p711-726.qxd 11/18/2002 12:47 PM Page 711

Chlorinated Pesticide Compounds Retention Time Index Data collected using 30m, 0.53mm ID, 0.50µm Rtx®-5, Rtx®-35, and Rtx®-1701 columns. Oven temp.: Rtx®-5: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 6 min.); Rtx®-35: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 16 min.); Rtx®-1701: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 6 min.); Carrier gas: heli- um; Regulation: constant pressure; Linear velocity: 40.0cm/sec. @ 100°C; Dead time: 1.250 min. @ 100°C.

Rtx®-5 Rtx®-35 Rtx®-1701 Rtx®-5 Rtx®-35 Rtx®-1701 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time DBCP 2.103 1.972 2.262 isodrin 17.605 20.569 19.923 hexachlorocyclopentadiene 3.193 3.356 3.418 heptachlor epoxide 18.24 21.352 21.536 tetradecane 3.528 2.633 3.221 captan 18.731 24.41 24.899 γ etridiazole 4.526 6.155 6.279 -chlordane 19.365 22.333 23.161 RETENTION TIME INDEXES chlorneb 5.407 7.847 8.227 endosulfan I 19.958 23.11 22.759 hexadecane 6.955 5.074 6.176 α-chlordane 20.118 23.131 23.472 propachlor 7.589 10.474 12.257 cis-nonachlor 20.341 22.654 23.608 tetrachloro-m-xylene (ISTD) 7.866 9.204 8.911 dieldrin 21.21 24.579 24.521 trifluralin 9.046 9.299 12.877 4,4'-DDE 21.295 24.513 24.03 cis-diallate 9.446 11.925 11.811 docosane 21.519 19.169 20.449 chlorpropham 9.511 10.724 13.229 endrin 22.229 26.179 25.483 α-BHC 9.673 12.784 13.763 nitrofen 22.285 26.446 27.441 trans-diallate 9.822 11.468 12.602 TOK 22.285 26.446 27.409 hexachlorobenzene 10.016 11.886 11.306 ethylan 22.531 26.131 25.292 dichloran 10.268 14.205 16.491 perthane 22.531 26.131 25.292 simazine 10.613 14.727 16.509 endosulfan II 22.695 27.181 27.926 atrazine 10.855 14.525 16.39 chlorobenzilate(a) 22.857 26.139 27.093 β-BHC 11.034 15.413 20.17 chloropropylate 22.878 25.75 26.849 γ-BHC 11.233 14.855 15.869 4,4'-DDD 23.295 27.158 27.862 lindane 11.233 14.855 15.869 trans-nonachlor 23.323 26.64 27.957 PCNB 11.428 14.284 14.418 endrin aldehyde 23.631 28.634 29.981 pronamide 11.776 13.833 17.649 kepone 23.747 26.625 25.26 Environmental Compounds octadecane 11.819 9.444 10.826 carbophenothion 24.486 28.606 28.705 dichlone 12.141 16.428 16.979 endosulfan sulfate 24.741 29.434 31.535 δ-BHC 12.433 17.207 21.072 4,4'-DDT 25.01 28.607 28.563 chlorothalonil 12.66 16.963 19.6 tetracosane 25.837 23.576 24.785 terbacil 12.767 17.497 21.225 captafol 25.933 31.856 32.7 metribuzin 14.154 18.973 19.872 endrin ketone 26.871 33.133 33.156 heptachlor 14.613 16.842 16.686 methoxychlor 27.792 32.464 31.57 alachlor 14.795 17.919 19.272 dibutylchlorendate 29.181 31.458 31.869 aldrin 16.247 18.461 17.936 mirex 29.273 32.799 30.193 metolachlor 16.547 19.571 20.95 hexacosane 29.84 27.532 28.793 eicosane 16.829 14.396 15.758 fenarimol 30.301 35.227 35.243 dicofol 16.851 20.574 20.758 rubigan 30.301 34.954 35.568 kelthane 16.851 20.574 20.758 cis-permethrin 31.912 35.558 34.886 bayleton 17.028 19.949 22.288 trans-permethrin 32.248 36.25 35.254 triadimefon 17.028 19.949 22.288 decachlorobiphenyl (ISTD) 35.131 38.949 36.977 dacthal 17.03 19.999 20.738 octacosane — 31.28 32.61 DCPA 17.03 19.999 20.738

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Chlorinated Pesticide Compounds Retention Time Index Data collected using 30m, 0.32mm ID, 0.50µm Rtx®-CLPesticides and Rtx®-CLPesticides2 columns. Oven temp.: 120°C (hold 1 min.) to 300°C @ 9°C/min.; Carrier gas: helium; Flow rate: 1.31mL/min. @ 120°C; Linear velocity: 27.62cm/sec.; Dead time: 1.810 min.; Regulation: constant pressure.

Rtx®-CLPesticides Rtx®-CLPesticides2 Rtx®-CLPesticides Rtx®-CLPesticides2 Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time 1.825 1.837 atrazine 12.184 14.491 bromodichloromethane 1.851 1.896 terbuthylazine 12.576 14.846 chlorodibromomethane 1.900 2.049 secbumeton 12.659 15.158 1,1,1,2-tetrachloroethane 2.000 2.178 isodrin 12.881 16.819 bromoform 2.054 2.688 simetryn 12.907 16.436 1,2-dibromoethane 2.071 2.075 ametryn 12.987 16.457 1,2,3-trichloropropane 2.217 2.558 pentachloronitrobenzene 13.106 14.877 DBCP 2.443 3.567 3,4-dinitrotoluene 13.221 13.637 hexachlorocyclopentadiene 4.321 6.421 heptachlor epoxide (B) 13.368 16.743 4-chloro-3-nitrobenzotrifluoride 6.020 5.826 γ-chlordane 13.652 17.181 1-bromo-2-nitrobenzene 8.049 9.037 prometryn 13.840 16.473 hexachlorobenzene 8.913 12.430 α-chlordane 13.946 17.522 diallate (cis/trans) 9.077 12.162 terbutryn 14.157 16.762 α-BHC 9.239 12.426 4,4'-DDE 14.179 17.848 diallate (cis/trans) 9.452 12.492 endosulfan I 14.215 17.673 γ-BHC 10.064 13.409 dieldrin 14.743 18.292 β-BHC 10.321 12.426 endrin 15.236 18.940 δ-BHC 10.751 14.386 4,4'-DDD 15.449 19.133 1,2-dinitrobenzene 11.216 11.937 chlorobenzilate 15.657 19.339 heptachlor 11.260 14.559 endosulfan II 15.719 19.412

RETENTION TIME INDEXES prometon 11.380 14.110 4,4'-DDT 16.009 19.832 simazine 11.503 14.463 endrin aldehyde 16.601 20.182 atraton 11.691 14.064 methoxychlor 17.105 21.264 propazine 11.819 14.551 endosulfan sulfate 17.495 20.786 aldrin 11.962 15.381 endrin ketone 18.081 22.054 tributylphosphate 12.074 12.655 triphenylphosphate 20.111 26.284

Nitrogen-Containing Pesticide Compounds Retention Time Index Data collected using 30m, 0.53mm ID, 0.50µm Rtx®-5, Rtx®-35, and Rtx®-1701 columns. Oven temp.: Rtx®-5: 150°C (hold 5 min.) to 275°C @ 4°C/min. (hold 3 min.); Rtx®-35: 150°C (hold 5 min.) to 275°C @ 4°C/min. (hold 7 min.); Rtx®-1701: 150°C (hold 5 min.) to 275°C @ 4°C/min. (hold 5 min.); Carrier gas: helium; Regulation: constant pressure; Linear velocity: 40.0cm/sec. @ 150°C; Dead time: 1.250 min. @ 150°C.

Rtx®-5 Rtx®-35 Rtx®-1701 Rtx®-5 Rtx®-35 Rtx®-1701 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time 1,3-dimethyl-2-nitrobenzene 6.12 8.975 — alachlor 27.742 31.069 32.362 dodecane 6.137 4.733 5.187 ametryn 27.842 32.084 32.592

Environmental Compounds dichlorvos 7.795 11.342 12.865 prometryn 28.112 31.828 32.397 EPTC 11.145 13.408 13.83 terbutryn 28.699 32.547 33.075 tetradecane 12.396 10.615 11.704 bromacil 29.283 34.755 38.462 butylate 13.545 14.955 15.678 metolachlor 29.602 32.72 34.082 mevinphos-cis 13.764 18.046 19.697 eicosane 29.907 27.478 28.82 vernolate 14.098 16.133 16.51 triadimefon 30.043 33.08 35.4 pebulate 14.57 16.704 17.035 MGK 264A 30.628 33.376 33.994 tebuthiuron 16.505 21.271 24.066 diphenamid 30.797 36.102 36.418 molinate 16.894 20.619 20.056 isopropalin 31.033 33.532 35.299 hexadecane 18.886 16.7 17.76 MGK 264B 31.204 34.492 — propachlor 19.424 23.206 25.016 pendamethalin 31.508 34.731 35.717 cycloate 19.967 22.63 22.559 merphos 31.557 33.359 33.221 ethoprop 20.068 23.485 24.267 stirofos 33.307 37.568 38.174 chlorpropham 20.672 23.485 26.19 butachlor 33.528 35.997 37.334 trifluralin 21.643 22.128 25.822 napropamide 33.812 38.105 38.706 benefin 21.767 22.311 25.964 fenamiphos 33.925 38.216 39.476 atraton 23.021 26.937 27.89 tricyclozole 34.198 41.331 43.369 prometon 23.368 26.99 27.861 docosane 34.638 32.233 33.558 atrazine 23.552 27.537 29.448 carboxin 34.808 40.365 40.676 propazine 23.801 27.298 29.293 oxadiazon 34.819 37.477 39.076 terbufos 24.195 26.986 27.756 oxyfluorfen 35.133 37.958 40.832 pronamide 24.484 26.902 30.725 norflurazon 38.168 43.291 46.651 profluralin 24.645 25.286 28.781 hexazinone 38.718 45.075 46.735 octadecane 24.678 22.229 23.596 tetracosane 38.955 36.632 37.9 disulfoton 25.057 28.498 29.119 triphenyl phosphate (ISTD) 39.126 43.949 43.959 Diazinon® 25.058 27.932 28.198 hexacosane 42.905 40.716 41.871 terbacil 25.654 30.658 34.349 fenarimol 43.358 48.382 49.362 metribuzin 27.074 32.106 32.976 octacosane 46.548 44.339 45.678 bimetryn 27.615 32.215 32.743 fluridone 48.914 58.305 —

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Organophosphorus Pesticide Compounds Retention Time Index Data collected using 30m, 0.32mm ID, 0.50µm Rtx®-OPP column and 30m, 0.32mm ID, 0.32µm Rtx®-OPP2 column. Oven temp.: 80°C (hold 0.5 min.) to 280°C (hold 10 min.) @ 12°C/min.; split/splitless, purge on 0.5min; Inj.: 200°C; FPD: 250°C; Dead time for Rtx®-OPP2: 1.03 min. @ 80°C; Dead time for Rtx®-OPP: 0.98min @ 80°C

Rtx®-OPP2 Rtx®-OPP Component Name Ret. Time Component Name Ret. Time dichlorvos 6.35 dichlorvos 7.19 hexamethylphosphoramide 6.94 hexamethylphosphoramide 8.66 mevinphos 8.59 trichlorfon 9.41

trichlorfon 8.68 mevinphos 9.65 RETENTION TIME INDEXES TEPP 10.27 demeton-O 10.06 demeton-O 10.44 thionazin 10.27 tributyl phosphate (SS) 10.52 ethoprop 10.67 thionazin 10.57 phorate 10.70 ethoprop 10.73 naled 11.04 naled 11.17 sulfotepp 11.04 sulfotepp 11.27 tributyl phosphate (SS) 11.09 phorate 11.36 diazinon 11.40 dicrotophos 11.50 terbufos 11.53 monocrotophos 11.66 TEPP 11.64 demeton-S 11.75 fonophos 11.64 terbufos 12.07 dioxathion 11.81 dimethoate 12.17 disulfoton 11.81 diazinon 12.25 demeton-S 11.86 dioxathion 12.30 dichlorofenthion 12.44 fonophos 12.32 chlorpyrifos methyl 12.59 disulfoton 12.48 dimethoate 12.66 phosphamidon isomer (breakdown product) 12.60 dicrotophos 12.75 dichlorofenthion 13.02 monocrotophos 12.75 Environmental Compounds phosphamidon 13.31 ronnel 12.83 chlorpyrifos methyl 13.39 merphos 12.83 parathion-methyl 13.51 chlorpyrifos 13.30 ronnel 13.54 aspon 13.35 aspon 13.87 fenthion 13.43 fenitrothion 13.97 trichloronate 13.50 malathion 14.03 phosphamidon isomer (breakdown product) 13.79 chlorpyrifos 14.15 parathion-methyl 14.01 trichloronate 14.25 malathion 14.01 parathion-ethyl 14.25 fenitrothion 14.30 fenthion 14.29 tokuthion 14.60 merphos 14.45 phosphamidon 14.68 chlorfenvinphos 14.95 chlorfenvinphos 14.73 crotoxyphos 15.12 parathion-ethyl 14.73 stirofos 15.50 merphos oxone (breakdown product) 14.76 tokuthion 15.64 stirofos 15.22 merphos oxone (breakdown product) 15.68 crotoxyphos 15.29 ethion 16.66 bolstar 15.77 fensulfothion 16.78 carbophenothion 15.90 bolstar 16.91 ethion 15.90 carbophenothion 17.08 triphenyl phosphate (SS) 16.95 famphur 17.33 leptophos 17.30 triphenyl phosphate (SS) 17.76 fensulfothion 17.44 EPN 18.35 tri-o-cresyl phosphate 17.90 phosmet 18.66 EPN 18.14 leptophos 19.11 phosmet 18.14 tri-o-cresyl phosphate 19.31 famphur 18.36 azinphos-methyl 19.63 azinphos-methyl 18.71 azinphos-ethyl 20.34 azinphos-ethyl 19.26 coumaphos 21.13 coumaphos 22.09

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Organophosphorus Pesticide Compounds Retention Time Index Data collected using 30m, 0.53mm ID, 0.50µm Rtx®-5, Rtx®-35, and Rtx®-1701 columns. Oven temp.: Rtx®-5: 125°C (hold 10 min.) to 250°C @ 4°C/min. (hold 10 min.); Rtx®-35: 125°C (hold 10 min.) to 250°C @ 4°C/min. (hold 19 min.); Rtx®-1701: 125°C (hold 10 min.) to 250°C @ 4°C/min. (hold 24 min.); Carrier gas: helium; Regulation: constant pressure; Linear velocity: 40.0cm/sec. @ 125°C; Dead time: 1.250 min. @ 125°C.

Rtx®-5 Rtx®-35 Rtx®-1701 Rtx®-5 Rtx®-35 Rtx®-1701 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time dodecane 3.171 2.442 3.025 malathion 27.568 31.774 32.837 1,3-dimethyl-2-nitrobenze 3.28 4.287 5.058 fenthion 27.826 32.585 32.606 dichlorvos 3.918 5.889 7.595 chlorpyrifos 27.898 31.489 31.521 tetradecane 7.074 5.154 6.365 parathion 27.96 31.872 33.971 mevinphos 8.475 14.425 16.532 eicosane 28.083 25.553 26.929 TEPP 14.814 20.627 23.077 trichloronate 28.526 31.186 31.769 hexadecane 15.483 12.434 14.011 merphos 29.7 31.571 31.459 demeton-O 16.153 19.99 21.042 chlorfenvinphos 30.078 34.212 34.844 ethoprop 16.892 21.016 21.871 crotoxyphos 30.688 35.302 36.199 naled 17.649 22.808 23.472 tetrachlorvinphos 31.401 35.904 36.536 dicrotophos 18.508 24.615 26.758 tokuthion 32.328 35.579 35.733 phorate 18.939 23.017 23.563 docosane 32.973 30.537 31.867 sulfotep 18.972 23.144 24.15 fensulfothion 34.414 39.916 41.682 monocrotophos 19.002 25.757 29.436 ethion 34.95 39.074 39.636 demeton-S 20.098 24.663 25.787 sulprofos 35.569 39.839 39.712 dimethoate 20.128 26.751 29.531 famphur 35.961 41.625 44.191 dioxathion 21.404 26.617 26.928 tetracosane 37.358 35.018 36.284 terbufos 21.714 24.974 25.764 triphenyl phosphate (ISTD) 37.388 42.427 42.345 octadecane 22.416 19.673 21.166 phosmet 38.616 45.903 46.276 disulfoton 22.677 26.51 27.131 EPN 38.792 44.05 45.257 RETENTION TIME INDEXES Diazinon® 22.728 26.038 26.257 azinphos-methyl 40.502 49.635 49.032 phosphamidon 24.831 29.819 32.259 hexacosane 41.382 39.074 40.334 methyl parathion 25.171 29.962 31.942 coumaphos 44.471 54.028 59.312 ronnel 25.912 29.611 29.906 octacosane 46.353 42.889 44.512

Phenoxy Acid Herbicide Methyl Ester Compounds Retention Time Index Data collected using 30m, 0.32mm ID, 0.50µm Rtx®-CLPesticides column and 30m, 0.32mm ID, 0.25µm Rtx®-CLPesticides2 column. Oven temp.: 90°C (hold 1 min.) to 300°C @ 9°C/min. (hold 10 min.); Carrier gas: helium; Flow rate: 2.1mL/min. @ 120°C; Dead time: 1.735 min.; Head pressure: 5.0psi (constant).

Rtx®-CLPesticides Rtx®-CLPesticides2 Rtx®-CLPesticides Rtx®-CLPesticides2 Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time dalapon methyl ester 3.0 2.7 4,4'-dibromooctafluorobiphenyl 14.6 13.9 1,4-dichlorobenzene 4.2 4.0 2,4,5-TP (Silvex) methyl ester 15.1 15.9 3,5-dichlorobenzoic acid methyl ester 10.0 9.9 bentazon methyl ester 15.4 18.0

Environmental Compounds 4-nitroanisole 11.2 11.0 chloramben methyl ester 15.4 16.0 DCAA methyl ester 11.7 11.9 picloram methyl ester 15.4 18.6 dicamba methyl ester 12.1 12.2 2,4,5-T methyl ester 15.6 16.7 MCPP methyl ester 12.4 12.5 2,4-DB methyl ester 16.4 15.3 MCPA methyl ester 12.7 12.9 dinoseb methyl ester 18.0 17.2 dichlorprop methyl ester 13.4 13.5 DCPA dimethyl ester 18.4 18.5 2,4-D methyl ester 13.7 14.0 acifluorfen 21.9 21.9 pentachloroanisole 14.2 14.7

Phenoxy Acid Herbicide Compounds Retention Time Index Data collected using 30m, 0.53mm ID, 0.50µm Rtx®-5, Rtx®-35, and Rtx®-1701 columns. Oven temp.: Rtx®-5: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 6 min.); Rtx®-35: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 16 min.); Rtx®-1701: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 6 min.); Carrier gas: helium; Regulation: constant pressure; Linear velocity: 40.0cm/sec. @ 100°C; Dead time: 1.250 min. @ 100°C.

Rtx®-5 Rtx®-35 Rtx®-1701 Rtx®-5 Rtx®-35 Rtx®-1701 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time dalapon 1.837 2.351 2.3 pentachlorophenol 22.413 25.816 25.3 3,5-dichlorobenzoic acid 11.935 14.775 15.264 2,4,5-TP (Silvex) 23.552 27.172 27.861 4-nitrophenol 12.17 17.22 18.909 chloramben 23.696 29.357 30.994 DCAA 15.836 19.873 20.126 2,4,5-T 24.36 28.747 29.472 dicamba 16.324 20.639 20.897 dinoseb 25.048 28.119 30.608 MCPP 17.404 20.887 21.723 2,4-DB 26.139 30.281 30.839 MCPA 17.928 22.107 22.808 bentazon 27.057 32.953 33.492 dichlorprop 19.283 23.192 23.965 picloram 28.496 35.108 36.402 2,4-D 20.089 24.621 25.378 acifluorfen 35.625 39.773 42.296 DBOB 21.523 22.813 24.681

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Semivolatile Compounds Retention Time Index Data collected using a 30m, 0.25mm ID, 0.50µm Rtx®-5MS column. Oven temp.: 40°C (hold 5 min.) to 300°C @ 10°C/min. (hold 4 min.) to 330°C @ 5°C/min. (hold 8 min.); Carrier gas: helium; Regulation: constant pressure; Linear velocity: 32.1cm/sec. @ 40°C; Dead time: 1.560 min. @ 40°C.

Rtx®-5MS Rtx®-5MS Component Name Ret. Time Component Name Ret. Time pyridine 6.83 3-nitroaniline 21.89 N-nitrosodimethylamine 7.06 acenaphthene-d10 (ISTD) 21.90 2-fluorophenol 10.75 2,4-dinitrophenol 22.07

-d6 13.05 4-nitrophenol 22.17 RETENTION TIME INDEXES phenol 13.08 dibenzofuran 22.43 2-chlorophenol-d4 13.18 2,4-dinitrotoluene 22.52 decane 13.26 hexadecane 22.67 bis(2-chloroethyl)ether 13.29 diethyl phthalate 23.09 2-chlorophenol 13.42 fluorene 23.19 1,3-dichlorobenzene 13.79 4-chlorophenyl phenyl ether 23.25 1,4-dichlorobenzene-d4 (ISTD) 13.86 2-methyl-4,6-dinitrophenol 23.52 1,4-dichlorobenzene 13.93 4-nitroaniline 23.57 1,2-dichlorobenzene-d4 14.16 N-nitrosodiphenylamine 23.58 benzyl 14.35 2,4,6-tribromophenol 24.00 1,2-dichlorobenzene 14.41 4-bromophenyl phenyl ether 24.53 2-methylphenol 14.56 hexachlorobenzene 25.03 bis(2-chloroisopropyl)ether 14.65 octadecane 25.06 m-cresol 14.79 pentachlorophenol 25.43 4-methylphenol 14.93 phenanthrene 25.74 N-nitroso-di-n-propylamine 15.03 phenanthrene-d10 (ISTD) 25.80 hexachloroethane 15.19 anthracene 25.87 nitrobenzene-d5 15.36 decafluorotriphenylphosphine 26.38 nitrobenzene 15.46 carbazole 26.45 Environmental Compounds isophorone 16.05 eicosane 27.23 2-nitrophenol 16.26 di-n-butyl phthalate 27.29 2,4-dimethylphenol 16.29 fluoranthene 28.92 bis(2-chloroethoxy)methane 16.57 docosane 29.21 benzoic acid 16.73 benzidine 29.22 2,4-dichlorophenol 16.82 pyrene 29.54 dodecane 16.91 p-terphenyl-d14 29.95 1,2,4-trichlorobenzene 17.12 tetracosane 30.99 naphthalene 17.13 butyl benzyl phthalate 31.22 naphthalene-d8 (ISTD) 17.20 hexacosane 32.80 4-chloroaniline 17.48 bis(2-ethylhexyl)phthalate 32.81 hexachlorobutadiene 17.71 benzo(a)anthracene 32.83 4-chloro-3-methylphenol 18.64 3,3'-dichlorobenzidine 32.84 2-methylnaphthalene 19.09 chrysene 32.99 hexachlorocyclopentadiene 19.67 chrysene-d12 (ISTD) 33.01 2,4,6-trichlorophenol 19.85 octacosane 35.19 2,4,5-trichlorophenol 19.96 benzo(b)fluoranthene 37.02 tetradecane 19.98 benzo(k)fluoranthene 37.16 fluorobiphenyl 20.06 di-n-octyl phthalate 37.19 2-chloronaphthalene 20.36 benzo(a)pyrene 38.39 2-nitroaniline 20.78 perylene-d12 (ISTD) 38.81 dimethyl phthalate 21.23 dibenzo(a,h)anthracene 42.76 acenaphthylene 21.38 indeno(1,2,3-cd)pyrene 42.93 2,6-dinitrotoluene 21.48 benzo(g,h,i)perylene 43.89 acenaphthene 21.86

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PCB Compounds Retention Time Index Data collected using a 60m, 0.25mm ID, 0.25µm Rtx®-5 column; Oven: 75°C (hold 2 min.) @ 15°C/min to 150°C @ 1.2°C/min to 300°C; Carrier gas: helium; Regulation: constant pressure; Linear velocity: 30.0cm/sec @ 75°C; Dead time: 3.33 min. @ 75°C.

Rtx®-5 Rtx®-5 Rtx®-5 Rtx®-5 Component Name Ret. Time Component Name Ret. Time Component Name Ret. Time Component Name Ret. Time Biphenyl 15.453 3,3',4 47.223 2,2',4,4',5 58.491 2,2',3,4,5,6,6' 73.598 2 19.801 2,2',3,5' 47.746 2,2',3,4',6,6' 59.13 2,3,3',4,5,6 73.649 3 22.894 2,3,3',6 48.086 2,3',4,4',6 59.239 2,3,3',4',5,6 73.649 4 23.233 2,2',3,4' 48.246 2,3,3',5,6 59.395 12,3,3',4',5',6 73.69 2,2' 25.166 3,4,4' 48.472 2,3,3',4,6 59.652 2,2',3,4,4',5' 73.732 2,6 25.166 2,2',3,4 49.329 2,2',3,5,6,6' 60.102 2,3,3',4,4',6 74.025 2,4 27.738 2,3',4',6 49.336 2,2',3',4,5 60.309 2,2',3,3',4,5 74.914 2,5 27.738 2,3',5,5' 49.336 2,3,4,5,6 60.728 2,2',3,3',5,5',6 75.002 2,3' 28.805 2,3,4',6 49.571 2',3,4,5,6' 60.816 3,3',4,4',5 75.174 2,3 29.53 2,3',4,5' 50.011 2,3,4',5,6 60.883 2,3,4,4',5,6 75.723 2,4' 29.53 2,2',3,3' 50.616 2,2',3,4,6,6' 60.936 2,2',3,3',4,5',6 75.762 3,5 31.157 2,3,3',5 51.104 2,3,4,4',6 61.068 2,2',3,4,4',5,6' 76.234 2,2',6 31.764 2,3',4,5 51.655 2,3,3',5,5' 61.44 2,2',3,4',5,5',6 76.234 2,4,6 32.7 2,3,3',5' 52.186 2,2',3,4',5,6' 61.856 2,3,3',4,5,5' 76.651 3,3' 33.511 2,3,4',5 52.19 2,3',4,5,5' 61.863 2,2',3,4,4',5',6 76.98 3,4 34.319 2,2',3,5,6' 52.442 2,2',3,3',6,6' 61.988 2,3,3',4',5,5' 77.576 3,4' 34.385 2,3,4,5 52.793 2,3,3',4',6 62.565 2,2',3,3',4,4' 77.85 2,2',5 34.425 2,4,4',5 52.878 2,2',4,4',5,6' 62.881 2,3',4,4',5,5' 78.443 2,2',4 34.728 2,3',4',5 53.406 2,2',3,5,5',6 64.283 2,2',3,4,5,5',6 78.482 2,3,6 35.635 2',3,4,5 53.406 2,2',3,3',5,6' 64.957 2,2',3,3',4,5,6' 79.603 2,3',6 35.758 2,2',3,5,6 53.585 2,2',3,4,5',6 64.957 2,2',3,4,4',5,6 79.634

RETENTION TIME INDEXES 2,2',3 36.729 2,3',4,4' 53.872 2',3,4,5,5' 65.387 2,2',3,3',4',5,6 80.474 2,4',6 36.729 2,2',3,5',6 53.885 2,2',3,4',5,6 65.452 2,2',3,3',4,4',6 81.05 2',3,5 37.945 3,3',5,5' 54.058 2,3,3',4,5' 65.793 2,2',3,3',4,5,6 81.367 2,3,5 38.049 2,2',3,4,6 54.146 2,3,3',4',5 65.799 2,3,3',4,4',5 81.679 2,2',6,6' 38.234 2,2',3,4',6 54.68 2,2',3,4',5',6 66.07 2,3,3',4,4',5' 82.565 2,4,5 38.279 2,3,3',4 55.136 2',3,4,4',5 66.123 2,2',3,3',4,5,5' 82.886 2,3',5 39.09 2,3,3',4' 56.313 2,2',3,4,4',6 66.345 2,2',3,4,4',5,5' 83.758 2,3',4 39.48 2,3,4,4' 56.313 2,2',3,4,4',6' 66.345 2,3,3',4,4',5',6 84.679 2,2',4,6 40.06 2,2',3,3',6 57.286 2,3,3',4,5 66.36 3,3',4,4',5,5' 87.665 2,4',5 40.213 2,2',3,5,5' 57.286 2,3',4,4',5 66.404 2,2',3,3',4,4',5 87.787 2,4,4' 40.42 2,2',3,4,6' 57.637 2,2',3,4,5,6' 67.169 2,3,3',4,4',5,6 87.787 2,3,4 41.329 4,4' 57.89 2,2',3,3',5,6 67.319 2,3,3',4,4',5,5' 92.331 2',3,4 41.593 2,2',3,4',5 57.999 2,2',3,4,5,6 67.841 2,2',3,3',5,5',6,6' 80.872 2,3,3' 41.645 3,3',4,5' 58.563 2,2',3,3',4,6 67.889 2,2',3,3',4,5',6,6' 82.038 2,2',5,6' 41.687 2,2',3,3',5 59.745 2,2',3,3',5,5' 67.94 2,2',3,4,4',5,6,6' 82.212 2,2',4,6' 42.344 3,3',4,5 60.01 2,3,4,4',5 67.963 2,3,3',4,5,5',6 82.793 2,3,4' 42.569 2,2',3,4,5 60.365 2',3,3',4,5 68.372 2,2',3,3',4,4',6,6' 83.124 2,2',3,6 43.233 2,2',3,4,5' 61.102 2,2',3,4',5,6,6' 68.403 2,3,3',4',5,5',6 84.158 3,3',5 43.699 3,4,4',5 61.353 2,3,3',5,5',6 68.593 2,2',3,3',4,5,6,6' 85.216 Environmental Compounds 2,2',3,6' 44.353 2,2',3,4,4' 61.722 2,2',3,4',5,5' 68.894 2,2',3,3',4,5,5',6 88.647 2,3',4,6 44.7 3,3',4,4' 62.903 2,3,3',4,5',6 69.07 2,2',3,3',4,5,5',6' 89.082 3,4',5 44.799 2,2',3,3',4 64.139 2,2',3,4,4',6,6' 69.4 2,2',3,3',4,4',5',6 89.859 2,3',5',6 44.91 2,2',4,6,6' 46.332 2,2',3,3',4,6' 69.76 2,2',3,4,4',5,5',6 89.859 2,2',5,5' 44.987 2,2',3,6,6' 49.465 2,2',4,4',5,5' 69.76 2,2',3,3',4,5,5',6,6' 93.771 2,2',3,5 45.228 2,2',4,5',6 50.418 2,3',4,4',5',6 70.041 2,2',3,3',4,4',5,6 94.055 2,2',4,5' 45.642 2,2',4,4',6 51.13 2,3,3',4,4' 70.231 2,2',3,3',4,4',5,6,6' 94.911 3,4,5 45.779 2,2',3',4,6 53.343 3,3',4,5,5' 70.554 2,2',3,3',4,4',5,5' 96.977 2,2',4,4' 46.013 2,2',4,5,6' 53.521 2,2',3,3',5,6,6' 71.427 2,3,3',4,4',5,5',6 97.851 2,2',4,5 46.013 2,3',4,5',6 54.504 2,2',3,4,5,5' 71.464 2,2',3,3',4,4',5,5',6 102.107 2,4,4',6 46.013 2,2',4,4',6,6' 56.29 2,2',3,3',4,6,6' 72.399 Decachlorobiphenyl 106.43 2,3,5,6 46.281 2,2',4,5,5' 57.999 2,2',3,3',4,5' 72.404 2,3,4,6 46.415 2,3,3',5',6 58.339 2,2',3,4,4',5 72.911

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Volatile Organic Compounds Retention Time Index Data collected using a 60m, 0.25mm ID, 1.4µm Rtx®-VMS column; Oven: 40°C (hold 6 min.) to 230°C @ 14°C/min. (hold 11 min); Carrier gas: helium; Regulation: constant pressure; Flow rate: 1mL/min.; Linear velocity: 21cm/sec.; Dead time: 4.90 min.

Rtx®-VMS Rtx®-VMS Rtx®-VMS Rtx®-VMS Component Name Ret. Time Component Name Ret. Time Component Name Ret. Time Component Name Ret. Time dichlorodifluoromethane 5.52 methyl acrylate 13.87 4-methyl-2-pentanone 17.76 trans-1,4-dichloro-2- 21.40 chloromethane 6.26 carbon tetrachloride 13.94 2-bromo-1-chloropropane 17.81 2-chlorotoluene 21.40 vinyl chloride 6.54 tetrahydrofuran 14.03 2-nitropropane 17.83 4-chlorotoluene 21.61 water 6.70 1,1,1-trichloroethane 14.06 pyridine 17.86 cyclohexane 21.78

bromomethane 7.61 ethyl acetate 14.13 1,1-dichloropropanone 17.88 tert-butylbenzene 21.81 RETENTION TIME INDEXES 7.93 2-butanone 14.18 trans-1,3-dichloropropene 17.88 1-ethyl-2-methylbenzene 21.82 2-methylbutane 7.96 dibromofluoromethane 14.18 tetrachloroethene 17.89 1,2,4-trimethylbenzene 21.88 8.00 1,1-dichloropropene 14.20 ethyl methacrylate 17.92 pentachloroethane 21.92 trichlorofluoromethane 8.41 propargyl alcohol 14.35 1,1,2-trichloroethane 18.11 1,3-dichloro-2-propanol 22.05 n-pentane 8.61 1-chlorobutane 14.51 dibromochloromethane 18.40 sec-butylbenzene 22.06 diethylether 9.59 2,2,4-trimethylpentane 14.53 1,3-dichloropropane 18.49 isocaproic acid 22.09 1,1-dichloroethene 9.64 propionitrile 14.59 isobutyric acid 18.55 p-isopropyltoluene 22.22 carbon disulfide 9.65 14.60 1,2-dibromoethane 18.78 1,3-dichlorobenzene 22.53 Freon® 113 9.70 n-heptane (C7) 14.62 n-butyl acetate 18.80 caproic acid 22.55 ethanol 9.74 methacrylonitrile 14.64 2-hexanone 18.82 1,4-dichlorobenzene 22.64 iodomethane 9.99 benzene-d6 14.72 butyric acid 19.17 n-butylbenzene 22.88 3-chlorotrifluoropropane 10.45 pentafluorobenzene 14.75 1-chloro-3-fluorobenzene 19.17 malononitrile 22.89 chloro-methyl-methylether 10.54 1,2-dichloroethane-d4 14.79 ethylbenzene 19.36 benzyl chloride 23.23 acrolein 10.57 1,2-dichloroethane 14.90 chlorobenzene 19.39 1,2-dichlorobenzene-d4 23.36 2-methylpentane 10.59 tert-amyl-methyl ether 15.00 1-chloro-4-fluorobenzene 19.39 1,2-dichlorobenzene 23.38 allyl chloride 10.72 isobutyl alcohol 15.06 ethylbenzene-d10 19.40 hexachloroethane 23.63 methylene chloride 10.98 fluorobenzene 15.16 1-chlorohexane 19.41 1-octanol 23.70 3-methylpentane 11.09 isopropyl acetate 15.34 1,1,1,2-tetrachloroethane 19.44 bis-(2-chloro-isopropyl) ether 24.06 Environmental Compounds 11.24 formic acid 15.37 m-xylene 19.53 4-bromo-1-chlorobenzene 24.09 trans-1,2-dichloroethene 11.24 trichloroethene 15.39 p-xylene 19.54 benzyl alcohol 24.23 methyl tert-butyl ether 11.42 1,4-difluorobenzene 15.58 chlorobenzene-d5 19.55 heptanoic acid 24.29 2-propanol 11.52 n-butanol 15.60 1-chloro-2-fluorobenzene 19.67 n-dodecane 24.54 tert-butyl alcohol 11.56 methyl cyclohexane 15.78 o-xylene 20.13 3-bromochlorobenzene 24.61 methyl acetate 11.63 acetic acid 15.93 stryrene 20.17 1,2-dibromo-3-chloropropane 24.78 hexane 11.64 dibromomethane 16.05 isovaleric acid 20.18 2-bromochlorobenzene 25.54 acetonitrile 12.22 1,2-dichloropropane 16.17 bromoform 20.30 hexachlorobutadiene 25.99 chloroprene 12.30 bromodichloromethane 16.23 isopropylbenzene 20.51 nitrobenzene 26.02 1,1-dichloroethane 12.42 methyl methacrylate 16.28 1,2-butanediol 20.82 1,2,4-trichlorobenzene 26.19 acrylonitrile 12.60 α,α,α-trifluorotoluene 16.45 valeric acid 20.89 benzyl acetate 26.29 diisopropyl ether 12.62 1,4-dioxane 16.49 1,4-dichlorobutane 20.90 n-tridecane 26.51 2,4-dimethylpentane 12.68 n-propyl acetate 16.70 bromobenzene 20.91 naphthalene 27.01 vinyl acetate 13.02 2-chloroethyl-vinyl-ether 16.92 4-bromo-1-fluorobenzene 20.95 1,2,3-trichlorobenzene 27.46 ethyl-tert-buyl ether 13.08 2-chloroethanol 16.93 cis-1,4-dichloro-2-butene 20.97 n-tetradecane 28.83 1-propanol 13.18 cis-1,3-dichloropropene 17.04 n-decane 21.04 2-methylnaphthalene 30.36 cis-1,2-dichloroethene 13.32 1-bromo-2-chloroethane 17.05 n-propylbenzene 21.07 1-methyl-naphthalene 30.96 allyl alcohol 13.35 n-octane 17.17 1,1,2,2-tetrachloroethane 21.10 n-pentadecane 31.65 2,2-dichloropropane 13.48 -d8 17.28 1,3,5-trimethylbenzene 21.30 2-chloronaphthalene 33.36 bromochloromethane 13.62 toluene 17.36 1-ethyl-4-methylbenzene 21.33 chloroform 13.75 propionic acid 17.61 1-ethyl-3-methylbenzene 21.34 cyclohexane 13.84 chloroacetonitrile 17.64 1,2,3-trichloropropane 21.39

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Volatile Retention Time Index Data collected using 60m, 0.53mm ID, 3.0µm columns (phase as indicated); Oven: 35°C (hold 9 min.) to 220°C @ 11°C/min. (hold 10 min); Carrier gas: helium; Regulation: constant pressure; Flow rate: 10mL/min.; Linear velocity: 56cm/sec.; Dead time: 1.800 min.

Component Name Rtx®-VGC Rtx®-502.2 Rtx®-VRX Rtx®-624 Rtx®-1 dichlorodifluoromethane 2.31 2.18 2.54 2.59 2.16 chloromethane 2.64 2.51 2.75 2.94 2.30 vinyl chloride 2.78 2.67 2.99 3.16 2.51 bromomethane 3.35 3.35 3.46 3.86 2.89 chloroethane 3.58 3.44 3.66 4.07 3.04 trichlorofluoromethane 3.83 3.91 4.50 4.56 3.80 1,1-dichloroethene 4.83 4.93 5.32 5.75 4.74 Freon® 113 4.91 4.61 5.77 5.68 4.93 methylene chloride 6.10 6.02 5.68 7.39 4.62 trans-1,2-dichloroethene 6.49 6.78 7.07 8.07 5.85 methyl tert-butyl ether 6.80 6.67 7.68 8.21 6.28 tert-butyl alcohol 7.19 5.76 5.99 8.40 4.62 1,1-dichloroethane 8.10 8.08 7.74 9.74 6.16 cis-1,2-dichloroethene 9.80 10.14 9.47 11.51 7.59 2,2-dichloropropane 10.10 10.01 10.24 11.37 8.22 bromochloromethane 10.33 11.05 9.88 12.13 7.91 chloroform 10.61 10.65 10.11 12.38 8.21 carbon tetrachloride 10.87 12.31 12.60 12.87 11.39 1,1,1-trichloroethane 11.07 11.68 11.85 12.59 10.28 1,1-dichloropropene 11.39 12.09 12.31 12.98 10.89 benzene 11.97 12.72 12.70 13.43 11.13 1,2-dichloroethane 12.44 12.73 11.67 13.70 8.78

RETENTION TIME INDEXES fluorobenzene 12.90 13.22 13.24 14.11 11.70 trichloroethene 13.24 14.08 14.09 14.83 12.89 dibromomethane 14.03 14.97 13.89 15.63 12.47 1,2-dichloropropane 14.25 14.44 14.00 15.39 12.51 bromodichloromethane 14.39 14.92 14.20 15.94 12.83 2-chloroethylvinylether 15.48 15.57 14.92 16.52 13.80 cis-1,3-dichloropropene 15.54 15.96 15.46 16.76 14.18 toluene 15.95 16.53 16.74 17.23 15.48 tetrachloroethene 16.58 17.67 17.92 18.13 16.94 trans-1,3-dichloropropene 16.61 16.87 16.23 17.78 14.91 2-bromo-1-chloropropane 16.71 17.13 16.48 17.88 15.46 1,1,2-trichloroethane 16.91 17.13 16.45 18.10 15.13 dibromochloromethane 17.18 18.01 17.20 18.71 16.03 1,3-dichloropropane 17.36 17.57 16.86 18.38 15.33 1,2-dibromoethane 17.56 18.35 17.58 18.92 16.34 chlorobenzene 18.42 19.05 18.97 19.69 17.79 ethyl benzene 18.47 19.15 19.31 19.79 18.26 1,1,1,2-tetrachloroethane 18.53 19.13 18.87 19.83 17.78 m-xylene 18.69 19.28 19.62 19.98 18.48 Environmental Compounds p-xylene 18.71 19.28 19.62 19.99 18.48 1-chloro-2-fluorobenzene 19.08 19.44 19.14 20.20 18.16 o-xylene 19.37 20.01 20.22 20.66 19.07 styrene 19.45 20.04 20.10 20.69 18.93 bromoform 19.49 20.56 19.96 21.08 18.58 isopropyl benzene 19.86 20.60 20.77 21.23 19.80 bromobenzene 20.47 21.30 21.09 21.83 19.92 n-proplyl benzene 20.51 21.22 21.43 21.89 20.46 1,4-dichlorobutane 20.56 20.71 19.95 21.54 18.94 1,1,2,2-tetrachloroethane 20.62 20.83 20.21 21.84 19.06 2-chlorotoluene 20.76 21.47 21.55 22.10 20.42 1,3,5-trimethylbenzene 20.81 21.52 21.88 22.17 20.75 1,2,3-trichloropropane 20.84 21.08 20.42 21.93 19.22 4-chlorotoluene 21.03 21.59 21.67 22.28 20.52 tert-butylbenzene 21.32 22.04 22.26 22.69 21.31 1,2,4-trimethylbenzene 21.42 22.11 22.44 22.78 21.32 sec-butylbenzene 21.60 22.38 22.59 23.04 21.69 p-isopropyl toluene 21.81 22.60 22.87 23.26 21.91 1,3-dichlorobenzene 21.95 22.77 22.66 23.33 21.54 1,4-dichlorobenzene 22.09 22.93 22.77 23.48 21.64 n-butylbenzene 22.47 23.25 23.46 23.92 22.53 1,2-dichlorobenzene 22.76 23.52 23.30 24.10 22.13 4-bromo-1-chlorobenzene 23.77 24.82 22.18 25.28 23.37 1,2-bromo-3-chloropropane 24.02 24.75 23.96 25.38 22.78 hexachlorobutadiene 25.03 26.37 26.42 26.82 25.55 1,2,4-trichlorobenzene 25.13 26.16 25.95 26.66 24.79 naphthalene 25.64 26.61 26.30 27.13 24.98 1,2,3-trichlorobenzene 25.94 27.04 26.63 27.57 25.41

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Volatile Compounds Retention Time Index Data collected using 105m, 0.53mm ID, 3.0µm Rtx®-502.2, Rtx®-1, and Rtx®-624 columns. Oven temp.: Rtx®-502.2: 35°C (hold 10 min.) to 220°C @ 4°C/min. (hold 2 min.), Rtx®-1: 35°C (hold 10 min.) to 220°C @ 4°C/min. (hold 2 min.), Rtx®-624: 35°C (hold 12 min.) to 220°C @ 7°C/min.; Carrier gas: helium; Regulation: constant flow; Flow rate: 10.0mL/min.

Rtx®-502.2 Rtx®-1 Rtx®-624 Rtx®-502.2 Rtx®-1 Rtx®-624 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time dichlorodifluoromethane 4.173 4.24 4.255 C8 27.186 27.642 24.868 C3 4.181 4.241 4.211 toluene-d8 27.502 24.835 24.612 chloromethane 4.838 4.513 4.857 pyridine 27.525 22.8 24.598 C4 5.136 5.319 6.321 toluene 27.78 25.081 24.768 vinyl chloride 5.159 4.872 5.243 trans-1,3-dichloropropene 28.428 24.014 25.417 RETENTION TIME INDEXES oxide 6.289 5.467 6.389 ethyl methacrylate 28.455 25.852 25.489 bromomethane 6.527 5.604 6.412 1,1,2-trichloroethane 28.925 24.384 25.829 chloroethane 6.812 5.938 6.798 2-bromo-1-chloropropane 28.965 25.018 25.569 ethanol 7.109 6.261 9.056 2-hexanone 29.03 25.778 26.326 C5 7.692 8.133 8.069 1,3-dichloropropane 29.826 25.124 26.205 trichlorofluoromethane 7.715 7.426 7.672 tetrachloroethene 30.036 27.8 25.928 8.857 8.232 8.977 dibromochloromethane 30.685 26.024 26.639 1,1,2-trichloro-1,2,2-trifluoroethane 9.142 9.745 10.044 2-picoline 31.242 27.462 26.977 acrolein 9.285 6.831 9.817 1,2-dibromoethane (EDB) 31.375 26.613 26.924 acetone 9.558 7.042 10.6 1-chlorohexane 32.066 29.717 27.831 1,1-dichloroethene 10.117 8.74 9.953 bromochloroacetonitrile 32.079 25.757 28.837 tert-butyl alcohol 10.516 8.864 13.546 C9 32.546 32.893 28.243 acetonitrile 10.661 6.571 12.909 1,1,1-trichloro-2-propanane 32.633 28.967 28.104 iodomethane 11.311 8.567 10.634 chlorobenzene-d5 32.749 29.372 27.887 methyl iodide 11.311 8.567 10.634 ethylbenzene-d10 32.756 30.191 27.934 allyl chloride 11.717 9.323 11.9 chlorobenzene 32.864 29.473 27.949 n-propylamine 11.815 9.36 11.69 ethylbenzene-d5 32.976 30.378 28.089 carbon disulfide 12.069 9.658 10.747 3-chloropropionitrile 33.001 24.824 29.176 12.169 9.001 13.034 1,1,1,2-tetrachloroethane 33.03 29.429 28.133 methylene chloride 12.169 9.001 13.034 ethylbenzene 33.087 30.476 28.118 Environmental Compounds allyl alcohol 12.659 10.215 16.115 m-xylene 33.351 30.898 28.37 methyl tert-butyl ether 12.785 12.074 13.734 p-xylene 33.354 30.961 28.358 acrylonitrile 13.429 7.947 14.158 1-chloro-2-fluorobenzene 33.68 30.232 28.605 trans-1,2-dichloroethene 13.438 11.346 13.725 malononitrile 34.623 26.078 31.796 C6 13.828 14.557 14.668 o-xylene 34.877 32.149 29.238 propargyl alcohol 14.458 11.32 18.532 styrene 34.975 31.843 29.294 di-isopropyl ether 14.874 14.602 15.745 1,3-dichloro-2-propanol 36.032 31.018 31.41 1,1-dichloroethane 15.151 11.849 15.616 bromoform 36.123 30.983 29.746 vinyl acetate 15.256 12.283 15.883 isopropylbenzene 36.139 33.718 30.014 2-butanone 16.82 12.834 17.766 cis-1,4-dichloro-2-butene 36.312 31.594 30.302 methyl ethyl ketone 16.82 12.834 17.766 1,4-dichlorobutane 36.471 31.864 30.377 propionitrile 17.053 10.733 18.167 1,1,2,2-tetrachloroethane 36.735 32.053 30.779 2,2-dichloropropane 17.337 14.659 17.506 4-bromofluorobenzene 37.004 33.318 30.426 cis-1,2-dichloroethene 17.478 13.924 17.628 1,2,3-trichloropropane 37.233 32.402 30.902 methacrylonitrile 17.837 12.732 18.505 C10 37.305 37.539 31.095 methylacrylate 17.947 14.54 18.351 trans-1,4-dichloro-2-butene 37.516 32.626 30.929 isobutyl alcohol 18.015 15.723 20.048 n-propylbenzene 37.566 35.151 30.895 chloroform 18.104 14.659 18.625 bromobenzene 37.652 33.875 30.772 pentafluorobenzene 18.628 16.371 19.273 dibromoacetonitrile 37.812 30.956 31.86 bromochloromethane 18.667 14.289 18.355 1,3,5-trimethylbenzene 38.133 35.817 31.268 THF 18.777 15.554 18.341 2-chlorotoluene 38.166 34.986 31.145 dibromofluoromethane 18.893 14.966 19.086 4-chlorotoluene 38.33 35.214 31.4 1,1,1-trichloroethane 19.575 17.042 18.972 tert-butylbenzene 39.393 37.008 31.959 cyclohexane 19.619 18.779 16.854 1,2,4-trimethylbenzene 39.521 37.033 32.089 1-chlorobutane 19.724 17.221 19.314 pentachloroethane 39.576 35.98 32.088 1,1-dichloropropene 20.163 17.808 19.448 thiophenol 39.606 35.186 31.919 carbon tetrachloride 20.502 18.493 19.333 sec-butylbenzene 40.151 37.886 32.428 1,2-dichloroethane-d4 20.726 16.133 20.04 p-isopropyltoluene 40.657 38.413 32.731 benzene-d6 20.91 17.998 19.888 1,3-dichlorobenzene 40.938 37.404 32.765 C7 20.935 21.532 20.582 1,4-dichlorobenzene-d4 41.228 37.544 32.92 1,2-dichloroethane 21.047 16.411 20.263 1,4-dichlorobenzene 41.317 37.624 32.972 benzene 21.097 18.124 19.999 C11 41.585 41.76 33.638 fluorobenzene 21.897 18.917 20.802 benzyl chloride 41.739 37.378 33.279 2-chloroethanol 21.951 17.171 23.115 n-butylbenzene 42.12 39.764 33.612 trichloroacetonitrile 22.125 33.558 30.181 bis(2-chloroisopropyl)ether 42.498 39.009 34.229 1,4-difluorobenzene 22.209 19.061 21.179 1,2-dichlorobenzene-d4 42.536 38.589 33.74 trichloroethene 23.326 20.674 21.713 1,2-dichlorobenzene 42.62 38.685 33.8 trifluorotoluene 23.607 21.311 22.527 hexachloroethane 43.898 40.901 34.244 1,2-dichloropropane 23.924 20.036 22.378 3-bromochlorobenzene 45.335 41.342 35.231 methyl methacrylate 24.233 21.258 22.632 1,2-dibromo-3-chloropropane 45.501 40.095 35.485 chloroacetonitrile 24.239 17.035 23.993 4-bromochlorobenzene 45.567 41.476 35.377 bromodichloromethane 24.743 20.545 23.045 C12 45.586 45.659 35.96 1,4-dioxane 24.808 20.645 22.644 nitrobenzene 45.742 40.282 35.992 dibromomethane 24.881 19.975 22.668 2-bromochlorobenzene 46.885 42.47 36.162 2-nitropropane 24.999 19.356 23.762 bis(2-chloroethoxy)methane 47.514 42.935 36.98 2-chloroethylvinylether 25.888 22.108 23.796 1,2,4-trichlorobenzene 48.643 44.704 37.165 dichloroacetonitrile 25.894 19.998 25.478 hexachlorobutadiene 49.219 46.558 37.418 4-methyl-2-pentanone (MIBK) 26.001 22.887 24.458 C13 49.276 49.295 38.078 epichlorohydrin 26.109 20.907 23.971 naphthalene 49.544 45.073 37.729 1,1-dichloropropanone 26.444 22.124 25.469 1,2,3-trichlorobenzene 50.481 46.076 38.23 cis-1,3-dichloropropene 26.674 22.744 24.104 C14 52.771 52.704 40.173

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Volatile Retention Time Index Data collected using a 60m, 0.53mm ID, 3.0µm columns (phase as indicated); Oven: 35°C (hold 9 min.) to 220°C @ 11°C/min. (hold 10 min); Carrier gas: helium; Regulation: constant pressure; Flow rate: 10mL/min.; Linear velocity: 56cm/sec.; Dead time: 1.800 min.

Component Name Rtx®-VGC Rtx®-1701 Rtx®-200 Rtx®-35 Rtx®-50 Rtx®-DX1 dichlorodifluoromethane 2.31 1.99 1.95 2.04 1.96 1.97 chloromethane 2.64 2.36 2.18 2.39 2.39 2.19 vinyl chloride 2.78 2.51 2.23 2.51 2.47 2.37 bromomethane 3.35 3.16 2.62 3.21 3.27 2.84 chloroethane 3.58 3.32 2.85 3.21 3.27 2.89 trichlorofluoromethane 3.83 3.45 2.85 3.46 3.25 3.46 1,1-dichloroethene 4.83 4.57 3.34 4.58 4.46 5.92 Freon® 113 4.91 4.17 3.56 3.78 3.38 4.32 methylene chloride 6.10 6.64 3.97 6.07 6.40 6.05 trans-1,2-dichloroethene 6.49 6.68 4.20 6.40 6.59 6.08 methyl tert-butyl ether 6.80 6.34 4.88 5.76 5.52 5.63 tert-butyl alcohol 7.19 7.61 4.86 5.08 5.48 5.74 1,1-dichloroethane 8.10 8.68 5.54 8.00 8.30 6.76 cis-1,2-dichloroethene 9.80 10.75 6.12 10.27 10.50 9.77 2,2-dichloropropane 10.10 10.15 7.41 9.60 9.41 7.98 bromochloromethane 10.33 11.66 6.12 11.46 12.06 11.17 chloroform 10.61 11.79 5.69 10.66 11.02 10.73 carbon tetrachloride 10.87 11.26 6.44 11.80 11.72 10.98 1,1,1-trichloroethane 11.07 11.31 7.59 11.40 11.25 10.01 1,1-dichloropropene 11.39 11.67 7.79 11.74 11.62 10.53 benzene 11.97 12.44 8.66 12.86 12.95 11.25 1,2-dichloroethane 12.44 13.38 9.52 12.90 13.60 12.36

RETENTION TIME INDEXES fluorobenzene 12.90 13.27 10.55 13.25 13.38 12.18 trichloroethene 13.24 13.79 9.52 13.93 13.98 13.04 dibromomethane 14.03 15.23 10.03 15.51 16.02 14.75 1,2-dichloropropane 14.25 14.83 12.04 14.54 14.77 13.26 bromodichloromethane 14.39 15.48 9.68 15.22 15.60 14.79 2-chloroethylvinylether 15.48 16.08 13.32 15.81 16.01 14.89 cis-1,3-dichloropropene 15.54 16.21 13.19 16.20 16.36 15.15 toluene 15.95 16.30 13.55 16.58 16.57 15.33 tetrachloroethene 16.58 16.88 13.77 17.51 17.35 16.46 trans-1,3-dichloropropene 16.61 17.39 14.47 17.16 17.45 16.25 2-bromo-1-chloropropane 16.71 17.28 14.43 17.32 17.52 15.94 1,1,2-trichloroethane 16.91 17.76 14.23 17.49 17.74 16.93 dibromochloromethane 17.18 18.28 13.30 18.50 18.86 17.66 1,3-dichloropropane 17.36 17.99 15.64 17.91 18.10 16.36 1,2-dibromoethane 17.56 18.46 14.49 18.77 19.16 17.43 chlorobenzene 18.42 18.91 16.31 19.27 19.38 17.95 ethyl benzene 18.47 18.83 16.14 19.25 19.09 17.93 1,1,1,2-tetrachloroethane 18.53 19.14 16.02 19.29 19.39 18.21 m-xylene 18.69 19.02 16.42 19.27 19.17 18.15 Environmental Compounds p-xylene 18.71 19.02 16.45 19.27 19.17 18.15 1-chloro-2-fluorobenzene 19.08 19.50 17.28 19.61 19.67 18.43 o-xylene 19.37 19.74 17.26 20.07 20.02 18.80 styrene 19.45 19.92 17.44 20.25 20.33 18.99 bromoform 19.49 20.64 15.88 21.19 21.63 20.07 isopropyl benzene 19.86 20.20 17.54 20.54 20.35 19.37 bromobenzene 20.47 21.08 18.32 21.65 21.78 20.08 n-propyl benzene 20.51 20.87 18.20 21.19 20.99 20.04 1,4-dichlorobutane 20.56 21.14 19.02 21.01 21.16 19.40 1,1,2,2-tetrachloroethane 20.62 21.49 17.72 21.19 21.41 20.67 2-chlorotoluene 20.76 21.22 18.66 21.68 21.66 20.31 1,3,5-trimethylbenzene 20.81 21.15 18.50 21.42 21.31 20.40 1,2,3-trichloropropane 20.84 21.61 18.81 21.45 21.65 20.34 4-chlorotoluene 21.03 21.46 19.04 21.68 21.76 20.43 tert-butylbenzene 21.32 21.62 19.06 21.98 21.72 20.82 1,2,4-trimethylbenzene 21.42 21.79 19.15 22.09 22.02 20.95 sec-butylbenzene 21.60 21.95 19.16 22.29 22.04 21.17 p-isopropyl toluene 21.81 22.17 19.30 22.49 22.24 21.42 1,3-dichlorobenzene 21.95 22.49 19.87 22.95 23.03 21.58 1,4-dichlorobenzene 22.09 22.68 20.00 23.15 23.30 21.77 n-butylbenzene 22.47 22.85 20.12 23.18 22.89 22.03 1,2-dichlorobenzene 22.76 23.36 20.73 23.84 23.96 22.31 4-bromo-1-chlorobenzene 23.77 24.50 21.55 25.15 25.33 23.57 1,2-bromo-3-chloropropane 24.02 24.98 21.70 25.26 25.54 23.71 hexachlorobutadiene 25.03 25.53 22.42 26.41 26.15 24.97 1,2,4-trichlorobenzene 25.13 25.77 22.96 26.37 26.55 24.79 naphthalene 25.64 26.40 23.70 27.18 27.45 25.36 1,2,3-trichlorobenzene 25.94 26.72 23.81 27.46 27.65 25.56

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Flavor and Fragrance Compounds Retention Time Index Retention time data collected using 60m, 0.25mm ID, 0.25µm Rtx®-1 and Stabilwax® columns. Oven temp.: 100°C to 260°C @ 4°C/min.; Carrier gas: helium; Linear velocity: 27.2cm/sec. @ 100°C; Dead time: 3.68 min. @ 100°C.

Rtx®-1 Stabilwax® Rtx®-1 Stabilwax® Rtx®-1 Stabilwax® Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time 3.66 3.93 2-methyl-3-pentanol 4.36 4.59 5-methyl-3-heptanone 5.65 4.94 allyl alcohol 3.67 4.05 2-hexanone 4.41 4.11 ethyl amyl ketone 5.65 4.94 tert-butyl alcohol 3.68 3.89 ethyl butanoate 4.41 4.18 5-methylfurfural 5.73 9.64 1-propanol 3.70 4.13 cyclopentanol 4.42 5.74 α-pinene 5.81 4.84

3-buten-2-ol 3.71 4.12 cyclopentanone 4.46 4.96 benzaldehyde 5.90 8.76 RETENTION TIME INDEXES ethyl formate 3.71 3.84 2,4-dimethyl-2-pentanol 4.47 4.45 tricyclene 5.91 4.16 acetone 3.72 3.86 3-hexanol 4.47 4.84 1-heptanol 5.95 7.54 methyl acetate 3.75 3.86 2-hexanol 4.48 5.01 camphene 6.02 4.24 2-butanol 3.76 4.03 4-methyl-3-penten-2-one 4.48 4.61 2,6-dimethyl-4-heptanone 6.03 4.81 propyn-1-ol 3.77 6.26 hexanal 4.48 4.41 1-octen-3-ol 6.09 7.33 tert- 3.79 4.14 2,4-dimethyl-3-pentanone 4.49 3.95 furfuryl acetate 6.09 8.77 isobutyraldehyde 3.79 3.84 pyridine 4.50 4.91 3-octanone 6.16 5.35 2-methyl-3-buten-2-ol 3.82 4.12 propyl propanoate 4.51 4.22 2-octanone 6.20 6.35 methyl ethyl ketone 3.84 3.83 α-angelicalactone 4.51 7.26 sec-butylbenzene 6.28 5.37 cis-2-buten-1-ol 3.84 5.01 butyl acetate 4.54 4.29 tert-butylbenzene 6.32 5.15 ethyl acetate 3.86 3.90 methyl pentanoate 4.61 4.36 myrcene 6.32 4.53 propyl formate 3.87 3.83 furfural 4.64 7.65 butyl butyrate 6.34 5.02 2-methylfuran 3.88 3.87 2,2-dimethyl-3-pentanol 4.65 4.63 β-pinene 6.38 4.40 isobutyl alcohol 3.89 4.72 2-methyl-1-pentanol 4.65 5.63 octanal 6.39 5.73 methyl propanoate 3.89 4.03 4-hexen-3-one 4.67 4.88 2-octanol 6.39 7.00 3-buten-1-ol 3.91 4.76 isopropyl butyrate 4.72 4.19 hexyl acetate 6.49 5.41 3-methyl-2-butanol 3.92 4.25 furfuryl alcohol 4.74 11.07 decane 6.58 4.08 2-butenal 3.94 4.26 2,4-dimethyl-3-pentanol 4.75 4.76 2-methylanisole 6.60 6.97 Flavor & Fragrance Compounds 2-pentanol 3.95 4.42 trans-2-hexenal 4.78 5.08 α-phellandrene 6.69 6.13 isopropyl acetate 3.96 4.03 pinacol 4.79 7.91 3-methylanisole 6.74 7.39 1-butanol 3.96 4.57 ethyl-2-methyl butanoate 4.80 4.26 4-methylanisole 6.78 7.42 neopentanol 3.99 4.60 2-ethyl-1-butanol 4.80 5.72 2-ethyl-1-hexanol 6.85 8.10 methyl isobutyrate 4.03 4.08 trans-2-hexenol 4.82 6.56 benzyl alcohol 6.86 16.48 2-pentanone 4.03 3.95 5-methyl-2-hexanone 4.84 4.54 3-carene 6.89 4.67 isoamyl alcohol 4.04 4.96 1-hexanol 4.92 6.16 p-cymene 6.91 5.38 allyl acetate 4.05 4.14 3-ethyl-3-pentanol 4.94 4.94 α-terpinene 6.93 12.38 ethyl acrylate 4.06 4.08 isoamyl acetate 4.98 4.49 limonene 7.09 4.84 3-pentanone 4.07 4.08 cis-3-hexen-1-ol 4.98 6.58 salicaldehyde 7.09 11.93 pentanal 4.07 4.08 4-heptanone 4.99 4.45 camphor 7.11 8.77 tert-butyl acetate 4.09 3.93 trans-2-hexen-1-ol 5.01 6.81 trans-ocimene 7.13 4.72 pinacolone 4.09 4.00 anisole 5.06 6.13 1,8-cineole 7.16 5.06 propyl acetate 4.10 4.04 3-heptanone 5.08 4.62 eucalyptol 7.16 5.06 2-ethylfuran 4.10 3.99 1,3-xylene 5.09 4.67 cis-ocimene 7.21 5.06 2,5-dimethylfuran 4.12 3.98 1,4-xylene 5.09 4.64 α-methylbenzylalcohol 7.34 18.34 3-methyl-1-butanol 4.18 4.88 2-heptanone 5.10 4.85 p-cresol 7.45 21.40 3-penten-2-one 4.18 4.45 4-heptanol 5.14 5.45 γ-terpinene 7.54 5.26 2-methyl-1-butanol 4.20 4.88 propyl butyrate 5.16 4.49 1-octanol 7.55 9.37 pinacol alcohol 4.20 4.38 ethyl pentanoate 5.17 4.54 2,6-dimethylanisole 7.55 7.16 thiophene 4.21 4.16 cyclohexanone 5.19 5.85 5-nonanone 7.57 6.39 methylisobutylketone (MIBK) 4.22 4.15 2-heptanol 5.20 5.63 tetrahydrofurfuryl acetate 7.60 9.84 methyl butanoate 4.22 4.09 heptanal 5.21 4.35 fenchone 7.68 7.08 2-methyl-3-pentanone 4.27 4.15 butyl propionate 5.24 4.56 linalool oxide 7.81 7.56 ethyl isobutyrate 4.28 4.03 amyl acetate 5.29 4.73 3-nonanone 7.82 6.38 cis-2-penten-1-ol 4.29 5.85 1,2-xylene 5.30 4.93 2-nonanone 7.89 7.17 3-methyl-3-pentanol 4.29 4.37 nonane 5.32 3.80 methyl benzoate 8.03 10.72 1-pentanol 4.30 5.24 isobutyl isobutyrate 5.34 4.39 linalool 8.13 9.02 3-hexanone 4.30 4.28 methyl hexanoate 5.41 3.81 2-nonanol 8.15 8.65 3-methyl-2-buten-1-ol 4.32 5.81 tetrahydro-2-fufanmethanol 5.50 8.53 nonanal 8.16 6.86 isobutyl acetate 4.34 4.13 δ-valerolactone 5.51 9.57 terpinyl acetate 8.18 12.51 butryolactone 4.34 7.07 cumene 5.62 4.84 maltol 8.23 18.48

continued on the next page…

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Flavor and Fragrance Compounds Retention Time Index (continued) Rtx®-1 Stabilwax® Rtx®-1 Stabilwax® Rtx®-1 Stabilwax® Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time trans-sabinene hydrate 8.37 9.06 r-carvone 11.48 13.28 carvone hydrate 16.25 27.44 2,4-dimethylanisole 8.39 8.45 s-carvone 11.51 13.36 tetradecane 16.38 6.95 2,5-dimethylanisole 8.39 8.42 geraniol 11.74 15.84 coumarin 16.54 29.90 undecane 8.41 4.38 trans-cinnamaldehyde 11.97 20.50 cis-carvyl propionate 16.63 14.68 α-thujone 8.46 15.01 citral b 12.12 13.25 α-ionone 16.88 16.23 methyl octanoate 8.57 6.69 neral 12.12 13.25 trans-cinnamyl acetate 16.88 23.12 β-thujone 8.68 7.63 propyl benzoate 12.16 13.82 ethyl vanillin 17.08 31.44 2,3-dimethylanisole 8.87 9.30 1-decanol 12.36 13.99 isoeugenol 17.09 27.57 citronellal 9.19 7.99 perillaldehyde 12.37 14.52 3-methyl-p-anisaldehyde 17.23 20.08 benzyl acetate 9.31 13.02 citronellyl formate 12.38 10.69 β-caryophyllene 17.32 10.56 menthone 9.42 7.97 trans-menthyl acetate 12.56 9.01 trans-carvyl propionate 17.65 15.76 9.53 12.52 indole 12.57 29.33 α-methylcinnamic acid 18.15 4.64 ethyl benzoate 9.62 11.74 trans-anethole 12.67 15.41 α-humulene 18.29 12.05 1-nonanol 9.70 11.56 cumin alcohol 12.68 21.88 2,3-dimethylanisaldehyde 18.46 25.74 isoborneol 9.72 11.69 12.71 23.82 β-ionone 18.57 18.37 menthofuran 9.73 8.14 2-undecanone 12.81 10.45 vanillin acetate 18.93 30.85 isomenthone 9.75 8.57 carvacrol 12.87 24.56 pentadecane 19.34 8.60 neomenthol 9.85 10.22 bornyl acetate 12.88 10.09 valencene 19.40 13.15 α-terpineol 9.91 5.58 trans-cinnamyl alcohol 12.94 26.11 2,5-dimethylanisaldehyde 19.50 21.72 9.95 11.16 cis-menthyl acetate 13.02 9.62 6-methylcoumarin 20.22 32.66 dihydrocarveol 10.09 13.64 perillyl alcohol 13.02 19.36 carvone acetate 20.50 26.09 terpinen-4-ol 10.11 10.31 tridecane 13.47 5.72 7-methylcoumarin 20.65 32.52 2-decanone 10.14 8.41 2-methylcinnamaldehyde 13.59 19.52 ethyl laurate 21.69 16.17 RETENTION TIME INDEXES α-terpinolene 10.32 7.36 triacetin 13.67 21.33 caryophyllene oxide 21.88 19.47 4-allylanisole 10.35 11.75 methyl decanoate 13.69 10.26 hexadecane 22.27 10.64 estragole 10.35 11.75 cis-carvyl acetate 14.09 13.23 cinnamide 22.36 45.53 decanal 10.48 8.51 cumic acid 14.40 34.95 amyl cinnamaldehyde 23.08 25.95 trans-dihydrocarvone 10.59 23.12 γ-valerolactone 14.48 10.55 cis-trans-farnesol 24.61 27.48 verbenone 10.67 12.88 citronellyl acetate 14.49 11.81 heptadecane 25.10 12.94 dodecane 10.75 4.90 eugenol 14.55 23.53 trans-trans-farnesol 25.28 28.09 cis-dihydrocarvone 10.80 10.80 thiazole 14.67 5.23 guaiazulene 27.04 28.98 linalyl acetate 10.93 9.36 neryl acetate 14.76 13.08 nootketone 27.69 31.89 β-citronellol 11.06 13.93 trans-carvyl acetate 14.88 14.05 octadecane 27.83 15.40 cis-nerol 11.14 13.82 dihydrocoumarin 14.91 26.02 nonadecane 30.44 17.92 carveol 11.24 16.29 geranyl acetate 15.26 13.08 eicosane 32.94 20.44 benzyl acetone 11.27 16.25 dihydrojasmone 15.34 16.24 heneicosane 35.32 22.91 citral a 11.39 12.13 vanillin 15.34 32.21 docosane 37.62 25.35 geranial 11.39 12.13 ethyl decanoate 15.69 11.22 tricosane 39.79 27.68 cuminaldehyde 11.43 14.40 2-dodecanone 15.72 12.83 tetracosane 42.02 29.95 pulegone 11.43 11.46 cis-jasmone 15.75 18.34 hexacosane 47.40 34.26 p-anisaldehyde 11.47 20.15 trans-cinnamyl acid 16.07 37.16 Flavor & Fragrance Compounds

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Petroleum Hydrocarbon Compounds Retention Time Index Retention time data collected using a 100m, 0.25mm ID, 0.50µm Rtx®-1PONA column. Oven temp.: 35°C (hold 13 min.) to 45°C @ 10°C/min. (hold 15 min.) to 60°C @ 1.0°C/min. (hold 15 min.), to 200°C @ 1.9°C/min. (hold 5 min.); Carrier gas: helium; Inj./det. temp: 250°C; Linear velocity: 24cm/sec. @ 35°C; FID sensitivity: 4 x 10-12 AFS; Split ratio: 100:1. Rtx®-1PONA Rtx®-1PONA Rtx®-1PONA Component Name Ret. Time Component Name Ret. Time Component Name Ret. Time 7.4 3-methyl-cis-hexene-3 24.869 7-methyl-octene-3 67.802 iso-/methanol 7.828 trans-heptene-3 25.362 n-nonane 69.275 butene-1/iso-butene 8.071 n-heptane 25.68 1,1-methyl-ethyl-cyclohexane 69.609 n-butane 8.19 cis-heptene-3 25.827 iso-propyl-benzene 71.09 RETENTION TIME INDEXES trans-butene-2 8.315 2-methyl-hexene-2 25.94 2,2-dimethyl-octane 72.657 cis-butene-2 8.522 3-methyl-hexene-2 26.091 2,4-dimethyl-octane 73.111 ethanol 8.782 trans-heptene-2 26.359 2,6-dimethyl-octane 74.247 3-methyl-butene-1 9.11 3-ethyl-pentene-2 26.611 2,5-dimethyl-octane 74.44 iso-pentane 9.524 cis-heptene-2 27.09 n-butyl-cyclopentane 75.065 iso-propanol 9.747 2,3-dimethyl-pentene-2 27.639 3,3-dimethyl-octane 76.053 n-pentene-1 9.899 3-ethyl-cyclopentene 28.318 n-propyl-benzene 76.645 2-methyl-butene-1 10.094 1-cis-2-dimethyl-cyclopentene 28.64 3,6-dimethyl-octane 76.958 n-pentane 10.244 methyl-cyclopentane 28.791 1-methyl-3-ethyl-benzene 78.016 isoprene 10.395 1,1,3-trimethyl-cyclopentane 29.317 1-methyl-4-ethyl-benzene 78.33 trans-pentene-2 10.478 ethyl-cyclopentane 30.788 1,3,5-trimethyl-benzene 79.315 tert-butanol 10.665 2,5-dimethyl-hexane 31.037 2,3-dimethyl-octane 79.471 cis-pentene-2 10.756 2,4-dimethyl-hexane 31.375 5-methyl-nonane 80.697 2-methyl-butene-2 10.937 1-cis-2-trans-4-trimethyl-cyclopentane 32.366 1-methyl-2-ethyl-benzene 80.796 1-trans-3-pentadiene 11.029 3,3-dimethyl-hexane 32.629 2-methyl-nonane 81.11 1-cis-3-pentadiene 11.514 1,2,3-trimethyl-cyclopentane 33.699 3-ethyl-octane 81.59 2,2-dimethyl-butane 11.609 2,3,4-trimethyl-pentane 34.318 3-methyl-nonane 82.115 cyclopentene 12.445 toluene 34.901 1,2,4-trimethyl-benzene 83.188 4-methyl-pentene-1 12.607 2,3-dimethyl-hexane 36.332 iso-butyl-cyclohexane 83.843 Petroleum Hydrocarbon Compounds 3-methyl-pentene-1 12.696 2-methyl-3-ethyl-pentane 36.554 iso-butyl-benzene 85.481 cyclopentane/methyl tert-butyl ether 13.052 2-methyl-heptane 37.544 sec-butyl-benzene 85.869 2,3-dimethyl-butane 13.13 4-methyl-heptane 37.816 n-decane 86.289 2,3-dimethyl-butene-1 13.242 3-methyl-3-ethyl-pentane 37.996 1,2,3-trimethyl-benzene 87.05 2-methyl-pentane 13.358 1-cis-3-dimethyl-cyclohexane 38.576 1-methyl-3-iso-propyl-benzene 87.363 3-methyl-pentane 14.172 3-methyl-heptane 39.005 1-methyl-4-iso-propyl-benzene 87.783 2-methyl-pentene-1 14.443 1-cis-2-trans-3-trimethyl-cyclopentane 39.192 indan 88.52 n-hexene-1 14.505 3-ethyl-hexane 39.349 1-methyl-2-iso-propyl-benzene 89.544 2-butene-1 15.17 1-trans-4-dimethyl-cyclohexane 39.559 1,3-dimethyl-benzene 90.923 n-hexane 15.251 1,1-dimethyl-cyclohexane 40.607 1-methyl-3-propyl-benzene 91.26 trans-hexene-3 15.368 2,2,5-trimethyl-hexane 41.132 1,4-diethyl-benzene 91.73 cis-hexene-3 15.455 3-cis-ethyl-methyl-cyclohexane 41.353 1-methyl-4-propyl-benzene 91.856 trans-hexene-2 15.563 2,6-dimethyl-heptene-1 41.772 n-butyl-benzene 92.12 2-methyl-pentene-2 15.727 3-trans-ethyl-methyl-cyclopentane 42.018 1,3-dimethyl-5-ethyl-benzene 92.375 3-methyl-pentene-1 15.918 2,2,4-trimethyl-hexane 42.526 trans-decahydronaphylene 92.781 3-methyl-pentene-2 15.975 1-trans-3-dimethyl-cyclohexane 42.954 1-methyl-2-propyl-benzene 93.14 hexyne-1 16.147 trans-octene-4 43.181 4-methyl-decane 94.135 cis-hexene-2 16.254 trans-octene-3 43.747 1,4-dimethyl-4-ethyl-benzene 94.391 3,3-dimethyl-pentene-1 16.625 1-trans-3-dimethyl-cyclohexane 44.057 1,3-dimethyl-4-ethyl-benzene 94.587 3-methyl-trans-pentene-2 16.73 n-octane 44.343 1,2-dimethyl-4-ethyl-benzene 95.303 2,2-dimethyl-pentane 17.095 octene-2 45.049 1,3-dimethyl-2-ethyl-benzene 95.898 methyl-cyclopentane 17.307 iso-propyl-cyclopentane 45.744 1-methyl-4-tert-butyl-benzene 97.438 2,4-dimethyl-pentane 17.611 2,3,4-trimethyl-hexane 47.747 1,2-dimethyl-3-ethyl-benzene 97.59 2,3,3-trimethyl-butane 18.1 1-cis-2-dimethyl-cyclohexane 49.495 n-undecane 98.514 4,4-dimethyl-pentene-2 19.086 1,1,4-trimethyl-cyclohexane 50.646 1,2,4,5-tetra-methyl-benzene 98.967 2,4-dimethyl-pentene-1 19.228 2,2,3-trimethyl-hexane 51.088 1,2,3,5-tetra-methyl-benzene 99.34 1-methyl-cyclopentene 19.333 2,4-dimethyl-heptane 51.473 5-methyl-indan 101.15 benzene 19.426 n-propyl-cyclopentane 52.695 4-methyl-indan 101.69 3-methyl-hexene-1 19.658 1-cis-3-cis-5-trimethyl-cyclohexane 52.994 1-ethyl-2-propyl-benzene 101.985 3,3-dimethyl-pentane 19.917 2-methyl-4-ethyl-hexane 53.288 2-methyl-indan 102.211 5-methyl-hexene-1 20.14 1,1,3-trimethyl-cyclohexane 54.002 1-methyl-3-butyl-benzene 102.487 cyclohexane 20.4 ethyl-benzene 55.129 1,3-dipropyl-benzene 102.662 2-methyl-hexene-3 20.529 1-cis-2-trans-4-trans-trimethyl-cyclohexane 55.889 sec-pentyl-benzene 102.768 4-methyl-hexene-1 20.93 m-xylene 57.597 n-pentyl-benzene 103.269 4-methyl-trans-hexene-2 21.185 p-xylene 57.872 1,2-dipropyl-benzene 103.671 2-methyl-hexane 21.368 2,3-dimethyl-heptane 58.255 1,4-dipropyl-benzene 104.304 2,3-dimethyl-pentane 21.566 3,5-dimethyl-heptane 58.785 1,2,3,4-tetrahydro-naphthylene 104.718 1,1-dimethyl-cyclopentane 21.905 3,4-dimethyl-heptane 59.04 naphthalene 105.198 cyclohexene 22.157 4-methyl-octane 60.594 1,3-dipropyl-benzene 107.28 3-methyl-hexane 22.394 2-methyl-octane 60.9 n-dodecane 108.48 3,4-dimethyl-ethyl-pentene-2 22.805 3-ethyl-heptane 62.266 2,6-dimethyl-undecane 110.575 1-cis-3-dimethyl-cyclopentane 23.19 3-methyl-octane 62.66 1,2,4-triethyl-benzene 110.854 1-trans-3-dimethyl-cyclopentane 23.545 1-cis-2-trans-4-trans-trimethyl-cyclohexane 63.289 1-methyl-4-pentyl-benzene 112.042 3-ethyl-pentane/2-methyl-hexene-1 23.668 o-xylene 63.592 pentamethyl-benzene 114.772 1-trans-2-dimethyl-cyclopentane 23.899 1-methyl-2-propyl-cyclopentane 65.199 2-methyl-naphthalene 115.65 2,2,4-trimethyl-pentane 24.02 1-cis-ethyl-3-methyl-cyclohexane 65.433 1-methyl-naphthalene 117.011 n-heptene-1 24.114 iso-butyl-cyclopentane 66.62 n-tridecane 117.152

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Pharmaceutical Compounds Retention Time Index Retention time data collected using 30m, 0.25mm ID, 0.50µm Rtx®-1, Rtx®-5, Rtx®-35, Rtx®-50, and Rtx®-200 columns. Oven temp.: 40°C (hold 1 min.) to 100°C @ 20°C/min. to 300°C @ 6°C/min. (hold 17 min.); Carrier gas: helium; Regulation: constant pressure; Linear velocity: 33.78cm/sec.; Dead time: 1.480 min.

Rtx®-1 Rtx®-5 Rtx®-35 Rtx®-50 Rtx®-200 Rtx®-1 Rtx®-5 Rtx®-35 Rtx®-50 Rtx®-200 Component Ret. Time Ret. Time Ret. Time Ret. Time Ret. Time Component Ret. Time Ret. Time Ret. Time Ret. Time Ret. Time acetophenetidin 21.294 22.276 26.399 27.929 24.646 lidocaine 25.52 26.126 29.034 29.948 28.23 acetopromazine 38.588 39.533 46.242 49.719 37.662 34.215 35.127 40.185 42.621 35.034 alphaprodine 24.276 24.723 27.124 27.728 23.351 maprotyline 33.29 33.979 37.565 38.758 31.031 42.81 44.822 62.701 76.095 53.326 31.643 32.478 36.834 38.264 29.763 31.029 31.616 34.781 35.599 27.901 meperidine 23.121 23.633 26.255 27.055 21.484 22.138 22.775 25.42 26.63 24.284 mephobarbital 25.748 26.578 30.424 31.889 27.224 aprobarbital 20.088 20.843 24.086 25.553 22.422 23.398 24.414 28.576 30.284 27.198 atropine 30.998 31.738 35.55 36.705 30.247 methadone 30.25 30.799 33.57 34.387 27.612 17.379 18.308 21.537 23.075 20.523 methapyriline 27.466 28.162 31.58 32.525 24.938 benzocaine 18.801 19.765 23.951 25.434 20.627 30.232 31.14 35.91 37.52 30.538 benzphetamine 24.957 25.39 27.803 28.372 22.016 18.23 19.278 23.104 24.395 21.933 36.995 38.286 48.826 55.47 38.082 34.746 35.588 41.151 44.069 NA brompheniramine 29.483 30.161 33.384 34.309 26.775 nalorphine 36.77 37.519 43.859 47.393 35.536 bupivacaine 32.471 33.026 35.945 36.827 33.218 nicotine 14.415 14.987 NA 18.091 14.359 20.985 21.655 24.861 26.223 23.455 norcodeine 34.038 35.022 40.825 43.667 33.584 21.112 21.856 24.689 26.004 23.158 nortriptyline 31.248 31.964 35.556 36.602 28.647 butethal 21.031 21.675 24.682 25.97 23.429 papaverine 40.08 41.464 53.419 61.599 39.026 C12 11.524 11.387 10.203 9.51 7.885 pentazocine 32.333 32.896 36.044 37.069 29.677 C26 36.481 36.318 35.161 34.403 29.983 22.64 23.284 26.201 27.448 24.711 caffeine 24.129 25.165 30.223 32.206 26.415 phencyclidine 26.154 26.562 28.911 29.393 21.998

RETENTION TIME INDEXES carisoprodal 25.024 25.877 29.152 30.362 27.867 24.334 24.991 28.104 28.839 21.591 chlorpheniramine 27.8 28.435 31.377 32.175 25.281 26.671 27.59 32.009 33.841 28.763 35.734 36.436 40.543 42.086 33.267 phenothiazine 28.097 29.173 33.998 35.606 28.187 chlorprothixene 35.674 36.263 40.337 41.922 32.749 phenylbutazone 33.544 34.409 40.49 42.746 35.509 36.27 37.371 44.356 48.239 40.304 phenyltoloxamine 26.731 27.323 30.227 30.966 24.139 clomipramine 34.417 34.988 38.193 39.189 31.762 37.737 38.628 45.242 48.871 38.04 40.444 42.457 58.096 66.751 47.241 30.909 32.413 39.019 42.272 34.054 cocaine 30.919 31.788 35.756 36.945 30.625 procainamide 31.309 32.352 36.86 38.633 33.957 codeine 33.988 34.816 39.698 41.798 32.832 prochlorperazine 43.745 45.138 55.919 61.673 39.158 cotinine 21.357 22.606 27.464 29.162 26.636 promazine 33.123 33.799 37.682 38.972 30.955 desipramine 31.832 32.725 36.322 37.3 29.621 32.06 NA 36.847 NA NA desmethyldiazepam 35.43 36.478 43.273 47.042 37.06 propoxyphene 30.919 31.418 35.963 32.96 28.257 dextromethorphan 30.229 37.379 34.075 34.958 27.118 pyrilamine 31.426 32.174 35.728 36.789 29.027 34.629 35.537 40.771 43.313 35.961 32.9 33.733 38.2 39.876 33.774 dibucaine 38.267 38.985 43.261 45.365 37.931 23.643 24.274 27.066 28.322 25.269 25.292 25.811 28.716 29.371 22.332 strychnine 48.562 51.711 81.422 99.656 47.459 25.29 25.8 28.714 29.368 22.374 36.857 37.722 45.186 49.596 38.928 diphenylhydantoin 32.769 34.005 39.686 42.785 34.933 tetracaine 31.299 32.013 35.002 36.08 31.28 31.533 32.201 35.633 36.586 29.203 25.976 26.607 29.466 30.532 25.894

Pharmaceutical Compounds 26.172 26.802 29.872 30.661 22.899 thiopental 25.141 25.721 28.705 29.756 25.452 ethosuximide 11.544 12.325 15.358 16.801 15.806 47.726 49.712 67.355 77.396 41.549 37.034 38.011 45.701 49.937 41.415 53.619 58.412 97.02 118.632 52.211 39.543 40.51 47.129 50.274 39.261 45.255 47.731 70.454 84.7 57.235 24.797 25.708 29.777 31.187 27.396 trifluoperazine 38.17 38.804 42.726 44.265 35.91 haloperidol 42.9 44.461 55.087 60.937 42.584 trimeprazine 32.823 33.389 36.904 37.875 30.25 25.07 25.76 29.559 30.839 26.835 31.457 32.046 34.966 35.669 28.394 hydrocodone 34.828 35.799 41.638 44.419 35.503 tripelennamine 27.349 28.017 31.238 32.116 24.652 hydromorphone 35.093 36.049 42.258 45.662 36.299 triprolidine 31.826 32.602 36.503 37.617 28.298 imipramine 31.468 32.105 35.351 36.178 28.562 valproic acid 9.272 9.729 9.815 10.046 7.423 ketamine 25.088 25.811 29.793 30.94 25.494 verapamil 48.236 50.808 65.948 74.857 46.748 levorphanol 31.48 32.151 36.075 37.334 28.951

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Alcohols, Aldehydes, and Ketones Retention Time Index Retention time data collected using 60m, 0.53mm ID, 1.0µm Rtx®-1, Stabilwax®, and Rtx®-502.2 columns. Oven temp.: 45°C (hold 10 min.) @ 12°C/min. to 250°C; Carrier gas: helium; Regulation: constant pressure; Linear velocity: 51.5cm/sec. @ 45°C; Dead time: 1.941 min. @ 45°C. Rtx®-1 Stabilwax® Rtx®-502.2 Rtx®-1 Stabilwax® Rtx®-502.2 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time water 2.001 12.841 2.041 hexanal 9.474 13.508 12.425 methanol 2.095 5.41 2.168 3-hexanol 9.704 16.312 11.635 acetaldehyde 2.098 2.685 2.195 2-hexanol 9.899 16.833 11.858 ethanol 2.268 6.704 2.388 2-furaldehyde 10.561 21.127 14.549 2,2,2-trifluoroethanol 2.289 16.133 2.383 furfural 10.561 21.127 14.549 2-propanone (acetone) 2.382 3.887 2.701 2,2-dimethyl-3-pentanol 11.076 15.899 12.537 RETENTION TIME INDEXES acetone 2.382 3.887 2.701 4-hexen-3-one 11.311 16.524 13.995 propanal 2.413 3.505 2.715 diacetone alcohol 11.448 19.605 14.327 propional 2.413 3.505 2.715 4-hydroxy-4-methyl-2-pentanone11.448 19.605 14.327 2-propanol 2.436 6.363 2.61 2-methyl-1-pentanol 11.72 18.331 13.273 isopropyl alcohol 2.436 6.363 2.61 2,4-dimethyl-3-pentanol 11.943 16.229 13.146 dimethoxymethane 2.528 2.928 2.791 2-ethyl-1-butanol 12.001 18.472 13.564 methyal 2.528 2.928 2.791 2-furanmethanol 12.092 23.275 14.835 2-methyl-2-propanol 2.603 5.566 2.802 furfuryl alcohol 12.092 23.275 14.835 tert-butyl alcohol 2.603 5.566 2.802 5-methyl-2-hexanone 12.492 15.236 14.321 allyl alcohol 2.747 5.899 3.121 cis-3-hexen-1-ol 12.692 19.709 14.349 2-propen-1-ol 2.747 5.899 3.121 3-ethyl-3-pentanol 12.704 16.597 14.103 vinyl carbinol 2.747 5.899 3.121 trans-2-hexen-1-ol 13.021 20.015 14.61 2-methylpropanal 2.81 3.809 3.321 4-heptanone 13.15 14.805 14.819 isobutyraldehyde 2.81 3.809 3.321 1-hexanol 13.171 19.19 14.571 1-propanol 2.85 11.835 3.198 cyclohexanone 13.359 18.667 16.287 2-propyn-1-ol 2.979 19.13 3.428 cyclohexanol 13.387 20.048 15.449 propargyl alcohol 2.979 19.13 3.428 tetra-hydro-2-furan-metol 13.426 21.561 15.719 3-buten-2-ol 3.053 13.148 3.471 3-heptanone 13.617 15.642 15.281

2-butanone (MEK) 3.149 5.796 3.983 2,2-dimethyl-1-pentanol 13.647 18.799 14.787 Solvents methylethylketone (MEK) 3.149 5.796 3.983 2-heptanone 13.716 16.312 14.819 2-butanol 3.294 11.193 3.794 4-heptanol 13.947 18.012 15.017 butyraldehyde 3.324 3.53 3.87 heptanal 14.075 16.292 15.744 2-methyl-3-buten-2-ol 3.55 12.01 3.98 2-heptanol 14.093 18.599 15.333 2-methyl-1-propanol 3.687 13.709 4.361 hexylene glycol 14.259 22.807 16.484 isobutyl alcohol 3.687 13.709 4.361 2-methyl-2,4-pentanediol 14.259 22.807 16.484 2-methoxyethanol 3.715 16.001 4.803 2-butoxyethanol 14.306 20.072 15.793 2-butenal 3.806 12.058 5.664 1,4-butanediol 14.769 26.043 17.33 crotonaldehyde 3.806 12.058 5.664 2(2-methoxyethoxy)ethanol 14.872 22.676 17.019 3-buten-1-ol 3.82 15.802 4.838 diethylene glycol 15.335 26.672 18.623 2-methyl-2-butanol 3.893 10.566 4.614 2,2'-oxy-bis-ethanol 15.335 26.672 18.623 tert-amyl alcohol 3.893 10.566 4.614 5-methyl-3-heptanone 15.375 16.347 16.634 1-butanol 4.402 15.14 5.465 benzylaldehyde 15.415 22.097 17.931 cis-2-buten-1-ol 4.459 16.777 5.701 1-heptanol 16.116 20.659 17.187 2-pentanone 4.779 8.91 6.615 2,6-dimethyl-4-heptanone 16.193 16.046 17.132 ethylene glycol 4.82 22.426 7.268 3-octanone 16.436 17.804 17.707 3-methyl-2-butanol 4.824 13.714 5.88 2-octanone 16.524 18.347 17.834 1-penten-3-ol 4.831 15.559 6.054 3-octanol 16.742 19.743 17.646 pentanal 5.001 8.886 7.032 2(2-ethoxyethoxy)ethanol 16.759 22.906 18.429 3-pentanone 5.063 8.95 7.007 octanal 16.791 18.362 18.086 2-pentanol 5.31 14.493 6.546 2-octanol 16.854 20.11 17.73 3-pentanol 5.317 14.075 6.595 1-methyl-2-pyrrolidinone 17.066 24.035 19.874 2-ethoxyethanol 5.668 16.978 7.553 benzyl alcohol 17.275 25.858 19.333 3-penten-2-one 6.278 14.84 9.745 2-ethyl-1-hexanol 17.466 21.129 18.375 propylene glycol 6.476 22.885 9.915 α-methylbenzylalcohol 17.989 25.155 19.764 4-methyl-2-pentanone 6.567 10.555 9.015 1-octanol 18.303 21.974 19.207 methylisobutylketone (MIBK) 6.567 10.555 9.015 5-nonanone 18.332 19.025 19.344 3-methyl-1-butanol 6.633 16.574 8.3 3-nonanone 18.564 19.525 19.611 2-methyl-1-butanol 6.724 16.608 8.492 2-nonanone 18.65 20.018 19.738 2-methyl-3-pentanone 7.079 9.778 9.648 nonanal 18.862 20.051 19.948 3-methyl-3-pentanol 7.304 14.363 9.171 2-nonanol 18.871 21.459 19.646 butyrolactone 7.657 20.355 13.713 1-nonanol 20.058 23.17 20.889 4-methyl-2-pentanol 7.669 15.594 9.401 2(2-butoxyethoxy)ethanol 20.238 24.901 21.584 1-pentanol 8.046 17.416 10.387 2-decanone 20.379 21.467 21.348 cis-2-penten-1-ol 8.188 18.679 10.812 2-decanol 20.569 22.684 21.257 2,3-butanediol 8.236 22.34 13.249 decanal 20.588 21.492 21.554 cyclopentanone 8.282 16.45 12.927 triethylene glycol 20.629 30.7 22.646 2-methyl-3-pentanol 8.295 15.483 10.393 2-phenoxyethanol 20.647 28.617 22.534 3-methyl-2-buten-1-ol 8.605 18.713 11.115 4-phenyl-2-butanone 21.015 25.754 22.901 3-hexanone 8.676 12.609 11.696 benzyl acetone 21.015 25.754 22.901 cyclopentanol 8.775 18.373 11.813 1-decanol 21.602 24.3 22.391 2-hexanone 8.87 13.597 11.979 2-undecanone 21.904 22.787 22.787 4-methyl-3-penten-2-one 9.335 15.029 12.493 1-undecanol 22.964 25.353 23.737 mesityl oxide 9.335 15.029 12.493 2-dodecanone 23.233 23.995 24.11 2,4-dimethyl-2-pentanol 9.344 14.886 11.112 1-dodecanol 24.246 26.376 24.994 2,4-dimethyl-3-pentanone 9.449 9.836 11.71 tetraethylene glycol 24.311 38.265 26.471

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Aromatics, Esters, and Ethers Retention Time Index Retention time data collected using 60m, 0.53mm ID, 1.0µm Rtx®-1, Stabilwax®, and Rtx®-502.2 columns. Oven temp.: 45°C (hold 10 min.) @ 12°C/min. to 250°C; Carrier gas: helium; Regulation: constant pressure; Linear velocity: 51.5cm/sec. @ 45°C; Dead time: 1.941 min @ 45°C.

Rtx®-1 Stabilwax® Rtx®-502.2 Rtx®-1 Stabilwax® Rtx®-502.2 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time methyl ether 2.192 2.048 2.1 methyl hexanoate 14.807 16.317 16.132 methyl formate 2.297 3.183 2.316 cumene 14.93 16.064 14.992 ethyl ether 2.416 2.319 2.6 2-methoxyethyl ether 15.259 19.002 17.111 ethyl formate 2.578 4.035 2.819 propylbenzene 15.751 16.868 16.979 methyl acetate 2.637 4.083 2.918 phenol 16.027 27.141 17.786 vinyl acetate 2.96 5.537 3.557 1,3,5-trimethylbenzene 16.171 — 17.294 1,3-dioxolane 3.189 8.138 4.423 ethylene glycol diacetate 16.198 22.015 18.282 ethyl acetate 3.277 5.368 4.186 1,2-ethanediol diacetate 16.199 22.014 18.282 isopropyl ether 3.299 2.484 3.468 isopropylbenzene 16.22 16.063 16.248 propyl formate 3.329 6.344 4.36 α-methylstyrene 16.37 19.169 17.806 methyl propionate 3.456 5.98 4.623 butyl butyrate 16.682 16.951 17.708 1,2-dimethoxy ethane 3.872 6.43 5.318 tert-butylbenzene 16.749 17.451 17.855 isopropyl acetate 4.055 5.709 5.396 ethyl hexanoate 16.758 17.269 17.779 benzene 4.084 6.328 5.556 ethyl caproate 16.76 17.271 17.778 tetrahydro-2-methyl furan 4.262 4.898 5.658 1,2,4-trimethylbenzene 16.785 18.334 17.914 methyl isobutyrate 4.597 6.367 6.226 hexyl acetate 17.049 17.994 18.05 ethyl acrylate 4.811 5.195 6.965 isobutylbenzene 17.131 17.514 18.117 allyl acetate 4.832 11.748 7.071 sec-butylbenzene 17.187 17.686 18.235 allyl ether 4.922 6.458 6.449 1,2,3-trimethylbenzene 17.401 19.342 18.666 1,4-dioxane 4.967 12.844 7.803 isopropyltoluene 17.448 18.083 18.481 tert-butyl acetate 5.173 5.854 6.655 cymene 17.479 18.083 17.501

RETENTION TIME INDEXES ethyl propionate 5.267 7.839 7.379 o-cresol 17.676 27.077 19.354 propyl acetate 5.327 8.671 7.535 1,3-diethylbenzene 17.966 18.64 19.042 methyl butyrate 5.628 9.269 7.918 p-cresol 18.052 27.905 19.677 pyridine 6.014 16.237 10.292 m-cresol 18.081 27.994 19.693 ethyl isobutyrate 7.23 8.181 9.714 1,4-diethylbenzene 18.09 18.817 19.172 toluene 7.591 12.011 10.482 butylbenzene 18.111 18.865 19.132 isobutyl acetate 7.888 10.786 10.688 1,2-diethylbenzene 18.21 19.177 19.349

Solvents ethyl butyrate 9.446 11.891 12.093 tetrahydrofurfuryl acetate 18.213 22.62 20.062 propyl propionate 10.041 12.221 12.491 nitrobenzene 18.244 24.871 20.573 butyl acetate 10.359 13.246 12.698 2-ethoxyethyl ether 18.284 20.116 19.581 methyl valerate 10.93 13.691 13.108 trans-decahydronaphthalene 18.318 15.533 19.023 methyl pentanoate 10.937 13.691 13.111 2-butoxyethyl acetate 18.421 20.86 19.745 2-methoxyethyl acetate 11.144 17.67 14.193 methyl benzoate 18.577 23.336 20.337 1,2-ethanediol monoacetate 11.411 23.039 14.705 cis-decahydronaphthalene 19.131 17.211 19.978 2-hydroxyethyl acetate 11.411 23.039 14.705 methyl octanoate 19.203 19.923 20.116 ethylene glycol monoacetate 11.417 23.041 14.707 benzyl acetate 19.679 24.44 21.468 isopropyl butyrate 11.994 11.994 13.523 diisopropylbenzene 19.857 19.508 20.716 ethyl-2-methylbutyrate 12.332 12.483 13.82 ethyl benzoate 19.915 23.805 — ethyl pentanoate 12.431 13.076 13.98 1,2,3,4-tetrahydronaphthalene 19.981 22.256 21.488 ethylbenzene 12.769 14.885 14.499 naphthalene 20.3 22.054 22.054 1,3-xylene 13.127 15.096 14.683 p-methoxyphenol 20.369 31.76 22.318 1,4-xylene 13.166 15.259 14.733 1,2-bis(2-methoxyethoxy)ethane 20.632 24.145 22.208 isoamyl acetate 13.311 14.726 14.76 triethylene glycol dimethyl ether 20.636 24.144 22.21 styrene 13.737 17.874 15.596 triethylbenzene 20.902 21.025 21.847 butyl ether 13.865 7.835 14.379 propyl benzoate 21.428 24.851 22.975 1,2-xylene 13.883 16.35 15.521 methyl decanoate 22.149 22.645 23.045 propyl butyrate 13.998 14.729 15.369 ethyl decanoate 23.046 23.121 23.93 2-ethoxyethyl acetate 14.005 18.363 16.059 bis(2-(2-methoxyethoxy)ethyl) ether24.065 28.183 25.933 butyl propionate 14.339 15.211 15.662 tetraethylene glycol dimethyl ether 24.066 28.183 25.933 amyl acetate 14.501 15.995 15.818 bibenzyl 24.705 28.696 26.642 isobutyl isobutyrate 14.628 13.752 15.634 benzyl ether 26.07 32.14 28.335

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