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Petrographic Analyses of Late Pennsylvanian Limestones

Petrographic Analyses of Late Pennsylvanian Limestones

PETROGRAPHIC ANALYSES OF LATE

WITHIN THE NORTHERN APPALACHIAN BASIN, USA

A thesis presented to

the faculty of

the College of Arts and Sciences of University

In partial fulfillment

of the requirements for the degree

Master of Science

Christopher F. Cassle

June 2005

This thesis entitled

PETROGRAPHIC ANALYSES OF LATE PENNSYLVANIAN LIMESTONES

WITHIN THE NORTHERN APPALACHIAN BASIN, USA

BY

CHRISTOPHER F. CASSLE

has been approved for

the Department of Geological Sciences

and the College of Arts and Sciences by

Elizabeth H. Gierlowski-Kordesch

Associate Professor of Geological Sciences

Leslie A. Flemming

Dean, College of Arts and Sciences

Cassle, Christopher F. M.S. June 2004. Geological Sciences

Petrographic Analyses of Late Pennsylvanian Limestones within the Northern

Appalachian Basin, USA (245p.)

Director of Thesis: Elizabeth H. Gierlowski-Kordesch

Marine influence in the Pennsylvanian- rocks of the northern

Appalachian basin supposedly ended during the deposition of the mid- of the lower Upper Pennsylvanian (Missourian). However, evidence for marine influence extends up to the Permian Dunkard Group. It is difficult, however, to delineate the exact positions of land vs. ocean within cyclothemic sequences at outcrop scale. The cyclothemic rocks in this basin are interpreted as sediments from upper to lower deltaic plains, estuaries, and nearshore marine situated along an extensive lowland coast. The transition between marine and freshwater environments is blurred because of long-term sea level changes as well as short-term marine incursions of a daily, seasonal, or catastrophic nature along a coastal setting. To define freshwater, brackish, and marine paleoenvironments more precisely in an attempt to understand the coastal transition zone of Pennsylvanian age cyclothems, samples from 52 localities in Ohio,

Kentucky, , and within the Conemaugh Group, as well as the overlying Monongahela Group, were collected for sedimentologic and paleontologic analyses. The brackish or marine influence in the cyclothems can be defined by the presence of the marine worm tube Spirorbis, which is restricted to cm-scale units within freshwater limestones. Their presence indicate episodic marine incursions on a time scale less then that of a cyclothemic cycle. A coastal zone similar to that of the tidally influenced coast at the mouths of the Amazon River in northern Brazil is envisioned where marine incursions occur on all time scales. Work needs to be done on the distribution of fossils within the associated siliciclastics in the cyclothems to better refine the pattern of marine influence throughout the Pennsylvanian to Permian in the northern

Appalachian basin.

Approved: Elizabeth H. Gierlowski-Kordesch

Associate Professor of Geological Sciences

This thesis is dedicated in loving memory to my stepfather Paul B. Pack, whose character and wisdom set the standard by which I strive to live my life.

Acknowledgments

I greatly appreciate the assistance and guidance of Beth Gierlowski-Kordesch,

Dave Schneider, Greg Nadon, and the rest of the geology department. Daphne Metts and

Vicky Tong also deserve my gratitude, without them this thesis would not have been

possible. Many thanks to Ron Martino of Marshall University, as well as Vik Skema and

John Harper of the Pennsylvania Geological Survey for assisting with locating sample

localities, Lisa Park of the University of Akron for ostracode analysis, and Jake Glascock

and Kevin Kallini for providing thin sections. I would also like to extend thanks to Zak

Wessel for his assistance with field reconnaissance, sample collection, and unconditional friendship. 7

Table of Contents

Page Abstract...... 3

Dedication...... 5

Acknowledgments...... 6

List of Figures...... 9

List of Tables ...... 10

Chapter 1: Introduction ...... 11

Chapter 2: Geologic Background...... 13 2.1 Introduction...... 13 2.2 Pennsylvanian Cyclothems...... 19 2.3 General Stratigraphy and Depositional Environments...... 20 2.4 Lacustrine Limestones...... 22 2.5 Overview of Tropical vs. Temperate Lakes...... 24 2.6 Brackish Water Environment...... 31 2.7 Spirorbis ...... 34

Chapter 3:Methodology...... 38

Chapter 4: Facies Descriptions and Interpretations ...... 42 4.1 Introduction...... 42 4.2 Type 1: Micrite...... 44 4.3 Type 2: Ostracodal Wackestone to Packstone...... 47 4.4 Type 3: Intraclastic Microbreccia ...... 50 4.5 Type 4: Mottled Micrite and Microbreccia...... 53 4.6 Type 5: Spirorbis-bearing Biomicrite ...... 56 4.7 Type 6: Matrix-supported Siliciclastic Microbreccia...... 62 4.8 Type 7: Wackestone ...... 65 4.9 Type 8: Packstone ...... 68

Chapter 5: Ostracode Analysis ...... 71 8

Chapter 6: Depositional Environment Discussion...... 73 6.1 Marine Environment...... 73 6.2 Freshwater Environment...... 73 6.3 Brackish Environment...... 75 6.4 Modern Analog Environment ...... 77 6.5 Pennsylvanian/Permian Environment ...... 78

Chapter 7: Conclusions ...... 82

References ...... 84

Appendix A: Sample Localities...... 109

Appendix B: Photomicrographs of the 174 Studied Samples ...... 146

Appendix C: Facies Types and Characteristics of the 174 Studied Samples...... 233 9

List of Figures

Page 1. Late Pennsylvanian Paleogeography of North America ...... 14 2. Structural Architecture of the Northern Appalachian Basin...... 15 3. Outcrop Pattern of the Conemaugh Group and Monongahela Group...... 17 4. Generalized Stratigraphic Column of the Northern Appalachian Basin ...... 18 5. Photograph of Modern Spirorbis Worm Tubes ...... 35 6. Localities of Sampled Limestone Units ...... 41 7. Photomicrograph of Sample JG-1-24...... 44 8. Photomicrograph of Sample K-49B...... 45 9. Photomicrograph of Sample PA-5-B ...... 45 10. Photomicrograph of Sample R-32c-FP-23 ...... 46 11. Photomicrograph of Sample JG-1-26...... 47 12. Photomicrograph of Sample PA-6D-A ...... 48 13. Photomicrograph of Sample WV50-2T...... 48 14. Photomicrograph of Sample WV79-6B ...... 49 15. Photomicrograph of Sample WV79-6C ...... 50 16. Photomicrograph of Sample WV79-2M...... 51 17. Photomicrograph of Sample WV50-1D ...... 51 18. Photomicrograph of Sample JG-2-43C ...... 52 19. Photomicrograph of Sample PA-12-2 ...... 53 20. Photomicrograph of Sample WV50-1A ...... 54 21. Photomicrograph of Sample WV79-4-OOP...... 54 22. Photomicrograph of Sample WV50-3A ...... 55 23. Magnified Hand Sample Image of Sample K-49A...... 57 24. Magnified Hand Sample Image of Sample K-49A...... 57 25. Sample Locality PA-11 ...... 58 26. Photomicrograph of Sample K-44D...... 59 27. Photomicrograph of Sample L3A-2 ...... 59 28. Photomicrograph of Sample PA-11-3 ...... 60 29. Photomicrograph of Sample PA-12-4A ...... 60 30. Photomicrograph of Sample KY-21B-1...... 62 31. Photomicrograph of Sample KY-3A...... 63 32. Photomicrograph of Sample JG-1-8...... 63 33. Photomicrograph of Sample JG-1-10...... 64 34. Photomicrograph of Sample KY-31L ...... 65 35. Photomicrograph of Sample PA-21-1 ...... 66 36. Photomicrograph of Sample WV79-1...... 66 37. Photomicrograph of Sample PA-16-1 ...... 67 38. Photomicrograph of Sample KY-30...... 68 39. Photomicrograph of Sample PA-36 ...... 69 40. Photomicrograph of Sample KY-26...... 69 41. Photomicrograph of Sample KY-21A...... 70 10

List of Tables

Page 1. Identification Criteria and Interpretations for the Eight Lithofacies Types...... 43 2. Ostracode Identification ...... 72 11

Chapter 1: Introduction

The northern Appalachian basin contains a sequence of Pennsylvanian-Permian

rocks deposited in the distal reaches of a during the Alleghanian

(Hatcher, 1989; Belt and Lyons, 1989; Eriksson et al., 2004). Sea level fluctuations from

tectonic and glacial/climatic perturbations (e.g. Klein, 1994; Crowell, 1999; Heckel,

2002) resulted in the deposition of an array of sediments, generally called cyclothems

(Wanless and Weller, 1932; Sturgeon et al., 1958; Ferm, 1975). During this deposition,

an overall increase in sea level occurred in the Early to Middle Pennsylvanian with a

decrease in the Late Pennsylvanian to Permian (Ross and Ross, 1987), allegedly causing

nonmarine conditions to prevail in the northern Appalachian Basin from the mid-

Missourian time (post Ames limestone deposition, mid Conemaugh Group until the

Permian Dunkard Group) with lacustrine limestones also occurring in the lower portion

of the Conemaugh Group as well as in the Allegheny group below (Donaldson, 1979;

Donaldson et al., 1985; Weedman, 1988; 1994). Exclusively nonmarine conditions are

interpreted for the sequence from the Skelley Limestone (above the Ames) in the

Conemaugh Group through the Monongahela and Dunkard Groups (Eager, 1975;

Edmunds et al., 1999). However, Lingula shells have been identified in the

Elm Grove limestone and associated Washington coal zone (see Martin, 1998), which are in the upper portion of the Dunkard Group. The alleged nonmarine paleoconditions for the deposition of the Pennsylvanian to Permian cyclothems in the northern Appalachian basin (Dunkard Synclinorium) need to be re-evaluated. 12

To do this, sedimentologic differentiation between freshwater and marine in this

low coastal setting (Ferm, 1970; 1974; Donaldson, 1979; Donaldson et al., 1985) needs to

be directly applied at the outcrop scale. Geochemical and paleontologic work has been done on the Upper Freeport cyclothem (Allegheny Group, Valero-Garcés et al., 1994;

1997; Eagar and Belt, 2003) to substantiate a freshwater origin for its carbonates and siliciclastics. However, the recognition of possible tidal bundles in freshwater Upper

Freeport shales (Belt et al., 2002), as well as the identification of a brackish marine worm tube (Spirorbis) in the lacustrine limestones of the Allegheny through Dunkard Groups

(Eagar, 1975; Yochelson, 1975; Eggleston, 1994; Weedman, 1994; Petzold, 1989; 1990;

Martin, 1998), contribute uncertainty as to the exact nature of the coastal transition zone between freshwater and marine areas. The goal of this research is to enhance definition of the coastal transition zone during the Pennsylvanian by identifying the differences among brackish, freshwater, and marine paleoconditions within the limestones of the

Conemaugh and Monongahela Group cyclothems in the northern Appalachian basin.

13

Chapter 2: Geologic Background

2.1 Introduction

Mid- to Late Paleozoic Appalachian orogenic events resulted in the formation of the Appalachian foreland basin (Secor et al., 1986; Hatcher, 1989; Snoke and Mosher,

1989). During the Late Pennsylvanian, the northern part of this basin was located within

the equatorial zone approximately 10°S latitude, bounded to the southeast by the

Allegheny Range of the Central Pangean Mountains, opening toward an epeiric sea to the

west (Figure 1; Donaldson et al., 1985). The northern Appalachian basin can be divided

into two distinct depositional zones (Figure 2). To the east is the Pocahontas basin,

representing the most proximal trough of the foreland basin (Donaldson et al., 1985). In

the western portion of the basin resides the Dunkard synclinorium, representing a more

cratonic portion of the basin. Sediment fill within the Pocahontas basin and Dunkard

synclinorium is composed of cyclothems containing alternating siliciclastics, carbonates,

and coal. The cyclothems are interpreted as marine to nonmarine environments affected

by glacial eustatic, tectonic, and hydrologic conditions (e.g. Klein and Willard, 1989;

Cecil, 1990; Heckel, 1995; 2002). 14

Figure 1. Late Pennsylvanian paleogeography of North America. Yellow ellipse represents location of study area; modern day geopolitical boundaries are superimposed in approximate locations during the Late Pennsylvanian (with permission, Blakey, 2004).

15

Ohio River

Ohio West Virginia

Thrust Fault

NW SE

Dunkard Synclinorium

Pocahontas Basin Dunkard Group

Monongahela Group 0 100 miles Conemaugh Group 0 100 kilometers Allegheny Group/Charleston Formation

Pottsville Group/ 00

New River Formation/ 300meters 1000 feet

Figure 2. Structural architecture of the Northern Appalachian Basin (adapted from Nadon et al., 1998)

16

The most distal portions of the Appalachian basin may have had a topographic gradient sufficiently low enough to produce an extensive alluvial-deltaic complex;

continually affected by sea level fluctuations resulting in the accumulation of the

Pennsylvanian cyclothemic sediments (Ferm, 1978; Donaldson et al., 1985).

Differentiation of marine versus nonmarine cyclothems in the northern Appalachian basin

is defined by the last significant marine transgression as represented by the Ames

Limestone in the Conemaugh Group, however marine units do exist above this horizon

(Petzold, 1990; Heckel, 1995).

Limestone units targeted for this study in the Conemaugh and Monongahela

Groups of the northern Appalachian basin outcrop in an elliptical pattern displaying the

basin architecture (Figure 3). All limestones stratigraphically above the Ames Limestone

have been interpreted exclusively as nonmarine in origin (Figure 4; Nadon et al., 1998)

though lacustrine limestones are present in some cyclothems lower in the section, within

the Allegheny Group (Weedman, 1994). Initially, limestones of continental cyclothems

were interpreted as being deposited in dry climates (Cecil, 1990). A more recent

interpretation juxtaposes lithologies of the cyclothems into many different

subenvironments within an anastomosed fluvial system, including lakes, swamps, bogs,

elongate lake deltas, and alluvial plains (paleosols), within a tropical seasonal climate

(Valero Garcés et al., 1994; 1997). 17

83° 82° 81° 80° 79°

Monongahela Group 42° Conemaugh Group 42°

PA

41° 41° OH

40° 40°

39° 39°

WV 0 10 20 30 40 miles 38° N 0 10 20 30 40 50 kilometers 38°

82° 81° 80° 79°

Figure 3. Outcrop pattern of the Conemaugh and Monongahela Groups (adapted from Carothers and Rollins, 1979). 18

Waynesburg Coal Gilboy SS Little Waynesburg Coal Waynesburg LS Uniontown SS Uniontown Shale Uniontown Coal Uniontown LS Arnoldsburg SS Fulton Green Shale Benwood Coal Benwood/Arnoldsburg LS Sewickley SS Sewickley Coal Lower Sewickley SS Fishpot Coal Fishpot LS Redstone Coal Redstone LS Pittsburgh SS Pittsburgh Coal Lower Pittsburgh SS Upper Pittsburgh LS Little Pittsburgh Coal Lower Pittsburgh LS Connellsville SS Little Clarksburg Coal Clarksburg LS Clarksburg Shale Morgantown SS Elk Lick Coal Elk Lick LS Upper Grafton SS Birmingham Shale Skelley LS (M) Duquesne Coal Lower Grafton SS Ames LS (M) Harlem Coal Pittsburgh Shale Saltsburg SS Upper Bakerstown Coal Ewing LS Portersville Shale (Woods Run LS-PA) (M) Lower Bakerstown Coal Cambridge (Nadine-PA) LS (M) Buffalo SS Two Mile LS (WV) (M) Upper Brush Creek (Pine Creek-PA) LS (M) Lower Brush Creek LS (M) Brush Creek Shale Brush Creek Coal Mahoning Coal Mahoning SS Figure 4. Generalized stratigraphic column of the Northern Appalachian Basin, (M) denotes marine interpretation (adapted from Condit, 1912; Lamborn, 1951; Sturgeon et al., 1958; Fedorko, 1979; Kovach, 1979; Rice et al., 1979; Rice, 1981; Busch and Rollins, 1984; Edmunds et al., 1999). 19

2.2 Pennsylvanian Cyclothems

Cyclothems are lithostratigraphic units consisting of a repetitive vertical succession of beds deposited in a single sedimentary cycle (Wanless and Weller, 1932).

A cyclothem based on units from western Illinois by Weller et al. (1942) consists of a sequence of ten units in the following ascending order: fine-grained micaceous residing unconformably atop underlying beds, sandy shale, freshwater limestone, underclay, coal, gray marine shale containing pyritic nodules, marine limestone, black laminated shale containing carbonate concretions or interbedded with thin carbonate layers, marine limestone, marine shale containing siderite concretions. Defined as the

‘ideal’ cyclothem, this suite represents the optimum succession during a complete sedimentary cycle in western Illinois; however, typical cyclothems rarely exhibit all ten facies.

‘Cyclothems’ occurring within separate basins are the result of varying degrees of sedimentation and subsidence rates (Heckel, 1984; 1994; Chesnut and Ettensohn,

1994), producing a variety of facies alternations. Controls on this cyclic sedimentation have been attributed to glacio-eustacy, tectonics, or a combination of the two (Wanless and Shepard, 1936; Weller, 1930; Heckel, 1983; 1986; 1995; Heckel et al., 1998). The most distal portions of the Appalachian basin had a topographic gradient sufficiently low enough to produce an extensive alluvial-deltaic complex. This region was continually affected by sea level fluctuations resulting in the deposition/formation of the

Pennsylvanian cyclothemic sediments (Ferm, 1978; Donaldson et al., 1985). 20

2.3 General Stratigraphy and Depositional Environments

The Pennsylvanian System of the northern Appalachian basin generally consists of a sequence of alternating siliciclastics, carbonates, and coal, which were deposited in a variety of shallow marine, lacustrine, and fluvial environments. These units lie unconformably atop strata within two distinct depositional zones. To the east is the Pocahontas basin (Figure 2), representing the most proximal foredeep trough of the foreland basin (Donaldson et al., 1985). In the western portion of the basin resides the Dunkard synclinorium (Figure 2), representing a more cratonic portion of the basin.

Sediment fill within the Pocahontas basin comprises the Pocahontas through Kanawha

Formations (Lower through Middle Pennsylvanian), while fill within the Dunkard synclinorium comprises Pottsville through Dunkard Groups (Middle Pennsylvanian through Lower Permian). The Late Pennsylvanian units are subdivided into the following ascending order: Pottsville Group, Allegheny Group, Conemaugh Group, and

Monongahela Group, with the Dunkard Group bridging the Pennsylvanian/Permian transition. The intervals of interest for this study reside within the Conemaugh and

Monongahela Groups (Figure 4).

The Conemaugh Group is defined stratigraphically as the units from the

Mahoning Sandstone (above Upper Freeport Coal) to the Lower Pittsburgh Sandstone

(below Pittsburgh coal) (Condit, 1912; Edmunds, 1999; Fedorko, 1979; Kovach, 1979;

Lamborn, 1951; Rice et al., 1979; Rice, 1981; Sturgeon et al., 1958). The Conemaugh was further subdivided into the Glenshaw and Casselman Formations by Flint (1965).

The Glenshaw is noted by the presence of numerous, laterally extensive marine units, 21

most notably the Ames limestone. The Casselman Formation only contains one marine

unit (Skelley limestone), which is not laterally extensive. The top of the Glenshaw is

marked as the last significant marine incursion by the Ames limestone, which is easily

identifiable across much of the northern to central Appalachian basin. All limestones

above the Skelley limestone within the Casselman Formation have been interpreted as

exclusively freshwater in origin (Condit, 1912; Miller, 1934; Lamborn, 1951, Donaldson,

1985; Edmunds et al., 1999).

The Monongahela Group is defined stratigraphically as the units from the

Pittsburgh Coal to the Uniontown Limestone (Figure 4, Condit, 1912; Lamborn, 1951;

Sturgeon et al., 1958; Fedorko, 1979; Kovach, 1979; Rice, 1981; Rice et al., 1979; Busch and Rollins, 1984; Edmunds et al., 1999). The Monongahela Group has been interpreted as purely freshwater, dominated by limestones, dolostones, mudstones, shales, siltstones, and few persistent coals. 22

2.4 Lacustrine Limestones

The nonmarine limestones of the Allegheny through Dunkard Groups are

interpreted generally as freshwater to brackish in origin. Characteristics indicative of a

nonmarine origin for these carbonates include bedded ostracode carapace debris, red-

yellow mottling, charophytes, and pedogenic structures. These carbonates have recently

been re-evaluated as palustrine/lacustrine deposits on an anastomosing river floodplain

(Valero Garcés et al., 1994; 1997; Nadon et al., 1998). Reinterpretation of nonmarine

carbonates based on stable isotope geochemistry as well as petrography suggests that the

paleoclimate was mostly humid rather than predominately arid as previously postulated

(Cecil, 1990). Nonmarine carbonates can be deposited in any climate (Gierlowski-

Kordesch, 1998) and their textures reflect the extent of exposure (Platt and Wright,

1992).

The proximity of these carbonate lakes (whether brackish or freshwater) to the ocean is unclear. Weedman (1988, 1994) interpreted the Upper Freeport Limestone

(Allegheny Group) in western Pennsylvania as deposits of upper delta floodplain lakes.

However, she found Spirorbis worm tubes in the clastic to disturbed facies of these carbonate lakes. More recently, Belt and Lyons (1989) and Eager and Belt (2003) substantiated a freshwater interpretation for the roof shales of the Upper Freeport Coal in western , calling on a thrust model to shelter peat deposition. Petzold (1989,

1990) analyzed the facies of the Benwood Limestone (Monongahela Group) finding well- laminated carbonates as well as grainstones and wackestones, interpreting the limestones as lacustrine in origin. Spirorbis worm tubes were common to abundant in the Benwood 23

Limestone, mostly in grain-dominated limestones and calcareous shale and siltstone.

Eggleston (1992; 1994) described the Redstone limestone (Monongahela Group) as deposits of large shallow lakes and identified nonmarine fossils included bivalves, gastropods, and ostracodes; however, one photo of a questionable Spirorbis tube replaced by pyrite was documented. 24

2.5 Overview of Tropical vs. Temperate Lakes

Late Pennsylvanian lacustrine carbonates of the northern Appalachian Basin were deposited within an equatorial tropical environment. To accurately assess these units, it is necessary to understand the limnologic variation between shallow tropical lakes and more commonly understood temperate-based lakes. Differences between these two types of lakes can be characterized by their latitudinal separation; processes within these lakes consist of a complex interaction among the physical, chemical, and biologic activities.

This section will define common limnologic processes and terminology while illustrating the characteristics of lakes residing in temperate and tropical climates and focusing upon their primary differences. The shape, size and position of the basin directly affect the energy input and biologic processes, which in turn greatly affect the chemistry of a lake.

Chemical variations can also reflect regional bedrock-geology, structure, and hydrology.

However, these controls are not specific to a temperate or tropical climate.

Climate with respect to latitude is an important variable controlling both temperate and tropical lakes (Beadle, 1974; Kalff, 2002; Cohen, 2003). Global distribution of lakes with respect to latitude is skewed, with the temperate zones possessing the majority of lakes (Kalff, 2002). Fewer lakes exist in the tropics mainly due to the lack of glacially dominated terrains. Temperate zones are marked by an abundance of glacial lakes, which have been the focus of the majority of limnologic research to date. Shallow-tropical lake formation is primarily a result of fluvial, coastal and eolian processes, while deep-tropical lakes result from tectonic activity such as rifting (Herdendorf, 1990; Meybeck, 1995).

Climate variation is primarily controlled by solar irradiance variation between the 25 tropics and temperate zones. Irradiance contrasts are determined by the angle of incidence of sunlight to a lake’s surface, as well as regional variations in atmospheric density (attenuation coefficient). Regional variations in atmospheric density are governed by ephemeral phenomena in the atmosphere, such as clouds, dust, and fog (Horne and

Goldman, 1994). The time of highest irradiance contrast between temperate and tropical lakes is during hemispherical winter when the temperate zone experiences its greatest angle of incidence (minimal irradiance).

Solar radiation also contributes heat to drive Earth’s wind circulation, which transfers energy to a lake’s surface, initiating mixing. Heat produced by the transformation of light energy interacts with wind mixing to produce thermal stratification during hemispherical summer (Horne and Goldman, 1994). Lakes are often classified using thermal stratification characteristics, and are referred to as: amictic, monomictic, polymictic, or dimictic (Cole, 1994; Wetzel, 2001; Cohen, 2003).

Stratification types are highly latitude and altitude dependent. Amictic lakes are associated with high latitudes/elevations, and are permanently covered with ice preventing thermal stratification.

Monomictic lakes undergo a single mixing episode annually and are typically subdivided into cold monomictic and warm monomictic. Cold monomictic lakes are

Arctic or alpine lakes that experience ice cover and stratification during the majority of the year. During summer the ice cover melts and remains absent long enough for wind induced mixing to occur.

Warm-monomictic temperate lakes posses intermittent ice cover or lack thereof, 26 allowing stratification to occur during summer while remaining mixed during the remainder of the year. Warm-monomictic tropical lakes are a result of a cool season coincident with hemispheric winter. Temperature variation between the top and the bottom of the water column during this time is roughly 2°C, providing a density contrast sufficient to maintain seasonal stratification (Kalff, 2002; Wetzel, 2001).

Polymictic lakes undergo multiple mixing episodes annually, to the extent that they are mixed throughout the year and are typically subdivided into cold polymictic and warm polymictic. Cold polymictic lakes exist as shallow or highly wind influenced lakes.

These lakes undergo seasonal ice cover while remaining ice-free during hemispherical summer. During summer, shallower lakes will stratify daily with sufficient sunlight and turn over during heat loss at night. Deep lake stratification remains stable for days to weeks, requiring more energy to initiate mixing. Cold polymictic lakes occur from polar lowlands through upper temperate zones.

Warm polymictic lakes are typically shallow as well but lack ice-cover during hemispherical winter. Residing at high altitudes in tropical regions, these lakes are subject to frequent wind activity triggering daily to weekly turnover. Shallow lakes can also undergo nightly mixing initiated by surface cooling.

Dimictic lakes exhibit two annual mixing cycles per year corresponding with hemispherical spring and fall, as well as two periods of stratification corresponding with hemispherical summer and winter (Wetzel, 2001; Dodson, 2004). Full mixing occurs only in the brief periods between ice breakup and the onset of thermal stratification in spring and between the destruction of thermal stratification and subsequent formation of 27

ice cover in winter (Horne and Goldman, 1994). The presence of winter ice cover serves

two functions: first, it serves as a wind barrier preventing mixing, and second, it acts as

an insulator conserving some heat within the lake. The majority of temperate lakes act as

dimictic lakes.

Tropical lakes typically act as warm monomictic lakes; however, the shallower a

lake is, the more likely it is to act as a warm polymictic lake. These stratification models

assume that fluvial inputs do not significantly alter the thermal structure of the lake.

However, in some cases, a continuous source of cold river water may in fact stabilize

stratification, preventing seasonal mixing of the entire water column (Tundisi, 1994).

Despite the fact that tropical lakes are typically warm monomictic and stratify seasonally

given sufficient depth to prevent polymixis, they do posses significant variation from

temperate lakes with respect to the mixed layer during stratification. Stratification

stability in a temperate lake is much greater than that of a tropical lake, given similar

morphology (Talling, 2001). This characteristic is a result of periodic variability in the

heat content of lakes. During hemispherical summer (maximum heat content), thermocline dimensions stabilize in temperate lakes until seasonal heat loss begins during fall (Kalff, 2002; Dodson, 2004). In contrast, tropical lake thermoclines undergo periods

of thickening and thinning due to the alternation of heat loss and addition, resulting in the

formation of multiple thermal layers (Lewis, 1987). This alternation in the thickness of

the thermocline on a weekly scale may influence variation of phytoplankton abundance,

zooplankton abundance, and primary production (Lampert and Sommer, 1997).

Thermocline dimensional fluctuation amplifies the recycling of nutrients within tropical 28

lakes, promoting phytoplankton accumulation. The stabilized thermocline in temperate lakes prevents nutrients lost from the epilimnion to be made available for primary production until turnover in the fall (Ruttner, 1963; Hutchinson, 1967). Tropical lakes undergoing thermocline dimensional fluctuation are far more likely to be eutrophic than temperate lakes (Lewis, 1987).

Water temperature affects metabolic processes of organisms within lakes throughout the year. Temperatures within shallow or small, low-elevation temperate lakes

during summer come close to those of tropical lakes; however, annual average

thermocline temperatures are much lower in temperate lakes (Scheffer, 1998). As a

result, metabolic processes dependent on temperature remain stable in the upper mixed

layers of tropical lakes (Lewis, 1987). Nutrient cycling and photosynthesis will also occur

more rapidly in the upper mixed layers during stratification (Brönmark and Hansson,

1998). Hypolimnion temperatures display greater sensitivity with respect to latitude than

do those of the epilimnion. Hypolimnion temperatures in tropical lakes only drop as low

as the seasonal minimum air temperature, which is roughly 24°C within 10° of the

equator at low altitudes (Kalff, 2002). These high temperatures allow metabolism to

remain at high rates, and consequently higher rates for nutrient regeneration and oxygen

removal than in temperate lakes.

Primary production is influenced by solar irradiance and temperature, as well as

nutrient availability (Brönmark and Hansson, 1998). Significant nutrient loss could

overcome the effects of temperature and irradiance, allowing a nutrient-limited tropical

lake to maintain near equal primary production as a temperate lake with similar nutrient 29 limitation. Tropical lakes display greater primary productivity due to high solar irradiance and temperature, as well as nutrient recycling.

Tropical terrestrial environments display extremely high species diversity as compared to temperate terrestrial environments. This diversity is consistent for both aquatic vertebrates and invertebrates (Serruya and Pollingher, 1983). Lakes within the

African rift valley sustain varying fish species ranging into the hundreds, many of which are specific to individual lakes (Beadle, 1974). Conversely, many of the dominant species occupying tropical lakes are similar if not identical to organisms occupying temperate lakes (Hutchinson, 1967; Beadle, 1974). Phytoplankton diversity bears no significant latitudinal variability, with similar diversities occurring in both tropical and temperate lakes (Lewis, 1987). Blue-green algae does, however show latitudinal preference with greater diversity in the warm tropics, but lacustrine fauna diversity with exception of fish do not show significant variability with latitude (Lewis, 1987). Lack of benthic diversity in tropical lakes is likely an effect of anoxia due to high productivity.

Significant differences exist between temperate and tropical lakes. The majority of the contrasts are a function climate and solar irradiance. These features leave little evidence in the sediments of ancient lakes. Deeper lakes will exhibit seasonality contrasts, manifesting as varves in glacial lakes, and in some cases in tropical lakes

(Verschuren, 2002). Shallow lakes will not produce these features as a result of intense mixing and bioturbation (Sly, 1978; Håkanson and Jansson, 1983). Shallow lakes do however provide evidence of water table fluctuation due to hydrologic and climatic controls. Evidence such as marmorization, root colonization, pseudo-microkarstification, 30 and pedogenic features are indicative of lake margin environments and are apparent in shallow lake deposits within the rock record (Freytet and Plaziat, 1982; Freytet and

Verrecchia, 2002). These features are abundant in the lacustrine limestones of the northern Appalachian basin, supporting a shallow water depositional environment. 31

2.6 Brackish Water Environment

Marine and freshwater carbonate environments can be identified quite readily from fossil and sedimentologic features (e.g. Scholle et al., 1982; Freytet and Plaziat,

1982) while brackish conditions in general are more problematic. Brackish water environments are characterized by highly variable physical and chemical conditions, which impose considerable physiological demands on the associated fauna (Remane and

Schlieper, 1971; Cognetti and Maltagliati, 2000). Typical brackish environments occur as estuaries (Boyd et al., 1992; Reinson, 1992; Bird, 2000) and coastal lakes with a freshwater surplus relative to saline water input, producing salinity concentrations intermediate between normal fresh and marine water (>5º/oo to 30º/oo; Remane and

Schlieper, 1971; Barnes, 1989; Eby, 2004). Brief inundations of saline water into a fresh water coastal lake could result from catastrophic events (storms, tsunamis) breaching barrier bars, producing temporary brackish conditions (Staub and Cohen, 1979; Boyd et al., 1992; Minoura et al., 1994; Bondevik et al., 1997; Clague et al., 1999; 2000; Sawai,

2002; Donnelly et al., 2004). More sustained inundations are characterized by a permanent input of marine water as in typical estuaries or connected basins (Dalrymple et al., 1992; Croghan, 1983) or by highly periodic inputs produced by seasonal, bimonthly, or tidal cycles, such as in Lake Pontchartrain, Louisiana (Darnell, 1962; Manheim and

Hayes, 2002), the eastern portion of the Amazon River north of the Xingu River

(Goulding et al., 2003) or the Baixada Maranheuse in northern Brazil (Ibañez et al.,

2000). Mixing of freshwater with marginal to full marine species could easily occur along 32

these coastal transition zones, as especially seen in the tidal forests and floodplain lakes of northern Brazil.

The identification of brackish water paleoenvironments in the fossil record is problematic (Holmden et al., 1997). Some brackish indicators used include the interpretation of fossils, displaced marine fossils, ichnology, and presence of tidal sedimentary structures (Calver, 1965; Ferm and Williams, 1965; Hobday and Horne,

1977; Williams, 1979; Archer and Maples, 1984; Leckie and Singh, 1991; Dalrymple et al., 1992; Pemberton and Wightman, 1992; Shanley et al., 1992; Wightman et al., 1993;

Archer et al., 1995; Martino, 1996; Buatois et al., 1997; Dini et al, 1998; Hippensteel and

Martin, 1999; Knox and Gordon, 1999; Tibert and Scott, 1999; Goff, 2000; Süss et al.,

2002; Mángano and Buatois, 2004; Wehrmann et al., 2005). Unfortunately, the extent of

brackish water conditions, long- or short-term, is often difficult to assess (Barnes, 1989).

However, fossil evidence still remains a valuable way to assess marine influence, especially with carbonates because of good preservation potential (see Schopf, 1978).

Organisms commonly associated with a brackish environment include lingulid , the feeding trace Spirophyton, microforaminifera Spirillinia, as well as

various species of diatoms, foraminifera, and ostracodes (Wightman et al., 1993; Archer

et al., 1995; Dini et al, 1998; Knox and Gordon, 1999; Tibert and Scott, 1999; Sawai,

2002). It is important to note that in coastal or marginal marine settings, short-term

changes in salinity can juxtapose marine and freshwater fossils through postmortem

transport (Wightman et al., 1993), movement of offshore organisms onshore during a

storm event (Minoura et al., 1994; Hippensteel and Martin, 1999; Sawai, 2002) or even 33 larval transport during storms. Researchers must understand the biology of the fossil organisms as well as the sedimentology of the deposit to interpret the paleoecology and paleosalinity correctly (e.g. Barnes, 1989).

All aquatic organisms posses a specific range of tolerance to salinity in which they can survive (Hammer, 1986). Organisms are commonly classified in relation to their range of tolerance. Stenohaline organisms exhibit a narrow range of tolerance, and are represented by the majority of marine and freshwater organisms. Euryhaline organisms exhibit a wide range of tolerance, and represent truly brackish water organisms. If introduced into a salinity regime outside their tolerance level, most organisms will either perish or exhibit sub-lethal effects including modification of metabolic rate, change in activity patterns, or alteration of growth rates (Remane and Schlieper, 1971). The species living in these environments will commonly display a gradient of resistance to the increasing environmental stress. Generally, at a critical salinity level between 5 and 8 ppt, there exists an extreme numerical drop in species diversity (Cognetti and Maltagliati,

2000).

Fossils within the limestones of the Pennsylvanian cyclothems of the northern

Appalachian basin may be the best way to identify the extent of marine influence because sedimentologic indicators appear to be rare (Martin, 1998; Belt et al., 2002). A fossil with marine affinities found in the lacustrine limestones of the Pennsylvanian cyclothems may be useful in assessing marine-influenced freshwater or temporary brackish water depositional environments. This fossil is the polychaete worm tube Spirorbis. 34

2.7 Spirorbis

Spirorbis sp. (Figure 5) is a member of the Family Serpulidae (polychaete worms)

which produces a preservable, mostly spiral, calcareous tube (Railsback, 1993; Rouse and

Pleijel, 2001). In thin section, tubes can range up to a few millimeters in diameter and several centimeters in length. Serpulid worm tubes are identified in thin section by a layered microstructure that appears in longitudinal section as an outer cone-in-cone pattern and a laminated or clear inner layer (Weedon, 1994; Flügel, 2004). Tubes cut tangentially consist of concentric-irregular rings (Flügel, 2004). Spirorbis sp. has been in existence since the (Ruedemann, 1934; Moore, 1962; Peryt, 1974; Belokrys,

1984; Boardman et al., 1987; Railsback, 1993) living in the shallow marine (Harris,

1972), including saline coastal bays and lagoons, rarely extending into deeper shelf locales (Rouse and Pleijel, 2001; Ruppert et al., 2003; Scholle and Ulmer-Scholle, 2003;

Flügel, 2004). Very few species of polychaete worms can exist in freshwater and none of these produce calcareous tubes like Spirorbis. Polychaete worms that can tolerate lower salinities display a more intimate association of nephridia (kidneys) with blood vessels to maintain salt/water balances. In the modern, spirorbids are only known to occur along coastal transition zones which are continually marine-influenced, including coastal lakes with connections to the sea and even in subterranean caves linked to the marine (Foster,

1972; Klemm, 1985; Rouse and Pleijel, 2001; Ruppert et al., 2003).

Spirorbids, as many serpulid worms, secrete a carbonate tube around their body, commonly spiral in shape, and typically attach via an anchoring structure (Flügel, 2004) to a fixed object, such as a shell, rock, or plant (Figure 5), in colonial masses, or as 35 isolated encrustors. (Dana, 1880; Trueman, 1947; Bosence, 1979; Ten Hove, 1979;

Schwindt and Iribarne, 2000; Ruppert et al., 2003). These serpulid worms produce ciliated, swimming larvae called trophophores. The larvae develop quickly and become too large to support themselves in the water column so they sink to the sea floor to begin colonization (Rouse and Pleijel, 2001; Ruppert et al., 2003). Spirorbids have been observed initiating colonization in as little as three days after entering the swimming stage (Ushakova, 2003).

Figure 5. Photograph of modern Spirorbis worm tubes encrusting a bivalve shell; upper scale in inches. 36

The use of Spirorbis as a paleosalinity indicator began in the 19th and early 20th century. Dawson (1868), Dana (1880), Etheridge (1880), Price (1914), and Grabau

(1920) all supported a brackish-water interpretation in the fossil record for these serpulid worm tubes. Other workers found Spirorbis in association with land plants, spores, fish remains, lamellibranchs, and ostracodes, all of which were interpreted as freshwater fauna and flora (Barrois 1904; Cox, 1926; Davies, 1930; Trueman, 1942; 1947; Scott and

Summerson, 1943; Cooper, 1946; Beckmann, 1954; Weller, 1957; Strauch, 1966) and assigned Spirorbis as a freshwater organism. Later, at least, the lamellibranchs with encrusted Spirorbis tubes were re-interpreted as brackish fauna (Weir, 1945; Eagar,

1960). Interestingly enough, Spirorbis was also found in association with marine communities in the Pennsylvanian/Permian of the USA (Ruedemann, 1934; Condra and

Elias, 1944; Sturgeon et al., 1958; Stevens, 1966; Suchy and West, 1988; Kietzke and

Heckert, 1995; Fahrer, 1996; Maeda et al., 2003). This dichotomy of habitat lead Cox

(1926) and Trueman (1942) to propose a separate name (Microconchus) for the

“nonmarine worm tubes” but this was not generally accepted in the literature because there was no difference in the body form of the fossils from the two environments

(Calver, 1965). The most perplexing associations with Spirorbis for these workers was that with vascular plants (Grabau, 1920; Trueman, 1947; Weller, 1957; Strauch, 1966), amphibian footprints (Martino, 1991), stromatolites (Vasey and Zodrow, 1983), and freshwater ostracodes (Scott, 1944) from the as well as vascular plants

(Mamay, 1966; Stapf, 1971; Warth, 1982; Kelber, 1986; 1987; Mapes and Maples, 1988), eurypterids (Kues, 1988), and coal (Warth, 1982) from the Permian /, 37

encouraging, in some cases, an interpretation of brackish to strictly freshwater conditions

(or unusual depositional processes). Mixing of fauna in coastal transition zones through

post-mortem transport or short-term marine incursions was not always considered in

some of these environmental interpretations. Most assumptions of faunal and floral

mixing involve material from land going into the sea (e.g. Wehrmann et al., 2005) but not

vice versa.

In the northern Appalachian basin, Spirorbis sp. is found in the lacustrine

limestones of the Allegheny through Dunkard Groups (Eager, 1975; Yochelson, 1975;

Donaldson. 1979; Weedman, 1988; 1994; Petzold, 1989; 1990; Eggleston, 1994; Fahrer,

1996; Lewis and Dunagan, 2000). In many cases, the worm tube occurrences are in

association with facies containing carbonate clastic textures, implying transport, though

detailed sedimentologic logs are lacking. A more systematic look at a spectrum of

limestone facies interpreted as marine to brackish or freshwater in the northern

Appalachian basin may help clarify the exact conditions of preservation for the Spirorbis worm tubes in relation to fully freshwater and marine deposits in the Pennsylvanian. 38

Chapter 3: Methodology

The focus of this research was to determine whether the salinity of the

depositional environments of Late Pennsylvanian limestones of the northern Appalachian

basin could be ascertained through detailed petrography and sedimentology. Specifically

the aim was to recognize any textural/compositional ‘markers’ by which brackish and

freshwater carbonates could be differentiated from marine carbonates in the absence of stable isotopic data.

Significant limitations prevent application of stable isotope methods to the carbonates of the Appalachian basin. These techniques may not be an adequate tool to determine paleosalinity in marginal marine areas (Hendry and Kalin, 1997) because of the effects of hydrodynamic restriction, i.e. changing water salinities through evaporation, tides, etc. as well as vital effects in organic matter degradation. The latitude of the depositional environment limits 18O values, producing similar results for marine

and freshwaters in low latitude tropical settings (Keith and Weber, 1964; Holmden, et al.,

1997). Isotopic 13C results are also inconsistent if any marine carbonates are present within the watershed of the studied units, as is the case in the Appalachian basin (Keith and Weber, 1964; Holmden, et al., 1997). The determination of 87Sr/86Sr ratios of shells

may be more useful in determining the relative contributions of seawater and freshwater

into a coastal environment (Brand and Gibling, 1994; Holmden et al., 1997); however, a

simple, inexpensive petrographic technique to identify potential paleosalinity changes would aid in recognizing the proper sequences to sample geochemically. 39

Fieldwork was conducted during the winter of 2002 and the summer of 2003.

Limestone units of the Pennsylvanian cyclothems targeted for this study in the

Conemaugh and Monongahela Groups (Busch and Rollins, 1984) of the northern

Appalachian basin crop out in an elliptical pattern in Kentucky, Ohio, Pennsylvania, and

West Virginia (Figure 3). Ten limestones units were targeted: Ames,

Benwood/Arnoldsburg, Clarksburg, Upper Brush Creek/Pine Creek, Lower Brush Creek,

Redstone, Cambridge/Nadine, Two Mile, Ewing, and Pittsburgh, stratigraphically

represented in Figure 4. These are limestones designated in the literature (Fedorko, 1979;

Fonner and Fedorko, 1985; Cecil and Eble, 1992; Edmunds et al., 1999) as marine,

freshwater, and freshwater to brackish (after Condit, 1912; Miller, 1934; Lamborn, 1951).

The distribution of sample localities was chosen to adequately represent the variation in depositional conditions with regards to the source area (orogen).

Sampling across the entire northern Appalachian basin was necessary to increase the likelihood of collecting freshwater, brackish, and marine limestones. Samples were

collected laterally within individual units on a local scale and on a basin wide scale in an

attempt to illuminate transitional phases within the depositional regime as well as the

possible resolution of a salinity gradient within a single lithology (see Figures 4 and 6).

Vertical sampling of limestones within a stratigraphic interval was also undertaken in order to illustrate the change in depositional environment, if present, over time at a single location. Individual locations were chosen based on quality of exposure and accessibility.

Sample locations of specific lithologies were provided for Kentucky and West Virginia

by Ronald Martino of Marshall University, and for Pennsylvania by John Harper and Vik 40

Skema of the Pennsylvania Geological Survey. Additional locations were chosen from the literature based on quality of exposure and accessibility. A total of 52 locations in four states (Figure 6) were sampled to obtain a spectrum of limestone facies. See appendix for summary of sample numbers and locations. 174 thin sections were prepared from the collected samples and examined petrographically. Criteria used to evaluate textures included faunal content, sedimentary structures, textures, diagenetic fabrics, and mineralogic content. 41

83° 82° 81° 80° 79°

Kittanning PA-45 Beaver Falls 42° Butler Co. A Armstrong Co. Beaver Co. PA-46 42°

PA-12 PA-16 PA-38 Indiana Co. PA-47 PA-19 PA-35

Pittsburgh PA-23 PA-21 Blairsville PA-11 PA-22 Allegheny Co. PA-36 Westmoreland Co. PA PA-4 PA-6 PA-7 Greensburg Washington Co. 0 20 miles PA-5 PA-13 41° 0 20 kilometers 41° Inset A

OH Pittsburgh

Wheeling 40° Cambridge Somerset 40°

JG-1 JG-2 WV79-6R WV79-6P WV68-1 Morgantown B-31a CN-11/CN-5a Athens CN-16 R-32c WV50-2 WV50-3 WV79-5 CR-23 WV50-4 WV50-1 WV79-3E WV79-3 WV79-1 WV79-2 39° Ames Weston Benwood 39° Clarksburg U. Brush Creek/Pine Creek WV WV79-4 L. Brush Creek/Brush Creek Redstone K-48 Cambridge/Nadine KY-30 K-44 K-43 KY-27 K-50 Two Mile KY-26 Huntington K-49 KY-4 L-3 Ewing KY-31 L-7 Charleston Pittsburgh N

KY-3 0 10 20 30 40 miles 38° KY-21B KY-21A 0 10 20 30 40 50 kilometers 38°

82° 81° 80° 79°

Figure 6. Localities (52 total) of sampled limestone units from the Conemaugh and Monongahela Groups within the northern Appalachian basin. See appendix for details on localities as well as sample numbers and paleosalinity interpretations.

42

Chapter 4: Facies Descriptions and Interpretations

4.1 – Introduction

Detailed petrographic analysis of the ten studied limestone units from 174 thin sections, varying with respect to depositional environment from purely freshwater to open marine, provides the identification of eight basic lithofacies types:

• Type 1: Micrite

• Type 2: Ostracodal wackestone to packstone

• Type 3: Intraclastic microbreccia

• Type 4: Mottled micrite and microbreccia

• Type 5: Spirorbis-bearing biomicrite

• Type 6: a) Matrix-supported siliciclastic microbreccia

b) Intraclastic, matrix-supported siliciclastic microbreccia

• Type 7: Wackestone

• Type 8: Packstone

A summary of facies types and their description and interpretation is found in Table 1.

*Note-A modification of the Folk and Dunham classification systems is necessary when describing freshwater limestones because these two classification systems were originally based only on marine limestones alone (e.g. Wright, 1993; Arp, 1995). 43

Facies Depositional Lithofacies Identification Criteria Type Environment Contains < 10% allochems in micrite matrix. Fossils Freshwater, Type 1 Micrite limited to ostracodes, gastropods, charophytes. Average lacustrine unit thickness ranges from cm- to m- scale. Ostracodal Consists of micritic matrix containing 10-50% ostracode Freshwater, Type 2 wackestone shells (intact or disarticulated carapaces). Average unit lacustrine to packstone thickness ranges from cm- to dm- scale. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to Intraclastic Freshwater, pebble. Common features include: spar-filled planar void Type 3 microbreccia palustrine spaces, clay-lined tubules, ostracodes, and peloidal structures. Average unit thickness ranges from mm- to dm- scale. Exhibits features of Type 1 and Type 3 facies overprinted Mottled Freshwater, by yellow-orange-red mottling. Samples contain Type 4 micrite & palustrine ostracode fragments and spar filled void spaces. Average microbreccia unit thickness ranges from cm- to dm- scale. Occurs as restricted layers (< 10cm) within Type 1 and Type 3 facies. Spirorbis worm tubes (~1mm in diameter Spirorbis– and length) float as fragments, individual tubes, or small Type 5 bearing Brackish clusters in a micritic matrix. Tubes are commonly filled biomicrite with sparry cement and are associated with ostracode and charophyte fragments, and carbonate microbreccia and intraclasts. Consists of 40-80% regular to sub-angular quartz, chert, Matrix- microcline, and plagioclase grains floating in a micritic supported Type 6a Marine matrix. Siliciclastic grains range in size from very fine siliciclastic sand to very coarse sand. Glauconite is present. Average microbreccia unit thickness ranges from cm- to m- scale. Displays similar features as Type 6a, with siliciclastic Intraclastic mineral grains (matrix- or grain-supported) as high as matrix- 70%. This facies type differs from Type 6a with the Fresh / Type 6b supported additional presence of very fine sand to pebble-sized, brackish? siliciclastic angular to subangular-micritic intraclasts. No Glauconite microbreccia present. Average unit thickness ranges from cm- to m- scale. Contains >10% allochems surrounded by a micritic matrix. Fossil content is highly varied: bryozoans, Type 7 Wackestone Marine brachiopods, bivalves, gastropods, , foraminifera, and trilobites. Average unit thickness ranges from cm- to m- scale. Only differs from Type 7 in allochems vs. micrite matrix abundance with less matrix and a self-supporting Type 8 Packstone Marine framework of fossils. Average unit thickness ranges from cm- to m- scale.

Table 1. Identification criteria and interpretations for the eight lithofacies types. 44

4.2 – Type 1: Micrite Description

This facies contains less than 10% allochems in a micrite matrix. Fossil content normally is limited to ostracodes, gastropods, charophytes, and rare plant debris. Rare fine-grained detrital quartz grains floating in micritic matrix can be observed. Isolated patches of void-filling spar cement occur as geopetal structures within disarticulated ostracode carapaces. Relict horizontal laminations can also be identified by millimeter- scale color alternations as well as sparsely-bedded ostracode carapaces. Thickness of units varied from cm-to-m scale. Figures 7-10 illustrate typical examples of Facies Type

1.

Figure 7. Photomicrograph (cross-polarized) of sample JG-1-24 (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm. 45

Figure 8. Photomicrograph (plane-polarized) of sample K-49B (unnamed limestone above the Two Mile Limestone), FOV = 5.5mm.

Figure 9. Photomicrograph (plane-polarized) of sample PA-5-B (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm. 46

Figure 10. Photomicrograph (cross-polarized) of sample R-32c-FP-23 (Pittsburgh Limestone), FOV = 5.5mm.

Interpretation

The micrite facies is interpreted as open lacustrine in origin (after Freytet and

Plaziat, 1982; Freytet and Verrecchia, 2002). This facies lacks marine fossils and rarely contains freshwater fossils. Relict laminations and sparsely bedded ostracode carapaces are indicative of quiet water deposition. These units also lack any significant pedogenic alteration, also suggesting a more distal, open water environment (after Valero Garcés et al., 1994).

47

4.3 - Type 2: Ostracodal wackestone to packstone

Description

This facies type consists of micritic matrix containing between 10-50 % ostracode shells, occurring as intact body fossils or as detached carapaces. Detached carapaces commonly display horizontal layering interbedded with non-fossiliferous micrite.

Packstone samples are dominated by detached carapaces surrounded by minor micrite matrix and sparse fine-grained, detrital quartz grains. Articulated shells are commonly filled with void-filling spar cement and rarely micrite. Unit thickness varied from cm-to- dm scale. Figures 11-14 illustrate typical examples of Facies Type 2.

Figure 11. Photomicrograph (cross-polarized) of sample JG-1-26 (Benwood/ Arnoldsburg) Limestone, FOV = 5.5mm. 48

Figure 12. Photomicrograph (cross-polarized) of sample PA-6D-A (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm.

Figure 13. Photomicrograph (plane-polarized) of sample WV50-2T (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm. 49

Figure 14. Photomicrograph (cross-polarized) of sample WV79-6B (Pittsburgh Limestone), FOV = 5.5mm.

Interpretation

The ostracodal wackestone to packstone facies only differs from the micrite facies in the percentage of allochems versus matrix present, and is also interpreted as open lacustrine (after Freytet and Plaziat, 1982; Valero Garcés et al., 1994; Freytet and

Verrecchia, 2002). These samples contain the same homogenous micrite matrix with varying amounts of exclusively ostracode remains. These samples contain no marine or brackish fossils.

50

4.4 - Type 3: Intraclastic microbreccia

Description

This facies consists of lithorelict intraclasts in varying degrees of diagenetic

alteration. Intraclasts float in micritic matrix of varying densities and can be recognized

by color variation from the matrix. Intraclast grain sizes range from very fine sand to

medium to coarse pebble. Common features within the intraclasts and the matrix include

spar-filled planar void spaces, clay-lined tubules, ostracode fragments, and peloidal

structures. Samples with low densities of intraclasts show only minor alteration by

common features listed above. Samples with high densities of intraclasts display abundant spar-filled void spaces, with individual intraclasts rimmed by drusy calcite cement. Some specimens display curved planes of spar-filled circumgranular cracks.

Thicknesses of units in this facies are highly variable, from mm- to dm-scale. Figures 15-

18 illustrate typical examples of Facies Type 3.

Figure 15. Photomicrograph (cross-polarized) of sample WV79-6C (Pittsburgh Limestone), FOV = 5.5mm. 51

Figure 16. Photomicrograph (cross-polarized) of sample WV79-2M (Clarksburg Limestone), FOV = 5.5mm.

Figure 17. Photomicrograph (cross-polarized) of sample WV50-1D (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm. 52

Figure 18. Photomicrograph (cross-polarized) of sample JG-2-43C (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm.

Interpretation

The intraclastic microbreccia facies is interpreted as lacustrine/palustrine in

origin. This intraclastic texture is indicative of marginal lacustrine environments constantly affected by water level fluctuations (Alonzo-Zarza and Calvo, 2000). Water table fluctuation causes desiccation to occur during dry times and swelling of hydrated

clays during wetter times (Grim, 1953; Weaver, 1989; Evans, 1992). The net effect is the

occurrence of in-situ brecciation and microkarstification (Freytet and Plaziat, 1982;

Alonzo-Zarza et al., 1992; Freytet and Verrecchia, 2002). Many of these samples also

contain clay-lined tubules (rhizoliths) produced by plant colonization in a marginal

environment. Plant colonization accelerates the pedogenic alteration due to water table

fluctuation, producing more severe intraclastic textures (Alonzo-Zarza, 2003).

53

4.5 - Type 4: Mottled micrite and microbreccia

Description

This facies exhibits features similar to the micrite facies (Type 1) and the intraclastic microbreccia facies (Type 3), except that it exhibits yellow-orange-red mottling. Micritic samples contain sparse ostracode fossils and rare spar-filled, planar void spaces. More brecciated samples also contain rare ostracode fragments and a higher density of spar-filled void spaces with linear, circumgranular, planar, and irregular shapes. The colored mottling overprints all these features. Thickness of units is generally on the cm- to dm-scale. Figures 19-22 illustrate typical examples of Facies Type 4.

Figure 19. Photomicrograph (plane-polarized) of sample PA-12-2 (Clarksburg Limestone), FOV = 5.5mm. 54

Figure 20. Photomicrograph (cross-polarized) of sample WV50-1A (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm.

Figure 21. Photomicrograph (plane-polarized) of sample WV79-4-OOP (Redstone Limestone), FOV = 5.5mm. 55

Figure 22. Photomicrograph (plane-polarized) of sample WV50-3A (Clarksburg Limestone), FOV = 5.5mm.

Interpretation

Mottled micrites and microbreccias are interpreted as palustrine (marginal lacustrine) in origin. These facies only differ from the micrites (Type 1) and the intraclastic microbreccias (Type 3) with the presence of mottling. This mottling is indicative of iron remobilization due to water table fluctuation, common in palustrine environments, and is interpreted as marmorization (Schlichting and Schwertmann, 1973;

PiPujol and Buurman, 1994; Alonzo-Zarza, 2003). The common occurrence of in situ brecciation, rhizoliths, and microkarstification also support the palustrine interpretation

(Alonzo-Zarza et al., 1992; Alonzo-Zarza and Calvo, 2000).

56

4.6 - Type 5: Spirorbis-bearing biomicrite

Description

This facies occurs as single layers (<10cm) within units ranging from micrite

(Type 1) to intraclastic microbreccias (Type 3). Spirorbis worm tubes, just mm in diameter and length (Figures 23, 24), typically float as fragments, individual tubes, or as small clusters in the micritic matrix. Orientation of tubes varies showing the lack of symmetrical coiling. Tangential sections exhibit concentric rings with ropy texture.

Longitudinal sections at various angles show the irregularities of tube growth; however, a very well preserved specimen displays a cone-in-cone layering pattern. Cross-sectional views of worm tubes reveal ropy-undulating structure, containing spar void-filling cement, and rarely micrite. Relict laminations can also be observed within intraclasts in microbrecciated Spirorbis-bearing layers. Spirorbis fossils are commonly associated with ostracode fragments, charophytes, carbonate microbreccia and intraclasts, and isolated fine-grained detrital quartz grains. Vertical sampling through the limestone units at fourteen of the sampled localities (K-43, K-44, K-48, K-49, Ky-26B, L-3A, L-7, PA-11,

PA-12, WV50-1, WV50-3C, Wv79-2B, WV79-5. WV79-6, see appendix for locations) exhibited the restricted occurrence of Spirorbis to discrete cm-thick layers, see Figure 25 for detailed section of PA-12 as an example of this. Figures 26 – 29 illustrate typical examples of Facies Type 5. 57

1mm

Figure 23. Magnified hand sample image of a Spirorbis worm tube on the surface of limestone sample K-49A (unnamed limestone above Two Mile Limestone). Note lack of symmetry of the coiled tube.

1 mm

Figure 24. Magnified hand sample image of a Spirorbis worm tube internal cast on the surface of limestone sample K-49A (unnamed limestone above Two Mile Limestone). 58

1

PA-11-1, Facies Type 1, Freshwater

6.7m 2

PA-11-2, Facies Type 5, Brackish

5.6m

5.0m 3 1 4.9m 4.7m PA-11-3, Facies Type 5, Brackish

4.0m

4 2 3.3m 3.0m 3 PA-11-4, Facies Type 3, Freshwater 4

5 2.2m 5 6 1.4m PA-11-5, Facies Type 5, Brackish

6 0m PA-11-6, Facies Type 3, Freshwater

Figure 25. Sample locality PA-11 (Clarksburg limestone) located near Delmont, PA (see appendix for exact location). Exact sample layers are shown by numbers along with a photo and interpretation of thin section texture. Section legend: circle pattern = sandstone; lined pattern = calcic shale; brick pattern = limestone; crosshatch = cover. Thin section views: FOV = 5.5mm. 59

Figure 26. Photomicrograph (cross-polarized) of sample K-44D (Two Mile Limestone), FOV = 5.5mm.

Figure 27. Cross-polarized view of sample L3A-2 (Two Mile Limestone), FOV = 5.5mm.

60

Figure 28. Photomicrograph (cross-polarized) of sample PA-11-3 (Clarksburg Limestone), FOV = 5.5mm.

Figure 29. Photomicrograph (plane-polarized) of sample PA-12-4A (Clarksburg Limestone), FOV = 5.5mm. 61

Interpretation

The Spirorbis-bearing biomicrite facies is interpreted as a brackish water

environment. All Spirorbis occurrences are restricted to discrete layers within lacustrine carbonates. Rarely, Spirorbis is associated with unsorted quartz grains. These samples represent more proximal to barrier breach (washover) deposits, while samples occurring

in micritic matrix void of quartz represent more distal (inland deposits). The occurrence

of Spirorbis in a single discrete layer within a lacustrine carbonate unit fits within the

model of short-term marine incursion indicating brackish conditions (Morris, 1967;

Baker, 1975).

62

4.7 - Type 6: Matrix-supported siliciclastic microbreccia

Description

6A – This facies (Figures 30, 31) is comprised of large populations of regular to

sub-angular clastic mineral grains floating in micritic matrix. The mineral grains include

quartz, chert, microcline, and plagioclase and comprise 40-80% of the texture. Sizes of

these siliciclastic grains range from very fine sand (<0.062mm) to very coarse sand (1.0-

2.0mm). Also present is glauconitic clay. Unit thickness is cm-m scale.

6B – This facies (Figures 32, 33) is similar to the intraclastic microbreccia facies

(Type 3), however the amount of siliciclastic mineral grains, as listed for Type 6A, floating or supported in the texture, can be as high as 70%. Size ranges for the carbonate intraclasts range from very fine sand to pebble size while siliciclastic grain sizes are similar to those in Type 6A.

Figure 30. Photomicrograph (cross-polarized) of sample KY-21B-1 (Upper Brush Creek Limestone), FOV = 5.5mm. 63

Figure 31. Photomicrograph (cross-polarized) of sample KY-3A (Upper Brush Creek Limestone), FOV = 5.5mm.

Figure 32. Photomicrograph (cross-polarized) of sample JG-1-8 (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm. 64

Figure 33. Photomicrograph (cross-polarized) of sample JG-1-10 (Benwood/ Arnoldsburg Limestone), FOV = 5.5mm.

Interpretation

Facies Type 6a is interpreted as nearshore marine deposits because of the presence of glauconitic clay (Weaver, 1989). These carbonates display a continuous influence from the detrital regime, commonly containing coarse-grained feldspars that limit the deposits as proximal to the source.

The matrix-supported siliciclastic microbreccia facies type 6b is interpreted as a possible brackish washover deposit. Catastrophic deposition caused by storm surges and tsunamis commonly disturb underlying deposits while depositing allochthonous siliciclastic material from offshore and barrier locations (Staub and Cohen, 1979;

Minaura et al., 1994; Ritter et al., 2002; Sawai, 2002). Facies type 6b contains angular

rip-up clasts of micrite, intercalated with poorly sorted quartz grains and rare feldspar

grains floating within a micrite matrix. These textures suggest catastrophic deposition. 65

4.8 - Type 7: Wackestone

Description

This carbonate facies contains greater than 10% allochems surrounded by a micritic

matrix. Fossil content is highly varied: bryozoans, brachiopods, bivalves, gastropods, echinoderms, foraminifera, and trilobites. Glauconite and quartz grains rarely float in the

matrix. Thickness of units ranges from cm-m scale. Figures 34-37 illustrate typical

examples of Facies Type 7.

Figure 34. Photomicrograph (cross-polarized) of sample KY-31L (Lower Brush Creek Limestone), FOV = 5.5mm. 66

Figure 35. Photomicrograph (cross-polarized) of sample PA-21-1 (Ames Limestone), FOV = 5.5mm.

Figure 36. Photomicrograph (cross-polarized) of sample WV79-1 (Ames Limestone), FOV = 5.5mm. 67

Figure 37. Photomicrograph (cross-polarized) of sample PA-16-1 (Ames Limestone), FOV = 5.5mm.

Interpretation

The wackestone facies is interpreted as shallow marine in origin due to the abundance of exclusively marine fossils, glauconite, and rare detrital siliciclastics (after

Enos, 1983; Weaver, 1989).

68

4.9 Type 8: Packstone

Description

This facies type only differs from Facies Type 7 (wackestone) in allochem versus micrite matrix abundance. These samples contain less micritic matrix with fossil content displaying a self-supporting framework. The majority of grains are in contact with one another; however, small amounts of micrite and microspar matrix are present. Fossil content in this facies type is identical to Facies Type 7 and comprises: bryozoans, brachiopods, bivalves, gastropods, echinoderms, foraminifera, and trilobites. Facies thickness ranges from cm-to-m scale. Figures 38-41 illustrate examples of Facies Type 8.

Figure 38. Photomicrograph (cross-polarized) of sample KY-30 (Lower Brush Creek Limestone), FOV = 5.5mm. 69

Figure 39. Photomicrograph (cross-polarized) of sample PA-36 (Nadine Limestone), FOV = 5.5mm.

Figure 40. Photomicrograph (cross-polarized) of sample KY-26 (Cambridge Limestone), FOV = 5.5mm. 70

Figure 41. Photomicrograph (cross-polarized) of sample KY-21A (Lower Brush Creek Limestone), FOV = 5.5mm.

Interpretation

The packstone facies is interpreted as marine in origin due to the abundance of exclusively marine fossils and glauconite (after Enos, 1983; Weaver, 1989).

71

Chapter 5: Ostracode Analysis

Ostracodes from the Benwood, Clarksburg, Two Mile, and Pittsburgh limestones

were identified as Gutschickia sp., Darwinula stevensoni, Carbonita sp, Pruvostina sp.,

Whippela sp., and Candona bairdoides by Dr. Lisa Park of the University of Akron

(Table 2). In most cases, identification down to the species level was not possible because

only thin sections were provided for analysis. However, despite this, the assemblage is

freshwater in origin with additional brackish water affinities for Darwinula stevensoni

and Carbonita sp. (Swain, 1999). Since most of the limestones sampled had more than

one species present, the assemblages with the co-occurrence of D. stevensoni and

Carbonita sp. with Gutschickia sp., Pruvostina sp., Whippela sp. and Candona bairdoides indicate a probable freshwater paleoenvironment for facies types 1, 2, and 3.

Facies type 5 has both D. stevensoni and Gutschickia sp. and is interpreted as brackish, based upon the sedimentology and presence of the spirorbids. The ostracodes preserved in some of the samples of facies type 5 were few in number and extremely poorly preserved. When abundant, the ostracodes in these samples were found in a coquina of disarticulated carapaces in hydrodynamically stable positions, indicating significant transport (after Park et al., 2003).

Carbonita sp. is a common genus in Pennsylvanian-Permian cyclothems and has certain morphological affinities with Cypridopsis (Scott and Summerson, 1943).

Pruvostina sp. and Whippela sp. can also be confused, although there are prominent differences in the hinge structures that allow discrimination (Swain, 1999). The presence of these ostracodes indicates that the lakes in which they lived were most likely shallow 72 of no more than three meters depth. They most likely lived on algae in these permanent waters (Scott, 1944).

Comparative Material Age Formation Species Environment Reference Carbonita Freshwater lake or brackish marsh Sohn, 1985 Gutschickia Freshwater Sohn, 1985 Mississippian Bluestone Pruvostina Freshwater Sohn, 1985 Whipplella Freshwater Sohn, 1985 Darwinula Fresh or brackish water Sohn, 1985 Gutschickia Freshwater Sohn, 1977 Pennsylvanian Monongahela Darwinula Fresh or brackish water Sohn, 1977

Use the Treatise (Q) Athropoda 3 (p. Q234-248) to reference these. Limestone Sample Genus Environment Comments Unit Benwood/ Gutschickia Freshwater Coquina of ostracodes; PA6D-B Arnoldsburg Darwinula stevensoni Fresh or brackish water mostly disarticulated and in Carbonita Freshwater lake or brackish marsh Gutschickia Freshwater Far greater number of Benwood/ JG-1 (26) Pruvostina Freshwater species; many still Arnoldsburg Whipplela Freshwater articulated Darwinula stevensoni Fresh or brackish water Whipplela Freshwater Articulation is high, but Benwood/ JG-1 (15A) Gutschickia Freshwater evidence of transport; Arnoldsburg Carbonita Freshwater lake or brackish marsh valves internested within Benwood/ PA6D-A same as PA6D-A Fresh or brackish water Arnoldsburg Benwood/ WV50-1C Gutschickia Freshwater Very few preserved Arnoldsburg Coquina of ostracodes; Benwood/ mostly disarticulated and in WV50-4T Gutschickia Freshwater Arnoldsburg hydrodynamically stable positions PA11-1 Clarksburg same as JG-1 (15A) Fresh or brackish water Dissolution? Algal mats? Darwinula stevensoni Fresh or brackish water PA11-5 Clarksburg Preservation poor Gutschickia Freshwater Candona bairdoides Freshwater WV79-2T Clarksburg Gutschickia Freshwater Candona bairdoides Freshwater L3A-1 Two Mile Gutschickia Freshwater Coquina of ostracodes; mostly disarticulated and in WV79-6B Pittsburgh Gutschickia??? Freshwater hydrodynamically stable positions

Table 2. Ostracode identification from specific thin sections of the sampled limestones from the Conemaugh and Monongahela Groups of the northern Appalachian basin. See appendix for location of thin section samples. 73

Chapter 6: Depositional Environment Discussion

6.1 – Marine Environment

Fully marine carbonates are identified on the basis of abundant exclusively marine

fossils, including brachiopods and echinoderms, as well as the presence of glauconite

(Weaver, 1989). Here they are represented by matrix-supported siliciclastic microbreccia

with glauconite (Type 6A), wackestone (Type 7), and packstone (Type 8). The matrix-

supported siliciclastic microbreccia with glauconite is interpreted as a catastrophic influx of sand into a dominantly carbonate environment (Enos, 1983).

6.2 Freshwater Environment

Lacustrine to palustrine carbonates are distinguished by the presence of charophytes

and nonmarine ostracodes associated with aquatic to subaerial features of a continental carbonate environment (Freytet and Plaziat, 1982; Gierlowski-Kordesch et al., 1991;

Freytet and Verrecchia, 2002; Alonso-Zarza, 2003). No glauconitic clay or conodonts are present. Lacustrine features include thin and thick lamination, massive textures interpreted as bioturbated sediment, oncolites, and microbial textures. Palustrine carbonates are

shallow lake (marginal) sediments affected by water level fluctuations. Exposure and

pedogenic features characterize this paleoenvironment including spar-filled rhizoliths lined

with clay cutans, marmorization (mottling), intraformational brecciation, transported

intraclasts within other clasts or surrounded by circumgranular spar, oncolites, voids such

as curved, crazed, and skewed spar-filled planes, and microkarstic structures. Here the 74 freshwater facies are represented by micrite (Type 1), ostracodal wackestone to packstone

(Type 2), intraclastic microbreccias (Type 3) and mottled micrite/microbreccia (Type 4).

The micrite facies (Type 1) only differs from the ostracodal wackestone to packstone facies

(Type 2) in the percentage of allochems present. Both are interpreted as a shallow lacustrine environment (after Valero Garcés et al., 1994; 1997). The ostracodes are interpreted as nonmarine (see Table 2) with no marine fossils present. The intraclastic microbreccias and mottled micrite/microbreccia are interpreted as palustrine to pedogenically-altered lacustrine and palustrine sediments (after Freytet and Plaziat, 1982;

Freytet and Verrecchia, 2002). Water table fluctuations within these Pennsylvanian lakes caused subaerial exposure and soil processes to alter the carbonate sediments. Brecciation and intraclast formation proceeded through subaerial exposure and plant colonization

(Freytet and Plaziat, 1982; Alonzo-Zarza, 2003). Spar-filled tubules, circumgranular spar- filled cracks, as well as crazed, skewed, and curved spar-filled planes represent cement filling of root voids (rhizoliths) as well as cracks from brecciation processes. Mottling is interpreted as marmorization resulting from iron mobilization or gleying within sediment during water table fluctuations (Schlichting and Schwertmann, 1973; PiPujol and Buurman,

1994; Freytet and Verrecchia, 2002). 75

6.3 – Brackish Environment

The facies which represent brackish, or perhaps more correctly “marine influence”,

are the Spirorbis-bearing biomicrites (Type 5) and the matrix-supported siliciclastic microbreccia without glauconite (Type 6B) is interpreted as a deposit that could occur in freshwater to brackish conditions.

The matrix-supported siliciclastic microbreccia without glauconite is interpreted as a catastrophic influx of sand (washover deposit) into a dominantly continental carbonate environment. This could occur from seasonal, bimonthly, or tidal cycles as well as storm surges, hurricanes, and tsunamis bringing coarse sediment into coastal lakes. lagoons, or swamps (Darnell, 1962; Staub and Cohen, 1979; Minoura et al., 1994;

Bondevik et al., 1997; Hippensteel and Martin, 1999; Clague et al., 1999; 2000; Goff et al., 2000; Ibañez et al., 2000; Manheim and Hayes, 2002; Sawai, 2002; Goulding et al.,

2003).

In addition to bringing in sediment, such catastrophic inputs of marine waters can also bring in marine fauna, whether dead or alive (Darnell, 1962; Staub and Cohen, 1979;

Wightman et al., 1993; Minoura et al., 1994; Bondevik et al., 1997; Hippensteel and

Martin, 1999; Clague et al., 1999; 2000; Goff et al., 2000; Ibañez et al., 2000; Manheim and Hayes, 2002; Sawai, 2002; Goulding et al., 2003). The Spirorbis-bearing biomicrite is interpreted as a short-term, catastrophic marine incursion into Pennsylvanian coastal to floodplain lakes. Features of the facies supporting this interpretation include the following. (1) Spirorbis appears to be restricted to discrete layers within the lacustrine units (Figure 25). (2) The worm tubes are never found attached to a substrate or grouped 76

as a mass colonial reef. Mostly isolated tubes are found with no evidence of anchoring

structures, implying transport of the tubes or attachment to easily decayed material

(plants). (3) The worm tubes are only millimeters in length (Figures 23, 24) while modern

marine examples can be several centimeters long (Figure 5). This indicates easy transport

during a catastrophic event of a young that subsequently died as salinity decreases

after the event or larval transport and an attempt at colonization before death as

conditions freshened. Spirorbids can initiate colonization quickly from the larval stage

(Ushakova, 2003). Spirorbis worm tubes are commonly associated with clastic carbonate features in other lacustrine limestones of the Appalachian basin as well (Donaldson,

1974; 1979; Weedman, 1988; 1994; Petzold, 1989; 1990).

Spirorbis was strictly a marine animal throughout the Phanerozoic, especially during the Pennsylvanian (see Chapter 2.6: Morris, 1967; Baker, 1975). It is highly unlikely for this worm to adapt to a fully freshwater environment during Pennsylvanian time and then become strictly marine again. Morris (1967) collected evidence supporting a coastal gradient during the deposition of the Cambridge Limestone (Conemaugh

Group) in the northern Appalachian basin. In his paleogeographic reconstruction of the lower Conemaugh Group, using data from over 2800 control points across the northern portion of the basin, Morris showed how facies containing Spirorbis are found between fully marine and continental facies along a regional transect for Cambridge time. He concluded that Spirorbis must be a marginal marine animal that tolerates brackish water.

Its association with freshwater fauna and flora in the Pennsylvanian and the geologic record elsewhere in the world was likely due to the intermixing of freshwater and marine 77 organisms in lowland coastal areas affected by tidal exchange, storm surges, or tsunamis.

Such lowland coastal environments can be found today in northern Brazil.

6.4 - Modern Analog Environment

Coastal regions associated with river mouths can contain a wide variety of environments, including estuaries and deltas (Boyd et al., 1992; Bird, 2000). The area where the Amazon River enters the in northern Brazil (referred to as

‘Mouths of the Amazon’) as well as the estuaries to the east (including the Baixada

Maranheuse) contain components of both a delta and an estuary (Daly and Mitchell,

2000; Ibañez, 2000; Zarin et al, 2001; Goulding et al., 2003), including anastomosing river channels (both fresh and brackish), floodplain lakes (várzea) affected by tides, levees, bays, brackish mangrove forests, tidal freshwater forests, terra firma forest, savannah, sand dunes, fresh and saltwater marshes, and tidal flats. Both estuary systems are affected by tides; however, the composition of the tidal water, whether saline or fresh, is controlled by the freshwater output from the mouth of the rivers. The Amazon River freshwater plume can reach up to 155km into the Atlantic Ocean during the wet season.

During the dry season or “low water period” of the Amazon, brackish water can reach up to 80km upstream and spread across the floodplain environments. Tidal effects raise the water level on the floodplain and its lakes twice a day all year round between 1.2-4 m near the coastline to over 300 km from the river mouth; at 800 km inland along the river, the tide is around 15cm in height (Anderson et al., 1999; Goulding et al., 2003). This is not unique to the Amazon - the tidal range is between 2.3-4m at the river mouth of the 78

Columbia River and can propagate upstream for nearly 300km during low river flows

(Dyer, 1973).

Lakes on the Amazonian floodplain experience small to significant changes in

water level between the dry and wet seasons (Lesack and Melack, 1995; Junk, 1997; Junk

and Piedade, 1997). On a time scale of 101 to 103 years, climate change is connected to

ocean-atmospheric processes and, in the case of the El Niño/Southern Oscillation cycle,

is represented by discrete 20-80cm thick sediment packages on the floodplains (Aalto et

al., 2003; Wang et al., 2004). Deposition on the Amazonian floodplain can range from

several cm to more than one meter per year, causing a succession of plant communities

over time as substrates change over time (Junk and Piedade, 1997; Worbes, 1997). Large-

scale erosional events, linked to tectonics, as well as sea level changes, are also part of

the Amazonian sediment record (Bigarella and Ferreira, 1985; Dickinson and Virji,

1987). Many features of the Amazon depositional system can be recognized in the

Pennsylvanian to Permian rocks of the northern Appalachian basin.

6.5 - Pennsylvanian/Permian Depositional Environment

The paleoenvironments of the Pennsylvanian/Permian cyclothems have been studied in detail by many workers, principally Ferm and Williams (1965), Donaldson

(1969; 1972; 1974; 1979); Ferm, 1970; Donaldson et al. (1985); Horne et al. (1978); and

as summarized by Martin (1998). The list of interpreted depositional environments covers

deltaic as well as estuarine types including: levees, crevasse splays, swamps, marshes,

lakes, channels (meandering, distributary), “river-dominated” bays or “sea lakes”/”bay 79

lakes” (estuaries?), distributary mouth bars, prodeltaic muds, paleosols, beaches, and

backbarrier lagoons.

The Conemaugh and Monongahela rocks are described as tide-dominated

delta/bay coastline (Donaldson, 1969; 1974) containing small lakes on the lower to upper

deltaic plain. Within the Allegheny Group, Ferm and Williams (1965) documented a marine invasion (transgression to “maximum inundation” to regression) within the lower portion of the Kittanning cyclothem across Ohio and Pennsylvania in a sequence- stratigraphic type of analysis. They postulated subsidence as the mechanism causing the transgression that formed a marine to brackish ‘embayment’, resembling an estuary, with its sediments interfingering with fluvio-lacustrine (deltaic) deposits.

Marine influence as storm deposits during the Pennsylvanian have been documented from back barrier lagoons within the Appalachian basin (Horne et al., 1978;

Staub and Cohen, 1979). Evidence for marine influence during tsunamis, storms, or tidal cycles within the nonmarine dominated cyclothems of the northern Appalachian basin is interpreted as the Spirorbis-bearing biomicrites/packstones within the Pennsylvanian lacustrine limestones (Eggleston, 1994; Weedman, 1994; Petzold, 1990; this study).

Other evidence includes eurypterids and Lingula brachiopods from the Dunkard Group

(Martin, 1998). Interestingly enough, detailed sedimentologic work on the depositional packages within the lacustrine limestones of the Alleghenian Upper Freeport cyclothem showed decimeter-scale packages of laminated micrites that are mudcracked to brecciated

(Weedman, 1988; 1994;Valero Garcés et al., 1994; 1997). This is similar in scale to the 80 sediment packages documented from the Amazonian floodplain based on the El

Niño/Southern Oscillation cycles.

Clearly, various sedimentary processes within a deltaic/estuarine complex are building cyclothemic sequences at different time scales as climate and tectonics change the configuration of the tidally-influenced Pennsylvanian coastline as well as the sea level through time. An important control defining freshwater to brackish to marine zones may have been the output of freshwater from the Carboniferous rivers. This is a significant factor controlling estuarine characteristics and evolution today (Schubel, 1971;

Dalrymple et al., 1992). Archer and Greb (1995) postulated an Amazon-scale drainage system for the Early Pennsylvanian in the US midcontinent based on the area covered by the paleodrainage of the Central Appalachian basin. An Amazon-like delta to estuary system is also likely for the Pennsylvanian rocks of the northern Appalachian basin based on similarities in the variety of preserved depositional environments through time. The restriction of marine Spirorbis worm tubes to specific layers within otherwise lacustrine units suggests that, similar to the Amazon River, episodic influx of brackish water onto the floodplain along the Pennsylvanian coast occurred.

The rocks of the upper Conemaugh and Monongahela Groups were mostly nonmarine in origin with episodic marine influence based on the presence of Spirorbis sp. layers as well as other brackish fossils, washover deposits (i.e., matrix-supported siliciclastic microbreccia in this study) and tidal sedimentary structures (Belt et al., 2002).

The major factors controlling the facies distribution of brackish to freshwater facies were 81 the freshwater output patterns of the Pennsylvanian rivers into the deltaic/estuarine coastal area, climate, and tectonic subsidence.

Further work is needed to further refine these marine incursion events in the limestones across the basin as well as in associated siliciclastic sequences. For example,

Spirorbis was found associated in clusters on large plant fragments and as isolated individuals within the freshwater shale of the lower Conemaugh Group in Ohio

(McComas and Mapes, 1988). Application of modern sedimentologic methods using estuarine and deltaic models as well as sequence stratigraphic analysis will clarify the coastal setting during the Pennsylvanian to Permian in the northern Appalachian basin. 82

Chapter 7: Conclusions

1. Eight facies were identified from the ten limestone units sampled at 52 localities

in the Conemaugh and Monongahela Groups of the northern Appalachian basin.

Facies types included: micrite (Type 1), ostracodal wackestone and packstone

(Type 2), intraclastic microbreccias (Type 3), mottled micrite/microbreccia (Type

4), Spirorbis-bearing biomicrite (Type 5), matrix-supported siliciciclastic

microbreccia with (Type 6A) and without (Type 6B) glauconite, wackestone

(Type 7), and packstone (Type 8). Types 6A, 7, and 8 were interpreted as marine

in origin. Types 1—4 were interpreted as freshwater facies. Types 5 and possibly

6B were interpreted as brackish or influenced by marine waters.

2. Spirorbis, worm tubes of a serpulid worm, is grown by a marine organism that

cannot live in freshwater. Their presence in discrete layers within lacustrine

limestones of the Pennsylvanian cyclothems of the northern Appalachian basin

indicate that marine incursions occurred on a time scale less than a cyclothemic

cycle. Probable mechanisms of deposition of worm tubes inland include tidal or

seasonal changes of seawater influx onto floodplains as well as catastrophic

deposition due to hurricanes or even tsunamis. These processes are corroborated

with modern depositional processes associated with estuaries, deltas, and coastal

lakes today. 83

3. Evidence for marine incursion into the sediments of the Pennsylvanian to Permian

cyclothems of the northern Appalachian basin is not limited to that of Spirorbis

within the limestones. Possible tidal bundles in the freshwater Upper Freeport

shales (Belt et al., 2002) of the Allegheny Group as well as the presence of

Lingula brachiopod shells and a eurypterid from the Dunkard Group (Scott, 1971;

Martin, 1998) indicate marine influence as well. More work is needed to better

refine the pattern of limestone facies across the basin as well as fossil distribution

within the associated siliciclastics of the cyclothems. 84

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Appendix A – Sample Localities

WV50-1 Unit: Benwood/Arnoldsburg Limestone Source: Fedorko et al., 1979. p. 58, mileage total 86.1. Location: US-50 westbound lane, just past Smithburg, Doddridge County WV. GPS Reading: E5235842/N4348460 Sampled By: C. Cassle & Z. Wessel. Thin section samples were collected from three limestone beds separated by shales and paleosols. Sample 1A was collected from the lower limestone, 1B was collected from the middle limestone, and 1C (bottom) and 1D (top) were collected from the upper limestone.

110

WV50-2 Unit: Benwood/Arnoldsburg Limestone Source: Fedorko et al., 1979. p. 58, mileage total 101.1. Location: US-50 eastbound lane, at the junction with Wolfsummit Road and Sycamore Road. GPS Reading: E546140/N4347583 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from a 2m thick limestone bed, 7.5 m above road level. Sample 2T was collected from the top of the bed and 2B was collected from the bottom.

111

WV50-3 Unit: Clarksburg Limestone Source: Fedorko et al., 1979. p. 59, mileage total 105.0. Location: US-50 eastbound lane, 0.5 miles before intersection with Wilsonburg Road. GPS Reading: E552801/N4348418 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from three limestone beds separated by shales. The bottom limestone crops out 2m above road level. Sample 3A was collected from the base of the bottom bed, sample 3B was collected from the top of the bottom bed, sample 3C was collected from the middle bed, and sample 3D was collected from the top bed.

112

WV50-4

Unit: Benwood/Arnoldsburg Limestone Source: Fedorko et al., 1979. p. 61, mileage total 114.3. Location: US-50 eastbound lane, 0.5 miles before I-79 exit. GPS Reading: E560545/N4347487 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from two limestone beds separated by shale. Sample 4T was collected from the top bed, sample 4M was collected from the bottom bed, and sample OOP was collected from float. 113

WV79-1 Unit: Ames Limestone Source: Fonner, R.F. and Fedorko, N., 1985. Section 12. Location: I-79 southbound lane, milepost 113.2-113.4. GPS Reading: E559423/N4339087 Sampled By: C. Cassle & Z. Wessel Thin section sample was collected from a 8cm thick limestone bed 2m above road level.

114

WV79-2 Unit: Clarksburg Limestone Source: Fonner, R.F. and Fedorko, N., 1985. Section 10. Location: I-70 northbound lane, milepost 112.4-112.5. GPS Reading: E558252/N4338144 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from a single limestone bed approximately 6m above road level. Sample T was collected from the top, sample m was collected from the middle, and sample B was collected from the bottom.

115

WV79-3 Unit: Ames Limestone and Ewing Limestone Source: Fonner, R.F. and Fedorko, N., 1985. Section 14. Location: I-79 northbound lane, milepost 115.6. GPS Reading: E560723/N4342355 Sampled By: C. Cassle & Z. Wessel Thin section sample A was collected from a massive limestone bed (Ames) approximately 12m above road level, and sample E was collected from a nodular layer (Ewing) within shale 3m above road level.

WV79-4 Unit: Redstone Limestone Source: Cecil, C.B. and Eble, C.E., 1992. Stop 6, p. 36. Location: I-79 southbound lane, milepost 72.8. GPS Reading: E528403/N4291965 Sampled By: C. Cassle & Z. Wessel Thin section sample OOP was collected from float due to poor exposure. 116

WV79-5 Unit: Clarksburg Limestone Source: Fonner, R.F. and Fedorko, N., 1985. Section 26. Location: I-79 northbound lane at the north end of Exit 125. GPS Reading: E567183/N4355069 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from a single limestone bed approximately 15m above road level. Sample T was collected from the top of the bed and sample B was collected from the bottom of the bed.

117

WVI68-1 Unit: Clarksburg Limestone Source: Cecil, C.B. and Eble, C.E., 1992. Stop 3, p. 17. Location: I-68 westbound lane, milepost 4.0 just west of Exit 4 (Sabraton). GPS Reading: E592176/N4384815 Sampled By: C. Cassle & Z. Wessel Thin section sample was collected from the base of a single limestone bed approximately 10m above road level.

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WV79-6 Units: Redstone Limestone and Pittsburgh Limestone Source: Cecil, C.B. and Eble, C.E., 1992. Stop 4, p. 22. Location: North side of the Morgantown Mall complex near I-79, Exit 152. GPS Reading: E592176/N4384815 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from two separate limestone beds, the lower bed is at road level and the upper bed resides just below a coal approximately 30m above road level. Samples A (base), B (middle), and C (top) were collected from the lower bed (Pittsburgh). Samples L (base), M (middle), and T (top) were collected from the upper bed (Redstone).

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PA-5

Unit: Benwood/Arnoldsburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Along the west bank of Chartiers Creek southwest of the Washington Fairgrounds at Arden, Strabane Township, Washington County, PA. GPS Reading: E586234/N4386377 Sampled By: C. Cassle & Z. Wessel Thin section samples were collected from three limestone beds along the west bank of Chartiers Creek. Sample 2 was collected from the bottom bed at stream level. Sample 1 was collected from the middle bed, and samples B (base) and A (top) were collected from the upper bed.

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PA-6 Unit: Benwood/Arnoldsburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Southwest corner of intersection between US-19 (Washington Road) and Gilkeson Road (Yellow Belt), behind the Ground Round restaurant in Mount Lebanon, PA. GPS Reading: E580585/N4467409 Sampled By: C. Cassle & Z. Wessel Thin section sample A was collected from a massive limestone bed 3m above road level. Sample B was collected from the next massive limestone, 1m above sample A. Samples C-B (base) and C-A (top) were collected from a limestone bed 10cm above sample B. Samples D-B (base) and D-A (top) were collected from a massive limestone 6cm above sample C-A.

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PA-4 Unit: Benwood/Arnoldsburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Southeast side of PA-50, 2 miles past intersection with I-79 at Bridgeville Exit. GPS Reading: E571746/N4465973 Sampled By: C. Cassle & Z. Wessel Thin section sample 2 was collected from a massive limestone directly beneath a 4m sandstone at the top of the outcrop. Samples 1A (top) and 1B (base) were collected from the next massive limestone beneath sample 2 (separated by 15cm of shale). Sample 3 was collected from the next massive limestone beneath sample 1 (separated by 2.5m shale). Samples 4A (top) and 4B (base) were collected from the next massive limestone beneath sample 3 (separated by 20cm of shale). Samples 5T-A (top), 5T-B (middle), and 5B (bottom) were collected from the next massive limestone beneath sample 4 (separated by 1m shale). Sample 6 was sampled from the next massive limestone beneath sample 5 (separated by 2m shale, directly above cover).

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PA-7 Unit: Benwood/Arnoldsburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Northeast side of Old Clairton Road in Option, 0.3 miles northwest of the intersection with Streets Run Road, behind brickyard. GPS Reading: E586947/N4466920 Sampled By: C. Cassle & Z. Wessel Thin section samples B (base), M (middle), and T (top) were collected from a massive limestone bed above 2.5m of cover, behind brickyard.

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PA-13 Unit: Clarksburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: East side of PA-906, 0.5 miles south of Webster, Westmoreland County PA (east side of Monongahela River). GPS Reading: E597787/N4446868 Sampled By: C. Cassle & Z. Wessel Thin section samples M (middle) and B (bottom) were collected from a single massive limestone bed approximately 20 meters above road level, within a 40-50m thick black shale bed.

124

PA-36 Unit: Nadine Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: North side of PA-48, 0.4 miles east of intersection with PA-148, McKeesport PA. GPS Reading: E599202/N4464169 Sampled By: C. Cassle & Z. Wessel Thin section sample was collected from a 5cm thick limestone bed, directly atop a 15cm coal bed (approximately 3m above road level).

125

PA-23 Unit: Ames Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: West side of Braddock Avenue, 0.35 miles south of intersection with Forbes Road, hillside behind Frick Park tennis courts, Edgewood/Wilkinsburg area of Pittsburgh PA. GPS Reading: E593533/N4476650 Sampled By: C. Cassle & Z. Wessel Thin section sample collected from a crinoidal limestone bed approximately 10m down hillside behind tennis courts.

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PA-11 Unit: Clarksburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: South side of US-22, 3.3 miles east of Allegheny/Westmoreland County Line, between Murraysville and Delmont, PA. GPS Reading: E614928/N4474668 Sampled By: C. Cassle & Z. Wessel. See Figure 25, p. 58 for thin section collection sites.

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PA-21 Unit: Ames Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: North side of US-22 in Monroeville, PA. Just east of the junction with PA-376 (across from Spitzer Auto). GPS Reading: E607088/N4477083 Sampled By: C. Cassle & Z. Wessel Thin section samples 1 (top) and 2 (bottom) were collected from a massive limestone bed 0.75m above road level.

128

PA-22 Unit: Ames Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: North side of PA-130, 1 mile west of Pitcairn, PA. GPS Reading: E602814/N4472493 Sampled By: C. Cassle & Z. Wessel Thin section sample 3 was collected from a massive limestone bed, 4m above road level. Sample 2 was collected from a massive limestone 45cm above sample 3 (separated by shale). Sample 1 was collected from a massive limestone directly above sample 2 (separated by a thin ~1-2cm thick shale).

129

PA-35 Unit: Nadine Limestone (Type Locality) Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Allegheny River Boulevard opposite Nadine Pumping Station, just before the intersection with Nadine Road on the south side of Allegheny River, approximately 1.5 miles east of Highland Park Bridge. GPS Reading: E595318/N4481590 Sampled By: C. Cassle & Z. Wessel Thin section sample collected from a 10-15cm nodular layer within a black shale, 0.5m above road level.

130

PA-19 Unit: Ames Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: North side of PA-28 west, at the Etna Exit. GPS Reading: E589942/N4483240 Sampled By: C. Cassle & Z. Wessel Thin section sample T (top), M-A (upper middle), M-B (lower middle), and B (base) were collected from a massive limestone approximately 10m above road level.

131

PA-38 Unit: Pinecreek Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Fall Run Park, Shaler Township, Allegheny County, PA. Fall Run Road intersects PA-8, 3 miles north of intersection between PA-8 and PA-28, at Etna. The outcrop is located 600 feet past the upper falls in the creek bed. GPS Reading: E589257/N4487268 Sampled By: C. Cassle & Z. Wessel Thin section sample U-2 was collected from a massive limestone beneath water level in the creek bed. Sample U-1 was collected directly above sample U-2, slightly out of water.

132

PA-47 Unit: Lower Brush Creek Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Fall Run Park, Shaler Township, Allegheny County, PA. Fall Run Road intersects PA-8, 3 miles north of intersection between PA-8 and PA-28, at Etna. The outcrop is located in the bed of Fall Run about 1200 feet northeast of the lower parking circle. GPS Reading: E589257/N4487268 Sampled By: C. Cassle & Z. Wessel Thin section samples L-2 (base) and L-1 (top) were collected from a massive limestone unit 1.5m above creek bed.

133

PA-16 Unit: Ames Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: East side of I-279, 2.2 miles north of the Camp Horn Road Exit. GPS Reading: E577520/N4489694 Sampled By: C. Cassle & Z. Wessel Thin section sample was collected from the top of a massive limestone, 3m above road level.

134

PA-12 Unit: Clarksburg Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: I-79 south, 1.5 miles south of the Wexford Exit and just north of the I-79/I-279 split. GPS Reading: E576340/N44993530 Sampled By: C. Cassle & Z. Wessel Thin section sample 5A (top) and 5B (base) were collected from a massive limestone approximately 2m above road level. Samples 3 (top), 4A (middle), and 4B (base) were collected from a 1m thick limestone directly atop sample 5. Sample 2 was collected from a 15cm thick limestone, 1m above sample 3 (separated by shale). Sample 1 was collected from a nodular layer within shale, 1.5-2m above sample 2.

135

PA-45 Unit: Pine Creek Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Along PA-28 bypass around Kittanning, Armstrong County, PA. Just past PA-28/PA-422E intersection. Sampled By: C. Cassle & Z. Wessel Thin section sample 3 was collected from a massive limestone 2m above road level. Sample 2 was collected from a 1m nodular layer directly above sample 3. Sample 1 was collected from a 30cm massive limestone directly above the nodular layer.

136

PA-46 Unit: Pine Creek Limestone Source: John Harper, Pennsylvania Geological Survey, personal communication. Location: Outcrops on unnamed side road paralleling Crooked Creek, 700 feet from intersection with US-422, 0.5 miles northwest of Shelocta, Indiana County, PA. GPS Reading: E642819/N4502301 Sampled By: C. Cassle & Z. Wessel Thin section sample was collected from a massive limestone approximately 2m above road level.

137

K-44 Unit: Two Mile Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: WV-27 (Edens Fork Road) Charleston, WV. Just off I-77 Exit 106. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples A (lower 20cm), B (middle 60cm), and C (upper 10cm) were collected from a massive limestone just above a red paleosol. Samples D (lower 20cm) and E (upper 10cm) were sampled down the road from the same unit as samples A,B, and C.

K-43 Unit: Two Mile Limestone (Type Section) Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: WV-27 (Edens Fork Road) west of intersection with I-77, 0.5 miles west of Guthrie, WV. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples A-E were sampled in sequence (from base to top; A=bottom, E=top) from a massive limestone on top of a red paleosols, approximately 10m above road level..

K-50 Unit: Two Mile Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Southwest side of Route 622 (WV-21), 0.25 miles south of Guthrie, WV (by Allen’s Auto Recycling). Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section sample collected from a massive limestone beneath a nodular layer.

138

K-49

Unit: Unnamed limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along I-77 southbound lane 1 mile south of Exit 106. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples A (bottom) and B (top) were sampled from a 50cm thick massive limestone, cropping out 24m above the Two Mile limestone.

K-48 Unit: Two Mile Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along I-77 northbound lane, 1 mile north of I-77/I-79 split. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples 1 (bottom), 2 (40cm from top), and 3 (top), were collected from a 1.2 meter interval of interbedded claystone and massive limestone.

L-3 Unit: Two Mile Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: WV-119, 0.25 miles east of Priestly, Lincoln County, WV. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples A-1 (upper) and A-2 (lower) were sampled from a massive limestone bed approximately 10-15m above road level and samples A-3 (upper) and A-4 (lower ) were sampled from a massive limestone 0.75m above samples A-1 and A-2 (separated by mudstone).

139

L-7 Unit: Lower Brush Creek Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: WV-119, 0.8 miles south of Priestly, Lincoln County, WV. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples 1 (upper) and 2 (lower) were sampled from a 1m thick limestone.

KY-4 Unit: Lower Brush Creek Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along west side of route 23 at milepost 9.5, 1 mile south of I-64, and 0.1 miles south of intersection with Campbell Run Road, Boyd County, KY. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section sample collected from a nodular layer within shales and mudstones, 1.5m above a coal.

140

KY-3 Unit: Upper Brush Creek Limestone Source: Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: KY-23 south, 246 feet north of Campbells Run Road. Sampled By: C. Cassle, E. H. Gierlowski-Kordesch & R. Martino Thin section samples C (middle), B (bottom), and A (top) were collected from a siliceous-quartz silt limestone, approximately 25m above road level.

141

KY-21 Unit: Upper Brush Creek Limestone & Lower Brush Creek Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along KY-23, 2 miles west of Louisa Kentucky, and just past intersection of KY-23 and KY-3. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples B1 (top), B2 (middle), and B3 (bottom) were collected from the Upper Brush Creek, and sample A was collected from the Lower Brush Creek.

KY-26 Unit: Cambridge Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along the north side of I-64, east of exit 185. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section sample KY-26 was sampled from a massive limestone 5m above road level and samples B-1 (top) and B-2 (bottom) were sampled from an unnamed nodular unit above.

KY-27 Unit: Lower Brush Creek Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along the north side of I-64, 0.25 miles east of exit 185. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section sample collected out of place due to slumping.

142

KY-30 Unit: Lower Brush Creek Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: Along KY-67 (Industrial Parkway), just off I-64 Exit 179. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section collected from a massive limestone approximately 30m above road level.

KY-31 Unit: Lower Brush Creek Limestone Source: Ron Martino, Marshall University, Geology Department, personal communication. Location: KY-180, 0.25 miles south of I-64 Exit 185, behind the Flying-J truck stop. Sampled By: C. Cassle, E.H. Gierlowski-Kordesch & R. Martino Thin section samples U (upper) and L (lower) were sampled from a massive limestone approximately 30m above road level.

143

JG-1 Unit: Benwood/Arnoldsburg Limestone Source: Jacob M. Glascock, Ohio University Department of Geological Sciences, Senior Thesis. Location: Along Hook Lake loop road, just off OH-83 within the American Electric Power Recreation Land Park, Morgan County, OH. Sampled By: J. Glascock

JG-2 Unit: Benwood/Arnoldsburg Limestone Source: Jacob M. Glascock, Ohio University Department of Geological Sciences, Senior Thesis. Location: Along T-944, 2 miles west of OH-83 near the Sand Hollow camping area, within the American Electric Power Recreation Land Park, Morgan County, OH. Sampled By: J. Glascock

R-32c Unit: Pittsburgh Limestone Source: Kevin D. Kallini, Ohio University Department of Geological Sciences, Masters Thesis. Location: Along US-50, 1 mile east of OH-622 (at East Canaan Church), Rome Township, Athens County, Stewart OH, Quadrangle. Sampled By: K. Kallini

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CN-16 Unit: Pittsburgh Limestone Source: Kevin D. Kallini, Ohio University Department of Geological Sciences, Masters Thesis. Location: Along US-50, 1 mile east of OH-690. Canaan Township, Athens County, Stewart OH, Quadrangle. GPS Reading: E2112371.84/N482582.42 Sampled By: K. Kallini

CN-11 Unit: Pittsburgh Limestone Source: Kevin D. Kallini, Ohio University Department of Geological Sciences, Masters Thesis. Location: Along the east side of OH-690, 1 mile south of Rt. 34 (Mush Run Road). GPS Reading: E2115472/N491554 Sampled By: K. Kallini

CN-5a Unit: Pittsburgh Limestone Source: Kevin D. Kallini, Ohio University Department of Geological Sciences, Masters Thesis. Location: Along Canaan Township Road 221, 0.25 miles north of Rt. 34 (Mush Run Road). GPS Reading: E2120366.92/N493050.18 Sampled By: K. Kallini

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CR-23 Unit: Benwood/Arnoldsburg Limestone Source: Kevin D. Kallini, Ohio University Department of Geological Sciences, Masters Thesis. Location: Along OH-42, 0.5 miles west of US-50. GPS Reading: E2136261.57/N456488.28 Sampled By: K. Kallini

B-31a Unit: Benwood/Arnoldsburg Limestone Source: Kevin D. Kallini, Ohio University Department of Geological Sciences, Masters Thesis. Location: Along the east side of Rt. 48, 1 mile north of the intersection with RT. 48, Bern Township, Athens County, OH. GPS Reading: E2127227.02/N499197.13 Sampled By: K. Kallini

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Appendix B – Photomicrographs of the 174 studied limestone samples.

**Note: Instances where two numbers appear with one in parenthesis: the first number is the sample locality number, and the number in parenthesis is the sample (thin section) number. All sample localities are detailed in Appendix A.

B-31a (48), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse ostracode fossils and spar-filled and clay-lined tubules present.

CN-5a (T-221), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse pyritized ostracode fossils and spar-filled and clay-lined tubules present.

147

CN-11 (99-L-22), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse ostracode fossils, plant fragments, and spar-filled voids present.

CN-16 (690B/A), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse ostracode fossils, plant fragments, and pyrite present.

148

CN-16 (99-L-21), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse ostracode fossils and spar-filled voids present.

CR-23 (T-108/42), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in a micrite matrix. Planar spar-filled void spaces present. 149

JG-1 (2), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 6b – Intraclastic matrix-supported siliciclastic microbreccia. Consists of 40-80% regular to subangular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix, along with very fine sand- to pebble-sized, angular to subangular, micritic intraclasts.

JG-1 (7), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 6B – Intraclastic matrix-supported siliciclastic microbreccia. Consists of 40-80% regular to subangular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix, along with very fine sand- to pebble-sized, angular to subangular, micritic intraclasts. 150

JG-1 (8), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 6B – Intraclastic matrix-supported siliciclastic microbreccia. Consists of ~60% regular to subangular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix in addition to very fine sand- to pebble-sized, angular to subangular, micritic intraclasts.

JG-1 (9), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 6B – Intraclastic matrix-supported siliciclastic microbreccia. Consists of ~50% regular to subangular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix along with very fine sand- to pebble-sized, angular to subangular, micritic intraclasts. 151

JG-1 (10), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 6B – Intraclastic matrix-supported siliciclastic microbreccia. Consists of ~30% regular to subangular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix with very fine sand- to pebble-sized, angular to subangular, micritic intraclasts.

JG-1 (13B), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. 152

JG-1 (15A), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 & 3 – Ostracodal wackestone to packstone and intraclastic microbreccia. Consists of ~20% ostracode fossils and lithorelict intraclasts floating in a micritic matrix.

JG-1 (18), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar void spaces, clay-lined tubules, and ostracodes. 153

JG-1 (21), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~25% ostracode shells (intact or disarticulated carapaces).

JG-1 (23), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~30% ostracode shells (intact or disarticulated carapaces)

154

JG-1 (24), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite.

JG-1 (25), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 & 3 – Ostracodal wackestone to packstone and intraclastic microbreccia. Consists of micritic matrix containing ~15% ostracode shells (intact or disarticulated carapaces) and lithorelict intraclasts floating in a micritic matrix.

155

JG-1 (26), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~30% ostracode shells (intact or disarticulated carapaces)

JG-1 (27), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Features include: spar- filled planar void spaces, clay-lined tubules, ostracodes, and peloidal structures.

156

JG-2 (40), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains sparse charophytes and spar-filled fractures.

JG-2 (42), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 3 – Micrite and Intraclastic microbreccia. Consists primarily of micritic matrix with some lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Features include: spar-filled planar void spaces, clay-lined tubules, ostracodes, charophytes, and peloidal structures.

157

JG-2 (43C), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common feature include: spar-filled planar void spaces, clay-lined tubules, ostracodes, and detrital quartz grains.

JG-2 (46), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common feature include: spar-filled planar void spaces, clay-lined tubules, ostracodes, and peloidal structures.

158

JG-2 (50), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 3 – Micrite and intraclastic microbreccia. Consists primarily of micritic matrix with relict laminations, and some lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common feature include: spar- filled planar void spaces, clay-lined tubules, ostracodes, and charophytes.

JG-2 (101), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common feature include: spar-filled, planar/circum-granular void spaces, clay-lined tubules, ostracodes, and peloidal structures.

159

JG-2 (102), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Some spar-filled voids, ostracodes, and charophytes present.

JG-2 (103), Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Some spar-filled voids, ostracodes, and charophytes present.

160

JP-KY-26, unnamed limestone above the Cambridge limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Rare spar-filled voids, ostracodes, and charophytes present.

K-43A, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments, individual tubes, or small clusters in a micritic matrix. Tubes are commonly filled with sparry cement and are associated with ostracode and charophyte fragments and carbonate microbreccia and intraclasts.

161

K-43B, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments and individual tubes. Tubes are filled with sparry cement and associated with ostracode fragments, and carbonate microbreccia and intraclasts.

K-43C, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 3 – Micrite and Intraclastic microbreccia. Consists primarily of micritic matrix with some lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Features include: spar-filled planar void spaces, clay-lined tubules, and ostracodes.

162

K-43D, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 3 – Micrite and Intraclastic microbreccia. Consists primarily of micritic matrix with some lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Features include: spar-filled planar void spaces, clay-lined tubules, and ostracodes.

K-43E, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tube (~1mm in diameter and length) floats in micritic matrix and filled with sparry cement. Tube is also associated with carbonate microbreccia and intraclasts.

163

K-44A-1, Two Mile limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia, Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar to circumgranular void spaces, clay-lined tubules, and ostracodes.

K-44A-2, Two Mile limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, and ostracodes.

164

K-44A-3, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, and ostracodes.

K-44B, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, and spar-filled ostracodes.

165

K-44C, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse ostracodes and spar-filled void spaces.

K-44D, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments and individual tubes, in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode fragments and carbonate microbreccia and intraclasts.

166

K-48-1, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common feature include: spar- filled planar void spaces, clay-lined tubules, and ostracodes.

K-48-2, Two Mile limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tube is filled with sparry cement and with associated ostracode fragments and carbonate microbreccia and intraclasts.

167

K-48-3, Two Mile limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite, Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode fragments.

K-49A, unnamed limestone above the Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments, individual tubes, or small clusters in a micritic matrix. Tubes are filled with sparry cement and associated with ostracode and charophyte fragments.

168

K-49B, unnamed limestone above the Two Mile limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sparse ostracodes, relict lamination, and pyrite present.

K-50, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Pyrite present.

169

KY-3A, Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 6A – Matrix-supported siliciclastic microbreccia. Consists of ~40% regular to sub-angular quartz and chert grains floating in a micritic matrix. Siliciclastic grains range in size from very fine sand to very coarse sand. Glauconite is present.

KY-3B, Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 & 6A – Wackestone and matrix-supported siliciclastic microbreccia. Contains ~50% allochems surrounded by a micritic matrix. Micritic matrix contains ~10% floating angular to subangular quartz grains. Fossil content is highly varied: brachiopods, bivalves, and echinoderms.

170

KY-3C, Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 6A – Matrix-supported siliciclastic microbreccia. Consists of ~60% regular to sub-angular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix. Siliciclastic grains range in size from very fine sand to very coarse sand.

KY-4, Lower Brush Creek limestone (plane polarized, FOV = 5.5mm). Facies Type 7 to 8 – Wackestone to packstone. Contains varying amounts of allochems (surrounded by a micritic matrix grading into grain contact with little matrix). Fossil content is highly varied: brachiopods, bivalves, echinoderms, and foraminifera.

171

KY-21A, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 8 – Packstone. Contains a self supporting framework of fossils. Fossil content is highly varied: brachiopods, bivalves, echinoderms, and foraminifera.

KY-21B-1, Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 6A – Matrix-supported siliciclastic microbreccia. Consists of ~80% regular to sub- angular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix. Siliciclastic grains range in size from very fine sand to very coarse sand. Very fine- grained glauconite is present. 172

KY-21B-2, Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 & 6A – Wackestone and matrix-supported siliciclastic microbreccia. Contains ~50% allochems surrounded by a micritic matrix. Micrite matrix contains ~15% floating angular to subangular quartz grains. Fossil content primarily consists of echinoderms and bivalves.

KY-21B-3, Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 6A – Matrix-supported siliciclastic microbreccia. Consists of ~70% regular to sub- angular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix. Siliciclastic grains range in size from very fine sand to very coarse sand.

173

KY-26, Cambridge limestone (cross polarized, FOV = 5.5mm). Facies Type 8 – Packstone. Consists of a self-supporting framework of fossils. Fossil content includes bivalves, echinoderms, and foraminifera. Some very fine quartz grains also present.

KY-26B-1, unnamed limestone above the Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments and individual tubes, in a micritic matrix. Tubes are filled with sparry cement.

174

KY-26B-2, unnamed limestone above the Upper Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments, individual tubes, or small clusters in a micritic matrix. Tubes are filled with sparry cement and micrite, and are associated with ostracode fragments, and carbonate microbreccia and intraclasts.

KY-27, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 8 – Packstone. Contains a self supporting framework of fossils. Fossil content is highly varied: bryozoans, bivalves, echinoderms, foraminifera, and trilobites.

175

KY-30, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 8 – Packstone. Contains a self-supporting framework of fossils. Fossil content is highly varied: brachiopods, bivalves, echinoderms, foraminifera, and trilobites.

KY-31L, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~50% allochems surrounded by a micritic matrix. Fossil content is highly varied: bryozoans, bivalves, gastropods, echinoderms, foraminifera.

176

KY-31U, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~20% allochems surrounded by a micritic matrix. Fossil content includes bryozoans and bivalves.

L3A-1, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~30% ostracode shells (intact or disarticulated carapaces).

177

L3A-2, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes in cross section (~1mm in diameter) float in micritic matrix. Tubes are filled with sparry cement.

L3A-3, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode fragments. 178

L3A-4, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as a small cluster in micritic matrix. Tubes are filled with sparry cement and are associated with ostracode fragments.

L7-1, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments and individual tubes in a micritic matrix. Tubes are filled with sparry cement and micrite, and are associated with ostracode fragments.

179

L7-2, Two Mile limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis- bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments, individual tubes, or small clusters in a micritic matrix. Tubes are commonly filled with sparry cement and are associated with ostracode and charophyte fragments, and carbonate microbreccia and intraclasts.

PA-4-1A, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble.

180

PA-4-1B, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled void spaces, and ostracodes.

PA-4-2, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled circumgranular void spaces.

181

PA-4-3, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled planar void spaces and clay-lined tubules. Sample also exhibits red- orange-yellow mottling.

PA-4-4A, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled planar to circumgranular void spaces.

182

PA-4-4B, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 3 – Micrite and Intraclastic microbreccia. Consists primarily of micrite with some lithorelict intraclasts floating in matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled planar void spaces, clay-lined tubules, and a spar-filled ostracode.

PA-4-5B, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with ostracodes.

183

PA-4-5T-A, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled void spaces, and ostracodes.

PA-4-5T-B, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with ostracode fragments.

184

PA-4-6A, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains some disarticulated ostracode carapaces.

PA-4-6B, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 2 – Micrite and ostracodal wackestone to packstone. Sample transitions from micritic intervals with few fossils to dense ostracode layers.

185

PA-5-1, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled circumgranular voids and clay-lined tubules,.

PA-5-2, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: clay-lined tubules, ostracode fragments, and red-orange-yellow mottling.

186

PA-5-A, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite.

PA-5-B, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite.

187

PA-6-A, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Some very fine quartz grains are present.

PA-6-B

PA-6-B, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite.

188

PA-6C-A, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite.

PA-6C-B

PA-6C-B, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of micritic-peloidal intraclasts surrounded by spar-filled void spaces.

189

PA-6D-A, Benwood/Arnoldsburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~70% disarticulated ostracode carapaces.

PA-6D-B, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 1 & 2 – Micrite and Ostracodal wackestone to packstone. Sample transitions from mostly micrite to an ostracodal wackestone (~30% disarticulated carapaces).

190

PA-7B, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces and clay-lined tubules.

PA-7M, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains some ostracode shell fragments.

191

PA-7T, Benwood/Arnoldsburg limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains ostracode shells and floating lithorelict intraclasts.

PA-11-1, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 & 2 – Micrite and Ostracodal wackestone to packstone. Contains alternating layers of micrite and ostracodal wackestone (~30% disarticulated carapaces).

192

PA-11-2, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode fragments.

PA-11-3, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments, individual tubes, in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode and charophyte fragments.

193

PA-11-4, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled circumgranular void spaces, and ostracode fragments.

PA-11-5, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as small clusters in a micritic matrix. Tubes are filled with sparry cement and micrite, and are associated with ostracode and charophyte fragments, and carbonate microbreccia and intraclasts.

194

PA-11-6, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled circumgranular voids and clay-lined tubules.

PA-12-1, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite.

195

PA-12-2, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar void spaces and orange-red-yellow mottling.

PA-12-3, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 5 & 6B – Spirorbis-bearing biomicrite and intraclastic matrix-supported siliciclastic microbreccia. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix containing ~25% quartz grains. Tubes are filled with sparry cement and micrite, and are associated with ostracode fragments and carbonate microbreccia and intraclasts.

196

PA-12-4A, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 & 6B – Spirorbis-bearing biomicrite and intraclastic matrix-supported siliciclastic microbreccia. Spirorbis worm tubes (~1mm in diameter and length) float as fragments and individual tubes, in a micritic matrix containing ~25% quartz grains. Tubes are filled with sparry cement and are associated with ostracodes, carbonate microbreccia and intraclasts.

PA-12-4B, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as individual tubes or small clusters in a micritic matrix with rare quartz grains. Tubes are filled with sparry cement and are associated with ostracodes and carbonate microbreccia and intraclasts.

197

PA-12-5A, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains rare clay-lined tubules, spar-filled microfractures, and spar-filled charophyte fossils.

PA-12-5B, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, and ostracodes.

198

PA-13B, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains rare ostracode fossils and quartz grains.

PA-13M, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains rare ostracode fossils and quartz grains.

199

PA-16-1, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~25% allochems surrounded by a micritic matrix. Fossil content primarily consists of echinoderms and trilobites.

PA-19B, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~40% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods, echinoderms, and foraminifera.

200

PA-19M-A, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~40% allochems surrounded by a micritic matrix. Fossil content includes bivalves, echinoderms, and foraminifera.

PA-19M-B, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~30% allochems surrounded by a micritic matrix. Fossil content includes brachiopods, foraminifera, and ostracodes.

201

PA-19T, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~35% allochems surrounded by a micritic matrix. Fossil content includes brachiopods, bivalves, foraminifera, and trilobites.

PA-21-1, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~70% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods and trilobites.

202

PA-21-2, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~75% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods, bivalves, and foraminifera.

PA-22-1, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~50% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods and foraminifera.

203

PA-22-2, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~40% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods, echinoderms, and foraminifera.

PA-22-3, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains 30% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods, echinoderms, and foraminifera.

204

PA-23, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~45% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods and echinoderms.

PA-35, Nadine limestone (cross polarized, FOV = 5.5mm). Facies Type 6A – Matrix- supported siliciclastic microbreccia. Consists of ~40% regular to sub-angular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix. Siliciclastic grains range in size from very fine sand to very coarse sand. Glauconite is present.

205

PA-36, Nadine limestone (cross polarized, FOV = 5.5mm). Facies Type 8 – Packstone. Contains a self supporting framework of fossils. Fossil content primarily consists of brachiopods and echinoderms. Rare quartz grains present.

PA-38-U1, Pine Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~35% allochems surrounded by a micritic matrix. Fossil content primarily consists of bivalves, echinoderms, and foraminifera. Rare quartz grains also present.

206

PA-38-U2, Pine Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 & 6A – Wackestone and matrix-supported siliciclastic microbreccia. Contains 60% allochems surrounded by a micritic matrix. Fossil content primarily consists of bryozoans and brachiopods. Sample also contains ~20% quartz grains.

PA-45-1, Pine Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~20% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods, bivalves, and echinoderms.

207

PA-45-2, Pine Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~60% allochems surrounded by a micritic matrix. Fossil content primarily consists of bivalves, echinoderms, and algae.

PA-45-3, Pine Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 6A – Matrix-supported siliciclastic microbreccia. Consists of ~40% regular to sub-angular quartz, chert, microcline, and plagioclase grains floating in a micritic matrix. Siliciclastic grains range in size from very fine sand to very coarse sand.

208

PA-46, Pine Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~50% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods and echinoderms.

PA-47-L1, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 & 6A – Wackestone and Matrix-supported siliciclastic microbreccia. Contains >10% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods, echinoderms, and foraminifera. Sample also contains ~10% fine-grained quartz grains.

209

PA-47-L2, Lower Brush Creek limestone (cross polarized, FOV = 5.5mm). Facies Type 7 & 6A – Wackestone and Matrix-supported siliciclastic microbreccia. Contains ~40% allochems surrounded by a micritic matrix. Fossil content primarily consists of bryozoans, bivalves, echinoderms, and foraminifera. Sample also contains ~20% fine- grained quartz grains.

R-32c (FP-2), Pittsburgh limestone (plane polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Rare ostracode shell fragments present.

210

R-32c (FP-3), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Sample contains ostracode shell fragments and one spar-filled articulated ostracode.

R-32C (FP-4), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled circumgranular void spaces, clay-lined tubules, and ostracodes.

211

R-32C (FP-5), Pittsburgh limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar void spaces, clay-lined tubules, and ostracodes. Red-orange-yellow mottling also present.

R-32C (FP-6A), Pittsburgh limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar void spaces, clay-lined tubules, and ostracodes. Red-orange-yellow mottling also present.

212

R-32C (FP-7), Pittsburgh limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments and individual tubes in a micritic matrix. Tubes are filled with micrite and are associated with ostracode fragments, and carbonate microbreccia and intraclasts

R-32C (FP-8), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~40% ostracode shells (intact or disarticulated carapaces) with sparry cement.

213

R-32C (FP-9), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains clay-lined tubules with sparry cement.

R-32C (FP-10), Pittsburgh Limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains ostracode fragments and some floating lithoclasts.

214

R-32C (FP-11), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains some lithoclasts and ostracode shell fragments.

R-32C (FP-13L), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains rare ostracode shell fragments.

215

R-32C (FP-13U), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains some lithoclasts and ostracode shell fragments.

R-32C (FP-18), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, and ostracode shell fragments.

216

R-32C (FP-19), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains some lithorelict intraclasts and ostracode shell fragments.

R-32C (FP-20), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains some lithorelict intraclasts and ostracode shell fragments.

217

R-32C (FP-21), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, and ostracode shell fragments.

R-32C (FP-22), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains rare ostracode shell fragments.

218

R-32C (FP-23), Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Displays some relict laminations and pyritized ostracode carapaces.

WV50-1A, Benwood Limestone (cross polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar to circumgranular void spaces, and ostracode shell fragments. Also displays red-orange-yellow mottling.

219

WV50-1B, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tube (~2mm in diameter) float as individual tubes in a micritic matrix. Tube is filled with sparry cement and are associated with ostracode fragments, and carbonate microbreccia and intraclasts.

WV50-1C, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains ostracode shell fragments and two spar-filled articulated ostracodes.

220

WV50-1D, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar/circumgranular void spaces and ostracodes.

WV50-2B, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar void spaces, clay-lined tubules, charophytes, and ostracodes.

221

WV50-2T, Benwood limestone (plane polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~30% ostracode shells (intact or disarticulated carapaces).

WV50-3A, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of micrite containing spar-filled void spaces overprinted by red-orange-yellow mottling.

222

WV50-3B, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar/circumgranular void spaces, and spar-filled to fragmentary ostracode shells.

WV50-3C, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and micrite, and are associated with ostracode fragments, and carbonate microbreccia and intraclasts.

223

WV50-3D, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments, individual tubes, or small clusters in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode and charophyte fragments, and carbonate microbreccia and intraclasts.

WV50-4M, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains of clay-lined tubules with sparry cement.

224

WV50-4-OOP, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains spar-filled ostracode shells and spar-filled void spaces.

WV50-4T, Benwood limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~40% ostracode shells (intact or disarticulated carapaces).

225

WV79-1, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~45% allochems surrounded by a micritic matrix. Fossil content primarily consists of brachiopods and echinoderms.

WV79-2B, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and are associated with rare ostracode fragments, and carbonate microbreccia and intraclasts.

226

WV79-2M, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble, and are associated with spar-filled planar/circumgranular void spaces.

WV79-2T, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~10% ostracode shells (intact or disarticulated carapaces).

227

WV79-3A, Ames limestone (cross polarized, FOV = 5.5mm). Facies Type 7 – Wackestone. Contains ~20% allochems surrounded by a micritic matrix. Fossil content primarily consists of bryozoans, brachiopods, foraminifera.

WV79-3E, Ewing limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains lithorelict intraclasts and floating quartz grains.

228

WV79-4-OOP, Redstone limestone (plane polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar void spaces, clay-lined tubules, and ostracode shell fragments. Sample also displays red-yellow-orange mottling.

WV79-5B, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and micrite, and are associated with ostracode shell fragments, and carbonate microbreccia and intraclasts.

229

WV79-5T, Clarksburg limestone (cross polarized, FOV = 5.5mm). Facies Type 1 – Micrite. Contains spar-filled ostracode and charophyte fossils.

WV79-6A, Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Displays vague outlines of lithorelict intraclasts and disseminated pyrite.

230

WV79-6B, Pittsburgh limestone (cross polarized, FOV = 5.5mm). Facies Type 2 – Ostracodal wackestone to packstone. Consists of micritic matrix containing ~50% ostracode shells (intact or disarticulated carapaces).

WV79-6C, Pittsburgh limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar/circumgranular void spaces and clay-lined tubules.

231

WV79-6L, Redstone limestone (plane polarized, FOV = 5.5mm). Facies Type 3 – Intraclastic microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar- filled planar/circumgranular void spaces, clay-lined tubules, and ostracode shell fragments.

WV79-6M, Redstone limestone (cross polarized, FOV = 5.5mm). Facies Type 4 – Mottled micrite and microbreccia. Consists of lithorelict intraclasts floating in micritic matrix. Intraclasts range in size from very fine sand to pebble. Common features include: spar-filled planar void spaces and ostracode shell fragments. Also displays red-orange- yellow mottling.

232

WV79-6T, Redstone limestone (plane polarized, FOV = 5.5mm). Facies Type 5 – Spirorbis-bearing biomicrite. Spirorbis worm tube (~1mm in diameter and length) float as fragments in a micritic matrix and filled with sparry cement.

WVI68-1, Clarksburg limestone (plane polarized, FOV = 5.5mm). Facies Type 5 - Spirorbis-bearing biomicrite. Spirorbis worm tubes (~1mm in diameter and length) float as fragments or individual tubes in a micritic matrix. Tubes are filled with sparry cement and are associated with ostracode fragments.

233

Appendix C - Facies types, characteristics, and interpreted depositional salinity of the ten limestone units sampled from the Conemaugh and Monongahela Groups across the northern Appalachian basin from 52 localities and studied from 174 thin sections. Facies type descriptions appear in Table 1, on page 41.

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment Along E side of Rt. 48, 1 mile N of intersection with Rt. B-31a 48 Benwood/Arnoldsburg Type 1 Freshwater 48, Athens Co. OH Along Canaan Twp. Rd. 221, 0.25 miles N of Rt. 34, CN-5a T-221 Pittsburgh Type 1 Freshwater Athens Co. OH Along E side of OH-690, 1 mile S of Rt. 34 (mush Run CN-11 99-L-22 Pittsburgh Type 1 Freshwater Rd., Athens Co. OH Along US-50, 1 mile E of OH-690, Canaan Twp. Athens CN-16 690B/A Benwood/Arnoldsburg Type 1 Freshwater Co. OH Along US-50, 1 mile E of OH-690, Canaan Twp. Athens CN-16 99-L-21 Pittsburgh Type 1 Freshwater Co. OH CR-23 T-108/42 Benwood/Arnoldsburg Type 3 Freshwater Along OH-42, 0.5 miles of US-50, Athens Co. OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 2 Benwood/Arnoldsburg Type 6b Brackish? OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 7 Benwood/Arnoldsburg Type 6b Brackish? OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 8 Benwood/Arnoldsburg Type 6b Brackish? OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 9 Benwood/Arnoldsburg Type 6b Brackish? OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 10 Benwood/Arnoldsburg Type 6b Brackish? OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 13B Benwood/Arnoldsburg Type 1 Freshwater OH

234

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 15A Benwood/Arnoldsburg Type 2 & 3 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 18 Benwood/Arnoldsburg Type 3 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 21 Benwood/Arnoldsburg Type 2 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 23 Benwood/Arnoldsburg Type 2 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 24 Benwood/Arnoldsburg Type 1 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 25 Benwood/Arnoldsburg Type 2 & 3 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 26 Benwood/Arnoldsburg Type 2 Freshwater OH Along Hook Lake loop Rd., just off OH-43, Morgan Co. JG-1 27 Benwood/Arnoldsburg Type 3 Freshwater OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 40 Benwood/Arnoldsburg Type 1 Freshwater camping area, Morgan Co. OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 42 Benwood/Arnoldsburg Type 1 & 3 Freshwater camping area, Morgan Co. OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 43C Benwood/Arnoldsburg Type 3 Freshwater camping area, Morgan Co. OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 46 Benwood/Arnoldsburg Type 3 Freshwater camping area, Morgan Co. OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 50 Benwood/Arnoldsburg Type 1 & 3 Freshwater camping area, Morgan Co. OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 101 Benwood/Arnoldsburg Type 3 Freshwater camping area, Morgan Co. OH

235

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 102 Benwood/Arnoldsburg Type 1 Freshwater camping area, Morgan Co. OH Along T-944, 2 miles W of OH-83 near the Sand Hollow JG-2 103 Benwood/Arnoldsburg Type 1 Freshwater camping area, Morgan Co. OH Unnamed, above JP-KY-26 JP-KY-26 Type 1 Freshwater Along N side of I-64, E of Exit 185 Cambridge WV-27 (Edens Fork Rd.) W of intersection with I-77, 0.5 K-43 A Two Mile Type 5 Brackish miles west of Guthrie, WV. WV-27 (Edens Fork Rd.) W of intersection with I-77, 0.5 K-43 B Two Mile Type 5 Brackish miles west of Guthrie, WV. WV-27 (Edens Fork Rd.) W of intersection with I-77, 0.5 K-43 C Two Mile Type 1 & 3 Freshwater miles west of Guthrie, WV. WV-27 (Edens Fork Rd.) W of intersection with I-77, 0.5 K-43 D Two Mile Type 1 & 3 Freshwater miles west of Guthrie, WV. WV-27 (Edens Fork Rd.) W of intersection with I-77, 0.5 K-43 E Two Mile Type 5 Brackish miles west of Guthrie, WV. WV-27 (Edens Fork Rd.) Charleston WV. Just off I-77 K-44 A-1 Two Mile Type 3 Freshwater Exit 106 WV-27 (Edens Fork Rd.) Charleston WV. Just off I-77 K-44 A-2 Two Mile Type 3 Freshwater Exit 106 WV-27 (Edens Fork Rd.) Charleston WV. Just off I-77 K-44 A-3 Two Mile Type 3 Freshwater Exit 106 WV-27 (Edens Fork Rd.) Charleston WV. Just off I-77 K-44 B Two Mile Type 3 Freshwater Exit 106 WV-27 (Edens Fork Rd.) Charleston WV. Just off I-77 K-44 C Two Mile Type 1 Freshwater Exit 106 WV-27 (Edens Fork Rd.) Charleston WV. Just off I-77 K-44 D Two Mile Type 5 Brackish Exit 106

236

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment

K-48 1 Two Mile Type 3 Freshwater Along I-77 north, 1 mile N of I-77/I-79 split

K-48 2 Two Mile Type 5 Brackish Along I-77 north, 1 mile N of I-77/I-79 split

K-48 3 Two Mile Type 5 Brackish Along I-77 north, 1 mile N of I-77/I-79 split

K-49 A Unnamed, above Two Mile Type 5 Brackish Along I-77 south, 1 mile S of Exit 106

K-49 B Unnamed, above Two Mile Type 1 Freshwater Along I-77 south, 1 mile S of Exit 106 SW side of Rt. 622 (WV-21), 0.25 miles S of Guthrie, K-50 K-50 Two Mile Type 1 Freshwater WV (by Allen’s Auto Recycling) KY-23 S, 246 feet N of Campbells Run Rd., Boyd Co. KY-3 A Upper Brush Creek Type 6a Marine KY KY-23 S, 246 feet N of Campbells Run Rd., Boyd Co. KY-3 B Upper Brush Creek Type 7 & 6a Marine KY KY-23 S, 246 feet N of Campbells Run Rd., Boyd Co. KY-3 C Upper Brush Creek Type 6a Marine KY Along W side of Rt. 23 at milepost 9.5, 1 mile S of I-64, KY-4 KY-4 Lower Brush Creek Type 7 to 8 Marine Boyd Co. KY KY-21 A Lower Brush Creek Type 8 Marine Along KY-23, 2 miles W of Louisa KY

KY-21 B-1 Upper Brush Creek Type 6a Marine Along KY-23, 2 miles W of Louisa KY

KY-21 B-2 Upper Brush Creek Type 7 & 6a Marine Along KY-23, 2 miles W of Louisa KY

KY-21 B-3 Upper Brush Creek Type 6a Marine Along KY-23, 2 miles W of Louisa KY

237

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment

KY-26 KY-26 Cambridge Type 8 Marine Along N side of I-64, E of Exit 185 Unnamed, above Upper KY-26 B-1 Type 5 Brackish Along N side of I-64, E of Exit 185 Brush Creek Unnamed, above Upper KY-26 B-2 Type 5 Brackish Along N side of I-64, E of Exit 185 Brush Creek KY-27 KY-27 Lower Brush Creek Type 8 Marine Along N side of I-64, 0.25 miles E of Exit 185

KY-30 KY-30 Lower Brush Creek Type 8 Marine Along KY-67 (industrial parkway), just off I-64 Exit 179 KY-180, 0.25 miles S of I-64 Exit 185, behind Flying J KY-31 L Lower Brush Creek Type 7 Marine truck stop KY-180, 0.25 miles S of I-64 Exit 185, behind Flying J KY-31 U Lower Brush Creek Type 7 Marine truck stop L3 A-1 Two Mile Type 2 Freshwater WV-119. 0.25 miles E of Priestly, Lincoln Co. WV

L3 A-2 Two Mile Type 5 Brackish WV-119. 0.25 miles E of Priestly, Lincoln Co. WV

L3 A-3 Two Mile Type 5 Brackish WV-119. 0.25 miles E of Priestly, Lincoln Co. WV

L3 A-4 Two Mile Type 5 Brackish WV-119. 0.25 miles E of Priestly, Lincoln Co. WV

L7 1 Two Mile Type 5 Brackish WV-119, 0.8 miles S of Priestly, Lincoln Co. WV

L7 2 Two Mile Type 5 Brackish WV-119, 0.8 miles S of Priestly, Lincoln Co. WV SE side of PA-50, 2 miles past intersection with I-79 at PA-4 1A Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit

238

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment SE side of PA-50, 2 miles past intersection with I-79 at PA-4 1B Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 2 Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 3 Benwood/Arnoldsburg Type 4 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 4A Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 4B Benwood/Arnoldsburg Type 1 & 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 5B Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 5T-A Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 5T-B Benwood/Arnoldsburg Type 3 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 6A Benwood/Arnoldsburg Type 1 Freshwater Bridgeville Exit SE side of PA-50, 2 miles past intersection with I-79 at PA-4 6B Benwood/Arnoldsburg Type 1 & 2 Freshwater Bridgeville Exit West bank of Chartiers Creek, SW of fairgrounds at PA-5 1 Benwood/Arnoldsburg Type 3 Freshwater Arden, Washington Co. PA West bank of Chartiers Creek, SW of fairgrounds at PA-5 2 Benwood/Arnoldsburg Type 4 Freshwater Arden, Washington Co. PA West bank of Chartiers Creek, SW of fairgrounds at PA-5 A Benwood/Arnoldsburg Type 1 Freshwater Arden, Washington Co. PA West bank of Chartiers Creek, SW of fairgrounds at PA-5 B Benwood/Arnoldsburg Type 1 Freshwater Arden, Washington Co. PA

239

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment SW corner of intersection between US-19 & Gilkeson PA-6 A Benwood/Arnoldsburg Type 1 Freshwater Rd., Mount Lebanon, PA SW corner of intersection between US-19 & Gilkeson PA-6 B Benwood/Arnoldsburg Type 1 Freshwater Rd., Mount Lebanon, PA SW corner of intersection between US-19 & Gilkeson PA-6 C-A Benwood/Arnoldsburg Type 1 Freshwater Rd., Mount Lebanon, PA SW corner of intersection between US-19 & Gilkeson PA-6 C-B Benwood/Arnoldsburg Type 3 Freshwater Rd., Mount Lebanon, PA SW corner of intersection between US-19 & Gilkeson PA-6 D-A Benwood/Arnoldsburg Type 2 Freshwater Rd., Mount Lebanon, PA SW corner of intersection between US-19 & Gilkeson PA-6 D-B Benwood/Arnoldsburg Type 1 & 2 Freshwater Rd., Mount Lebanon, PA NE side of Old Clairton Rd. in Option, 0.3 miles NW of PA-7 B Benwood/Arnoldsburg Type 3 Freshwater intersection with Streets Run Rd., Allegheny Co. PA NE side of Old Clairton Rd. in Option, 0.3 miles NW of PA-7 M Benwood/Arnoldsburg Type 1 Freshwater intersection with Streets Run Rd., Allegheny Co. PA NE side of Old Clairton Rd. in Option, 0.3 miles NW of PA-7 T Benwood/Arnoldsburg Type 1 Freshwater intersection with Streets Run Rd., Allegheny Co. PA S side of US-22, 3.3 miles east of PA-11 1 Clarksburg Type 1 & 2 Freshwater Allegheny/Westmoreland Co. Line, Delmont, PA. S side of US-22, 3.3 miles east of PA-11 2 Clarksburg Type 5 Brackish Allegheny/Westmoreland Co. Line, Delmont, PA. S side of US-22, 3.3 miles east of PA-11 3 Clarksburg Type 5 Brackish Allegheny/Westmoreland Co. Line, Delmont, PA. S side of US-22, 3.3 miles east of PA-11 4 Clarksburg Type 3 Freshwater Allegheny/Westmoreland Co. Line, Delmont, PA. S side of US-22, 3.3 miles east of PA-11 5 Clarksburg Type 5 Brackish Allegheny/Westmoreland Co. Line, Delmont, PA.

240

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment S side of US-22, 3.3 miles east of PA-11 6 Clarksburg Type 3 Freshwater Allegheny/Westmoreland Co. Line, Delmont, PA. I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 1 Clarksburg Type 1 Freshwater I-79/I-279 split I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 2 Clarksburg Type 4 Freshwater I-79/I-279 split I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 3 Clarksburg Type 5 & 6b Brackish I-79/I-279 split I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 4A Clarksburg Type 5 & 6b Brackish I-79/I-279 split I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 4B Clarksburg Type 5 Brackish I-79/I-279 split I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 5A Clarksburg Type 1 Freshwater I-79/I-279 split I-79 south, 1.5 miles S of Wexford Exit & just N of PA-12 5B Clarksburg Type 3 Freshwater I-79/I-279 split E side of PA-906, 0.5 miles S of Webster, Westmoreland PA-13 B Clarksburg Type 1 Freshwater Co. PA E side of PA-906, 0.5 miles S of Webster, Westmoreland PA-13 M Clarksburg Type 1 Freshwater Co. PA E side of I-279, 2.2 miles N of Camp Horn Rd. Exit, PA-16 1 Ames Type 7 Marine Allegheny Co. PA PA-19 B Ames Type 7 Marine N side of PA-28W at the Etna Exit

PA-19 M-A Ames Type 7 Marine N side of PA-28W at the Etna Exit

PA-19 M-B Ames Type 7 Marine N side of PA-28W at the Etna Exit

241

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment

PA-19 T Ames Type 7 Marine N side of PA-28W at the Etna Exit N side of US-22 in Monroeville, PA., just E of junction PA-21 1 Ames Type 7 Marine with PA-376 (across from Spitzer Auto) N side of US-22 in Monroeville, PA., just E of junction PA-21 2 Ames Type 7 Marine with PA-376 (across from Spitzer Auto) PA-22 1 Ames Type 7 Marine N side of PA-130, 1 mile W of Pitcairn, PA

PA-22 2 Ames Type 7 Marine N side of PA-130, 1 mile W of Pitcairn, PA

PA-22 3 Ames Type 7 Marine N side of PA-130, 1 mile W of Pitcairn, PA W side of Braddock Ave., 0.35 miles S of intersection PA-23 PA-23 Ames Type 7 Marine with Forbes Rd., behind Frick Park, Pittsburgh, PA Allegheny River Blvd. opposite Nadine Pumping Station, PA-35 PA-35 Nadine Type 6a Marine 1.5 miles E of Highland Park Bridge N side of PA-48, 0.4 miles E of intersection with PA- PA-36 PA-36 Nadine Type 8 Marine 148, McKeesport, PA Fall Run Park, Shaler Twp. Allegheny Co. PA, 600 feet PA-38 U1 Pine Creek Type 7 Marine past upper falls in creek bed Fall Run Park, Shaler Twp. Allegheny Co. PA, 600 feet PA-38 U2 Pine Creek Type 7 & 6a Marine past upper falls in creek bed Just past PA-28/PA-422E intersection along PA-28 PA-45 1 Pine Creek Type 7 Marine bypass around Kittanning, Armstrong Co. PA Just past PA-28/PA-422E intersection along PA-28 PA-45 2 Pine Creek Type 7 Marine bypass around Kittanning, Armstrong Co. PA Just past PA-28/PA-422E intersection along PA-28 PA-45 3 Pine Creek Type 6a Marine bypass around Kittanning, Armstrong Co. PA

242

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment Along road next to Crooked Creek, 700 feet from US- PA-46 PA-46 Pine Creek Type 7 Marine 422, 0.5 miles NW of Shelocta, Indiana Co. PA Fall Run Park, Shaler Twp. Allegheny Co. PA, 1200 feet PA-47 L1 Lower Brush Creek Type 7 & 6a Marine NE of lower parking circle, in creek bed Fall Run Park, Shaler Twp. Allegheny Co. PA, 1200 feet PA-47 L2 Lower Brush Creek Type 7 & 6a Marine NE of lower parking circle, in creek bed Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-2 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-3 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-4 Pittsburgh Type 3 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-5 Pittsburgh Type 4 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-6A Pittsburgh Type 4 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-7 Pittsburgh Type 5 Brackish Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-8 Pittsburgh Type 2 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-9 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-10 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-11 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-13L Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH

243

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-13U Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-18 Pittsburgh Type 3 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-19 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-20 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-21 Pittsburgh Type 3 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-22 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH Along US-50, 1 mile E of OH-622 (at East Canaan R-32c FP-23 Pittsburgh Type 1 Freshwater Church), Rome Twp. Athens Co. OH WV50-1 A Benwood/Arnoldsburg Type 4 Freshwater US-50 west, Just past Smithburg, Doddridge Co. WV

WV50-1 B Benwood/Arnoldsburg Type 5 Brackish US-50 west, Just past Smithburg, Doddridge Co. WV

WV50-1 C Benwood/Arnoldsburg Type 1 Freshwater US-50 west, Just past Smithburg, Doddridge Co. WV

WV50-1 D Benwood/Arnoldsburg Type 3 Freshwater US-50 west, Just past Smithburg, Doddridge Co. WV US-50 east, at the junction of Wolfsummit Rd. & WV50-2 B Benwood/Arnoldsburg Type 3 Freshwater Sycamore Rd., Doddridge Co. WV US-50 east, at the junction of Wolfsummit Rd. & WV50-2 T Benwood/Arnoldsburg Type 2 Freshwater Sycamore Rd., Doddridge Co. WV US-50 east, 0.5 miles before intersection with WV50-3 A Clarksburg Type 4 Freshwater Wilsonburg Rd., Doddridge Co. WV

244

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment US-50 east, 0.5 miles before intersection with WV50-3 B Clarksburg Type 3 Freshwater Wilsonburg Rd., Doddridge Co. WV US-50 east, 0.5 miles before intersection with WV50-3 C Clarksburg Type 5 Brackish Wilsonburg Rd., Doddridge Co. WV US-50 east, 0.5 miles before intersection with WV50-3 D Cambridge Type 5 Brackish Wilsonburg Rd., Doddridge Co. WV WV50-4 M Benwood/Arnoldsburg Type 1 Freshwater US-50 east, 0.5 miles before I-79 exit ramp

WV50-4 OOP Benwood/Arnoldsburg Type 1 Freshwater US-50 east, 0.5 miles before I-79 exit ramp

WV50-4 T Benwood/Arnoldsburg Type 2 Freshwater US-50 east, 0.5 miles before I-79 exit ramp

WV79-1 WV79-1 Ames Type 7 Marine I-79 south, milepost 113.2-113.4

WV79-2 B Clarksburg Type 5 Brackish I-79 north, milepost 112.4-112.5

WV79-2 M Clarksburg Type 3 Freshwater I-79 north, milepost 112.4-112.5

WV79-2 T Clarksburg Type 2 Freshwater I-79 north, milepost 112.4-112.5

WV79-3 A Ames Type 7 Marine I-79 north, milepost 115.6

WV79-3 E Ewing Type 1 Freshwater I-79 north, milepost 115.6

WV79-4 OOP Redstone Type 4 Freshwater I-79 south, milepost 72.8

WV79-5 B Clarksburg Type 5 Brackish I-79 north, along Exit 125 ramp

245

Sample Interpretation Location ID Lithologic Unit Location Number Facies Type Environment

WV79-5 T Clarksburg Type 1 Freshwater I-79 north, along Exit 125 ramp North side of Morgantown Mall complex, near I-79 Exit WV79-6 A Pittsburgh Type 3 Freshwater 152 North side of Morgantown Mall complex, near I-79 Exit WV79-6 B Pittsburgh Type 2 Freshwater 152 North side of Morgantown Mall complex, near I-79 Exit WV79-6 C Pittsburgh Type 3 Freshwater 152 North side of Morgantown Mall complex, near I-79 Exit WV79-6 L Redstone Type 3 Freshwater 152 North side of Morgantown Mall complex, near I-79 Exit WV79-6 M Redstone Type 4 Freshwater 152 North side of Morgantown Mall complex, near I-79 Exit WV79-6 T Redstone Type 5 Brackish 152 WVI68-1 WVI68-1 Clarksburg Type 5 Brackish I-68 west, milepost 4.0, just west of Exit 4 (Sabraton)