Winter 1998 Gems & Gemology
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Age and Origin of Silicocarbonate Pegmatites of the Adirondack Region
minerals Article Age and Origin of Silicocarbonate Pegmatites of the Adirondack Region Jeffrey Chiarenzelli 1,*, Marian Lupulescu 2, George Robinson 1, David Bailey 3 and Jared Singer 4 1 Department of Geology, St. Lawrence University, Canton, NY 13617, USA 2 New York State Museum, Research and Collections, Albany, NY 12230, USA 3 Geosciences Department, Hamilton College, Clinton, NY 13323, USA 4 Earth and Environmental Sciences, Rensselaer Polytechnic Institute, Rensselaer, NY 12180, USA * Correspondence: [email protected]; Tel.: +1-315-229-5202 Received: 24 July 2019; Accepted: 19 August 2019; Published: 23 August 2019 Abstract: Silicocarbonate pegmatites from the southern Grenville Province have provided exceptionally large crystal specimens for more than a century. Their mineral parageneses include euhedral calc–silicate minerals such as amphibole, clinopyroxene, and scapolite within a calcite matrix. Crystals can reach a meter or more in long dimension. Minor and locally abundant phases reflect local bedrock compositions and include albite, apatite, perthitic microcline, phlogopite, zircon, tourmaline, titanite, danburite, uraninite, sulfides, and many other minerals. Across the Adirondack Region, individual exposures are of limited aerial extent (<10,000 m2), crosscut metasedimentary rocks, especially calc–silicate gneisses and marbles, are undeformed and are spatially and temporally associated with granitic pegmatites. Zircon U–Pb results include both Shawinigan (circa 1165 Ma) and Ottawan (circa 1050 Ma) intrusion ages, separated by the Carthage-Colton shear zone. Those of Shawinigan age (Lowlands) correspond with the timing of voluminous A-type granitic magmatism, whereas Ottawan ages (Highlands) are temporally related to orogenic collapse, voluminous leucogranite and granitic pegmatite intrusion, iron and garnet ore development, and pervasive localized hydrothermal alteration. -
The Wittelsbach-Graff and Hope Diamonds: Not Cut from the Same Rough
THE WITTELSBACH-GRAFF AND HOPE DIAMONDS: NOT CUT FROM THE SAME ROUGH Eloïse Gaillou, Wuyi Wang, Jeffrey E. Post, John M. King, James E. Butler, Alan T. Collins, and Thomas M. Moses Two historic blue diamonds, the Hope and the Wittelsbach-Graff, appeared together for the first time at the Smithsonian Institution in 2010. Both diamonds were apparently purchased in India in the 17th century and later belonged to European royalty. In addition to the parallels in their histo- ries, their comparable color and bright, long-lasting orange-red phosphorescence have led to speculation that these two diamonds might have come from the same piece of rough. Although the diamonds are similar spectroscopically, their dislocation patterns observed with the DiamondView differ in scale and texture, and they do not show the same internal strain features. The results indicate that the two diamonds did not originate from the same crystal, though they likely experienced similar geologic histories. he earliest records of the famous Hope and Adornment (Toison d’Or de la Parure de Couleur) in Wittelsbach-Graff diamonds (figure 1) show 1749, but was stolen in 1792 during the French T them in the possession of prominent Revolution. Twenty years later, a 45.52 ct blue dia- European royal families in the mid-17th century. mond appeared for sale in London and eventually They were undoubtedly mined in India, the world’s became part of the collection of Henry Philip Hope. only commercial source of diamonds at that time. Recent computer modeling studies have established The original ancestor of the Hope diamond was that the Hope diamond was cut from the French an approximately 115 ct stone (the Tavernier Blue) Blue, presumably to disguise its identity after the that Jean-Baptiste Tavernier sold to Louis XIV of theft (Attaway, 2005; Farges et al., 2009; Sucher et France in 1668. -
The Anjahamiary Pegmatite, Fort Dauphin Area, Madagascar
The Anjahamiary pegmatite, Fort Dauphin area, Madagascar Federico Pezzotta* & Marc Jobin** * Museo Civico di Storia Naturale, Corso Venezia 55, I-20121 Milano, Italy. ** SOMEMA, BP 6018, Antananarivo 101, Madagascar. E-mail:<[email protected]> 21 February, 2003 INTRODUCTION Madagascar is among the most important areas in the world for the production, mainly in the past, of tourmaline (elbaite and liddicoatite) gemstones and mineral specimens. A large literature database documents the presence of a number of pegmatites rich in elbaite and liddicoatite. The pegmatites are mainly concentrated in central Madagascar, in a region including, from north to south, the areas of Tsiroanomandidy, Itasy, Antsirabe-Betafo, Ambositra, Ambatofinandrahana, Mandosonoro, Ikalamavony, Fenoarivo and Fianarantsoa (e.g. Pezzotta, 2001). In general, outside this large area, elbaite-liddicoatite-bearing pegmatites are rare and only minor discoveries have been made in the past. Nevertheless, some recent work made by the Malagasy company SOMEMEA, discovered a great potential for elbaite-liddicoatite gemstones and mineral specimens in a large, unusual pegmatite (the Anjahamiary pegmatite), hosted in high- metamorphic terrains. The Anjahamiary pegmatite lies in the Fort Dauphin (Tôlanaro) area, close to the southern coast of Madagascar. This paper reports a general description of this locality, and some preliminary results of the analytical studies of the accessory minerals collected at the mine. Among the most important analytical results is the presence of gemmy blue liddicoatite crystals with a very high Ca content, indicating the presence in this tourmaline crystal of composition near the liddicoatite end-member. LOCATION AND ACCESS The Anjahamiary pegmatite is located about 70 km NW of the town of Fort Dauphin (Tôlanaro) (Fig. -
Preliminary Investigation of Purple Garnet from a New Deposit in Mozambique
GIT GEMSTONE UPDATE Preliminary Investigation of Purple Garnet from a New Deposit in Mozambique By GIT-Gem testing laboratory 11 May 2016 Introduction In March 2016, a group of Thai gem dealer led by Mr. Pichit Nilprapaporn paid a visit to the GIT and informed us about a new garnet deposit in Mozambique, that was discovered near the western border with Zimbabwe. They also displayed a large parcel of rough and a few cut stones claimed to be the material found in this new deposit (Figure 1). According to the stone’s owner, these garnet specimens were unearthed from an unconsolidated sediment layer, just a few meters below ground surface. This brief report is our preliminary investigation on the interesting vivid purple garnet from the new deposit in Mozambique. Figure 1: Mr. Pichit Nilprapaporn (center), the stone’s owner, showing a large parcel of purple gar- net roughs claimed to be from a new deposit in Mozambique to the GIT director (left). The Gem and Jewelry Institute of Thailand (Public Organization) 140, 140/1-3, 140/5 ITF-Tower Building. 1st - 4th and 6th Floor,Silom Road, Suriyawong, Bangrak, Bangkok 10500 Thailand Tel: +66 2634 4999 Fax: +66 2634 4970; Web: http://www.git.or.th; E-mail: [email protected] 11 May, 2016 Preliminary Investigation of Purple Garnet from a New Deposit in Mozambique 2 Samples and Testing Procedure The stone’s owners donated some specimens (one 6.10 ct oval-facetted stone and 13 rough samples weighing from 3.83 to 9.43 cts) to the GIT Gem Testing Laboratory for studying. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Some Uncommon Sapphire “Imitations”: Blue Co-Zirconia, Kyanite & Blue Dumortierite Dr Michael S
Some Uncommon Sapphire “Imitations”: Blue Co-zirconia, Kyanite & Blue Dumortierite Dr Michael S. Krzemnicki Swiss Gemmological Institute SSEF [email protected] 筆者滙報數個瑞士珠寶研究院(SSEF)近期收到 in the ring showed a negative RI reading 要求鑑證的藍色寶石,經檢測後確定其中包括 (above 1.79), an isotropic optical character 一些非常罕見的藍寶石模擬石:含錮氧化鋯、 (polariscope) and thus no pleochroism at all. 藍晶石及藍線石等。 Under the microscope, we saw no inclusions, however a slightly greenish reaction under Sapphires are among the most abundant gems the LWSW and there was a weaker similar we receive at the Swiss Gemmological Institute reaction under SWUV lamps. Based on these (SSEF) for testing. From time to time, however, properties and a chemical analysis by X-ray we are quite surprised by the imitations which fluorescence (EDXRF), the blue stone was we find among the goods sent in and this can readily identified as cubic zirconia (ZrO2). then be disappointing news for the clients. In Having seen this artificial product in a wide the following short note, the author presents a range of colours, the author had not previously few uncommon imitations identified recently at seen one of such a saturated and attractive the SSEF. Identification of these imitations is blue. Based on literature (Nassau 1981) the straightforward and should be no problem for analysed traces of cobalt in that stone have any experienced gemmologist. been identified as the colouring element in this specimen. The absorption spectrum of the stone The first case is that of an attractive blue (Fig. 2) – although superposed by several rare faceted stone of approximately 1.4 ct, set in a ring with diamonds (Fig. -
HK Fancy Sapphire
Hong Kong, March 2011 Fancy Coloured Sapphires: The Beauty beyond "Blue" of Sapphire and "Red" of Ruby Dr. Michael S. Krzemnicki Swiss Gemmological Institute SSEF Switzerland All photos © M.S. Krzemnicki, SSEF except where indicated. The range of colours... © Swiss Gemmological Institute SSEF 1 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 2 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 3 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 4 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 5 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 6 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 7 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... © Swiss Gemmological Institute SSEF 8 The range of colours... © Swiss Gemmological Institute SSEF The range of colours... Fancy sapphires: The colour range beyond red of rubies and blue of sapphires © Swiss Gemmological Institute SSEF 9 The range of colours... Photo: © SilkenEast Ltd, Bangkok © Swiss Gemmological Institute SSEF The range of colours... Collection: SilkenEast Ltd, Bangkok © Swiss Gemmological Institute SSEF 10 Jewellery with fancy sapphires Photos © Luc Phan, SSEF © Swiss Gemmological Institute SSEF © Swiss Gemmological PhotoInstitute © Luc SSEF Phan, SSEF 11 Corundum Chemical composition: aluminium oxide, Al2O3 Chemical pure aluminium oxide is colourless © Wikipedia In nature always with trace elements (chemical impurities), usually: - Mg, Ti, V, Cr, Fe, Ga - and occasionally rare HFS-elements such as Nb, Sn, Ta, Th Not all trace elements are affecting the colour (e.g. -
Abstract Spectroscopic Characterization of Fluorite
ABSTRACT SPECTROSCOPIC CHARACTERIZATION OF FLUORITE: RELATIONSHIPS BETWEEN TRACE ELEMENT ZONING, DEFECTS AND COLOR By Carrie Wright This thesis consists of two separate papers on color in fluorite. In the first paper, synthetic fluorites doped with various REEs (10-300 ppm) were analyzed using direct current plasma spectrometry, optical absorption spectroscopy, fluorescence spectrophotometry, and electron paramagnetic resonance spectroscopy before and after receiving 10-25 Mrad of 60Co gamma irradiation. The combined results of these techniques indicate that the irradiation-induced color of the Y-, Gd-, La- and Ce-doped samples are the result of a REE-associated fluorine vacancy that traps two electrons. Divalent samarium may be the cause of the irradiation-induced green color of the Sm- doped sample. In the second paper, fluorite crystals from Bingham, NM, Long Lake, NY, and Westmoreland, NH were similarly investigated to determine the relationship between sectorally zoned trace elements, defects, and color. The results indicate causes of color similar to those in the synthetic samples with the addition of simple F-centers. SPECTROSCOPIC CHARACTERIZATION OF FLUORITE: RELATIONSHIPS BETWEEN TRACE ELEMENT ZONING, DEFECTS AND COLOR A Thesis Submitted to the Faculty of Miami University In partial fulfillment of The requirements for the degree of Master of Science Department of Geology By Carrie Wright Miami University Oxford, OH 2002 Advisor_____________________ Dr. John Rakovan Reader______________________ Dr. Hailiang Dong TABLE OF CONTENTS Chapter 1: Introduction to the cause of color in fluorite 1 Manuscript 1-Chapter 2 29 “Spectroscopic investigation of lanthanide doped CaF2 crystals: implications for the cause of color” Manuscript 2-Chapter 3 95 “Spectroscopic characterization of fluorite from Bingham, NM, Long Lake, NY and Westmoreland, NH: relationships between trace element zoning, defects and color ii TABLE OF FIGURES Chapter 1 Figures 21 Figure 1a. -
Origin of Color in Cuprian Elbaite from Sflo Jos6 De Batalha, Paraiba, Brazil
American Mineralogist, Volume 76, pages 1479-1484, I99I Origin of color in cuprian elbaite from Sflo Jos6 de Batalha, Paraiba, Brazil Gnoncn R. Rosslvr,tN Division of Geology and Planetary Sciences,l7O-25, California Institute of Technology, Pasadena,California 9l125, U.S.A Evrvrm.luel FnrrscH, J,lvrns E. Srncr.Bv GIA Research,Gemological Institute of America, 1660 Stewart Street,Santa Monica, California 90404-4088, U.S.A. Ansrn-q.cr Gem-quality elbaite from Paraiba, Brazil, containing up to 1.4 wt0i6Cu has been char- acterizedusing optical spectroscopyand crystal chemistry. The optical absorption spectra of Cu2t in these tourmalines consist of two bands with maxima in the 695- to 940-nm region that are more intense in the E I c direction. The vivid yellowish green to blue- greencolors of theseelbaite samplesarise primarily from Cu2*and are modified to violet- blue and violet hues by increasingabsorptions from Mn3*. IwrnooucrtoN in a small, decomposed granitic pegmatite (formerly quartz, The color of elbaite has hen extensively investigated. prospectedfor manganotantalite).The associated Most colors are determined by small amounts of transi- altered feldspar, and lepidolite have not been character- tion elements(Dietrich, 1985).In particular, blue to green ized. Most of the tourmalines occur as crystal fragments colors have been attributed to various processesinvolv- weighing less than a g.ram,although pieceslarge enough ing both Fe2*and Fe3*ions (Mattson and Rossman, 1987) to produce facetedgemstones up to 33 carats(6.6 g) have and Fe2*- Tia* chargetransfer (Mattson, as cited in Die- been found. In rare instances, small crystals are recov- trich, 1985, p. -
Personal Body Ornamentation on the Southern Iberian Meseta: an Archaeomineralogical Study
Journal of Archaeological Science: Reports 5 (2016) 156–167 Contents lists available at ScienceDirect Journal of Archaeological Science: Reports journal homepage: www.elsevier.com/locate/jasrep Personal body ornamentation on the Southern Iberian Meseta: An archaeomineralogical study Carlos P. Odriozola a,⁎, Luis Benítez de Lugo Enrich b,c, Rodrigo Villalobos García c, José M. Martínez-Blanes d, Miguel A. Avilés e, Norberto Palomares Zumajo f, María Benito Sánchez g, Carlos Barrio Aldea h, Domingo C. Salazar-García i,j a Dpto. de Prehistoria y Arqueología, Universidad de Sevilla, Spain b Dpto. de Prehistoria y Arqueología, Universidad Autónoma de Madrid, Spain c Dpto. de Prehistoria y Arqueología, Centro asociado UNED-Ciudad Real, Universidad Nacional de Educación a Distancia, Spain d Dpto. de Prehistoria, Arqueología, Antropología Social y Ciencias y Técnicas Historiográficas, Universidad de Valladolid, Spain e Instituto de Ciencia de Materiales de Sevilla, Centro mixto Universidad de Sevilla—CSIC, Spain f Anthropos, s.l., Spain g Laboratorio de Antropología Forense, Universidad Complutense de Madrid, Spain h Archaeologist i Department of Archaeology, University of Capetown, South Africa j Departament de Prehistòria i Arqueologia, Universitat de València, Spain article info abstract Article history: Beads and pendants from the Castillejo del Bonete (Terrinches, Ciudad Real) and Cerro Ortega (Villanueva de la Received 22 June 2015 Fuente, Ciudad Real) burials were analysed using XRD, micro-Raman and XRF in order to contribute to the cur- Received in revised form 30 October 2015 rent distribution map of green bead body ornament pieces on the Iberian Peninsula which, so far, remain Accepted 14 November 2015 undetailed for many regions. -
Blue Sapphire Engagement Ring, RG-2817U Dramatic Color And
Blue Sapphire Engagement Ring, RG-2817u Dramatic color and unusual elegance come together in this vintage style blue sapphire engagement ring. The 18k white gold band of this engagement ring is set along the shoulders and shank with a collection of seventy-four round brilliant cut diamonds that total 0.52 carats. Eight of these diamonds, four on each side, are arranged in a floral design. The diamond flowers flank a bewitching blue sapphire at the center. This is a vintage style (new) blue sapphire engagement ring. Options None Item # rg2817u Metal 18k white gold Weight in grams 4.6 Special characteristics A matching band is available and may be purchased separately. Please see item RG-2817wb. Condition New Diamond cut or shape round brilliant Diamond carat weight 0.52 Diamond mm measurements 1.4-0.9 Diamond color G-H Diamond clarity VS1 Diamond # of stones 74 Gemstone name Natural Corundum (sapphire) Gemstone cut or shape round faceted mixed cut Gemstone carat weight 1.05 Gemstone type Type II Gemstone clarity VS Gemstone hue very very slightly greenish blue Gemstone tone 4-Medium Light Gemstone saturation 4-Moderately Strong Gemstone # of stones 1 Top of ring length (N-S) 6.75 mm [0.26 in] Width of shank at shoulders 4.85 mm [0.19 in] Width of shank at base 2.25 mm [0.09 in] Ring height above finger 6.9 mm [0.27 in] Other ring info For new rings like this one, the gram weight, diamond and gemstone carat weights, color, and clarity, as well as other jewelry details, may vary from the specifications shown on this page, but are similar in quality. -
Mineral of the Month Club May 2017
Mineral of the Month Club May 2017 BERYL var. GOSHENITE This month’s featured mineral is goshenite, the colorless variety of beryl, or beryllium aluminum silicate, from the pegmatites of Namibia. Our write-up explains the mineralogy, history, and lore of goshenite, and discusses the many colored-gem varieties of beryl. OVERVIEW PHYSICAL PROPERTIES: Chemistry: Be3Al2Si6O18 Beryllium Aluminum Silicate Class: Silicates Subclass: Cyclosilicates (Ring Silicates) Group: Beryl Crystal System: Hexagonal Crystal Habits: Usually as hexagonal (six-sided) prisms, often with flat or modified-flat terminations; also massive and compact. Color: Beryl can be colorless or white to blue, green, yellow, pink, and red; goshenite crystals are colorless; massive forms are white. Luster: Vitreous Transparency: Goshenite crystals are usually transparent to translucent; massive forms are translucent to opaque. Streak: Colorless to white Cleavage: Poor in one direction Fracture and Tenacity: Uneven to conchoidal; brittle. Hardness: 7.5-8.0 Specific Gravity: 2.66-2.92 Luminescence: None Refractive Index: 1.577-1.583 Distinctive Features and Tests: Best field marks for goshenite are hardness; six-sided prisms with flat or modified-flat terminations; lack of color; and occurrence primarily in granite pegmatites. Dana Classification Number: 61.1.1.1 NAME: The word “goshenite,” pronounced GAH-shun-ite, is derived from the town of Goshen, Massachusetts, where this mineral variety was first named. Goshenite is also known as “clear beryl,” “white beryl,” and “white aquamarine.” In European mineralogical literature, goshenite appears as goshenit and goshenita. The word “beryl” stems from bēryllion, the Indo-Aryan word for the mineral. Beryl appears in European mineralogical literature as berilo, berylita, and Berylit.