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Estimation of Available Oxygen in Powder Form of Oxygen Releaser in Henna Based Hair Dyes

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Estimation of Available Oxygen in Powder Form of Oxygen Releaser in Henna Based Hair Dyes SSRG International Journal of Applied Chemistry (SSRG-IJAC) – volume 4 Issue 2 May to Aug 2017 Estimation of Available Oxygen in Powder Form of Oxygen Releaser in Henna Based Hair Dyes Jayaganesh Sankar*, Bachan Singh Rawat, Jainendra Malankar, Venkataramana Arbettu Padmanabha Dabur Research and Development, International Business Development, Dubai, P.O.Box. 6399; United Arab Emirates Abstract Cream based hair colour offers the hydrogen peroxide as an oxidizing agent, it promote the emollient, anti oxidant and alkali (ammonia). oxidation of hair dyes and helps to deliver the desired Another component called as a developer, the name colours. Henna based powder of hair dyes containing itself indicates that function, it helps to develop the the inorganic peroxides. Inorganic peroxides namely reaction; cream and developer mixed together for the barium peroxide, calcium peroxide, magnesium colour development. During mixing time, the oxygen peroxide, sodium perborate mono hydrate, sodium released from the hydrogen peroxide and promotes the perborate penta hydrate etc., used as an oxidizing dye material oxidation and initiates the coloring agent; whenever the inorganic peroxides reacts with reaction step. Henna based hair colour containing the water it releases the oxygen. Inorganic peroxide powder form of oxygen releaser like potassium reaction mechanisms are similar to hydrogen peroxide. perborate, sodium perborate and ammonium perborate, Articles deals about the estimation of available oxygen other perborate, potassium percarbonate, sodium in barium peroxide, sodium perborate and calcium percarbonate and other percarbonate, potassium peroxide in powder hair dyes. Theoretical value and persulfate, sodium persulfate and other persulfates, estimated values are match together and having higher potassium percarbamide, sodium per cabamide and regression coefficient values. Calcium peroxide other percarbamide; barium peroxide, calcium dioxide releases more amount oxygen when compared to the and others salts of oxides etc. Estimation of releasable sodium perborate and barium peroxide. Around 10% oxygen is essential for the colour delivery process. of calcium peroxide incorporation henna based hair The iodimetric titration easily determines the available dye formula it releases the 1.6 % of available oxygen; oxygen content in hydrogen peroxide. Hydrogen however, around 20% of barium peroxide incorporated peroxide titrated against the KMnO4 and the end point in the formula releases 1.5% of available oxygen. is appearance of pink colour. However in henna based This study is a viable tool for the formulator for hair colour is complicated one, herbal material obstruct adjusting the available oxygen content. This article the end point of regular iodimetric titration. Herbal confirms that among the powder form of oxidizing materials obstruct/hinder the end point appearance. agent, calcium peroxide releases higher amount of This article aim to develop the new methods of oxygen and also having the high purity. Therefore the available oxygen estimation in henna based powder incorporation of calcium peroxide in henna based colours. Articles deals with three powder form of formula delivers the superior colour and produces the oxygen releaser namely barium peroxide; sodium long lasting colour with low price. perborate mono hydrate and calcium peroxide. Estimation of available oxygen will be immense useful Keywords: Iodimetric method, calcium peroxide, to adjust the formula against the colour delivery and barium peroxide, sodium perborate, available oxygen, frame the dosage of powder form of oxygen releaser. henna based powder hair dyes Many scientists worked the estimation of hydrogen peroxide and powder oxygen releaser in detergent filed I. INTRODUCTION ([1], [2], [3],[4]). Many researcher work the in- organic peroxides in agriculture field because the Henna based powder colors very much inorganic oxides releases the oxygen and it help to cure pronounced by people, because of herbal connectivity the contaminated soil ([5],[6] [7],[8]). However, the and safety aspects. In normal market leading cream data available for henna based hair colour is meager colours offers the hydrogen peroxide as an oxidizing and need to be documented. This article completely agent and cream colour containing two components; patches up the grey area of estimation of available one is a cream and it containing dyes material, oxygen in henna based hair colour system. ISSN: 2393 - 9133 www.internationaljournalssrg.org Page 39 SSRG International Journal of Applied Chemistry (SSRG-IJAC) – volume 4 Issue 2 May to Aug 2017 II. MATERIALS AND METHODS III.RESULTS AND DISCUSSION A. Estimation of available oxygen in barium A. Estimation of available oxygen in barium peroxide based henna hair colour peroxide Take accurately 0.2 gm of henna hair colour Barium peroxide falls under the inorganic in volumetric flask and dissolved with 20 mL of water oxide group and it having the atomic weight of 169.33; and then add 10 mL of concentrated hydro chloric acid it completely decompose/dissolve in presence added for initiating the reaction. Add 2 gm of concentrated hydro chloric acid solution. It further potassium iodide to the mixture and shake thoroughly reacts with water liberates the oxygen molecule. and kept for 15 minutes for reaction in dark place. The Liberated oxygen molecule estimated by iodimetric solution titrated against sodium thio sulphate (0.1 N), titration. Reaction steps are as below; the solution turn in to pale yellow colour, at that time Step 1: add 2 ml of freshly prepared starch solution and continue the titration against sodium thio sulphate 2BaO2 + 2H2O Con. HCl 2Ba(OH)2 + O2 (0.1N); the solution turn into the blue colour. The end point is disappearance of blue colour. Step 2: B. Estimation of available oxygen in O2 + 2KI Na2S2O3 I2 sodiumperborate based henna hair colour In step 1, barium hydroxide reacts with water Take accurately 0.2 gm of henna hair colour in the presence of acid medium it liberates the oxygen in volumetric flask and dissolved with 20 mL of water and forms a barium hydroxide. Commercial grades of and then add 10 mL of concentrated sulphuric acid barium are available with 80 % purity and liberates the added for initiating the reaction. Add 2 gm of 7.0 – 8.0 % available oxygen; initially we have tested potassium iodide to the mixture and shake thoroughly the 20% of barium peroxide in the formula with and kept for 15 minutes for reaction in dark place. The iodimetric titration and it liberates 1.5% of available solution titrated against sodium thio sulphate (0.1 N), oxygen; the accuracy level done with five different the solution turn in to pale yellow colour, at that time weights and we get the standard deviation of available add 2 ml of freshly prepared starch solution and oxygen estimation is 1.542 ± 0.0414 continue the titration against sodium thio sulphate Liberated oxygen estimated against the (0.1N); the solution turn into the blue colour. The end iodimetric titration. The amount of iodine liberated point is disappearance of blue colour. directly proportional to the amount of oxygen liberation. Concentration of barium peroxide increases C. Estimation of available oxygen in calcium the releasable oxygen increases. The experiment was peroxide based henna hair colour carried out with different percentage barium peroxide and gets the different available oxygen and it plotted in 1. Acid mixture preparation: below mentioned graph. Study results indicated that the methods are having high accuracy and got the 12.5 % of orthophosphoric acid (85%) and regression coefficient is r=0.9986. Below mentioned 12.5 % of concentrated hydro chloric acid (37%) mixed formula used for the estimation of available oxygen; and then add 75% of water to mix together. The Available oxygen (%) = 0.8 X burette reading X concentrated acid mixture used for the catalyst for the Normality of thio / weight of the sample calcium peroxide. 0.8 correction factor included for the oxygen Take accurately 0.2 gm of henna hair colour in volumetric flask and dissolved with 25 mL of above 4 mentioned acid mixture for initiating the reaction. Add 3 y = 0.080x - 0.040 2 gm of potassium iodide to the mixture and shake 2 R² = 0.998 thoroughly and kept for 10 minutes for reaction in dark 1 place. The solution titrated against sodium thio 0 sulphate (0.1 N), the solution turn in to pale yellow colour, at that time add 2 ml of freshly prepared starch 0 10 20 30 40 50 solution and continue the titration against sodium thio (%) oxygen Available Barium peroxide (%) sulphate (0.1N); the solution turn into the blue colour. The end point is disappearance of blue colour. Figure 1. Estimation of available oxygen content in henna based hair colour (Barium peroxide) ISSN: 2393 - 9133 www.internationaljournalssrg.org Page 40 SSRG International Journal of Applied Chemistry (SSRG-IJAC) – volume 4 Issue 2 May to Aug 2017 B. Estimation of available oxygen in calcium Sodium perborate is a reservoir of available oxygen peroxide /active oxygen supplier in detergents, laundry products, cleaning products, bleaches and hair colour dyeing Calcium peroxide fall under the inorganic segment. In recent years sodium perborate oxide group and it having the atomic weight of 72.077; monohydrate also used in oral care for tooth bleaching it completely decompose/dissolve in acid mixture / whitening agent. It having the atomic weight of described in materials and method section. It further 99.815 g and the chemical structure
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