Tsn AupnrcAN MrNpRALocrsr

JOURNAL OF TIIE MINEMI,OGICAL SOCIENY OF'AMERICA

Vol. 57 SEPTEMBER-OCTOBER Nos. 9 aod 10

Anerican Mineralooist Vql. 57, pp. tg25-1332 (1922\

THE OF Peur,D. Ronnrsolt,J. H. FeNc,eNo Y. Onv.r, Sutthern I llinois Uniu ersity Carb on d"ale, Illi,nois

Assrnecr

Kainite, KMg(SO)CI.2 3,/4IJ.,O,is monoclinic C 2/m with a,- 79.72 -r .U2, - -+ b 16.23 .Al, c - 9.53 -f .01 A, p ,- S4.Sy + 5,, and Z - 16. The struc- ture was solved by the symbolic addition procedure utilizing 1698 intensity data, collected with a Buerger automated difiractometer and cuKa radiation. A full- matrix least-squares refinement, with anisotropic temperature factors for cations and chlorine , yielded a final R-index of 0.M2. The structure can be en- visioned as polyhedral layers composed of corner-*haring Mg-octahedra and s-tetrahedra. The negatively charged layers are balanced by positively charged Mg and K ions which, together with chlorine ions and water molecules, occupy the spaces between the layers. The layers are parallel to (r00), thus responsibre for the perfect {100} . The geometry of the octahedra and sulphur tetrahedra is close to ideal. Two of the three independent K ions are in irregular &{old coordination while the third has nine ligands. The mean cation-anion distancesare: S-O - 1.47,Mg-O,Ow - 2.07, K-O - 2.g2, and K-Cr - 3.23A. INrnonucrroN Kainite, KMg(SO+)C1.2 B/4IJ.O, distinguishesitself among other K-Mg sulphates (such as ,, and ) by virtue of its cl contentand its commercialimportance. First noted in the muchstudied salt depositsof stassfurt,Germany, the mineralis also found abundantly in the Zechstein Formation of Europe and the Salado tr'ormation of Texas and New Mexico,,both permian in age, andnoted potash deposits of oeeanicorigin. Two questionsconcerning the minerai, aside from the fact that its structure was unknown, prompted our study. First, the water con- tent of the is listed in Dana's system of Minerarogy (palache et al., l95l) as 3H2O.However, Kiihn and Ritter (lgb8) reporteda water contentof 2 3/4H2o, basedon chemicalanalyses of naturar as well as synthetic kainite. second,the relatively low birefringeneeof t325 L3% ROBINSON, FANG, AND OHYA the mineral is suggestiveof a framework structure; yet a perfect kainite {100} cleavageis observed.Herein we presentthe structureof which providesthe answersto the aforementionedquestions.

ExpnnrlrpNrer,

A large transparent crystal of kainite from Stassfurt, Germany was obtained from the U. S. National Museum, Smithsonian Catalogue No' C-4613' Preces- sion photographs and measurements with a Buerger single-crystal diffra'ctometer -r - yielded the fotlowlng lattice constants: a = 19.72 .02 A, b 16'23 r- '01 A, - c - 9.53 -t- .01 A, P - 94'5Y + .?, space group C 2/m, and Z 16' The transformation matrix from the morphological cell of Grothr to our stmc- ture cell is 002/010/i00. After transformation (ours -> Groth) our axial ratio becomes 1.1?4:1.0:0.607,in good agreement with the ratio reported by Groth of. t.1727:1.0:0.6093.In addition, our cell dimensions are in good agreement with those reported by Evans' who also gave the space group as C 2/m' The calculated specific gravity of 2.176 is in reasonably good agreement with the

Areflectionwas consideredobservedrf I - B > 3*\/I * Bwherel : totalcounts accumulated.during the scan and B : total background. standard reflections were carefully monitoreJ to insure system stability. The data were corrected for Zp and spherical absorption (pr : 1.378).

Srnucrunr DtrnnltrNerrow Alln RnrrNnltpur

Experimental normalized structure-factor statisties,along with the theoretical values for centrosymmetric and noncentrosymmetric crystals calculated by RarIe et ol. (1965), are given in Table 1. They correspondto those for a cen- trosymmetric crystal and accordingly c 2/m was rxed throughout the determina- tion. The crystal structure was solved by the symbolic addition procedure, using the semi-automatic scnrp program of Bednowitz (1970). The distribution of intensities indicated a pseudo-facecentered cell making the determination some- what less than straightforward. Ifowever, by careful, manual manipulation of the data and the acceptanceof lower probability values for the interactions of the weaker reflections, a sufficient number of phases were determined to yield an .E'-map which showed the complete structure. It should be mentioned that the fully automated program of R. E. Long (1965) failed to reveal the structure. Three cycles of full-matrix least-squares refinement employing the nrrNn program of Finger (1969) lowered the isotropic .R-index to 0.066.The coefficients for the analytical form factors for K'*, Mg'*, So, CIt-, and O'- were obtained from Cromer and Mann (1968). The weights were calculated from the variance for eachstructure factor:

1 As quoted in Palacheet al.,1951. STRUCTUNE OF KAINITE BN

o'(F): + a + o.oooe('t' - B)?l =\r,#U' - D/- - where 7 total count, B = average background count, and the additional term involving (T - B) is to allow for errors proportional to the net count, such as variation in the beam and absorption errors (Brandle and steinfink, 1g6g).

TABLE1. EXPERIIYENIALAND THEORETICAL VALUES OF NOR}4ALIZEDSTRUCTURE FACTORS

Non-Cent rosymmetri c

Av. El 0.733 0.798 O.886 nv. t2-l 0.985 0.968 0.736 lEl:3.0 0.3% 0 0t% IEli 2.0 501 l.8z lEll r o 25.2 32.01 37.A%

An experimental value for the extinction parameter, s

F2"u,,: Ft" .",,1(l - s12,,"o,.) was determined by examination of twenty large, low angle reflections obviously suffering from extinction. Refinement of s (initial value - 0.40 X 10+; final value : 0.448 X 10-u)and all other parameterslowered ,B to 0.0bg.In the last cycle, the isotropic temperature factors of the cations and the cl atoms were

listed in Table 4 which has been deposited with the National Auxiliary publica- tions Service.l

DrscussroN oF THE Srnucrunn The structure of kainite is illustrated in the polyhedral drawing of Figure 1. The sheet-like structure of kainite is apparent; the Mg(3) octahedraserve as links betweenthe octahedral-tetrahedral sheets.The alternate arrangementof the positively chargedMg(B) arid K cations and the negatively charged octahedrar-tetrahedral sheets,parallel to (100),accounts for the perfect{100} cleavage. Table 5 lists selectedinteratomic distances and anglesfor kainite. The shapeof the two sulphatetetrahedra approaches the ideal, with 1To obtain a copy of this material, order NAps Doiument Number 0rg5g The present addressis National Auxiliary publications service of the A.s.r.s., c/o CCM Information Corporation, 866 Third Avenue. New york, New york 10022,and price g2.00for microfiche or $b.00for photocopies,payable in advance to OcMIC-NAPS. check a recent issue of the journal for current address and pnce. 1328 ROBINSON,FANG, AND OHYA

Table2. AtomicCoordinates and Isolropic TemperatureFactors for Kainiteo

Atom Equipoint x y z B(A'z)

astandarderrors in Parentheses. bAnisotropictemperature factors converted to equivalentisotropic.

an averageS-O distanceo! 1.471A and a range of only 0.016A' All sulphateoxygens, with the exceptionof 0(S)' are also coordinat"edto Mg, resulting in the small spreadof the S-O distances.The t'hermal motion of the S atomsis practically isotropic (Table 3). The Mg-O,Ow distancesrange from 2.023Llo 2.173A with the Mg-O distancestend- ing to be slightly shortcr,as expected. Two of the three non-equivalentK atoms are surroundedby four oxygensand four chlorineligands whereas the third K is in nine-fold coordination.These coordinationnumbers are low relative to those found in the K-Fe hydrated sulphateswhere the numbersare 10 and l1 (Graeberand Rosenzweig,1971). Also, the K-O distancesare much longer (mean : 3.03A, range : 0.70A) than those of kainite which hasa meanK-O distanceo12.870 A and a rangeof 0.19A. The average K-Cl distancein kainite is 3.225 A, slightly longer than the ionic S'I'RACTUREOF KAINITE t9w

Iable 3. l4agnitudes and 0rientation of prlncioal Axes of Themal Ell'iDsoids in Kainite

m Angle, in degrees, ms Angle, in degrees, Aton. di splacc- with respect to displace- with respect to axls SenE nent A(q) A(o) +b(ol +c(q)

s(r),r .o8s(3) 25(13) r06(r4) i5(il ) .r3s(3) r56(3) s0 6r(3) 2 .096(3) 66(16) 72(52\ r53(48) .'137(6) 90 180 90 .oee(6) 82(23) 24(45',t 68(54) .177(3,t 66(3) e0 2A(1\ s(2), .093(3) ii5(46) . s4(19) 21(471 .i26(3) 167(4) eo 72(4\ .096(3) 153(45) ror(21 ) il0(48) . l4l (6) e0 180 90 .l04(6) 79(21) r59(2r) 90(r6) .ls4(3) 77(4, eo r8(4) rlg(l ), .081(8) 172(6) 90 77(7',) K(3), .r3s(2) 84(rs) 84(8) l3(r7) .r02{16) 90 180 90 ,140(2) 25(s) 66(3) r03(r7) .127(6) 82(7) on r3(7) .re5(3) 65(2) l5s(2) e0(2) Ms(2), .097(7) 153(10) 90 s8(ro) .152(7',) 90 0 90 2 . r r4(r4) 90 180 90 .15e(3) 95(21 eo t70(21 .r26(6) 63(10) 90 32(ro) .2i1(3) 17s(2') 90 80(3) r4s(3),I .il0(5) 173(16) 90 78(15 ) .rs8(3) r74(5) 90 7e(5) .122(41 s7(16) 90 168(r6) 2 .167(6) 90 180 qn .128(8) 90 0 90 3 . 182(3) 84(5) s0 u(s) fis(a), I .oe4(4) 44(14) 83(7) cr(3), r .141(2', r63(3) r07(4) 82(4) 2 .r0s(4) 47(14) 108(7) 2 .163(3) 84(5) 122(3\ r48(3) .134(6) e8(6) r6r(7) 3 .207(31 74(2') 143(3) 5s(3)

Frc. 1. A polyhedral representation of the kainite structure (K and cl atoms omitted). 1330 ROBINSON,FANG, AND OHYA

Tabte 5. Selected Interatomic Distances and Anglisa

Tetrahedral coordination arolnd S

0(2)-o(3) 2.40215)A o(2)-s(r)-o(3) ll0.o(2)" s(r r.464(4)A o(2 ) -0(4) 2.405(6) 0(2)-s(r)-0(4) Ilo.4(2) )-o(2) 109.8(2) s(r)-o(3) 1.46e(3) o(2)-o(7) 2.407(5) o(2)-s(r)-o(7) s(r)-o(4) r.465(4) o(3)-o(4) 2.401(5) o(3)-s(l)-o(4) i'10.3(2) s(l )-o(7) r .478(3) 0(3)-o(7) 2.398(s) o(3)-s(1)-o(7) loe.o(2) o(4)-o(7) 2.372(5J 0(4)-s(r)-0(7) 107.s(2) Mean 1.469i l'4ean 2.3s8i l4ean 109.5'

s(2)-0(1) r.qzc(q)i s(2)-o(5) r.480{4) liii.liiii,ii6ili' iili,iiiiiiii lil,lili s(2)-o(6) r .479(3) s(2)-o(8) l .460(3) ii:i:iiiii,iiiiiili:i:ii;i:ligiiii,iiii l4ean t.+z:i Mean z.qoai\ Mean 109.5'

octahedral coordination around Mg

0(4)-o(4) z.gtae) i lxz'J o(a)-r\ag(t)-o(+)93.2(2\" lxzl Mq(l)-0(a) 2.048(4)A [x4] 0(4)-0(4) 2.813(8) [x2] 0(4)-Ms(l)-0(4)86.8(2) [x2] Mg(1)-0w(2) 2.09112\ lxzl o(4)-ow(2) 2.ee8(s) [x4] 0(4)-ns(l)-0w(2) e2.8(1) [x4] 0w(2)-0(a) 2.854(6) [)(4] 0w(2)-Me(l)-0(4) 87.2(t) [x4] l4ean 2.062A Mean z,gto i Mean 90.0"

0(5)-0(s) 2.7e0(B)A [x2] o(s)-tag(z)-o(s) 86.7(2)"lx27 Me(2)-0(5) 2.032(4)A Ix4] 0(5)-0(5) 2.e56(7) lxzl 0(s)-Ms{2)-0(5) s3.3(2) LxzJ Ms(2)-0w(l) Lr73(5) [x2] 0(5)-0;(i) z.stoie) [x4] o(s)-rlq(2)-0w(t)B7.7(l) [x4] owlr)-0(d)' s.oe:{ol [x+] 0w(t)-t4i(2)-0(5)e2.3(l) [x4] Mean 2.079A I,,lean Z.S+i fi Mean 90.0'

0(7)-0w (6)

las(3)-0w(3)l1s(e)-e(71.2.085(4)?.eee{1)ityt fft3}:3,l1}r !x2l 0.t6i-iltai"ijtti-iliii ;,rlriii'iliiliiii:illfii.trfii Mg(3)-0w(6)2.046(4) ;iil]l [x2] il'l 0w(3)-0(7)i,z,iiiliiii] ili:i.ilil:i.iliitsi,:iriFfl Nlean z.oeq "A flean

0(r)-0(3) z.ze:(s)fl u(r)-is(4)-0{3) 85.8(l). 0(1)-0(6) 3.017(5) 0(l)-l'ts(a)-0(6)e4.7(l) 0(l )-ow(a) 2.839(5) 0(l )-Ms(4)-0w(4)86.6(l ) Ig(a)-0(l) 2.023(4)A 0(l)-0w(5) 3.075(5) 0(1)-lag(a)-0w(5)95.3(2) Ms(a)-0(2) 2.043(4) 0(2)-0(3) 2.s70(51 0(2)-ils(a)-0(3) s2.6l1l Ms(a)-0(3) 2.06714l 0(2)-0(6) 2.838(5) o(2)-r,ls(a)'0(0) 87'0(1) Ias(a)-0(6) 2.079(4\ 0(2)-0w(a) 2.ee8(5) 0(2)-il9(a)-0w(a)s2'2(21 Ms(a)-0w(a)2.il6{4) 0(2)-0w(s)2.848(5) 0(2)-Ms(a)-0w(5)85.9(l ) Ms(a)-0w(5) 0(3)-ow(a) 2.ss0(5) 0(3)-l'ls(4)-0w(4)8s.7(l ) 0(3)-0w(5) 3.044(6) 0(3).tlg(a)-0w(s)s2.8(2) 0(6)-0w(a) 2.ss6(6\ 0(6)-lti{s(a)-0w(a)sl.2(l ) 0(6)-0w(s) 2.882(5) o(o)-Mg(a)-0w(s)86.3(2) l4ean 2,077 A Mean z.gY "a Mean 90.0"

coordination around l(

K(2)

K(3)-o(8) z.s+:(+)i K(3)-o(B) 2.84713) K(2)-o(5) z.ao:(q)i K(3)-o(r) 2.848(4) K(r)-o(4) z.eoe(q)i txzl txzl (3) K(r)-0(7) 2.s4s(4) lxzl K(2)-o(8) 2.848(4)[x2] K(3)-o(3) 2.86r K(r)-cr (3) 3.246(2) ix2l K(2)-cr(3) 3.22e121txzl K(3)-0w(3) 2.e]4(4) K(r)-cr (r ) 3.322(31 K(2)-Cr(r) 3.167(2) K(3)-0w(6) 2.s4r(4) K(1 (2) 3.38s(2) K(2)-Ci(2) 3.llo(3) K(3)-cr(3) )-cr K(3)-o(7) 3.092(3) K(3) -0w(7) 3.2e0(3)

astandard emors in parentheses. STNUCTUREOF RAINITE , 1331

radius sum of 1.33+ 1.81= 3.14A. This is probably due to the fact that the Cl atomsare locatedin rather spaciousvoids. There are three non-equivalentCl atoms in the structure,two of which are in specialpositions. Aside from beingbonded to the K atoms, the Cl atoms have somewater neighborswhich are closeenough to conceivablybe hydrogenbonded to Cl. Theseare: Cl(l)-Ow(Z) = 3.0594,Cl(1)-Ow(6) = 3.715AIx2], Cl(2),Ow(3):3.156A Ix2], C1(3)-Ow(3) : 2.987A, and Cl($)-Ow.(a) : 3.068A. No further study of the H-bondingscheme was attempted.

Srnucrunus or OtHrn K-Mg Sur,pnerns The most abundant chemical compoundsin marine are calcium sulphate hydrates and sodium chloride. However, of grearer interest are the rare deposits of the more soluble salts obtainable from seawater-the chlorides and sulphatesof magnesiumand potas- sium. They are: langbeinite-KrMg,(SOn)r, leonite-KrMg(SOn), .4HrO, picromerite (or schonite)-K,Mg(SO4),.6H,O, and kainite. It is of interest to make structural comparisonsamong these . The octahedral-tetrahedralarrangement in langbeiniteis a B-dimen- sional framework, with all S-tetrahedral and Mg-octahedral corners shared (Zemannand Zemann, 1gb7).The K is coordinatedto seven sulphate oxygens.This 3-dimensionallinkage of ? and O polyhedra is morphologically manifestedby a lack of cleavage(and the presenceof a conchoidalfracture). In leonite (Schneider,lg6l), the linkage is altered becauseof the introduction of four water moleculesin the for- mula. All the water surrounds the octahedral cation as usual and the remaining two corners are made up of sulphate oxygens. The water ligands of Mg make the 3-dimensional ... T-O-T-O ... linkage impossible,and three out of the four independentsulphate oxygensare unsharedwith the Mg-octahedra. The structural formula can thus be written as Kr[Mg(HrO)n](SOn)r.Leonite also showsno cleavageand possesseslow .These characteristicscannot be explained in terms of the ?-O linkage. However, the structure becomesa frame- work type when the K coordination (G oxygen and B water ligands) is consideredto be an integral part of the linkage. The highest hydrate in this seriesis picromerite (Kannan and.Viswamitra, 1965),the struc- tural formula being K,[Mg(HrO).](SOJ,. Here the number of water moleculesis just sufficient to surround the octahedral cation and no sharing betweenthe S-tetrahedra and Mg-octahedra takes place. The structure thus consists of isolated T or O groups. Accordingly, one might expect no cleavageto develop, as in soda alum. However, the K coordination again plays an important role in picromerite. The g- 1332 ROBINSON,FANG, AND OHYA fold coordinate K polyhedra form infinite sheetsparallel to (201) and, as a result, the mineral exhibits a perfect {201} cleavage.Thus one sees a contrasting role played by K polyhedra in leonite and picromerite. In the former the K polyhedra give rise to a framework structure, whereasin the latter mineral, the K polyhedraimpart a sheetstructure. In kainite, there also exist K polyhedra. However, the role played by these polyhedra is reduced to secondaryimportance, for the cleavage in this mineral is the consequencesolely of the octahedral-tetrahedral topology in the structure. 1t is apparent that the spatial arrangementof coordinationpoly- hedra, other than those of tetrahedra and octahedra,can be an im- portant controlling factor of the cleavagesin sulphateminerals. AcrcNowrclcrvrnNrs We thank Mr. Paul Desautels. of the U.S. National Museum, for supplying us with the excellent kainite crystal. The authors acknowledge the advice given by Prof. Eugo Steinfink in abridging the section on Structure Determination' The polyhedral drawing is the work of Mr. Alex Ray. This work was zupported in part by the National ScienceFoundation (Grant GA 19688). RnrnnoNcns BnoNowrrz, A. L. (1970) sonrr-A program to aid in the implementation of the symbolic addition method for the direct determination of centrosymmetric crystal structures. fta F. R. Ahmed, (ed.), Crgstallographin Compwti'ng, Munksgaard, Copenhagen,Denmark, p. 58-62. BRAwor,n,C. D., aN'n I[. SrnrNrrNr (1969) The crystal structure of Eu+Al,Ou' Inorg. C hem. 8, 1320-1324. Cnoltnn, DoN T., rNn Josnpu B. MINN (1968) X-ray scatiering factors com- puted from numerical llartree-Fock wave functions. Acta Crgsballogr' A2+, 321-323. FrNcnn, L. W. (1969) The crystal structure and cation distribution of a grunerite. Mineral. Sbc.Amer. Spec.Pap.2, 95-100. Gneornn, E. J., elll A. Rosuxzwuc (1971) The crystal stmctures of yavapaiite, K'Fe(SOn),, and gotdichite, KFe(SOn),'4H"O. Amer. Mi'neral- 56' 1917-1933. I(lNreN, K. K., eNn M. A. Vrswalnrne (1965) Crystal structure of magnesium sulfate hexahydrate. Z. Kristallogr. 722,16l-174. Kenlr, I. L., K. S. DnecoNnrrr, exl S. A. Bnur.rxnn (1965) The crysial structure of the serotonin-creatininesulpha,te complex. Acta Crgstallogr.19,7t3-716. LoNc, R. E. (1965) A Program lor Phase Determin'ation bg Reiter'atiue Applica- ti,on of Sayre's Equntion. Ph.D. thesis, University of California, at Los Angeles. Per,acnp.C., II. BsnueN. eNn C. FnoNnol (1951) The Sgstem of Minetaloga . . . ol Dana, Tth ed., VoI. 2. John Wiley and Sons, fnc., New York. Scrnrrronn, Vow W. (1961) Neubestimmung der Kristallstruktur des Mangan- Leonits, K,Mn(SO')r'4H"O. Acta Crgstallogr. 74, 7U=79I. ZnrrlNN, Vow Awr.re, aNo J. Znuallx (1957) Die Kristallstruktur von Langbeinit, IGMgi, (SO,)". Acba Crg stallogr. 70, 409-413.

Manuscript receiued, March 16, 19/2; accepted for yubhcation, May 8, Im2.