The Mineralogy of Pegmatites
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The Krásno Sn-W Ore District Near Horní Slavkov: Mining History, Geological and Mineralogical Characteristics
Journal of the Czech Geological Society 51/12(2006) 3 The Krásno Sn-W ore district near Horní Slavkov: mining history, geological and mineralogical characteristics Sn-W rudní revír Krásno u Horního Slavkova historie tìby, geologická a mineralogická charakteristika (47 figs, 1 tab) PAVEL BERAN1 JIØÍ SEJKORA2 1 Regional Museum Sokolov, Zámecká 1, Sokolov, CZ-356 00, Czech Republic 2 Department of Mineralogy and Petrology, National Museum, Václavské nám. 68, Prague 1, CZ-115 79, Czech Republic The tin-tungsten Krásno ore district near Horní Slavkov (Slavkovský les area, western Bohemia) belongs to the most important areas of ancient mining in the Czech Republic. The exceptionally rich and variable mineral associations, and the high number of mineral species, make this area one of the most remarkable mineralogical localities on a worldwide scale. The present paper reviews the data on geological setting of the ore district, individual ore deposits and mining history. Horní Slavkov and Krásno were known as a rich source of exquisite quality mineral specimens stored in numerous museum collections throughout Europe. The old museum specimens are often known under the German locality names of Schlaggenwald (= Horní Slavkov) and Schönfeld (=Krásno). The megascopic properties and paragenetic position of selected mineral classics are reviewed which include arsenopyrite, fluorapatite, fluorite, hübnerite, chalcopyrite, carpholite, cassiterite, quartz, molybdenite, rhodochrosite, sphalerite, topaz and scheelite. Key words: Sn-W ores; tin-tungsten mineralization; mining history; ore geology; mineralogy; Slavkovský les; Krásno, Horní Slavkov ore district; Czech Republic. Introduction valleys dissected parts of the area. In the ore district area, the detailed surface morphology is modified by large de- In the mining history of Central Europe, Bohemia and pressions caused by the collapse of old underground Moravia are known as important source of gold, silver, workings and by extensive dumps. -
L. Jahnsite, Segelerite, and Robertsite, Three New Transition Metal Phosphate Species Ll. Redefinition of Overite, an Lsotype Of
American Mineralogist, Volume 59, pages 48-59, 1974 l. Jahnsite,Segelerite, and Robertsite,Three New TransitionMetal PhosphateSpecies ll. Redefinitionof Overite,an lsotypeof Segelerite Pnur BnnN Moone Thc Departmcntof the GeophysicalSciences, The Uniuersityof Chicago, Chicago,Illinois 60637 ilt. lsotypyof Robertsite,Mitridatite, and Arseniosiderite Peur BmaN Moonp With Two Chemical Analvsesbv JUN Iro Deryrtrnent of GeologicalSciences, Haraard Uniuersity, Cambridge, Massrchusetts 02 I 38 Abstract Three new species,-jahnsite, segelerite, and robertsite,-occur in moderate abundance as late stage products in corroded triphylite-heterosite-ferrisicklerite-rockbridgeite masses, associated with leucophosphite,hureaulite, collinsite, laueite, etc.Type specimensare from the Tip Top pegmatite, near Custer, South Dakota. Jahnsite, caMn2+Mgr(Hro)aFe3+z(oH)rlPC)oln,a 14.94(2),b 7.14(l), c 9.93(1)A, p 110.16(8)", P2/a, Z : 2, specific gavity 2.71, biaxial (-), 2V large, e 1.640,p 1.658,t l.6lo, occurs abundantly as striated short to long prismatic crystals, nut brown, yellow, yellow-orange to greenish-yellowin color.Formsarec{001},a{100},il2oll, jl2}ll,ft[iol],/tolll,nt110],andz{itt}. Segeierite,CaMg(HrO)rFes+(OH)[POdz, a 14.826{5),b 18.751(4),c7.30(1)A, Pcca, Z : 8, specific gaavity2.67, biaxial (-), 2Ylarge,a 1.618,p 1.6t5, z 1.650,occurs sparingly as striated yellow'green prismaticcrystals, with c[00], r{010}, nlll0l and qll2l } with perfect {010} cleavage'It is the Feg+-analogueofoverite; a restudy on type overite revealsthe spacegroup Pcca and the ideal formula CaMg(HrO)dl(OH)[POr]r. Robertsite,carMna+r(oH)o(Hro){Ponlr, a 17.36,b lg.53,c 11.30A,p 96.0o,A2/a, Z: 8, specific gravity3.l,T,cleavage[l00] good,biaxial(-) a1.775,8 *t - 1.82,2V-8o,pleochroismextreme (Y, Z = deep reddish brown; 17 : pale reddish-pink), @curs as fibrous massesand small wedge- shapedcrystals showing c[001 f , a{1@}, qt031}. -
Alteration of Spodumene, Montebrasite and Lithiophilite In
American Mineralogist, Volume 67, pages 97-113, 1982 Alteration of spodumene,montebrasite and lithiophilite in pegmatites of the White PicachoDistrict, Arizona Davrp Lor.rooxrnNo DoNer-uM. Bunr Department of Geology Arizona State University Tempe, Arizona 85281 Abstract The crystallization sequence and metasomatic alteration of spodumene (LiAlSizOe), montebrasite(LiAIPO4(OH,F)), and lithiophilite (Li(Mn,Fe)PO+)are describedfor nine zoned lithium pegmatitesin the White Picacho district, Arizona. The observedcrystalliza- tion trends suggesta progressiveincrease in the activities of lithium species(spodumene follows microcline as the principal alkali aluminosilicate), as well as an increase in the activities of the acidic volatiles phosphorus and fluorine (montebrasite succeedsspodu- mene as the stableprimary lithium phase).Much of the lithiophilite occurs with columbite, apatite, beryl, zircon, and tourmaline in cleavelanditecomplexes that formed in part at the expenseof quartz-spodumenepegmatite. Fracture-controlledpseudomorphic alteration of the primary lithium minerals is widespread and apparently is the result of subsolidus reactionswith residualpegmatitic fluids. Spodumenehas been replacedby eucryptite, albite, and micas. Alteration products of montebrasite include low-fluorine secondary montebrasite,crandallite (tentative), hydroxylapatite, muscovite, brazilianite, augelite (tentative),scorzalite, kulanite, wyllieite, and carbonate-apatite.Secondary phases identi- fied in altered lithiophilite include hureaulite, triploidite, eosphorite, -
1 CRYSTAL CHEMISTRY of SELECTED Sb, As and P MINERALS
Crystal Chemistry of Selected Sb, As, and P Minerals Item Type text; Electronic Dissertation Authors Origlieri, Marcus Jason Publisher The University of Arizona. Rights Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. Download date 07/10/2021 10:49:41 Link to Item http://hdl.handle.net/10150/194240 1 CRYSTAL CHEMISTRY OF SELECTED Sb, As AND P MINERALS by Marcus Jason Origlieri ___________________________________________ A Dissertation Submitted to the Faculty of the DEPARTMENT OF GEOSCIENCES In Partial Fulfillment of the Requirements For the Degree of DOCTOR OF PHILOSOPHY In the Graduate College THE UNIVERSITY OF ARIZONA 2005 2 THE UNIVERSITY OF ARIZONA GRADUATE COLLEGE As members of the Dissertation Committee, we certify that we have read the dissertation prepared by Marcus Jason Origlieri entitled Crystal Chemistry of Selected Sb, As, and P Minerals and recommend that it be accepted as fulfilling the dissertation requirement for the Degree of Doctor of Philosophy _______________________________________________________________________ Date: November 15, 2005 Robert T. Downs _______________________________________________________________________ Date: November 15, 2005 M. Bonner Denton _______________________________________________________________________ Date: November 15, 2005 Mihai N. Ducea _______________________________________________________________________ Date: November 15, 2005 Charles T. Prewitt Final approval and acceptance of this dissertation is contingent upon the candidate’s submission of the final copies of the dissertation to the Graduate College. I hereby certify that I have read this dissertation prepared under my direction and recommend that it be accepted as fulfilling the dissertation requirement. -
Trolleite Al4(PO4)3(OH)3 C 2001-2005 Mineral Data Publishing, Version 1
Trolleite Al4(PO4)3(OH)3 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Lamellar, massive, to 3 cm. Physical Properties: Cleavage: In two directions, indistinct. Fracture: Even to conchoidal. Hardness = 8.5 D(meas.) = 3.10 D(calc.) = 3.08 Optical Properties: Translucent. Color: Pale green to bright blue. Luster: Vitreous. Optical Class: Biaxial (–). Dispersion: r> v,weak. α = 1.619 β = 1.639 γ = 1.643 2V(meas.) = 49◦ Cell Data: Space Group: I2/c. a = 18.894(5) b = 7.161(1) c = 7.162(2) β =99.99(2)◦ Z=4 X-ray Powder Pattern: Champion mine, California, USA. 3.208 (100), 3.095 (90), 3.075 (50), 2.519 (45), 3.336 (40), 6.667 (35), 1.983 (35) Chemistry: (1) (2) (3) P2O5 46.72 48.00 47.97 Al2O3 43.26 43.87 45.94 Fe2O3 2.75 0.34 CaO 0.97 0.02 H2O 6.23 [7.77] 6.09 Total 99.93 [100.00] 100.00 (1) V¨astan˚amine, Sweden. (2) H¨okens˚as, Sweden; by electron microprobe, total Fe as Fe2O3, H2O by difference. (3) Al4(PO4)3(OH)3. Occurrence: In amphibolite-grade metamorphic rocks. Association: Berlinite, attakolite, augelite, lazulite (V¨astan˚amine, Sweden); scorzalite, augelite, vis´eite(Champion mine, California, USA); montebrasite, scorzalite, bertossaite, brazilianite, apatite, gatumbaite, samuelsonite, wyllieite (Buranga pegmatite, Rwanda). Distribution: In Sweden, from the V¨astan˚amine, near N¨asum,Sk˚ane; at H˚alsj¨oberg, V¨armland;from H¨okens˚as,V¨asterg¨otland.In the Buranga pegmatite, Rwanda. -
Geology of the Hugo Pegmatite Keystone, South Dakota
Geology of the Hugo Pegmatite Keystone, South Dakota GEOLOGICAL SURVEY PROFESSIONAL PAPER 297-B Geology of the Hugo Pegmatite Keystone, South Dakota By J. J. NORTON, L. R. PAGE, and D. A. BROBST PEGMATITES AND OTHER PRECAMBRIAN ROCKS IN THE SOUTHERN BLACK HILLS GEOLOGICAL SURVEY PROFESSIONAL PAPER 297-P A detailed structural and petrologic study of a pegmatite containing seven zones and two replacement bodies UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1962 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY Thomas B. Nolan, Director For sale by the Superintendent of Documents, U.S. Government Printing Office Washington 25, D.C. CONTENTS Page Page Abstract.. _ ________________________________________ 49 Mineral distribution and paragenesis of the entire Introduction. ______________________________________ 49 pegmatite_ _ ______________________-___---------_ 96 General geology. ___________________________________ 52 Comparison of the zonal sequence with that in other Metamorphic rocks_ ____________________________ 52 pegmatites. ______________________________________ 97 Roy and Monte Carlo pegmatites.- _ __---__-______ 53 Replacement features-______________________________ 100 Structure __________________________________________ 53 Review of the evidence for replacement in pegma Pegmatite units ____________________________________ 53 tites __ _____________________________________ 100 Zone 1 : Albite-quartz-musco vite pegmatite ________ 56 Replacement in the Hugo pegmatite.____-_____-_- 102 -
Llallagua Tin Ore Deposit (Bolivia)
resources Article Speculations Linking Monazite Compositions to Origin: Llallagua Tin Ore Deposit (Bolivia) Elizabeth J. Catlos * and Nathan R. Miller Department of Geological Sciences, Jackson School of Geosciences, The University of Texas at Austin, 1 University Sta. C9000, EPS 1.130, Austin, TX 78712, USA; [email protected] * Correspondence: [email protected]; Tel.: +1-512-471-4762 Received: 3 May 2017; Accepted: 25 July 2017; Published: 29 July 2017 Abstract: Monazite [(Ce,Th)PO4] from the Llallagua tin ore deposit in Bolivia is characterized by low radiogenic element contents. Previously reported field evidence and mineral associations suggest the mineral formed via direct precipitation from hydrothermal fluids. Monazite compositions thus may provide insight into characteristics of the fluids from which it formed. Chemical compositions of three Llallagua monazite grains were obtained using Electron Probe Microanalysis (EPMA, n = 64) and laser ablation mass spectrometry (LA-ICP-MS, n = 56). The mineral has higher amounts of U (123 ± 17 ppm) than Th (39 ± 20 ppm) (LA-ICP-MS, ±1σ). Grains have the highest amounts of fluorine ever reported for monazite (0.88 ± 0.10 wt %, EPMA, ±1σ), and F-rich fluids are effective mobilizers of rare earth elements (REEs), Y, and Th. The monazite has high Eu contents and positive Eu anomalies, consistent with formation in a highly-reducing back-arc environment. We speculate that F, Ca, Si and REE may have been supplied via dissolution of pre-existing fluorapatite. Llallagua monazite oscillatory zoning is controlled by an interplay of low (P + Ca + Si + Y) and high atomic number (REE) elements. -
38Th RMS Program Notes
E.fu\wsoil 'og PROGRAM Thursday Evening, April 14, 2011 PM 4:00-6:00 Cocktails and Snacks – Hospitality Suite 400 (4th Floor) 6:00-7:45 Dinner – Baxter’s 8:00-9:15 THE GUALTERONI COLLECTION: A TIME CAPSULE FROM A CENTURY AGO – Dr. Renato Pagano In 1950, the honorary curator of the Museum of Natural History in Genoa first introduced Dr. Renato Pagano to mineral collecting as a Boy Scout. He has never looked back. He holds a doctorate in electrical engineering and had a distinguished career as an Italian industrialist. His passion for minerals has produced a collection of more than 13,000 specimens, with both systematic and aesthetic subcollections. His wife Adriana shares his passion for minerals and is his partner in collecting and curating. An excellent profile of Renato, Adriana, and their many collections appeared earlier this year in Mineralogical Record (42:41-52). Tonight Dr. Pagano will talk about an historic mineral collection assembled between 1861 and 1908 and recently acquired intact by the Museum of Natural History of Milan. We most warmly welcome Dr. Renato Pagano back to the speakers’ podium. 9:15 Cocktails and snacks in the Hospitality Suite on the 4th floor will be available throughout the rest of the evening. Dealers’ rooms will be open at this time. All of the dealers are located on the 4th floor. Friday Morning, April 15, 2011 AM 9:00 Announcements 9:15-10:15 CRACKING THE CODE OF PHLOGOPITE DEPOSITS IN QUÉBEC (PARKER MINE), MADAGASCAR (AMPANDANDRAVA) AND RUSSIA (KOVDOR) – Dr. Robert F. Martin Robert François Martin is an emeritus professor of geology at McGill University in Montreal. -
Winter 2006 Gems & Gemology Gem News
EDITOR Brendan M. Laurs ([email protected]) CONTRIBUTING EDITORS Emmanuel Fritsch, IMN, University of Nantes, France ([email protected]) Henry A. Hänni, SSEF, Basel, Switzerland ([email protected]) Franck Notari, Geneva, Switzerland ([email protected]) Kenneth V. G. Scarratt, GIA Research, Bangkok, Thailand ([email protected]) DIAMONDS Angola and the Democratic Republic of Congo. This situ- Update on Diamond Trading in Sierra Leone. During the ation led to the Kimberley Process for certifying dia- decade-long civil war in Sierra Leone, the Revolutionary monds from mine to market, which was implemented in United Front (RUF) rebel army committed widespread 2002. With the signing of the Lomé Peace Agreement atrocities against innocent civilians, drawing global con- between the Sierra Leone government and the RUF earlier demnation by governments, human rights groups, and that year, peace has returned to the country. concerned citizens. The RUF was partially funded by the In August 2006, GIA Education instructor Ric Taylor country’s diamond resources, bringing the issue of con- traveled through the Sierra Leone diamond mining areas of flict diamonds in Sierra Leone to world attention in the Koidu, Tongo, Kenema, and Bo, some of which were once late 1990s. Meanwhile, similar diamond-funded conflicts controlled by the rebels. He saw no evidence of continuing were being waged in other African nations, such as conflict, and residents and journalists in these areas con- firmed that there is no desire to return to war. In the town of Koidu (figure 1), in the diamond mining district of Kono Figure 1. The town of Koidu, in the Kono district of in eastern Sierra Leone, one can still see the bare walls of eastern Sierra Leone, was at the center of the county’s buildings that were looted and burned, but many others protracted conflict because of the area’s diamond have been rebuilt and have roofs of corrugated metal or resources. -
NEW MINERALS It Is Proposed Hereafter to Indicate In.A General Way the Classification of All New Minerals Recoided in This Department
JOURNAL MINERALOGICAL SOCIETY OF AMENICA 63 Dr. Kunz then spoke of the various city localities and the minerals found therein. He stated that the East Side, from 37 to 110 St., probably afforded the most specimens. The various tunnels and their minerals were spoken of. Capt. Miller called attention to the fine collection of Brooklyn Drift Minerals and Rocks in the collection of the Long Island Historical Society. Ife abo mentioned the occurrence of monazite and xenotime crystals, on the Speedway,Harlem River. Dr. Kunz emphasizedthe irnportance of complete records being kept of all finds. Tnou,q,s L Mrr,r,nn, SecretaryPro, Tem. NEW MINERALS It is proposed hereafter to indicate in.a general way the classification of all new minerals recoided in this department. Subdivision will be first into "families," of which nine may be recognized,as listed in the January number (Am. Min.6 (1), 12,1921). Eachfamilywillbe separatedinto "subfamilies " based on special features of composition. This arrangement is tentative and open to modification, and criticism of it will be welcome, [Eo.] FAMILY 2. SULFIDES, ETC. SosreMrr,v 3. Doust,u suLFrDEs oF METALSAND sEMr-METAr,s. I'LTRABASITE V. Rosrcxf and J. Srnnse-Btinu. Ultrabasit, ein neues Mineral aus Freiberg in Sachsen. (Ultrabasite, a new mineral from Freiberg, Saxony). Rozpr.Eeslcd Ako,il. Prag,25, No. 45, 1916;Z. Krgst. Min., 55,43H39, 1920, Neun: From its extremely basic chemical composition. Pnrsrcar, Pnopnnrrus Color black, somewhat grayish; luster metallic; streak black; cleavage none; fracture scaly, with somewhat greasy luster on the surface. H. : 5; sp. gr. -
Strengite.Pdf
3+ Strengite Fe PO4 • 2H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. Crystals are variable in habit, may be dominated by {111}, lathlike along [001], or elongated along [100] or [010], to 5 cm, with many forms. Generally radial fibrous, as botryoidal or spherical aggregates and crusts. Twinning: Rarely on {201}. Physical Properties: Cleavage: On {010}, good; on {001}, poor. Hardness = 3.5 D(meas.) = 2.84–2.87 D(calc.) = 2.84 Optical Properties: Transparent to translucent. Color: Purple, violet, pink, peach-blossom- red, carmine, greenish white; may be nearly colorless. Streak: White. Luster: Vitreous. Optical Class: Biaxial (+). Orientation: X = a; Y = c; Z = b. Dispersion: r< v,strong. α = 1.697–1.708 β = 1.708–1.719 γ = 1.741–1.745 2V(meas.) = Moderate to small. Cell Data: Space Group: P cab. a = 10.122(1) b = 9.886(1) c = 8.7233(7) Z = 8 X-ray Powder Pattern: The Kreuzberg, Germany. (ICDD 33–667). 3.114 (100), 4.383 (85), 5.509 (60), 2.546 (50), 3.996 (45), 3.002 (45), 2.949 (45) Chemistry: (1) (2) P2O5 38.24 37.99 Fe2O3 43.40 42.73 H2O 18.89 19.28 Total 100.53 100.00 • (1) Pleystein, Germany. (2) FePO4 2H2O. Polymorphism & Series: Dimorphous with phosphosiderite, forms a series with variscite. Mineral Group: Variscite group. Occurrence: A late secondary mineral in complex granite pegmatites; in “limonite” iron ores and gossans; with magnetite iron ores; rarely a cave mineral. Association: Beraunite, hur´eaulite,dufr´enite,bermanite, stewartite, cacoxenite, rockbridgeite, vivianite, apatite, leucophosphite, phosphosiderite. -
LAYERED PEGMATITE-APLITE Division of Earth Sciences, The
MINERALOGICAL SOCIETY OF AMERICA, SPECIAL PAPER 1, 1963 INTERNATIONALMINERALOGICALASSOCIATION,PAPERS, THIRD GENERAL MEETING LAYERED PEGMATITE-APLITE INTRUSIVES 1 RICHARD H. JAHNS AND O. FRANK TUTTLE Division of Earth Sciences, The Pennsylvania State University, University Park, Pennsylvania ABSTRACT Intrusive bodies of granitic pegmatite and aplite with simple or complex layering include those representing multiple injections of magma from external sources and those representing single injections of magma followed by segregation dur- ing crystallization. Those of the latter category can be subdivided into four classes, intergradations among which are not uncommon: 1. Bodies of aplite or fine-grained pegmatite with very large phenocrysts, or megacrysts. 2. Aplite bodies with mar- ginal or interior pegmatite masses generally formed in situ. 3. Pegmatite bodies with marginal or interior aplite masses formed in situ or by autoinjection. 4. Highly asymmetric bodies whose upper parts consist mainly or wholly of pegmatite and whose lower parts consist mainly or wholly of aplite. Zonal structure defines a gross layering within many pegmatite bodies, and a layer-like distribution of pegmatite and aplite also is common over a wide range of scales. Some of the aplites are faintly to distinctly flow layered, and others are featured by rhythmic layering in which adjacent thin and regular units differ from each other in composition. None of the observed types of layering is regarded as a result of crystal accumulation. The bulk composition of the layered intrusive bodies falls in the thermal valley of petrogeny's residua system at an average composition corresponding to a parent magma saturated with water at high pressures (e.g.