p711-726.qxd 11/18/2002 12:47 PM Page 711 Chlorinated Pesticide Compounds Retention Time Index Data collected using 30m, 0.53mm ID, 0.50µm Rtx®-5, Rtx®-35, and Rtx®-1701 columns. Oven temp.: Rtx®-5: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 6 min.); Rtx®-35: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 16 min.); Rtx®-1701: 100°C (hold 5 min.) to 275°C @ 4°C/min. (hold 6 min.); Carrier gas: heli- um; Regulation: constant pressure; Linear velocity: 40.0cm/sec. @ 100°C; Dead time: 1.250 min. @ 100°C. Rtx®-5 Rtx®-35 Rtx®-1701 Rtx®-5 Rtx®-35 Rtx®-1701 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time DBCP 2.103 1.972 2.262 isodrin 17.605 20.569 19.923 hexachlorocyclopentadiene 3.193 3.356 3.418 heptachlor epoxide 18.24 21.352 21.536 tetradecane 3.528 2.633 3.221 captan 18.731 24.41 24.899 γ etridiazole 4.526 6.155 6.279 -chlordane 19.365 22.333 23.161 RETENTION TIME INDEXES chlorneb 5.407 7.847 8.227 endosulfan I 19.958 23.11 22.759 hexadecane 6.955 5.074 6.176 α-chlordane 20.118 23.131 23.472 propachlor 7.589 10.474 12.257 cis-nonachlor 20.341 22.654 23.608 tetrachloro-m-xylene (ISTD) 7.866 9.204 8.911 dieldrin 21.21 24.579 24.521 trifluralin 9.046 9.299 12.877 4,4'-DDE 21.295 24.513 24.03 cis-diallate 9.446 11.925 11.811 docosane 21.519 19.169 20.449 chlorpropham 9.511 10.724 13.229 endrin 22.229 26.179 25.483 α-BHC 9.673 12.784 13.763 nitrofen 22.285 26.446 27.441 trans-diallate 9.822 11.468 12.602 TOK 22.285 26.446 27.409 hexachlorobenzene 10.016 11.886 11.306 ethylan 22.531 26.131 25.292 dichloran 10.268 14.205 16.491 perthane 22.531 26.131 25.292 simazine 10.613 14.727 16.509 endosulfan II 22.695 27.181 27.926 atrazine 10.855 14.525 16.39 chlorobenzilate(a) 22.857 26.139 27.093 β-BHC 11.034 15.413 20.17 chloropropylate 22.878 25.75 26.849 γ-BHC 11.233 14.855 15.869 4,4'-DDD 23.295 27.158 27.862 lindane 11.233 14.855 15.869 trans-nonachlor 23.323 26.64 27.957 PCNB 11.428 14.284 14.418 endrin aldehyde 23.631 28.634 29.981 pronamide 11.776 13.833 17.649 kepone 23.747 26.625 25.26 Environmental Compounds octadecane 11.819 9.444 10.826 carbophenothion 24.486 28.606 28.705 dichlone 12.141 16.428 16.979 endosulfan sulfate 24.741 29.434 31.535 δ-BHC 12.433 17.207 21.072 4,4'-DDT 25.01 28.607 28.563 chlorothalonil 12.66 16.963 19.6 tetracosane 25.837 23.576 24.785 terbacil 12.767 17.497 21.225 captafol 25.933 31.856 32.7 metribuzin 14.154 18.973 19.872 endrin ketone 26.871 33.133 33.156 heptachlor 14.613 16.842 16.686 methoxychlor 27.792 32.464 31.57 alachlor 14.795 17.919 19.272 dibutylchlorendate 29.181 31.458 31.869 aldrin 16.247 18.461 17.936 mirex 29.273 32.799 30.193 metolachlor 16.547 19.571 20.95 hexacosane 29.84 27.532 28.793 eicosane 16.829 14.396 15.758 fenarimol 30.301 35.227 35.243 dicofol 16.851 20.574 20.758 rubigan 30.301 34.954 35.568 kelthane 16.851 20.574 20.758 cis-permethrin 31.912 35.558 34.886 bayleton 17.028 19.949 22.288 trans-permethrin 32.248 36.25 35.254 triadimefon 17.028 19.949 22.288 decachlorobiphenyl (ISTD) 35.131 38.949 36.977 dacthal 17.03 19.999 20.738 octacosane — 31.28 32.61 DCPA 17.03 19.999 20.738 Pro ezGC™ Methods Development Software • GC optimization software—software routines for Fast GC, Windows® 95, 98, 2000, NT, ME, and XP. • Optimize temperature and flow programs from a single analysis. • Reduce analyses times and improve sample resolution. • Model retention gap and guard column applications, including Restek Integra-Guard™ columns. • Model columns in parallel or in series for process GC and multi-dimensional GC analyses. • Optimize dual-column run conditions. • Low price. Includes the FREE Master Library which contains over 3,000 compounds! Pro ezGC™ includes the entire Master Set of Retention Index Libraries at no extra charge! These libraries contain more than 3,000 compounds analyzed on the most commonly used stationary phases, in ten different application areas including: pesticides, PCBs, dioxins/furans, flavor and fragrance compounds, drugs of abuse, FAMEs, semi- volatile and volatile pollutants, petroleum hydrocarbons, and solvents and chemicals. These libraries permit comput- er simulation without entering actual laboratory data. Order by phone 800-356-1688 or 814-353-1300 • Order online www.superchrom.it p711-726.qxd 11/15/2002 8:29 AM Page 712 Chlorinated Pesticide Compounds Retention Time Index Data collected using 30m, 0.32mm ID, 0.50µm Rtx®-CLPesticides and Rtx®-CLPesticides2 columns. Oven temp.: 120°C (hold 1 min.) to 300°C @ 9°C/min.; Carrier gas: helium; Flow rate: 1.31mL/min. @ 120°C; Linear velocity: 27.62cm/sec.; Dead time: 1.810 min.; Regulation: constant pressure. Rtx®-CLPesticides Rtx®-CLPesticides2 Rtx®-CLPesticides Rtx®-CLPesticides2 Component Name Ret. Time Ret. Time Component Name Ret. Time Ret. Time chloroform 1.825 1.837 atrazine 12.184 14.491 bromodichloromethane 1.851 1.896 terbuthylazine 12.576 14.846 chlorodibromomethane 1.900 2.049 secbumeton 12.659 15.158 1,1,1,2-tetrachloroethane 2.000 2.178 isodrin 12.881 16.819 bromoform 2.054 2.688 simetryn 12.907 16.436 1,2-dibromoethane 2.071 2.075 ametryn 12.987 16.457 1,2,3-trichloropropane 2.217 2.558 pentachloronitrobenzene 13.106 14.877 DBCP 2.443 3.567 3,4-dinitrotoluene 13.221 13.637 hexachlorocyclopentadiene 4.321 6.421 heptachlor epoxide (B) 13.368 16.743 4-chloro-3-nitrobenzotrifluoride 6.020 5.826 γ-chlordane 13.652 17.181 1-bromo-2-nitrobenzene 8.049 9.037 prometryn 13.840 16.473 hexachlorobenzene 8.913 12.430 α-chlordane 13.946 17.522 diallate (cis/trans) 9.077 12.162 terbutryn 14.157 16.762 α-BHC 9.239 12.426 4,4'-DDE 14.179 17.848 diallate (cis/trans) 9.452 12.492 endosulfan I 14.215 17.673 γ-BHC 10.064 13.409 dieldrin 14.743 18.292 β-BHC 10.321 12.426 endrin 15.236 18.940 δ-BHC 10.751 14.386 4,4'-DDD 15.449 19.133 1,2-dinitrobenzene 11.216 11.937 chlorobenzilate 15.657 19.339 heptachlor 11.260 14.559 endosulfan II 15.719 19.412 RETENTION TIME INDEXES prometon 11.380 14.110 4,4'-DDT 16.009 19.832 simazine 11.503 14.463 endrin aldehyde 16.601 20.182 atraton 11.691 14.064 methoxychlor 17.105 21.264 propazine 11.819 14.551 endosulfan sulfate 17.495 20.786 aldrin 11.962 15.381 endrin ketone 18.081 22.054 tributylphosphate 12.074 12.655 triphenylphosphate 20.111 26.284 Nitrogen-Containing Pesticide Compounds Retention Time Index Data collected using 30m, 0.53mm ID, 0.50µm Rtx®-5, Rtx®-35, and Rtx®-1701 columns. Oven temp.: Rtx®-5: 150°C (hold 5 min.) to 275°C @ 4°C/min. (hold 3 min.); Rtx®-35: 150°C (hold 5 min.) to 275°C @ 4°C/min. (hold 7 min.); Rtx®-1701: 150°C (hold 5 min.) to 275°C @ 4°C/min. (hold 5 min.); Carrier gas: helium; Regulation: constant pressure; Linear velocity: 40.0cm/sec. @ 150°C; Dead time: 1.250 min. @ 150°C. Rtx®-5 Rtx®-35 Rtx®-1701 Rtx®-5 Rtx®-35 Rtx®-1701 Component Name Ret. Time Ret. Time Ret. Time Component Name Ret. Time Ret. Time Ret. Time 1,3-dimethyl-2-nitrobenzene 6.12 8.975 — alachlor 27.742 31.069 32.362 dodecane 6.137 4.733 5.187 ametryn 27.842 32.084 32.592 Environmental Compounds dichlorvos 7.795 11.342 12.865 prometryn 28.112 31.828 32.397 EPTC 11.145 13.408 13.83 terbutryn 28.699 32.547 33.075 tetradecane 12.396 10.615 11.704 bromacil 29.283 34.755 38.462 butylate 13.545 14.955 15.678 metolachlor 29.602 32.72 34.082 mevinphos-cis 13.764 18.046 19.697 eicosane 29.907 27.478 28.82 vernolate 14.098 16.133 16.51 triadimefon 30.043 33.08 35.4 pebulate 14.57 16.704 17.035 MGK 264A 30.628 33.376 33.994 tebuthiuron 16.505 21.271 24.066 diphenamid 30.797 36.102 36.418 molinate 16.894 20.619 20.056 isopropalin 31.033 33.532 35.299 hexadecane 18.886 16.7 17.76 MGK 264B 31.204 34.492 — propachlor 19.424 23.206 25.016 pendamethalin 31.508 34.731 35.717 cycloate 19.967 22.63 22.559 merphos 31.557 33.359 33.221 ethoprop 20.068 23.485 24.267 stirofos 33.307 37.568 38.174 chlorpropham 20.672 23.485 26.19 butachlor 33.528 35.997 37.334 trifluralin 21.643 22.128 25.822 napropamide 33.812 38.105 38.706 benefin 21.767 22.311 25.964 fenamiphos 33.925 38.216 39.476 atraton 23.021 26.937 27.89 tricyclozole 34.198 41.331 43.369 prometon 23.368 26.99 27.861 docosane 34.638 32.233 33.558 atrazine 23.552 27.537 29.448 carboxin 34.808 40.365 40.676 propazine 23.801 27.298 29.293 oxadiazon 34.819 37.477 39.076 terbufos 24.195 26.986 27.756 oxyfluorfen 35.133 37.958 40.832 pronamide 24.484 26.902 30.725 norflurazon 38.168 43.291 46.651 profluralin 24.645 25.286 28.781 hexazinone 38.718 45.075 46.735 octadecane 24.678 22.229 23.596 tetracosane 38.955 36.632 37.9 disulfoton 25.057 28.498 29.119 triphenyl phosphate (ISTD) 39.126 43.949 43.959 Diazinon® 25.058 27.932 28.198 hexacosane 42.905 40.716 41.871 terbacil 25.654 30.658 34.349 fenarimol 43.358 48.382 49.362 metribuzin 27.074 32.106 32.976 octacosane 46.548 44.339 45.678 bimetryn 27.615 32.215 32.743 fluridone 48.914 58.305 — Order by phone 800-356-1688 or 814-353-1300 • Order online www.superchrom.it p711-726.qxd 11/15/2002 8:29 AM Page 713 Organophosphorus Pesticide Compounds Retention Time Index Data collected using 30m, 0.32mm ID, 0.50µm Rtx®-OPP column and 30m, 0.32mm ID, 0.32µm Rtx®-OPP2 column.