Supporting Information
The Journal of Organic Chemistry Manuscript ID: jo 2015 008303
Micelle Formation in Liquid Ammonia
Joseph M. Griffin, John H. Atherton and Michael I. Page*
IPOS, The Page Laboratories, Department of Chemical and Biological Sciences, The University of Huddersfield, Queensgate, Huddersfield, HD1 3DH, United Kingdom
Contents Page
1. Ostwald’s dilution law for weak electrolytes 2
2. Kohlrausch’s law for strong electrolytes 4
3. Observed pseudo first order rate constants for the ammonolysis of propargyl benzoate as a function of perfluorononanamide concentration 6
1
1. Ostwald’s dilution law for weak electrolytes:
Attempts were made to fit the liquid ammonia data to Ostwald’s dilution law:
1 1 Λ c = ∘ + ∘ Λ Λ (Λ )
Where: