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Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
An Investigation of the Crystal Growth of Heavy Sulfides in Supercritical
AN ABSTRACT OF THE THESIS OF LEROY CRAWFORD LEWIS for the Ph. D. (Name) (Degree) in CHEMISTRY presented on (Major) (Date) Title: AN INVESTIGATION OF THE CRYSTAL GROWTH OF HEAVY SULFIDES IN SUPERCRITICAL HYDROGEN SULFIDE Abstract approved Redacted for privacy Dr. WilliarriIJ. Fredericks Solubility studies on the heavy metal sulfides in liquid hydrogen sulfide at room temperature were carried out using the isopiestic method. The results were compared with earlier work and with a theoretical result based on Raoult's Law. A relative order for the solubilities of sulfur and the sulfides of tin, lead, mercury, iron, zinc, antimony, arsenic, silver, and cadmium was determined and found to agree with the theoretical result. Hydrogen sulfide is a strong enough oxidizing agent to oxidize stannous sulfide to stannic sulfide in neutral or basic solution (with triethylamine added). In basic solution antimony trisulfide is oxi- dized to antimony pentasulfide. In basic solution cadmium sulfide apparently forms a bisulfide complex in which three moles of bisul- fide ion are bonded to one mole of cadmium sulfide. Measurements were made extending the range over which the volumetric properties of hydrogen sulfide have been investigated to 220 °C and 2000 atm. A virial expression in density was used to represent the data. Good agreement, over the entire range investi- gated, between the virial expressions, earlier work, and the theorem of corresponding states was found. Electrical measurements were made on supercritical hydro- gen sulfide over the density range of 10 -24 moles per liter and at temperatures from the critical temperature to 220 °C. Dielectric constant measurements were represented by a dielectric virial ex- pression. -
Hazardous Material Inventory Statement
City of Brooklyn Park FIRE DEPARTMENT 5200 - 85th Avenue North Brooklyn Park MN 55443 Phone: (763)493-8020 Fax: (763) 493-8391 Hazardous Materials Inventory Statement Users Guide A separate inventory statement shall be provided for each building. An amended inventory statement shall be provided within 30 days of the storage of any hazardous materials or plastics that changes or adds a hazard class or which is sufficient in quantity to cause an increase in the quantity which exceeds 5 percent for any hazard class. The hazardous materials inventory statement shall list by hazard class categories. Each grouping shall provide the following information for each hazardous material listed for that group including a total quantity for each group of hazard class. 1. Hazard class. (See attached Hazardous Materials Categories Listing) 2. Common or trade name. 3. Chemical Abstract Service Number (CAS number) found in 29 Code of Federal Regulations (C.F.R.). 4. Whether the material is pure or a mixture, and whether the material is a solid, liquid or gas 5. Maximum aggregate quantity stored at any one time. 6. Maximum aggregate quantity In-Use (Open to atmosphere) at any one time. 7. Maximum aggregate quantity In-Use (Closed to atmosphere) at any one time. 8. Storage conditions related to the storage type, high-pile, encapsulated, non-encapsulated. Attached is a listing of categories that all materials need to be organized to. Definitions of these categories are also attached for your use. At the end of this packet are blank forms for completing this project. For questions regarding Hazardous Materials Inventory Statement contact the Fire Department at 763-493-8020. -
Toxicological Profile for Antimony
ANTIMONY AND COMPOUNDS 11 CHAPTER 2. HEALTH EFFECTS 2.1 INTRODUCTION The primary purpose of this chapter is to provide public health officials, physicians, toxicologists, and other interested individuals and groups with an overall perspective on the toxicology of antimony. It contains descriptions and evaluations of toxicological studies and epidemiological investigations and provides conclusions, where possible, on the relevance of toxicity and toxicokinetic data to public health. When available, mechanisms of action are discussed along with the health effects data; toxicokinetic mechanistic data are discussed in Section 3.1. A glossary and list of acronyms, abbreviations, and symbols can be found at the end of this profile. To help public health professionals and others address the needs of persons living or working near hazardous waste sites, the information in this section is organized by health effect. These data are discussed in terms of route of exposure (inhalation, oral, and dermal) and three exposure periods: acute (≤14 days), intermediate (15–364 days), and chronic (≥365 days). As discussed in Appendix B, a literature search was conducted to identify relevant studies examining health effect endpoints. Figure 2-1 provides an overview of the database of studies in humans or experimental animals included in this chapter of the profile. These studies evaluate the potential health effects associated with inhalation, oral, or dermal exposure to antimony, but may not be inclusive of the entire body of literature. A systematic review of the scientific evidence of the health effects associated with exposure to antimony was also conducted; the results of this review are presented in Appendix C. -
Toxicological Profile for Zinc
TOXICOLOGICAL PROFILE FOR ZINC U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES Public Health Service Agency for Toxic Substances and Disease Registry August 2005 ZINC ii DISCLAIMER The use of company or product name(s) is for identification only and does not imply endorsement by the Agency for Toxic Substances and Disease Registry. ZINC iii UPDATE STATEMENT A Toxicological Profile for Zinc, Draft for Public Comment was released in September 2003. This edition supersedes any previously released draft or final profile. Toxicological profiles are revised and republished as necessary. For information regarding the update status of previously released profiles, contact ATSDR at: Agency for Toxic Substances and Disease Registry Division of Toxicology/Toxicology Information Branch 1600 Clifton Road NE Mailstop F-32 Atlanta, Georgia 30333 ZINC vi *Legislative Background The toxicological profiles are developed in response to the Superfund Amendments and Reauthorization Act (SARA) of 1986 (Public law 99-499) which amended the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA or Superfund). This public law directed ATSDR to prepare toxicological profiles for hazardous substances most commonly found at facilities on the CERCLA National Priorities List and that pose the most significant potential threat to human health, as determined by ATSDR and the EPA. The availability of the revised priority list of 275 hazardous substances was announced in the Federal Register on November 17, 1997 (62 FR 61332). For prior versions of the list of substances, see Federal Register notices dated April 29, 1996 (61 FR 18744); April 17, 1987 (52 FR 12866); October 20, 1988 (53 FR 41280); October 26, 1989 (54 FR 43619); October 17, 1990 (55 FR 42067); October 17, 1991 (56 FR 52166); October 28, 1992 (57 FR 48801); and February 28, 1994 (59 FR 9486). -
List of Reactive Chemicals
LIST OF REACTIVE CHEMICALS Chemical Prefix Chemical Name Reactive Reactive Reactive CAS# Chemical Chemical Chemical Stimulus 1 Stimulus 2 Stimulus 3 111-90-0 "CARBITOL" SOLVENT D 111-15-9 "CELLOSOLVE" ACETATE D 110-80-5 "CELLOSOLVE" SOLVENT D 2- (2,4,6-TRINITROPHENYL)ETHYL ACETATE (1% IN ACETONE & BENZENE S 12427-38-2 AAMANGAN W 88-85-7 AATOX S 40487-42-1 AC 92553 S 105-57-7 ACETAL D 75-07-0 ACETALDEHYDE D 105-57-7 ACETALDEHYDE, DIETHYL ACETAL D 108-05-4 ACETIC ACID ETHENYL ESTER D 108-05-4 ACETIC ACID VINYL ESTER D 75-07-0 ACETIC ALDEHYDE D 101-25-7 ACETO DNPT T 126-84-1 ACETONE DIETHYL ACETAL D 108-05-4 ACETOXYETHYLENE D 108-05-4 1- ACETOXYETHYLENE D 37187-22-7 ACETYL ACETONE PEROXIDE, <=32% AS A PASTE T 37187-22-7 ACETYL ACETONE PEROXIDE, <=42% T 37187-22-7 ACETYL ACETONE PEROXIDE, >42% T S 644-31-5 ACETYL BENZOYL PEROXIDE (SOLID OR MORE THAN 45% IN SOLUTION) T S 644-31-5 ACETYL BENZOYL PEROXIDE, <=45% T 506-96-7 ACETYL BROMIDE W 75-36-5 ACETYL CHLORIDE W ACETYL CYCLOHEXANE SULFONYL PEROXIDE (>82% WITH <12% WATER) T S 3179-56-4 ACETYL CYCLOHEXANE SULFONYL PEROXIDE, <=32% T 3179-56-4 ACETYL CYCLOHEXANE SULFONYL PEROXIDE, <=82% T 674-82-8 ACETYL KETENE (POISON INHALATION HAZARD) D 110-22-5 ACETYL PEROXIDE, <=27% T 110-22-5 ACETYL PEROXIDE, SOLID, OR MORE THAN 27% IN SOLUTION T S 927-86-6 ACETYLCHOLINE PERCHLORATE O S 74-86-2 ACETYLENE D 74-86-2 ACETYLENE (LIQUID) D ACETYLENE SILVER NITRATE D 107-02-08 ACRALDEHYDE (POISON INHALATION HAZARD) D 79-10-7 ACROLEIC ACID D 107-02-08 ACROLEIN, INHIBITED (POISON INHALATION HAZARD) D 107-02-08 ACRYLALDEHYDE (POISON INHALATION HAZARD) D 79-10-7 ACRYLIC ACID D 141-32-2 ACRYLIC ACID BUTYL ESTER D 140-88-5 ACRYLIC ACID ETHYL ESTER D 96-33-3 ACRYLIC ACID METHYL ESTER D Stimulus - Stimuli is the thermal, physical or chemical input needed to induce a hazardous reaction. -
LABORATORY SAFETY and CHEMICAL HYGIENE PLAN
LABORATORY SAFETY and CHEMICAL HYGIENE PLAN INDIANA UNIVERSITY Produced by University Environmental Health and Safety December 1996 in cooperation with University Chemical Hygiene Committees Revised 2015 Page 1 Table of Contents EMERGENCY INFORMATION .................................................................................................. 4 Major Emergencies............................................................................................................ 4 Minor Emergencies............................................................................................................ 4 Accident Reports ............................................................................................................... 4 Fires and Fire Alarms ........................................................................................................ 5 Tornado Watches and Warnings (Sirens) .......................................................................... 6 LABORATORY SAFETY CONTACTS ...................................................................................... 7 1. INTRODUCTION ........................................................................................................10 1.1. Purpose ................................................................................................................ 10 1.2. Regulatory Basis ................................................................................................... 10 1.3. Applicability .......................................................................................................... -
Antimony Trioxide [CAS No. 1309-64-4]
Antimony Trioxide [CAS No. 1309-64-4] Brief Review of Toxicological Literature Prepared for National Toxicology Program (NTP) National Institute of Environmental Health Sciences (NIEHS) National Institutes of Health U.S. Department of Health and Human Services Contract No. N01-ES-35515 Project Officer: Scott A. Masten, Ph.D. NTP/NIEHS Research Triangle Park, North Carolina Prepared by Integrated Laboratory Systems, Inc. Research Triangle Park, North Carolina July 2005 Chemical Name: Antimony Trioxide CAS RN: 1309-64-4 Formula: Sb2O3 Basis for Nomination: Antimony trioxide was nominated by the National Institute of Environmental Health Sciences for chronic toxicity, cardiotoxicity and carcinogenicity studies due to the potential for substantial human exposure in occupational settings and lack of adequate two-year exposure carcinogenicity studies. Additional studies of antimony trioxide are of interest, in lieu of studies with antimony trisulfide or another antimony compound, considering the higher volume of use and magnitude of human exposure, and the lack of two- year exposure carcinogenicity studies for any antimony compound by any route of administration. Antimony trisulfide was nominated to the NTP by the National Cancer Institute in 2002 for carcinogenicity studies (http://ntp.niehs.nih.gov/ntpweb/index.cfm?objectid=25BEBA08-BDB7-CEBA- FC56EAD78615ADCF). Subsequent to the nomination review process, the NTP concluded that antimony trisulfide should not be studied further at this time for the following reasons: 1) antimony trisulfide does not appear to represent a major form of antimony to which humans are exposed; 2) carcinogenicity studies of antimony trisulfide is unlikely to lead to a sufficient understanding of the carcinogenicity hazard for antimony compounds as a group; and 3) there is concern regarding the safe handling of pure antimony trisulfide in experimental settings due to its flammable/combustible nature. -
Screening Assessment Report Template
Draft Screening Assessment Antimony-containing Substances Environment and Climate Change Canada Health Canada September 2018 Synopsis Pursuant to section 74 of the Canadian Environmental Protection Act, 1999 (CEPA), the Minister of the Environment and the Minister of Health have conducted a screening assessment of 11 substances referred to collectively as the Antimony-containing Substances Group. Substances in this group were identified as priorities for assessment as they met categorization criteria under subsection 73(1) of CEPA. The Chemical Abstracts Service Registry Numbers (CAS RN1), their Domestic Substances List (DSL) names and their common names are listed in the table below. Substances in the Antimony-containing Substances Group CAS RN DSL name Common name 1314-60-9 Antimony oxide (Sb2O5) Antimony pentoxide 1327-33-9a Antimony oxide Antimony oxide 1345-04-6 Antimony sulfide (Sb2S3) Antimony sulfide 10025-91-9 Stibine, trichloro- Antimony trichloride 1- 15432-85-6 Antimonate (SbO3 ), sodium Sodium antimonate Phosphorodithioic acid, O,O- 15874-48-3 NA dipropyl ester, antimony(3+) salt Antimony, Antimony 15890-25-2 tris(dipentylcarbamodithioato-S,S’)-, diamyldithiocarbamate (OC-6-11)- Antimony, tris[bis(2- 15991-76-1 ethylhexyl)carbamodithioato-S,S’]-, NA (OC-6-11)- Antimonate(2-), bis[µ-[2,3- di(hydroxy-κO)butanedioato(4-)- Antimony potassium 28300-74-5 κO1:κO4]]di-, dipotassium, trihydrate, tartrate (APT) stereoisomer 4- Antimonate (Sb2O7 ), 29638-69-5 Potassium antimonate tetrapotassium 1- Antimonate (Sb(OH)6 ), sodium, Sodium 33908-66-6 (OC-6-11)- hexahydroxoantimonate Abbreviations: NA, Not Available 1 The Chemical Abstracts Service Registry Number (CAS RN) is the property of the American Chemical Society and any use or redistribution, except as required in supporting regulatory requirements and/or for reports to the Government of Canada when the information and the reports are required by law or administrative policy, is not permitted without the prior, written permission of the American Chemical Society. -
2020 Emergency Response Guidebook
2020 A guidebook intended for use by first responders A guidebook intended for use by first responders during the initial phase of a transportation incident during the initial phase of a transportation incident involving hazardous materials/dangerous goods involving hazardous materials/dangerous goods EMERGENCY RESPONSE GUIDEBOOK THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE HAZARDOUS MATERIALS/ DANGEROUS GOODS REGULATIONS OR 2020 TO CREATE WORKER SAFETY DOCUMENTS EMERGENCY RESPONSE FOR SPECIFIC CHEMICALS GUIDEBOOK NOT FOR SALE This document is intended for distribution free of charge to Public Safety Organizations by the US Department of Transportation and Transport Canada. This copy may not be resold by commercial distributors. https://www.phmsa.dot.gov/hazmat https://www.tc.gc.ca/TDG http://www.sct.gob.mx SHIPPING PAPERS (DOCUMENTS) 24-HOUR EMERGENCY RESPONSE TELEPHONE NUMBERS For the purpose of this guidebook, shipping documents and shipping papers are synonymous. CANADA Shipping papers provide vital information regarding the hazardous materials/dangerous goods to 1. CANUTEC initiate protective actions. A consolidated version of the information found on shipping papers may 1-888-CANUTEC (226-8832) or 613-996-6666 * be found as follows: *666 (STAR 666) cellular (in Canada only) • Road – kept in the cab of a motor vehicle • Rail – kept in possession of a crew member UNITED STATES • Aviation – kept in possession of the pilot or aircraft employees • Marine – kept in a holder on the bridge of a vessel 1. CHEMTREC 1-800-424-9300 Information provided: (in the U.S., Canada and the U.S. Virgin Islands) • 4-digit identification number, UN or NA (go to yellow pages) For calls originating elsewhere: 703-527-3887 * • Proper shipping name (go to blue pages) • Hazard class or division number of material 2. -
Barium Chlorate Safety Data Sheet
Hummel Croton Inc. In Case Of Emergency Call 10 Harmich Rd. (U.S.) (800) 424-9300 South Plainfield, NJ 07080 (International) +1 (813) 248-0585 www.HummelCroton.com Phone: 908-754-1800 Fax: 908-754-1815 Barium Chlorate Safety Data Sheet 1. Product and Company Product name: Barium Chlorate HMIS Rating Synonym: Chloric Acid Barium Salt Health 3 Flammabilitiy 0 CAS-No.: 10294-38-9 Reactivity 3 Company: Hummel Croton Inc. Personal Protection E 10 Harmich Rd. South Plainfield, NJ 07080 Telephone: 908-754-1800 Fax: 908-754-1815 Emergency telephone number Emergency Phone #: Chemtrec US: 1-800-424-9300 ChemTel International: +1-813-248-0585 2. Hazards GHS Classification Oxidizing solids (Category 1), H271 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 4), H332 Acute aquatic toxicity (Category 2), H401 Chronic aquatic toxicity (Category 2), H411 GHS Label elements Pictogram(s) Signal word DANGER Hazard statement(s) H271 May cause fire or explosion; strong oxidizer. H302 + H332 Harmful if swallowed or if inhaled H411 Toxic to aquatic life with long lasting effects. Precautionary statement(s) P210 Keep away from heat. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P283 Wear fire/ flame resistant/ retardant clothing. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. -
Bacitracin B:0050 Medical Surveillance: Evaluation by a Qualified Allergist
B Bacitracin B:0050 Medical Surveillance: Evaluation by a qualified allergist. Kidney function tests. First Aid: In case of large-scale exposure, the directions for Molecular Formula: C H N O S 66 103 17 16 medicines (nonspecific, n.o.s.) would be applied as follows: Synonyms: Ayfivin; Baciguent; Baci-Jel; Baciliquin; Move victim to fresh air; call emergency medical care. If Bacitek ointment; Fortracin; Parentracin; Penitracin; not breathing, give artificial respiration. If breathing is diffi- Topitracin; Zutracin cult, give oxygen. In case of contact with material, immedi- CAS Registry Number: 1405-87-4 ® ately flush skin or eyes with running water for at least RTECS Number: CP0175000 15 min. Speed in removing material from skin is of extreme UN/NA & ERG Number: UN3249 (medicine, solid, toxic, importance. Remove and isolate contaminated clothing and n.o.s.)/151 shoes at the site. Keep victim quiet and maintain normal EC Number: 215-786-2 body temperature. Effects may be delayed; keep victim Regulatory Authority and Advisory Bodies under observation. Listed on the TSCA inventory. Storage: Color Code—Green: General storage may be used. List of Acutely Toxic Chemicals, Chemical Emergency Shipping: The DOT category of medicine, solid, toxic, n.o.s. Preparedness Program (EPA) and formerly on CERCLA/ calls for the label of “POISONOUS/TOXIC MATERIALS.” SARA 40CFR302, Table 302.4 Extremely Hazardous Bacitracin would fall in Hazard Class 6.1 and in Packing Substances List. Dropped from listing in 1988. Group III. Listed on Canada’s DSL List. Spill Handling: Evacuate and restrict persons not wearing WGK (German Aquatic Hazard Class): No value assigned.