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A HISTORY of the SOLAR CELL, in PATENTS Karthik Kumar, Ph.D
A HISTORY OF THE SOLAR CELL, IN PATENTS Karthik Kumar, Ph.D., Finnegan, Henderson, Farabow, Garrett & Dunner, LLP 901 New York Avenue, N.W., Washington, D.C. 20001 [email protected] Member, Artificial Intelligence & Other Emerging Technologies Committee Intellectual Property Owners Association 1501 M St. N.W., Suite 1150, Washington, D.C. 20005 [email protected] Introduction Solar cell technology has seen exponential growth over the last two decades. It has evolved from serving small-scale niche applications to being considered a mainstream energy source. For example, worldwide solar photovoltaic capacity had grown to 512 Gigawatts by the end of 2018 (representing 27% growth from 2017)1. In 1956, solar panels cost roughly $300 per watt. By 1975, that figure had dropped to just over $100 a watt. Today, a solar panel can cost as little as $0.50 a watt. Several countries are edging towards double-digit contribution to their electricity needs from solar technology, a trend that by most accounts is forecast to continue into the foreseeable future. This exponential adoption has been made possible by 180 years of continuing technological innovation in this industry. Aided by patent protection, this centuries-long technological innovation has steadily improved solar energy conversion efficiency while lowering volume production costs. That history is also littered with the names of some of the foremost scientists and engineers to walk this earth. In this article, we review that history, as captured in the patents filed contemporaneously with the technological innovation. 1 Wiki-Solar, Utility-scale solar in 2018: Still growing thanks to Australia and other later entrants, https://wiki-solar.org/library/public/190314_Utility-scale_solar_in_2018.pdf (Mar. -
Microchip Manufacturing
Si3N4 Deposition & the Virtual Chemical Vapor Deposition Lab Making a transistor, the general process A closer look at chemical vapor deposition and the virtual lab Images courtesy Silicon Run Educational Video, VCVD Lab Screenshot Why Si3N4 Deposition…Making Microprocessors http://www.sonyericsson.com/cws/products/mobilephones /overview/x1?cc=us&lc=en http://vista.pca.org/yos/Porsche-911-Turbo.jpg On a wafer, billions of transistors are housed on a single square chip. One malfunctioning transistor could cause a chip to short-circuit, ruining the chip. Thus, the process of creating each microscopic transistor must be very precise. Wafer image: http://upload.wikimedia.org/wikipedia/fr/thumb/2/2b/PICT0214.JPG/300px-PICT0214.JPG What size do you think an individual transistor being made today is? Size of Transistors One chip is made of millions or billions of transistors packed into a length and width of less than half an inch. Channel lengths in MOSFET transistors are less than a tenth of a micrometer. Human hair is approximately 100 micrometers in diameter. Scaling of successive generations of MOSFETs into the nanoscale regime (from Intel). Transistor: MOS We will illustrate the process sequence of creating a transistor with a Metal Oxide Semiconductor(MOS) transistor. Wafers – 12” Diameter ½” to ¾” Source Gate Drain conductor Insulator n-Si n-Si p-Si Image courtesy: Pro. Milo Koretsky Chemical Engineering Department at OSU IC Manufacturing Process IC Processing consists of selectively adding material (Conductor, insulator, semiconductor) to, removing it from or modifying it Wafers Deposition / Photo/ Ion Implant / Pattern Etching / CMP Oxidation Anneal Clean Clean Transfer Loop (Note that these steps are not all the steps to create a transistor. -
Three-Dimensional Integrated Circuit Design: EDA, Design And
Integrated Circuits and Systems Series Editor Anantha Chandrakasan, Massachusetts Institute of Technology Cambridge, Massachusetts For other titles published in this series, go to http://www.springer.com/series/7236 Yuan Xie · Jason Cong · Sachin Sapatnekar Editors Three-Dimensional Integrated Circuit Design EDA, Design and Microarchitectures 123 Editors Yuan Xie Jason Cong Department of Computer Science and Department of Computer Science Engineering University of California, Los Angeles Pennsylvania State University [email protected] [email protected] Sachin Sapatnekar Department of Electrical and Computer Engineering University of Minnesota [email protected] ISBN 978-1-4419-0783-7 e-ISBN 978-1-4419-0784-4 DOI 10.1007/978-1-4419-0784-4 Springer New York Dordrecht Heidelberg London Library of Congress Control Number: 2009939282 © Springer Science+Business Media, LLC 2010 All rights reserved. This work may not be translated or copied in whole or in part without the written permission of the publisher (Springer Science+Business Media, LLC, 233 Spring Street, New York, NY 10013, USA), except for brief excerpts in connection with reviews or scholarly analysis. Use in connection with any form of information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed is forbidden. The use in this publication of trade names, trademarks, service marks, and similar terms, even if they are not identified as such, is not to be taken as an expression of opinion as to whether or not they are subject to proprietary rights. Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com) Foreword We live in a time of great change. -
Light Trapping in Thin Film Organic Solar Cells
Light trapping in thin film organic solar cells Zheng Tang, Wolfgang Tress and Olle Inganäs Linköping University Post Print N.B.: When citing this work, cite the original article. Original Publication: Zheng Tang, Wolfgang Tress and Olle Inganäs, Light trapping in thin film organic solar cells, 2014, Materials Today, (17), 8, 389-396. http://dx.doi.org/10.1016/j.mattod.2014.05.008 Copyright: Elsevier / Elsevier: Creative Commons http://www.elsevier.com/ Postprint available at: Linköping University Electronic Press http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-103929 Materials Today Volume 17, Number 8 October 2014 RESEARCH Review Light trapping in thin film organic solar cells RESEARCH: Zheng Tang*, Wolfgang Tress and Olle Ingana¨s* Biomolecular and Organic Electronics, IFM, and Center of Organic Electronics, Linko¨ping University, SE-581 83 Linko¨ping, Sweden A major issue in organic solar cells is the poor mobility and recombination of the photogenerated charge carriers. The active layer has to be kept thin to facilitate charge transport and minimize recombination losses. However, optical losses due to inefficient light absorption in the thin active layers can be considerable in organic solar cells. Therefore, light trapping schemes are critically important for efficient organic solar cells. Traditional light trapping schemes for thick solar cells need to be modified for organic thin film solar cells in which coherent optics and wave effects play a significant role. In this review, we discuss the light trapping schemes for organic thin film solar cells, which includes geometric engineering of the structure of the solar cell at the micro and nanoscale, plasmonic structures, and more. -
Graphene-Based Composite Thin Films for Electronics
NANO LETTERS 2009 Graphene-based Composite Thin Films Vol. 9, No. 2 for Electronics 814-818 Goki Eda and Manish Chhowalla* Rutgers UniVersity, Materials Science and Engineering, Piscataway, New Jersey 08854 Received November 21, 2008; Revised Manuscript Received January 4, 2009 ABSTRACT The electrical properties of solution-processed composite thin films consisting of functionalized graphene sheets (FGS) as the filler and polystyrene (PS) as the host material are described. We demonstrate that transistors from graphene-based composite thin films exhibit ambipolar field effect characteristics, suggesting transport via percolation among FGS in the insulating PS matrix. Device characteristics as a function of the FGS size are also reported. The results indicate that devices fabricated using the largest size FGS yield the highest mobility values. This simple and scaleable fabrication scheme based on a commodity plastic could be useful for low-cost, macro-scale electronics. Graphene-based composites are emerging as new class of introduction of percolating graphene network within an materials that hold promise for several applications.1 Graphene, insulating material may render it semiconducting. In this a single sheet of graphite, possesses extraordinary electrical, study, we show that incorporation of functionalized graphene thermal, and mechanical properties arising from its unique sheets (FGS) in polystyrene (PS) matrix results in composite structure.2 When incorporated into polymer3-6 or ceramic7 thin films that are semiconducting and exhibit ambipolar field matrices, these properties manifest as remarkable improve- effect. These composites can be deposited uniformly over ments in the host material. Graphene-based polymer com- large areas in the form of thin films from solution onto which posites exhibit extraordinarily low electrical percolation devices can be fabricated without extensive lithography. -
Research Into Fabrication and Popularization of Organic Thin Film Solar Cells, Chemical Engineering Transactions, 55, 25-30 DOI:10.3303/CET1655005 26
25 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 55, 2016 The Italian Association of Chemical Engineering Online at www.aidic.it/cet Guest Editors: Tichun Wang, Hongyang Zhang, Lei Tian Copyright © 2016, AIDIC Servizi S.r.l., ISBN 978-88-95608-46-4; ISSN 2283-9216 DOI: 10.3303/CET1655005 Research into Fabrication and Popularization of Organic Thin Film Solar Cells Bin Zhang*a, Yan Lia, Shanlin Qiaob, Le Lic, Zhanwen Wanga a Hebei Chemical & Pharmaceutical College, No. 88 Fangxing Road, Shijiazhuang, Hebei Province, China; b Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao, Shandong Province, China c Shijiazhuang Naienph Chemical Technology Co., Ltd, No. 12 Shifang Road, Shijiazhuang, Hebei Province, China. [email protected] An analysis was conducted herein on the research status of several popular solar cells at the present stage, including silicon solar cell, thin film photovoltaic cell, and dye-sensitized solar cell (DSSC). In doing so, we concluded that the current situations provide a favorable objective environment for the popularization of organic thin film solar cells. Finally, we reviewed the merits and demerits of the organic thin film solar cell together with the major research focus on and progress of it, and summarized obstacles to and development trails of the popularization of organic thin film solar cells. 1. Introduction As the energy crisis further deepens in the 21st century, the existing development level for solar cells has already failed to satisfy increasing social demands for energy. This phenomenon is mainly reflected in the costly high-purity silicon solar panels, in the defects at new amorphous silicon (a-Si) during energy conversion, and in the limited theoretical energy conversion efficiency (around 25%) of silicon solar panels as well. -
Reflectance in Thin Films
TECHNICAL PAPER Reflectance in Thin Films Abstract Reflectance (R) is the fraction of incident light reflected from a surface and is an intrinsic optical property of thin films. It is essential in determining color, transparency and polarization characteristics of the film. Total internal reflectance is also important in devices such as optical waveguides. Reflectance depends on the energy band structure and associated plasma frequency of charge carriers. As a result, high reflection spectral regions are different for metals, semiconductors and insulators. Basic relations that determine reflectance will be presented and related to refractive index, extinction coefficient, color and transparency of these three classes of thin film materials. Reflectance of thin films also depends on thickness and surface quality. In addition to spectral dependence, the color associated with reflectance can also be described by Tristimulus values and Chromaticity diagrams. Antireflection and high reflection multilayer thin film coatings will also be addressed. Introduction The reflectivity or reflectance (R), of a surface is an intrinsic optical property of a surface. In many optical, electrooptic, telecommunications, solar concentrator and architectural applications, reflectance must either be controlled (reduced or enhanced), or the color of the object changed (e.g., given a “gold” color). For example, heat mirrors are used to reflect infrared wavelengths to reduce heat loss or ingress through windows. Infrared reflectance must be maximized while keeping visible light transmission through the window high. Multilayer low-e and solar control coatings are used to achieve this performance but must be applied to low cost plastic films and glazings. Combined with absorption, reflectance determines color and intensity (or energy) of reflected light. -
Demonstrating Solar Conversion Using Natural Dye Sensitizers
Demonstrating Solar Conversion Using Natural Dye Sensitizers Subject Area(s) Science & Technology, Physical Science, Environmental Science, Physics, Biology, and Chemistry Associated Unit Renewable Energy Lesson Title Dye Sensitized Solar Cell (DSSC) Grade Level (11th-12th) Time Required 3 hours / 3 day lab Summary Students will analyze the use of solar energy, explore future trends in solar, and demonstrate electron transfer by constructing a dye-sensitized solar cell using vegetable and fruit products. Students will analyze how energy is measured and test power output from their solar cells. Engineering Connection and Tennessee Careers An important aspect of building solar technology is the study of the type of materials that conduct electricity and understanding the reason why they conduct electricity. Within the TN-SCORE program Chemical Engineers, Biologist, Physicist, and Chemists are working together to provide innovative ways for sustainable improvements in solar energy technologies. The lab for this lesson is designed so that students apply their scientific discoveries in solar design. Students will explore how designing efficient and cost effective solar panels and fuel cells will respond to the social, political, and economic needs of society today. Teachers can use the Metropolitan Policy Program Guide “Sizing The Clean Economy: State of Tennessee” for information on Clean Economy Job Growth, TN Clean Economy Profile, and Clean Economy Employers. www.brookings.edu/metro/clean_economy.aspx Keywords Photosynthesis, power, electricity, renewable energy, solar cells, photovoltaic (PV), chlorophyll, dye sensitized solar cells (DSSC) Page 1 of 10 Next Generation Science Standards HS.ESS-Climate Change and Human Sustainability HS.PS-Chemical Reactions, Energy, Forces and Energy, and Nuclear Processes HS.ETS-Engineering Design HS.ETS-ETSS- Links Among Engineering, Technology, Science, and Society Pre-Requisite Knowledge Vocabulary: Catalyst- A substance that increases the rate of reaction without being consumed in the reaction. -
Encapsulation of Organic and Perovskite Solar Cells: a Review
Review Encapsulation of Organic and Perovskite Solar Cells: A Review Ashraf Uddin *, Mushfika Baishakhi Upama, Haimang Yi and Leiping Duan School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney 2052, Australia; [email protected] (M.B.U.); [email protected] (H.Y.); [email protected] (L.D.) * Correspondence: [email protected] Received: 29 November 2018; Accepted: 21 January 2019; Published: 23 January 2019 Abstract: Photovoltaic is one of the promising renewable sources of power to meet the future challenge of energy need. Organic and perovskite thin film solar cells are an emerging cost‐effective photovoltaic technology because of low‐cost manufacturing processing and their light weight. The main barrier of commercial use of organic and perovskite solar cells is the poor stability of devices. Encapsulation of these photovoltaic devices is one of the best ways to address this stability issue and enhance the device lifetime by employing materials and structures that possess high barrier performance for oxygen and moisture. The aim of this review paper is to find different encapsulation materials and techniques for perovskite and organic solar cells according to the present understanding of reliability issues. It discusses the available encapsulate materials and their utility in limiting chemicals, such as water vapour and oxygen penetration. It also covers the mechanisms of mechanical degradation within the individual layers and solar cell as a whole, and possible obstacles to their application in both organic and perovskite solar cells. The contemporary understanding of these degradation mechanisms, their interplay, and their initiating factors (both internal and external) are also discussed. -
Thin Film Cdte Photovoltaics and the U.S. Energy Transition in 2020
Thin Film CdTe Photovoltaics and the U.S. Energy Transition in 2020 QESST Engineering Research Center Arizona State University Massachusetts Institute of Technology Clark A. Miller, Ian Marius Peters, Shivam Zaveri TABLE OF CONTENTS Executive Summary .............................................................................................. 9 I - The Place of Solar Energy in a Low-Carbon Energy Transition ...................... 12 A - The Contribution of Photovoltaic Solar Energy to the Energy Transition .. 14 B - Transition Scenarios .................................................................................. 16 I.B.1 - Decarbonizing California ................................................................... 16 I.B.2 - 100% Renewables in Australia ......................................................... 17 II - PV Performance ............................................................................................. 20 A - Technology Roadmap ................................................................................. 21 II.A.1 - Efficiency ........................................................................................... 22 II.A.2 - Module Cost ...................................................................................... 27 II.A.3 - Levelized Cost of Energy (LCOE) ....................................................... 29 II.A.4 - Energy Payback Time ........................................................................ 32 B - Hot and Humid Climates ........................................................................... -
I OPTIMIZATION of ORGANIC SOLAR CELLS a DISSERTATION
OPTIMIZATION OF ORGANIC SOLAR CELLS A DISSERTATION SUBMITTED TO THE DEPARTMENT OF ELECTRICAL ENGINEERING AND THE COMMITTEE ON GRADUATE STUDIES OF STANFORD UNIVERSITY IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY Seung Bum Rim March 2010 i © 2010 by Seung Bum Rim. All Rights Reserved. Re-distributed by Stanford University under license with the author. This work is licensed under a Creative Commons Attribution- Noncommercial 3.0 United States License. http://creativecommons.org/licenses/by-nc/3.0/us/ This dissertation is online at: http://purl.stanford.edu/yx656fs6181 ii I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Peter Peumans, Primary Adviser I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Michael McGehee I certify that I have read this dissertation and that, in my opinion, it is fully adequate in scope and quality as a dissertation for the degree of Doctor of Philosophy. Philip Wong Approved for the Stanford University Committee on Graduate Studies. Patricia J. Gumport, Vice Provost Graduate Education This signature page was generated electronically upon submission of this dissertation in electronic format. An original signed hard copy of the signature page is on file in University Archives. iii Abstract Organic solar cell is a promising technology because the versatility of organic materials in terms of the tunability of their electrical and optical properties and because of their relative insensitivity to film imperfections which potentially allows for very low-cost high-throughput roll-to-roll processing. -
Thin-Film Silicon Solar Cells
SOLAR CELLS Chapter 7. Thin-Film Silicon Solar Cells Chapter 7. THIN-FILM SILICON SOLAR CELLS 7.1 Introduction The simplest semiconductor junction that is used in solar cells for separating photo- generated charge carriers is the p-n junction, an interface between the p-type region and n- type region of one semiconductor. Therefore, the basic semiconductor property of a material, the possibility to vary its conductivity by doping, has to be demonstrated first before the material can be considered as a suitable candidate for solar cells. This was the case for amorphous silicon. The first amorphous silicon layers were reported in 1965 as films of "silicon from silane" deposited in a radio frequency glow discharge1. Nevertheless, it took more ten years until Spear and LeComber, scientists from Dundee University, demonstrated that amorphous silicon had semiconducting properties by showing that amorphous silicon could be doped n- type and p-type by adding phosphine or diborane to the glow discharge gas mixture, respectively2. This was a far-reaching discovery since until that time it had been generally thought that amorphous silicon could not be doped. At that time it was not recognised immediately that hydrogen played an important role in the newly made amorphous silicon doped films. In fact, amorphous silicon suitable for electronic applications, where doping is required, is an alloy of silicon and hydrogen. The electronic-grade amorphous silicon is therefore called hydrogenated amorphous silicon (a-Si:H). 1 H.F. Sterling and R.C.G. Swann, Solid-State Electron. 8 (1965) p. 653-654. 2 W. Spear and P.