Annexure-Additional Attachments

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EC FOR PROPOSED GREENFIELD PROJECT OF CHLORINATED AND M/S. RADHA MADHAV HYDROGENATED DERIVATIVES FOR AGRO INTERMEDIATES PLANT PROCESSORS PVT. LTD. AT GIDC DAHEJ II, TAL: VAGRA, DIST: BHARUCH, GUJARAT ANNEXURES

1 ANNEXURES (ADDITIONAL ATTACHMENTS)

Annexure 1: Details of Product List with Production Capacities ...... 2

Annexure 2: Details of Storage Facilities for Raw material and Finished Goods ...... 4

Annexure 3: Details of Hazardous wastes ...... 9

Annexure 4: Water Consumption & Waste Water Details ...... 10

Annexure 5: Copy of Water supply request letter from GIDC ...... 11

Annexure 6: Stack details ...... 12

Annexure 7: Flood Map of Gujarat ...... 13

Annexure 8: Seismic Map of Gujarat ...... 14

Annexure 9: Water bodies and Water Courses of the region ...... 15

Annexure 10: Populated or built up area of the region ...... 16

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Annexure 1: Details of Product List with Production Capacities

Plant Common Capacity Products Code Name (MTPM)

Plant A CPVC Chlorinated Poly Vinyl Chloride 1500 Benzyl chloride 2,6 Dichloro Phenol 2,4 Dichloro Phenol 2,4 Chloro Phenol Benzyl chloride/Benzo Trichloride/Benzal chloride Chlorination p-Chorobenzyl choride/p-chorobenzal choride/ p-

of Benzene chloro benzotrichloride 2000 Plant B and Toluene o-Chorobenzyl Choride/o-Chorobenzal Choride/o- Chloro Benzotrichloride Chloro Benzene/Di Chloro Benzene Mono Chloro Benzene (MCB) Dichloro Benzene (DCB) (Ortho/Meta/Para) Para Chloro Toluene/ Ortho Chloro Toluene Chlorination Mono Chloro Acetic Acid Plant C of Acetic 1500 Tri Chloro Acetyl Chloride Acid Iso Phthaloyl chloride Phthaloyl chloride o-Chlorobenzaldehyde p-Chlorobenzaldehyde Benzyl Alcohol o-Chloro Benzyl Alcohol p-Chloro Benzyl Alcohol Benzoyl Chloride

Hydrolysis Benzaldehyde of 2-Methoxy 5-Bromo 6-Methyl Benzoyl Chloride Plant D 1500 Chlorinated 2,4 Dichloro Benzoyl Chloride Compound 4 Methyl Benzoyl Chloride Propargyl Chloride Pivaloyl Chloride 4-Chloro Butyryl Chloride Terephthaloyl Chloride n-Valeroyl Chloride 4-Chloro Benzoyl Chloride 3-Nitro Benzoyl Chloride 4-Nitro Benzoyl Chloride Primary Amines Plant E Amines 1000 Ethoxylation of Primary Amines Plant F Paracetamol 1000

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Plant Common Capacity Products Code Name (MTPM)

4-Chloro 3,5 Dinitro Benzoic Acid 6, Nitro 3,4 Dichloro Aniline 4-Nitro ,5-Chloro, 2-Methyl Aniline 1000 2-Nitro 4-Methyl Aniline 3, Nitro 4-Chloro Benzoic Acid 3-Nitro-para Toluic Acid 2,4 Dichloro 6 Nitro Phenol Nitro 2,3 Dichloro 4 Nitro Phenol Plant G Compounds 2,5 Dichloro 4 Nitro Phenol 1,3 Di Nitro Benzene Nitro Benzene

2/3/4 Nitro Toluene 3,5 Di Nitro Benzoic Acid p-Nitro Salicylic Acid 2,5 Dichloro Nitro Benzene 3,4/2,3 Dichloro Nitro Benzene p-Hydroxy Aniline/o-Hydroxy Aniline 1000 3,4 Dichloro Aniline 3-Iso Propoxy Aniline o-Toluidine m-Toluidine p-Toluidine Aniline 3,4 Diamine Toluene 2,5 Dimethyl 1,4 Phenylene Diamine 2 Chloro, 5-Methyl, 1,4 Phenylene Diamine Hydrogenati 2, Chloro 1,4 Phenylene Diamine Plant H on 2,5 Dichloro 1,4 Phenylene Diamine 500 compounds 2,4,5 Trichloro Aniline 6-Methyl 5-Amino Benzimidazolone 5-Amino Benzimidazolone 3-Amino 4-Chloro Benzoic acid 3-Amino 4-Chloro Benzotrifluoride 3-Amino Benzotrifluoride 3,5 Dichloro Aniline 2,5 Dichloro Aniline 2,3 Dichloro Aniline 3 Amino 4-Methyl Benzoic Acid

Total 11000

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Annexure 2: Details of Storage Facilities for Raw material and Finished Goods Table 1: Details of Raw material and Storage facilities

Quantity Raw material State Means of Storage Mt/M

1C4M2,5DNB Solid 619 Cool & dry place, in tightly closed container 2,3 DCNB Solid 657.5 Cool & dry place, in tightly closed container

2,4,5 TCN Solid 637.5 Cool & dry place, in tightly closed container

2,4-Dichloro Benzoic Solid 1530 Cool & dry place, in tightly closed container Acid

2,5 DCNB Solid 575 Cool & dry place, in tightly closed container

2,5DC4DNB Solid 714 Cool & dry place, in tightly closed container 2,5DM4DNB Solid 619 Cool & dry place, in tightly closed container 2.3 Dichloro phenol Solid 826 Cool & dry place, in tightly closed container 2.4 Dichloro phenol Solid 826 Cool & dry place, in tightly closed container 2.5 Dichloro phenol Solid 826 Cool & dry place, in tightly closed container 25 % HCl Liquid 7245 Cool & dry place, in tightly closed container 2-Chloro phenol Liquid 1582 Cool & dry place, in tightly closed container 2M5B6MBA Liquid 1575 Cool & dry place, in tightly closed container 2-Nitro Toluene Liquid 675.5 Cool & dry place, in tightly closed container 3,4 DCNB Liquid 657.5 Cool & dry place, in tightly closed container 3,4 Dichloro Aniline Solid 869 Cool & dry place, in tightly closed container 3,4 DNT Solid 643.5 Cool & dry place, in tightly closed container 3,5 DCNB Solid 649 Cool & dry place, in tightly closed container 3-Iso Propoxy Nitro Solid 666.5 Cool & dry place, in tightly closed container Benzene 3N4CBA Solid 652.5 Cool & dry place, in tightly closed container 3N4CBZ Liquid 607.7 Cool & dry place, in tightly closed container 3-NBZ Liquid 659 Cool & dry place, in tightly closed container 3-Nitro 4-Methyl Solid 632.5 Cool & dry place, in tightly closed container Benzoic Acid 3-Nitro Toluene Liquid 614.4 Cool & dry place, in tightly closed container

3-Nitrobenzoic Acid Solid 1524 Cool & dry place, in tightly closed container

4-Chloro Benzoic Acid Solid 709 Cool & dry place, in tightly closed container 4-Chloro Liquid 888 Cool & dry place, in tightly closed container Benzotrifluoride 4-Chloro Phenol Solid 1600 Cool & dry place, in tightly closed container 4-Chlorobenzoic Acid Solid 1500 Cool & dry place, in tightly closed container 4-Chlorobutanoic Acid Liquid 1363.5 Cool & dry place, in tightly closed container 4-Methyl Aniline Solid 781 Cool & dry place, in tightly closed container

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Quantity Raw material State Means of Storage Mt/M

4-Methyl Benzoic Acid Solid 823 Cool & dry place, in tightly closed container 4-Methyl Benzoic Acid Solid 1417.5 Cool & dry place, in tightly closed container 4-Nitro Toluene Solid 625.5 Cool & dry place, in tightly closed container 4-Nitrobenzoic Acid Solid 1515 Cool & dry place, in tightly closed container 5-Chloro-2-Methyl Solid 854 Cool & dry place, in tightly closed container Aniline 5NBZ Solid 706.5 Cool & dry place, in tightly closed container 60% Nitric Acid Liquid 946 Cool & dry place, in tightly closed container 6M5NBZ Liquid 696 Cool & dry place, in tightly closed container Benzal Chloride Liquid 2415 Cool & dry place, in tightly closed container Benzene Liquid 2124 Cool & dry place, in tightly closed container Benzotrichloride 3555 Cool & dry place, in tightly closed container Carbon Solid 50 Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container Causitc Solid 9120 u/N2 atm Chlorine gas 4265 Cool & dry place, in tightly closed container

FeCl3 Solid 3 Cool & dry place, in tightly closed container Hydrogen gas gas 285 Cool & dry place, in tightly closed container Iso Phathlic Acid Solid 1252.5 Cool & dry place, in tightly closed container Methanol Liquid 2307 Cool & dry place, in tightly closed container ML Liquid 720 Cool & dry place, in tightly closed container Nitro benzene Liquid 1410 Cool & dry place, in tightly closed container N-Valeroyl acid Liquid 1606.5 Cool & dry place, in tightly closed container o-Chloro Benzal Liquid 2190 Cool & dry place, in tightly closed container Chloride ODCB Liquid 813 Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container Para Amino Phenol Solid 2100 u/N2 atm p-Chloro Benzal Solid 2197.5 Cool & dry place, in tightly closed container Chloride p-DCB Solid 813 Cool & dry place, in tightly closed container Phathlic Acid Solid 1260 Cool & dry place, in tightly closed container Phenol liquid 1540 Cool & dry place, in tightly closed container Pivalic acid Solid 1350 Cool & dry place, in tightly closed container PNCB Solid 7410 Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container Prop-2-yn-1-ol Liquid 1200 (at 2-8 C) PVC Resins Solid 1171.5 Cool & dry place, in tightly closed container Pyridine Liquid 3 Cool & dry place, in tightly closed container

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Quantity Raw material State Means of Storage Mt/M

Cool & dry place, in tightly closed container Rany Nickel Solid 38 (In Water ) Salicylic acid Solid 700 Cool & dry place, in tightly closed container SMC Liquid 370.5 Cool & dry place, in tightly closed container Sulphuric acid Liquid Cool & dry place, in tightly closed container Terephthalic acid Solid 1293 Cool & dry place, in tightly closed container Toluene Liquid 746 Cool & dry place, in tightly closed container

Table 2: Details of Finished goods and Storage facilities

Product State Capacity Means of Storage

Chlorinated Poly Vinyl Solid 1500 Dry place, at normal condition. Chloride 2,6 dichloro phenol Solid Cool & dry place, in tightly closed container 2,4 dichloro phenol Solid Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container 2/4 Chloro Phenol Solid u/N2 atm Benzyl chloride/ Benzo Cool & dry place, in tightly closed container Liquid Trichloride/ Benzal chloride u/N2 atm p-Chorobenzyl Choride/ p- Cool & dry place, in tightly closed container Chorobenzal Choride/ p- Solid u/N2 atm Chloro Benzotrichloride 2000 o-Chorobenzyl Choride/o- Chorobenzal Choride/ o- Liquid Cool & dry place, in tightly closed container Chloro Benzotrichloride Mono chloro benzene Liquid Cool & dry place, in tightly closed container Ortho Dichloro Benzene Liquid Cool & dry place, in tightly closed container Para Dichloro Benzene Solid Cool & dry place, in tightly closed container p-Chloro Toluene/O- Chloro Liquid Cool & dry place, in tightly closed container Toluene Mono Chloro Acetic Acid Solid Cool & dry place, in tightly closed container 1500 Cool & dry place, in tightly closed container Tri Chloro Acetyl Chloride Liquid u/N2 atm Cool & dry place, in tightly closed container Iso Phthaloyl Chloride Liquid u/N2 atm Phthaloyl Chloride Liquid Cool & dry place, in tightly closed container o-Chlorobenzaldehyde Liquid Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container P-Chlorobenzaldehyde Solid 1500 u/N2 atm Cool & dry place, in tightly closed container Benzyl Alcohol Liquid u/N2 atm o-Chloro Benzyl Alcohol Solid Cool & dry place, in tightly closed container p-Chloro Benzyl Alcohol Solid Cool & dry place, in tightly closed container

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Product State Capacity Means of Storage

Cool & dry place, in tightly closed container Benzaldehyde Liquid u/N2 atm 2-Methoxy-5-Bromo-6- Liquid Cool & dry place, in tightly closed container Methyl Benzoyl Chloride 2,4 Dichloro Benzoyl Liquid Cool & dry place, in tightly closed container Chloride 4-Methyl Benzoyl Chloride Liquid Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container Propargyl Chloride Liquid (at 2-8 C) Cool & dry place, in tightly closed container Pivaloyl Chloride Liquid u/N2 atm. 4-Chloro Butyryl Chloride liquid Cool & dry place, in tightly closed container Terephthaloyl Chloride solid Cool & dry place, in tightly closed container n-Valeroyl Chloride Liquid Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container 4-Chloro Benzoyl Chloride Liquid u/N2 atm 3-Nitro Benzoyl Chloride Solid Cool & dry place, in tightly closed container 4-Nitro Benzoyl Chloride Solid Cool & dry place, in tightly closed container Paracetamol Solid 100 Cool & dry place, in tightly closed container 4-Chloro 3,5 Dinitro Benzoic Solid Cool & dry place, in tightly closed container Acid 6-Nitro 3,4 Dichloro Aniline Solid Cool & dry place, in tightly closed container 4-Nitro ,5-Chloro, 2-Methyl Solid Cool & dry place, in tightly closed container Aniline 2-Nitro 4-Methyl Aniline Solid Cool & dry place, in tightly closed container 3-Nitro 4-Chloro Benzoic Solid Cool & dry place, in tightly closed container Acid 3 Nitro Para Toluic Acid Solid Cool & dry place, in tightly closed container 2,4 Dichloro 6 Nitro Phenol Solid Cool & dry place, in tightly closed container 2,3-Dichloro 4-Nitro Phenol Solid 100 Cool & dry place, in tightly closed container 2,5 Di Chloro 4 Nitro Phenol Solid Cool & dry place, in tightly closed container 1,3 Di Nitro Benezene Solid Cool & dry place, in tightly closed container Nitro Benzene Liquid Cool & dry place, in tightly closed container 2/3/4- Nitro Toulene Liquid Cool & dry place, in tightly closed container 3,5 Di Nitro Benzoic Acid Solid Cool & dry place, in tightly closed container p-Nitro Salicylic Acid Solid Cool & dry place, in tightly closed container 2,5 Dichloro Nitro Benzene Solid Cool & dry place, in tightly closed container 3,4/2,3 Dichloro Nitro Solid Cool & dry place, in tightly closed container Benzene p-Hydroxy Aniline/O-Hydroxy Cool & dry place, in tightly closed container Solid 1000 Aniline u/N2 atm

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Product State Capacity Means of Storage

Cool, dry & dark place, in tightly closed 3,4 Dichloro Aniline Solid container 3-Iso propoxy Aniline Liquid Cool & dry place, in tightly closed container Cool & dry place, in tightly closed container o-Toluidine Liquid u/N2 atm m-Toluidine Liquid Cool & dry place, in tightly closed container p-Toluidine Solid Cool & dry place, in tightly closed container Aniline Liquid Cool & dry place, in tightly closed container 3,4 Diamino Toluene Solid Cool & dry place, in tightly closed container 2,5 Dimethyl 1,4 Phenylene Solid Cool & dry place, in tightly closed container Diamine 2-chloro, 5-Methyl, 1,4 Cool & dry place, in tightly closed container Solid Phenylene Diamine (at 2-8 C) 2 Chloro 1,4 Phenylene Solid Cool & dry place, in tightly closed container Diamine 2,5 Dichloro 1,4 Phenylene Solid Cool & dry place, in tightly closed container Diamine 500 2,4,5 Tri Chloro Aniline Solid Cool & dry place, in tightly closed container 6-Methyl 5-Amino Liquid Cool & dry place, in tightly closed container Benzimidazolone 5-Amino Benzimidazolone Solid Cool & dry place, in tightly closed container 3-Amino 4-Chloro Benzoic Solid Cool & dry place, in tightly closed container Acid 3-Amino 4-chloro Liquid Cool & dry place, in tightly closed container Benzotrifluoride 3-Amino Benzotrifluoride Solid Cool & dry place, in tightly closed container 3,4 Dichloro Aniline Solid Cool & dry place, in tightly closed container 3,5 Dichloro Aniline Solid Cool & dry place, in tightly closed container Solid 2,5 Dichloro Aniline (at Cool & dry place, in tightly closed container 250C) 2,3 Dichloro Aniline Solid Cool & dry place, in tightly closed container 3 Amino 4-Methyl Benzoic Solid Cool & dry place, in tightly closed container Acid

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Annexure 3: Details of Hazardous wastes Table 3: Details of Hazardous waste along with the Category and disposal method S. Waste Category Quantity/Year Source Disposal Method No Name Collection, Storage, Process transportation and send 1 26.1 600 Process residue to CHWIF for incineration. Collection, Storage, Carbon 2 35.3 4452 Process transportation and send waste to TSDF.

Hypo Sale to authorized 3 D2 24162.00 Process chlorite vendors

Sale to authorized 4 HCl D2 98874 Process vendors

Sale to authorized 5 Acetic Acid D2 44040.00 Process vendors

Sale to authorized 6 Spent Acid D2 68232.00 Process vendors

Collection, Storage, transportation and send Spent 7 35.2 44.4 Process for catalyst regeneration/reactivation to supplier. Collection, storage, 8 Used Oil 5.1 200 Ltrs Process reuse/sell to authorized recycler Collection, Discarded decontaminations, 9 drums and 33.3 12000 Nos Process storage, reuse/sell to containers authorized recycler. Collection, Storage, 10 ETP waste 34.3 960 ETP transportation and send to TSDF.

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Annexure 4: Water Consumption & Waste Water Details Table 4: Details Raw water consumption S. No. Areas of Consumption Fresh Water (KLD)

1 Domestic 9 2 Manufacturing process 1760 3 Washing 20 4 Cooling Tower 200 5 Boiler 120 6 Gardening 50 Total 2159

Table 5: Details of Waste water generation S. No. Sources of generation Waste Water (KLD) 1 Domestic 7.5 2 Manufacturing process 1803 3 Washing 16 4 Cooling Tower 45 5 Boiler 10 6 Gardening 0 Total 1881.5

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Annexure 5: Copy of Water supply request letter from GIDC

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Annexure 6: Stack details Table 6: Details of emissions from proposed process and flue gas stacks along with the mitigation methods Air Stack Stack Stack Probable S. Pollution Attached Height Diamete Pollutants Concentra No. Control to (m) r (m) tion Measures Process Emission Water Scrubber Reactor in 1. 15 0.2 followed by MCA plant Alkali scrubber CPVC plant Alkali 2. 15 0.2 reactor scrubber Water 3. CPVC dryer 15 0.2 Less than 9 scrubber Chlorination Chlorine mg/NM3 Caustic and 4 Reactor in 15 0.2 water TCAC plant HCL Less than scrubber CAC reactor 20 mg/NM3 Caustic and 5 in TCAC 15 0.2 water plant scrubber Benzene Caustic and 6 Chlorination 15 0.2 water Reactor scrubber Toluene Caustic and 7 Chlorination 15 0.2 water Reactor scrubber Flue Gas Emission Coal Fire Dust 1 Steam 20 1.2 Collector Boiler PM 150 m/NM3 Hightem SOx 100 ppm 3 15 1.2 None Boiler Nox 50 ppm Adequate 4 D.G Set 11 0.2 Stack Height

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Annexure 7: Flood Map of Gujarat

Source: Gujarat State Disaster Management Authority

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Annexure 8: Seismic Map of Gujarat

Source: Seismic Map of Gujarat (Institute of Seismological Research, Govt. of Gujarat)

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Annexure 9: Water bodies and Water Courses of the region Rivers/Pond Distance in km Direction Vadadla Pond 1.3 ENE Dahej Pond 3.0 WSW Jolva Pond 3.6 SSE Vav Pond 3.8 NE Ambetha Pond 4.8 SW Kadodara Pond 4.9 NNE Galenda Pond 5.4 ENE Suva Pond 5.4 SSE Sambethi Pond 5.6 ENE Samatpor Pond 5.8 ENE Rahiyad Pond 5.9 SE Padariya Pond 6.4 NNE Jageshwar Pond 6.9 SW Lakhigam Pond 7.3 WSW Janiadara Pond 7.4 NE Paniadara Pond 8.2 NNE Koliyad Pond 8.3 SE Luvara Pond 8.4 WSW Narnavi Pond 8.6 NE Atali Pond 8.6 ESE Akhod Pond 9.2 ENE Nadarkha Pond 10.3 ENE Goladara Pond 10.5 NNE Vegni Pond 10.6 SE Aladar Pond 11.6 NE Nandida Pond 12 ENE Kaladara Pond 13.2 SE Trankal Pond 13.7 NNE Khojbal Pond 13.7 ESE Bhelsli Pond 13.9 ESE Pakhajan Pond 14.3 ENE Creek 2.57 SE

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Annexure 10: Populated or built up area of the region

Villages/Towns Distance in ~km Direction Vadadla 1.3 ENE Dahej 3.0 WSW Jolva 3.6 SSE Vav 3.8 NE Ambetha 4.8 SW Kadodara 4.9 NNE Galenda 5.4 ENE Suva 5.4 SSE Sambethi 5.6 ENE Samatpor 5.8 ENE Rahiyad 5.9 SE Padariya 6.4 NNE Jageshwar 6.9 SW Lakhigam 7.3 WSW Janiadara 7.4 NE Paniadara 8.2 NNE Koliyad 8.3 SE Luvara 8.4 WSW Narnavi 8.6 NE Atali 8.6 ESE Akhod 9.2 ENE Nadarkha 10.3 ENE Goladara 10.5 NNE Vegni 10.6 SE Aladar 11.6 NE Nandida 12 ENE Ambhel 12.8 NE Kaladara 13.2 SE Trankal 13.7 NNE Khojbal 13.7 ESE Bhelsli 13.9 ESE Pakhajan 14.3 ENE Limdi 15 ENE

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