COEXISTING GALENA, Pbso and SULFOSALTS
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Article Is Available On- Cu2 Site Is More Difficult, Certainly Due to the Small Size Line At
Eur. J. Mineral., 32, 449–455, 2020 https://doi.org/10.5194/ejm-32-449-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Luxembourgite, AgCuPbBi4Se8, a new mineral species from Bivels, Grand Duchy of Luxembourg Simon Philippo1, Frédéric Hatert2, Yannick Bruni2, Pietro Vignola3, and Jiríˇ Sejkora4 1Laboratoire de Minéralogie, Musée National d’Histoire Naturelle, Rue Münster 25, 2160 Luxembourg, Luxembourg 2Laboratoire de Minéralogie, Université de Liège B18, 4000 Liège, Belgium 3CNR-Istituto di Geologia Ambientale e Geoingegneria, via Mario Bianco 9, 20131 Milan, Italy 4Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, 193 00 9, Prague, Czech Republic Correspondence: Frédéric Hatert ([email protected]) Received: 24 March 2020 – Revised: 30 June 2020 – Accepted: 15 July 2020 – Published: 12 August 2020 Abstract. Luxembourgite, ideally AgCuPbBi4Se8, is a new selenide discovered at Bivels, Grand Duchy of Lux- embourg. The mineral forms tiny fibres reaching 200 µm in length and 5 µm in diameter, which are deposited on dolomite crystals. Luxembourgite is grey, with a metallic lustre and without cleavage planes; its Mohs hard- ness is 3 and its calculated density is 8.00 g cm−3. Electron-microprobe analyses indicate an empirical formula Ag1:00.Cu0:82Ag0:20Fe0:01/61:03Pb1:13Bi4:11.Se7:72S0:01/67:73, calculated on the basis of 15 atoms per formula unit. A single-crystal structure refinement was performed to R1 D 0:0476, in the P 21=m space group, with 3 a D 13:002.1/, b D 4:1543.3/, c D 15:312.2/Å, β D 108:92.1/◦, V D 782:4.2/Å , Z D 2. -
Overview of Tungsten Indicator Minerals Scheelite and Wolframite with Examples from the Sisson W-Mo Deposit, Canada
Overview of tungsten indicator minerals scheelite and wolframite with examples from the Sisson W-Mo deposit, Canada M. Beth McClenaghan1, M.A. Parkhill2, A.A. Seaman3, A.G. Pronk3, M. McCurdy1 & D.J. Kontak4 1Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario, Canada K1A 0E8 (e-mail: [email protected]) 2New Brunswick Department of Energy and Mines, Geological Surveys Branch, P.O. Box 50, Bathurst, New Brunswick, Canada E2A 3Z1 3New Brunswick Department of Energy and Mines, Geological Surveys Branch, P.O. Box 6000, Fredericton, New Brunswick, Canada E3B 5H1 4Department of Earth Sciences, Laurentian University, Sudbury, Ontario, Canada P3E 2C6 These short course notes provide an overview of published lit- Table 1. List of regional surveys and case studies conducted around erature on the use of scheelite and wolframite as indicator min- the world in which scheelite and/or wolframite in surficial sediments erals for W, Mo, and Au exploration. The use of scheelite and have been used as indicator minerals. wolframite in stream sediments is well documented for mineral Mineral Media Location Source of Information exploration but less so for using glacial sediments (Table 1). scheelite stream sediments Pakistan Asrarullah (1982) wolframite stream sediments Burma ESCAP Scretariat (1982) The Geological Survey of Canada has recently conducted a scheelite, wolframite stream sediments USA Theobald & Thompson (1960) glacial till and stream sediment indicator mineral case study scheelite stream sediments, soil Thailand Silakul (1986) around the Sisson W-Mo deposit in eastern Canada. scheelite stream sediments Greenland Hallenstein et al. (1981) Preliminary indicator mineral results from this ongoing study scheelite stream sediments Spain Fernández-Turiel et al. -
Tin-Bearing Chalcopyrite and Platinum-Bearing Bismuthinite in the Active Tiger Chimney, Yonaguni Knoll IV Seafloor Hydrothermal System, South Okinawa Trough, Japan
OKAYAMA University Earth Science Reports, Vol. 12, No. I, 1-5, (2005) Tin-bearing chalcopyrite and platinum-bearing bismuthinite in the active Tiger chimney, Yonaguni Knoll IV seafloor hydrothermal system, South Okinawa Trough, Japan Kaul GENA, Hitoshi CHmA and Katsuo KASE Department ofEarth Sciences, Faculty ofScience, Okayama University, Okayama 700-8530, Japan The active sulfide chimney ore sampled from the flank of the active TIger chimney in the Yonaguni Knoll N hydrothermal system, South Okinawa Trough, consists of anhydrite, pyrite, sphalerite, galena. chalcopyrite and bismuthinite. Electron microprobe analyses indicated that the chalcopyrite and bismuthinite contain up to 2.4 wt. % Sn and 1.7 wt. % Pt, respectively. The high Sn-bearing chalcopyrite and Pt-bearing bismuthinite are the first occurrence of such minerals on the submarine hydrothermal systems so far reported. The results confirm that the Sn enters the chalcopyrite as a solid solution towards stannite by the coupled substitution ofSn#Fe2+ for Fe3+Fe3+ while Pt enters the bismuthinite structure as a solid solution during rapid growth. The homogenization temperature of the fluid inclusions in anhydrite (220-31O°C) and measured end-member temperature of the vent fluids (325°C) indicate that the minerals are precipitated as metastable phases at temperature around 300°C. The Sn-bearing chalcopyrite and Pt-bearing bismuthinite express the original composition of the minerals deposited from a hydrothermal fluid with temperatures ofabout 300°C. Keywords: Sn-bearing chalcopyrite,Pt-bearing bismuthinite, Active sulfide Chimney, Yonaguni Knoll IV, Okinawa Trough, seafloor hydrothermal system. I. Introduction IT. Tiger chimney in Yonaguni Knoll IV hydrothermal Since 1998, a lot of seafloor hydrothermal activities system. -
Standard X-Ray Diffraction Powder Patterns
NBS MONOGRAPH 25 — SECTION 1 Standard X-ray Diffraction U.S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS THE NATIONAL BUREAU OF STANDARDS Functions and Activities The functions of the National Bureau of Standards are set forth in the Act of Congress, March 3, 1901, as amended by Congress in Public Law 619, 1950. These include the development and maintenance of the national standards of measurement and the provision of means and methods for making measurements consistent with these standards; the determination of physical constants and properties of materials; the development of methods and instruments for testing materials, devices, and structures; advisory services to government agencies on scien- tific and technical problems; invention and development of devices to serve special needs of the Government; and the development of standard practices, codes, and specifications. The work includes basic and applied research, development, engineering, instrumentation, testing, evaluation, calibration services, and various consultation and information services. Research projects are also performed for other government agencies when the work relates to and supplements the basic program of the Bureau or when the Bureau's unique competence is required. The scope of activities is suggested by the listing of divisions and sections on the inside of the back cover. Publications The results of the Bureau's research are published either in the Bureau's own series of publications or in the journals of professional and scientific societies. The Bureau itself publishes three periodicals available from the Government Printing Office: The Journal of Research, published in four separate sections, presents complete scientific and technical papers; the Technical News Bulletin presents summary and preliminary reports on work in progress; and Basic Radio Propagation Predictions provides data for determining the best frequencies to use for radio communications throughout the world. -
Calaverite Aute2 C 2001-2005 Mineral Data Publishing, Version 1 Crystal Data: Monoclinic
Calaverite AuTe2 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m or 2. Bladed and short to slender prisms elongated k [010], striated k [010], to 1 cm; also massive, granular. Twinning: Common on {110}, less common on {031} and {111}. Physical Properties: Fracture: Uneven to subconchoidal. Tenacity: Brittle. Hardness = 2.5–3 VHN = 197–213 (100 g load). D(meas.) = 9.10–9.40 D(calc.) = 9.31 Optical Properties: Opaque. Color: Grass-yellow to silver-white; white in reflected light. Streak: Greenish to yellowish gray. Luster: Metallic. Pleochroism: Weak. Anisotropism: Weak. R1–R2: (400) 45.7–54.4, (420) 48.4–57.1, (440) 51.1–59.6, (460) 53.6–61.8, (480) 56.0–63.6, (500) 57.9–65.2, (520) 59.4–66.4, (540) 60.6–67.3, (560) 61.3–68.0, (580) 61.8–68.3, (600) 62.2–68.4, (620) 62.5–68.6, (640) 62.7–68.5, (660) 62.8–68.4, (680) 62.9–68.2, (700) 63.0–68.1 Cell Data: Space Group: C2/m or C2. a = 7.1947(4) b = 4.4146(2) c = 5.0703(3) β =90.038(4)◦ Z=2 X-ray Powder Pattern: Cripple Creek, Colorado, USA. 3.02 (10), 2.09 (8), 2.20 (4), 2.93 (3), 1.758 (3), 1.689 (3), 1.506 (3) Chemistry: (1) (2) (3) Au 41.66 42.15 43.59 Ag 0.77 0.60 Te 57.87 57.00 56.41 Total 100.30 99.75 100.00 (1) Cripple Creek, Colorado, USA. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
A Single-Crystal Epr Study of Radiation-Induced Defects
A SINGLE-CRYSTAL EPR STUDY OF RADIATION-INDUCED DEFECTS IN SELECTED SILICATES A Thesis Submitted to the College of Graduate Studies and Research In Partial Fulfillment of the Requirements For the Degree of Doctor of Philosophy In the Department of Geological Sciences University of Saskatchewan Saskatoon By Mao Mao Copyright Mao Mao, October, 2012. All rights reserved. Permission to Use In presenting this thesis in partial fulfilment of the requirements for a Doctor of Philosophy degree from the University of Saskatchewan, I agree that the Libraries of this University may make it freely available for inspection. I further agree that permission for copying of this thesis in any manner, in whole or in part, for scholarly purposes may be granted by the professor or professors who supervised my thesis work or, in their absence, by the Head of the Department or the Dean of the College in which my thesis work was done. It is understood that any copying or publication or use of this thesis or parts thereof for financial gain shall not be allowed without my written permission. It is also understood that due recognition shall be given to me and to the University of Saskatchewan in any scholarly use which may be made of any material in my thesis. Requests for permission to copy or to make other use of material in this thesis in whole or part should be addressed to: Head of the Department of Geological Sciences 114 Science Place University of Saskatchewan Saskatoon, Saskatchewan S7N5E2, Canada i Abstract This thesis presents a series of single-crystal electron paramagnetic resonance (EPR) studies on radiation-induced defects in selected silicate minerals, including apophyllites, prehnite, and hemimorphite, not only providing new insights to mechanisms of radiation-induced damage in minerals but also having direct relevance to remediation of heavy metalloid contamination and nuclear waste disposal. -
Oxygenic Bismuth Minerals in the NE Part of the Karkonosze Pluton (West Sudetes, SW Poland)
Acta Geologica Polonica, Vol. 68 (2018), No. 4, pp. 537–554 DOI: 10.1515/agp-2018-0016 Oxygenic bismuth minerals in the NE part of the Karkonosze pluton (West Sudetes, SW Poland) ANDRZEJ KOZŁOWSKI and WITOLD MATYSZCZAK* Faculty of Geology, University of Warsaw, Żwirki i Wigury 93, PL-02-089 Warszawa, Poland. *E-mail: [email protected] ABSTRACT: Kozłowski, A. and Matyszczak, W. 2018. Oxygenic bismuth minerals in the NE part of the Karkonosze pluton (West Sudetes, SW Poland). Acta Geologica Polonica, 68 (4), 537–554. Warszawa. The study presents fifteen oxygen-bearing secondary minerals of bismuth from the north-eastern part of the Variscan Karkonosze granitoid pluton in the northern zone of the Bohemian massif. The minerals were inves- tigated by optical, electron microprobe, classic chemical, XRD, IR absorption and fluid inclusion methods. The late, very low temperature epithermal solutions most probably caused formation of sillénite, kusachiite, bismoclite, bismutite, beyerite, kettnerite, pucherite, schumacherite, namibite and eulytite. Solutions dominated by supergene (meteoric) waters were the parents for bismite, russellite, koechlinite, ximengite and walpurgite. The paper also contains information on early research on the investigated minerals. Key words: Karkonosze granitoid pluton; Bismuth minerals; Secondary minerals; Oxidation; Vein; Pegmatite. FOREWORD joined by WM as the co-author, interested like him in further investigations of the Karkonosze pluton (see The paper presents an investigation of several ox- e.g., Matyszczak 2018). ygen-bearing minerals of bismuth, which were found in the Karkonosze granitoid, collected during field work by AK in 1976–1990. Most of the minerals were INTRODUCTION not known until the present either from the Polish part of the Karkonosze pluton, or from the area of The systematic scientific investigation of the Poland. -
The Gersdorffite-Bismuthinite-Native Gold Association and the Skarn
minerals Article The Gersdorffite-Bismuthinite-Native Gold Association and the Skarn-Porphyry Mineralization in the Kamariza Mining District, Lavrion, Greece † Panagiotis Voudouris 1,* , Constantinos Mavrogonatos 1 , Branko Rieck 2, Uwe Kolitsch 2,3, Paul G. Spry 4 , Christophe Scheffer 5, Alexandre Tarantola 6 , Olivier Vanderhaeghe 7, Emmanouil Galanos 1, Vasilios Melfos 8 , Stefanos Zaimis 9, Konstantinos Soukis 1 and Adonis Photiades 10 1 Department of Geology & Geoenvironment, National and Kapodistrian University of Athens, 15784 Athens, Greece; [email protected] (C.M.); [email protected] (E.G.); [email protected] (K.S.) 2 Institut für Mineralogie und Kristallographie, Universität Wien, 1090 Wien, Austria; [email protected] 3 Mineralogisch-Petrographische Abteilung, Naturhistorisches Museum, 1010 Wien, Austria; [email protected] 4 Department of Geological and Atmospheric Sciences, Iowa State University, Ames, IA 50011, USA; [email protected] 5 Département de Géologie et de Génie Géologique, Université Laval, Québec, QC G1V 0A6, Canada; [email protected] 6 Université de Lorraine, CNRS, GeoRessources UMR 7359, Faculté des Sciences et Technologies, F-54506 Vandoeuvre-lès-Nancy, France; [email protected] 7 Université de Toulouse, Géosciences Environnement Toulouse (GET), UMR 5563 CNRS, F-31400 Toulouse, France; [email protected] 8 Department of Mineralogy-Petrology-Economic Geology, Faculty of Geology, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece; [email protected] 9 Institut für Mineralogie, TU Bergakademie Freiberg, 09599 Freiberg, Germany; [email protected] 10 Institute of Geology and Mineral Exploration (I.G.M.E.), 13677 Acharnae, Greece; [email protected] * Correspondence: [email protected]; Tel.: +30-210-7274129 † The paper is an extended version of our paper published in 1st International Electronic Conference on Mineral Science. -
1 Revision 1 Single-Crystal Elastic Properties of Minerals and Related
Revision 1 Single-Crystal Elastic Properties of Minerals and Related Materials with Cubic Symmetry Thomas S. Duffy Department of Geosciences Princeton University Abstract The single-crystal elastic moduli of minerals and related materials with cubic symmetry have been collected and evaluated. The compiled dataset covers measurements made over an approximately seventy year period and consists of 206 compositions. More than 80% of the database is comprised of silicates, oxides, and halides, and approximately 90% of the entries correspond to one of six crystal structures (garnet, rocksalt, spinel, perovskite, sphalerite, and fluorite). Primary data recorded are the composition of each material, its crystal structure, density, and the three independent nonzero adiabatic elastic moduli (C11, C12, and C44). From these, a variety of additional elastic and acoustic properties are calculated and compiled, including polycrystalline aggregate elastic properties, sound velocities, and anisotropy factors. The database is used to evaluate trends in cubic mineral elasticity through consideration of normalized elastic moduli (Blackman diagrams) and the Cauchy pressure. The elastic anisotropy and auxetic behavior of these materials are also examined. Compilations of single-crystal elastic moduli provide a useful tool for investigation structure-property relationships of minerals. 1 Introduction The elastic moduli are among the most fundamental and important properties of minerals (Anderson et al. 1968). They are central to understanding mechanical behavior and have applications across many disciplines of the geosciences. They control the stress-strain relationship under elastic loading and are relevant to understanding strength, hardness, brittle/ductile behavior, damage tolerance, and mechanical stability. Elastic moduli govern the propagation of elastic waves and hence are essential to the interpretation of seismic data, including seismic anisotropy in the crust and mantle (Bass et al. -
Abraplata Resource Corp. Technical Report on the Diablillos Project, Salta Province, Argentina
ABRAPLATA RESOURCE CORP. TECHNICAL REPORT ON THE DIABLILLOS PROJECT, SALTA PROVINCE, ARGENTINA NI 43-101 Report Qualified Persons: David W. Rennie, P.Eng. Scott Ladd, P.Eng. Ian Weir, P.Eng. Gerry Neeling, FAusIMM April 16, 2018 RPA 55 University Ave. Suite 501 I Toronto, ON, Canada M5J 2H7 IT + 1 (416) 947 0907 www.rpacan.com Report Control Form Document Title Technical Report on the Diablillos Project, Salta Province, Argentina Client Name & Address AbraPlata Resource Corp. Esmeralda 920, Suite 2906 C1007ADL Buenos Aires Argentina Document Reference Status & FINAL Project # 2841 Issue No. Version Issue Date April 16, 2018 Lead Author Scott Ladd (Signed) Peer Reviewer William Roscoe (Signed) Glen Ehasoo (Signed) Project Manager Approval Scott Ladd (Signed) Project Director Approval Jason Cox (Signed) Report Distribution Name No. of Copies Client RPA Filing 1 (project box) Roscoe Postle Associates Inc. 55 University Avenue, Suite 501 Toronto, ON M5J 2H7 Canada Tel: +1 416 947 0907 Fax: +1 416 947 0395 [email protected] www.rpacan.com FORWARD-LOOKING INFORMATION This report contains forward-looking statements. All statements, other than statements of historical fact regarding AbraPlata Resource Corp. or Diablillos Project, are forward-looking statements. The words "believe", "expect", "anticipate", "contemplate", "target", "plan", "intend", "project", "continue", "budget", "estimate", "potential", "may", "will", "can", "could" and similar expressions identify forward-looking statements. In particular, this report contains forward-looking statements with respect to cash flow forecasts, projected capital, operating and exploration expenditure, targeted cost reductions, mine life and production rates, potential mineralization and metal or mineral recoveries, and information pertaining to potential improvements to financial and operating performance and mine life at the Diablillos Project that may result from expansion projects or other initiatives. -
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THE AMERICAN MINERALOGIS'I, VOL. 52, MAY-JUNE, 1967 NEW MINERAL NAMI'S Mrcu.q.Br,FrBrscnnn Niningerite Kleus Knrr- aNo K. G. SNrrsrxcnn (1967) Niningerite, a nern'meteoritic sulfide. Seience 155, 451-543. Averages of electron probe analyses of the mineral from 6 enstatite chondrites (1-Abee, 2-Saint Sauveur, 3-Adhi-Kot, 4-Indarch, 5-St. Mark's and 5-Kota-Kota) give: S 41.0 42.7 42.6 43.4 47.4 46.9 Mg 10.1 13.2 II.J 18.3 22.7 23.5 Mn 4.02 3.93 11 6.5 11.8 11.6 l'e 37.r 35.2 34.2 270 16.6 15.6 Ca 3.03 2.55 1.96 r.28 0.53 0.39 Zn 0.31 n.d. n.d. n.d. n.d. n d. Cr 1.84 t.97 IOD 0.40 0.14 Total 97.40 99.3s 99.t3 98.1'+ 99.43 98.13 No. of grains analyzed 20 IJ t4 10 10 a 5.17 516 n d. 5.r8 5.17 n.d G. calc. 3 .68 J.5v 3.644 3.35 s.Ll J,Zr * Calc G. assuminga:5.17A. These correspond to RS, with R: S ranging from 0 97 to 1.05, or (Mg, Fe, Mn)S. Mg is dominant in nos. 4, 5, 6, but Fe)Mg in nos 1, 2, and 3;no. I has Fe:Mg:Mn:0.52: 0.33:0.06. The X-ray pattern is very similar to that of aiabandite and ferroan alabandite (cubic), but with o slightly lower.