DOCSLIB.ORG

| Hao Hata Kama Maria De Un Militaan Van Die Matter

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
| Hao Hata Kama Maria De Un Militaan Van Die Matter |HAO HATA KAMA MARIAUS009833509B2 DE UN MILITAAN VAN DIE MATTER (12 ) United States Patent ( 10 ) Patent No. : US 9 , 833 ,509 B2 Vissman et al . (45 ) Date of Patent: Dec. 5 , 2017 ( 54 ) BIOCERAMIC COMPOSITIONS AND ( 58 ) Field of Classification Search BIOMODULATORY USES THEREOF CPC .. .. B32B 1 /02 ; Y10T 428 / 1352 ; A41B 1 /00 ; A61K 33 /00 ; A61K 33 / 08 ; C04B 33 /04 ; @(71 ) Applicant : Multiple Energy Technologies LLC , A61N 5 /0613 ; A61M 21 /02 Washington , PA (US ) See application file for complete search history . @(72 ) Inventors : Shannon Vissman , Upper St . Clair, PA (US ) ; Francisco Jose Cidral- Filho , (56 ) References Cited Washington , PA (US ) ; Francisco de U . S . PATENT DOCUMENTS Paula Moreira , Florianópolis (BR ) ; Steven Midttun , Boca Raton , FL (US ) 2 ,929 ,414 A 3 / 1960 Lienhard 3 , 969 ,551 A 7 / 1976 Ellsworth (73 ) Assignee : MULTIPLE ENERGY (Continued ) TECHNOLOGIES LLC , Washington , PA (US ) FOREIGN PATENT DOCUMENTS ( * ) Notice : Subject to any disclaimer , the term of this BR PI0801804 A2 2 / 2009 patent is extended or adjusted under 35 BR 10805782 A2 8 /2010 U . S . C . 154 (b ) by 0 days . ( Continued ) ( 21 ) Appl. No. : 14 /702 ,467 OTHER PUBLICATIONS ( 22 ) Filed : May 1, 2015 Australian Patent Application No . 2013323956 Examiner ' s Report No. 3 dated Jan . 22 , 2016 . (65 ) Prior Publication Data (Continued ) US 2015 /0335742 A1 Nov. 26 , 2015 Primary Examiner — Marc A Patterson Related U . S . Application Data (74 ) Attorney , Agent, or Firm — Wilson Sonsini Goodrich (60 ) Provisional application No . 62 /115 ,567 , filed on Feb . & Rosati 12 , 2015, provisional application No . 62 / 064 , 939, ( Continued ) (57 ) ABSTRACT ( 51 ) Int. Ci. The subject matter described herein is directed to articles , B32B 1 / 02 ( 2006 . 01 ) compositions, systems, and methods of using and preparing A61K 41/ 00 ( 2006 . 01) bioceramic compositions and to the bioceramic composi ( Continued ) tions . A bioceramic composition of the disclosure radiates (52 ) U .S . CI. infrared energy or rays and can be used in the treatment of CPC .. .. .. .. A61K 41 /0052 (2013 .01 ) ; A61K 33/ 00 various conditions . (2013 .01 ) ; A61K 33 /08 ( 2013 .01 ) ; (Continued ) 15 Claims, 51 Drawing Sheets Peak Expiratory flow ( PEF ) Use Durma procice - 3 days a week Continuous Uso - days a wex * * Utors(0) Utensu ?????????????? www * * * * * 400 . NE WEEK I WOK 2 * BioPower O No BloPower US 9 ,833 , 509 B2 Page 2 Related U . S . Application Data 6 ,669 , 882 B2 12 / 2003 Seok 6 , 797 , 377 B1 9 /2004 Delucia et al . filed on Oct. 16 , 2014 , provisional application No . 6 , 884 , 256 B2 4 / 2005 Huang et al. 6 ,951 ,900 B2 10 / 2005 Blanchard et al. 62/ 062 ,686 , filed on Oct . 10 , 2014 , provisional ap 7 , 056, 845 B2 6 /2006 Waeber et al. plication No . 62 /018 ,085 , filed on Jun . 27 , 2014 , 7 ,063 , 801 B2 6 / 2006 Sato provisional application No. 61/ 988 , 837 , filed on May 7 , 074, 499 B2 7 / 2006 Schnurer et al. 5 , 2014 7 , 311 , 209 B2 12 / 2007 Bentz et al . D598 ,660 S 8 / 2009 Schaller Int. CI. 7 , 824 ,350 B2 11 / 2010 Lu (51 ) D629 ,210 S 12 / 2010 Hong C04B 33 / 04 ( 2006 . 01 ) D631 , 971 S 2 / 2011 Turtzo et al . A6IN 5 / 06 ( 2006 .01 ) 8 , 104 , 482 B2 1 / 2012 Komuro AGIM 21/ 02 ( 2006 .01 ) 8 , 231, 968 B2 7 /2012 Lin et al. DOOM 11 / 36 ( 2006 . 01 ) D664 , 739 S 8 / 2012 Gibson DOOM 11/ 45 D667 , 226 S 9 / 2012 Levy ( 2006 .01 ) 8 , 333 , 018 B2 12 /2012 Lin et al. DOOM 11/ 46 ( 2006 . 01 ) 8 ,366 , 757 B2 2 /2013 Oliveira et al . DO6M 11/ 79 ( 2006 .01 ) 8 , 388, 750 B2 3 / 2013 Gay et al . A61K 33 / 00 ( 2006 .01 ) 8 , 409 , 262 B2 4 /2013 Lin et al. A61K 33 /08 ( 2006 .01 ) 8 , 491 , 825 B2 7 / 2013 Lin et al. A61K 33 / 22 ( 2006 .01 ) D704 , 455 S 5 /2014 Blakely et al . A61K 33 / 24 ( 2006 . 01 ) 8 , 815 ,158 B2 8 / 2014 Zheng et al . 8 ,968 , 819 B2 3 / 2015 Hirata B32B 1 / 08 ( 2006 .01 ) 8 , 980 , 775 B2 3 / 2015 Francy et al . A41B 1 / 00 ( 2006 .01 ) 9 , 044 , 384 B2 6 / 2015 Canova et al . A61M 21 /00 ( 2006 .01 ) 9 , 120, 959 B2 9 / 2015 Hara et al . A61F 7700 ( 2006 .01 ) D746 ,543 S 1 /2016 McClain DOOM 15 /643 ( 2006 .01 ) 9 ,376 ,576 B2 6 / 2016 Jung et al. U . S . CI. 2002 / 0014716 Al * 2 /2002 Seok CO8K 3 / 34 (52 ) 264 / 140 ??? .. A61K 33 /22 (2013 .01 ) ; A61K 33 / 24 2002 /0042641 AL 4 /2002 Johnson et al . ( 2013 .01 ) ; A61M 21/ 02 ( 2013 .01 ) ; A6IN 2002 /0195751 A1 12 /2002 Kim et al. 5 /0613 ( 2013 . 01 ) ; A61N 5 /0616 ( 2013 .01 ) ; 2004 /0043174 A1 3 / 2004 Schnurer et al . A61N 5 / 0625 (2013 . 01 ) ; C04B 33 / 04 2004 / 0087430 AL 5 /2004 Sola ( 2013. 01 ) ; DOM 11/ 36 ( 2013. 01 ) ; DOM 2004 /0202899 Al 10 /2004 Komuro 11/ 45 (2013 . 01 ) ; D06M 11 /46 ( 2013 .01 ) ; 2004 /0225049 AL 11 / 2004 Komuro DOOM 11 / 79 ( 2013 . 01 ) ; A61F 2007 /0088 2005 / 0060807 A1 * 3 / 2005 Kaizuka . .. .. .. .. .. .. A47G 9 /007 (2013 .01 ) ; A61M 2021 /0016 ( 2013 .01 ) ; A61N 5 /636 2005 /0066448 AL 3 /2005 Waeber et al. 2005 / 066 (2013 . 01 ) ; A61N 2005 /0643 2005 /0171584 Al 8 /2005 Slingo ( 2013 . 01 ) ; A61N 2005 /0645 ( 2013 .01 ) ; A61N 2005 /0227047 Al 10 /2005 Sutter et al . 2005 / 0656 ( 2013 .01 ) ; A61N 2005 /0659 2005 / 0241069 A 11 / 2005 Lin ( 2013. 01 ) ; C04B 2235/ 9607 ( 2013. 01 ) ; DOOM 2006 / 0137701 A1 6 / 2006 Snaidr 15 /643 (2013 .01 ) 2006 / 0275348 A1 12 / 2006 Komuro 2007 /0116775 A1 5 /2007 Lee 2009 / 0065732 A 3 / 2009 Yeh et al . ( 56 ) References Cited 2009 / 0137171 Al 5 /2009 Waeber et al. U . S . PATENT DOCUMENTS 2009 / 0171266 A1 7 / 2009 Harris 2009 / 0267271 A1 10 /2009 Kim 4 , 175 , 556 A 11 / 1979 Freezer 2010 / 0186917 A1 7 / 2010 Simonson et al. 4 , 344 , 908 A * 8 / 1982 Smith . .. .. B29C 70 /10 2010 / 0282433 Al 11/ 2010 Blackford 264 / 203 2011 /0021098 A1 1 / 2011 Tabellion et al . 4 ,680 ,822 A 7 / 1987 Fujino et al. 2011 /0027548 A1 2 / 2011 Nusser et al. 4 , 968, 531 A * 11/ 1990 Maeda .. A61F0 7 /02 2011/ 0059037 A1 3 / 2011 Canova et al . 427 / 160 2011 / 0112461 A1 5 / 2011 Hirata 5 , 208 ,089 A 5 / 1993 Norris 2011 /0208099 A1 8 / 2011 Naghavi et al. 5 , 258 , 228 A 11/ 1993 Komuro 2012 / 0060344 Al 3 / 2012 Smeets 5 , 296 ,531 A 3 / 1994 Belde et al. 2012 /0135485 A1 5 / 2012 Koros et al. 5 , 299 , 335 A 4 / 1994 Ivester et al . 2014 / 0079920 A1 3 / 2014 Blakely 5 ,645 , 934 A 7 / 1997 Marcolongo et al . 2014 / 0087040 A1 3 /2014 Vissman et al. 5 ,820 ,348 A * 10 / 1998 Fricke FO1D 5 /027 2014 /0173801 Al 6 / 2014 Bell 188 / 268 2014 /0187413 A1 7 /2014 Lagaron Cabello et al. D405 , 885 S 2 / 1999 Pinter 5 , 894 , 067 A 4 / 1999 Kim 2014 /0197562 A1* 7 /2014 Piccinini .. .. .. C08J 9 /0061 5 , 935 , 550 A 8 / 1999 Mohri et al . 264 / 54 5 , 972 ,215 A 10 / 1999 Kammel 2014 /0209594 A1 7 / 2014 Besner 5 ,972 ,815 A 10 / 1999 Bae 2014 / 0255664 A1 9 /2014 Gartmann et al. 6 ,074 ,754 A 6 / 2000 Jacobsen et al. 2014 /0264186 A1 9 / 2014 Spatz et al . 6 , 207 , 077 B1 3 / 2001 Burnell - Jones 2014 / 03 24132 Al 10 / 2014 6 , 207 , 600 B1 3 / 2001 Nakajima et al. 2015 / 0017856 A1 1 / 2015 Davis et al . 6 , 264 , 907 B1 7 / 2001 Matsuda et al . 2015 /0224230 AL 8 / 2015 Hirata 6 , 506 , 403 B11 / 2003 Yu 2015 /0291868 A1 10 /2015 Rajagopalan et al. 6 ,516 , 229 B1 2 / 2003 Wey 2015 /0335742 A1 11/ 2015 Vissman et al. 6 ,645 ,517 B2 11 / 2003 West et al. 2016 /0136386 A15 / 2016 Vissman et al. 6 ,651 ,256 B1 * 11 / 2003 Swift A42B 1 /004 2016 /0136452 A1 5 /2016 Vissman et al . 2 / 15 2016 /0143838 A15 /2016 Canova et al . US 9 ,833 , 509 B2 Page 3 ( 56 ) References Cited Columbia Patent Application No. 15 -090 . 148 Official Action dated Nov . 11 , 2016 . U . S . PATENT DOCUMENTS Eurasian Patent Application No . 201590577 Office Action dated Aug. 30 , 2016 . 2016 /0151300 A16 / 2016 Madvin Japanese Patent Application No . 11335966 - A dated May 1998 to 2017 /0049890 A12 / 2017 Vissman et al . Kusakari et al . Korean Patent Application No. 1020100009129 - A dated Jan . 2010 FOREIGN PATENT DOCUMENTS to Kim . PCT/ US2015 /028910 International Preliminary Report on Patent BR MU9000125 U2 9 / 2011 ability dated Nov . 17 , 2016 . BR MU9001019 U2 1 / 2012 U . S . Appl. No. 13 / 760 ,546 Office Action dated Dec . 13 , 2016 . CN 1887784 A 1 / 2007 CN 102553623 A 7 / 2012 U . S . Appl. No . 13 / 760 , 546 Office Action dated Jun . 17 , 2016 . EP 1816254 A1 8 / 2007 U . S . Appl. No . 14 / 965 ,741 First Action Interview Office Action EP 2900621 A1 8 / 2015 Summary dated Sep . 14 , 2016 . EP 3140004 A1 3 / 2017 U . S . Appl. No. 14 / 965, 746 Office Action dated Aug . 25 , 2016 . GB 883264 A 11 / 1961 Emer et al. , University of Southern Santa Catarina , Laboratory of GB 1093041 A 11 / 1967 Experimental Neuroscience Far Infrared Emitted by Bioceramics GB 1378140 A 12 / 1974 Reduced Hypernociception of Inflammatory Origin in Mice Study GB 2073613 A 10 / 1981 presented at the 45th Congress of Pharmacology and Experimental GB 2463264 A 3 / 2010 Therapeutics , Ribeirao Preto , SP , Brazil, 2013 , 4 pages , 2014 .
Load more

Recommended publications
  • Catalysis of the Oxygen Evolution Reaction by 4–10 Nm Cobalt Nanoparticles
    Topics in Catalysis https://doi.org/10.1007/s11244-018-0923-4 ORIGINAL PAPER Catalysis of the Oxygen Evolution Reaction by 4–10 nm Cobalt Nanoparticles Edward Locke1 · Shan Jiang1 · Simon K. Beaumont1 © The Author(s) 2018 Abstract Electrolysis of water is key technology, not only for clean energy production, but to ensure a continued supply of hydrogen beyond fossil resources, essential to the manufacture of many chemical goods other than fuels. Cobalt nanomaterials have been widely identified as a promising candidate for the anode (oxygen evolution) reaction in this process, but much work has focused on applied materials or electrode design. Given the importance of oxidation state changes Co(III) → Co(IV) in the accepted reaction mechanism, in this work we look at size effects in small (4–10 nm) cobalt nanoparticles, where the ease of oxidation for lower cobalt oxidation states is known to change with particle size. To discriminate between geometric and chemical effects we have compared the catalysts in this study to others in the literature by turnover frequency (widely used in other areas of catalysis), in addition to the more commonly employed performance metric of the overpotential required to produce a current density of 10 mA cm−2. Comparisons are drawn to key examples of using well defined nanomaterials (where the surface are of cobalt sites can be estimated). This has enabled an estimated intrinsic turnover rate of ~ 1 O2 mol- ecule per surface Co atom per second at an overpotential of 500 mV in the oxygen evolution reaction under typical alkaline reaction conditions (pH 14.0) to be identified.
    [Show full text]
  • Potential Ivvs.Gelbasedre
    US010644304B2 ( 12 ) United States Patent ( 10 ) Patent No.: US 10,644,304 B2 Ein - Eli et al. (45 ) Date of Patent : May 5 , 2020 (54 ) METHOD FOR PASSIVE METAL (58 ) Field of Classification Search ACTIVATION AND USES THEREOF ??? C25D 5/54 ; C25D 3/665 ; C25D 5/34 ; ( 71) Applicant: Technion Research & Development HO1M 4/134 ; HOTM 4/366 ; HO1M 4/628 ; Foundation Limited , Haifa ( IL ) (Continued ) ( 72 ) Inventors : Yair Ein - Eli , Haifa ( IL ) ; Danny (56 ) References Cited Gelman , Haifa ( IL ) ; Boris Shvartsev , Haifa ( IL ) ; Alexander Kraytsberg , U.S. PATENT DOCUMENTS Yokneam ( IL ) 3,635,765 A 1/1972 Greenberg 3,650,834 A 3/1972 Buzzelli ( 73 ) Assignee : Technion Research & Development Foundation Limited , Haifa ( IL ) (Continued ) ( * ) Notice : Subject to any disclaimer , the term of this FOREIGN PATENT DOCUMENTS patent is extended or adjusted under 35 CN 1408031 4/2003 U.S.C. 154 ( b ) by 56 days . EP 1983078 10/2008 (21 ) Appl. No .: 15 /300,359 ( Continued ) ( 22 ) PCT Filed : Mar. 31 , 2015 OTHER PUBLICATIONS (86 ) PCT No .: PCT/ IL2015 /050350 Hagiwara et al. in ( Acidic 1 - ethyl - 3 -methylimidazoliuum fluoride: a new room temperature ionic liquid in Journal of Fluorine Chem $ 371 (c ) ( 1 ), istry vol . 99 ( 1999 ) p . 1-3 ; ( Year: 1999 ). * (2 ) Date : Sep. 29 , 2016 (Continued ) (87 ) PCT Pub . No .: WO2015 / 151099 Primary Examiner — Jonathan G Jelsma PCT Pub . Date : Oct. 8 , 2015 Assistant Examiner Omar M Kekia (65 ) Prior Publication Data (57 ) ABSTRACT US 2017/0179464 A1 Jun . 22 , 2017 Disclosed is a method for activating a surface of metals , Related U.S. Application Data such as self- passivated metals , and of metal -oxide dissolu tion , effected using a fluoroanion -containing composition .
    [Show full text]
  • 2012 Summer Undergraduate Research Fund (SURF) Recipients
    2012 Summer Undergraduate Research Fund (SURF) Recipients Project Title: Improving Efficiency of Narrative Discourse Analysis in Persons with Brain Injuries Alexandra Addabbo, Communications Disorders , YOG: 2013 Faculty Mentor: Dr. Carl Coelho, Department of Communications Disorders Project Title: The Role of BspA-like Protein in the Microbial Gut Community of Reticulartermes Flavipes and Identification of Species that are Involved in Lignocellulose Degredation Adam Bartholomeo, Molecular and Cell Biology, YOG: 2013 Faculty Mentor: Dr. Daniel Gage, Department of Molecular and Cell Biology Named Award: Ocean Rain Family Foundation Fund for Summer Undergraduate Research Award Project Title: Surveying the Self-Medication Practices of Adults with Sickle Cell Disease Courtney Beyers, Nursing, YOG: 2013 Faculty Mentor: Victoria Odesina, DNP, Department of Nursing Project Title: Investigating of an Efficient System to Harvest Clean Energy from Structural Vibrations Bryan Blanc, Civil Engineering, YOG: 2013 Faculty Mentor: Dr. Ramesh Malla, Department of Civil and Environmental Engineering Named Award: The DeMaio Family Summer Undergraduate Research Fund Project Title: Investigating of an Efficient System to Harvest Clean Energy from Structural Vibrations Kelsey Boch, Chemical Engineering, YOG: 2013 Faculty Mentor: Dr. Yong Wang, Department of Chemical, Materials, and Biomolecular Engineering Project Title: On the Semantic Organization of Concrete and Abstract Terms: a Follow-up to Dunabietia et al. 2009 Christopher Brozowski, Cognitive Science, YOG: 2013 Faculty Mentor: Dr. James Magnuson, Department of Psychology Project Title: Psychological and Emotional Factors to Development in Young Adults with HIV Jenna Burns, Nursing, YOG: 2013 Faculty Mentor: Dr. Elizabeth Anderson, Department of Nursing Project Title: An Investigation into the Synthesis and Reaction Properties of Sulfur Monoxide Casey Camire, Chemistry, YOG: 2014 Faculty Mentor: Dr.
    [Show full text]
  • Nitrato Complexes of Manganese
    NITFLAT0 COMPLEXES OF MANGANESE (II I ) DAVID WILLIAM JOHNSON B.Sc., University of Alberta, Calgary, 1966 A THESIS SUBMITTED IN PARTIAL FULFILMENT OF Tm REQUIREMENTS FOR THE3 DEGRE3E OF DOCTOR OF PHILOSOPHY in the Department of Chemistry 0 DAVID WILLIAM JOHNSON SIMON FRASER UNIVERSITY AUGUST, 1972, APPROVAL Name: David William Johnson Degree : Doctor of Philosophy Title of Thesis: Nitrato Complexes of ~snganese(111) Examining Committee : Chairman: T.N. Bell D. Sutton, denior Supervisor F.W.B, Einstein C.H,W, Jones L.K. Peterson - - N. Paddock, Professor, University of British Columbia Vancouver, B .C . Date Approved : I! Abstract The thesis describes a study of the reactions of a variety of manganese compounds with N204 or N205 leading to the synthesis of new manganese compounds with coordinated nitrate groups and other ligands, The aim of this work, to synthesise the first reported nitrato-complexes of manganese in an oxidation state higher than the common state (II), has been achieved, Manganese(II1) trinitrate, M~L(NO~)~,has been prepared by reaction of manganese(II1) trifluoride and dinitrogen pentoxide in dinltrogen tetroxide, Manganese (111) trinitrate is stable indefinitely below -14OC, but rapidly evolves N204 at room temperature and fumes in moist alr, The properties indicate that all nitrate groups are strongly coordinated and suggest that the compound fs polymeric with bridging nitrate groups. The bipyridyl, -o-phenanthroline, triphenylphosphine oxide and acetonitrile complexes of Mn(N0 have been prepared; all are stable at
    [Show full text]
  • Defect Chemistry and Transport Properties of Solid State Materials for Energy Storage Applications
    University of Kentucky UKnowledge Theses and Dissertations--Chemical and Materials Engineering Chemical and Materials Engineering 2018 DEFECT CHEMISTRY AND TRANSPORT PROPERTIES OF SOLID STATE MATERIALS FOR ENERGY STORAGE APPLICATIONS Xiaowen Zhan University of Kentucky, [email protected] Author ORCID Identifier: https://orcid.org/0000-0002-1422-6233 Digital Object Identifier: https://doi.org/10.13023/etd.2018.418 Right click to open a feedback form in a new tab to let us know how this document benefits ou.y Recommended Citation Zhan, Xiaowen, "DEFECT CHEMISTRY AND TRANSPORT PROPERTIES OF SOLID STATE MATERIALS FOR ENERGY STORAGE APPLICATIONS" (2018). Theses and Dissertations--Chemical and Materials Engineering. 88. https://uknowledge.uky.edu/cme_etds/88 This Doctoral Dissertation is brought to you for free and open access by the Chemical and Materials Engineering at UKnowledge. It has been accepted for inclusion in Theses and Dissertations--Chemical and Materials Engineering by an authorized administrator of UKnowledge. For more information, please contact [email protected]. STUDENT AGREEMENT: I represent that my thesis or dissertation and abstract are my original work. Proper attribution has been given to all outside sources. I understand that I am solely responsible for obtaining any needed copyright permissions. I have obtained needed written permission statement(s) from the owner(s) of each third-party copyrighted matter to be included in my work, allowing electronic distribution (if such use is not permitted by the fair use doctrine) which will be submitted to UKnowledge as Additional File. I hereby grant to The University of Kentucky and its agents the irrevocable, non-exclusive, and royalty-free license to archive and make accessible my work in whole or in part in all forms of media, now or hereafter known.
    [Show full text]
  • Noble Gas Bonding Interactions Involving Xenon Oxides and Fluorides
    molecules Review Noble Gas Bonding Interactions Involving Xenon Oxides and Fluorides Antonio Frontera Department of Chemistry, Universitat de les Illes Balears, Crta de valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), Spain; [email protected] Academic Editor: Felice Grandinetti Received: 17 July 2020; Accepted: 27 July 2020; Published: 28 July 2020 Abstract: Noble gas (or aerogen) bond (NgB) can be outlined as the attractive interaction between an electron-rich atom or group of atoms and any element of Group-18 acting as an electron acceptor. The IUPAC already recommended systematic nomenclature for the interactions of groups 17 and 16 (halogen and chalcogen bonds, respectively). Investigations dealing with noncovalent interactions involving main group elements (acting as Lewis acids) have rapidly grown in recent years. They are becoming acting players in essential fields such as crystal engineering, supramolecular chemistry, and catalysis. For obvious reasons, the works devoted to the study of noncovalent Ng-bonding interactions are significantly less abundant than halogen, chalcogen, pnictogen, and tetrel bonding. Nevertheless, in this short review, relevant theoretical and experimental investigations on noncovalent interactions involving Xenon are emphasized. Several theoretical works have described the physical nature of NgB and their interplay with other noncovalent interactions, which are discussed herein. Moreover, exploring the Cambridge Structural Database (CSD) and Inorganic Crystal Structure Database (ICSD), it is demonstrated that NgB interactions are crucial in governing the X-ray packing of xenon derivatives. Concretely, special attention is given to xenon fluorides and xenon oxides, since they exhibit a strong tendency to establish NgBs. Keywords: noble gas interactions; noncovalent interactions; crystal packing; xenon 1.
    [Show full text]
  • Chemistry of the Noble Gases*
    CHEMISTRY OF THE NOBLE GASES* By Professor K. K. GREE~woon , :.\I.Sc., sc.D .. r".lU.C. University of N ewca.stle 1tpon Tyne The inert gases, or noble gases as they are elements were unsuccessful, and for over now more appropriately called, are a remark­ 60 years they epitomized chemical inertness. able group of elements. The lightest, helium, Indeed, their electron configuration, s2p6, was recognized in the gases of the sun before became known as 'the stable octet,' and this it was isolated on ea.rth as its name (i]A.tos) fotmed the basis of the fit·st electronic theory implies. The first inert gas was isolated in of valency in 1916. Despite this, many 1895 by Ramsay and Rayleigh; it was named people felt that it should be possible to induce argon (apy6s, inert) and occurs to the extent the inert gases to form compounds, and many of 0·93% in the earth's atmosphere. The of the early experiments directed to this end other gases were all isolated before the turn have recently been reviewed.l of the century and were named neon (v€ov, There were several reasons why chemists new), krypton (KpVn'TOV, hidden), xenon believed that the inert gases might form ~€vov, stmnger) and radon (radioactive chemical compounds under the correct con­ emanation). Though they occur much less ditions. For example, the ionization poten­ abundantly than argon they cannot strictly tial of xenon is actually lower than those of be called rare gases; this can be illustrated hydrogen, nitrogen, oxygen, fl uorine and by calculating the volumes occupied a.t s.t.p.
    [Show full text]
  • Sop Pyrophoric 2 12/16/2019
    Owner DOC. NO. REV. DATE C.H.O SOP PYROPHORIC 2 12/16/2019 DOC. TITLE SOP FOR PYROPHORIC CHEMICALS Environmental Health & Safety STANDARD OPERATING PROCEDURES (SOP) FOR WORKING WITH PYROPHORIC CHEMICALS AT AMHERST COLLEGE ___________________________________________________________________ General Information Pyrophoric Chemicals are solid, liquid, or gas compounds that, when exposed to air or moisture at or below 54°C (130°F), can spontaneously ignite. Examples of Pyrophoric chemicals used at Amherst College Laboratories include: sodium hydride, zinc powder, and Grignard reagents. See the “Appendix” page below for a full list of Pyrophoric Chemicals. Pyrophoric chemicals are often used as catalysts in chemical reactions or as reducing and deprotonating agents in organic chemistry. Note that Pyrophoric chemicals may also be characterized by other hazards, hence, users of these chemicals may also need to refer to other SOPs that cover other hazards. In addition, each individual chemical’s Safety Data Sheet (SDS) should be consulted before they are used. _____________________________________________________________________________________ Personal Protective Equipment When working with Pyrophoric Chemicals, the following personal protective equipment (PPE) must be worn, at a minimum. Depending on the specific chemical, other forms of protection might be required. Consult the SDS for each chemical before use: Splash goggles Lab coat (Fire resistant lab coat highly recommended) Long pants Close toed shoes Gloves – Nitrile gloves adequate for accidental contact with small quantities. However, the use of fire resistant Nomex/ Leather Pilot’s gloves is highly recommended _____________________________________________________________________________________ Safety Devices All work with Pyrophoric chemicals must be done in a glove box, vacuum manifold, or any enclosed inert environment. If work must be done in a fume hood, ensure that the hood sash is in the lowest feasible position.
    [Show full text]
  • Lightning in a Test Tube
    Published on ASSIST (https://assist.asta.edu.au) Home > Lightning in a test tube Lightning in a test tube Posted by Anonymous on Thu, 2015-08-20 15:08 Lightning in a test tube: I have a teacher who is planning on performing the 'lightning in a test tube' demonstration in the school lecture theatre. The experiment involves layering ethanol on top of sulfuric acid in a test tube and then dropping some potassium permanganate crystals into the sulfuric acid. I would prefer it to be performed in a fume cupboard. Voting: 0 No votes yet Year Level: 7 8 9 10 Senior Secondary Laboratory Technicians: Laboratory Technicians Showing 1-1 of 1 Responses Lightning in a test tube Submitted by sat on 25 August 2015 Science ASSIST strongly advises against this demonstration being performed in a school. The risks are too high and the demonstration is not able to be adequately controlled. Each of the chemicals involved in this activity has its own particular significant hazards. Ethanol: flammable liquid Sulfuric acid: corrosive acid Potassium permanganate: oxidising agent Sulfuric acid reacts with potassium permanganate to form manganese (VII) oxide (Mn2O7) [also called manganese heptoxide], which is explosive and reacts violently with the ethanol. Significant risks of explosion or fires or both are foreseeable and cannot be controlled, so the risk assessment would conclude that the risks of the demonstration are significant and cannot be adequately controlled at the moment and therefore should not be conducted. An alternative method for demonstrating this
    [Show full text]
  • Mole Ratio Problems
    Name: Answer Key Period: ______ Date: __________ Chem B Problems 1 – 6 for HW, the rest for extra practice/review WS 4.6: Mole Ratio Problems Directions: Solve the Following Problems. Show all work on a separate sheet of paper and box your final answer. 1) How many moles of Nitrogen Dioxide will be made from the reaction of 5.5 moles of Dinitrogen Tetraoxide? N2O4(g) → 2 NO2(g) 11 mol NO2 2) How many moles of NH3 will be produced when 13 moles of H2 reacts? N2(g) + 3 H2(g) → 2 NH3(g) 8.7 mol NH3 3) How many moles of NH3 will be produced when 7.0 moles of N2 reacts? N2(g) + 3 H2(g) → 2 NH3(g) 14 mol NH3 4) How many moles of Technetium(VII) Oxide will can be produced from 3.8 moles of Technetium? 4 Tc + 7 O2 → 2 Tc2O7 1.9 mol Tc2O7 5) Given the reaction below, how many moles of Vandium(II) Chloride will form when 3.22 moles of Hydrogen gas reacts? 2 VCl3 + H2 → 2 VCl2 + 2 HCl 6.44 mol VCl2 6) If 12 moles C8H18 burns in excess oxygen, how many moles of Carbon Dioxide will enter the atmosphere and further contribute to global warming? 2 C8H18(l) + 25 O2(g) → 16 CO2(g) + 18 H2O(g) 96 mol CO2 7) If 45.0 moles of CH4 reacts, how many moles of water will be produce? CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g) 90.0 mol H2O 8) How many moles of lead can be extracted if 50 moles of Carbon are used? 2 PbO + C → 2 Pb + CO2 100 mol Pb 9) For the reaction below, determine how many moles of S2Cl2 formed when 7.80 moles of Sulfur reacts? S8 + 4 Cl2 → 4 S2Cl2 31.2 mol S2Cl2 10) How many moles of Bismuth(III) Sulfate “Bi2(SO4)3” will can be produced if 25.0 moles
    [Show full text]
  • Multi-Ionic Lithium Salts for Use in Solid Polymer
    A Dissertation Submitted to the Temple University Graduate Board In Partial Fulfillment of the Requirements for the Degree by Examining Committee Members: ABSTRACT Commercial lithium ion batteries use liquid electrolytes because of their high ionic conductivity (>10-3 S/cm) over a broad range of temperatures, high dielectric constant, and good electrochemical stability with the electrodes (mainly the cathode). The disadvantages of their use in lithium ion batteries are that they react violently with lithium metal, have special packing needs, and have low lithium ion transference + numbers (tLi = 0.2-0.3). These limitations prevent them from being used in high energy and power applications such as in hybrid electric vehicles (HEVs), plug in electric vehicles (EVs) and energy storage on the grid. Solid polymer electrolytes (SPEs) will be good choice for replacing liquid electrolytes in lithium/lithium ion batteries because of their increased safety and ease of processability. However, SPEs suffer from RT low ionic conductivity and transference numbers. There have been many approaches to increase the ionic conductivity in solid polymer electrolytes. These have focused on decreasing the crystallinity in the most studied polymer electrolyte, polyethylene oxide (PEO), on finding methods to promote directed ion transport, and on the development of single ion conductors, where the anions are + + immobile and only the Li ions migrate (i.e. tLi = 1). But these attempts have not yet achieved the goal of replacing liquid electrolytes with solid polymer electrolytes in lithium ion batteries. In order to increase ionic conductivity and lithium ion transference numbers in solid polymer electrolytes, I have focused on the development of multi-ionic lithium salts.
    [Show full text]
  • Chemical Names and CAS Numbers Final
    Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride
    [Show full text]