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Kraft pulping process pdf

Continue Sulfate or craft is one of the chemical processes of cellulose. Produced by alkaline method. Craft is the dominant pulp production process in the world. Today, this process is most widely used with the production of 70-80% of the total volume of pulp. Raw materials: Although soft wood is mainly used, but any type of soft or solid wood pulp can be used to produce kraft pulp. The advantages of soft wood are that the pulp fiber is thin and long. Cooking chemicals is known as white liqueur. White liqueur contains active chemicals for cooking NaoH and Na2S. NaoH and Na2S are used to make wood chips in the reactor. In there is no fixed percentage of NaoH and Na2S chemicals, but it is better to keep 25-35% sulphide (based on total Titratable Alkali). Low sulphide percentage (especially below 15%) can affect the reaction rate and quality of the pulp. Black liqueur is used as a make-up liqueur to balance the need for liquid. The ratio of liquor to wood can be between 3 and 5 approximately. The concentration of liquor should not be more diluted, it can affect the reaction rate. In addition, steam is used to produce temperature and pressure. Pressure and temperature are very important for the cooking process. During the craft cellulose process above 360 ⁰F temperature strongly affects fiber strength and yield percentage. Below is a diagram of the craft pulp process Description of the digesting process is two types; party type and continuous type process. The reactor capacity can be 10-20 tons of pulp. In the process of batch type, the chips take a certain amount of reactor. Then a calculated amount of white liquor (contains NaOH and Na2S) or caustic soda and black liqueur (if necessary) are taken into the reactor, so that the preparation of the liqueur soak and cover the chips. Once the reactor is filled with chips and liquor, the heat is applied to the contents by cooking the liquor method of circulation, although the heat heater. The circulating liquor is collected from the middle point of the vessel through the pump and delivered to the upper and lower point of the vessel. Temperatures are controlled from 320 to 350 ⁰F. And the pressure control is 110 PSI to 150 PSI. To reach maximum temperature and pressure it takes from 1.5 hours to 3.0 hours. After reaching maximum temperature and pressure, the content is allowed to stay one to three hours to complete the cooking reaction. This time is called cooking time. Cooking time varies depending on the use of pulp. At this time, the chips soften. Once the cooking time is over, the contents are ready to be dumped into the shock tank. Pressure release control valve: B part of the vessel has a pressure control valve to release air and other non-condensed gases. The main advantage of the Kraft Kraft pulp process that used pulp chemicals can be extracted economically. About 90% of the chemicals can be extracted. International : Woodchips Craft Paper Factory for Paper (also known as Craft Pulp or Sulfate Process) is a process of converting wood into wood cellulose, which consists of almost pure cellulose fiber, the main component of paper. The crafting process involves the treatment of wood chips with a hot mixture of , hydroxide (NaOH) and (Na2S), known as white liqueur, which breaks the bonds that bind , hemicella and cellulose. The technology involves several stages, both mechanical and chemical. This is the dominant method for paper production. In some situations, this process has been controversial, as craft plants can produce odorous products and, in some situations, produce significant liquid waste. The history of the precursor to the crafting process was used during the Napoleonic Wars in England. The crafting process (so-called because of the excellent strength of the received paper, from the German word Kraft to power) was invented by Carl F. Dale in 1879 in Danzig, Prussia, Germany. U.S. Patent 296 935 was issued in 1884, and the using this technology began in Sweden in 1890. The invention of the restorative boiler by G. H. Tomlinson in the early 1930s was an important milestone in the advancement of the crafting process. This has allowed the rescue and reuse of inorganic cellulose chemicals in such a way that the craft mill is an almost closed cycle of process against inorganic chemicals, except those used in the bleaching process. For this reason, in the 1940s, the crafting process started the sulphite process as the dominant method of wood pulp production. The Process of The Continuous Craft Pulp and Paper Plant Impregnation Common Wood, used in the production of pulp, is 12-25 millimeters (0.47-0.98 inches) long and 2-10 millimeters (0.079-0.394 inches) thick. Chips usually first enter the presteaming, where they are soaked and warmed up by steam. The cavities inside the fresh wood chips are partially filled with liquid and partially air. Steam treatment causes air to expand and about 25% of the air to be excluded from the chips. The next step is to saturate the chips with black and white liqueur. The air left in the chips at the beginning of the ingesta of the liqueur is closed in the chips. The impregnation can be done before or after the chips get into the reactor and is usually done below 100 degrees Celsius (212 degrees Fahrenheit). Culinary liqueurs consist of a mixture of white liquor, water in chips, condensed steam and weak black liqueur. In impregnation, the brew liquor cuts through into the the structure of chips and low temperature chemical reactions with wood begins. Good impregnation is important to get a homogeneous cook and low rejects. About 40-60% of all alkaline consumption in process, takes place in the impregnation zone. Cooking wood chips are then prepared in pressurized vessels called reactors. Some reactors operate in a packaged manner, and some in a continuous process. There are several variants of cooking processes for both the batch and the continuous reactors. Diggers, which produce 1,000 tons or more of pulp per day, are common, with the largest producing more than 3,500 tons per day. In a continuous reactor, the materials feed at a speed that allows the pulp to break out by the time the materials come out of the reactor. As a rule, delegation requires several hours (1.5 hours) at 170-176 degrees Celsius (338 to 349 degrees Fahrenheit). In these conditions, lignin and degrade to give fragments soluble in the strongly core fluid. Solid pulp (about 50% by weight of dry wood shavings) is collected and washed. At the moment cellulose is known as brown stock because of its color. Combined liquids, known as black liqueur (because of its color), contain fragments of lignin, carbohydrates from the decay of gemichellosis, sodium carbonate, and other inorganic salts. pure reaction in the depolymerization of lignin by SH' (Ar and aryl, R and alkyl groups). One of the main chemical reactions that underpin the crafting process is the seion of ethereal bonds of nucleophilic sulphide (S2) or bisulfide (SS). The process of restoring excess black liquor contains about 15% of the solids and is concentrated in a multiple evaporative substance. After the first step, the black liqueur has about 20-30% solids. At this concentration, the pink soap rises to the surface and skim. The collected soap is additionally processed into a high oil. Removing soap improves evaporation of later effects. Weak black liquor additionally evaporates up to 65% or even 80% of solids (heavy black liquor and is burned in the recovery pot to restore inorganic chemicals for reuse in the cellulose process. During combustion, sodium sulfate is reduced to sodium sulfide with organic in the mixture: 1. Na2SO4 and 2 C → Na2S No. 2 CO2 This reaction is similar to the thermochemical reduction of sulfate in geochemist. Molten salts (smelt) from the restorative boiler dissolve in the process of water, known as weak washing. This water process, also known as weak white liqueur consists of all the liqueurs used to wash lime mud and green sediment liqueur. As a result, the solution of sodium carbonate and sodium sulfide is known as green liqueur, It is not known exactly what causes the liquor to be green. This liquid is mixed with oxide, which becomes calcium calcium in a solution to regenerate the white liqueur used in the cellulose process through a equilibrium reaction (Na2S is shown since it is part of the green liqueur but not involved in the reaction): 2. Na2CO3 and Ca (OH)2 ←→ 2 NaOH and CaCO3 Calcium carbonate is poured out of white liquor and restored and heated into a lime oven where it is converted into calcium oxide (lime). 3. CaCO3 → CaO and CO2 calcium oxide (lime) reacts with water to regenerate calcium hydroxide used in reaction 2: 4. Cao and H2O → Ca (OH)2 Combination of reactions 1-4 form a closed cycle against sodium, and calcium and is the main concept of the so-called reaustoleization process, where sodium carbonate responds to regeneration. The restorative boiler also generates high-pressure vapor, which is fed to turbo generators, reducing steam pressure to use the mill and generating electricity. The modern craft pulp and is more than self-sufficient in its electrical generation and will usually provide a clean flow of energy that can be used in an associated paper mill or sold to neighboring industries or communities up to the local electricity grid. In addition, the remnants of bark and wood are often burned in a separate boiler to generate steam. Although recovery boilers using the invention of H.H. Tomlinson have been in general use since the early 1930s, attempts have been made to find a more efficient process for the recovery of chemicals for cooking. Weyerhaeuser has successfully operated the first-generation Chemrec gas unit of black liqueur at its New Bern plant in North Carolina, while the second generation plant operates on a pilot scale at the Smurfit Kappa plant in Piteo, Sweden. Blowing up the finished wood chips, they are blown into a collection tank called a shock tank, which works at atmospheric pressure. This releases a lot of steam and volatile substances. Volatile materials are condensed and collected; in the of northern conifers, this consists mainly of raw squipira. Cellulose screening after cellulose is a process in which the pulp is separated from large shiva, knots, dirt and other debris. Reception is pulp. The material separated from the pulp is called to reject. The screening section consists of different types of sieve (screens) and centrifugal cleaning. The sieve is usually configured in a multi-stage cascading operation because a significant number of good fibers can go on a deviation stream when trying to achieve maximum purity in the acceptance flow. The fiber containing the shiva and knots is separated from the rest of the subsidy and processed either in the refinery or sent back to the reactor. The nodes are typically 0.5-3.0% of the reactor output, while Shiva is about 0.1-1.0%. Washing the brown from blowing goes to the washing stage where cooking is used separated from cellulose fibers. Usually the pulp and paper mill has 3-5 stages of washing in the series. The washing stages are also placed after delegipiation and between stages of bleaching as well. Cellulose washers use a counter current between stages so that the pulp moves in the opposite direction to the flow of washing water. Several processes are involved: thickening/dilution, displacement and diffusion. Dilution is a measure of the amount of water used in washing compared to the theoretical amount needed to displace the liqueur from the thickened pulp. A lower dilution factor reduces energy consumption, while a higher dilution rate usually gives cleaner cellulose. Careful washing of cellulose reduces the need for chemical oxygen (COD). Several types of washing equipment are used: Pressure diffusers of atmospheric diffusers Vacuum Wash Drum Wash Wash Washing Press Bleaching Main article: Bleaching of Wood Cellulose In a Modern Mill, Brown Raw (cellulose fibers containing about 5% residual lignin) produced by pulp first washed to remove some of the dissolved organic material, and then further delegated. In the case of a plant designed to produce pulp for the production of brown paper or a liner for and packaging, pulp does not always have to be bleached to high brightness. Bleaching reduces the mass of pulp produced by about 5%, reduces the strength of fibers and increases the cost of production. Process Chemicals Process Chemicals Are Added to Improve the Production Process: Soaking Helps. can be used to improve the impregnation of wood chips from the preparation of liqueurs. Retrackinone is used as a digester supplement. It works as a radox catalyst by oxidizing cellulose and reducing lignin. This protects the cellulose from degradation and makes lignin more water soluble. An emulsion switch can be added to the soap division to speed up and improve the separation of soap from used kitchen liqueurs by flocculation. Defoamers remove foam and speed up the production process. The drainage of the washing equipment improves and gives cleaner pulp. Dispersants, decaxifiers and sophisticated agents reduce the purity of the system and reduce the need for maintenance stops. Fixers fix the finely scattered potential deposits on the fibers and thus transport them out of the process. Comparisons with other pulp processes produced by the crafting process are stronger than in other pulp processes and support a high effective ratio of sulfur (sulphide), which is an important determinant of the Paper. Acid sulfite processes worsen cellulose more than the crafting process, leading to weaker fibers. Craft pulp removes most of lignin present initially in wood while mechanical pulp processes leave to leave lignin in fibers. Hydrophobic nature of lignin interferes with the formation of bonds between cellulose (and gemichellosis) in the fibers needed for paper strength (strength refers to strenuous strength and resistance to rupture). Craft pulp is darker than other wood pulp, but it can be bleached to make a very white pulp. Fully bleached craft pulp is used to produce high-quality paper, where strength, whiteness and resistance to yellowing are important. The crafting process can use a wider range of fiber sources than most other pulp processes. All types of wood, including very resinous types such as southern , and non-wood species such as and , can be used in the crafting process. By-products and emissions Additional information: Environmental impact paper Forchem high refinery in Rauma, Finland. The main by-products of craft pulp are raw sulfate sypidar and high oil soap. The availability of these species is highly dependent on wood types, growth conditions, log and chip storage time, and mill process. are the most extracted rich forests. Raw stydar is volatile and distilled off the reactor, while the raw soap is separated from the spent black liquor by decanting the soap layer formed on top of the liquor storage tanks. Of the pines, the average yield of the skipidar is 5-10 kg/t of pulp, and high crude oil is 30-50 kg/t of pulp. Various by-products containing hydrogen sulfide, methyl mercaptan, dimethylsulfide, dimethyl disulfide and other volatile sulfur compounds cause harmful air emissions typical of pulp and paper mills using the craft process. Emissions of sulphur dioxide in craft pulp mills are significantly lower than emissions of sulphite mills. In the ambient air outside of a typical modern craft pulp mill, the smell of sulphur dioxide is perceived only during disruption situations, such as when the mill shuts down for maintenance or when the power outage is long-lasting. Control of odors is achieved by collecting and burning these odorous gases in the recovery pot along with black liquor. In modern mills, where well-dried solids are burned in the boiler, it is unlikely that sulphur dioxide leaves the boiler. At high temperatures, the sodium boiler, released from the drops of black liquor, reacts with sulfur dioxide, thereby effectively cleaning it, forming sodium sulfate crystals without odor. Pulp mills are almost always located near large reservoirs because of their significant demand for water. The deligification of chemical cellulose releases a significant amount of organic material into the environment, especially in rivers or Wastewater can also be the main source of pollution containing liana from trees, high demand for biological oxygen (BOD) and dissolved organic carbon (DOC), (DOC), with alcohol, chlorate, heavy metals and chelating agents. The process of runoff can be treated in biological wastewater treatment plants, which can significantly reduce their toxicity. See. also H-factor - Inventor of the continuous process for digestion of wood pulp pulp and paper soda pulp and paper references to pulp wood - The name of the process comes from the German Kraft, which means strength in this context, because of the strength of craft paper produced using this process. The literature includes both capitalized and lower spelling (Kraft Process and Crafting Process), but crafting is most commonly used in the . Hoffman, E., Lyons, J., Boxall, J., Robertson, C., Lake, C.B., Walker, T.R. (2017). Spatiotemporal estimates (a quarter century) of pulp and paper mill metal (loid) of contaminated sediments to inform decision-making on reclamation. Environmental monitoring and assessment, 189 (6), 257. Hoffman, E., Bernier, M., Potnitsky, B., Golden, P.G., Janes, J., Kader, A., ... Assessment of public perception and environmental compliance at a pulp and paper enterprise: Canadian study. Environmental monitoring and evaluation, 187 (12), 766. Rudolf Patt et al. Paper and Pulp in the Encyclopedia of Industrial Chemistry Ullman 2002 Wiley-VCH, Weinheim. doi:10.1002/14356007.a18_545.pub4 - Pulp and paper production. 1969. - b c Biermann, Christopher J. (1993). San Diego: Academic Press, Inc. ISBN 0-12-097360-X. Wood Chemistry: Basics and Applications. Academic press. ISBN 0-12-647480-X. Pollution Prevention Technologies for the U.S. Pulp and Segment (see 66) (PDF). U.S. Environmental Protection Agency. Received 2007-09-11. Equipment for the processing of heavy black spirits. Archive from the original 2005-04-20. Received 2007-10-09. Se, Jeffrey S.; Smith, Jason B. Second critical solid black liqueur Scale (PDF). Pulp and , School of Chemical Engineering, Georgia Institute of Technology. Archive from the original (PDF) for 2011-08-31. Received 2007-10-09. The U.S. provided 5527427, Mualla Berksoy and Yaman Boluk, High Solid Black Liqueurs of Reduced Viscosity and Viscosity Reduction Method for High Solids Black Liquor, released 1996-06-18, designated Optima Specialty Chemicals and Technology Inc. Craft Pulp: Energy Consumption and Manufacturing. University of Wisconsin Biotech Center. Archive from the original on September 28, 2011. Received 2007-10-21. An external link to the Publishing website (help) and Chemrec. Archive from the original 2012-07-09. Environmental comparison of bleached craft pulp production technologies (PDF). Archive from the original (PDF) for 2004-12-18. Received 2007-09-28. Goyal, Gopal K. (1997). Annanon Pulping. ANTHOLOGY of press TAPPI published , 1977-1996. Atlanta: TAPKI Press. ISBN 0-89852-340-0. Archive copy (PDF). Archive from the original (PDF) for 2012-03-05. Extracted 2008-12-19.CS1 maint: archived copy as a title (link) - Hubbe, Martin A.; Lucian A. Lucia (2007). Love-hate relationships present in Lignocellulosic materials. Bioresources. 2 (4): 534–535. Received 2015-02-03. Southern Pines (PDF). Usda. 1985. Received 2007-09-13. a b Stenyus, Per, ed. (2000). 2. Chemistry of forest products. Paper science and technology. 3. Helsinki, Finland: Fapet OY. 73-76. ISBN 952-5216-03-9. Hoffman, E. Guernsey, J.R., Walker, T.R., Kim, J.S., Sherren, K., Andreu, (2017) Experimental study examining toxic emissions into the atmosphere near the Canadian craft pulp and paper complex in Pictow County, Nova Scotia. Environmental and Pollution Research, 24 (25), 20685-20698. Hoffman, E., Bernier, M., Potnitsky, B., Golden, P.G., Janes, J., Kader, A., ... Assessment of public perception and environmental compliance at a pulp and paper enterprise: Canadian study. Environmental monitoring and assessment, 187 (12), 766. Hoffman, E., Lyons, J., Boxall, J., Robertson, C., Lake, C.B., Walker, T.R. (2017). Spatiotemporal estimates (a quarter century) of pulp and paper mill metal (loid) of contaminated sediments to inform decision-making on reclamation. Environmental monitoring and assessment, 189 (6), 257. Further reading Gullichsen, Johan; Karl-Johan Vogelholm (2000). Paper science and technology: 6. Chemical cellulose. Finland: Tapby Press. ISBN 952-5216-06-3. Wikimedia Commons's external links have media related to kraft's process. Pulp and Paper Circle provides industry information (especially Kraft Mills) to pulp and paper engineers. A U.S. EPA article about Kraft Pulp Reference document on the best available methods in the European Commission's pulp and paper industry, 2001 extracted from kraft pulping process diagram. kraft pulping process pdf. kraft pulping process ppt. advantages of kraft pulping process. lignin kraft pulping process. kraft pulping recovery process. the alcell process a proven alternative to kraft pulping. kraft pulping process flow diagram

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