All-Fiber Passively Mode-Locked Thulium/Holmium Laser with Two Center Wavelengths
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Rare Earth Elements: the Global Supply Chain
Rare Earth Elements: The Global Supply Chain Marc Humphries Analyst in Energy Policy September 30, 2010 Congressional Research Service 7-5700 www.crs.gov R41347 CRS Report for Congress Prepared for Members and Committees of Congress Rare Earth Elements: The Global Supply Chain Summary The concentration of production of rare earth elements (REEs) outside the United States raises the important issue of supply vulnerability. REEs are used for new energy technologies and national security applications. Is the United States vulnerable to supply disruptions of REEs? Are these elements essential to U.S. national security and economic well-being? There are 17 rare earth elements (REEs), 15 within the chemical group called lanthanides, plus yttrium and scandium. The lanthanides consist of the following: lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium. Rare earths are moderately abundant in the earth’s crust, some even more abundant than copper, lead, gold, and platinum. While more abundant than many other minerals, REE are not concentrated enough to make them easily exploitable economically. The United States was once self-reliant in domestically produced REEs, but over the past 15 years has become 100% reliant on imports, primarily from China, because of lower-cost operations. There is no rare earth mine production in the United States. U.S.-based Molycorp operates a separation plant at Mountain Pass, CA, and sells the rare earth concentrates and refined products from previously mined above-ground stocks. Neodymium, praseodymium, and lanthanum oxides are produced for further processing but these materials are not turned into rare earth metal in the United States. -
Carrier-Envelope Phase Stabilization and Control Using a Transmission Grating Compressor and an AOPDF
May 1, 2009 / Vol. 34, No. 9 / OPTICS LETTERS 1333 Carrier-envelope phase stabilization and control using a transmission grating compressor and an AOPDF Lorenzo Canova,1 Xiaowei Chen,1 Alexandre Trisorio,1 Aurélie Jullien,1,* Andreas Assion,2 Gabriel Tempea,2 Nicolas Forget,3 Thomas Oksenhendler,3 and Rodrigo Lopez-Martens1 1Laboratoire d’Optique Appliquée, Ecole Nationale Supérieure des Techniques Avancées, ParisTech, CNRS, Ecole Polytechnique, 91761 Palaiseau Cedex, France 2Femtolasers Produktions GmbH, Fernkongasse 10, 1100 Vienna, Austria 3Fastlite, Centre Scientifique d’Orsay, Bâtiment 503, Plateau du Moulon–B.P. 45, 91401 Orsay, France *Corresponding author: [email protected] Received February 4, 2009; accepted March 17, 2009; posted March 26, 2009 (Doc. ID 107145); published April 20, 2009 Carrier-envelope phase (CEP) stabilization of a femtosecond chirped-pulse amplification system featuring a compact transmission grating compressor is demonstrated. The system includes two amplification stages and routinely generates phase-stable (ϳ250 mrad rms) 2 mJ, 25 fs pulses at 1 kHz. Minimizing the optical pathway in the compressor enables phase stabilization without feedback control of the grating separation or beam pointing. We also demonstrate for the first time to the best of our knowledge, out-of-loop control of the CEP using an acousto-optic programmable dispersive filter inside the laser chain. © 2009 Optical Society of America OCIS codes: 140.7090, 320.7090, 140.3280, 320.7160. In the past few years, one major breakthrough in ul- control of the grating position in the compressor is trafast laser science has been the ability to measure necessary for CEP stabilization. We also demonstrate and stabilize the carrier-envelope phase (CEP) drift arbitrary control of the relative CEP value using of amplified femtosecond laser pulses. -
The Development of the Periodic Table and Its Consequences Citation: J
Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1. -
Chirped Pulse Oscillators: Generating Microjoule Femtosecond Pulses at Megahertz Repetition Rate
MAX-PLANCK-INSTITUT FUR¨ QUANTENOPTIK Chirped Pulse Oscillators: Generating microjoule femtosecond pulses at megahertz repetition rate Alma del Carmen Fernandez´ Gonzalez´ MPQ 310 Juni 2007 Chirped Pulse Oscillators: Generating microjoule femtosecond pulses at megahertz repetition rate Alma Fernandez´ Gonzalez´ Munchen¨ 2007 Chirped Pulse Oscillators: Generating microjoule femtosecond pulses at megahertz repetition rate Alma Fernandez´ Gonzalez´ Dissertation an der Fakultat¨ fur¨ Physik der Ludwig–Maximilians–Universitat¨ Munchen¨ vorgelegt von Alma Fernandez´ Gonzalez´ aus Penonome,´ Cocle,´ Panama´ Munchen,¨ den 27. Februar 2007 Erstgutachter: Prof. Dr. Ferenc Krausz Zweitgutachter: Prof. Dr. Harald Weinfurter Tag der mundlichen¨ Prufung:¨ 31. Mai 2007 vii to my mother and my father viii Abstract The maximum energy achievable directly from conventional Ti:sapphire oscillators has been limited by the onset of instabilities such as cw-generation and pulse splitting because of the high intensity in the laser medium. Generation of microjoule pulses at megahertz repetition rates are of special interest in many areas of science and technology. The main subject of this thesis is the development of high energy Ti:sapphire oscillators at megahertz repetition rate. The main concept that was applied to overcome the difficulties pointed out above was to operate the laser in the positive dispersion regime. By operating the laser in this regime, intracavity picosecond pulses are generated that can be externally compressed down to femtosecond pulse durations. The long pulse duration inside the laser offers an elegant way to reduce pulse instabilities by decreasing the intracavity intensity via pulse stretching. Drawing on this concept, Ti:sapphire chirped-pulse oscillators delivering sub-50-fs pulses of 0.5 µJ and 60 nJ energy are demonstrated at average power levels of 1 and 4 W (repetition rate: 2 MHz and 70 MHz), respectively. -
The Symbols of the Chemical Elements
42 THE SYMBOLS OF THE CHEMICAL ELEMENTS DARRYL FRANCIS Sutton, Surrey, England [email protected] The names of the chemical elements have received a certain amount of attention in Word Wa s over the years. The very first issue of Word Ways in February 1968 presented a quiz on 20 transposed element names. Later articles have offered more extensive transpositions, trnsadditions, old names for some of the elements, elements in US placenames, and words composed solely of the element symbols, such as CoAgULaTe. In this article, I want to examine the symbols of the chemical elements as an ordered coUection of letters. Many earlier items in Word Ways have treated the typewriter (computer) keyboard as an ordered sequence of letters (QWERTYillOPASDFGHJKLZXCVBNM) and have posed ques tions such as: • What is the longest word with its letters spelled in keyboard order? • What is the longest word with its letter spelled in rever e keyboard order? • What is the longest word with letters from the first letter row? Similar questions can be raised with regard to the elemental symbols. First off let's take a look at the periodic table, the listing of chemical elements in atomic number order and the corre ponding symbols. The list below contains 109 elements, with atomic numbers from 1 to 109. For three f the elements (aluminum, sulfur, cesium) there exist variant Briti h pellings (aluminium ulphur, caesium). For elements 104 to 109 I have used the new provisional name rather than the earlier suggested names. My 1998 printing of the Merriam-Webster ollegiate Di tionary lOth editi n. -
THULIUM Element Symbol: Tm Atomic Number: 69
THULIUM Element Symbol: Tm Atomic Number: 69 An initiative of IYC 2011 brought to you by the RACI IONA JOHNSON www.raci.org.au THULIUM Element symbol: Tm Atomic number: 69 The element Thulium (when purified from mineral ores) is a silver-grey lustrous metal. Thulium metal is soft, malleable and ductile, and is so soft that it can be cut with a knife. The density is 9.32 grams per cubic centimetre: which is a bit lighter than Lead, but heavier than Iron, Copper, Nickel, and Tin. The surface of the metal will readily tarnish in air and produce an oxide. Thulium will also burn readily in air. Thulium will react slowly with cold water, and quite quickly with hot water to form Thulium hydroxide and Hydrogen. Thulium was named in honour of Thule: an ancient Roman name for a mythical country in the far North, which was probably Scandinavia. The first compound containing Thulium was discovered and named by Swedish Chemist Per Teodor Cleve (1840 – 1905) in 1879. Cleve made his discovery while studying the black-coloured rock that had been discovered around the town of Ytterby, Sweden in 1787. After removing all the other components from the rock the most interesting portion was where the Thulium accumulated because the solution possessed a bluish green colour. The compound was Thulium oxide (also called Thulia). Solid Thulium oxide has a pale green colour. The complete analysis of that rock took more than 100 years, and in the process nine new elements were discovered including Thulium. Pure metallic Thulium was not produced until 1910 by Charles James (1880-1928) an American chemist. -
Holmium Laser Versus Thulium Laser Enucleation of the Prostate
TAU0010.1177/1756287218779784Therapeutic Advances in UrologyGM Pirola, G Saredi 779784research-article2018 Therapeutic Advances in Urology Original Research Ther Adv Urol Holmium laser versus thulium laser 1 –11 DOI:https://doi.org/10.1177/1756287218779784 10.1177/ enucleation of the prostate: a matched- 1756287218779784https://doi.org/10.1177/1756287218779784 © The Author(s), 2018. Reprints and permissions: pair analysis from two centers http://www.sagepub.co.uk/ journalsPermissions.nav Giacomo Maria Pirola , Giovanni Saredi, Ricardo Codas Duarte, Lorraine Bernard, Andrea Pacchetti, Lorenzo Berti, Eugenio Martorana, Giulio Carcano, Lionel Badet and Hakim Fassi-Fehri Abstract Background: The aim of our study was to compare perioperative and functional outcomes of two different prostatic laser enucleation techniques performed in two high-volume centers: 100 W holmium laser enucleation of the prostate (HoLEP) (Lyon, France) and 110 W thulium laser enucleation of the prostate (ThuLEP) (Varese, Italy). Materials and Methods: A nonrandomized, observational, retrospective and matched-pair analysis was performed on two homogeneous groups of 117 patients that underwent prostate laser enucleation in the HoLEP or ThuLEP centers between January 2015 and April 2017, following the classical ‘three lobes’ enucleation technique. The American Society of Anesthesiologists (ASA) score and prostate volume were the main parameters considered for matching the patients between the two groups. Patients on anticoagulant therapy, with documented detrusor hypoactivity or hyperactivity or with the finding of concurrent prostate cancer were excluded from the study. Follow up was assessed at 3, 6 and 12 months after surgery. Results: Median enucleation and morcellation time was 75.5 and 11.5 min, respectively, in the HoLEP group versus 70.5 and 12 min, respectively, in the ThuLEP group (p = 0.001 and 0.49, respectively). -
Periodic Table 1 Periodic Table
Periodic table 1 Periodic table This article is about the table used in chemistry. For other uses, see Periodic table (disambiguation). The periodic table is a tabular arrangement of the chemical elements, organized on the basis of their atomic numbers (numbers of protons in the nucleus), electron configurations , and recurring chemical properties. Elements are presented in order of increasing atomic number, which is typically listed with the chemical symbol in each box. The standard form of the table consists of a grid of elements laid out in 18 columns and 7 Standard 18-column form of the periodic table. For the color legend, see section Layout, rows, with a double row of elements under the larger table. below that. The table can also be deconstructed into four rectangular blocks: the s-block to the left, the p-block to the right, the d-block in the middle, and the f-block below that. The rows of the table are called periods; the columns are called groups, with some of these having names such as halogens or noble gases. Since, by definition, a periodic table incorporates recurring trends, any such table can be used to derive relationships between the properties of the elements and predict the properties of new, yet to be discovered or synthesized, elements. As a result, a periodic table—whether in the standard form or some other variant—provides a useful framework for analyzing chemical behavior, and such tables are widely used in chemistry and other sciences. Although precursors exist, Dmitri Mendeleev is generally credited with the publication, in 1869, of the first widely recognized periodic table. -
Dispersion and How to Control It
Dispersion and how to control it Group velocity versus phase velocity Angular dispersion Prism sequences Grating pairs Chirped mirrors Intracavity and extra-cavity examples 1 Pulse propagation and broadening After propagating a distance z, an (initially) unchirped Gaussian of initial duration tG becomes: 2 tz/Vgp Etz(, ) exp tikz2 2" G 2 2"k exp 1 iz tz2 122 t 2 G G pulse duration increases with z chirp parameter 3 2 pulse duration t (z)/t G G 1 0 0 123 2 propagation distance z Chirped vs. transform-limited A transform-limited pulse: •satisfies the ‘equal’sign in the relation C •is as short as it could possibly be, given the spectral bandwidth • has an envelope function which is REAL (phase = 0) • has an electric field that can be computed directly from S • exhibits zero chirp: A chirped pulse: the same period • satisfies the ‘greater than’ sign in the relation C • is longer than it needs to be, given the spectral bandwidth • has an envelope function which is COMPLEX (phase 0) •requires knowledge of more than just S in order to determine E(t) • exhibits non-zero chirp: 3 not the same period Propagation of Gaussian pulses 2 1 t z / Vg p E(t, z) E0 expi p t z / V p t z t z G G where: t 2 pulse width increases with propagation G z tG 2ik"z p Vp phase velocity kp 1 d V group velocity - g 0 speed of pulse envelope k' p dk p dk2 d 1 k Group velocity dispersion (GVD) ddV 2 g (different for each material) If (and only if) GVD = 0, then V = Vg. -
Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals
metals Review Separation of Radioactive Elements from Rare Earth Element-Bearing Minerals Adrián Carrillo García 1, Mohammad Latifi 1,2, Ahmadreza Amini 1 and Jamal Chaouki 1,* 1 Process Development Advanced Research Lab (PEARL), Chemical Engineering Department, Ecole Polytechnique de Montreal, C.P. 6079, Succ. Centre-ville, Montreal, QC H3C 3A7, Canada; [email protected] (A.C.G.); mohammad.latifi@polymtl.ca (M.L.); [email protected] (A.A.) 2 NeoCtech Corp., Montreal, QC H3G 2N7, Canada * Correspondence: [email protected] Received: 8 October 2020; Accepted: 13 November 2020; Published: 17 November 2020 Abstract: Rare earth elements (REE), originally found in various low-grade deposits in the form of different minerals, are associated with gangues that have similar physicochemical properties. However, the production of REE is attractive due to their numerous applications in advanced materials and new technologies. The presence of the radioactive elements, thorium and uranium, in the REE deposits, is a production challenge. Their separation is crucial to gaining a product with minimum radioactivity in the downstream processes, and to mitigate the environmental and safety issues. In the present study, different techniques for separation of the radioactive elements from REE are reviewed, including leaching, precipitation, solvent extraction, and ion chromatography. In addition, the waste management of the separated radioactive elements is discussed with a particular conclusion that such a waste stream can be -
Hyperbolic Secant Squared Pulse Shape
Dispersion and Ultrashort Pulses Angular dispersion and group-velocity dispersion Phase and group velocities Group-delay dispersion Negative group- delay dispersion Pulse compression Chirped mirrors Refractive index dispersion Sellmeiera formula e.g. SF 10 glass from Schott 2 2 2 2 B1 B2 B3 n 1 2 2 2 C1 C2 C3 B1 = 1,61625977 B2 = 0,259229334 B3 = 1,07762317 C1 = 0,0127534559 C2 = 0,0581983954 C3 = 116,607680 n(0,532 mm) = 1,73673 Dispersion in Optics The dependence of the refractive index on wavelength has two effects on a pulse, one in space and the other in time. Dispersion disperses a pulse in space (angle): angular dispersion dn/d out ()blue otu ()red Dispersion also disperses a pulse in time: temporal dispersion d2n/d2 vgr(blue) < vgr(red) Both of these effects play major roles in ultrafast optics. Movies! Group velocity v0 vv vs. g phase velocity vvg vvg Calculating the group velocity vg dw /dk Now, w is the same in or out of the medium, but k = k0 n, where k0 is the k-vector in vacuum, and n is what depends on the medium. So it's easier to think of w as the independent variable: 1 v/g dk dw Using k = w n(w) / c0, calculate: dk /dw = (n + w dn/dw) / c0 vg c0 / n w dn/dw) = (c0 /n) / (1 + w /n dn/dw ) Finally: w dn vg v phase / 1 ndw So the group velocity equals the phase velocity when dn/dw = 0, such as in vacuum. But n usually increases with w, so dn/dw > 0, and: vg < vphase. -
Large Compensation Range, Single-Prism Femtosecond Pulse Compressor
A high throughput (>90%), large compensation range, single-prism femtosecond pulse compressor Lingjie Kong, Meng Cui* Janelia Farm Research Campus, Howard Hughes Medical Institute, Ashburn, Virginia 20147, USA * [email protected] Abstract: We demonstrate a high throughput, large compensation range, single-prism femtosecond pulse compressor, using a single prism and two roof mirrors. The compressor has zero angular dispersion, zero spatial dispersion, zero pulse-front tilt, and unity magnification. The high efficiency is achieved by adopting two roof mirrors as the retroreflectors. We experimentally achieved ~ -14500 fs2 group delay dispersion (GDD) with 30 cm of prism tip-roof mirror prism separation, and ~90.7% system throughput with the current implementation. With better components, the throughput can be even higher. 1. Introduction Femtosecond pulses with high peak-power have found broad applications in micromachining, biomedical imaging, and spectroscopy[1, 2]. However, femtosecond pulses are susceptible to GDD when they propagate through optical elements, resulting in longer pulse duration and lower peak power. Generally, pulse compressors are used to compensate the material dispersion. In multi-photon microscopy, femtosecond pulses with high peak-power are expected to achieve high excitation efficiency[2]. The excitation pulses should be prechirped by pulse compressors before entering the microscope, such that the negative GDD introduced by the compressor cancels the positive GDD of the microscope components. Components with angle dispersion, such as gratings and prisms, are commonly used to introduce negative GDD. So far, various schemes of femtosecond pulse compressor (with either gratings, prisms, or phase compensation based on SLM or deformable mirrors) have been demonstrated [3-6].