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PHYSICS 149: Lecture 26

• Chapter 14:

– 14.1 Internal – 14.2 Heat – 14.3 and Specific Heat – 14.5 Transitions – 14.6 Thermal Conduction – 14.7 Thermal – 14.8 Thermal Radiation

Lecture 26 Purdue University, Physics 149 1 Final Exam • Wednesday, December 15, 8:00 – 10:00 AM • Place: MSEE B012 • Chapters 1 – 15 (only the sections we covered) • The exam is closed book. • The exam is a multiple-choice test. • There will be 30 multiple-choice problems. – Each problem is worth 10 points. • You may make a single crib sheet. – you may write on both sides of an 8.5” × 11.0” sheet.

• Review session on Monday • Course Evaluation: – courseval.itap.purdue.edu/etw/ets/et.asp?nxappid=WCQ&nxmid=start&s=8 – open until 12/12/2010 Lecture 10 Purdue University, Physics 149 2 ILQ 1

The intensity of a sound wave is directly proportional to

A) the frequency B) the square of the speed of sound C) the amplitude D) the square of the amplitude

Lecture 26 Purdue University, Physics 149 3 ILQ 2

An open (open at both ends) has a length of 50 cm. What is the wavelength of the second harmonic frequency?

A) 25 cm B) 50 cm C) 75 cm D) 100 cm

Lecture 26 Purdue University, Physics 149 4 • The internal energy of a system is the total energy of all of the molecules in the system except for the macroscopic (kinetic energy associated with macroscopic translation or rotation) and the external potential energy (energy due to external interactions).

• Internal energy includes – Translational kinetic energy of the molecules • the average translational kinetic energy of the molecules of an = (3/2)⋅k⋅TSI (Note: TSI in K) – Rotational and vibrational kinetic energy of the molecules – Potential energy between molecules – Chemical and nuclear binding energy of the molecules

• Internal energy does not include – any energy related to outside or macroscopic sources or motions, like • overall translational energy of the system • potential energy due to external fields such as gravity.

Lecture 26 Purdue University, Physics 149 5 Energy Conversion: Joule’s Experiment

As the two masses fall, they cause paddles to rotate. – Gravitational potential energy is converted into kinetic energy of the paddle wheel. As the paddles agitate the , it causes water’s rise. – Kinetic energy of the paddle wheel is converted into internal energy.

Lecture 26 Purdue University, Physics 149 6 Heat

• Definition: Flow of energy between two objects due to difference in temperature – Note: similar to – Object does not “have” heat (it has energy)

• Units: calorie – Amount of heat needed to raise 1g of water 1ºC – 1 Calorie = 1 kcal = 1000 cal = 4186 Joules • Heat flows from a system at higher temperature to one at lower temperature

Lecture 26 Purdue University, Physics 149 7 The Cause of Thermal Expansion

• Objects expand when their increase because the vibrational energy of their molecules increases; this makes the average distance between molecules increase. – Example: -in- relies on thermal expansion of the or alcohol.

Lecture 26 Purdue University, Physics 149 8 Thermal Expansion • When temperature rises – molecules have more kinetic energy • they are moving faster, on the average – consequently, things tend to expand • Amount of expansion depends on… – change in temperature Temp: T L – original length 0 Temp: T+ΔT – coefficient of thermal expansion ΔL •L0 + ΔL = L0 + α L0 ΔT

• ΔL = α L0 ΔT (linear expansion)

• ΔA = 2α A0 ΔT (area expansion)

• ΔV = β V0 ΔT ( expansion)

Lecture 26 Purdue University, Physics 149 9 Expansion Coefficients

Lecture 26 Purdue University, Physics 149 10 Thermal Expansion

Lecture 26 Purdue University, Physics 149 11 Amazing Water

Water is very unusual in that it has a maximum at 4 degrees C. That is why floats, and we exist! ρ (kg m-3)

T (C)

Lecture 26 Purdue University, Physics 149 12 Stuck Lid ILQ

A glass jar (α = 3x10-6 K-1) has a metal lid (α = 16x10-6 K-1) which is stuck. If you heat them by placing them in hot water, the lid will be A) Easier to open B) Harder to open C) Same

Copper lid expands more, making a looser fit, and easier to open!

Lecture 26 Purdue University, Physics 149 13 Jar ILQ

A cylindrical glass container (β = 28x10-6 k-1) is filled to the brim with water (β = 208x10-6 k-1). If the cup and water are heated 50C what will happen?

A) Some water overflows B) Same C) Water below rim

Water expands more than container, so it overflows.

Lecture 26 Purdue University, Physics 149 14 Heat Capacity, C • If no mechanical work is done either on or by a system, its change in internal energy is equal to the heat energy transferred into the system. • For many substances, the change in temperature is proportional to the change in heat energy; the constant of proportionality is called the heat capacity. In other words, the heat capacity of the system is the ratio of heat flow into a system to the temperature change of the system:

– Heat capacity depends on both the substance and also on the amount of the substance which is present. – Heat capacity is a scalar quantity. – Units: J/K or J/˚C – Q > 0 for heat flow into the system, which causes ΔT > 0 – Q < 0 for heat flow out of the system, which causes ΔT < 0 Lecture 26 Purdue University, Physics 149 15 Specific Heat, c • The (or specific heat) of a substance is the heat capacity per unit mass.

– Specific heat means the amount of heat necessary to change the temperature of 1 kg of a substance by 1˚C – Specific heat depends only on the substance (since we divide the heat capacity by the mass). – Specific heat is a scalar quantity. – Units: J/(kg⋅K) or J/(kg⋅˚C) • If more than two substances are in contact, heat energy is transferred until they are all in thermal equilibrium. The final temperature and the changes in temperature of the various substances depend on the specific and the amounts of the substances that are present. • The heat required to produce a temperature change in a system is:

– Q > 0 for heat flow into the system, which causes ΔT > 0 – Q < 0 for heat flow out of the system, which causes ΔT < 0 Lecture 26 Purdue University, Physics 149 16 Specific Heat • Heat adds energy to object/system • IF system does NO work then: – Heat increases internal energy: Q = ΔU – Heat increases temperature: Q = C ΔT •Q = c m ΔT – Heat required to increase T depends on amount of material (m) and type of material (c) •Q= cmΔT: “Cause” = “inertia” x “effect” (just like F=ma) – cause = Q – effect = ΔT – inertia = cm (mass x specific heat capacity) – c … specific heat • ΔT = Q/cm (just like a = F/m) Lecture 26 Purdue University, Physics 149 17 Phase Transitions • Phase transitions occur when a substance goes from one phase (, liquid, or gas) to another. • Phase transitions occur at constant temperature. During a , heat flow continues, but the temperature of the substance does not change.

• The is the heat energy required per unit mass of effect a phase change.

– The latent heat of fusion Lf: The heat per unit mass that must flow to melt a solid or to freeze a liquid (that is, Lf is for the solid-liquid transition).

– The latent heat of vaporization Lv: The heat per unit mass that must flow to change the phase from liquid to gas or from gas to liquid (that is, Lv is for the liquid-gas transition). – Latent heat is a scalar quantity. – Unit: J/kg • Phase transitions can go in either direction, the latent heat is the same (but the heat energy flows the opposite way, of course).

Lecture 26 Purdue University, Physics 149 18 Example: Ice Æ Water Æ Steam Phase Transitions m = 1 kg

Q = miceciceΔT = 1 kg × 2.1 kJ/kg⋅K × 25 K = 52.3 kJ

Q = mi+wLf = 1 kg × 333.7 kJ/kg = 333.7 kJ

Q = mwatercwaterΔT = 1 × 4.19 × 100 = 419 kJ

Q = mw+sLv = 1 × 2256 = 2256 kJ

Q = msteamcsteamΔT = 1 × 2 × 25 = 50 kJ Lecture 26 Purdue University, Physics 149 19 Evaporation

evaporate due to the spread in kinetic energy of their molecules; the highest-energy molecules are able to escape (because it can break loose from the molecular bonds at the surface of the water), which reduces the average energy of those that are left (thereby cooling the liquid).

Lecture 26 Purdue University, Physics 149 20 Molecular Picture of Gas

• Gas is made up of many individual molecules • Number density is number of molecules/volume – N/V = ρ/m – ρ is the mass density – m is the mass for one molecule

• Number of moles n = N / NA 23 -1 –NA = Avogadro’s number = 6.022×10 mole –NA= number of molecules per mole – 1 mole = amount of substance that contains as many elementary entities as there are atoms in exactly 12 grams of -12

Lecture 26 Purdue University, Physics 149 21 Atoms, Molecules and Moles

23 • 1 mole = 6.022 × 10 molecules (NA = Avogadro’s Number) •NA = Number of atoms or molecules that make a mass equal to the substance's atomic or molecular mass in grams. • 1 u = 1 atomic mass unit = (mass of 12C atom)/12 – Approximately # of neutrons + # of protons – Atomic weight W

-27 • 1 u = 1.66 × 10 kg = 1gram/NA • Mass of 1 mole of “stuff” in grams = molecular mass in u

– E.g. 1 mole of N2 has mass of 2 × 14 = 28 grams

Lecture 26 Purdue University, Physics 149 22 The

•P V = N kB T – P = in N/m2 (or Pascals) – V = volume in m3 – N = number of molecules – T = absolute temperature in K -23 –kB = Boltzmann’s constant = 1.38 x 10 J/K – Note: P V has units of N-m or J (energy!)

Lecture 26 Purdue University, Physics 149 23 Ideal Gas Law

You inflate the tires of your car so the pressure is 30 psi, when the air inside the tires is at 20 degrees C. After driving on the highway for a while, the air inside the tires heats up to 38 C. Which number is closest to the new air pressure?

A) 16 psi B) 32 psi C) 57 psi

Careful, you need to use the temperature in K

P = P0 (38+273)/(20+273)

Lecture 26 Purdue University, Physics 149 24 Balloon ILQ

What happens to the pressure of the air inside a hot-air balloon when the air is heated? (Assume V is constant)

A) Increases B) Same C) Decreases

Balloon is still open to atmospheric pressure, so it stays at 1 atm

Lecture 26 Purdue University, Physics 149 25 Transfer of Heat Energy

• There are three ways in which heat energy can be transferred:

– Conduction – Convection – Radiation

For each case, we will study the rate of heat flow (that is, ).

Lecture 26 Purdue University, Physics 149 26 : Conduction • Hot molecules have more KE than cold molecules

• High-speed molecules on left collide with low- speed molecules on right – energy transferred to lower-speed molecules – heat transfers from hot to cold

• I = rate of heat transfer = Q/t [J/s]

–I = κ A (TH-TC)/d • Q/t = κ A ΔT/Δx – κ = thermal conductivity • Units: J/s-m-C • good thermal conductors…high κ d = Δx TH TC • good thermal insulators … low κ Hot Cold –R = d/(Aκ) = thermal resistance Area A

Lecture 26 Purdue University, Physics 149 27 Heat Transfer: Convection

• Air heats at bottom • Thermal expansion…density gets smaller • Lower density air rises – Archimedes: low density floats on high density • Cooler air pushed down • Cycle continues with net result of circulation of air • I = Q/t = h A ΔT – h = coefficient of convection • Practical aspects – heater ducts on floor – A/C ducts on ceiling – stove heats water from bottom – “riding the thermals” Lecture 26 Purdue University, Physics 149 28 Convection

Lecture 26 Purdue University, Physics 149 29 Heat Transfer: Radiation

• All things radiate electromagnetic energy 4 –Iemit = Q/t = eAσT • e = emissivity (between 0 and 1) – perfect “black body” has e=1 • T is temperature • σ = Stefan-Boltzmann constant = 5.67 x 10-8 J/s-m2-K4 –No “medium” required • All things absorb energy from surroundings 4 –Iabsorb = eAσT0 • good emitters (e close to 1) are also good absorbers

Lecture 26 Purdue University, Physics 149 30 Thermal Radiation

• Thermal radiation does not (have to) travel through a material medium (unlike convection) and does not have to be in direct contact (unlike conduction).

• The energy is carried by electromagnetic waves that travel at the speed of light. All bodies emit energy through electromagnetic radiation. • All materials radiate electromagnetic waves whose frequency depends on their temperature; some radiate in the visible spectrum, such as the and glowing coals, while others radiate in the infrared. – Ex) The Earth is warmed by the Sun’s heat, which is transferred via radiation.

Lecture 26 Purdue University, Physics 149 31 Heat Transfer: Radiation

All things radiate and absorb electromagnetic energy 4 Surroundings at T –Iemit = eAσT 0 4 –Iabsorb = eAσT0 T Hot stove 4 4 –Inet = Iemit -Iabsorb = eAσ(T -T0 )

if T > T0, object cools down if T < T0, object heats up

Lecture 26 Purdue University, Physics 149 32 Radiation

Which of the following is an example of radiative heat transfer?

A) You stir some hot soup with a spoon and notice that the spoon warms up. B) You stand watching a bonfire, but cant get too close because of the heat. C) Its hard for central air-conditioning in an old house to cool the attic.

Lecture 26 Purdue University, Physics 149 33 Blackbody

• An idealized body that absorbs all the radiation incident on it is called a blackbody. • A blackbody emits more radiant power per unit surface area than any real object at the same temperature. – Note that a good absorber is also a good emitter of radiation, because it has to emit the same amount of radiation to keep the same temperature.

• It emits a unique radiation spectrum which depends only on its temperature and size, and not on the material it is made of or its shape.

Lecture 26 Purdue University, Physics 149 34 Radiation Spectrum

Infrared: 100 μm - 0.7 μm Visible Light: 0.7 μm - 0.4 μm Ultraviolet: < 0.4 μm

-3 Wien’s Law: λmaxT = 2.898 × 10 mK

Lecture 26 Purdue University, Physics 149 35 Greenhouse Effect

Lecture 26 Purdue University, Physics 149 36 PHYS 149 Students

You guys are great!

Good luck for the exam

Thank you for being my students.

Lecture 26 Purdue University, Physics 149 37