Thermal Expansion and Sea Level Rise
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Lasting Coastal Hazards from Past Greenhouse Gas Emissions COMMENTARY Tony E
COMMENTARY Lasting coastal hazards from past greenhouse gas emissions COMMENTARY Tony E. Wonga,1 The emission of greenhouse gases into Earth’satmo- 100% sphereisaby-productofmodernmarvelssuchasthe Extremely likely by 2073−2138 production of vast amounts of energy, heating and 80% cooling inhospitable environments to be amenable to human existence, and traveling great distances 60% Likely by 2064−2105 faster than our saddle-sore ancestors ever dreamed possible. However, these luxuries come at a price: 40% climate changes in the form of severe droughts, ex- Probability treme precipitation and temperatures, increased fre- 20% quency of flooding in coastal cities, global warming, RCP2.6 and sea-level rise (1, 2). Rising seas pose a severe risk RCP8.5 0% to coastal areas across the globe, with billions of 2020 2040 2060 2080 2100 2120 2140 US dollars in assets at risk and about 10% of the ’ Year when 50-cm sea-level rise world s population living within 10 m of sea level threshold is exceeded (3–5). The price of our emissions is not felt immedi- ately throughout the entire climate system, however, Fig. 1. Cumulative probability of exceeding 50 cm of sea-level rise by year (relative to the global mean sea because processes such as ice sheet melt and the level from 1986 to 2005). The yellow box denotes the expansion of warming ocean water act over the range of years after which exceedance is likely [≥66% course of centuries. Thus, even if all greenhouse probability (12)], where the left boundary follows a gas emissions immediately ceased, our past emis- business-as-usual emissions scenario (RCP8.5, red line) sions have already “locked in” some amount of con- and the right boundary follows a low-emissions scenario (RCP2.6, blue line). -
Hydrothermal Vents. Teacher's Notes
Hydrothermal Vents Hydrothermal Vents. Teacher’s notes. A hydrothermal vent is a fissure in a planet's surface from which geothermally heated water issues. They are usually volcanically active. Seawater penetrates into fissures of the volcanic bed and interacts with the hot, newly formed rock in the volcanic crust. This heated seawater (350-450°) dissolves large amounts of minerals. The resulting acidic solution, containing metals (Fe, Mn, Zn, Cu) and large amounts of reduced sulfur and compounds such as sulfides and H2S, percolates up through the sea floor where it mixes with the cold surrounding ocean water (2-4°) forming mineral deposits and different types of vents. In the resulting temperature gradient, these minerals provide a source of energy and nutrients to chemoautotrophic organisms that are, thus, able to live in these extreme conditions. This is an extreme environment with high pressure, steep temperature gradients, and high concentrations of toxic elements such as sulfides and heavy metals. Black and white smokers Some hydrothermal vents form a chimney like structure that can be as 60m tall. They are formed when the minerals that are dissolved in the fluid precipitates out when the super-heated water comes into contact with the freezing seawater. The minerals become particles with high sulphur content that form the stack. Black smokers are very acidic typically with a ph. of 2 (around that of vinegar). A black smoker is a type of vent found at depths typically below 3000m that emit a cloud or black material high in sulphates. White smokers are formed in a similar way but they emit lighter-hued minerals, for example barium, calcium and silicon. -
Introduction to Co2 Chemistry in Sea Water
INTRODUCTION TO CO2 CHEMISTRY IN SEA WATER Andrew G. Dickson Scripps Institution of Oceanography, UC San Diego Mauna Loa Observatory, Hawaii Monthly Average Carbon Dioxide Concentration Data from Scripps CO Program Last updated August 2016 2 ? 410 400 390 380 370 2008; ~385 ppm 360 350 Concentration (ppm) 2 340 CO 330 1974; ~330 ppm 320 310 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 Year EFFECT OF ADDING CO2 TO SEA WATER 2− − CO2 + CO3 +H2O ! 2HCO3 O C O CO2 1. Dissolves in the ocean increase in decreases increases dissolved CO2 carbonate bicarbonate − HCO3 H O O also hydrogen ion concentration increases C H H 2. Reacts with water O O + H2O to form bicarbonate ion i.e., pH = –lg [H ] decreases H+ and hydrogen ion − HCO3 and saturation state of calcium carbonate decreases H+ 2− O O CO + 2− 3 3. Nearly all of that hydrogen [Ca ][CO ] C C H saturation Ω = 3 O O ion reacts with carbonate O O state K ion to form more bicarbonate sp (a measure of how “easy” it is to form a shell) M u l t i p l e o b s e r v e d indicators of a changing global carbon cycle: (a) atmospheric concentrations of carbon dioxide (CO2) from Mauna Loa (19°32´N, 155°34´W – red) and South Pole (89°59´S, 24°48´W – black) since 1958; (b) partial pressure of dissolved CO2 at the ocean surface (blue curves) and in situ pH (green curves), a measure of the acidity of ocean water. -
Thermal Properties and the Prospects of Thermal Energy Storage of Mg–25%Cu–15%Zn Eutectic Alloy As Phasechange Material
materials Article Thermal Properties and the Prospects of Thermal Energy Storage of Mg–25%Cu–15%Zn Eutectic Alloy as Phase Change Material Zheng Sun , Linfeng Li, Xiaomin Cheng *, Jiaoqun Zhu, Yuanyuan Li and Weibing Zhou School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China; [email protected] (Z.S.); [email protected] (L.L.); [email protected] (J.Z.); [email protected] (Y.L.); [email protected] (W.Z.) * Correspondence: [email protected]; Tel.: +86-13507117513 Abstract: This study focuses on the characterization of eutectic alloy, Mg–25%Cu–15%Zn with a phase change temperature of 452.6 ◦C, as a phase change material (PCM) for thermal energy storage (TES). The phase composition, microstructure, phase change temperature and enthalpy of the alloy were investigated after 100, 200, 400 and 500 thermal cycles. The results indicate that no considerable phase transformation and structural change occurred, and only a small decrease in phase transition temperature and enthalpy appeared in the alloy after 500 thermal cycles, which implied that the Mg–25%Cu–15%Zn eutectic alloy had thermal reliability with respect to repeated thermal cycling, which can provide a theoretical basis for industrial application. Thermal expansion and thermal Citation: Sun, Z.; Li, L.; Cheng, X.; conductivity of the alloy between room temperature and melting temperature were also determined. Zhu, J.; Li, Y.; Zhou, W. Thermal The thermophysical properties demonstrated that the Mg–25%Cu–15%Zn eutectic alloy can be Properties and the Prospects of considered a potential PCM for TES. -
Sea-Level Rise for the Coasts of California, Oregon, and Washington: Past, Present, and Future
Sea-Level Rise for the Coasts of California, Oregon, and Washington: Past, Present, and Future As more and more states are incorporating projections of sea-level rise into coastal planning efforts, the states of California, Oregon, and Washington asked the National Research Council to project sea-level rise along their coasts for the years 2030, 2050, and 2100, taking into account the many factors that affect sea-level rise on a local scale. The projections show a sharp distinction at Cape Mendocino in northern California. South of that point, sea-level rise is expected to be very close to global projections; north of that point, sea-level rise is projected to be less than global projections because seismic strain is pushing the land upward. ny significant sea-level In compliance with a rise will pose enor- 2008 executive order, mous risks to the California state agencies have A been incorporating projec- valuable infrastructure, devel- opment, and wetlands that line tions of sea-level rise into much of the 1,600 mile shore- their coastal planning. This line of California, Oregon, and study provides the first Washington. For example, in comprehensive regional San Francisco Bay, two inter- projections of the changes in national airports, the ports of sea level expected in San Francisco and Oakland, a California, Oregon, and naval air station, freeways, Washington. housing developments, and sports stadiums have been Global Sea-Level Rise built on fill that raised the land Following a few thousand level only a few feet above the years of relative stability, highest tides. The San Francisco International Airport (center) global sea level has been Sea-level change is linked and surrounding areas will begin to flood with as rising since the late 19th or to changes in the Earth’s little as 40 cm (16 inches) of sea-level rise, a early 20th century, when climate. -
Causes of Sea Level Rise
FACT SHEET Causes of Sea OUR COASTAL COMMUNITIES AT RISK Level Rise What the Science Tells Us HIGHLIGHTS From the rocky shoreline of Maine to the busy trading port of New Orleans, from Roughly a third of the nation’s population historic Golden Gate Park in San Francisco to the golden sands of Miami Beach, lives in coastal counties. Several million our coasts are an integral part of American life. Where the sea meets land sit some of our most densely populated cities, most popular tourist destinations, bountiful of those live at elevations that could be fisheries, unique natural landscapes, strategic military bases, financial centers, and flooded by rising seas this century, scientific beaches and boardwalks where memories are created. Yet many of these iconic projections show. These cities and towns— places face a growing risk from sea level rise. home to tourist destinations, fisheries, Global sea level is rising—and at an accelerating rate—largely in response to natural landscapes, military bases, financial global warming. The global average rise has been about eight inches since the centers, and beaches and boardwalks— Industrial Revolution. However, many U.S. cities have seen much higher increases in sea level (NOAA 2012a; NOAA 2012b). Portions of the East and Gulf coasts face a growing risk from sea level rise. have faced some of the world’s fastest rates of sea level rise (NOAA 2012b). These trends have contributed to loss of life, billions of dollars in damage to coastal The choices we make today are critical property and infrastructure, massive taxpayer funding for recovery and rebuild- to protecting coastal communities. -
Temperature & Thermal Expansion
Temperature & Thermal Expansion Temperature Zeroth Law of Thermodynamics Temperature Measurement Thermal Expansion Homework Temperature & Thermal Equilibrium Temperature – Fundamental physical quantity – Measure of average kinetic energy of molecular motion Thermal equilibrium – Two objects in thermal contact cease to have an exchange of energy The Zeroth Law of Thermodynamics If objects A and B are separately in thermal equilibrium with a third object C (the thermometer), the A and B are in thermal equilibrium with each other. Temperature Measurement In principle, any system whose physical properties change with tempera- ture can be used as a thermometer Some physical properties commonly used are – The volume of a liquid – The length of a solid – The electrical resistance of a conductor – The pressure of a gas held at constant volume – The volume of a gas held at constant pressure The Glass-Bulb Thermometer Common thermometer in everyday use Physical property that changes is the volume of a liquid - usually mercury or alcohol Since the cross-sectional area of the capillary tube is constant, the change in volume varies linearly with its length along the tube Calibrating the Thermometer The thermometer can be calibrated by putting it in thermal equilibrium with environments at known temperatures and marking the end of the liquid column Commonly used environments are – Ice-water mixture in equilibrium at the freezing point of water – Water-steam mixture in equilibrium at the boiling point of water Once the ends of the liquid column have -
Thermal Expansion
Protection from Protect Your Thermal Expansion Water Heater from Protection from thermal expansion is provided in a For further plumbing system by the installation of a thermal expansion tank and a temperature and information Thermal pressure relief valve (T & P Valve) at the top of the tank. contact your Expansion The thermal expansion tank controls the increased local water pressure generated within the normal operating temperature range of the water heater. The small purveyor, tank with a sealed compressible air cushion Without a functioning provides a space to store and hold the additional expanded water volume. City or County Temperature & building The T & P Valve is the primary safety feature for the water heater. The temperature portion of the Pressure Relief Valve T & P Valve is designed to open and vent water department, to the atmosphere whenever the water your water heater can temperature within the tank reaches approxi- licensed plumber º º mately 210 F (99 C). Venting allows cold water to enter the tank. or the The pressure portion of a T & P Valve is designed PNWS/AWWA to open and vent to the atmosphere whenever water pressure within the tank exceeds the Cross-Connection pressure setting on the valve. The T & P Valve is normally pre-set at 125 psi or 150 psi. Control Committee through the Water heaters installed in compliance with the current plumbing code will have the required T & P PNWS office at Valve and thermal expansion tank. For public health protection, the water purveyor may require (877) 767-2992 the installation of a check valve or backflow preventer downstream of the water meter. -
Lecture 15 November 7, 2019 1 / 26 Counting
...Thermodynamics Positive specific heats and compressibility Negative elastic moduli and auxetic materials Clausius Clapeyron Relation for Phase boundary \Phase" defined by discontinuities in state variables Gibbs-Helmholtz equation to calculate G Lecture 15 November 7, 2019 1 / 26 Counting There are five laws of Thermodynamics. 5,4,3,2 ... ? Laws of Thermodynamics 2, 1, 0, 3, and ? Lecture 15 November 7, 2019 2 / 26 Third Law What is the entropy at absolute zero? Z T dQ S = + S0 0 T Unless S = 0 defined, ratios of entropies S1=S2 are meaningless. Lecture 15 November 7, 2019 3 / 26 The Nernst Heat Theorem (1926) Consider a system undergoing a pro- cess between initial and final equilibrium states as a result of external influences, such as pressure. The system experiences a change in entropy, and the change tends to zero as the temperature char- acterising the process tends to zero. Lecture 15 November 7, 2019 4 / 26 Nernst Heat Theorem: based on Experimental observation For any exothermic isothermal chemical process. ∆H increases with T, ∆G decreases with T. He postulated that at T=0, ∆G = ∆H ∆G = Gf − Gi = ∆H − ∆(TS) = Hf − Hi − T (Sf − Si ) = ∆H − T ∆S So from Nernst's observation d (∆H − ∆G) ! 0 =) ∆S ! 0 As T ! 0, observed that dT ∆G ! ∆H asymptotically Lecture 15 November 7, 2019 5 / 26 ITMA Planck statement of the Third Law: The entropy of all perfect crystals is the same at absolute zero, and may be taken to be zero. Lecture 15 November 7, 2019 6 / 26 Planck Third Law All perfect crystals have the same entropy at T = 0. -
OCEAN WARMING • the Ocean Absorbs Most of the Excess Heat from Greenhouse Gas Emissions, Leading to Rising Ocean Temperatures
NOVEMBER 2017 OCEAN WARMING • The ocean absorbs most of the excess heat from greenhouse gas emissions, leading to rising ocean temperatures. • Increasing ocean temperatures affect marine species and ecosystems. Rising temperatures cause coral bleaching and the loss of breeding grounds for marine fishes and mammals. • Rising ocean temperatures also affect the benefits humans derive from the ocean – threatening food security, increasing the prevalence of diseases and causing more extreme weather events and the loss of coastal protection. • Achieving the mitigation targets set by the Paris Agreement on climate change and limiting the global average temperature increase to well below 2°C above pre-industrial levels is crucial to prevent the massive, irreversible impacts of ocean warming on marine ecosystems and their services. • Establishing marine protected areas and putting in place adaptive measures, such as precautionary catch limits to prevent overfishing, can protect ocean ecosystems and shield humans from the effects of ocean warming. The distribution of excess heat in the ocean is not What is the issue? uniform, with the greatest ocean warming occurring in The ocean absorbs vast quantities of heat as a result the Southern Hemisphere and contributing to the of increased concentrations of greenhouse gases in subsurface melting of Antarctic ice shelves. the atmosphere, mainly from fossil fuel consumption. The Fifth Assessment Report published by the Intergovernmental Panel on Climate Change (IPCC) in 2013 revealed that the ocean had absorbed more than 93% of the excess heat from greenhouse gas emissions since the 1970s. This is causing ocean temperatures to rise. Data from the US National Oceanic and Atmospheric Administration (NOAA) shows that the average global sea surface temperature – the temperature of the upper few metres of the ocean – has increased by approximately 0.13°C per decade over the past 100 years. -
The Coefficient of Thermal Expansion and Your Heating System By: Admin - May 06, 2021
The Coefficient of Thermal Expansion and your Heating System By: Admin - May 06, 2021 We’ve all been there. The lid on pickle jar is impossibly tight, but when you run hot water over the jar you can easily unscrew the lid. The metal lid expands more than the glass jar, which is a simple illustration of how materials, when heated, expand at different rates. The relationship of how materials expand or contract through temperature change is driven by the coefficient of thermal expansion or CTE of those materials and is a critical factor when designing a heater. Determining the appropriate materials for the heater is not as simple as running warm water over a metal lid. The coefficient of thermal expansion is a critical factor when pairing dissimilar materials in a system. With the help of Watlow representatives, you can make sure your system is designed for success, efficiency and a long lifespan. What is the coefficient of thermal expansion? To understand the science behind the coefficient of thermal expansion (CTE), one must first understand the basics of thermal expansion. Physical property changes, such as shape, area, volume and density, occur during thermal expansion. Every material or metal/metal alloy will have a slightly different expansion rate. CTE, then, is the relative expansion or contraction of materials driven by a change in temperature. Metals, ceramics and other materials have unique coefficients of thermal expansion and do not expand and contract at equal rates. For example, if the volume of a section of aluminum and a section of ceramic are equal and are heated from X to Y degrees, the aluminum could increase in dimension by a factor of four compared to the ceramic. -
Microbiology of Seamounts Is Still in Its Infancy
or collective redistirbution of any portion of this article by photocopy machine, reposting, or other means is permitted only with the approval of The approval portionthe ofwith any articlepermitted only photocopy by is of machine, reposting, this means or collective or other redistirbution This article has This been published in MOUNTAINS IN THE SEA Oceanography MICROBIOLOGY journal of The 23, Number 1, a quarterly , Volume OF SEAMOUNTS Common Patterns Observed in Community Structure O ceanography ceanography S BY DAVID EmERSON AND CRAIG L. MOYER ociety. © 2010 by The 2010 by O ceanography ceanography O ceanography ceanography ABSTRACT. Much interest has been generated by the discoveries of biodiversity InTRODUCTION S ociety. ociety. associated with seamounts. The volcanically active portion of these undersea Microbial life is remarkable for its resil- A mountains hosts a remarkably diverse range of unusual microbial habitats, from ience to extremes of temperature, pH, article for use and research. this copy in teaching to granted ll rights reserved. is Permission S ociety. ociety. black smokers rich in sulfur to cooler, diffuse, iron-rich hydrothermal vents. As and pressure, as well its ability to persist S such, seamounts potentially represent hotspots of microbial diversity, yet our and thrive using an amazing number or Th e [email protected] to: correspondence all end understanding of the microbiology of seamounts is still in its infancy. Here, we of organic or inorganic food sources. discuss recent work on the detection of seamount microbial communities and the Nowhere are these traits more evident observation that specific community groups may be indicative of specific geochemical than in the deep ocean.