Superconductivity

Total Page:16

File Type:pdf, Size:1020Kb

Superconductivity Pramana Research Journal ISSN NO: 2249-2976 SUPERCONDUCTIVITY: A REVIEW 1Rajiv Khullar, 2Ankit Pal Singh, 3Harshil Abhijeet 1Assistant Professor, Department of Mechanical Engineering, Chandigarh University, Punjab 2,3B.E Student, Department of Mechanical Engineering, Chandigarh University, Punjab [email protected],[email protected] Abstract What if superconductors could work on room temperature? There is a reason for asking this silly question that, if thisthing happen then we will have “a new technological revolution.” That is superconductor can transmit electrical current with absolutely no loss of energy. If scientists could bring that at room temperature then we can replace any thing requiring electricity, including the large power grids. INTRODUCTION Superconductivity could be a development of specifically zero electrical resistant and expulsion of magnetic flux field occuring in bound material referred to as superconductors, once these materials ar cooled down below a characteristic important temperature. It absolutely was discovered by Dutch scientist Heike Kamerling Onnes on April eight,1911, in Leiden. Like magnetism and atomic field lines, it's associate degree quantum physical phenomenon. it's characterised as Meissner result.The complete removing out of the magnetic lines from the inside of the superconductor throughout the transition into superconductor state. incidence of Meissner result indiccates the electrical conduction can't be understood merely because the idealisation of good physical phenomenon by classical medication. The resistance of gold conductors decreases usually because the temperature is lowered . In standard conductors like copper and silver, the decreases is proscribed by impurities and alternative defects. Even close to temperature, rare sample of traditional conductors show some resistance however in superconductors the resistacnce drop suddenly to zeroas the fabric is cooled below important temperature. A electrical current through the loops of superconducting wire will persist indefinately with no power supply.[1][2][3][4] SUPERCONDUCTING MATERIAL Superconductor material categories embrace chemical components , alloys , ceramic, superconducting pnictides or organic superconductors(carbon nanotubes and fullerenes; although perhaps these examples need to be clathrate among the chemical components).[15] HISTORY OF SUPERCONDUCTIVITY Superconductivity was discovered on Apr eight, 1911 by Heike Kamerlingh Onnes, World Health Organization was finding resisting solid mercury at refrigerant temperatures exploitation currently created the liquid. At the temperature of four.2 K, he discovered that the resistance dead disappeared. within the identical experiment, he conjointly discovered the superfluid transition of Helium,argon,inert gases and noble gases at 2.2 K, which not allow their significance.[5][6] Volume 8, Issue 3, 2018 44 https://pramanaresearch.org/ Pramana Research Journal ISSN NO: 2249-2976 Many attempts are dedicated to sorting out how it being process and why electrical conduction works; the necessary step occurred in 1933,Ochsenfeld and Meissner found that applied magnetic fields is expelled by supeconductors, a development that has return that called the Meissner result. [7][8] HIGH-TEMPERATURE SUPERCONDUCTIVITY Till 1986, physicists had believed that BCS theory forbade electrical conduction at temperatures higher than concerning thirty K. there in year, Muller and Bednorz light on the electrical conduction during lanthanum based material, like cuprte perovskite, that had a conversion temperature of thirty five K (Nobel Prize in Physics, 1987). it had been shortly found that commutation the metallic element with metallic element (i.e., creating YBCO) raised the important temperature to ninety two K.[9] This temperature jump is especially important, since it permits liquid nitorgen as a refrigerant, commutation liquid argonon. this could be vital commercially as a result of cryogen may be made comparatively cheaply, even on-the-scene. Also, the upper temperatures facilitate avoid a number of the issues that arise at liquid argonon temperatures, like the development of frozen air plugs which may pause refrigerant pipes and creates the doubtless and unexcepted venturous pressure buildup.[10] In Gregorian calendar month two thousand eight the associate degree high-temperature superconductors which was based on the family of iron-based.Hideo Hosono, of the Tokio Technology Institute, and found metallic element gas F iron compound (LaO1−xFxFeAs), associate degree oxypnictide that superconducts below twenty six K. Commutation the metallic element in LaO1−xFxFeAs with metallic element ends up in superconductors that job at fifty five K.[11] In could 2014, hydrofen chemical compound (H2S) was perdicted to be a heat superconductor with a transition temperature of 80K at 10 GPa of pressure. In the year 2015, H2S has determined to give away electrical conduction unnder the temperature of 203K, however extraordinarily high pressures around a hundred and fifty gigapascals. In 2018, the Department of Physics, Massachusetts Institute of Technology, got that the bilayer graphene that have electric conduction which is twisted at associate degree of roughly angle one degrees with applying a little changes and cooling. Notwithstanding this type of experiments weren't dispensed during a surrounding of high temperature, result of the area unit are correlative less to classical however heat superconductors, on condition that no foreign atoms ought to be introduced.[12] APPLICATION Superconducting magnets area unit a number of the foremost powerful magnet well-known. they're employed in mass spectrometers,machine like MRI/NMR,particle accelerators in which the beam- steeing magnets and some tokamaks that have plasma confining magnets. They'll even be used for separation of magnetic, wherever feeble magnetic particles area unit extracted from a background of less or non-magnetic particles, as within the pigment industries.[15] In 1950’s, superconductors are not to build experiment things like digital computers victimization cryoton switches.Currently,superconductors are wont to create digital circuits supported fast single flux quantum technology and RF and microwave filters for itinerant base stations.[13] UNLEASING DIFFERENT TECHNOLOGIES BY BRING AT ROOM TEMPEATURE Volume 8, Issue 3, 2018 45 https://pramanaresearch.org/ Pramana Research Journal ISSN NO: 2249-2976 Superconductors area unit among the foremost eccentric and material that are existing are nonetheless discovered.Quantum-mechanical effects mean that, below a essential temperature, they need zero resistivity. This property alone is quite enough to bring out the brillilant imagination. A current that would flow forever while not losing any energy suggests that transmission of power with nearly no losses within the cables. Once renewable energy sources begin to dominate the grid and high-voltage transmission across continents becomes vital to beat intermittence, lossless cables can lead to substantial savings. What’s a lot of, a superconducting wire carrying a current that ne'er, ever diminishes would act as an ideal store of power. in contrast to batteries, that degrade over time, if the resistance is actually zero, you'll come back to the superconductor during a billion years and realize that very same previous current flowing through it. Energy may well be captured and keep indefinitely! With no resistance, an enormous current may well be skilled in turn the wire that is superconducting,turn out magnetoic fields of unimaginable power.[14] CONCLUSION After reviewing on the topic superconductivity,we find that superconductivity can be new energy source for the whole mankind, even if superconductivity is discovered at the room temperature then there will be a new era of technology which will supress sources of energy such has hydro,bio-fuel and many more. ACKNOWLEDGMENTS It’s my pleasure to thank Mr. Amanparteek Singh and Rajiv Khullar sir for providing me constant support and suggestions. Their experience and advices were invaluable to my ability to make an accurate analysis. REFERENCE [1] John Bardeen; Leon Cooper; J. R. Schriffer (December one, 1957). "Theory of Superconductivity". Physical Review. 108 (5): 1175. Bibcode:1957PhRv..108.1175B. doi:10.1103/physrev.108.1175. ISBN 978-0-677-00080-0. Retrieved June half dozen, 2014. reprinted in Nikolaĭ Nikolaevich Bogoliubov (1963) the idea of electrical conduction, Vol. 4, CRC Press, ISBN 0677000804, p. 73 [2] John Daintith (2009). The Facts on File lexicon of Physics (4th erectile dysfunction.). Infobase commercial enterprise. p. 238. [3] John C. Gallop (1990). SQUIDS, the Josephson Effects and Superconducting natural philosophy. CRC Press. pp. 1, 20. [4] Durrant, Alan (2000). physical science of Matter. CRC Press. pp. 102–103. [5] H. K. Onnes (1911). "The resistance of pure mercury at He temperatures". Commun. Phys. Lab. Univ. Leiden. 12: 120. [6] Dirk vanDelft & Peter Kes (September 2010). "The Discovery of Superconductivity" (PDF). Physics these days. yankee Institute of Physics. sixty three (9): 38–43. Volume 8, Issue 3, 2018 46 https://pramanaresearch.org/ Pramana Research Journal ISSN NO: 2249-2976 [7] W. Meissner & R. Ochsenfeld (1933). "Ein neuer Effekt bei Eintritt der Supraleitfähigkeit". Naturwissenschaften. twenty one (44): 787–788. [8] F. London & H. London (1935). "The magnetism Equations of the Supraconductor". Proceedings of the honorary society of London
Recommended publications
  • Progress in Wire Fabrication of Iron-Based Superconductors
    Progress in wire fabrication of iron-based superconductors Yanwei Ma* Key Laboratory of Applied Superconductivity, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China Abstract: Iron-based superconductors, with Tc values up to 55 K, are of great interest for applications, due to their lower anisotropies and ultrahigh upper critical fields. In the past 4 years, great progress has been made in the fabrication of iron-based superconducting wires and tapes using the powder-in-tube (PIT) processing method, including main three types of 122, 11, and 1111 iron-based parent compounds. In this article, an overview of the current state of development of iron-based superconducting wires and tapes is presented. We focus on the fabrication techniques used for 122 pnictide wires and tapes, with an emphasis on their meeting the critical current requirements for making high-performance conductors, such as a combination of using Ag sheath, addition element and optimized heat treatment to realize high Jc, ex situ process employed to reduce non-superconducting phases and to obtain a high relative density, and a texture control to improve grain connectivity. Of particular 4 2 interest is that so far transport Jc values above 10 A/cm at 4.2 K and 10 T are obtained in 122 type tapes, suggesting that they are prospective candidates for high-field applications. Finally, a perspective and future development of PIT pnictide wires are also given. * E-mail: [email protected] 1 Contents 1. Introduction ...........................................................................................................
    [Show full text]
  • Selected High-Temperature Superconducting Electric Power Products
    Selected High-Temperature Superconducting Electric Power Products Prototypes are outperforming design goals full-scale utility applications are moving onto the power system and ... Modernizing the Existing Electricity Infrastructure Superconductivity Program for Electric Systems•• Office of Power Delivery U.S. Department of Energy January 2000 HIGH TEMPERATURE SUPERCONDUCTING POWER PRODUCTS CAPTURE THE ATTENTION OF UTILITY ENGINEERS AND PLANNERS Soon superconductors could be so common that we will drop the “super” and refer to them simply as conductors Critical Role of Wire The application of superconductors to electric power systems has been pursued for more than 30 years. This persistence is starting to pay off and utilities that once politely acknowledged the long-term potential of superconducting applications are now paying close attention to several prototype devices that are being tested or are nearing testing on utility systems. What has prompted this interest is the development of electric wires that become superconducting when cooled to the affordable operating-temperature realm of liquid nitrogen as well as the development of coils, magnets, conductors, and machines and power components made with these wires. Superconducting wires have as much as 100 times the current carrying capacity as (Courtesy of American Superconductor Corp.) ordinary conductors. Flexible HTS conductors promise reduced A Real Need operating costs and many other benefits when incorporated into electric power devices. They can change the way power is managed and The timing is right for superconducting solutions consumed. to emerging business problems. Power generation and transmission equipment is aging and must be replaced. Environmental considerations are increasing. Utilities are changing the way they evaluate capital investments.
    [Show full text]
  • Sn and Ti DIFFUSION, PHASE FORMATION, STOICHIOMETRY, and SUPERCONDUCTING PROPERTIES of INTERNAL-Sn-TYPE Nb3sn CONDUCTORS
    Sn AND Ti DIFFUSION, PHASE FORMATION, STOICHIOMETRY, AND SUPERCONDUCTING PROPERTIES OF INTERNAL-Sn-TYPE Nb3Sn CONDUCTORS A Thesis Presented in Partial Fulfillment of the Requirements for The Degree of Master of Science in the Graduate School of the Ohio State University By Rakesh Kumar Dhaka, B. Tech. ***** The Ohio State University 2007 Masters Examination Committee Professor Mike Sumption, Adviser Professor John Morral, Adviser Professor Katharine Flores ABSTRACT In the present work the diffusion of Sn through the interfilamentary matrix within a subelement and the formation of the associated Cu-Sn intermetallics were observed experimentally for several different Nb3Sn internal-Sn type strands during the pre- reaction part of the heat treatment. An analytical-based model was then developed to determine the time and temperature dependence of Sn-diffusion through the Cu matrix of Nb3Sn subelements. The output of the model is in the form of radial positions of , and phases as a function of time during pre-reaction heat treatment process. These predicted radial positions can be used to determine the optimum heat treatment parameters. The model was then compared to the experimental results. Experimental results for Ti-bearing superconductor strands were also discussed. Following the pre-reaction heat treatment studies, the effects of Titanium doping in presence of Tantalum on the kinetics of Nb3Sn formation and superconducting properties of internal-tin type strands were examined. A series of internal-tin type Nb3Sn sublements which had Nb-7.5wt%Ta filaments and various levels of Ti doping were investigated. Titanium was introduced into the Sn core of the subelements such that the core contained 0 at% to 2.8 at% Ti before reaction.
    [Show full text]
  • Structure-Property Relationships of Layered Oxypnictides
    AN ABSTRACT OF THE DISSERTATION OF Sean W. Muir for the degree of Doctor of Philosophy in Chemistry presented on April 17, 2012. Title: Structure-property Relationships of Layered Oxypnictides Abstract approved:______________________________________________________ M. A. Subramanian Investigating the structure-property relationships of solid state materials can help improve many of the materials we use each day in life. It can also lead to the discovery of materials with interesting and unforeseen properties. In this work the structure property relationships of newly discovered layered oxypnictide phases are presented and discussed. There has generally been worldwide interest in layered oxypnictide materials following the discovery of superconductivity up to 55 K for iron arsenides such as LnFeAsO1-xFx (where Ln = Lanthanoid). This work presents efforts to understand the structure and physical property changes which occur to LnFeAsO materials when Fe is replaced with Rh or Ir and when As is replaced with Sb. As part of this work the solid solution between LaFeAsO and LaRhAsO was examined and superconductivity is observed for low Rh content with a maximum critical temperature of 16 K. LnRhAsO and LnIrAsO compositions are found to be metallic; however Ce based compositions display a resistivity temperature dependence which is typical of Kondo lattice materials. At low temperatures a sudden drop in resistivity occurs for both CeRhAsO and CeIrAsO compositions and this drop coincides with an antiferromagnetic transition. The Kondo scattering temperatures and magnetic transition temperatures observed for these materials can be rationalized by considering the expected difference in N(EF)J parameters between them, where N(EF) is the density of states at the Fermi level and J represents the exchange interaction between the Ce 4f1 electrons and the conduction electrons.
    [Show full text]
  • High Performance Magnesium Diboride (Mgb ) Superconductors
    High Performance Magnesium Diboride (MgB2) Superconductors: Towards the Prospect for Commercialization M.S.A. Hossain (ARC DECRA Fellow) The Australian National University– 16/04/2014 Research Programs at ISEM/AIIM Faculty . Applied Superconductivity Group • Bulk • Wire • Tape • Cable • Thin Film . Energy Storage Group . Spintronics and Electronic Materials Group . Thin Film Technology Group . Terahertz Science, Solid State Physics Group . Nanostructure Materials Group . Advanced Photovoltaic Materials Group ISEM Performance Profile highlight ISEM Team: 40 research staff (12 ARC fellows) and more than 80 PhD Seven research program centred on energy and electronics Electrification Program leader in Automotive CRC 2020 More than 50% citations in Li ion battery and superconductivity from ISEM in Australia ISEM is ranked at first place in magnesium diboride supercondcutors and eighth place in Li ion battery research in terms of outputs since 2001 105 PhD graduates widely spread across five continents since 1994 50 ARC fellowship awards to ISEM since 1995 80 ARC projects since 2000 12% publications, 15% ARC funding and 24% citations of UoW are from ISEM $80m for building & $20m for facilities for research infrastructure Member of CoE, ANFF and Flagship Bao Steel Joint Centre with other 3 Universities; Network with more than 50 institutions world-wide Strong links with more than 10 industry partners ERA assessment ranked at 5 for materials engineering, materials chemistry, physical chemistry and interdisciplinary engineering of UOW Superconductivity? Applications • Making a good superconducting product is a formidable interdisciplinary problem Wire cost Wire performance Engineering Cryogenics MgB2 Very simple crystal structure Very high current densities Polycristalline materials observed in films carry large currents Moderately high Tc Tc of 39K Factor of 10 larger than in bulks; room for large improvement in wires still available from R&D MgB2 presents very Good mechanical properties Potentially high critical field 60 1.2 promising features Sample No.
    [Show full text]
  • (Nb-Ti) Superconducting Joints for Persistent-Mode Operation
    www.nature.com/scientificreports OPEN Niobium-titanium (Nb-Ti) superconducting joints for persistent-mode operation Received: 21 June 2019 Dipak Patel1,2, Su-Hun Kim1,3, Wenbin Qiu1, Minoru Maeda4, Akiyoshi Matsumoto2, Accepted: 26 August 2019 Gen Nishijima2, Hiroaki Kumakura2, Seyong Choi4 & Jung Ho Kim1 Published: xx xx xxxx Superconducting joints are essential for persistent-mode operation in a superconducting magnet system to produce an ultra-stable magnetic feld. Herein, we report rationally designed niobium- titanium (Nb-Ti) superconducting joints and their evaluation results in detail. For practical applications, superconducting joints were fabricated by using a solder matrix replacement method with two types of lead-bismuth (Pb-Bi) solder, including Pb42Bi58 as a new composition. All the joints attained a critical current of >200 A below 1.43 T at 4.2 K. Our optimized superconducting joining method was tested in a closed-loop coil, obtaining a total circuit resistance of 3.25 × 10−14 Ω at 4.2 K in self-feld. Finally, persistent-mode operation was demonstrated in an Nb-Ti solenoid coil with a persistent-current switch. This work will pave the way to developing high-performance Nb-Ti superconducting joints for practical applications. Superconducting magnets are used to produce a strong magnetic feld in a compact system, which otherwise cannot be attained using conventional copper (Cu) based magnets. Niobium-titanium (Nb-Ti) with a critical temperature (Tc) of 9.2 K is usually used to fabricate superconducting magnets for various practical applications. One of the distinct features of Nb-Ti that makes it ideal for most commercial applications is the possibility to produce reliable “superconducting joints”.
    [Show full text]
  • Thermal Analysis and Simulation of the Superconducting Magnet in the Spinquest Experiment at Fermilab
    Thermal Analysis and Simulation of the Superconducting Magnet in the SpinQuest Experiment at Fermilab Z. Akbar∗and D. Keller† University of Virginia November 18, 2020 Abstract The SpinQuest experiment at Fermilab aims to measure the Sivers asymmetry for theu ¯ and d¯ sea quarks in the range of 0.1 < xB < 0.5 using the Drell-Yan production of dimuon pairs. A nonzero Sivers asym- metry would provide an evidence for a nonzero orbital angular momentum of sea quarks. The proposed beam intensity is 1.5 × 1012 of 120 GeV unpo- larized proton/sec. The experiment will utilize a target system consisting 4 of a 5T superconducting magnet, NH3 and ND3 target material, a He evaporation refrigerator, a 140 GHz microwave source and a large pump- ing system. The expected average of the target polarization is 80% for the proton and 32% for the deuteron. The polarization will be measured with three NMR coils per target cell. A quench analysis and simulation of the superconducting magnet is performed to determine the maximum intensity of the proton beam be- fore the magnet transitions to a resistive state. Simulating superconduc- tor as they transition to a quench is notoriously very difficult. Here we approach the problem with the focus on producing an estimate of the maximum allowable proton beam intensity given the necessary instru- mentation materials in the beam-line. The heat exchange from metal to helium goes through different transfer and boiling regimes as a function of temperature, heat flux, and transferred energy. All material proper- ties are temperature dependent. A GEANT-4 based simulation is used to calculate the heat deposited in the magnet and the subsequent cooling processes are modeled using the COMSOL Multiphysics simulation pack- age.
    [Show full text]
  • Creating New Superconducting & Semiconducting Nanomaterials And
    Scholars' Mine Doctoral Dissertations Student Theses and Dissertations Summer 2013 Creating new superconducting & semiconducting nanomaterials and investingating the effect of reduced dimensionality on their properties Sukhada Mishra Follow this and additional works at: https://scholarsmine.mst.edu/doctoral_dissertations Part of the Chemistry Commons Department: Chemistry Recommended Citation Mishra, Sukhada, "Creating new superconducting & semiconducting nanomaterials and investingating the effect of reduced dimensionality on their properties" (2013). Doctoral Dissertations. 2060. https://scholarsmine.mst.edu/doctoral_dissertations/2060 This thesis is brought to you by Scholars' Mine, a service of the Missouri S&T Library and Learning Resources. This work is protected by U. S. Copyright Law. Unauthorized use including reproduction for redistribution requires the permission of the copyright holder. For more information, please contact [email protected]. CREATING NEW SUPERCONDUCTING & SEMICONDUCTING NANOMATERIALS AND INVESTINGATING THE EFFECT OF REDUCED DIMENSIONALITY ON THEIR PROPERTIES by SUKHADA MISHRA A DISSERTATION Presented to the Faculty of the Graduate School of the MISSOURI UNIVERSITY OF SCIENCE AND TECHNOLOGY In Partial Fulfillment of the Requirements for the Degree DOCTOR OF PHILOSOPHY in CHEMISTRY 2013 Approved by Dr. Manashi Nath, Advisor Dr. Philip Whitefield Dr. Nicholas Leventis Dr. Jeffrey Winiarz Dr. Matthew O’Keefe © 2013 Sukhada Mishra All rights reserved iii PUBLICATION DISSERTATION OPTION This dissertation consists of two published articles, two articles which have been submitted for publication and one manuscript in preparation. Paper I, found on pages 52—88, is published in ‗ACS Nano‘. Paper II included in pages 89—109, has been submitted for publication to ‗Advanced Materials‘. Paper III, found on pages 110—135, is published in ‗Nano Energy‘.
    [Show full text]
  • Synthesis and Characterization of Superconducting Ferropnictide Bulks and Wires Jeremy Weiss
    Florida State University Libraries Electronic Theses, Treatises and Dissertations The Graduate School 2015 Synthesis and Characterization of Superconducting Ferropnictide Bulks and Wires Jeremy Weiss Follow this and additional works at the FSU Digital Library. For more information, please contact [email protected] FLORIDA STATE UNIVERSITY THE GRADUATE SCHOOL SYNTHESIS AND CHARACTERIZATION OF SUPERCONDUCTING FERROPNICTIDE BULKS AND WIRES By JEREMY WEISS A Dissertation submitted to the Department of Materials Science and Engineering in partial fulfillment of the requirements for the degree of Doctor of Philosophy Degree Awarded: Spring Semester, 2015 Jeremy Weiss defended this dissertation on April 9, 2015. The members of the supervisory committee were: Eric Hellstrom Professor Directing Dissertation Gregory Boebinger University Representative David Larbalestier Committee Member Theo Siegrist Committee Member Per Arne Rikvold Committee Member The Graduate School has verified and approved the above-named committee members, and certifies that the dissertation has been approved in accordance with university requirements. ii This dissertation is dedicated to the memory of Professor James Brooks who served on this dissertation advisory committee until his passing in Fall 2014 iii ACKNOWLEDGMENTS Firstly, I would like to thank David Larbalestier for giving me the undergraduate opportunity to do the preliminary lab work that sparked an interest in applied research and ultimately lead to the following dissertation. To vaguely paraphrase the first toast of his I heard; an observation relevant to my developing career: “We never could have guessed that we would have ended up here, but we stumble through life as opportunities present themselves and it really is fascinating how it seems to work out for us.” It was David who introduced me to Jianyi Jiang who mentored me for two and a half years as an undergraduate.
    [Show full text]
  • Numerical Studies of Iron Based Superconductors Using Spin- Fermion Models
    University of Tennessee, Knoxville TRACE: Tennessee Research and Creative Exchange Doctoral Dissertations Graduate School 12-2017 Numerical Studies of Iron Based Superconductors using Spin- Fermion Models Christopher Brian Bishop University of Tennessee, Knoxville, [email protected] Follow this and additional works at: https://trace.tennessee.edu/utk_graddiss Part of the Condensed Matter Physics Commons Recommended Citation Bishop, Christopher Brian, "Numerical Studies of Iron Based Superconductors using Spin-Fermion Models. " PhD diss., University of Tennessee, 2017. https://trace.tennessee.edu/utk_graddiss/4735 This Dissertation is brought to you for free and open access by the Graduate School at TRACE: Tennessee Research and Creative Exchange. It has been accepted for inclusion in Doctoral Dissertations by an authorized administrator of TRACE: Tennessee Research and Creative Exchange. For more information, please contact [email protected]. To the Graduate Council: I am submitting herewith a dissertation written by Christopher Brian Bishop entitled "Numerical Studies of Iron Based Superconductors using Spin-Fermion Models." I have examined the final electronic copy of this dissertation for form and content and recommend that it be accepted in partial fulfillment of the equirr ements for the degree of Doctor of Philosophy, with a major in Physics. Adriana Moreo, Major Professor We have read this dissertation and recommend its acceptance: Elbio Dagotto, Steve Johnston, Takeshi Egami Accepted for the Council: Dixie L. Thompson Vice Provost and Dean of the Graduate School (Original signatures are on file with official studentecor r ds.) Numerical Studies of Iron Based Superconductors using Spin-Fermion Models A Dissertation Presented for the Doctor of Philosophy Degree The University of Tennessee, Knoxville Christopher Brian Bishop December 2017 c by Christopher Brian Bishop, 2017 All Rights Reserved.
    [Show full text]
  • 1 the Phase Diagrams of Iron-Based Superconductors
    The phase diagrams of iron-based superconductors: theory and experiments Les diagrammes de phases des supraconducteurs à base de fer: La théorie etles expériences A. Martinelli1,*, F. Bernardini2,3, S. Massidda3 1 SPIN-CNR, C.so Perrone 24, I-16152 Genova – Italy 2 Dipartimento di Fisica, Università di Cagliari, Cittadella Universitaria, I-09042 Monserrato - Italy 3 IOM-CNR c/o Dipartimento di Fisica, Università di Cagliari, Cittadella Universitaria, I-09042 Monserrato - Italy Abstract Phase diagrams play a primary role in the understanding of materials properties. For iron-based superconductors (Fe-SC), the correct definition of their phase diagrams is crucial because of the close interplay between their crystallo-chemical and magnetic properties, on one side, and the possible coexistence of magnetism and superconductivity, on the other. The two most difficult issues for understanding the Fe-SC phase diagrams are: 1) the origin of the structural transformation taking place during cooling and its relationship with magnetism; 2) the correct description of the region where a crossover between the magnetic and superconducting electronic ground states takes place. Hence a proper and accurate definition of the structural, magnetic and electronic phase boundaries provides an extremely powerful tool for material scientists. For this reason, an exact definition of the thermodynamic phase fields characterizing the different structural and physical properties involved is needed, although it is not easy to obtain in many cases. Moreover, physical properties can often be strongly dependent on the occurrence of micro- structural and other local-scale features (lattice micro-strain, chemical fluctuations, domain walls, grain boundaries, defects), which, as a rule, are not described in a structural phase diagram.
    [Show full text]
  • On the New Oxyarsenides Eu5zn2as5o and Eu5cd2as5o
    crystals Article On the New Oxyarsenides Eu5Zn2As5O and Eu5Cd2As5O Gregory M. Darone 1,2, Sviatoslav A. Baranets 1,* and Svilen Bobev 1,* 1 Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA; [email protected] 2 The Charter School of Wilmington, Wilmington, DE 19807, USA * Correspondence: [email protected] (S.B.); [email protected] (S.A.B.); Tel.: +1-302-831-8720 (S.B. & S.A.B.) Received: 20 May 2020; Accepted: 1 June 2020; Published: 3 June 2020 Abstract: The new quaternary phases Eu5Zn2As5O and Eu5Cd2As5O have been synthesized by metal flux reactions and their structures have been established through single-crystal X-ray diffraction. Both compounds crystallize in the centrosymmetric space group Cmcm (No. 63, Z = 4; Pearson symbol oC52), with unit cell parameters a = 4.3457(11) Å, b = 20.897(5) Å, c = 13.571(3) Å; and a = 4.4597(9) Å, b = 21.112(4) Å, c = 13.848(3) Å, for Eu5Zn2As5O and Eu5Cd2As5O, respectively. The crystal structures include one-dimensional double-strands of corner-shared MAs4 tetrahedra (M = Zn, Cd) and As–As bonds that connect the tetrahedra to form pentagonal channels. Four of the five Eu atoms fill the space between the pentagonal channels and one Eu atom is contained within the channels. An isolated oxide anion O2– is located in a tetrahedral hole formed by four Eu cations. Applying the valence rules and the Zintl concept to rationalize the chemical bonding in Eu5M2As5O(M = Zn, Cd) reveals that the valence electrons can be counted as follows: 5 [Eu2+] + 2 [M2+] + 3 × × × [As3–] + 2 [As2–] + O2–, which suggests an electron-deficient configuration.
    [Show full text]