SINGLE PARTICLE ANALYSIS OF PARTICULATE POLLUTANTS IN YELLOWSTONE NATIONAL PARK DURING THE WINTER SNOWMOBILE SEASON. Richard E. Peterson* and Bonnie J. Tyler** * Dept. of Chemistry and Biochemistry **Dept. of Chemical Engineering Montana State University, Bozeman, MT 59717, USA
[email protected] Introduction: Particulate, or aerosol, pollution is a complex mixture of organic and inorganic compounds which includes a wide range of sizes and whose composition can vary widely depending on the time of year, geographical location, and both local and long range sources. Aerosol are important because of participation in atmospheric electricity, absorption and scattering of radiation (i.e. sunlight and thus affecting climate and visibility), their role as condensation nuclei for water vapor (and thus affecting precipitation chemistry and pH), and health effects. Particles greater than 2 micrometers in diameter (coarse) are generally formed by mechanical processes while smaller particles (fine) are formed by gas to particle conversion and accumulation/coagulation of these smallest aerosol. Because particles smaller than 2.5 micrometers (USEPA PM2.5) can become trapped deep in the lungs, it is of particular interest to identify toxic substances, such as heavy metals and polyaromatic hydrocarbons, that may be present in particles of this size range. Epidemiological studies have typically used particle size as the metric for identifying adverse health effects of particulate matter (PM), largely because data on PM size is available. Data on particle composition or other characteristics are less well known, if known at all in many cases. We are evaluating the potential for using Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) to study the composition of single particles from atmospheric aerosol.