Loss Prevention Bulletin Improving Process Safety by Sharing Experience
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Chemical Accident Prevention & Preparedness
Lessons Learned Bulletin No. 5 Chemical Accident Prevention & Preparedness Major accidents involving fertilizers The aim of the bulletin is to provide insights on lessons learned from accident reported in the European Major Accident Reporting System (eMARS) and other accident sources for both industry operators and government regulators. In future the CAPP Lessons Learned Bulletin will be produced on a semi-annual basis. Each issue of the Bulletin focuses on a particular theme. Accident 1 Summary Wholesale and retail storage and distribution In preparing this bulletin, 25 major accidents in eMARS involving fertiliz- Sequence of events was to attack the source of the fire with ers were studied together with an ad- portable fire extinguishers, in the absence ditional 25 accidents from other free A fire occurred in a warehouse storing fer- of activated fire hose reels. Arriving on sources, including also accidents in tilizers and chemical products belonging the site, firemen observed that very thick transport. Events were chosen on the to a wholesale distributor of numerous smoke was emitted from the storage basis that ammonium nitrate or NPK products, including sugar, molasses, fer- compartment. It also appeared that a fertilizer (nitrogen-phosphorus-potas- tilizers, and cereals. The storage instal- fire was burning beneath the mass. How- sium) was involved in the accident. lation was subdivided into 8 compart- ever, the intervention of the firefighters ments of which two contained NPK (15% appeared to focus solely on the presence In general, with some exceptions, N, 8% P, 22% K) fertilizers in quantities of ammonium nitrate fertilizer, ignoring, most accidents occurred in ware- of 600 tonnes and 850 tonnes respec- the nature of the other chemical prod- houses or general chemicals manu- tively. -
Victims of Seveso Disaster Face Higher Risk from Some Cancers 14 September 2009
Victims of Seveso disaster face higher risk from some cancers 14 September 2009 People living in the Seveso area of Italy, which was excess of lymphatic and hematopoietic risk. We did exposed to dioxin after an industrial accident in not identify an all-cancer excess, as seen in 1976, have experienced an increased risk of occupational cohorts which had similar, sometimes developing cancer. Researchers writing in BioMed higher, and more complex exposures". Central's open access journal Environmental Health found an increased risk of breast cancer in More information: Cancer incidence in the women from the most exposed zone and an population exposed to dioxin after the "Seveso excess of lymphatic and hematopoietic tissue accident": twenty years of follow-up; Angela Cecilia neoplasms in all but the least exposed zone. Pesatori, Dario Consonni, Maurizia Rubagotti, Paolo Grillo and Pier Alberto Bertazzi; Angela Pesatori led a team of researchers from the Environmental Health (in press); Fondazione IRCCS Ospedale Maggiore Policlinico, www.ehjournal.net/ a local hospital associated with the University of Milan, who extended a study of cancer incidence in Source: BioMed Central the area, which now covers the period 1977-96. She said, "The industrial accident that occurred in the Seveso area in 1976 exposed a large residential population to substantial amounts of TCDD [2,3,7,8-tetrachlorodibenzo-p-dioxin]. Although the International Agency for Research on Cancer and the US Environmental Protection Agency have both classified TCDD as human carcinogen, scientific debate still persists on the actual cancer risk posed to the general population. We've found that it does pose a carcinogenic hazard, although lower than anticipated from animal studies, at least at the levels experienced by this population after this accident". -
Air Pollution and Increased Safety Risks to Workers and Nearby Residents
1 ACKNOWLEDGEMENTS Written by Ari Phillips with analysis from Courtney Bernhardt and Gabriel Clark-Leach of the Environmental Integrity Project. THE ENVIRONMENTAL INTEGRITY PROJECT The Environmental Integrity Project (http://www.environmentalintegrity.org) is a nonpartisan, nonprofit organization established in March of 2002 by former EPA enforcement attorneys to advocate for effective enforcement of environmental laws. EIP has three goals: 1) to provide objective analyses of how the failure to enforce or implement environmental laws increases pollution and affects public health; 2) to hold federal and state agencies, as well as individual corporations, accountable for failing to enforce or comply with environmental laws; and 3) to help local communities obtain the protection of environmental laws. CONTACTS: For questions about this report, please contact: Tom Pelton, Environmental Integrity Project, (202) 888- 2703 or [email protected] PHOTO CREDITS: Cover Image: The ExxonMobil Baytown Olefin’s plant fire sends a toxic brew of chemicals into the sky on July 31, 2019. Thirty-seven people experienced minor injuring from the explosion, which occurred at a part of the facility where plastics are made. Photo by the Associated Press, used with permission. Page 1: Houston industrial district, Shutterstock. Page 4: Petrochemical complex, La Porte, Texas, by Roy Luck/Flickr. Page 8: Assessment units for the Wolfcamp Shale and Bone Spring Formation of the Delaware Basin, USGS. 2 Plastics Pollution on the Rise Executive Summary hat the word ‘plastic’ means pliable or easily shaped is deceiving. Over the last 50 years plastic has developed a stranglehold over us, with no sign of loosening up. It is T hard to imagine life without plastic: The versatile material is found in computers, phones, medical devices, packaging, and thousands of other products. -
Risk and Safety Management of Ammonium Nitrate Fertilizers: Keeping the Memory of Disasters Alive
32 | Loss Prevention Bulletin 251 October 2016 Incident Risk and safety management of ammonium nitrate fertilizers: keeping the memory of disasters alive Dr. Zsuzsanna Gyenes, EC Joint Research Centre, Italy; Nicolas Dechy, CHAOS association, France This paper is aimed at keeping the memory of disasters alive, with the new process had fractions with higher ammonium assuming that risk awareness and implementation of safety nitrate (AN) content and this inhomogeneous mass was stored measures are facilitated by case histories. There have been together with the ASN that was dried with the old process. several accidents and a few disasters in the ammonium nitrate Due to higher AN content, lower density, lower water content fertilizer industry, and it is worthwhile to review these from (reduction from 4% to 2% with the new technique) and time to time, beyond the regulation and practice changes changed crystalline structure, the accumulated fine fraction which they triggered. was explosive. In addition, the operational issue was that the storage in large quantity lead to caking. The anti-caking BASF plant, Oppau, 1921 procedure at that time was to use dynamite! It was repeated over 20,000 times with no large explosion before that day. On 21 September in 1921, two consecutive explosions Similar risky procedures were at the origin of other accidents occurred in a silo in the BASF plant in Oppau, Germany, in Kriewald in Germany in 1921 (26 July)25 and Tessenderlo in creating a 20m deep, 90x125m large crater. The entire area Belgium in 1942 (29 April)26. was covered by dark green smoke and there were several additional fires and small explosions. -
The Seveso Disaster Legacy Laura Centemeri
The Seveso disaster legacy Laura Centemeri To cite this version: Laura Centemeri. The Seveso disaster legacy. Nature and History in Modern Italy, Ohio University Press & Swallow Press, pp.251-273, 2010. hal-01016045 HAL Id: hal-01016045 https://hal.archives-ouvertes.fr/hal-01016045 Submitted on 30 Jul 2014 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. 233 The Seveso Disaster Legacy Laura Centemeri 1. Introduction In the history of the environment as a public problem, industrial disasters have been insufficiently explored.1 Such disasters are nonetheless crucial because their collective interpretation weaves technical and scientific issues with problems of social justice and controversies concerning conflicting “common goods”, by destabilizing the equilibria that has formed between these elements.2 These disequilibria open the way for episodes of normative and cognitive uncertainty, and thereby become windows of opportunity for social critique and social change, especially by opening public debates on rules, institutions, and representations about technical progress. In short, industrial disasters become opportunities for rethinking the types of "compromise" between "orders of worth"—in particular industrial and civic--upon which a society rests.3 Yet there is still little acknowledgment of the social change that industrial disasters can trigger. -
Is the European Laboratory Over-Reach-Ing
Volume 21 Issue 1 Article 4 2010 Is the European Laboratory Over-Reach-ing - The Experimentation, Reaction and Product Yielded by the European Union's Registration, Evaluation, and Authorization of Chemicals Conrad Bendetto Follow this and additional works at: https://digitalcommons.law.villanova.edu/elj Part of the Environmental Law Commons, and the European Law Commons Recommended Citation Conrad Bendetto, Is the European Laboratory Over-Reach-ing - The Experimentation, Reaction and Product Yielded by the European Union's Registration, Evaluation, and Authorization of Chemicals, 21 Vill. Envtl. L.J. 75 (2010). Available at: https://digitalcommons.law.villanova.edu/elj/vol21/iss1/4 This Comment is brought to you for free and open access by Villanova University Charles Widger School of Law Digital Repository. It has been accepted for inclusion in Villanova Environmental Law Journal by an authorized editor of Villanova University Charles Widger School of Law Digital Repository. Bendetto: Is the European Laboratory Over-Reach-ing - The Experimentation, 2010] IS THE EUROPEAN LABORATORY OVER-REACH-ING? THE EXPERIMENTATION, REACTION AND PRODUCT YIELDED BY THE EUROPEAN UNION'S REGISTRATION, EVALUATION, AND AUTHORIZATION OF CHEMICALS I. BEFORE THE REACTION: AN INTRODUCTION TO REACH On July 10, 1976, in Seveso, Italy, just north of Milan, a mush- room cloud formed above a small chemical manufacturing plant, unleashing thirty to forty kilograms of TCDD into the atmosphere. TCDD is the most dangerous form of dioxin and a major compo- nent found in Agent Orange; it has an extremely adverse effect on the ecosystem and can cause numerous human diseases.2 Due to the dioxin spill, the human population suffered severe dermato- logic and hepatic repercussions which caused potentially lethal con- ditions, while various wild and domestic animals were either instantly and fatally poisoned by the chemical or slaughtered later as a preventive measure. -
The Texas City Disaster
National Hazardous Materials Fusion Center HAZMAT HISTORY The Texas City Disaster The National Hazardous Materials Fusion Center offers Hazmat History as an avenue for responders to learn from the past and apply those lessons learned to future incidents for a more successful outcome. This coincides with the overarching mission of the Fusion Center – to improve hazmat responder safety and enhance the decision‐making process during pre‐planning and mitigation of hazmat incidents. Incident Details: Insert Location and Date Texas City, TX April 16, 1947 Hazardous Material Involved Ammonium Nitrate Fertilizer Type (mode of transportation, fixed facility) Cargo Ship Overview The morning of 16 April 1947 dawned clear and crisp, cooled by a brisk north wind. Just before 8 am, longshoremen removed the hatch covers on Hold 4 of the French Liberty ship Grandcamp as they prepared to load the remainder of a consignment of ammonium nitrate fertilizer. Some 2,086 mt (2,300 t) were already onboard, 798 (880) of which were in the lower part of Hold 4. The remainder of the ship's cargo consisted of large balls of sisal twine, peanuts, drilling equipment, tobacco, cotton, and a few cases of small ammunition. No special safety precautions were in focus at the time. Several longshoremen descended into the hold and waited for the first pallets holding the 45 kg (100 lb) packages to be hoisted from dockside. Soon thereafter, someone smelled smoke, a plume was observed rising between the cargo holds and the ship’s hull, apparently about seven or eight layers of sacks down. Neither a 3.8 L (1 gal) jug of drinking water nor the contents of two fire extinguishers supplied by crew members seemed to do much good. -
EPISODES of ENVIRONMENTAL POISONING WORLDWIDE N J Langford, R E Ferner *855
Occup Environ Med: first published as 10.1136/oem.59.12.855 on 1 December 2002. Downloaded from EPISODES OF ENVIRONMENTAL POISONING WORLDWIDE N J Langford, R E Ferner *855 Occup Environ Med 2002;59:855–860 The environment is composed of chemical substances, many of which are poisonous if present in large amounts, and some of which are poisonous even in small quantities. Within the industrial- ised world, specific concentrations of highly dangerous chemicals may be localised to a certain area, vastly increasing the risk to the local environment. Although highly regulated by legislation such as the Control of Major Accident Hazards Regulations 1999 (COMAH), and agencies such as the Health and Safety Executive (HSE) and the Environment Agency (in England and Wales), or the Scottish Environment Protection Agency (SEPA) (in Scotland), industry has been a common source of environmental contamination. Additionally, as we discuss below, manufacturing of chemicals is not the only industrial process that places the environment at risk. Environmental poisoning can also result from the transport, storage, and secondary uses of the primary product. Small scale releases of toxic chemical substances are common within the industrialised world.1 Their impact is usually limited by effective statutory controls and efficient emergency services, but the combination of system failures can lead to disaster. In limiting the impact of such chemical releases, effective communication is required not only between the operator and emergency serv- ices but also from the emergency services to the public. Without such communication, panic may ensue, leading to emergency and hospital services being overwhelmed and prevented from effec- tively pursuing their roles. -
Exposure to Endocrine Disrupting Chemicals and Risk of Breast Cancer
International Journal of Molecular Sciences Review Exposure to Endocrine Disrupting Chemicals and Risk of Breast Cancer Louisane Eve 1,2,3,4,Béatrice Fervers 5,6, Muriel Le Romancer 2,3,4,* and Nelly Etienne-Selloum 1,7,8,* 1 Faculté de Pharmacie, Université de Strasbourg, F-67000 Strasbourg, France; [email protected] 2 Université Claude Bernard Lyon 1, F-69000 Lyon, France 3 Inserm U1052, Centre de Recherche en Cancérologie de Lyon, F-69000 Lyon, France 4 CNRS UMR5286, Centre de Recherche en Cancérologie de Lyon, F-69000 Lyon, France 5 Centre de Lutte Contre le Cancer Léon-Bérard, F-69000 Lyon, France; [email protected] 6 Inserm UA08, Radiations, Défense, Santé, Environnement, Center Léon Bérard, F-69000 Lyon, France 7 Service de Pharmacie, Institut de Cancérologie Strasbourg Europe, F-67000 Strasbourg, France 8 CNRS UMR7021/Unistra, Laboratoire de Bioimagerie et Pathologies, Faculté de Pharmacie, Université de Strasbourg, F-67000 Strasbourg, France * Correspondence: [email protected] (M.L.R.); [email protected] (N.E.-S.); Tel.: +33-4-(78)-78-28-22 (M.L.R.); +33-3-(68)-85-43-28 (N.E.-S.) Received: 27 October 2020; Accepted: 25 November 2020; Published: 30 November 2020 Abstract: Breast cancer (BC) is the second most common cancer and the fifth deadliest in the world. Exposure to endocrine disrupting pollutants has been suggested to contribute to the increase in disease incidence. Indeed, a growing number of researchershave investigated the effects of widely used environmental chemicals with endocrine disrupting properties on BC development in experimental (in vitro and animal models) and epidemiological studies. -
Variables Associated with the Classification of Ammonium Nitrate – a Literature Review
Variables Associated with the Classification of Ammonium Nitrate – A Literature Review FINAL REPORT BY: Sean Gillis Sreenivasan Ranganathan Fire Protection Research Foundation, Quincy, MA March 2017 © 2017 Fire Protection Research Foundation 1 Batterymarch Park, Quincy, MA 02169-7417, USA Email: [email protected] | Web: nfpa.org/foundation —— Page ii —— FOREWORD Ammonium Nitrate (AN) “is a chemical compound produced in both solid and liquid forms that is commonly used in fertilizers”. The burning rate of technical-grade AN prill falls within the Class 2 oxidizer criteria in Annex G of NFPA 400, 2016. The loss history of AN also indicates potential for unstable reactive hazard properties, uncontrolled decomposition and/or detonation under circumstances that are not fully understood. In the most recent revision of NFPA 400, Hazardous Materials Code, the Technical Committee (TC) classified Ammonium Nitrate as a Class 2 Oxidizer. However recent hazardous material incidents involving AN have resulted in differing views regarding the reactivity of the compound and whether or not it should be considered an unstable reactive in NFPA 400. The different behaviors of AN in different fire situations make it difficult to determine the appropriate safe practices for AN storage and handling. There are also discrepancies between the NFPA and International Fire Code (IFC) classifications of Ammonium Nitrate. As a result there is a need for additional data to assist in the proper classification/treatment of AN. An examination of existing data involving the reactivity of AN will assist the NFPA 400 TC in determining the appropriate classification of Ammonium Nitrate, and perhaps point to a need for future Ammonium Nitrate testing. -
The Role of Leadership and Development of Management Systems to Ensure Safety Performance in Energy Sectors
THE ROLE OF LEADERSHIP AND DEVELOPMENT OF MANAGEMENT SYSTEMS TO ENSURE EFFECTIVE SAFETY PERFORMANCE A Thesis by SEYEDSHAYAN NIKNEZHAD Submitted to the Office of Graduate and Professional Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Chair of Committee, M. Sam Mannan Committee Members, Efstratios N. Pistikopoulos Mahmoud El-Halwagi Michael Wesson Intercollegiate Faculty Chair, Efstratios N. Pistikopoulos August 2017 Major Subject: Energy Copyright 2017 Seyedshayan Niknezhad ABSTRACT Safety is one of the crucial issues that industry has aimed at improving for many decades and continues to progress. Discoveries show that organizations optimize their effort when they provide effective management systems to support front line employees, supervisors, and senior level managers. In this research, the role of leaders regarding safety in the energy industry is studied, and moreover, how to develop safety management systems to ensure an effective safety performance is surveyed. Leadership has the greatest impact on safety improvement. Leaders by different techniques can increase their influence on employees; set the mission and vision for staff; implement rules; provide resources; improve the teamwork; make effective communication from top to bottom, bottom to top and along the organization, educate staff, develop a safety management system, and create safety culture in the organization. By organizational safety culture, I mean the shared common values that drive organizational performance, more commonly defined as “the way we do around here.” While there are regulations regarding safety, every organization requires self-standard beyond the codified rules to have effective safety programs. Regulations should follow new research to develop new management systems to ensure the highest standards for safety. -
Galveston's Balinese Room
Official State Historical Center of the Texas Rangers law enforcement agency. The Following Article was Originally Published in the Texas Ranger Dispatch Magazine The Texas Ranger Dispatch was published by the Texas Ranger Hall of Fame and Museum from 2000 to 2011. It has been superseded by this online archive of Texas Ranger history. Managing Editors Robert Nieman 2000-2009; (b.1947-d.2009) Byron A. Johnson 2009-2011 Publisher & Website Administrator Byron A. Johnson 2000-2011 Director, Texas Ranger Hall of Fame Technical Editor, Layout, and Design Pam S. Baird Funded in part by grants from the Texas Ranger Association Foundation Copyright 2017, Texas Ranger Hall of Fame and Museum, Waco, TX. All rights reserved. Non-profit personal and educational use only; commercial reprinting, redistribution, reposting or charge-for- access is prohibited. For further information contact: Director, Texas Ranger Hall of Fame and Museum, PO Box 2570, Waco TX 76702-2570. Galveston’s Balinese Room Galveston’s Balinese Room Born: 1942 – Died 2008 The Balinese Room was built on a peer stretching 600 feet into the Gulf of Mexico. Robert Nieman © All photos courtesy of Robert Nieman unless otherwise noted. For fifteen years, Galveston’s Balinese Room was one of the most renowned and visited gambling casinos in the world. Opened in 1942 by the Maceo brothers, it flourished until 1957, when the Texas Rangers shut it down permanently as a gambling establishment. In the times that followed, the building served as a restaurant, night club, and curiosity place for wide-eyed visitors. Mainly, though, it sat closed with its door locked—yes, it had only one door.