engineering, earth and environmental sciences, chemistry or astrophysics. As a common molecular species in our cosmic neighborhood, water ice polymorphs at high pressures in planetary interiors could be the most abundant “mineral group” in the Universe (Hanslmeier 2011). A focus on potentially habitable icy moons and ocean exoplanets hydrospheres (Sotin and Tobie 2004; Vance and Brown 2013; Journaux et al. -
Design and Deployment of a 3D Autonomous Subterranean Submarine Exploration Vehicle
DESIGN AND DEPLOYMENT OF A 3D AUTONOMOUS SUBTERRANEAN SUBMARINE EXPLORATION VEHICLE William C. Stone, Stone Aerospace / PSC, Inc. 3511 Caldwell Lane, Del Valle, TX 78617, Ph: (512) 247-6385, [email protected] ABSTRACT likely include the following components: The NASA Deep Phreatic Thermal Explorer • the parent spacecraft, which will remain in orbit (DEPTHX) project is developing a fully autonomous either about Jupiter or about Europa and which will underwater vehicle intended as a prototype of primarily serve as a data relay back to Earth from the the Europa lander third stage that will search for Lander. microbial life beneath the ice cap of that Jovian • the Lander, which will be a 3-stage device: moon. DEPTHX has two principal objectives: First, to develop and test in an appropriate environment Stage 1: the physical landing system that will contain the ability for an un-tethered robot to explore into propulsion systems, power, and data relay systems to unknown 3D territory, to make a map of what it sees, communicate with the orbiter, and which will control and to use that map to return home; and second, to and carry out the descent and automated landing on demonstrate that science autonomy behaviors can the moon. identify likely zones for the existence of microbial life, to command an autonomous maneuvering Stage 2: the “cryobot” second stage, which will melt platform to move to those locations, conduct localized a hole through up to ten kilometers of ice cap before searches, and to autonomously collect microbial reaching the sub-surface liquid ocean. Although the life in an aqueous environment. -
Revised Release on the Pressure Along the Melting and Sublimation Curves of Ordinary Water Substance
IAPWS R14-08(2011) The International Association for the Properties of Water and Steam Plzeň, Czech Republic September 2011 Revised Release on the Pressure along the Melting and Sublimation Curves of Ordinary Water Substance 2011 International Association for the Properties of Water and Steam Publication in whole or in part is allowed in all countries provided that attribution is given to the International Association for the Properties of Water and Steam President: Mr. Karol Daucik Larok s.r.o. SK 96263 Pliesovce, Slovakia Executive Secretary: Dr. R. B. Dooley Structural Integrity Associates, Inc. 2616 Chelsea Drive Charlotte, NC 28209, USA email: [email protected] This revised release replaces the corresponding revised release of 2008 and contains 7 pages. This release has been authorized by the International Association for the Properties of Water and Steam (IAPWS) at its meeting in Plzeň, Czech Republic, 4-9 September, 2011, for issue by its Secretariat. The members of IAPWS are: Britain and Ireland, Canada, the Czech Republic, Germany, Greece, Japan, Russia, Scandinavia (Denmark, Finland, Norway, Sweden), and the United States of America, and associate members Argentina and Brazil, France, Italy, and Switzerland. In 1993, IAPWS issued a “Release on the Pressure along the Melting and Sublimation Curves of Ordinary Water Substance.” The empirical equations presented were fitted to relatively old experimental data for the several sections of the melting curve and the sublimation curve. Thus, these equations are not thermodynamically consistent with the subsequently developed IAPWS equations of state for fluid and solid H2O. These equations are “The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use” [1, 2] and “The Equation of State of H2O Ice Ih” [3, 4]. -
Rheological Properties of Water Ice—Applications to Satellites of the Outer Planets1
P1: FUM March 17, 2001 14:11 Annual Reviews AR125-11 Annu. Rev. Earth Planet. Sci. 2001. 29:295–330 RHEOLOGICAL PROPERTIES OF WATER ICE—APPLICATIONS TO SATELLITES OF THE OUTER PLANETS1 WB Durham2 and LA Stern3 2University of California, Lawrence Livermore National Laboratory, Livermore, California 94550; e-mail: [email protected] 3US Geological Survey, Menlo Park, California 94025; e-mail: [email protected] Key Words high-pressure phases, grain-size-sensitive creep, deformation mechanisms, brittle-to-ductile transition, Europa ■ Abstract The icy moons of the outer solar system have not been quiescent bodies, in part because many have a substantial water component and have experi- enced significant internal heating. We can begin to understand the thermal evolution of the moons and the rate of viscous relaxation of surface topography because we now have good constraints on how ice (in several of its polymorphic forms) flows under deviatoric stress at planetary conditions. Details of laboratory-derived flow laws for pure, polycrystalline ice are reviewed in detail. One of the more important questions at hand is the role of ice grain size. Grain size may be a dynamic quantity within the icy moons, and it may (or may not) significantly affect rheology. One recent benefi- ciary of revelations about grain-size-sensitive flow is the calculation of the rheological structure of Europa’s outer ice shell, which may be no thicker than 20 km. INTRODUCTION The rheology of water ice has a first-order influence on the evolution and appear- ance of over 15 moons belonging to Jupiter and to planets beyond, many of which have a mass fraction of water >0.5. -
Rest of the Solar System” As We Have Covered It in MMM Through the Years
As The Moon, Mars, and Asteroids each have their own dedicated theme issues, this one is about the “rest of the Solar System” as we have covered it in MMM through the years. Not yet having ventured beyond the Moon, and not yet having begun to develop and use space resources, these articles are speculative, but we trust, well-grounded and eventually feasible. Included are articles about the inner “terrestrial” planets: Mercury and Venus. As the gas giants Jupiter, Saturn, Uranus, and Neptune are not in general human targets in themselves, most articles about destinations in the outer system deal with major satellites: Jupiter’s Io, Europa, Ganymede, and Callisto. Saturn’s Titan and Iapetus, Neptune’s Triton. We also include past articles on “Space Settlements.” Europa with its ice-covered global ocean has fascinated many - will we one day have a base there? Will some of our descendants one day live in space, not on planetary surfaces? Or, above Venus’ clouds? CHRONOLOGICAL INDEX; MMM THEMES: OUR SOLAR SYSTEM MMM # 11 - Space Oases & Lunar Culture: Space Settlement Quiz Space Oases: Part 1 First Locations; Part 2: Internal Bearings Part 3: the Moon, and Diferent Drums MMM #12 Space Oases Pioneers Quiz; Space Oases Part 4: Static Design Traps Space Oases Part 5: A Biodynamic Masterplan: The Triple Helix MMM #13 Space Oases Artificial Gravity Quiz Space Oases Part 6: Baby Steps with Artificial Gravity MMM #37 Should the Sun have a Name? MMM #56 Naming the Seas of Space MMM #57 Space Colonies: Re-dreaming and Redrafting the Vision: Xities in -
Arxiv:1803.04883V1 [Physics.Flu-Dyn] 13 Mar 2018
Melting probe technology for subsurface exploration of extraterrestrial ice – Critical refreezing length and the role of gravity K. Sch¨uller, J. Kowalski∗ AICES Graduate School, RWTH Aachen University, Schinkelstr. 2, 52062 Aachen, Germany. Abstract The ’Ocean Worlds’ of our Solar System are covered with ice, hence the water is not directly accessible. Using melting probe technology is one of the promising technological approaches to reach those scientifically interesting water reservoirs. Melting probes basically consist of a heated melting head on top of an elongated body that contains the scientific payload. The traditional engineering approach to design such melting probes starts from a global energy balance around the melting head and quantifies the power necessary to sustain a specific melting velocity while preventing the probe from refreezing and stall in the channel. Though this approach is sufficient to design simple melting probes for terrestrial applications, it is too simplistic to study the probe’s performance for environmental conditions found on some of the Ocean’s Worlds, e.g. a lower value of the gravitational acceleration. This will be important, however, when designing exploration technologies for extraterrestrial purposes. We tackle the problem by explicitly modeling the physical processes in the thin melt film between the probe and the underlying ice. Our model allows to study melting regimes on bodies of different gravitational acceleration, and we explicitly compare melting regimes on Europa, Enceladus and Mars. In addition to that, our model allows to quantify the heat losses due to convective transport around the melting probe. We discuss to which extent these heat losses can be utilized to avoid the necessity of a side wall heating system to prevent stall, and introduce the notion of the ’Critical Refreezing Length’. -
Phase Transitions of Ice V and Vi Y
PHASE TRANSITIONS OF ICE V AND VI Y. Handa, D. Klug, E. Whalley To cite this version: Y. Handa, D. Klug, E. Whalley. PHASE TRANSITIONS OF ICE V AND VI. Journal de Physique Colloques, 1987, 48 (C1), pp.C1-435-C1-440. 10.1051/jphyscol:1987160. jpa-00226306 HAL Id: jpa-00226306 https://hal.archives-ouvertes.fr/jpa-00226306 Submitted on 1 Jan 1987 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. JOURNAL DE PHYSIQUE Colloque C1, supplkment au no 3, Tome 48, mars 1987 PHASE TRANSITIONS OF ICE V AND VI Y.P. HANDA, D.D. KLUG and E. WHALLEY Division of Chemistry, National Research Council of Canada. Ottawa, Ontario, KIA OR9, Canada &6sd - Les transitions de phase de la glace V et VI dans le domaine 90-175 K cnt 6~ CtudiCes par cdlorh5trie. Les transitions dans le domaine 105-140 K qui sont semblables B des transitions ordredsordre, ont Qt6 identifiks. Les variations d'enthalpie de celles-i ainsi que les transformations des glaces V et VI en glace I, plus hautes teratures cnt 6th &termi&es. Abstract - Phase transitions of ice V and VI in the range 90-175 K have been investigated by heat-flow calorimetry. -
Regelation: Why Does Ice Melt Under Pressure?
Regelation: why does ice melt under pressure? Phase-boundary reversible dispersivity and hydrogen-bond extraordinary recoverability Chang Q Sun [email protected] Nanyang Technological University, Singapore Unlike other unusual materials whose bonds contract under compression, the O:H nonbond undergoes contraction and the H-O bond elongation towards O:H and H-O length symmetry in water and ice. The energy drop of the H-O bond dictates the melting point Tm depression of ice. Once the pressure is relieved, the O:H-O bond fully recovers its initial state, resulting in Regelation. Ref: [1] Anomaly 2: Floating ice, http://arxiv.org/abs/1501.04171 [2] Anomaly 1: Mpemba effect, http://arxiv.org/abs/1501.00765 [3] Hydrogen-bond relaxation dynamics: resolving mysteries of water ice. Coord. Chem. Rev., 2015. 285: 109-165. 1 Anomaly: Ice Regelation Observations in Figure 1 revealed the following: 1) Ice melts under pressure and freezes again when the pressure is relieved [1-4]Error! Bookmark not defined.. An ice block remains a solid after a weighted wire cutting it through [5]. 2) Ice melts at a limit temperature of -22C under 210 MPa pressure but a -95 MPa pressure (tension) raises the melting point up to +6.5C [6, 7]. a b 280 270 (K) Quasi-solid Liquid m T 260 V pdvH TP() V C 110 TPCH()00 E 250 -100 -50 0 50 100 150 200 P(MPa) Figure 1 Regelation of ice. (a) A weighted wire cuts a block of ice through without severing it [5]. (b) Theoretical formulation [8] of the pressure dependence of the ice melting temperature Tm(P) or the phase boundary between the liquid and quasi-solid [6, 7] indicates that the H-O bond energy relaxation dictates the Tm(P).