Illite/Smectite Geothermometry of the Proterozoic Oronto Group, Midcontinent Rift System
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Clays and Clay Minerals. Vol. 41 , No. 2, 134-147, 1993. ILLITE/SMECTITE GEOTHERMOMETRY OF THE PROTEROZOIC ORONTO GROUP, MIDCONTINENT RIFT SYSTEM KIRSTEN L. PRICE AND S. DOUGLAS McDOWELL Department of Geological Engineering, Geology and Geophysics, Michigan Technological University 1400 Townsend Drive, Houghton, Michigan 49931 Abstract-Characterization of the Nonesuch Formation, middle unit of the Proterozoic Oronto Group, as a potential hydrocarbon source for the Lake Superior basin portion of the Midcontinent Rift system requires an understanding of the thermal maturity of the region and its relationship to the thermal history. Illitelsmectite (liS) expandability data were collected from the Nonesuch Formation and the overlying Freda Sandstone and compared with organic thermal maturity data; both data sets coupled with a thermal and burial history for the White Pine area ofMichigan allow regional interpretation of maximum formation temperatures of the Nonesuch Formation and the Freda Sandstone with respect to time. Samples collected from drill holes in northeastern Wisconsin display nearly pure smectite within the lower Freda Sandstone trending abruptly to ordered liS within the Nonesuch Formation. Regular trends of decreasing expand ability with depth occur in four other drill holes to the northeast. Comparison ofI/S expandability between similar stratigraphic intervals reveals a significant trend of increasing thermal maturity to the northeast, with the lowest thermal maturities observed in the Iron River Syncline area just west of White Pine, Michigan. IISgeothermometry suggests maximum temperatures in the Nonesuch Formation of 1400c in Wis consin, 1150C in the Iron River Syncline area, 160·C at White Pine, and 1900c near the southern portions of the Keweenaw Copper District. The geographic pattern of temperatures determined from li S geother mometry is identical to that determined from organic thermal maturity indicators in the Nonesuch Formation (Imbus et al., 1988, 1990; Hieshima and Pratt, 1991; Pratt et al., 1991; Mauk and Hieshima, 1992). Regular variations in liS expandability with depth occur in the Freda Sandstone and the Nonesuch Formation near the southern limits of the Keweenaw Copper District. These variations suggest a fossil geothermal gradient of 550C/ km and limit the thickness of sediment above the Nonesuch Formation to approximately 3 km. In comparison, 3.6 km of Freda Sandstone are presently exposed near the Wisconsin border, and numerical modeling suggests a range of 4-6 km of sediment overlying the Nonesuch For mation. None of the data indicate the presence of the Bayfield Group sediments above the Nonesuch Formation at the time of clay diagenesis. Samples from White Pine suggest a two-stage burial history: I) clay reaction, possible hydrocarbon maturation, and copper-sulfide mineralization at maximum temper atures above 100·C during the main rifting and burial event, followed by 2) fracturing, reverse faulting, and fluid circulation during a rift-terminating compressional event that may have allowed petroleum migration and native copper mineralization at temperatures below 100·C. Abrupt changes in liS ex pandability with depth and the presence of poorly crystalline liS (greater than 80% expandable) and kaolinite in the Freda Sandstone in Wisconsin appear to represent later overprinting of the diagenetic assemblage by fluids that were probably cooler and of differing composition than earlier diagenetic fluids. However, the authigenic assemblage from the vicinity of White Pine, Michigan, which includes up to 25% expandable liS, appears to represent a diagenetic profile formed during the main rifting and burial event. Therefore, these expandable liS-type clays are essentially 1.0 billion years old. Key Words-Diagenesis, IllitelSmectite, Mineralization, Proterozoic, Retrograde, Thermal history. cial to the evaluation of its potential as a hydrocarbon INTRODUCTION source rock. Hydrocarbon exploration in the Midcontinent Rift The great age of the Nonesuch Formation and the system of North America (Figure I) has to date yielded other units of the Upper Keweenawan Oronto Group no economic reserves of either oil or gas (Dickas, 1986). significantly reduces the availability and reliability of However, speculation regarding its potential as a fron traditional methods of assessing the thermal maturity tier oil province continues. The Nonesuch Formation and thus the thermal history of sediments. To over hosts the large stratiform copper-sulfide deposit at White come this problem, illite/smectite (I/S) expandability Pine, Michigan. Mature oil seeps occur locally within (%Exp) data were used as a thermal maturity indicator the mine raising the possibility that the Nonesuch For (e.g., Waples, 1980; Pollastro and Barker, 1986; Pol mation may provide an economic hydrocarbon source lastro, 1990) and compared with available organic within the Lake Superior region. Understanding the thermal maturity data. These results were coupled with thermal evolution of the Nonesuch Formation is cru- a calculated thermal and burial history model for White Copyright © 1993, The Clay Minerals Society 134 Vol. 41 , No. 2, 1993 liS geothermometry of the I. I-Ga Oronto Group 135 JacOb,,,1I11 S5 ... Bayfl.ld Oroup N LAKE SUPER IOR Sindstoni r ~ Coppa, "I,bor CDntllomlral1 ~ Por tlg. l8ka Volcanic. Figure I. Geologic map of the Lake Superior region of the Midcontinent Rift system (inset) and the corresponding stratigraphy. 00-5, DO-14, WPB-I, WP, and W-II refer to collar location of drill holes from which samples were taken for this study. The Presque Isle Syncline is located about 25 km west-southwest of White Pine, Michigan; drill hole WPB-I is located on the southern limb of the Iron River Syncline. Modified from Daniels (1982), Green (1983) and Imbus et at. (1988). Pine, Michigan (Price et aI., in prep.) to estimate max oldest unit of the Oronto Group, the Copper Harbor imum formation temperatures for the Nonesuch For Conglomerate, interfingers with the overlying None mation with respect to time. There are two primary such Formation and includes lava flows known as the objectives of this project: 1) assessment of the thermal Lake Shore Traps. A high-precision U-Pb date ofl094.1 maturity of the Oronto Group with respect to depth ± 3.6 Ma for the Lake Shore Traps provides the age and geographic location using IIS geothermometry, and of deposition for the middle Copper Harbor Conglom 2) comparison of IIS expandability values to organic erate (Davis and Paces, 1990). The Nonesuch For thermal maturity indicators with respect to local and mation and the Freda Sandstone exhibit a conformable regional geologic events to assess the utility of IIS ex and gradational contact frequently extending over sev pandability as a thermal maturity indicator in ancient eral meters (Daniels, 1982). sedimentary basins. To avoid complications resulting from comparison of different lithologies, the study excluded the Copper Geologic setting Harbor Conglomerate and focused on the Nonesuch The Keweenawan stratigraphy (Figure 1) of the Lake Formation and the Freda Sandstone. The Nonesuch Superior portion of the Midcontinent Rift system rep Formation consists primarily of gray to black mica resents a classic rift sequence consisting of 3 to 5 km ceous siltstone and shale lithologies. Rock fragments of Portage Lake Volcanics overlain by a minimum of and quartz dominate the detrital component. Lithic 6 km ofOronto Group rift sediments. The Keweenaw fragments include primarily mafic volcanic fragments, an section of the region also includes the Bayfield Group although silicic and intermediate volcanic fragments of northern Wisconsin and the Jacobsville Sandstone have also been identified (Hite, 1968). Twenty to SO of Upper Michigan. The relationship between the percent of the detrital component is composed of vol Oronto Group, the Bayfield Group and the Jacobsville canic rock fragments, while undulatory quartz, plagio Sandstone remains unclear, although Bayfield Group clase, potassium feldspars and opaque minerals com equivalents may rest unconformably on the Oronto prise the remaining SO to 80 percent. The most common Group units offshore beneath Lake Superior (Cannon cement is calcite, although silica, laumontite, and he et al., 1989). Exposures of the Portage Lake Volcanics matite also frequently occur (Hite, 1968). Matrix clays, and the Oronto Group occur along the Lake Superior primarily chlorite and illite (which probably includes shoreline from the Keweenaw Peninsula of Upper liS), average about 5.3% of the rock volume (Hite, Michigan, southwest into Wisconsin (Figure 1). The 1968; Vogel et al., 1976) and probably formed from 136 Price and McDowell Clays and Clay Minerals ations in compositional maturity are marked by fluc tuations in the relative percentages of quartz and vol canic fragments (Hubbard, 1975). Silicic and I intermediate volcanic fragments dominate mafic frag ments, while other common framework minerals in ~I clude potassium feldspars, plagioclase, and undiffer entiated opaque minerals (Hite, 1968). As in the ~Io . Nonesuch Formation, cements include calcite, quartz, ~I laumontite, hematite, and occasionally chlorite (Hite, 1968). Clay minerals dominate the matrix, comprising ~ about 7.8% of the rock volume (Hite, 1968). Prelim inary XRD studies of the Freda Sandstone indicate ~ that the clay composition, chlorite, illite, and liS are I very similar to that of the Nonesuch Formation (Price and McDowell, 1991).