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A Devotion to Their Science Pioneer Women of Radioactivity

MARELENE F. RAYNER-CANHAM

AND GEOFFREY W. RAYNER-CANHAM

SENIOR AUTHORS AND EDITORS

Chemical Heritage Foundation Philadelphia

McGill-Queen's University Press Montreal & Kingston • London • Buffalo Contents

Preface ix Acknowledgments xi Foreword xii MARIANNE AINLEY

PART ONE THE OVERVIEW 1 i Early Years of Radioactivity 3 2 Pioneer Women of Radioactivity 12

PART TWO THE FRENCH GROUP 29 3 Marie Curie: Time Only for Science and Family 31 HELENA M. PYCIOR 4 Ellen Gleditsch: Professor and Humanist 51 ANNE-MARIE WEIDLER KUBANER AND GRETE P. GRZEGOREK 5 May Sybil Leslie: From Radioactivity to Industrial Chemistry 76 6 Catherine Chamie: Devoted Researcher of the Institut de 82 vi Contents

7 Stefania Maracineanu: Ignored Romanian Scientist 87 MIRUNA POPESCU, MARELENE F. RAYNER-CANHAM, AND GEOFFREY W. RAYNER-CANHAM 8 Alicia Dorabialska: Polish Chemist 92 STEPHANIE WEINSBERG-TEKEL 9 Irene Joliot-Curie: Following in Her Mother's Footsteps 97 E. TINA CROSSFIELD 10 ... And Some Other Women of the French Group 124

PART THREE THE BRITISH GROUP 127 11 Harriet Brooks: From Research Pioneer to Wife and Mother 129 12 Fanny Cook Gates: A Promise Unfulfilled 138 13 Jadwiga Szmidt: A Passion for Science 145 14 Ada Hitchins: Research Assistant to Frederick Soddy 152 15 ... And Some Other Women of the British Group 156

PART FOUR THE AUSTRO-GERMAN GROUP l6l 16 : The Foiled Nobelist 163 SALLIE A. WATKINS 17 Stefanie Horovitz: A Crucial Role in the Discovery of 192 18 : Discoverer of the Cosmic Ray "Stars" 196 LEOPOLD E. HALPERN 19 Elizaveta Karamihailova: Bulgarian Pioneer of Radioactivity 205 SNEZHA TSONEVA-MATHEWSON, MARELENE F. RAYNER-CANHAM, AND GEOFFREY W. RAYNER-CANHAM 20 Elizabeth Rona: The Woman 209 21 Ida Tacke Noddack: Proposer of Nuclear Fission 217 FATHI HABASHI 22 ... And Some Other Women of the Austro-German Group 226 vii Contents

Epilogue: The End of an Era and a New Generation 229

Appendix: Dates of Selected Events in the History of Atomic Science (1895-1940) 235 Contributors 237 Notes 239 Index 303 7 Stefania Maracineanu: Ignored Romanian Scientist

MI RUNA PO PESCU, M A RELENE F. RA YNER-CAN I-I AM, ,nd GEOFFREY W. R AYNER- C AN H AM

As we look baek in time, it is d iffieu lt to appredatc the chal1enge that face

Curies would later I\.>ceive credit. As part of her study, she devised a mcthod for the measurement of thc intcnsity of strong a-ray emil­ ters.' On Ihe hasis of s uch promising research work, she was awardcd il doctorale degree in 1924.4 Marilcîneanu then applied for a posilion in her homeland to TUn the proposed Romanian Laboratory for the measurement of radioac­ livity. Curie wrote a reference for her. "1 have great cstccm for the work that shc ha s accomplished. In particular, shc has acquired a perfect knowlcdge of precise elcctrometric mea s urement s.~5 It is not dear whether shc was unsuccessful or whether the position did not materialize, for she continued to work in Paris with Curie for one more ycar, and then at the Meudon and Paris Astronomical Obscr­ vatori es with H. Deslandres until 19)o. Maracîneanu bcd that the half-life of polonium was differcnt when the polonium was dcposited on lcad, if th e deposilion was pcrfomed in sunlight.6 5he argued Ihat Ihe sun's rays had caus...'<1 the lead, then known 10 be the end of Ihe serics, ilself 10 become radioactive. In 1925 while al Meudron, she reported as long as a month. It is important to note thal Maracîneanu was not alone in heT convictions thal sunlight could induce materials 10 become radioacIÎ\'e. Three yea rs earlier, A. Nodon had proposcd that the sun and the uppcr atmosphere emitted pcnctrating radiation, enough 10 discharge elcctroscopcs and darken sealcd photographic film (this may have becn the effect of cosmic rays).! The following year, he d aimed Ihal Ihe rate of radioactive decay was affected by the sun.9 Maradneanu then lumed hcr attention 10 the measuremenl of Ihe level of radio."lctivily in ancient lcad roofs. Her studies suggested that south-facing roofs showed higher levels of radioactivity than north­ facing roofs. 'O H. Deslandrcs, who prcsented her result5, supportcd her findings, himself concluding thal the musl be due to some unknown fonn of radiation frorn the sun that he desig­ natcd ultril x." Gcnnan scientist5 became involvcd in the controversy over the sourre of this radiation from Ihe sun, atmosphere, ar both. {)ne of her fonner colleagues at the Institut de Radium, Franz Behounek. daimed that it was simply natural radioactivity that was being found, '2 while W. Kolhorster argued in support of Maracineanu. 'l Elizilbeth R6na '4 became involved in the debale, finding no evi­ dence that Ihc polonium in Maracineanu's earlier experiment5 could 89 Stefania Maracineanu rapidly have diffused inlo the lead 10 cause Ihe SUpposed radioactiv­ ity of the lead itsclf. '5 However, Maracineanu may have been observ­ ing decay fragments Ihal had become imbedded in the lead as a result of the Temil from partide emission, the phenomenon first observed by Harriet Brooks. ,6 Maradneanu had thought Ihal the solar radialion had oonverled lead back to polonium, but by 1928 she had decided that radium 0, the radioactive of lead, lead-l10, was actuaJly being formcd. '7 In 1929 she found evidenc:e of mercury, gold, and helium in the sun­ exposed lead, suggesting that Ihe lead had becn transmuted into the two other melal s.'" A flurry of papers on this subject appeared in 19JO, mosi, but not ali, attacking Maracincanu's claims. Fabry and Debreuil rcportcd that they had found no evidcnce of nuclear trans­ formations in old lead roofing as Maracineanu had claimcd. '9 Mara­ cineanu responded by suggesting that they had not obtained pmper samples.'" She had some supporters: the German scientist G.I. Pok­ rowsky had rcportcd thal x- rays and gamma rays had cause7 Meanwhile, in the German literature Mara­ cineanu and Behounek had a lively exchange on the topic of the quality and interpretation of Maradneanu's lIleasurcment.s ..!I This markcd the end of Maradneanu's ill-fatcd series of publica­ Hons on the possibility of the sun's rays causing radioacti ve tranSrOf­ mations. Neverthelcss, Maracineanu was convinced that she had bcen the first to observe Ih e phenomenon of artificial radioactivity. That is, through the bombaroment of a stable isotope wi th radiation she had generated a different, radioactive subslanc:e. It is possible in her early experiment5, when a layer of radioactive polonium was placed on different metal surfaces, some of the nuclei of the under­ Iying metal atoms oould have becn affectcd by the alpha rays in a nuclear reaction. However, the findings described by Maraci neanu more likcly rcsulted from thc recoil of the decaying radioactive atom. 90 The Fn'nch Gmup

There is certainly no oon temporary evidence ta support her theory of lighl-induced radioactivity. Convinced of the validity of her arguments, Maracineanu wrole la Lise Meitner in 1936 expressing her dismay Ihal lri:!ne Joliol-Curie, without acknowledgi ng Maracineanu, had used much of her work ­ parlicularly thal dealing wilh Ine phenomenon of artificial radioac­ li vi ty - in her publkations.>!I lrime Joliot-Curie had oommented. in 1934, "We recall Ihat the Romanian researcher [Maracineanu[ made a public announcemenl of Ihe discovery of the artifical radioactiv­ ity."" Marilcineanu noneth eless made her disagreement with the Joliot-Curies publk in a spirited. stalemenl of her claims ta Ihe prior discovery of artificial radioactivity during her work in Paris) ' In her own oountry she received grealer rerognilion. AI a meeting of Ihe Romanian Academy in 1936, the president, Alex Lapedatu, oongrat­ ulatcd h('r an her research work in Ihe field of artificial radioactivity: "This work places her among th(' ranks of Ihc famous sdentists who have studied Ihe problem."}> In 1930, Ihe year she ret umed to Romania,. Maracineanu took her research in il new direction, publishing a paper in which she posiled a link belween radioactivity and induced rainfal!. 5he recounled how her experiments on radioactivity induced by solar activity seemed la cause localizcd rain}' ln lhc wet climate of Bucharesl, It was difficult la prove her hypolhesis thal artificial rain oould be generated by Ihe pl'l.'SC nce of radio."lctive sources. To provide a more chal1enging test, Maracineanu obtained permission from the French aulhorities 10 tTilVel 10 the deserl regions of Ihe Touggourl territory of Algeria.>+ According la the auth orilies, the results of the expedilion were noi promising.'S bul th e representalive of Ihe govemor general of Alge­ ria senl Maracineanu an enoouraging lelter expressing his apprecia­ tion fo r her tenacity in purs uing Ihe research in spite of Ihe debililating heat.,ti Upon her retum la Bucharest, and as a resul! of her obscrvations of Ihe weath er, she daimed ta find a oorrelation between earthquake activily and rainfall.J7 She argued that thc link was electrical purturbalions in the atmosphere and the ground. Maracineanu died in 1944. The exact date was not recorded. In Augusi o( that year Romania was invaded by Ihe Russian army; whether her death was in some way related. to this event is not kn own.

Although we mi ghl dismiss somc of Maracineanu's proposals as unaccepiable, we lend la forge! thal in the early part of thc cenlury, Ihe nature of radioactivity was not well undcrstood. Many fam ous 91 Stefania Maracineanu sdcntists, including J.J. Thomson, hcld some belicfs that wcre latcr discredited. Maracincanu was obviously a dedicatesumably be the dean or who­ .. ver conlrolled lhe r<'S(!arch funding. 25 MllL." C. Chami ~ and H. Fil ~akova . uSur l'absorplion du polonium par le mereure dans diff~ rentes solutions,H Joumal de chimie el de physiro and Mmes H. Faraggi t'S " la deaoiSSOllct el ~ I"oeeumulali"" d .. rodon ou "minalion du ""Iiunl (['aris: Gaulhier-Villars. 1930)' 29 C. Chami~, Principes 1I00wear de psyelwlogie (Paris: Hermann, '937)' JO C. Chami~. Psyclwlogie tU saooir (Paris: Hermann, '950). 31 We thank Gimme GabJot. archivist, An:hives Curie el Joliol.curie, for this search. 32 Morse Haissinsky, u IAboroloirt Curie el 5l)Il apporl aux scienct'S 1I11c1~air(S (Paris: Laboratoire Curie, ' 97'). )3. 3) Eli7.abeth R6na, ~La boralOry Contamination in the Early Period of Radiation Re$I.'an; h ,~ Heollh Physics 37 (1 979): 72)-'7.

C I1APT E M SEVEN

MOSI of the biographical information on Maradneanu was obtain~>d from CG. fI

4 Mme Monique Bordry, Institut Curie, is thanked for this information. The thcsis was laic. published as S~phanie Maracineanu, &c~ SI" /11 rons/mllr du pa/onium el sur III pene/TII/ion d~ SUhs/ll l1 c:tS rlldiollc· I;1Ie5 dllllS les melilux (Paris: Presses universitaires de France, '924). 5 M. Curie 10 Ihe Faculty of Science, Bucharest,. , August '94 I.ibrary of tne Romanian Academy. 6 S. Maracineanu, "Rechen:hes sur la I*nNration des substanres radioactives dans les ml!tau~ ,~ Compld ""dus '77 (liFt)}: '~' 5- '7 ; S. Maracineanu, "R«hen:hes sur l'effel du solcil au polnt de vue r,ldioactif,# BIII/etin

als, N Si l z ung br richl~ Aktukmi~

18 S. Maracineanu, ~ L'effet du rayonnement solaire sur les phenomenes

de radioactivi tl! el dl! tral\Smulation. ff Bul/tiin d~ III ~'ion 5cicn/iji'lu ~ de I'AaulI'mw R ou "," i ,, ~ 12 (' 929): 5-<). 19 Ch. Fabry and E. Dubreuit "Sur une pretendue transformation du plomb par l't'ffet du raYOl\I'lemenl solaire,H CDmp'~ ,.."dus ,<)O ('9}O): 9' . 10 S. Maracineanu, ~Remarques sur unI' nole de MM. Fabry and Dubreuil inlituMe: sur unI' prl!tendue transformation du plomb par l'cffel du rayonnemenl solaire,H Co",p'~ ""dus 1<)0 (19JO): J7}-4. 2' G. l. Pokrowski. HQber eine m/lglische Wirkung kurzweUiger Slrml­ ung auf Atomkeme," Zeitschrifl fii r Physik 6} (19}O): 561--73. 2J See, for example, J. Reboul, HSur ['l!mission probabil' d'un rayonne­ meni peu penl!trant par certains ml!taux," Compla ""dus 19/> (19)J): IS96-8; J. Reboul, HSur ['action Ol!rd!Eo par les mMi\ux o rdinaires sur la plaque photographique el sur l'ell!drometre/ Compln ""dus 202 (936): '920-2. 2) A. Smits and Mile C.H . Ma<:Gillavry, HRemarques sur la note de Mile. Maracineanu;' Compln ",,,dus ,<)O (' 9)0): 6)5-'7· 24 A. Boularic and Mile Madelcine Roy, "Sur la rad ioactivitl! de divers mNaux pmvenanl de loitures anciennes,N Compln ""dus ,<)O (' 9JO): 48)-5· 25 A. Lepape and M. Ce-slin, ·Sur la radioactivitl! a<:quise par les mat&­ riaux exposl!s ~ I'action de!i agents almosphl!riques,H Comp/~ "",dus ,<)O (19)0): 6]6--8. 26 A. Boutaric and Mile Madcleine Roy. HSur la radioactivill! des mall!­ riaux pmvenant de toitures anciennes,"" Co"'pl~ ,.."dus 1<)0 (19)0): '410-2. 27 S. Maracineanu, NRemarques sur les noles de MM. Smits, Boutaric el Lepapc," Bulleli" dt 1" 5«tiem SeicntijiqUl dt I'ACfJdmrit RoumllllÎt 1) ('9)0): 55--8· :z8 H. Behounek. "Ein Beitrag zu den Versuchen iiber die Beeinflussung des radioaktiven Zerfalles,H Physiblisclu Ztitschrift )' h9JO): ~IS -24 ; S. Maracineanu. "Bemerkungen zu Behounek: Ein Beilrag zu den Ver­

suchen iiboer die Beeinflussung des radioactiven Zerfalls, ff Physibliseht liilschrift ) 1 119)0): 1 0J2~; F. Behounek. ~Erwid ero ng auf dic

Bemerkungcn von Frl. Sl Maracineanu, N Physiblischt Zeit5<'hrift 3' (19JO): 10)6-8; Stl!phanie Maracineanu, *Bemerkungen zur

Erwidcrung des Hcrm Behounek. ff Physiblischt ZriI5<'hrifl }1 (1 9}O): 'O)8-<}. 29 S. Maracineanu 10 L. Meilner, 12 Man:h 19)6, Meitner Collt'C"lion, CC A. )O Nrues Wir"..,. Zeitsch rift, 5 June ' 9)4· 31 Unidentified and unmled publicalion, S. Maracineanu, Library of the Romanian Academy.

Bull. Hist. Chem., VOLUME 25, Number 2 (2000) 103

STEFANIE HOROVITZ, ELLEN GLEDITSCH, ADA HITCHINS, AND THE DISCOVERY OF ISOTOPES

Mrln . nrCnh nd Gffr W. nrCnh, Sr Wlfrd Grnfl Cll

In th ntf dvr pr, n tnd t f r f 860 (4. h ht r nltd th n th "Grt " nd nr th rrhr h th v tht th fndtn f htr dpndd d th tl dvr r ntrbtd nfntl pn th n vl f th t ht f h l t th dvr. h frt dttn f plr a nt—nd n th tblt f th lnt th l xpl h brvtn d b rd lv. t tdnt, ln rnll, bt t hr prvr, h frt r n th fçd f trdtnl h Anthn h, h rvd th bl rz fr th tr th th dvr f rdtv trnfr dvr (. In th frt dd f th 20th ntr, tn (. h vr p n th d n th l f ttrbtn t th lbbnh rrhr h r dntfd b n lnd t tht f th prnt. hd nfnt fft f hdn th ntrbtn f r xpl, thr dd t thr I, t n ntt, fr f r bl t br thrh thr II, t rdthr, t thr , nd th "l ln" nd ttn rntn pr r n. At th t, h f th p blvd t rhr. b n nd n lnt. It MC nd At n n r hr n n n 0 h prvdd th nxt p n th pzzl th tt pld tv thh brdnt rl (2 (th th ttnt tht (6: th xptn f Mr Cr nd Mtnr. r Our experiments trnl ndt tht rdthr xpl, Ernt thrfrd frt rrh tnt ntrl nprbl fr thr b hl pr n—rrt r. W hv rprtd lhr . n hr rr, nldn th dvr f th rl f Expl f hll nnprbl pr (nd rp th rdtv t (. In th ppr, th f ll b f rdtv lnt bn t lt vr rp n th ntrbtn f thr n t th rl r dl. thr thn th br phr rd l n tp: Stfn rvtz, Elln Gldth, nd Ad nt hll nnprbl, Sdd td tht thn. But first, it is necessary to rv th rnd th tr tp b ntrdd (. r tht d th dvr f th xtn f tp pbl. It th jnSdd Grp plnt tht prvdd th nxt tp n th pzzl (8. In rd Background tv d, l f n prtl rltd n ttp hft t th lft n th prd tbl th n pn rntd ntt tnd t frt tht, fr th rl n t ht l f fr nt, hl l f bt htr f htr, t ht f pr prtl rltd n ntp hft t th rht th prtn. r xpl, th vl f th t ht nlbl hn n t ht. Strtn th th f lnt th pr f f th Krlrh Cn t f rn nd thr, Sdd l

104 Bull. Hist. Chem., VOLUME 25, Number 2 (2000)

lated the expected atomic weights of the lead produced jn n rlzd tht th t [f pr t from their respective radioactive decay as very differ- ht dtrntn] rrd h r tht ent from the 207.2 of 'normal' lead (9). To chemists, nl th rlt f rnzd xprt ld b dl finding samples of lead that had 'abnormal' atomic ptd. Sdd prtd n h ffrt, nl t hv weight would be a confirmation of the existence of iso- h rlt vd ptll n rtr. topes and proof of the group displacement law. In par- h world's leading expert on the measurement of ticular, lead from the decay of -238 was pre- atomic weights was Theodore William Richards of dicted to have an atomic weight of about 206 while that Harvard (13), but almost as high in estimation were his from the decay of -232 was expected to have an two former students, Gregory Paul Baxter, also of Harvard, and Otto Hönigschmid at the Radium Institut in Vienna (14).

Stfn rvtz

Hönigschmid had the talent and also the opportu- nity, for the major source of radioactive ores at the time was the mine at St. Joachimstal in Austria (15). Much of his work was accomplished with his research student, Stefanie Horovitz. Horovitz was born in Warsaw on April 17, 1887, her family moving to Vienna about 1890 (16). She graduated from the University of Vienna in 1914 with a doctorate in organic chemistry, although she seems to have started as a research worker at the Radium Institute of Vienna with Hönigschmid in late 1913. Hönigschmid was actually affiliated with the Technical University of Prague from 1911 to 1918, but he maintained research facilities in Vienna. Horovitz's initial task was the time-consuming separation of lead from the residues of the radioactive ores after the radium had been extracted. This was fol- lowed by the demanding gravimetric procedures to the Élln Gldth, rdtn pht, 02. (. Krnnn nearest hundred thousandth of a gram. The first report nd A. C. pp by Hönigschmid and Horovitz provided a value of 206.736 for the atomic weight of lead from the St. Joachimstal mine, compared to 207.190 for 'normal' lead atomic weight of about 208. It is the contributions of (17). Such a significant difference from a respected three women scientists to the discovery of lead with 'ab- analytical laboratory was the first definitive evidence normal' atomic weights that will be the focus of this that atomic weights were not necessarily invariant. As study (10). a result of its importance, this paper by Hönigschmid To accomplish this task, researchers needed lead- and Horovitz was chosen by Henry Leicester as one of containing samples from uranium or thorium ores. In the crucial publications in chemistry in the first half of addition, for the results to be accepted among the scien- the twentieth century (18). The two researchers were tific community, the researchers themselves had to have dedicated to their work, as is apparent in a letter from credibility in the field of the determination of atomic Hönigschmid to Lise Meitner (19): weights to high precision. Although Soddy and his col- ... Miss Horovitz and I rd l l. On th laborator, Henry Hyman, and Maurice Curie, nephew btfl Snd r tll ttn n th lbrtr of Marie Curie, both reported atomic weights of radio- t 6 l. active-origin lead that were significantly different from Subsequently, Hönigschmid and Horovitz analyzed new that of normal lead (11), neither of these reports was samples from St. Joachimstal as well as samples from sufficiently reliable in the eyes of analytical chemists. two other mines: pitchblende from German East Africa; As Badash has commented (12): and bröggerite from Norway. These results were even Bull. Hist. Chem., VOLUME 25, Number 2 (2000) 105

more convincing, giving values as low as 206.046 (20). firmly fixed ideas concerning the chemical elements A difference of over one mass unit could not be explained and their mutual relations, as well as the nature of by experimental error. There clearly were significant atoms. differences in the atomic weight of lead, depending upon His first report described lead samples with abnormally source. low atomic weights, the lowest value of 206.40 coming from a sample of uraninite from North Carolina (26). Hönigschmid and Horovitz made a second contri- This particular lead sample was noted in the data table bution to the isotope story. Boltwood had claimed the as being provided by Gleditsch. This was Dr. Ellen discovery of another radioactive element, ionium (21). Gleditsch, who at the time was working with Bertram Most chemists accepted the existence of this element, it Boltwood at Yale. In the paper, Richards stated that this even being assigned a symbol, Io. However, it was the "most valuable" of atomic weight the samples had and spectro- been supplied by scopic analyses Gleditsch as lead performed by chloride; thus Hönigschmid Gleditsch played an and Horovitz that active role in the showed ionium discovery process to be no more by performing the than an isotope extraction of a pure of thorium, mak- lead salt from the ing thorium only uranium ore. In a the second ele- subsequent paper ment for which (27) Richards re- isotopic behavior ported atomic had been proven weights of 206.12 at that time (22). and 206.08 for lead These were the from uranium ore last publications samples obtained of Horovitz. from Norway. He Many years later, added that these two Horovitz's fate samples "of especial was discussed in Gleditsch, with her assistants Ernst Fyn (left) and Ruth Bakken (right), in the value and signifi- an exchange of Chemistry Laboratory, , ca 1930 (T. Kronnen and A. C. Pappas) cance (27)" were letters between both obtained from Kasimir Fajans and Elizabeth Róna (23). In the last of Ellen Gleditsch, who had returned, by then, to her na- the correspondence, Fajans commented (24): tive country of Norway. These values were so close to You probably have not received any information from that predicted by Soddy for pure lead produced at the Vienna about the fate of Dr. Stephanie Horovitz. I end of the uranium decay series that the group displace- learned about it from a mutual relative at Warzawa. ment law could no longer be in doubt. Stephanie moved there after World War I and after her parents had died in Vienna to join her married Gleditsch was born on December 29, 1879 in sister. She was not active in chemistry and both were Mandal, in southern Norway (28). After obtaining a liquidated by the Nazis in 1940. pharmacological qualification, she became a research assistant at the University of Kristiania (now Oslo), be- Ellen Gleditsch ing unable to afford to enroll as a university student. From 1907 to 1912, she worked with Marie Curie in Concurrently the master himself, T. W. Richards, had Paris, where she received the qualification of Licenciée launched an investigation into what he called a subject es Sciences. In 1913, Gleditsch received a fellowship of (25): to work with Bertram Boltwood at Yale (29). Although peculiar and extraordinary interest, because it in- he was opposed to women researchers, Gleditsch arrived volves a readjustment and enlargement of many rather before he had a chance to reject her application. Her 106 Bull. Hist. Chem., VOLUME 25, Number 2 (2000)

work on the half-life of radium (30) so impressed her sister, Liv Gleditsch (35). The results showed that, Boltwood that he became a warm friend. While at Yale, unlike lead, the average atomic weight of chlorine was she received an invitation from Richards to visit him at invariant with the mineral source. Gleditsch maintained Harvard, and it was possibly during the meeting that an active life, becoming president of the International she agreed to supply the lead samples that proved most Federation of University Women, and during World War crucial. About this time, she was awarded an honorary II, being an active member of the resistance. She died Doctor of Science degree from Smith College, at the age of 89 on June 5, 1968. Northampton, Massachusetts. Gleditsch was to have a very successful career at Ada Hitchins the University of Oslo, being hired initially as a docent The search for the higher atomic weight value of lead and, by the time she retired, becoming a professor of derived from thorium-232 decay was pursued by chemistry. She spent most of her nonteaching time in önhd Paris. For ex- (6 nd b ample, during Soddy. Soddy, in World War I, Curie the report of his pleaded with definitive result Gleditsch to return of 207.74, noted to Paris to super- the contribution vise the radium ex- of his research traction facilities. student, Ada This journey in- Hitchins, for the volved a danger- separation and ous voyage across analysis work the U-boat ridden (37). The sample North Sea; and used by , Hönigschmid was a friend of provided by Gleditsch, ar- Soddy (37); thus ranged for a secu- both teams prob- rity clearance for ably relied on her stopover in Hitchins' extrac- England on the tions. Born in De- way. Her teaching von, England (38) demands at Oslo in 1891, Hitchins were very heavy, graduated with a leaving little time B.Sc. from th for research. She Cnr n dtvt, Oxfrd, 2, Gldth rrndd b Irèn University of did manage some, ltCr (lft nd rtz nth nd Mrrt r (rht. Glasgow in 1913. however, particu- (. Krnnn nd A. C. pp She commenced larly during her many sojourns in Paris (31). Following research with Soddy during her last undergraduate r Richards' work, she reported on the atomic weight of and when Soddy moved to the University of Aberdeen lead in another mineral sample from Norway, this one in 1915, Hitchins accompanied him, obtaining a posi- giving a value of 206.17 (32). Then she commenced tion as Carnegie Research Scholar. It was during this work on a study of the atomic weight of chlorine. Irène period that Hitchins performed the extraction and ana- Curie had claimed to find a salt sample in which the lytical work on the lead samples from thorium ores. In atomic weight of chlorine was above the normal value addition, Hitchins took over the research on protactinium (33). Gleditsch and coworker B. Samdahl showed that of Soddy's other student, John Cranston, when the lat- the value resulted from a contamination with bromide ter was drafted for World War I (39). ion (34). Nevertheless, Gleditsch pursued a more thor- ough study of possible variations in the atomic weight In 1916 Hitchins herself was drafted to work in the of chlorine, some of the research being performed with Admiralty Steel Analysis laboratories (40). She rejoined

Bull. Hist. Chem., VOLUME 25, Number 2 (2000) 107

Sdd n 2, b hh t h hd vd t Oxfrd 5. See, for example: A. Romer, "The Transformation Unvrt. pt bl rz n Chtr, Sdd Theory of Radioactivity," r, 1958, 49, 3-12. hd rt dfflt n ttrtn rdt tdnt t 6. H. N. McCoy and W. H. Ross, "The Specific Radioac- r th h (4 th thn pld rl rl tivity of Thorium and the Variation of the Activity with Chemical Treatment and with Time," n Sdd rrh prr. Intll ppntd th . A. Ch. S., 1907, 2, 1709-1718. nl tnt, h prtd t prvt rrh 7. It is from the placement of different species in the same tnt n 22. Sdd ntd (42: box in the periodic table that tp — 'same place' ... she has also charge of my radioactive materials — derives. The origin of the name is described by ... and has worked up considerable quantities of ra- Alexander Fleck: "Up to 1913 we used the phrase 'ra- dioactive residues and other materials for general . dio elements chemically non-separable' and at that time thn fnll lft Sdd pl n 2, vn the word isotope was suggested in a drawing-room dis- cussion with Dr. Margaret Todd in the home of Soddy's t Kn th hr fl. hr h rd Gv father-in-law, Sir George Beilby. Dr. Todd was an rnnt Ar nd Cht n th Mnn nd G Édinburgh trained medical doctor and was a writer of ll prtnt f th Clnl Gvrnnt ntl some distinction under the name of Graham Travers. The h rtrd n 46 nd rtrnd t Enlnd. At readiness and etymological accuracy with which she pnt, lt n lf, h rrd frr, hn produced isotopes is a standing testimony to her practi- Stphn. Sh dd n rtl n nr 4, 2. cal knowledge of the Greek tongue." A. Fleck, "Frederick Soddy," r. M. ll . S., 1957, Commentary , 208. 8. L. Badash, "The Suicidal Success of Radiochemistry," r. . t. S., 1979, 2, 245-256. Sntf rrh n th rl dd f th 20th n 9. 'Natural' lead has an isotopic composition of Pb-204 tr nl rrdd l prrv, xpt (.%, Pb-206 (23.6%), Pb-207 (22.6%), and Pb-208 fr tht f Mr Cr. r, thr n ntt (52.3%). hv bn dntfd h pld nfnt rl n th 10. A more general survey has been given by G. B. dvr f th xtn f tp, n f th t Kauffman, "The Atomic Weight of Lead of Radioactive rl ntf fndn f th prd. In n r hn Origin," . Ch. Ed., 1982, , 3-8 and 119-123. n ntt r lrl nfnd t pprt rl 11. F. Soddy and H. Hyman, "The Atomic Weight of Lead (4, t prtnt t rrt th htrl rrd nd from Ceylon Thorite," . Ch. S., 1914, 0, 1402- nld th ntrbtn f rvtz, Gldth, 1408; M. Curie, "Sur les &arts de poids atomiques obtenus avec le plomb provenant de divers minéraux," nd thn. C. . bd. Sén Ad. S., Sr. C, 1914, 8, 1676- 1679. 12. Ref. 8, p 251. 13. G. S. Forbes, "Investigations of Atomic Weights by REFERENCES AND NOTES Theodore William Richards," . Ch. Ed., 1932, , 453-458; and H. Gay, "The Chemical Philosophy of 1. N. Wade, "Discovery of Pulsars: A Graduate's Story," Theodore W. Richards," Abx, 1997, 44, 19-38. Sn, 1975, 8, 358-364. 14. E. Zintl, "Otto Hönigschmid zum 60. Geburtstag," 2. It is noteworthy to recall that Marie Curie was a lecturer . Anr. All. Ch.,8, 26, 3-11; R. É. Oesper, "Otto at the teaching college at Sèvres, her ability to do re- Hönigschmid," . Ch. Ed., 1941, 562; and L. search being primarily a result of her egalitarian mar- 8, Birckenbach, "Otto Hönigschmid 1878-1945: In Memo- riage to Pierre. She emerged from Pierre's shadow only riam," Ch. ,., 1949, 82, 9-65. following Pierre's untimely death, when she was judged 15. F. A. Paneth, "St. Joachimstal and the History of the to be his only suitable heir at the Sorbonne. See, for Chemical Elements," in H. Dingle and G. R. Martin, example: R. Pflaum, Grnd Obn: Md Cr Éd., Chtr nd nd: A Sltn fr th Wrt nd r Wrld, Doubleday, New York, 1991 and S. n f th t rfr .A. nth, Interscience, New Quinn, Mr Cr: A f, Simon & Schuster, New York, 1964, 20-28. York, 1995. 16. M. F. Rayner-Canham and G. W. Rayner-Canham, "Ste- 3. M. F. Rayner-Canham and G. W. Rayner-Canham, fanie Horovitz: A Crucial Role in the Discovery of Iso- rrt r nr lr Sntt, McGill- topes," in M. F. Rayner-Canham and G. W. Rayner- Queen's University Press, Montreal, 1992. Canham, Ed., A vtn t thr Sn: nr 4. C. de Milt, "The Congress at Karlsruhe," J. Ch. Ed., Wn f dtvt, Chemical Heritage Foundation, 1951, 28, 421-425; and A. J. Ihde, "The Karlsruhe Con- Philadelphia, PA, and McGill-Queen's University Press, gress: A Centennial Retrospect," . Ch. Ed., 1961, Montreal, 1997, 192-195. 8, 83-86. 108 Bull. Hist. Chem., VOLUME 25, Number 2 (2000)

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