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Enhanced Thermoelectric Performance of Bulk Tin Telluride: Synergistic Effect of Calcium and Indium Co-Doping

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Enhanced Thermoelectric Performance of Bulk Tin Telluride: Synergistic Effect of Calcium and Indium Co-Doping Materials Today Physics 4 (2018) 12e18 Contents lists available at ScienceDirect Materials Today Physics journal homepage: https://www.journals.elsevier.com/ materials-today-physics Enhanced thermoelectric performance of bulk tin telluride: Synergistic effect of calcium and indium co-doping * ** D. Krishna Bhat a, , U. Sandhya Shenoy b, a Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Mangalore 575025, India b Department of Chemistry, College of Engineering and Technology, Srinivas University, Mukka, Mangalore 574146, India article info abstract Article history: SnTe based materials are considered recently as a lead-free replacement of the well-known PbTe based Received 27 January 2018 thermoelectric (TE) materials in addressing the energy crisis worldwide. Herein we report both exper- Received in revised form imental and theoretical study on the effect of co-doping of calcium and indium on electronic structure 4 February 2018 and TE properties of SnTe. We show that the resonant levels introduced by indium and band gap opening Accepted 12 February 2018 caused by calcium, valence band convergence induced by both calcium and indium, synergistically in- creases the Seebeck coefficient for a wide range of temperatures. The co-doped SnTe with a high ZT of À À ~1.65 at 840 K and record high power factor of ~47 mWcm 1K 2 for SnTe based materials make it a Keywords: Thermoelectric promising material for TE applications. © Band degeneracy 2018 Published by Elsevier Ltd. Resonant levels Tin telluride Introduction similar crystal and electronic structure. Though safer than PbTe, SnTe suffers a drawback of low ZT due to high carrier concentration Exhaustion of non-renewable fossil fuel resources caused due to resulting out of inherent Sn vacancies, smaller band gap (~0.18 eV) its abuse has resulted in ever increasing energy crisis [1]. Materials and higher separation between the valence sub-bands (~0.3 eV) for sustainable power generation is considered as a solution to this than PbTe [17,18]. In order to improve the ZT of SnTe, electronic problem [2]. Thermoelectric materials which can directly and structure has been engineered using dopants such as Bi, Ca, Cd, Hg, reversibly convert heat into electricity have attracted considerable Ga, In, Mg, Mn, Sr and co-dopants such as Ag-In, Bi-In, Cd-In, Hg-In, attention in the scientific community as a pollution free technology Mg-In, Mn-In [14,19e36]. These work involve improving the power [3,4]. The thermoelectric efficiency of a material is governed by its factor by achieving carrier concentration optimization, valence figure of merit ZT which is given by ZT ¼ sS2T/k, where s is electrical band convergence, introduction of resonance level or all of them conductivity, S is Seebeck co-efficient and k is total thermal con- together [14,19e36]. Further the thermal conductivity is reduced by ductivity. Although at present all the materials are known have a employing various nanostructuring [1,21,22,24,27e30]. While nonzero thermoelectric effect, in most materials the ZT is too low to doping of Bi causes modulation of carrier concentration and an be useful [1]. Hence, there is a need to identify materials with increase in density of state effective mass, In introduces resonance higher efficiency than available at present [5e8]. Due to well- states around Fermi level, enhancing the TE properties of SnTe known interdependence of S, s and k, developing strategies to [19,32]. Dopants like Ca, Cd, Hg, Ga, Mg, Mn, Sr are known to bring improve material's average ZT is complicated [3]. Due to environ- about opening of band gap of SnTe and cause convergence of mental toxicity of lead, PbTe based materials are not advised for valence sub-bands to increase the Seebeck coefficient which in turn large scale usage, despite it being the best known TE material [9,10]. enhances the power factors of SnTe. Since fabricating the device Hence there is need to develop thermoelectric materials containing requires higher ZT throughout the temperature range, recently co- non-toxic elements [11e16]. SnTe, being a homologue of PbTe has doping was employed to get beneficial effects of dopants active at lower (In due to introduction of resonance states) as well as higher temperature (elements like Ag, Cd, Hg, Mg, Mn due to their ability to * Corresponding author. modify the electronic structure of SnTe) [14,31,33e36]. In spite of ** Corresponding author. these efforts, the maximum ZT achieved is in the range of 1.3e1.6 E-mail addresses: [email protected] (D.K. Bhat), sandhyashenoy347@gmail. with most of the work involving harmful materials like Cd and Hg com (U.S. Shenoy). https://doi.org/10.1016/j.mtphys.2018.02.001 2542-5293/© 2018 Published by Elsevier Ltd. D.K. Bhat, U.S. Shenoy / Materials Today Physics 4 (2018) 12e18 13 [15,21,22,33e35]. Recently, we reported enhancement of thermo- substitution does not have much effect on the lattice parameter of electric performance of bulk SnTe by co-doping Mg and In [14]. The SnTe as InTe and SnTe have approximately similar lattice parameter synergistic action of the two dopants led to a ZT maximum of ~1.5 at (~6.32 Å) [14]. The linear increase in the lattice parameter with 840 K. The study showed that the site occupied by the dopants play dopant concentration follows Vegard's law till 8 mol % of Ca an important role in modification of its electronic structure. We (Fig. 1b). know that for singly doped materials by far Ca doped SnTe holds the Thermoelectric transport properties as a function of tempera- maximum ZT value of ~1.35 at 873 K [20]. It would be of interest to ture were studied in the range 300 Ke840 K. We observe that co- know if Ca also goes into zinc blende site like Mg and whether the doping of Ca and In decreases the electrical conductivity values site occupied by Ca in SnTe has any effect on its electronic structure with increase in the concentration of the dopants and also with [14,26]. Since in some of the co-doping cases such as Bi-In and Mg- respect to increase in the temperature showing the degenerate In reported by Zhang et al. we see that the ZT maximum achieved is nature of semiconducting materials (Fig. 2a) [22]. The values of lower than the singly doped Bi and Mg in SnTe, we wanted to see electrical conductivity of the Ca-In co-doped samples are inter- how Ca and In would interact, whether the co-doping would mediate compared to the previously reported SnTe samples singly decrease the ZT than singly doped Ca in SnTe or would it increase doped with Ca and In [20,24,25]. The room temperature electrical À À the ZT due to synergistic action as in the case of Cd-In co-doped conductivity decreases from 6600 Scm 1 to 1970 Scm 1 as ‘x’ in- SnTe reported by Tan et al. and Mg-In co-doped SnTe previously creases from 0 to 4 mol % in Sn1.04-3xCa2xInxTe. The carrier con- 20 À3 reported by us [14,19,26,32,33]. Hence, we thought it is worthwhile centration ‘Np’ of SnTe reduces from 4.5 Â 10 cm to À to investigate the effect of co-doping of Ca and In in SnTe both 2.1 Â 1020 cm 3 on self compensation of Sn vacancies as established experimentally through synthesis using a combination of self in the previous report [14,21]. The carrier concentration decreases 20 À3 propagating high temperature synthesis (SHS) and direct current to 1.9 Â 10 cm as the ‘x’ increases to 4 mol % in Sn1.04-3xCa2x- fi sintering (DCS) and theoretically through simulations using rst InxTe. The details of carrier concentration and carrier mobility as a principles density functional theory (DFT) approach to see if we can function of doping concentration are given in Fig. 2b. We observe achieve further improvement in ZT. We show that the resonant that the carrier mobility ‘m’ decreases with increase in ‘x’ due to levels introduced by In and band gap opening caused by Ca, valence increase in scattering between the carriers, enhanced point defect band convergence caused by both In and Ca, synergistically in- scattering and increase in the effective mass of the carrier as creases the Seebeck coefficient for a wide range of temperatures explained in the later sections [20,33,37]. without involving toxic elements like Cd and Hg. We show through The Seebeck coefficient values show increasing trend with in- DFT simulations that unlike Mg, Ca prefers rock salt site in SnTe [14]. crease in temperature and dopant concentration (Fig. 3a). The Thus, co-doping of Ca and In results in enhancement of figure of positive value of Seebeck coefficient reveals that holes are the merit ZT due to complimentary role of Ca and In in modifying the majority carriers leading to p-type conduction in the material [22]. electronic structure of SnTe producing a record high power factor The pristine and self compensated SnTe show a maximum value of À À and ZT in SnTe based materials. The synergism shown here is much Seebeck coefficient of 110 mVK 1 and 145 mVK 1 respectively. The higher than any co-doped SnTe based materials including the co-doped sample shows room temperature Seebeck coefficient of À À recently reported Mg-In co-doped SnTe [14]. 95 mVK 1 and a maximum value of 235 mVK 1 at 840 K (when x ¼ 0.04 in Sn1.04-3xCa2xInxTe). To study the effect of co-dopants, we Results and discussions compared room temperature Seebeck coefficient versus Np with the theoretical Pisarenko plot reported by Zhang et al.
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