Past, Present and Future
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Brine Evolution in Qaidam Basin, Northern Tibetan Plateau, and the Formation of Playas As Mars Analogue Site
45th Lunar and Planetary Science Conference (2014) 1228.pdf BRINE EVOLUTION IN QAIDAM BASIN, NORTHERN TIBETAN PLATEAU, AND THE FORMATION OF PLAYAS AS MARS ANALOGUE SITE. W. G. Kong1 M. P. Zheng1 and F. J. Kong1, 1 MLR Key Laboratory of Saline Lake Resources and Environments, Institute of Mineral Resources, CAGS, Beijing 100037, China. ([email protected]) Introduction: Terrestrial analogue studies have part of the basin (Kunteyi depression). The Pliocene is served much critical information for understanding the first major salt forming period for Qaidam Basin, Mars [1]. Playa sediments in Qaidam Basin have a and the salt bearing sediments formed at the southwest complete set of salt minerals, i.e. carbonates, sulfates, part are dominated by sulfates, and those formed at the and chlorides,which have been identified on Mars northwest part of basin are partially sulfates dominate [e.g. 2-4]. The geographical conditions and high eleva- and partially chlorides dominate. After Pliocene, the tion of these playas induces Mars-like environmental deposition center started to move towards southeast conditions, such as low precipitation, low relative hu- until reaching the east part of the basin at Pleistocene, midity, low temperature, large seasonal and diurnal T reaching the second major salt forming stage, and the variation, high UV radiation, etc. [5,6]. Thus the salt bearing sediments formed at this stage are mainly playas in the Qaidam Basin servers a good terrestrial chlorides dominate. The distinct change in salt mineral reference for studying the depositional and secondary assemblages among deposition centers indicates the processes of martian salts. migration and geochemical differentiation of brines From 2008, a set of analogue studies have been inside the basin. -
Potash Case Study
Mining, Minerals and Sustainable Development February 2002 No. 65 Potash Case Study Information supplied by the International Fertilizer Industry Association This report was commissioned by the MMSD project of IIED. It remains the sole Copyright © 2002 IIED and WBCSD. All rights reserved responsibility of the author(s) and does not necessarily reflect the views of the Mining, Minerals and MMSD project, Assurance Group or Sponsors Group, or those of IIED or WBCSD. Sustainable Development is a project of the International Institute for Environment and Development (IIED). The project was made possible by the support of the World Business Council for Sustainable Development (WBCSD). IIED is a company limited by guarantee and incorporated in England. Reg No. 2188452. VAT Reg. No. GB 440 4948 50. Registered Charity No. 800066 1 Introduction 2 2 Global Resources and Potash Production 3 3 The use of potassium in fertilizer 4 3.1 Potassium Fertilizer Consumption 4 3.2 Potassium fertilization issues 6 Appendix A 8 1 Introduction Potash and Potassium Potassium (K) is essential for plant and animal life wherein it has many vital nutritional roles. In plants, potassium and nitrogen are the two elements required in greatest amounts, while in animals and humans potassium is the third most abundant element, after calcium and phosphorus. Without sufficient plant and animal intake of potassium, life as we know it would cease. Human and other animals atop the food chain depend upon plants for much of their nutritional needs. Many soils lack sufficient quantities of available potassium for satisfactory yield and quality of crops. For this reason available soil potassium levels are commonly supplemented by potash fertilization to improve the potassium nutrition of plants, particularly for sustaining production of high yielding crop species and varieties in modern agricultural systems. -
MORDANTING NATURAL DYES IRON SULPHATE (Ferrous Sulphate) Is Usually Used to Change the Colour of a Dye
MORDANTING NATURAL DYES IRON SULPHATE (Ferrous Sulphate) is usually used to change the colour of a dye. It also makes natural dyes Most natural dyes have great affinity for fibre but more light and wash fast. More often used with cellulose poor light and wash fastness. If the fibre is pre than protein as it can make protein fibres brittle and harsh. mordanted you create a bond between the dye Iron changes shades to deeper, darker shades and is better and the fibre which will improve this dramatically. used in a premordant bath than directly into the dyebath. The most common and least environmentally toxic Use at a maximum of 2 to 4 % WOF . are Alum, Iron and Tannin. Copper is a useful mordant but is toxic to marine COPPER (Copper Sulphate)tends dull colours and turn life and humans. It needs to be handled and them blue green ie. yellows become greens, pinks become disposed of carefully. Historically Tin and Chrome purple. You can use Copper as a premordant or as an after have been used but are hazardous to the treatment to adjust colours. Colours dyed with Copper are environment & your health and need to be usually more lightfast than those dyed with Alum. Copper disposed of with great care. For that reason we has a less harsh effect on Protein fibres than Iron. Dispose recommend only using Alum, Iron, Copper and of Copper solution responsibly by exhausting your Tannin. Copper is probably the least safe but will dyebaths, diluting the residue with clean water and don’t give you much brighter shades and is safe to use put it down the storm water. -
Preliminary Final
BLM HB In-Situ Solution Mine Project Record of Decision Carlsbad Field Office , New Mexico March 2012 DOI-BLM-NM-P020-2011-498-EIS BLM Mission Statement The Bureau of Land Management is responsible for stewardship of our public lands. The BLM is committed to manage, protect and improve these lands in a manner to serve the needs of the American people. Management is based upon the principles of multiple use and sustained yield of our nation's resources within a framework of environmental responsibility and scientific technology. These resources include recreation, rangelands, timber, minerals, watershed, fish and wildlife habitat, wilderness, air and scenic quality, as well as scientific and cultural values. Cover photo captions: • Top photo: View from Tower Hill looking north to the location of proposed evaporation ponds. • Lower left: Harvesting potash precipitated from evaporation ponds. Courtesy of Intrepid Potash. • Lower right: Ore pillar crushing out after second mining completed. Ore in the crushed out pillar is the primary ore target for the solution mine. Courtesy of Intrepid Potash. HB In-Situ Solution Mine Project Record of Decision BLM Carlsbad Acronyms and Abbreviations BLM Bureau of Land Management CFR Code of Federal Regulations EIS Environmental Impact Statement FLPMA Federal Land Policy and Management Act of 1976 Intrepid Intrepid Potash, Inc. MLA Mineral Leasing Act of 1920, as amended NEPA National Environmental Policy Act NMED New Mexico Environment Department NOA Notice of Availability OHV off-highway vehicle RMP Resource Management Plan ROW right-of-way SPA Secretary’s Potash Area USC United States Code USFWS U.S. Fish and Wildlife Service AA-1 HB In-Situ Solution Mine Project Record of Decision BLM Carlsbad Contents 1.0 Introduction ................................................................................................................................................ -
The Art of Mordanting and Staining and the Complete Treatment of Wood
The Artof/Aordanting and Staining ' N:i^\><v 5W^ \\ \ ^^^ Class. X ) 3^^ Book -A fe Copyright }1® - COPYRIGHT DEPOSIT. C^z-A-^^UX-ftUv^w*^ %««<«^vvwn''v<^t'^"t^'>vva-'VU'nH^ , THE ART OF M ORD A NTI NG AND STAINING AND THE COMPLETE TREATMENT OF WOOD SURFACES A HANDBOOK AND AID FOR ARCHITECTS, CABINET MAKERS, DECORATORS, PAINTERS, PIANO FACTORIES AND TRADE SCHOOLS BY WILLIAM ZIMMERMANN INSTRUCTOR OF CHKMISTRY IN POLYTECHNIC INSTITUTE, BARMEN, GERMANY BOSTON, MASS.: THE ARTI-STAIN CO. 1911 \J> First English Edition Copyright 191 i BY W. F. PURSCHER All Rights Reserved ^ r/> ARTI-STAIN CO. Sole Agents for U. S. A. and the Dominion of Canada / !)CI.A28t)433 PREFACE Since the appearance of the Fifth Edition of this work in 1908, it has again been considerably enlarged and revised and the results incorporated in the present Sixth Edition. In the portion relating to staining, the chapter on Brown Stains, which occupy an important position in connection with modern furniture and fittings, has been completely revised and enlarged by the introduction of the new and practically-tested Special-Oak Stains, An- thracene Stains and Genuine-Mahogany Stains, which have been very favorably received. Because of their lesser importance, the number of staining formulas for bright colors has been diminished, but these have been replaced by staining formulas for new products of greater fastness to light. All suggestions and experiments since the last edition have been incorporated here. The Sample Card of colors (in the Supplement) has been made to correspond with the new formulas in the book. -
Mining Methods for Potash
Potash—A Vital Agricultural Nutrient Sourced from Geologic Deposits Open File Report 2016–1167 U.S. Department of the Interior U.S. Geological Survey Cover. Photos of underground mining operations, Carlsbad, New Mexico, Intrepid Potash Company, Carlsbad West Mine. Potash—A Vital Agricultural Nutrient Sourced from Geologic Deposits By Douglas B. Yager Open File Report 2016–1167 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior SALLY JEWELL, Secretary U.S. Geological Survey Suzette M. Kimball, Director U.S. Geological Survey, Reston, Virginia: 2016 For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS. For an overview of USGS information products, including maps, imagery, and publications, visit http://store.usgs.gov/. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government. Although this information product, for the most part, is in the public domain, it also may contain copyrighted materials as noted in the text. Permission to reproduce copyrighted items must be secured from the copyright owner. Suggested citation: Yager, D.B., 2016, Potash—A vital agricultural nutrient sourced from geologic deposits: U.S. Geological Survey Open- File Report 2016–1167, 28 p., https://doi.org/10.3133/ofr20161167. ISSN 0196-1497 (print) ISSN 2331-1258 (online) ISBN 978-1-4113-4101-2 iii Acknowledgments The author wishes to thank Joseph Havasi of Compass Minerals for a surface tour of their Great Salt Lake operations. -
S40645-019-0306-X.Pdf
Isaji et al. Progress in Earth and Planetary Science (2019) 6:60 Progress in Earth and https://doi.org/10.1186/s40645-019-0306-x Planetary Science RESEARCH ARTICLE Open Access Biomarker records and mineral compositions of the Messinian halite and K–Mg salts from Sicily Yuta Isaji1* , Toshihiro Yoshimura1, Junichiro Kuroda2, Yusuke Tamenori3, Francisco J. Jiménez-Espejo1,4, Stefano Lugli5, Vinicio Manzi6, Marco Roveri6, Hodaka Kawahata2 and Naohiko Ohkouchi1 Abstract The evaporites of the Realmonte salt mine (Sicily, Italy) are important archives recording the most extreme conditions of the Messinian Salinity Crisis (MSC). However, geochemical approach on these evaporitic sequences is scarce and little is known on the response of the biological community to drastically elevating salinity. In the present work, we investigated the depositional environments and the biological community of the shale–anhydrite–halite triplets and the K–Mg salt layer deposited during the peak of the MSC. Both hopanes and steranes are detected in the shale–anhydrite–halite triplets, suggesting the presence of eukaryotes and bacteria throughout their deposition. The K–Mg salt layer is composed of primary halites, diagenetic leonite, and primary and/or secondary kainite, which are interpreted to have precipitated from density-stratified water column with the halite-precipitating brine at the surface and the brine- precipitating K–Mg salts at the bottom. The presence of hopanes and a trace amount of steranes implicates that eukaryotes and bacteria were able to survive in the surface halite-precipitating brine even during the most extreme condition of the MSC. Keywords: Messinian Salinity Crisis, Evaporites, Kainite, μ-XRF, Biomarker Introduction hypersaline condition between 5.60 and 5.55 Ma (Manzi The Messinian Salinity Crisis (MSC) is one of the most et al. -
1469 Vol 43#5 Art 03.Indd
1469 The Canadian Mineralogist Vol. 43, pp. 1469-1487 (2005) BORATE MINERALS OF THE PENOBSQUIS AND MILLSTREAM DEPOSITS, SOUTHERN NEW BRUNSWICK, CANADA JOEL D. GRICE§, ROBERT A. GAULT AND JERRY VAN VELTHUIZEN† Research Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada ABSTRACT The borate minerals found in two potash deposits, at Penobsquis and Millstream, Kings County, New Brunswick, are described in detail. These deposits are located in the Moncton Subbasin, which forms the eastern portion of the extensive Maritimes Basin. These marine evaporites consist of an early carbonate unit, followed by a sulfate, and fi nally, a salt unit. The borate assemblages occur in specifi c beds of halite and sylvite that were the last units to form in the evaporite sequence. Species identifi ed from drill-core sections include: boracite, brianroulstonite, chambersite, colemanite, congolite, danburite, hilgardite, howlite, hydroboracite, kurgantaite, penobsquisite, pringleite, ruitenbergite, strontioginorite, szaibélyite, trembathite, veatchite, volkovskite and walkerite. In addition, 41 non-borate species have been identifi ed, including magnesite, monohydrocalcite, sellaite, kieserite and fl uorite. The borate assemblages in the two deposits differ, and in each deposit, they vary stratigraphically. At Millstream, boracite is the most common borate in the sylvite + carnallite beds, with hilgardite in the lower halite strata. At Penobsquis, there is an upper unit of hilgardite + volkovskite + trembathite in halite and a lower unit of hydroboracite + volkov- skite + trembathite–congolite in halite–sylvite. At both deposits, values of the ratio of B isotopes [␦11B] range from 21.5 to 37.8‰ [21 analyses] and are consistent with a seawater source, without any need for a more exotic interpretation. -
Nabokoite Cu7(Te4+O4)
4+ Nabokoite Cu7(Te O4)(SO4)5 • KCl c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Tetragonal. Point Group: 4/m 2/m 2/m. Crystals are thin tabular on {001}, to 1 mm, showing {001}, {110}, {102}, {014}, in banded intergrowth with atlasovite. Physical Properties: Cleavage: Perfect on {001}. Hardness = 2–2.5 D(meas.) = 4.18(5) D(calc.) = 3.974 Optical Properties: Transparent. Color: Pale yellow-brown, yellow-brown. Streak: Yellow- brown. Luster: Vitreous. Optical Class: Uniaxial (–). ω = 1.778(3) = 1.773(3) Cell Data: Space Group: P 4/ncc. a = 9.833(1) c = 20.591(2) Z = 4 X-ray Powder Pattern: Tolbachik volcano, Russia. 10.35 (10), 2.439 (7), 3.421 (6), 2.881 (5), 4.57 (4), 3.56 (4), 1.972 (4) Chemistry: (1) (2) SO3 33.66 33.60 TeO2 13.78 13.40 V2O3 0.07 Bi2O3 0.49 Fe2O3 0.09 CuO 45.25 46.74 ZnO 1.26 PbO 0.28 K2O 3.94 3.95 Cs2O 0.11 Cl 2.92 2.98 −O=Cl2 0.66 0.67 Total 101.19 100.00 (1) Tolbachik volcano, Russia; by electron microprobe, corresponds to (Cu6.74Zn0.18)Σ=6.92 (Te1.02Bi0.02Pb0.01Fe0.01V0.01)Σ=1.07O4.10(SO4)4.98Cl0.98. (2) KCu7(TeO4)(SO4)5Cl. Polymorphism & Series: Forms a series with atlasovite. Occurrence: A rare sublimate formed in a volcanic fumarole. Association: Atlasovite, chalcocyanite, dolerophanite, chloroxiphite, euchlorine, piypite, atacamite, alarsite, fedotovite, lammerite, klyuchevskite, anglesite, langbeinite, hematite, tenorite. Distribution: From the Tolbachik fissure volcano, Kamchatka Peninsula, Russia. -
United States Patent (11) 3,615,174
United States Patent (11) 3,615,174 72 Inventor William J. Lewis 3,342,548 9/1967 Macey....... A. 2319 X South Ogden, Utah 3,432,031 3/1969 Ferris........................... 209/166 X 21 Appl. No. 740,886 FOREIGN PATENTS 22, Filed June 28, 1968 45 Patented Oct. 26, 1971 1,075,166 4f1954 France ......................... 209/66 (73) Assignee NL Industries, Inc. OTHER REFERENCES New York, N.Y. Chem. Abst., Vol. 53, 1959, 9587e I & EC, Vol. 56, 7, Jy '64, 61 & 62. Primary Examiner-Frank W. Lutter 54 PROCESSFOR THE SELECTIVE RECOVERY OF Assistant Examiner-Robert Halper POTASSUMAND MAGNESUMWALUES FROM Attorney-Ward, McElhannon, Brooks & Fitzpatrick AQUEOUSSALT SOLUTIONS CONTAINING THE SAME 11 Claims, 4 Drawing Figs. ABSTRACT: Kainite immersed in brine in equilibrium con 52) U.S. Cl........................................................ 23138, verted to carnalite by cooling to about 10 C. or under. Car 209/11, 209/166,23191, 22/121 nallite so obtained purified by cold flotation. Purified carnal (5) Int. Cl......................................................... B03b 1100, lite water leached to yield magnesium chloride brine and B03d 1102, C01f 5126 potassium chloride salt. Latter optionally converted to potas 50 Field of Search............................................ 209/166,3, sium sulfate by reaction with kainite, or by reacting the carnal 10, 11; 23.19, 38, 121 lite with kainite. Naturally occurring brine concentrated to precipitate principally sodium chloride, mother liquor warm 56 References Cited concentrated to precipitate kainite, cooled under mother UNITED STATES PATENTS liquor for conversion to carnallite. A crude kainite fraction 2,479,001 8/1949 Burke........................... 23.191 purified by warm flotation and a crude carnallite fraction pu 2,689,649 9, 1954 Atwood.... -
Ancient Potash Ores
www.saltworkconsultants.com John Warren - Friday, Dec 31, 2018 BrineSalty evolution Matters & origins of pot- ash: primary or secondary? Ancient potash ores: Part 3 of 3 Introduction Crossow of In the previous two articles in this undersaturated water series on potash exploitation, we Congruent dissolution looked at the production of either Halite Mouldic MOP or SOP from anthropo- or Porosity genic brine pans in modern saline sylvite lake settings. Crystals of interest formed in solar evaporation pans Dissolved solute shows stoichiometric match to precursor, and dropped out of solution as: dissolving salt goes 1) Rafts at the air-brine interface, A. completely into solution 2) Bottom nucleates or, 3) Syn- depositional cements precipitated MgCl in solution B. 2 within a few centimetres of the Crossow of depositional surface. In most cases, undersaturated water periods of more intense precipita- Incongruent dissolution tion tended to occur during times of brine cooling, either diurnally Carnallite Sylvite or seasonally (sylvite, carnallite and halite are prograde salts). All Dissolved solute does not anthropogenic saline pan deposits stoichiometrically match its precursor, examples can be considered as pri- while the dissolving salt goes partially into solution and a mary precipitates with chemistries new daughter mineral remains tied to surface or very nearsurface Figure 1. Congruent (A) versus incongruent (B) dissolution. brine chemistry. In contrast, this article discusses the Dead Sea and the Qaidam sump most closely resemble ancient potash deposits where the post-deposition chem- those of ancient MgSO4-depleted oceans, while SOP fac- istries and ore textures are responding to ongoing alter- tories in Great Salt Lake and Lop Nur have chemistries ation processes in the diagenetic realm. -
PSC Technical Advisory Panel Report.Pdf
National Organic Standards Board Technical Advisory Panel Review compiled by University of California Sustainable Agriculture Research and Education Program (UC SAREP) for the USDA National Organic Program Potassium Sulfate for use in crop production Executive Summary1 The following petition is under consideration with respect to NOP regulations subpart G, governing the inclusion of substances on the National List of Allowed and Prohibited Substances: Petitioned: Addition of potassium sulfate to section 205.601(j), “Synthetic substances allowed for use in organic crop production as plant or soil amendments.” Potassium sulfate is a source of highly soluble potassium, and has the additional benefit of supplying sulfur. It is used in agricultural production systems where potassium is a limiting nutrient and also as a substitute for potassium chloride on chloride- sensitive crops. The NOP has no prior ruling on the use of the substance. The nature of the petitioned substance is highly debatable. Naturally occurring potassium sulfate is not subject to the TAP review process because “naturally-occurring” substances are implicitly allowed for use in organics. The intended sourcing of the petitioned form of potassium sulfate, however, brings into question the interpretive distinctions between a “synthetic” and a “non-synthetic” under organic law. According to the petitioner, the product “should not be treated differently than product produced from natural brines” since it is produced from naturally occurring minerals. The crux of the decision to grant the petition rests on how one chooses to interpret this equivalency claim. All TAP reviewers agreed that the petitioned substance should be considered synthetic. In general, the reviewers also agreed that it should be restricted as a soil adjuvant.