Malcolm DE Forbes

Malcolm D. E. Forbes – Curriculum Vitae

CB# 3290, Department of Chemistry Caudill Laboratories 020 University of North Carolina, Chapel Hill, NC 27599 Tel. (919) 962–1696, FAX: (919) 962–2388 [email protected] Citizenship: U. S. Citizen

Education Ph.D., Chemistry, The University of Chicago, 1988 M.S., Chemistry, The University of Chicago, 1986 B.S., Chemistry, University of Illinois at Chicago, 1983

Professional History Program Director, U. S. National Science Foundation, Chemistry Division, July 2011–present Professor of Chemistry, University of North Carolina at Chapel Hill, July 1999–present Associate Professor, University of North Carolina at Chapel Hill, July 1995–1999 Assistant Professor, University of North Carolina at Chapel Hill, July 1990–1995 NSF Postdoctoral Research Fellow, Division of Chemistry and Chemical Engineering, California Institute of Technology, October 1988–1990 Research Assistant, Department of Chemistry, The University of Chicago, 1984–1988

Honors and Awards J. W. Fulbright Senior Scholar, 2008-2009 Reynolds Research Leave Award (UNC), Fall 2008 Visiting Professor, International Tomography Center and Novosibirsk State University, Russia, 2008- 2009 Visiting Professor, UCLA Department of Chemistry and Biochemistry, 2005 Visiting Professor, Shizuoka University, Japan, 2004 "Geographica" profile, National Geographic Magazine, 2002 Sir Harold Thompson Award from Elsevier, 2000 Japan Society for the Promotion of Science Foreign Fellow, 1999 Visiting Professor, Tohoku University, Japan, 1999 NSF Young Investigator Award, 1993–1998 Dupont Junior Faculty Development Award, 1994 John Charles Morrow Junior Faculty Development Award, 1994 IBM Junior Faculty Development Award, 1991 National Science Foundation Postdoctoral Fellow, 1988-1990 NATO Advanced Study Institute Travel Award, “Reactive and Flexible Molecules in Liquids,” Nafplion, Greece, 1988 Bernard Smaller Award for Research in Magnetic Resonance, 1988 B. S. awarded with College Honors, 1983 Freshman Chemistry Award, American International College, 1980

Professional Affiliations American Chemical Society Inter-American Photochemical Society (currently Vice President) International EPR Society Alpha Chi Sigma Professional Chemistry Fraternity (Faculty Brother 1995-present, UNC Faculty Advisor 1996-1998)

Departmental Service Vice Chair, 1995-1998 (Publicity Director), 2000-2002 (VC at large) Undergraduate Studies Committee, 1992-1994 Graduate Studies Committee, 1995-1996

1 Faculty Search Committees: Materials Science, 1995, Inorganic, 2003, Analytical, 2002, Organic, 2007, Soft Matter, 2011, General Search 2011, Staff: Instrument Shop, 1993 Ph.D. and undergraduate Honors defense committees, 1990-present Reappointment for Junior Faculty Committee (Chair), 2010 Graduate Program Review Committee, 1993-1994 Bicentennial Planning Committee, 1992-1994 (Chair 1993-1994) Bicentennial Symposium Organizer, 1993 Personnel Procedures Committee, 1993-1994 Graduate Student Recruitment Committee, 1994-1996 Visiting Scholars and Adjunct Faculty Committee, 1990-present

University Service Study Abroad Advisory Committee, 2010–present Trans-Atlantic Science Student Exchange Program Faculty Advisor, 2010 Faculty Advisor, Global Medical Training, 2009–present Faculty Advisor, Alpha Kappa Delta Phi Sorority, 1996-present UNC Representative to Tradeline Science and Engineering Architects Meeting, October 2011 Faculty Advisor, UNC Women’s Rugby Team, 2000-2002 Project Uplift Participant, 1993-1998 Carolina Renaissance Days Speaker, 1997-1998 Freshman Camp Advisor, 1997-2000 Carolina Close-Up Speaker, 1995-1997 Carolina Summer Reading Program Discussion Leader, 2007 Morehead-Cain Scholars Luncheon Faculty Host, 1996-2002 Faculty Advisor, UNC ACS Student Affiliates, 1996-present Faculty Advisor, UNC Shotokan Karate Club, 2002-2003 Chemistry Representative for Undergraduate Admissions Committee, 1998-2000 Advisory Board, UNC Science and Mathematics Education Network, 1995-1998 UNC Representative, Coalition for National Science Funding, U.S. Capitol, 1997 University Liaison to Dupont Corp. and Rohm & Haas Corp., 1995-1996

Local and Regional Service North Carolina Museum of Life and Science Exhibit for "Science of Beer" evening, 2010-2011 UNC Science Expo exhibit on "Beer Photochemistry," 2010 Co–Coach, North Carolina Odyssey of the Mind Competition, Culbreth Middle School, 2007-2008 (3rd place finish in NC east regional round, out of 8 teams) Coach, North Carolina Odyssey of the Mind Competition, Culbreth Middle School, 2008-2009 (3rd place finish in NC east regional round, out of 4 teams) Alternate Councilor, NC Local Section of the ACS, 1993-1995 Local Organizer, Reaction Mechanisms Conference, UNC–Chapel Hill, 2008 Chair and Organizer, Southeastern Magnetic Resonance Conference, Chapel Hill NC, 1994

National Service Program Director, U. S. National Science Foundation, 2011-present Co-Vice Chair, Gordon Research Conference on Photochemistry, 2013 (co-Chair in 2015) Co–Chair, 2008 Gordon Research Conference on Electron Donor Acceptor Interactions Symposium Organizer, Rocky Mountain Analytical Conference, 2010 Symposium Organizer, Southeast Regional Meeting of the ACS, 2012 Participant, NSF Workshop on Physical Organic Chemistry, 1994 ACS Project SEED Preceptor, 1991, 2000, 2010, 2011 NSF East Asia Pacific Student Interaction Fellowship Panel, 2010–2011 NRC Fellowships Panel (NAS), 2009–present NRC Advisory Board on COBASE Program for U.S.–Russian Science Collaboration, 1998–2000 Editorial Advisory Board, Applied Magnetic Resonance, 2009–present Editorial Advisory Board, Organic and Biomolecular Chemistry, 2002–2006 Editorial Advisory Board, Accounts of Chemical Research, 1997–2000

2 Guest Editor, Journal of Physical Chemistry, 1993 (G. L. Closs Memorial Issue), 2010 (M. R. Wasielewski Festschrift)

Referee for Journal of the American Chemical Society, Accounts of Chemical Research, Chemical Reviews, Journal of Physical Chemistry, Journal of Chemical Physics, Langmuir, Macromolecules, Chemical Physics, Chemical Physics Letters, Organic Letters, Proceedings of the National Academy of Sciences of the USA, Journal of Photochemistry and Photobiology, Photochemical and Photobiological Sciences, Analytical Chemistry, Journal of Environmental Chemistry, Applied Magnetic Reosnance, Journal of Magnetic Resonance, Molecular Physics, Zeitschrift fur Physikalische Chemie, Journal of Polymer Science, Polymer.

Reviewer for NSF, NIH (Ad Hoc Study Section on Metallobioproteins), PRF, DOE, Civilian Research and Development Foundation, Fulbright Program (U.S. and Russian Programs), Third World Academy of Science, International Science Foundation, Research Corporation, Russian Foundation for Basic Research.

External reviewer for promotion to tenure or full professor for Clemson University, the University of Denver, the University of Cincinnati, the University of Alabama, St. Joseph's University (PA), North Dakota State University, and N. C. State University.

International Service Vice President (2012-2014) and President-Elect (for 2014-2016), Inter-American Photochemical Society Secretary, Inter–American Photochemical Society, 1994-1996 Member, International Committee on Spin Chemistry, 2001-present Chairman and Organizer, 8th International Symposium on Spin and Magnetic Field Effects in Chemistry and Related Phenomena (SCM2003), Chapel Hill, NC, 2003 Organizing Committee, SCM1996, Chicago IL Organizing Committee, SCM1994, Novosibirsk, Russia External Reviewer of Ph.D. Theses for the University of Ghent, Belgium, 2003, and Chennai University, Anna, India, 2008. External reviewer for promotion, Oxford University (UK), 2012

Research Accomplishments Publications - more than 100 since 1987 (see list below). Invited Lectures - more than 150 since 1990 (list available on request).

Mentoring Postdocs supervised: Yi Dang (Boron Biologicals) Shyamalie Ruberu (Cal-OSHA) Nikolai Avdievich (Yale University Staff) Ruixin Xu (GE) Hiroaki Yonemura (Kyushu University, Japan) Valery Tarasov (Semenov Institute of Chemical Physics, Moscow, Russia) Haruhiko Yashiro (Osaka University Staff) Ryan Macarthur (NIH Staff) Natalia Lebedeva (UNC Staff) David Zigler (UNC staff) Robert Schmidt (Cree Corp, RTP, NC)

Ph.D. Students supervised: Katerina Dukes (Rohm & Haas, now retired) Gregory Schulz (Bayer, now Dupont) Jonathan Ball (King & Spaulding patent law) Colin Burns (East Carolina University faculty) Christine Clancy (Duke University postdoc, now retired) Vanessa McCaffrey (Albion College faculty)

3 Elizabeth Harbron (College of William & Mary faculty) Chrystal Bruce (Erskine College, now John Carroll University faculty) Ryan White (high school chemistry teacher, Sao Paul, Brazil) Lauren Jarocha (current) Sooyeon Sim (current)

M.S. students supervised: Hall Moore (Magellan Laboratories) Emily Warmoth (Magellan Laboratories) Scott Jenkins (Argonne National Laboratory, public relations) Adam Prowatzke (Inver Hills Community College faculty) Thomas Chen (Ph.D. candidate, N.C. State University) Darlene Taylor (N. C. Central University faculty)

Undergraduates supervised: I have mentored more than 50 undergraduate researchers. Several are now notable faculty members, e.g., Heather Maynard at UCLA, Chris Breivogel at Campbell University. I have published peer-reviewed papers with 13 of these undergraduate students, some of them more than once.

Funding External Federal Funding NSF Postdoctoral Fellowship, 1988-1990, $64,000 NSF Postdoctoral Fellowship Startup Award, 1990, $32,000 NSF Instrumentation Award 1991, $93,497 NSF Single Investigator Award, 1992, $271,500 NSF Young Investigator Award, 1993, $405,900 ($312,500 from agency, $93,400 in matching funds from various private sources) NSF Single Investigator Award, 1992, $354,404 NSF Instrumentation Award, 1997, $125,000 ($102,500 from agency, $22,500 in matching funds from UNC) NSF Single Investigator Award, 1998, $365,000 NSF 2002 Single Investigator Award, $465,000 NSF Single Investigator Award, 2005, $435,606 NSF Supplemental Award, 2006, $16,380 NSF Single Investigator Award 2008, $497,000 NSF Single Investigator Award 2011, $646,000 C-CNE UNC Cancer Center (NCI-NIH Center) Pilot Project Award, 2011, $50,000 Total: $3,821,287

External Collaborative Federal Funding (my share as PI only, unless otherwise indicated) UNC Energy Frontiers Research Center on Solar Fuels (DOE), 2009-2014, $240,420 NSF Science & Technology Center, 2000-2001, $90,000 NSF Science & Technology Center, 2003-2005, $125,000 NSF Consortium for High Field Time-Resolved EPR Spectroscopy (NHFML), $500,000 total for instrumentation only (I raised matching UNC matching funds of $50,000) Total: $505,420

External Private Foundation Funding PRF Type G, 1991, $21,000 PRF Type AC, 1993, $50,000 PRF Type AC, 1997, $50,000 Civilian Research and Development Foundation, 1999, $50,000 J. W. Fulbright Scholar Award, 2008, $35,000 J. W. Fulbright Scholar Follow-up Award, 2009, $5,000 Total: $211,000

4 External Industry Funding Eastman Chemical 1996, $25,000 Allied-Signal Corp., 1997, $67,995 Rohm & Haas Corp., 1997, $55,455 Dow–Corning Corporation, 2008, $3,000 Becton-Dickinson Co. 2011, $4,500 BASF Corp. (current), $55,000 Total: $205,950

Internal UNC Funding 3 Junior Faculty Development Awards 1 Reynolds Faculty Research Leave 2 University Research Council Awards Total: $74,000

Total funding acquired 1988-present (not including pending awards): $4,822,657

Collaborations At UNC: I have published with UNC colleagues Joe DeSimone, Tom Meyer, Rich Linton, Max Berkowitz, Andrew Moran, John Papanikolas, Wenbin Lin, and Royce Murray. In other UNC Departments I have current collaborations with Paul Dayton, Channing Dur, Ed Collins, and Janice Jones.

Former and present collaborations outside UNC: Josef Michl (University of Colorado) Miguel Garcia–Garibay (UCLA) Nick Turro (Columbia University) Jean Hatcher (Duke University) Matthew Platz (Ohio State University) Peter Hore (Oxford University, UK) Francesca Ottaviani (University of Urbino, Italy) Seigo Yamauchi (Tohoku University, Japan) Denis DeKeukeleire (University of Gent, Belgium) Martin Goez (University of Halle, Germany) Georg Gescheidt (TU-Graz, Austria) Stephan Langen (TU-Graz, Austria) Jaime Escalante (University of Morelos, Mexico) Monica Gonzales (INIFTA, La Plata, Argentina) Carmen Guedes (University of Londrina, Brazil) Miguel Neumann (USP Sao Carlos, Brazil) Cornelia Bohne (University of Victoria, Canada) Ksenija Glusac (Bowling Green State University) Rajendra Rathore (Marquette University) Dave Shultz (N. C. State University) Michael Therien (Duke University) Kenneth Jordan (University of Pittsburgh) James Barborak (UNC-Greensboro) Kenneth Wagener (University of Florida) Lowell Kispert (University of Alabama)

Member, Consortium for High Field Time-Resolved EPR Spectroscopy (Funded by NSF at NHFML), 1996-2001 (with Louis-Claude Brunel, Mike Bowman, Alex Angerhofer, and James Norris)

Visiting Senior Scientists to my Laboratory Dr. Yura Tsentalovich (ITC Novosibirsk) Dr. Elena Bagryanskaya (ITC Novosibirsk) Dr. Elena Gorelik (ITC Novosibirsk)

5 Dr. Alexandra Yurkovskaya (ITC Novosibirsk) Dr. Hiroaki Yonemura (Kyushu University, Japan) Dr. Valery Tarasov (Institute of Chemical Physics, Moscow) Dr. Paula Caregnato (INIFTA, La Plata, Argentina) Ms. Josy Osajima (USP Sao Carlos, Brazil) Ms. Fanny Cabrera (University of Morelos, Mexico)

Teaching Courses taught at the graduate level: Reaction Mechanisms (8), Organic Spectroscopy (7), Photochemistry Special Topics (1), Stereochemistry Special Topics (1), Organic Seminar Program (4)

Courses taught at the undergraduate level: Honors Organic I (2), Honors Organic II (1), Organic I (11), Organic II (5), General Chemistry II (1), General Chemistry I (2), First Year Seminar (4)

Manuscript Reviewer for the following textbooks: Brown, Foote and Iverson, Organic Chemistry, 3rd and 4th editions Bruice, Organic Chemistry, 4th, 5th, 6th and 7th editions Brown, LeMay and Bursten, General Chemistry, 10th edition Crews, Rodriguez and Jaspars, Organic Structural Analysis 1st and 2nd editions Karty, Gooch & Craig, Organic Chemistry, 1st edition

Accuracy Checker for the following textbooks: Bruice, Organic Chemistry, 5th edition Bruice, Essential Organic Chemistry, 2nd edition

Member, McGraw-Hill Advisory Board for Smith, Organic Chemistry, 2003-2004 Prospectus reviewer for Oxford University Press Organic Chemistry Prospectus reviewer for Pike, “Fourth Course” General and Inorganic Chemistry

6 Publication List

106. "Structural Studies of Vesicle/Micelle Phase Changes Using Stable and Transient Radicals," Lauren E. Jarocha, Valery Tarasov, and Malcolm D. E. Forbes, Langmuir, 2012, in preparation.

105. “A Little Spin on the Side: Solvent– and Temperature–Switchable Paramagnetism in II 2+ [Ru (bpy)2(phendione)] ," Caleb Kent, Robert D. Schmidt, Javier J. Concepcion, Thomas J. Meyer, Wenbin Lin, and Malcolm D. E. Forbes, Nature Chemistry, 2012, submitted.

104. “Time-resolved EPR Spectroscopy of Flexible Biradicals,” Malcolm D. E. Forbes, RSC Specialist Periodical Reports, 2012, in press.

103. “Spin Trapping Studies of Amine–Stabilized Trialkylborane Free Radical Initiator Systems: Kinetics and Mechanism,” Anne C. Moran, Natalia V. Lebedeva, Sabine Richert, and Malcolm D. E. Forbes, Appl. Magn. Resonance 2011, 41, 295-303.

102. “Multifrequency TREPR Investigation of Excited State ZnTPP/Nitroxide Radical Complexes,” Valery F. Tarasov, Saiful S. M. Islam, Yasunori Ohba, Malcolm D. E. Forbes, and Seigo Yamauchi, Appl. Magn. Resonance 2011, 41, 175-193.

101. “Concerted Electron-Proton Transfer in the Optical Excitation of Hydrogen Bonded Dyes,” Brittany C. Westlake, M. Kyle Brennaman, Javier J. Concepcion, Jared J. Paul, Stephanie E. Bettis, Shaun D. Hampton, Stephen R. Miller, Natalia Lebedeva, Malcolm D. E. Forbes, Andrew M. Moran, Thomas J. Meyer and John M. Papanikolas, Proc. Nat. Acad. Sci. USA, 2011, 108, 8554–8558.

100. “Electrostatic Control of Spin Exchange Between Mobile Spin–Correlated Radical Pairs Created in Micellar Solutions,” Paula Caregnato, Lauren E. Jarocha, Hali S. Esinhart, Natalia V. Lebedeva, Valery F. Tarasov and Malcolm D. E. Forbes, Langmuir, 2011, 27, 5304–5309.

99. “Structural and pH Dependence of Excited State PCET Reactions Involving Reductive Quenching of II 2+ the MLCT Excited State of [Ru (bpy)2(bpz)] (PF6)2 by Hydroquinones,” Natalia V. Lebedeva, Robert D. Schmidt, Javier J. Concepcion, M. Kyle Brennaman, Ian N. Stanton, Michael J. Therien, Thomas J. Meyer, and Malcolm D. E. Forbes, J. Phys. Chem. A, 2011, 115, 3346–3356.

98. “Nitronyl-Nitroxide Radicals as Organic Memory Elements with Both n- and p-type Properties,” Junghyun Lee, Sangkwan Kim, Gyeong Sook Bang, Eunkyo Lee, David A. Shultz, Robert D. Schmidt, Malcolm D. E. Forbes and Hyoyoung Lee, Angew. Chem. Intl. Ed. Eng. 2011, 50, 4414–4418.

97. “Supramolecular Photochemistry in β–Cyclodextrin Hosts: A TREPR, NMR, and CIDNP Investigation,” Olesya A. Krumkacheva, Vitaly R. Gorelik, Elena V. Bagryanskaya, Natalia V. Lebedeva and Malcolm D. E. Forbes, Langmuir, 2010, 26, 8971–8980.

96. “Chemisorbed Thiols on Silica Particles: Characterization of Reactive Sulfur Species,” Paula Caregnato, Malcom D. E. Forbes, Delia B. Soria, Daniel O. Martire, and Monica C. Gonzalez J. Phys. Chem. C, 2010, 114, 5080–5087.

95. “The Missing Link Between Molecular Triplets and Spin–Polarized Free Radicals: Room Temperature Triplet States of Nanocrystalline Radical Pairs,” Lebedeva, N. V.; Tarasov, V. F.; Resendiz, M. J. E.; Garcia–Garibay, M. A.; White, R. C.; Forbes, M. D. E. J. Am. Chem. Soc. 2010, 132, 82–84.

94. “Acrylic Polymer Radicals: Structural Characterization and Dynamics”, Lebedeva, N. V.; Forbes, M. D. E., in Carbon–Centered Radicals and Radical Cations, M.D.E. Forbes (ed.), Wiley Series on Reactive Intermediates in Chemistry and Biology, Volume 3 (Wiley, New York) 2010, pp. 323–355.

7 93. “A Brief History of Carbon Radicals,” Forbes, M. D. E., in Carbon–Centered Radicals and Radical Cations, M.D.E. Forbes (ed.), Wiley Series on Reactive Intermediates in Chemistry and Biology, Volume 3 (Wiley, New York), 2010, pp. 1–7.

92. “Solvent and Wavelength Dependent Photochemistry of 1,3–Dihydroxyacetone Studied by TREPR: Implications for Commercial Sunless Tanning Lotions,” Natalia V. Lebedeva, Thomas K. Chen, and Malcolm D. E. Forbes, Appl. Magn. Resonance, 2009, 38, 155–166.

91. “Carbene Spin Multiplicity in Solution Probed Using Time–Resolved EPR Spectroscopy,” Jin Wang, Natalia V. Lebedeva, Matthew S. Platz, and Malcolm D. E. Forbes, J. Mex. Chem. Soc. 2009, 53, 163–168.

90. “Inside Degradable Plastics,” Malcolm D. E. Forbes, Vanessa P. McCaffrey, and Elizabeth J. Harbron, in “The Treasures of Eureka, Volume 1: Electron Paramagnetic Resonance. From Fundamental Research to Pioneering Applications & Zavoisky Award,” K. A. Salikhov, Ed., AXAS Publishing (Auckland, NZ), 2009, pp. 150–151.

89. “Radical Pairs with Memory of Chirality for the Enantiospecific Synthesis of Adjacent Stereogenic Quaternary Centers in Solution,” Marino J. E. Resendiz, Farnosh Family, Scott Rodriguez, Kerrian Fuller, Luis M. Campos, Saeed I. Khan, Natalia V. Lebedeva, Malcolm D. E. Forbes and Miguel A. Garcia– Garibay, J. Am. Chem. Soc., 2009, 131, 8425–8433.

88. “Time–Resolved EPR Investigation of Potential Model Systems for Acrylate Polymer Main Chain Radicals Based on Esters of Kemp’s Tri–Acid,” Natalia V. Lebedeva, Elena V. Gorelik, Damaris Magnus– Aryitey, Terence E. Hill, and Malcolm D. E. Forbes, J. Phys. Chem. B 2009, 113, 6623–6629.

87. “Degradation of Human Eye Lens Filter Molecules and Adducts: A Mechanistic Study,” Lyudmila V. Kopylova, Olga A. Snytnikova, Malcolm D. E. Forbes, and Yuri P. Tsentalovich, Org. Biomol. Chem., 2009, 14, 2958–2966.

86. “Time–Resolved EPR Studies of Main Chain Radicals from Acrylic Polymers. The Poly(acrylic acid)s,” Natalia V. Lebedeva and Malcolm D. E. Forbes, Macromolecules 2008, 41, 1334–1340.

85. “Model Systems for Poly(Acrylic Acid) Main Chain Radicals Based on the Kemp’s Tri–Acid Framework,” Natalia V. Lebedeva, Elena V. Gorelik, Adam M. Prowatzke and Malcolm D. E. Forbes, J. Phys. Chem. B 2008, 112, 7574–7580.

84. “Initiator Addition to Methyl Methacrylate Studied in Liquid and Supercritical Carbon Dioxide,” Malcolm D. E. Forbes and Haruhiko Yashiro, Macromolecules 2007, 40, 1460–1465.

83. “On the Electron Spin Polarization Observed in TREPR Experiments Involving Hydroxyl and Sulfate Radicals,” Forbes, M. D. E.; Lebedeva, N. V.; White, R. C.; Chen, T. K.; MacArthur, R.; Caregnato, P.; and Hill, T. E., Mol. Phys. 2007, 105, 2127–2136.

82. “Excited State Quenching by Coupled Electron Proton Transfer (EPT),” Javier J. Concepcion, M. Kyle Brennaman, Jeremy R. Deyton, Natalia V. Lebedeva, Malcolm D. E. Forbes, John M. Papanikolas and Thomas J. Meyer, J. Am. Chem. Soc. 2007, 129, 6968–6969.

81. “Photo–Redox Chemistry of AOT: Electron Transfer and Hydrogen Abstraction in Microemulsions Involving the Surfactant” R. C. White, V. R. Gorelik, E. G. Bagryanskaya and Malcolm D. E. Forbes, Langmuir 2007, 23, 4183–4191.

80. "Flexible Biradicals in Liquid and Supercritical Carbon Dioxide: The Exchange Interaction, Chain Dynamics, and a Comparison with Conventional Solvents," Malcolm D. E. Forbes, Katerina E. Dukes, Nikolai I. Avdievich, Elizabeth J. Harbron and Joseph M. DeSimone, J. Phys. Chem. A 2006, 110, 1767– 1774.

8 79. “Oximetry of Oxygen Supersaturated Solutions Using Nitroxides as EPR Probe,” Alberto Moscatelli, Francesca Ottaviani, Nicholas J. Turro, Thomas K. Chen and Malcolm D. E. Forbes, J. Phys. Chem. B 2006, 110, 7574–7578.

78. “Spin–Polarized Peroxyl Radical Adducts Formed from the Addition of Oxygen to Amino Acid Radicals,” Ryan C. White and Malcolm D. E. Forbes, Org. Lett. 2006, 8, 6027–6030.

77. “Photochemical and Thermal Reactivity of Kynurenine,” Yuri P. Tsentalovich, Olga A. Snytnikova, Malcolm D. E. Forbes, Elena I. Chernyak and Sergey V. Morozov, Exp. Eye. Res. 2006, 83, 1439–1445.

76. “Photo–oxidation of Diglycine in Confined Media. Relaxation of Longitudinal Magnetization in Spin Correlated Radical Pairs,” Valery F. Tarasov, Ryan C. White and Malcolm D.E. Forbes, Spectrochimica Acta Part A 2006, 63, 776–783.

75. “Photooxidation of Diglycine in Confined Media. Application of the Microreactor Model for Spin– Correlated Radical Pairs in Reverse Micelles and Water–in–Oil Microemulsions,” Ryan C. White, Valery F. Tarasov, and Malcolm D. E. Forbes, Langmuir 2005, 21, 2721–2727.

74. “Time–Resolved EPR Studies of Main Chain Radicals from Acrylic Polymers. Dynamic Effects Due to Conformational Motion”, Vanessa P. McCaffrey, Elizabeth J. Harbron and Malcolm D. E. Forbes, Macromolecules, 2005, 38, 3342–3350.

73. “Time–Resolved EPR Studies of Main Chain Radicals from Acrylic Polymers. Effects of Tacticity, Solvent, and Side Group Structure on Chain Stiffness”, Vanessa P. McCaffrey, Elizabeth J. Harbron and Malcolm D. E. Forbes, J. Phys. Chem. B 2005, 109, 10686–10694.

72. “Structure and Dynamics of Macromolecular Free Radicals”, Malcolm D. E. Forbes, Vanessa P. McCaffrey, and Elizabeth J. Harbron, The Spectrum 2005, 18, 10–16.

71. “EPR Spin Probe Study of Carbon Dioxide Induced Polymer Plasticization”, Elizabeth J. Harbron, W. Clayton Bunyard and Malcolm D. E. Forbes, J. Poly. Sci. B: Polym. Phys., 2005, 43, 2097–2108.

70. “Chemically Induced Multiplet Electron–Nuclear Polarization of Micellized Radical Pairs in Low Magnetic Fields”, Elena Bagryanskaya, Matvey Fedin and Malcolm D. E. Forbes, J. Phys. Chem. A 2005, 109, 5064–5069.

69. “Chemically Induced Dynamic Electron Spin Polarization–Detected Energy Transfer. Substrate Size Effects and Solvent Dependence,” Vanessa P. McCaffrey and Malcolm D. E. Forbes J. Phys. Chem. A, 2005, 109, 4891–4898.

68. “Methionine Radical Cation: Structural Studies as a Function of pH Using X– and Q–Band Time– Resolved Electron Paramagnetic Resonance Spectroscopy”, Haruhiko Yashiro, Ryan C. White, Alexandra V. Yurkovskaya, and Malcolm D. E. Forbes, J. Phys. Chem. A 2005, 109, 5855–5864.

67. “Fate of Flavins in Sensitized Photodegradation of Isohumulones and Reduced Derivatives: Studies on Formation of Radicals via EPR Combined with Detailed Product Analyses”, Arne Heyerick, Kevin Huvaere, Denis De Keukeleire, and Malcolm D. E. Forbes, Photochem. Photobiol. Sci. 2005, 5, 412–419.

66. “Time–Resolved EPR Studies of Main Chain Radicals from Acrylic Polymers. Structural Characterization at High Temperatures”, Vanessa P. McCaffrey and Malcolm D. E. Forbes, Macromolecules 2005, 38, 3334–3341.

65. “Photochemistry of Kynurenine, a Tryptophan Metabolite: Properties of the Triplet State”, Yuri P. Tsentalovich, Olga A. Snytnikova, Peter S. Sherin and Malcolm D. E. Forbes, J. Phys. Chem. A 2005, 109, 3565–3568.

9 64. “Dynamics of Spin–Correlated Radical Pairs in Non–Ionic Surfactant Solutions”, Erin E. Chaney and Malcolm D. E. Forbes, J. Phys. Chem. B 2003, 107, 4464–4469.

63. Tarasov, V. F.; Yasina, L. L.; Aliev, I. I; Wasserman, A. M.; Forbes, M. D. E. "Comparison of dynamic parameters extracted from ESR spectra of spin correlated radical pairs and ESR spectra of spin probes in alkylsulfate micelles" Khim. Phiz. 2002, 21, 107–112.

62. “Molecular Dynamics Simulations of Sodium Dodecyl Sulfate Micelle in Water: The Behavior of Water”, Chrystal D. Bruce, Sanjib Senepati, Max L. Berkowitz, Lalith Perera, and Malcolm D.E. Forbes, J. Phys. Chem. B 2002, 106, 10902–10907.

61. “Time resolved CIDNP study of electron transfer reactions in proteins and model compounds,” Morozova, O. B.; Yurkovskaya, A. V.; Tsentalovich, Y. P.; Forbes, M. D. E.; Hore, P. J.; Sagdeev, R. Z. Mol. Phys. 2002, 100, 1187–1195.

60. “Theoretical and experimental studies of chemically induced electron–nuclear polarization in low magnetic fields,” Fedin, M. V.; Yashiro, H.; Purtov, P. A.; Bagryanskaya, E. G.; Forbes, M. D. E. Mol. Phys. 2002, 100, 1171–1180.

59. “Spin and Molecular Dynamics in Acyl–Containing Biradicals: Time–Resolved Electron Paramagnetic Resonance and Laser Flash Photolysis Study”, Yuri P. Tsentalovich, Malcolm D.E. Forbes, Olga B. Morozova, Igor A. Plotnikov, Vanessa P. McCaffrey, and Alexandra V. Yurkovskaya, J. Phys. Chem. A 2002, 106, 7121–7129.

58. “Chemically Induced Electron–Nuclear Spin Polarization in Zero and Very Low Magnetic Fields”, Elena G. Bagryanskaya, Haruhiko Yashiro, Matvei Fedin, Peter Purtov, and Malcolm D.E. Forbes, RIKEN Review 2002, 44, 116–118.

57. “Spin Relaxation in Acyl Radicals Measured Using Spin Correlated Radical Pair (SCRP) Polarization in Flexible Biradicals”, Yuri P. Tsentalovich and Malcolm D.E. Forbes, Mol. Phys. 2002, 100, 1209–1213.

56. “Molecular Dynamics Simulation of Sodium Dodecyl Sulfate Micelle in Water: Micellar Structural Characteristics and Counterion Distribution”, Chrystal D. Bruce, Max L. Berkowitz, Lalith Perera, and Malcolm D.E. Forbes, J. Phys. Chem. B 2002, 106, 3788–3793.

55. “Chemically Induced Multiplet Electron–Nuclear Polarization in Zero and Low Magnetic Fields”, Elena G. Bagryanskaya, Haruhiko Yashiro, Matvei Fedin, Peter Purtov, and Malcolm D.E. Forbes, J. Phys. Chem. A 2002, 106, 2820–2828.

54. “Time–Resolved CIDNP Study of Intramolecular Charge Transfer in the Dipeptide Tryptophan– Tyrosine”, Olga B. Morozova, Alexandra V. Yurkovskaya, Yuri P. Tsentalovich, Malcolm D.E. Forbes, and Renad Z. Sagdeev, J. Phys. Chem. B 2002, 106, 1455–1460.

53. “Study of the Rotational Barrier in the Hindered Bisphenoxyl A Radical”, Christine M.R. Clancy and Malcolm D.E. Forbes, J. Phys. Chem. A 2001, 105, 9869–9872.

52. “Neutral Peptide Biradicals Formed by Dissociative Electron Transfer”, Colin S. Burns, Lakecia Rochelle, and Malcolm D.E. Forbes, Organic Letters 2001, 3, 2197–2200.

51. "Mechanism for Formation of the Lightstruck Flavor in Beer Revealed by Time–Resolved Electron Paramagnetic Resonance", Colin S. Burns, Arne Heyerick, Denis De Keukeleire, and Malcolm D. E. Forbes, Chemistry—A European Journal 2001, 7, 4553–4561.

50. "Chemically–Induced Nuclear and Electron Polarization (CIDNP and CIDEP)", Elizabeth J. Harbron and Malcolm D. E. Forbes, Encyclopedia of Chemcial Physics and Physical Chemistry, Institute of Physics Publishing, Chapter B1.16, 2001, pp. 1389–1417.

49. "Stereochemistry and Pseudo–Symmetries in Main Chain Polymeric Free Radicals", Elizabeth J. Harbron, Vanessa P. McCaffrey, Ruixin Xu and Malcolm D. E. Forbes, J. Am. Chem. Soc. 2000, 122, 9182–9188.

48. "Energy Transfer Studied Using Spin Polarized Free Radicals. Effect of Substrate Structure and a Comparison Between Micellar Confinement and Free Solution", Vanessa P. McCaffrey and Malcolm D.E. Forbes, Tetrahedron 2000, 56, 6991–6997.

47. "Time–Resolved Electron Spin Resonance of Spin Correlated Micelle Confined Radical Pairs: Shape of the Anti–phase Structure", Valery F. Tarasov and Malcolm D.E. Forbes, Spectrochimica Acta Part A 2000, 56, 245–263.

46. "Theoretical and Experimental Stimulated Nuclear Polarization Investigation of Consecutive Biradicals", N.V. Lebedeva, E.G. Bagryanskaya, I.V. Koptyug, R.Z. Sagdeev, M.D.E. Forbes, Chem. Phys. Letters 1999, 308, 295–302.

45. "Time–Resolved Electron Paramagnetic Resonance Study of Photoionization of Tyrosine Anion in Aqueous Solution", Christine M. R. Clancy and Malcolm D. E. Forbes, Photochem. Photobiol. 1999, 69, 16–21.

44. "Time–Resolved EPR Studies in Organic Photochemistry", Christine M. R. Clancy, Valery F. Tarasov, and Malcolm D. E. Forbes, Specialist Reports of the Royal Society of Chemistry, EPR Series 1998, 16, 50– 78.

43. "Gateway Reactions to Diverse, Poly–functional Monolayer–Protected Gold Clusters", Allen C. Templeton, Michael J. Hostetler, Emily K. Warmoth, Shaowei Chen, Chris M. Hartshorn, Vijay M. Krishnamurthy, Malcolm D.E. Forbes, and Royce W. Murray, J. Am. Chem. Soc. 1998, 120, 4845–4849.

42. "Influence of Molecular Structure on the Rate of Intersystem Crossing in Flexible Biradicals", Yuri P. Tsentalovich, Olga B. Morozova, Nikolai I. Avdievich, Gennady S. Ananchenko, Alexandra V. Yurkovskaya, Jonathan D. Ball, and Malcolm D. E. Forbes, J. Phys. Chem. A 1997, 101, 8809–8816.

41. "Study of Consecutive Biradicals from 2–Hydroxy–2,12–dimethylcyclododecanone by TR–CIDNP, TREPR, and Laser Flash Photolysis", Olga B. Morozova, Alexandra V. Yurkovskaya, Yuri P. Tsentalovich, Renad Z. Sagdeev, Tina Wu, and Malcolm D. E. Forbes, J. Phys. Chem. A 1997, 101, 8803– 8808.

40. "Flow System and 9.5 GHz Microwave Resonators for Time–Resolved and Steady–State Electron Paramagnetic Resonance Spectroscopy in Compressed and Supercritical Fluids", Katerina E. Dukes, Elizabeth J. Harbron, Malcolm D. E. Forbes, and Joseph M. DeSimone, Rev. Sci. Instrum. 1997, 68, 2505– 2510.

39. "Time–Resolved EPR Study of a 1,9– Flexible Biradical Dissolved in Liquid Carbon Dioxide. Observation of a New Spin Relaxation Phenomenon: Alternating Intensities in Spin–Correlated Radical Pair Spectra", Nikolai I. Avdievich, Katerina E. Dukes, Malcolm D. E. Forbes and Joseph M. DeSimone, J. Phys. Chem. A 1997, 101, 617–621.

38. "Time–Resolved (CW) Electron Paramagnetic Resonance Spectroscopy. An Overview of the Technique and its Use in Organic Photochemistry", Malcolm D. E. Forbes, Photochem. Photobiol. 1997, 65, 73–81.

37. "Chain Dynamics Cause the Disappearance of Spin–Correlated Radical Pair Polarization in Flexible Biradicals", Malcolm D. E. Forbes, Nikolai I. Avdievich, Gregory R. Schulz, and Jonathan D. Ball, J. Phys. Chem. 1996, 100, 13887–13891.

11 36. "Micelles Formed from Photochemically Active Amphiphiles: Structural Characterization by Small– Angle Neutron Scattering," Gregory R. Schulz, Delia Chillura Martino, Roberto Triolo, and Malcolm D. E. Forbes, J. Mol. Struct. 1996, 383, 191–196.

35. "Unusual Dynamics of Micellized Radical Pairs Generated from Photochemically Active Amphiphiles", Malcolm D. E. Forbes, Gregory R. Schulz, and Nikolai I. Avdievich, J. Am. Chem. Soc. 1996, 118, 10652–10653.

34. "In Search of Through–Solvent Electronic Coupling in Flexible Biradicals", Malcolm D. E. Forbes, Jonathan D. Ball, and Nikolai I. Avdievich, J. Am. Chem. Soc. 1996, 118, 4707–4708.

33. "Useful Model Systems for the Study of SRN1 Chemistry in the Synthesis of Poly(arylene ether ketone)s", Katerina E. Dukes, Malcolm D. E. Forbes, Antony S. Jeevarajan, Anna M. Belu, Joseph M. DeSimone, Richard W. Linton, and Valerie V. Sheares, Macromolecules 1996, 29, 3081–3089.

32. "Photoionization of N,N,N’,N’–Tetramethylphenylenediamine Studied by Q–Band Time–Resolved EPR Spectroscopy. Separation of Singlet and Triplet Ionization Channels", Nikolai I. Avdievich, Antony S. Jeevarajan, and Malcolm D. E. Forbes, J. Phys. Chem. 1996, 100, 5334–5342.

31. "Strong Modulation of the Exchange Interaction in a Spin–Polarized, Aryl Ether–Linked 1,14– Biradical", Nikolai I. Avdievich and Malcolm D. E. Forbes, J. Phys. Chem. 1996, 100, 1993–1995.

30. "Role of Excited Singlet State in the Photooxidation of Carotenoids: A Time–Resolved Q–Band EPR Study", Antony S. Jeevarajan, Lowell D. Kispert, Nikolai I. Avdievich, and Malcolm D. E. Forbes, J. Phys. Chem. 1996, 100, 669–671.

29. "Time–Resolved Electron Paramagnetic Resonance Spectroscopy as a Structural and Mechanistic Tool in Organic Chemistry", Malcolm D. E. Forbes, The Spectrum 1995, 8, 1, 3–8.

28. "Site–Selective Photochemistry in an Alternating 2–Norbornyl–CO Copolymer: Importance of Stereoelectronic Effects", Malcolm D. E. Forbes, Shiyamalie R. Ruberu, Dana Nachtigallova, Kenneth D. Jordan, and James C. Barborak, J. Am. Chem. Soc. 1995, 117, 3946–3951.

27. "Dynamic Effects in Spin–Correlated Radical Pair Theory: J Modulation and a New Look at the Phenomenon of Alternating Line Widths in the EPR Spectra of Flexible Biradicals", Nikolai I. Avdievich and Malcolm D. E. Forbes, J. Phys. Chem. 1995, 99, 9660–9667.

26. "Low Temperature Disappearance of Spin Correlation in Flexible 1,n–Biradicals (N = 22, 24, 26)", Malcolm D. E. Forbes and Gregory R. Schulz, J. Am. Chem. Soc. 1994, 116, 10174–10177.

25. "Dynamics of Spin–Polarized Radical Pairs at the Solid/Solution Interface", Malcolm D.E. Forbes, Shiyamalie R. Ruberu and Katerina E. Dukes, J. Am. Chem. Soc. 1994, 116, 7299–7307.

24. "Photodegradation of Alternating p–tButylstyrenyl and exo–Norbornyl–CO Copolymers Studied by Multiple Frequency Time–Resolved EPR Spectroscopy," Malcolm D.E. Forbes, James C. Barborak, Katerina E. Dukes, and Shiyamalie R. Ruberu, Macromolecules 1994, 27, 1020–1026.

23. "Time–Resolved EPR Spectroscopy of Short Biradicals (1,3– to 1,8–) in Solution. The Inter– Connecting Roles of the External Magnetic Field, the Dipolar Coupling, the Exchange Interaction and Molecular Motion in the Spin Polarization and Relaxation Mechanisms," Malcolm D.E. Forbes and Shiyamalie R. Ruberu, J. Phys. Chem. 1993, 97, 13223–13233.

22. “Preface to G. L. Closs Memorial Issue” (as Guest Editor), J. Phys. Chem. 1993, 97, 13030.

12 21. "Time Resolved Electron Paramagnetic Resonance Spectroscopy in the Q–Band Microwave Region. 2. Magnetic Field Effects on CIDEP in Radicals, Biradicals, and Spin–Correlated Radical Pairs," Malcolm D.E. Forbes, Zeitschr. Phys. Chem. 1993, 182, 63–76.

20. "CIDEP Studies of Carotenoid Radical Cations," Anthony S. Jeevarajan, Mohammed Khaled, Malcolm D.E. Forbes, and Lowell D. Kispert, Zeitschr. Phys. Chem. 1993, 182, 51–61.

19. "Acyclic Diene Metathesis (ADMET) Polymerization: The Synthesis of Unsaturated Polyketones," Kenneth B. Wagener, Jasson T. Patton, Malcolm D.E. Forbes, Tanya L. Myers, and Heather D. Maynard, Polym. Intl. 1993, 32, 411–415.

18. "Macrocycle Syntheses: Cyclic Ketones, Keto–alkenes, Diketones and Dienes of Ring Size C21 to C26," Malcolm D.E. Forbes and Yi Dang, Org. Prep. Proc. Intl. 1993, 25, 309–314.

17. "Quantitative EPR Measurement of Long Distance Electronic Interactions in Two Geometric Isomers of an Unsaturated Biradical," Malcolm D.E. Forbes and Kanku Bhagat, J. Am. Chem. Soc. 1993, 115, 3382–3383.

16. "A Fast 35 GHz Time Resolved EPR Apparatus," Malcolm D.E. Forbes, Rev. Sci. Instrum. 1993, 64, 397–402.

15. "The Effect of System Spacers on Exchange Couplings and End to End Encounter Rates in Flexible Biradicals," Malcolm D.E. Forbes, J. Phys. Chem. 1993, 97, 3396–3400.

14. "The Effect of Localized Unsaturation on the Scalar Exchange Coupling in Flexible Biradicals," Malcolm D.E. Forbes, J. Phys. Chem. 1993, 97, 3390–3395.

13. "The Temperature Dependence of the Exchange Coupling in Polymethylene Biradicals. Conclusions Regarding the Mechanism of the Coupling," Malcolm D.E. Forbes, Gerhard L. Closs, Paloma Calle, and Pennathur Gautam, J. Phys. Chem. 1993, 97, 3384–3389.

12. "The Solution EPR Spectra of Reactive 1,5– and 1,6– Biradicals," Malcolm D.E. Forbes, J. Am. Chem. Soc. 1993, 115, 1613–1615.

11. "Solvent–Free Cyclization of Linear Dienes Using Olefin Metathesis and the Thorpe–Ingold Effect", Malcolm D.E. Forbes, Jasson T. Patton, Tanya L. Myers, Heather D. Maynard, Dennis W. Smith, Gregory R. Schulz, and Kenneth B. Wagener, J. Am. Chem. Soc. 1992, 114, 10978–10980.

10. "Time Resolved Electron Paramagnetic Resonance Spectroscopy in the Q–Band Microwave Region," Malcolm D.E. Forbes, J. Phys. Chem. 1992, 96, 7836–7839.

9. "Spin and Reaction Dynamics in Flexible Polymethylene Biradicals as Studied by EPR, NMR, Optical Spectroscopy and Magnetic Field Effects. Measurements and Mechanisms of Scalar Electron Spin–Spin Coupling," Gerhard L. Closs, Malcolm D.E. Forbes and Piotr Piotrowiak, J. Am. Chem. Soc. 1992, 114, 3285–3294.

8. "Biradicals and Spin–Correlated Radical Pairs Anchored to SiO2 Surfaces: Probing Diffusion at the Solid/Solution Interface," Malcolm D.E. Forbes, Tanya L. Myers, Katerina E. Dukes, and Heather D. Maynard, J. Am. Chem. Soc. 1992, 114, 353–354.

7. "Time Resolved Electron Paramagnetic Resonance Spectroscopy of Organic Free Radicals Anchored to SiO2 Surfaces," Malcolm D.E. Forbes, Katerina E. Dukes, Tanya L. Myers, Heather D. Maynard, Christopher S. Breivogel, and Heather B. Jaspan, J. Phys. Chem. 1991, 95, 10547–10549.

13 6. "Simple Modification of Varian E–Line Microwave Bridges for Fast Time–Resolved EPR Spectroscopy," Malcolm D.E. Forbes, John Peterson, and Christopher S. Breivogel, Rev. Sci. Instrum. 1991, 66, 2662–2665.

5. "EPR Spectroscopy of Electron Spin Polarized Biradicals in Liquid Solutions. Technique, Spectral Simulation, Scope and Limitations," Gerhard L. Closs and Malcolm D. E. Forbes, J. Phys. Chem. 1991, 95, 1924–1933.

4. "Real Time Measurements of Interfacial Charge Transfer Rates at Silicon/Liquid Junctions", Malcolm D.E. Forbes and Nathan S. Lewis, J. Amer. Chem. Soc. 1990, 112, 3682–3683.

3. "EPR Study of Polymethylene Biradicals," Gerhard L. Closs and Malcolm D. E. Forbes, in Kinetics and Spectroscopy of Carbenes and Biradicals, M. Platz, ed., Plenum (New York), 1990, pp. 51–75.

2. "Observation of Medium Chain Length Polymethylene Biradicals in Liquid Solutions by Time Resolved EPR Spectroscopy," Gerhard L. Closs and Malcolm D. E. Forbes J. Am. Chem. Soc. 1987, 109, 6185–6187.

1. "Spin–Polarized Electron Paramagnetic Resonance Spectra of Radical Pairs in Micelles. Observation of Electron Spin–Spin Interactions," Gerhard L. Closs, Malcolm D. E. Forbes and J. R. Norris, Jr. J. Phys. Chem. 1987, 91, 3592–3599.