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VINDHYA BHARTI (Multi-Disciplinary Peer Reviewed Research Journal) Foa/; Hkkjrh ¼'Kks/K If=Dk½ Vol. II No. 18, December 2019 ISSN 0976-9986 VINDHYA BHARTI (Multi-Disciplinary Peer Reviewed Research Journal) foa/; Hkkjrh ¼'kks/k if=dk½ Awadhesh Pratap Singh University Rewa (M.P.) Vol. II No. 18, December 2019 ISSN 0976-9986 PATRON : Prof. Peeush Ranjan Agrawal Vice-Chancellor A.P.S. University, Rewa (M.P.) CHEIF EDITOR : Prof. R.N. Singh EDITOR : Prof. Sunil Kumar Tiwari Prof. A.P.Mishra Prof. Dinesh K. Kushwah Prof. M.C. Srivastava Prof. Navita Srivsastava PUBLISHED BY : Registrar A.P.S. University Rewa (M.P.) ISSN 0976-9986 e-mail: [email protected] Printed by Anil Printing Press, Rewa (M.P.) Vol. II No. 18, December 2019 ISSN 0976-9986 Content Page No. 1. Modeling of Anticonvulsant Activity of Some Oxadiazole Neha Tiwari, Vinay Dubey 01 and Thiadiazole Derivatives Using Topological and and Vijay K. Agrawal Physicochemical Descriptors 2. Dust Deposition on the Leaves of Some Three and Rupam Yadav, Arpana Mishra, 09 Shrub Species Growing Around J.P.Cement Plant Laxmi Rawat & Pramila Singh of Naubasta, Rewa (M.P.) 3. Cognitive Radio Networks Implementation for Rahul Gupta & P. C. Gupta 13 Spectrum Utilization in Hadoti (Rajasthan) Region 4. Improve Performance of HadoopwithMapreduce Chandra Shekhar Gautam 19 Frame Work Using Data Compacting Technique & Sajal Kumar Kar 5. Farmers' Perception and Adoption Pattern in M.K.Mishra, N.Shrivastava 25 Relation to Information and Communication & Sanjay Singh Technology in Rewa District of M.P. 6. 'khr_rq ,oa rÙktU; O;kf/k;k¡ o jksdFkke nsodju ekdokus] /khjsUnz flag] 29 ,l-,u-frokjh ,oa izHkatu vkpk;Z 7. Preventive aspect of Bronchial Asthma Shivani Patkar, O.P.Shukla, 32 (Tamaka Shwasa) Pawan Kumar Kirar & S.N.Tiwari 8. Contract Labour Management Sushma Tiwari & 34 Sunil Kumar Tiwari 9. Assessment of Work Life Balance and Satisfaction in Pragya Singh & Anjali Srivastava 36 Employees of Public and Private Organizations 10. i;kZoj.k % ,d lekt'kkL=h; v/;;u vkjk/kuk feJk 42 11. 'krir czkã.k esa thouksÙkj /kkj.kkvksa dk ,sfrgkfld v/;;u eatw ;kno 47 12. bfrgkl ys[ku dh ijEijk % foU/; {ks= ds fo'ks"k lUnHkZ esa 'kkfyd jke feJ 49 13. Sources of financing of capital investments on the example Nadiia Stolarchuka 55 of Ukraine 14. fo/kok ,oa ifrR;Dr efgykvksa dk la?k"kZ fdju flag ,oa bUnzdey dq'kokgk 58 15. Srimad Bhagwad Gita : My Perspective Shubha Tiwari 61 16. An Ecocritical Study of William Dalrymple's : Minakshi Rajpur & 71 The Age of Kali Mrinal Srivastava 17. rkjlIrd dh i`"BHkwfe fnus'k dq'kokg 76 18. fdlku thou ij vk/kkfjr fgUnh miU;kl tequk izlkn f}osnh 80 ,oa fnus'k dq'kokg 19. tutkfr;ksa dk bfrgkl ,oa yksd u`R; pUnz izd'k iVsy 86 20 ;ksx% deZlq dkS'kye~ JhdkUr feJ 89 21. ekuo ewY; % ,d nk'kZfud foe'kZ nsonkl lkdsr 93 22. A Study of Impact of Type of Appeals in Public Anshula Kushwaha & 96 Service Advertising Vivek Sharma 23. A Study of Crop Diversification and its Determinants Utkal Kushawah & 101 - A Review Paper Ganesh Kawadia Vol. II No. 18, December 2019 Vindhya Bharti ISSN 0976-9986 MODELING OF ANTICONVULSANT ACTIVITY OF SOME OXADIAZOLE AND THIADIAZOLE DERIVATIVES USING TOPOLOGICAL AND PHYSICOCHEMICAL DESCRIPTORS Neha Tiwari, Vinay Dubey and Vijay K. Agrawal* Abstract. In this paper we have modelled the 25 mg/kg of test compounds; phenytoin sodium (25 anticonvulsant activities of some of the oxadiazole and mg/kg) was used as a standard. The abolition of the thiadiazole derivatives using topological and hind limb tonic extensor spasm was recorded as a physicochemical descriptors. It has been found that the measure of anticonvulsant activity (12). The activities Density, Parachor and Balaban index play dominant have been measured in terms of MES (%protection. role in modeling the activity. For modeling the activity we have converted these values to log values. Keywords: anticonvulsant activities, QSAR, The photochemical and topological indices are Topological parameters, Balaban Index, Density, very useful in modeling the biological activities of Parachor, Cross validation. organic drug molecules2-10. In fact Agrawal and Introduction: coworkers11-20 have successfully used these indices Shahar Yar and coworker1 have synthesized A in modeling biological activities of different set of series of five membered heterocyclic compounds by compounds. They include, CA inhibitors, Anti HIV the reaction between isoniazid and various substituted agents, anti inflammatory agents, Antimicrobial agents, isothiocyanates and were tested for their anticonvulsant Analgesics etc. activity by determining their ability to provide The aim of this study was to model the protection against convulsions induced by electro- anticonvulsant activities of compounds synthesized by convulsometer the synthesized compounds, (IIf) 2-(4- Mohammad Shahar Yar and coworker1 using chlorophenyl) amino-5-(4-pyridyl)-1,3,4-thiadiazole physicochemical and topological descriptors which has and (IIIf) 2-(4-chlorophenyl)amino-5-(4- pyridyl)-1, 3, been successfully done. 4-oxadiazole were found promising compounds of the Presentation of the Data: series. The structure of all the compounds synthesized Similarly, they synthesized a series of 2- by Mohammad and co-worker has been drawn using (substituted phenyl)amino-5-(4- pyridyl)-4H-1,3,4- latest version of Chem Skech software21 available by thiadiazole (IIa-f) and 2-(substituted phenyl)amino-5- ACD Lab. The physic-chemical parameters10 have (4-pyridyl)-4H-1,3,4-oxadiazole (IIIa-f) from isoniazid been calculated using this software. The mol files have and substituted phenyl isothiocyanates derived been prepared which were used for calculation of thiosemicarbazides. The structures of newly topological indices21. We have used Dragon software22 synthesized compounds were confirmed by spectral and for calculation of a set of topological parameters23. But analytical data Anti-convulsant activity only two of them have been used in modelling the The synthesized compounds were found to be activities as the variable selection method24 found them potent anticonvulsant agents. The Anticonvulsant to be useful. activity of the synthesized compounds was determined The compounds used in the present study and by their ability to provide protection from convulsions their anticonvulsant activity (log MES) have been in albino mice. They gave supra maximal electroshock presented in Table 1. The table 1 also include two of current intensity of 50 mA, 60 Hz for 0.2 s duration indicator parameters Ip1 and Ip2. Ip1 has been given a to the various groups of mice after administration of * QSAR and Computer Chemical Laboratories, A.P.S.University, Rewa, India 486003 E-mail:[email protected] (01) Vol. II No. 18, December 2019 ISSN 0976-9986 value of 1 if substituent R is a -chloro group otherwise The statistically significant correlations obtained it has been assigned zero value. Similarly, for any are reported below. substitution at R, Ip2 has been assigned a value of 1 One parametric models otherwise 0. Three one-parametric correlations have been The topological parameter J, and the physic- obtained with PC, D, and J index respectively. They chemical parameters: Density and Parachor have been are as below: reported in table 2. A correlation matrix showing logMES=-0.0026(±0.0019)PC+ correlation among the biological activity and physical 3.2635…………………………………………………..(1) chemical and topological parameters has been reported in Table 3. the quality of statistical parameters for N=12, MSE=0.0246, R2=0.1607, Adj R2= 0.0767 , different models obtained after regression analysis have F-ratio=1.914, Q=16.2967 logMES =2.0174 been reported in Table 4. The Table 5 contains the (±0.8175)D-0.8754 ……………………..............(2) cross-validated parameters for various statistically N=12, MSE=0.0182, R2=0.3785, Adj R2= 0.3163, significant models. We have computed the observed F-ratio=6.090 , Q=33.8022 and estimated log values using the best model in Table logMES = -3.9311(±1.3523)J+7.3898…..........…(3) 6.A graph between observed and estimated logMES N=12, MSE=0.0159, R2=0.458, Adj R2= 0.4038, F- values has been plotted the check the quality of the ratio=8.451 , Q=42.566 best model and the same is represented in Fig. 1. In fact the best one-parametric correlation is with The Ridge analysis 25 results are presented in Balaban index ( J) which has 0.4038 R2 value. Table 7 Here it is worth mentioning that Q is the Results and Discussion :- Pogliani's constant 29,30 which is ratio of R/MSE. This A perusal of Table 1 clearly shows that the is a parameter to check the quality of correlation. functional groups attached to two different structures Two parametric model sometimes give same activity but in few cases they show When Ip1 is added to one-parametric model with deviations. The 12 compounds in the present study may J as correlating parameter then a two-parametric model be arranged in order of decreasing activity as below: is obtained with R2=0.6624. The adjusted R2 also 12>1=7>5=9=11>2=3=10>4=8 shows a significant improvement and it has been found It is worth mentioning that two structures differ to be 0.5874. The value changes from 0.4038 to 0.5874 only due to presence of O or S in the five membered clearly indicates that the addition of Ip1 is justified. ring at the same position. But presence of -OCH3 The Q value is also increased from 42.566 to 73.99. shows different activity in two structures. Hence, no This correlation is as under: one is to one correlation can be established with logMES =-3.2556(±1.1616)J+0.1959(±0.0839)Ip1 structure and activities. Therefore, the data was +6.3945...............................................................(4) subjected to regression analysis using NCSS N=12, MSE=0.011, R2=0.6624, Adj R2= 0.5874, F- software26.
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