Polypropylene Chemical Resistance Tech Note (PDF)

Total Page:16

File Type:pdf, Size:1020Kb

Polypropylene Chemical Resistance Tech Note (PDF) Polypropylene Chemical Resistance Introduction Among many of the positive attributes of polypropylene, it is probably best known for its resistance to highly aggressive chemicals. While polypropylene is highly resistant to many chemicals at room temperatures, its chemical resistance decreases with increased temperatures. This technical note provides a basic resistance rating for many chemicals. This table is meant to serve as a general guide and should not be used to guarantee performance since specific site and application conditions may cause specific concerns which cannot be addressed in a general table. This chart rates the chemical resistance of polypropylene resin according to the following code: Ratings: A = Excellent B = Good, Minor Effect, slight corrosion or discoloration C = Fair, Moderate Effect, not recommended for continuous use. Softening, loss of strength, or swelling may occur. D = Severe Effect, not recommend for ANY use. N/A = Information not available Explanation of Footnotes: 1. means Satisfactory to 72°F (22°C) 2. means Satisfactory to 120°F (48°C) Chemical Compatibility Chemical Compatibility Chemical Compatibility Chemical Compatibility Ammonium Acetaldehyde A1-Excellent Alcohols: Diacetone B2-Good Alums A-Excellent Phosphate, A-Excellent Monobasic Acetamide A1-Excellent Alcohols: Ethyl A-Excellent Amines B2-Good Ammonium A-Excellent Phosphate, Tribasic Acetate Solvent B1-Good Alcohols: Hexyl N/A Ammonia 10% A2-Excellent Ammonium Sulfate A-Excellent Acetic Acid B-Good Alcohols: Isobutyl A1-Excellent Ammonia Nitrate A-Excellent Ammonium Sulfite A2-Excellent Acetic Acid 20% A-Excellent Ammonia, Alcohols: Isopropyl A2-Excellent A-Excellent Ammonium anhydrous N/A Thiosulfate Acetic Acid 80% A-Excellent Alcohols: Methyl A2-Excellent Ammonia, liquid A2-Excellent Amyl Acetate B1-Good Acetic Acid, Glacial A1-Excellent Alcohols: Octyl N/A Ammonium Acetate A-Excellent Amyl Alcohol B1-Good Acetic Anhydride B1-Good Ammonium Alcohols: Propyl A-Excellent A-Excellent D-Severe Bifluoride Amyl Chloride Effect Acetone A-Excellent Ammonium Aluminum Chloride A-Excellent A-Excellent Carbonate Aniline A1-Excellent Acetyl Bromide N/A Aluminum Chloride Ammonium A-Excellent N/A 20% Caseinate Aniline D-Severe D-Severe Hydrochloride Effect Acetyl Chloride (dry) Effect Aluminum Fluoride A-Excellent Ammonium Chloride A-Excellent D-Severe Antifreeze Effect Acetylene A1-Excellent Ammonium Aluminum Hydroxide A-Excellent A-Excellent Hydroxide Antimony Trichloride A-Excellent Acrylonitrile A1-Excellent Aluminum Nitrate A2-Excellent Ammonium Nitrate A-Excellent Aqua Regia (80% B1-Good HCl, 20% HNO3) Adipic Acid B2-Good Aluminum Potassium Sulfate A-Excellent Ammonium Oxalate A-Excellent D-Severe Arochlor 1248 10% Effect Alcohols: Amyl B1-Good Ammonium A-Excellent Aluminum Persulfate Aromatic D-Severe Potassium Sulfate A-Excellent Hydrocarbons Effect Alcohols: Benzyl A-Excellent Ammonium 100% A-Excellent Phosphate, Dibasic Arsenic Acid A-Excellent Alcohols: Butyl A-Excellent Aluminum Sulfate A-Excellent Page 1 of 6 1717 16th St NE | Willmar, MN 56201 | Phone: 800-922-1725 | www.prinsco.com © Prinsco, Inc. 04/17 Polypropylene Chemical Resistance Chemical Compatibility Chemical Compatibility Chemical Compatibility Chemical Compatibility D-Severe D-Severe Arsenic Salts N/A Butyl Ether Catsup A-Excellent Cresols Effect Effect Asphalt B1-Good Butyl Phthalate B2-Good Chloric Acid N/A Cresylic Acid A1-Excellent Barium Carbonate A-Excellent Butylacetate B1-Good Chlorinated Glue N/A Cupric Acid A2-Excellent D-Severe Barium Chloride A-Excellent Butylene N/A Chlorine (dry) Cyanic Acid N/A Effect D-Severe D-Severe D-Severe Barium Cyanide Butyric Acid B1-Good Chlorine Water Cyclohexane Effect Effect Effect Chlorine, Anhydrous D-Severe D-Severe Barium Hydroxide B-Good Calcium Bisulfate N/A Cyclohexanone Liquid Effect Effect Barium Nitrate A-Excellent Calcium Bisulfide A-Excellent Chloroacetic Acid C1-Fair Detergents A-Excellent Chlorobenzene Barium Sulfate B1-Good Calcium Bisulfite A-Excellent C1-Fair Diacetone Alcohol A1-Excellent (Mono) Chlorobromometha- Barium Sulfide B-Good Calcium Carbonate A-Excellent A-Excellent Dichlorobenzene C1-Fair ne D-Severe Beer A1-Excellent Calcium Chlorate N/A Chloroform C1-Fair Dichloroethane Effect D-Severe Beet Sugar Liquids A1-Excellent Calcium Chloride A2-Excellent Chlorosulfonic Acid Diesel Fuel A1-Excellent Effect D-Severe Benzaldehyde Calcium Hydroxide A2-Excellent Chocolate Syrup A2-Excellent Diethyl Ether A1-Excellent Effect D-Severe Calcium D-Severe Benzene A1-Excellent Chromic Acid 10% Diethylamine A1-Excellent Effect Hypochlorite Effect Benzene Sulfonic D-Severe D-Severe Calcium Nitrate A2-Excellent Chromic Acid 30% Diethylene Glycol A2-Excellent Acid Effect Effect D-Severe D-Severe Benzoic Acid B1-Good Calcium Oxide A-Excellent Chromic Acid 5% Dimethyl Aniline Effect Effect D-Severe Benzol B-Good Calcium Sulfate A-Excellent Chromic Acid 50% Dimethyl Formamide A-Excellent Effect D-Severe Benzonitrile N/A Calgon A-Excellent Chromium Salts N/A Diphenyl Effect D-Severe Benzyl Chloride C1-Fair Cane Juice C1-Fair Cider A-Excellent Diphenyl Oxide Effect Carbolic Acid Bleaching Liquors A1-Excellent B-Good Citric Acid A-Excellent Dyes N/A (Phenol) Borax (Sodium D-Severe Epsom Salts B-Good Carbon Bisulfide Citric Oils A-Excellent A-Excellent Borate) Effect (Magnesium Sulfate) D-Severe Boric Acid A-Excellent Carbon Dioxide (dry) A2-Excellent Clorox (Bleach) A-Excellent Ethane Effect Carbon Dioxide Brewery Slop N/A A2-Excellent Coffee A-Excellent Ethanol A-Excellent (wet) D-Severe D-Severe D-Severe Bromine Carbon Disulfide Copper Chloride A-Excellent Ethanolamine Effect Effect Effect D-Severe Butadiene C-Fair Carbon Monoxide A-Excellent Copper Cyanide A-Excellent Ether Effect Carbon D-Severe Butane A1-Excellent Copper Fluoborate N/A Ethyl Acetate A1-Excellent Tetrachloride Effect Butanol (Butyl Carbon D-Severe A1-Excellent Copper Nitrate A-Excellent Ethyl Benzoate B1-Good Alcohol) Tetrachloride (dry) Effect Carbon D-Severe D-Severe Butter N/A Copper Sulfate>5% A-Excellent Ethyl Chloride Tetrachloride (wet) Effect Effect D-Severe Buttermilk A1-Excellent Carbonated Water B-Good Copper Sulfate 5% A-Excellent Ethyl Ether Effect Butyl Amine B1-Good Carbonic Acid A-Excellent Cream A-Excellent Ethyl Sulfate N/A Page 2 of 6 1717 16th St NE | Willmar, MN 56201 | Phone: 800-922-1725 | www.prinsco.com © Prinsco, Inc. 04/17 Polypropylene Chemical Resistance Chemical Compatibility Chemical Compatibility Chemical Compatibility Chemical Compatibility D-Severe Gasoline (high- Hydrofluosilicic Acid Ethylene Bromide A-Excellent A-Excellent Lead Sulfamate A2-Excellent Effect aromatic) 100% Gasoline, leaded, Hydrofluosilicic Acid Ethylene Chloride C1-Fair B-Good A-Excellent Ligroin A2-Excellent ref. 20% Ethylene D-Severe Gasoline, unleaded C1-Fair Hydrogen Gas A-Excellent Lime N/A Chlorohydrin Effect Hydrogen Peroxide Ethylene Diamine N/A Gelatin A-Excellent A-Excellent Linoleic Acid B1-Good 10% D-Severe Hydrogen Peroxide Ethylene Dichloride Glucose A-Excellent B1-Good Lithium Chloride A2-Excellent Effect 100% Hydrogen Peroxide Ethylene Glycol A-Excellent Glue, P.V.A. N/A B1-Good Lithium Hydroxide N/A 30% D-Severe Hydrogen Peroxide Ethylene Oxide Glycerin A-Excellent B1-Good Lubricants A1-Excellent Effect 50% Hydrogen Sulfide Lye: Ca(OH)2 Fatty Acids A-Excellent Glycolic Acid A-Excellent A1-Excellent A2-Excellent (aqua) Calcium Hydroxide Hydrogen Sulfide Lye: KOH Ferric Chloride A-Excellent Gold Monocyanide N/A A1-Excellent (dry) Potassium A-Excellent Hydroxide Ferric Nitrate A-Excellent Grape Juice N/A Hydroquinone A-Excellent Lye: NaOH Sodium A-Excellent Hydroxide Hydroxyacetic Acid Ferric Sulfate A-Excellent Grease N/A N/A Magnesium 70% A2-Excellent Bisulfate Ferrous Chloride A-Excellent Heptane C2-Fair Ink N/A Magnesium A-Excellent Carbonate Ferrous Sulfate A-Excellent Hexane B1-Good Iodine C-Fair Magnesium Chloride A2-Excellent Fluoboric Acid A-Excellent Honey A-Excellent Iodine (in alcohol) N/A Magnesium A-Excellent Hydroxide D-Severe D-Severe Fluorine Hydraulic Oil (Petro) Iodoform N/A Effect Effect Magnesium Nitrate A-Excellent Hydraulic Oil D-Severe Fluosilicic Acid A-Excellent Isooctane A2-Excellent (Synthetic) Effect Magnesium Oxide N/A Formaldehyde 100% C-Fair Hydrazine C-Fair Isopropyl Acetate B1-Good Magnesium Sulfate A-Excellent (Epsom Salts) Hydrobromic Acid Formaldehyde 40% A-Excellent C1-Fair Isopropyl Ether B-Good 100% Maleic Acid A-Excellent Hydrobromic Acid D-Severe Formic Acid A1-Excellent A2-Excellent Isotane D-Severe 20% Effect Maleic Anhydride Effect D-Severe Hydrochloric Acid Jet Fuel (JP3, JP4, Freon 113 B1-Good A1-Excellent Effect 100% JP5) Malic Acid A1-Excellent Hydrochloric Acid Freon 12 A2-Excellent B2-Good Kerosene B-Good 20% Manganese Sulfate N/A Hydrochloric Acid Freon 22 B-Good C-Fair Ketones C-Fair 37% Mash N/A D-Severe Hydrochloric Acid, D-Severe Freon TF B-Good Lacquer Thinners Effect Dry Gas Effect Mayonnaise N/A D-Severe Freonr 11 A-Excellent Hydrocyanic Acid A-Excellent Lacquers Effect Melamine A-Excellent Hydrocyanic Acid Fruit Juice B-Good A-Excellent Lactic Acid B-Good Mercuric Chloride (Gas 10%) B-Good (dilute) Hydrofluoric Acid Fuel Oils A-Excellent C1-Fair Lard B1-Good 100% Mercuric Cyanide B-Good D-Severe Hydrofluoric Acid Furan Resin A2-Excellent Latex A2-Excellent Effect 20% Mercurous Nitrate A-Excellent D-Severe Hydrofluoric Acid Furfural A2-Excellent Lead Acetate A1-Excellent Effect 50% Mercury B-Good Hydrofluoric Acid Gallic Acid A-Excellent C1-Fair Lead Nitrate A2-Excellent
Recommended publications
  • Example of Tier I SPCC Plan
    Auto Service Station Facility Scenario Example Tier I Qualified Facility SPCC Plan Here is an example of an automotive service station facility and how the Step 1: Determine if the Gas owner determines he is covered by the SPCC rule and prepares an SPCC and Care Express needs an Plan. SPCC Plan. Description of Gas and Care Express Jack Smith, owner of the Gas and Care Express, believes he may have Gas and Care Express located in Malham, Pennsylvania is a self-service gasoline to develop, maintain, and implement station and automotive service shop offering basic automotive maintenance and a spill prevention plan under the repair services, including vehicle safety and emission inspections. The facility is SPCC rule. Let’s walk through the owned and operated by Jack Smith and is located at the intersection of Anywhere following scenario to determine if he and Sideways Streets. An empty lot sits adjacent to the back of the facility. A needs an SPCC Plan, and if so, then concrete storm drainage channel runs past one side of the empty lot and conveys we need to determine if he is eligible storm water into an unnamed creek about a 1/4-mile downstream from this location. to self‐certify his SPCC Plan and use The unnamed creek is a tributary of Muddy Creek, which is a tributary to the the Tier I SPCC Plan Template. Susquehanna River. There are four street storm culverts at the intersection where the facility is located. Storm water runoff collected by these culverts is conveyed by Is the facility or part of the facility the storm sewer into Muddy Creek at an outfall about 1 mile away.
    [Show full text]
  • Internal Revenue Service, Treasury § 48.4081–2
    Internal Revenue Service, Treasury § 48.4081±2 practical and commercial fitness solely sentence in the definition of terminal by reason of its possible or rare use as are effective January 2, 1998. a fuel in the propulsion engine of a [T.D. 8659, 61 FR 10453, Mar. 14, 1996, as highway vehicle, train, or boat. amended by T.D. 8748, 63 FR 25, Jan. 2, 1998] (iii) Cross reference. For the tax on blended taxable fuel, see § 48.4081±3(g). § 48.4081±1T Taxable fuel; definitions For the back-up tax on certain uses of (temporary). liquids other than diesel fuel, see (a) [Reserved] § 48.4082±4. (b) Definitions. (3) Gasoline blendstocksÐ(i) In general. Kerosene means, after June 30, 1998Ð Except as provided in paragraph (1) The two grades of kerosene (No. 1± (c)(3)(ii) of this section, gasoline K and No. 2±K) described in ASTM blendstocks meansÐ Specification D 3699; and (A) Alkylate; (2) Kerosene-type jet fuel described in (B) Butane; ASTM Specification D 1655 and mili- tary specifications MIL±T±5624R and (C) Butene; MIL±T±83133D (Grades JP±5 and JP±8). (D) Catalytically cracked gasoline; For availability of ASTM and military (E) Coker gasoline; specification material, see § 48.4081± (F) Ethyl tertiary butyl ether 1(c)(2)(i). (ETBE); (G) Hexane; [T.D. 8774, 63 FR 35801, July 1, 1998] (H) Hydrocrackate; § 48.4081±2 Taxable fuel; tax on re- (I) Isomerate; moval at a terminal rack. (J) Methyl tertiary butyl ether (a) Overview. This section provides (MTBE); the general rule that all removals of (K) Mixed xylene (not including any taxable fuel at a terminal rack are sub- separated isomer of xylene); ject to tax and the position holder with (L) Natural gasoline; respect to the fuel is liable for the tax.
    [Show full text]
  • Fluid Handling
    FLUID HANDLING Pumps Fluid Siphon Pump Battery-Operated Polypropylene Multi-Use Fluid Transfer Pump SKU 568475 99 Liquid Transfer Pump Lever-Action Pump SKU 094647 99 24863 14 SKU 471071 99 SKU 688036 99 25713 9 • Transfers Fluids Easily 25712 14 24471 29 • Small and Lightweight • Use to Transfer Gas, Water, Oil and Other Non-Corrosive • Move Liquids Safely and Easily with • Ideal for Diesel, Kerosene, Liquids • Intake and Discharge This Convenient Handheld Pump Lubricants and Other Oils Transfer System • Hose Reaches 6 Ft. • Pumps Gas, Water, Oil and Other • Not for Gasoline, Water-Based with 1/2" Diameter • Pumps Air into Inflatables Non-Corrosive Liquids Chemicals or DEF • Includes: (2) 50" • Pumps Up to 6 Quarts of (127 cm) Long Hoses Liquid per Minute Polypropylene Hand Oil Pump Ryton® Rotary Polypropylene Lever-Action Pump with Lever-Action Pump Barrel Pump Rotary Drum Pump SKU 462495 99 DEF Stainless Steel Rod 24381 27 with Stainless COMPATIBLE SKU 462486 99 SKU 688035 99 SKU 688038 • Oil Pump for Use with Steel Rod 24382 29 24470 79 99 Oil-Based Fluids, Heating 24472 29 SKU 688037 • Fluid Transfer • Ideal for Pumping Diesel, Oils, Motor Oils, Heavy 99 Pump for Use with Oils, Kerosene, Water-Based • Ideal for Pumping and Light Oils, Diesel 24473 39 Diesel, Oils, Kerosene, Oil-Based Fluids, Chemicals, Bases and and Kerosene • Ideal for Pumping Heating Oils, Mild Acids Water-Based Chemicals, • Built-in 1-1/2" and 2" Bung Diesel, Oils, Kerosene, Bases and Mild Acids Motor Oils, ATF, • Not for Gasoline or DEF for Use on 16 to 55 Gallon Water-Based Chemicals, Diesel and • Not for Gasoline or DEF Drums with Either Opening Bases and Acids Including DEF Kerosene • Not for Gasoline • Not for Gasoline • Not for Gasoline Lever-Action Manual Gear Lube Manual Rotary Pump with Hose for 55 Gallon Drums* BONUS Barrel Pump Dispenser SKU 265089 99 5 Qt.
    [Show full text]
  • General Tax Information Bulletin #300 Page 2
    INFORMATION BULLETIN #300 GENERAL TAX JUNE 2021 (Replaces Bulletin #300 dated June 2020) Effective Date: July 1, 2021 SUBJECT: Sales of Compressed Natural Gas (CNG) and Liquefied Natural Gas (LNG) REFERENCES: IC 6-2.5-5-51; IC 6-6-2.5-1; IC 6-6-2.5-16.5; IC 6-6-2.5-22; IC 6-6-2.5- 22.5; IC 6-6-2.5-28; IC 6-6-4.1-1; IC 6-6-4.1-4; IC 6-6-4.1-4.5. DISCLAIMER: Commissioner’s directives are intended to provide nontechnical assistance to the general public. Every attempt is made to provide information that is consistent with the appropriate statutes, rules, and court decisions. Any information that is not consistent with the law, regulations, or court decisions is not binding on either the department or the taxpayer. Therefore, the information provided herein should serve only as a foundation for further investigation and study of the current law and procedures related to the subject matter covered herein. SUMMARY OF CHANGES The bulletin was updated to provide the new special fuel tax rate effective July 1, 2021. I. DEFINITIONS “Natural gas” means compressed or liquid natural gas. “Natural gas product” means: (1) A liquid natural gas (LNG) or compressed natural gas (CNG) product; or (2) A combination of liquefied petroleum gas and a compressed natural gas product; used in an internal combustion engine or a motor to propel any form of vehicle, machine, or mechanical contrivance. “Alternative fuel” means a liquefied petroleum gas, not including a biodiesel fuel or biodiesel blend, used in an internal combustion engine or a motor to propel any form of vehicle, machine, or mechanical contrivance.
    [Show full text]
  • Waste Motor Oil (WMO) to Diesel Fuel Project Blaine M
    Southern Illinois University Carbondale OpenSIUC Presentations Department of Automotive Technology 3-7-2019 Waste Motor Oil (WMO) to Diesel Fuel Project Blaine M. Heisner Southern Illinois University Carbondale, [email protected] Follow this and additional works at: https://opensiuc.lib.siu.edu/auto_pres PowerPoint slides from a technical presentation at the Illinois College Automotive Instructors Association Spring 2019 conference. Recommended Citation Heisner, Blaine M. "Waste Motor Oil (WMO) to Diesel Fuel Project." (Mar 2019). This Article is brought to you for free and open access by the Department of Automotive Technology at OpenSIUC. It has been accepted for inclusion in Presentations by an authorized administrator of OpenSIUC. For more information, please contact [email protected]. Waste Motor Oil (WMO) to Diesel Fuel Project -Update Spring 2019- SIUC Automotive Technology Department Blaine Heisner AJ McNay Jake Lichter Colton Karas Ryan Mukherjee WMO? (Waste Motor Oil!) • What is in WMO? • Total amount of WMO generated • Petroleum mainly… • 1.3B gallons annually in U.S. • Crankcase oil, transmission fluid, • Only 60% of oil sold is collected power steering fluid, brake fluid, axle grease, gear oil, compressor oil • However… • What happens to WMO • Dumped • Metal, dirt, leaves, additives, coolant, brake clean, solvent, dead • Burned in open fires (brush piles) animals, fuel, chew spit, water, • Collected with a fee (or payment) benzene, etc… • Dropped off at a collection area • Industrial burners (energy gen.) • WMO Generators • Re-refined into new products • Repair shops, dealerships, public and • Lube, fuel, asphalt, etc… private fleets, personal residences, schools, trucking companies, farms Cost/Value of WMO • “The recent softness in crude oil markets, along with the associated declines in fuel pricing, have decreased the value of our recycled fuel oil (RFO) and other products.
    [Show full text]
  • What's the Difference Between Gasoline, Kerosene, Diesel, Etc?
    What's the difference between gasoline, kerosene, diesel, etc? Browse the article What's the difference between gasoline, kerosene, diesel, etc? The "crude oil" pumped out of the ground is a black liquid called petroleum. This liquid contains aliphatic hydrocarbons, or hydrocarbons composed of nothing but hydrogen and carbon. The carbon atoms link together in chains of different lengths. It turns out that hydrocarbon molecules of different lengths have different properties and behaviors. For example, a chain with just one carbon atom in it (CH4) is the lightest chain, known as methane. Methane is a gas so light that it floats like helium. As the chains get longer, they get heavier. The first four chains -- CH4 (methane), C2H6 (ethane), C3H8 (propane) and C4H10 (butane) -- are all gases, and they boil at -161, -88, -46 and -1 degrees F, respectively (-107, -67, -43 and -18 degrees C). The chains up through C18H32 or so are all liquids at room temperature, and the chains above C19 are all solids at room temperature. So what's the real chemical difference between gasoline, kerosene and diesel? It has to do with their boiling points. Carbon Chains in Petroleum Products The different chain lengths have progressively higher boiling points, so they can be separated out by distillation. This is what happens in an oil refinery -- crude oil is heated and the different chains are pulled out by their vaporization temperatures. (See How Oil Refining Works for details.) The chains in the C5, C6 and C7 range are all very light, easily vaporized, clear liquids called naphthas.
    [Show full text]
  • Acetic Anhydride
    ACETIC ANHYDRIDE Method number: 102 Matrix: Air Target concentration: 5 ppm (20 mg/m3) OSHA PEL: 5 ppm (20 mg/m3) TWA ACGIH TLV: 5 ppm (20 mg/m3) ceiling Procedure: Samples are collected open face on glass fiber filters coated with veratrylamine and di-n-octyl phthalate. Samples are extracted with 50/50 (v/v) 2-propanol/toluene and analyzed by GC using a nitrogen- phosphorus detector (NPD). Recommended air volume and sampling rate: 7.5 L at 0.5 L/min ceiling 7.5 L at 0.05 L/min TWA Reliable quantitation limit: 0.094 ppm (0.39 mg/m3) Standard error of estimate at the target concentration: 6.4% Special caution: Ketene and acetyl chloride produce the same derivative as acetic anhydride. Coated filters should be used within a month of preparation. Status of method: Evaluated method. This method has been subjected to the established evaluation procedures of the Organic Methods Evaluation Branch. Date: October 1993 Chemist: Yihlin Chan Organic Methods Evaluation Branch OSHA Salt Lake Technical Center Salt Lake City, UT 84165-0200 1. General Discussion 1.1 Background 1.1.1 History In OSHA Method 82, acetic anhydride is collected on a glass fiber filter impregnated with 1-(2-pyridyl)piperazine, which reacts with the anhydride to form a derivative (Ref. 5.1). Attempts at using 1-(2-pyridyl)piperazine for the derivatization of maleic, phthalic, and trimellitic anhydrides failed, however, because the resulting derivatives of these anhydrides were found to be unstable. These anhydrides were derivatized with veratrylamine instead (Refs. 5.2-5.4).
    [Show full text]
  • Title the Reaction of Methyl Chloride with Carbon Monoxide Author(S
    Title The reaction of methyl chloride with carbon monoxide Author(s) Osugi, Jiro; Mizukami, Tetuo Citation The Review of Physical Chemistry of Japan (1964), 34(1): 7-18 Issue Date 1964-11-05 URL http://hdl.handle.net/2433/46843 Right Type Departmental Bulletin Paper Textversion publisher Kyoto University The Review of Physical Chemistry of Japan Vol. 34 No. 1 (1964) TftE REVIEW OF PHYSICAL CHE'HISTRY OF IAPA~, VDL. 34, No. 1, 1964 THE REACTION OF METHYL CHLORIDE WITH CARBON MONOXIDE BY ]IRD ~stlf,l ANDTETUO IVIIEUI:A]II* The reaction of methyl chloride witb carbon monoxide in the presence of pumice•anhydrous sodium borate catalyst yields mainly hydrogen chloride, methane, acetyl chloride and phosgene, and deposits carbon. Moreover, hydro• gen, methylene chloride, ethyl chloride and ethylene dichloride are obtained in a trace. From [he stand point of chemical kinetics the reaction is studied. From the initial rates of the products, the values of 13.1, I8.5, 23.2 and 27.Okcal/mole are obtained as the apparent activation energies {or the formation of acetyl chloride, phosgene, hydrogen chloride and methane respectively. Furthermore, the rates of formation of acetyl chloride and pbosgene are discussed. From the apparent rate constants, the apparent activation energies are obtained. The values are 19.0 kcal/male for acetyl chloride and 17.6 kcal/mole for phosgene. The reaction mechanism is discussed. Introduction Since a few years ago, carhop monoxide has been considered as one of the important materials for organic chemical industry, so there are some utilizations, such as s}•nthetic petroleum, Reppe's carhoxy- Iation reaction and oxo reaction etc.
    [Show full text]
  • Prohibited and Restricted Chemical List
    School Emergency Response Plan and Management Guide Prohibited and Restricted Chemical List PROHIBITED AND RESTRICTED CHEMICAL LIST Introduction After incidents of laboratory chemical contamination at several schools, DCPS, The American Association for the Advancement of Science (AAAS) and DC Fire and Emergency Management Services developed an aggressive program for chemical control to eliminate student and staff exposure to potential hazardous chemicals. Based upon this program, all principals are required to conduct a complete yearly inventory of all chemicals located at each school building to identify for the removal and disposal of any prohibited/banned chemicals. Prohibited chemicals are those that pose an inherent, immediate, and potentially life- threatening risk, injury, or impairment due to toxicity or other chemical properties to students, staff, or other occupants of the school. These chemicals are prohibited from use and/or storage at the school, and the school is prohibited from purchasing or accepting donations of such chemicals. Restricted chemicals are chemicals that are restricted by use and/or quantities. If restricted chemicals are present at the school, each storage location must be addressed in the school's written emergency plan. Also, plan maps must clearly denote the storage locations of these chemicals. Restricted chemicals—demonstration use only are a subclass in the Restricted chemicals list that are limited to instructor demonstration. Students may not participate in handling or preparation of restricted chemicals as part of a demonstration. If Restricted chemicals—demonstration use only are present at the school, each storage location must be addressed in the school's written emergency plan. Section 7: Appendices – October 2009 37 School Emergency Response Plan and Management Guide Prohibited and Restricted Chemical List Following is a table of chemicals that are Prohibited—banned, Restricted—academic curriculum use, and Restricted—demonstration use only.
    [Show full text]
  • Process for Preparing a Stabilized Chromium \III\ Propionate Solution
    Europaisches Patentamt European Patent Office © Publication number: 0 194 596 Office europeen des brevets A2 © EUROPEAN PATENT APPLICATION C 07 C 53/122 © Application number: 86103020.3 ©intci.": C 07 C 51/41, C 08 L 5/00 © Date of filing: 07.03.86 C 08 L 33/26, E 21 B 47/00 © Priority: 11.03.85 US 710754 © Applicant: PHILLIPS PETROLEUM COMPANY 5th and Keeler Bartlesville Oklahoma 74004(US) © Date of publication of application: 17.09.86 Bulletin 86/38 © Inventor: Mumallah, Nairn Abdul-Kader 4519 E. Tuxedo Blvd © Designated Contracting States: Bartlesville, OK 74006IUS) AT DE FR GB IT NL SE © Inventor: Shtoyama.TodKay 5620 East Circle Bartlesville, OK 74006(US) © Representative: Dost, Wolfgang, Dr.rer.nat, Dipl.-Chem. et al. Patent- und Rechtsanwalte Bardehle-Pagenberg-Dost-Altenburg & Partner Postfach 86 0620 D-8000 Munchen 86IDE) © Process for preparing a stabilized chromium (III) propionate solution and formation treatment with a so prepared solution. © A A sulfate-free clear green solution of chromium (III) propionate is prepared by mixing aqueous propionic acid containing up to 55 weight percent propionic acid with a chromium (Vf) oxidant, such as a dichromate or chromate, and a sulfur-containing reductant, such as a bisulfite, which on reacting yields two phases: a lower sulfate-containing phase for discard or recycle and an upper phase solution of sulfate-free clear green propionate-sequestered chromium (III), the latter phase being stabilized with additional acid. The upper phase solution is useful for crosslinking polymeric viscosifiers such as partially hydrolyzed acrylamide-based polymers and the like in permeability contrast corrections in enhanced oil recovery operations.
    [Show full text]
  • Ketene Reactions. I. the Addition of Acid Chlorides
    KETENE REACTIONS. I. THE ADDITION OF ACID CHLORIDES TO DIMETHYLKETENE. II. THE CYCLOADDITION OF KETENES TO CARBONYL COMPOUNDS APPROVED: Graduate Committee: Major Professor Committee Member.rr^- Committee Member Committee Member Director of the Department of Chemistry Dean' of the Graduate School Smith, Larry, Ketene Reactions. I. The Addition of Acid Chlorides to DimethyIketene. II. The Cycloaddition of Ketenes to Carbonvl Compounds. Doctor of Philosophy (Chemistry), December, 1970, 63 pp., 3 tables, bibliography, 62 titles. Part I describes the addition of several acid chlorides to dimethylketene. The resulting 3-ketoacid chlorides were isolated and characterized. The reactivities of acid chlorides were found to parallel the parent acid pKa's. A reactivity order of ketenes toward acid chlorides was established. Dimethylketene is more reactive than ketene which is more reactive than diphenylketene. Attempts to effect the addition of an acid halide to a ketene produced by in situ dehydro- halogenation yielded a-halovinyl esters. The addition of acid chlorides to ketenes was concluded to be an ionic process dependent upon the nucleophilic character of the ketene oc- carbon and the polarity of the carbon-chlorine bond in the acid chloride. Part II describes the cycloaddition of several aldo- ketenes to chloral. The ketenes were generated in situ by dehydrohalogenation and dehalogenation of appropriately substituted acyl halides. Both cis- and trans-4-trichloro- Miyl-2-oxetanones are produced in the cycloadditions with the sterically hindered cis isomer predominating. Isomer distributions were determined by vpc or nmr analysis of the reaction solutions. Production of the ketenes by dehalo- genation resulted in enhanced reactivity of the carbonyl compounds.
    [Show full text]
  • Study on Gas-Phase Mechanism of Chloroacetic Acid Synthesis by Catalysis and Chlorination of Acetic Acid
    Asian Journal of Chemistry; Vol. 26, No. 2 (2014), 475-480 http://dx.doi.org/10.14233/ajchem.2014.15484 Study on Gas-Phase Mechanism of Chloroacetic Acid Synthesis by Catalysis and Chlorination of Acetic Acid * JIAN-WEI XUE , JIAN-PENG ZHANG, BO WU, FU-XIANG LI and ZHI-PING LV Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, P.R. China *Corresponding author: Fax: +86 351 6111178; Tel: +86 351 60105503; E-mail: [email protected] Received: 14 March 2013; Accepted: 17 May 2013; Published online: 15 January 2014; AJC-14570 The process of acetic acid catalysis and chlorination for synthesizing chloroacetic acid can exist in not only gas phase but also liquid phase. In this paper, the gas-phase reaction mechanism of the synthesis of chloroacetic acid was studied. Due to the high concentration of acetic acid and the better reaction mass transfer in the liquid-phase reaction, the generation amount of the dichloroacetic acid was higher than that in the gas-phase reaction. Under the solution distillation, the concentration of acetyl chloride, whose boiling point is very low, was very high in the gas phase, sometimes even up to 99 %, which would cause the acetyl chloride to escape rapidly with the hydrogen chloride exhaust, so that the reaction slowed down. Therefore, series reactions occured easily in the gas-phase reaction causing the amount of the dichloroacetic acid to increase. Keywords: Gas phase, Catalysis, Chlorination, Chloroacetic acid, Acetic acid. INTRODUCTION Martikainen et al.3 summed up the reaction mechanism that was consistent with a mechanism found by Sioli according Chloroacetic acid is not only a fine chemical product but to the system condition experiment and systematic theoretical also an important intermediate in organic synthesis.
    [Show full text]