Thermal Energy
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Thermal Properties and the Prospects of Thermal Energy Storage of Mg–25%Cu–15%Zn Eutectic Alloy As Phasechange Material
materials Article Thermal Properties and the Prospects of Thermal Energy Storage of Mg–25%Cu–15%Zn Eutectic Alloy as Phase Change Material Zheng Sun , Linfeng Li, Xiaomin Cheng *, Jiaoqun Zhu, Yuanyuan Li and Weibing Zhou School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China; [email protected] (Z.S.); [email protected] (L.L.); [email protected] (J.Z.); [email protected] (Y.L.); [email protected] (W.Z.) * Correspondence: [email protected]; Tel.: +86-13507117513 Abstract: This study focuses on the characterization of eutectic alloy, Mg–25%Cu–15%Zn with a phase change temperature of 452.6 ◦C, as a phase change material (PCM) for thermal energy storage (TES). The phase composition, microstructure, phase change temperature and enthalpy of the alloy were investigated after 100, 200, 400 and 500 thermal cycles. The results indicate that no considerable phase transformation and structural change occurred, and only a small decrease in phase transition temperature and enthalpy appeared in the alloy after 500 thermal cycles, which implied that the Mg–25%Cu–15%Zn eutectic alloy had thermal reliability with respect to repeated thermal cycling, which can provide a theoretical basis for industrial application. Thermal expansion and thermal Citation: Sun, Z.; Li, L.; Cheng, X.; conductivity of the alloy between room temperature and melting temperature were also determined. Zhu, J.; Li, Y.; Zhou, W. Thermal The thermophysical properties demonstrated that the Mg–25%Cu–15%Zn eutectic alloy can be Properties and the Prospects of considered a potential PCM for TES. -
HEAT and TEMPERATURE Heat Is a Type of ENERGY. When Absorbed
HEAT AND TEMPERATURE Heat is a type of ENERGY. When absorbed by a substance, heat causes inter-particle bonds to weaken and break which leads to a change of state (solid to liquid for example). Heat causing a phase change is NOT sufficient to cause an increase in temperature. Heat also causes an increase of kinetic energy (motion, friction) of the particles in a substance. This WILL cause an increase in TEMPERATURE. Temperature is NOT energy, only a measure of KINETIC ENERGY The reason why there is no change in temperature at a phase change is because the substance is using the heat only to change the way the particles interact (“stick together”). There is no increase in the particle motion and hence no rise in temperature. THERMAL ENERGY is one type of INTERNAL ENERGY possessed by an object. It is the KINETIC ENERGY component of the object’s internal energy. When thermal energy is transferred from a hot to a cold body, the term HEAT is used to describe the transferred energy. The hot body will decrease in temperature and hence in thermal energy. The cold body will increase in temperature and hence in thermal energy. Temperature Scales: The K scale is the absolute temperature scale. The lowest K temperature, 0 K, is absolute zero, the temperature at which an object possesses no thermal energy. The Celsius scale is based upon the melting point and boiling point of water at 1 atm pressure (0, 100o C) K = oC + 273.13 UNITS OF HEAT ENERGY The unit of heat energy we will use in this lesson is called the JOULE (J). -
A Comprehensive Review of Thermal Energy Storage
sustainability Review A Comprehensive Review of Thermal Energy Storage Ioan Sarbu * ID and Calin Sebarchievici Department of Building Services Engineering, Polytechnic University of Timisoara, Piata Victoriei, No. 2A, 300006 Timisoara, Romania; [email protected] * Correspondence: [email protected]; Tel.: +40-256-403-991; Fax: +40-256-403-987 Received: 7 December 2017; Accepted: 10 January 2018; Published: 14 January 2018 Abstract: Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included. Keywords: storage system; phase-change materials; chemical storage; cold storage; performance 1. Introduction Recent projections predict that the primary energy consumption will rise by 48% in 2040 [1]. On the other hand, the depletion of fossil resources in addition to their negative impact on the environment has accelerated the shift toward sustainable energy sources. -
IB Questionbank
Topic 3 Past Paper [94 marks] This question is about thermal energy transfer. A hot piece of iron is placed into a container of cold water. After a time the iron and water reach thermal equilibrium. The heat capacity of the container is negligible. specific heat capacity. [2 marks] 1a. Define Markscheme the energy required to change the temperature (of a substance) by 1K/°C/unit degree; of mass 1 kg / per unit mass; [5 marks] 1b. The following data are available. Mass of water = 0.35 kg Mass of iron = 0.58 kg Specific heat capacity of water = 4200 J kg–1K–1 Initial temperature of water = 20°C Final temperature of water = 44°C Initial temperature of iron = 180°C (i) Determine the specific heat capacity of iron. (ii) Explain why the value calculated in (b)(i) is likely to be different from the accepted value. Markscheme (i) use of mcΔT; 0.58×c×[180-44]=0.35×4200×[44-20]; c=447Jkg-1K-1≈450Jkg-1K-1; (ii) energy would be given off to surroundings/environment / energy would be absorbed by container / energy would be given off through vaporization of water; hence final temperature would be less; hence measured value of (specific) heat capacity (of iron) would be higher; This question is in two parts. Part 1 is about ideal gases and specific heat capacity. Part 2 is about simple harmonic motion and waves. Part 1 Ideal gases and specific heat capacity State assumptions of the kinetic model of an ideal gas. [2 marks] 2a. two Markscheme point molecules / negligible volume; no forces between molecules except during contact; motion/distribution is random; elastic collisions / no energy lost; obey Newton’s laws of motion; collision in zero time; gravity is ignored; [4 marks] 2b. -
Thermal Energy: Using Water to Heat a School
Thermal Energy: Using Water to Heat a School Investigation Notebook NYC Edition © 2018 by The Regents of the University of California. All rights reserved. No part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage or retrieval system, without permission in writing from the publisher. Teachers purchasing this Investigation Notebook as part of a kit may reproduce the book herein in sufficient quantities for classroom use only and not for resale. These materials are based upon work partially supported by the National Science Foundation under grant numbers DRL-1119584, DRL-1417939, ESI-0242733, ESI-0628272, ESI-0822119. The Federal Government has certain rights in this material. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation. These materials are based upon work partially supported by the Institute of Education Sciences, U.S. Department of Education, through Grant R305A130610 to The Regents of the University of California. The opinions expressed are those of the authors and do not represent views of the Institute or the U.S. Department of Education. Developed by the Learning Design Group at the University of California, Berkeley’s Lawrence Hall of Science. Amplify. 55 Washington Street, Suite 800 Brooklyn, NY 11201 1-800-823-1969 www.amplify.com Thermal Energy: Using Water to Heat a School -
Temperature & Thermal Expansion
Temperature & Thermal Expansion Temperature Zeroth Law of Thermodynamics Temperature Measurement Thermal Expansion Homework Temperature & Thermal Equilibrium Temperature – Fundamental physical quantity – Measure of average kinetic energy of molecular motion Thermal equilibrium – Two objects in thermal contact cease to have an exchange of energy The Zeroth Law of Thermodynamics If objects A and B are separately in thermal equilibrium with a third object C (the thermometer), the A and B are in thermal equilibrium with each other. Temperature Measurement In principle, any system whose physical properties change with tempera- ture can be used as a thermometer Some physical properties commonly used are – The volume of a liquid – The length of a solid – The electrical resistance of a conductor – The pressure of a gas held at constant volume – The volume of a gas held at constant pressure The Glass-Bulb Thermometer Common thermometer in everyday use Physical property that changes is the volume of a liquid - usually mercury or alcohol Since the cross-sectional area of the capillary tube is constant, the change in volume varies linearly with its length along the tube Calibrating the Thermometer The thermometer can be calibrated by putting it in thermal equilibrium with environments at known temperatures and marking the end of the liquid column Commonly used environments are – Ice-water mixture in equilibrium at the freezing point of water – Water-steam mixture in equilibrium at the boiling point of water Once the ends of the liquid column have -
Thermal Expansion
Protection from Protect Your Thermal Expansion Water Heater from Protection from thermal expansion is provided in a For further plumbing system by the installation of a thermal expansion tank and a temperature and information Thermal pressure relief valve (T & P Valve) at the top of the tank. contact your Expansion The thermal expansion tank controls the increased local water pressure generated within the normal operating temperature range of the water heater. The small purveyor, tank with a sealed compressible air cushion Without a functioning provides a space to store and hold the additional expanded water volume. City or County Temperature & building The T & P Valve is the primary safety feature for the water heater. The temperature portion of the Pressure Relief Valve T & P Valve is designed to open and vent water department, to the atmosphere whenever the water your water heater can temperature within the tank reaches approxi- licensed plumber º º mately 210 F (99 C). Venting allows cold water to enter the tank. or the The pressure portion of a T & P Valve is designed PNWS/AWWA to open and vent to the atmosphere whenever water pressure within the tank exceeds the Cross-Connection pressure setting on the valve. The T & P Valve is normally pre-set at 125 psi or 150 psi. Control Committee through the Water heaters installed in compliance with the current plumbing code will have the required T & P PNWS office at Valve and thermal expansion tank. For public health protection, the water purveyor may require (877) 767-2992 the installation of a check valve or backflow preventer downstream of the water meter. -
Thermal Profiling of Residential Energy Consumption
1 Thermal profiling of residential energy consumption Adrian Albert and Ram Rajagopal Abstract—Demand Response (DR) programs aim to dynami- the thermal mass of the premise may act as “thermal bat- cally match consumption on the grid with available supply in tery”. Affecting the thermally-sensitive load may be typically real-time. Understanding the patterns in demand of individuals achieved through direct load control of the HVAC system (e.g., is now being facilitated by granular consumption data collected load curtailment or automatic adjustment of the thermostat via smart meter sensors that power utility companies have rolled setpoint), through adjustable rates (e.g., critical peak pricing), out at scale. In this paper we propose a dynamic model that uses or through incentive schemes [4], [5]. hourly electricity and weather readings to characterize residential users’ thermally-sensitive consumption. From this model we Here we propose a simple model of consumption for a extract useful benchmarks to build profiles of individual users residential premise that is driven by unobserved “occupancy for use with DR programs that focus on temperature-dependent states” that have different responses to ambient weather. These consumption such as air conditioning or heating. We present are consumption regimes of a given household that depend on example profiles generated using our model on real consumers, lifestyle (work schedule, familial composition etc.), premise and show its performance on a large sample of residential characteristics (heating/cooling mass, square footage etc.), users. We then compute metrics that allow us to segment the appliance stock, and weather patterns. It is a daunting task population dynamically for the purpose of a thermally-motivated to disentangle how much energy each of these components DR program. -
Introducing Electric Thermal Energy Storage (ETES) – Putting Gigawatt Hours of Energy at Your Command
Same forces. New rules. Introducing Electric Thermal Energy Storage (ETES) – putting gigawatt hours of energy at your command. Impossible is just another word for never done before. 100% renewables is said to be impossible. As were the first flight, space travel, the internet … Now here is something that makes a complete energy transition possible: Electric Thermal Energy Storage (ETES). A proven energy storage solution that is inexpensive, built with 80% off-the-shelf components, and scalable to several GWh. No need to explain that ETES is a giant step – for SGRE and for the energy industry. While the forces of nature remain the same, Electric Thermal Energy Storage has launched a new era. Find out how it will boost the energy transition and how new players, energy-intensive companies and even conventional power plants will profit from it. Or, in short: time for new rules. Welcome TiteltextRule #1: Power in. Power out. ETES is technology that can be charged with electricity or directly with heat and which then releases heat that, in return, can generate electricity. Unlike other storage technologies, it is made of rocks absorbing heat. This makes ETES very sustainable in design and the first gigawatt-hour scale energy storage that can be built almost anywhere – limiting its size and use only to your imagination. Flexible scalability of charging power, discharging power and storage capacity. Proven, reliable technology – discharging technology used for more than a 100 years. Cost-competitive, GWh scale, multiple revenue streams. ETES technology TiteltextRule #2: If it works for you, it works for all. ETES solutions basically prolong the availability of ETES and all of its components are fully scalable energy that otherwise would be “wasted“. -
Lecture 15 November 7, 2019 1 / 26 Counting
...Thermodynamics Positive specific heats and compressibility Negative elastic moduli and auxetic materials Clausius Clapeyron Relation for Phase boundary \Phase" defined by discontinuities in state variables Gibbs-Helmholtz equation to calculate G Lecture 15 November 7, 2019 1 / 26 Counting There are five laws of Thermodynamics. 5,4,3,2 ... ? Laws of Thermodynamics 2, 1, 0, 3, and ? Lecture 15 November 7, 2019 2 / 26 Third Law What is the entropy at absolute zero? Z T dQ S = + S0 0 T Unless S = 0 defined, ratios of entropies S1=S2 are meaningless. Lecture 15 November 7, 2019 3 / 26 The Nernst Heat Theorem (1926) Consider a system undergoing a pro- cess between initial and final equilibrium states as a result of external influences, such as pressure. The system experiences a change in entropy, and the change tends to zero as the temperature char- acterising the process tends to zero. Lecture 15 November 7, 2019 4 / 26 Nernst Heat Theorem: based on Experimental observation For any exothermic isothermal chemical process. ∆H increases with T, ∆G decreases with T. He postulated that at T=0, ∆G = ∆H ∆G = Gf − Gi = ∆H − ∆(TS) = Hf − Hi − T (Sf − Si ) = ∆H − T ∆S So from Nernst's observation d (∆H − ∆G) ! 0 =) ∆S ! 0 As T ! 0, observed that dT ∆G ! ∆H asymptotically Lecture 15 November 7, 2019 5 / 26 ITMA Planck statement of the Third Law: The entropy of all perfect crystals is the same at absolute zero, and may be taken to be zero. Lecture 15 November 7, 2019 6 / 26 Planck Third Law All perfect crystals have the same entropy at T = 0. -
The Coefficient of Thermal Expansion and Your Heating System By: Admin - May 06, 2021
The Coefficient of Thermal Expansion and your Heating System By: Admin - May 06, 2021 We’ve all been there. The lid on pickle jar is impossibly tight, but when you run hot water over the jar you can easily unscrew the lid. The metal lid expands more than the glass jar, which is a simple illustration of how materials, when heated, expand at different rates. The relationship of how materials expand or contract through temperature change is driven by the coefficient of thermal expansion or CTE of those materials and is a critical factor when designing a heater. Determining the appropriate materials for the heater is not as simple as running warm water over a metal lid. The coefficient of thermal expansion is a critical factor when pairing dissimilar materials in a system. With the help of Watlow representatives, you can make sure your system is designed for success, efficiency and a long lifespan. What is the coefficient of thermal expansion? To understand the science behind the coefficient of thermal expansion (CTE), one must first understand the basics of thermal expansion. Physical property changes, such as shape, area, volume and density, occur during thermal expansion. Every material or metal/metal alloy will have a slightly different expansion rate. CTE, then, is the relative expansion or contraction of materials driven by a change in temperature. Metals, ceramics and other materials have unique coefficients of thermal expansion and do not expand and contract at equal rates. For example, if the volume of a section of aluminum and a section of ceramic are equal and are heated from X to Y degrees, the aluminum could increase in dimension by a factor of four compared to the ceramic. -
Lesson 8 Energy in Chemical Reactions Review
Name __________________________________________________ Date ______________________________ Lesson 8 Energy in Chemical Reactions Review Main Ideas Read each item. Then select the letter next to the best answer. 1. An ice pack is activated and placed on a person’s wrist. After the resulting chemical reaction, the average temperature of the hands-icepack system is lower. Which of the following statements best completes a statement about the transfer of energy in this chemical reaction. This reaction is: A. endothermic, because more thermal energy is absorbed than released. B. endothermic, because more thermal energy is released than absorbed. C. exothermic, because more thermal energy is absorbed than released. D. exothermic, because more thermal energy is released than absorbed. 2. Calcium ammonium nitrate is a chemical used in fertilizers. It can also be used to make an instant ice-pack. When the calcium ammonium nitrate is allowed to mix with the water inside the ice pack, a chemical reaction takes place. This reaction cannot occur on its own because it needs a source of heat to continue until it is complete. Which statement best describes the type of chemical reaction and the source of heat? A. Endothermic reaction, and the heat comes out of the water. B. Exothermic reaction, and the heat comes out of the water. C. Exothermic reaction, and the heat comes out of the reaction. D. Endothermic reaction, and the heat comes out of the reaction. 3. When a candle burns, a chemical reaction occurs changing wax and oxygen into carbon dioxide and water vapor. The average temperature of the candle-room system increases.