The Crystal Structure of Fornacite*
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Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Liroconite Cu2al(Aso4)(OH)4 • 4H2O C 2001-2005 Mineral Data Publishing, Version 1
Liroconite Cu2Al(AsO4)(OH)4 • 4H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Typically as crystals with a flattened octahedral or lenticular aspect, dominated by {110} and {011} and striated parallel to their intersections, also {001}, {010}, {100}, to 3.6 cm, alone and in sub-parallel groups. May be granular, massive. Physical Properties: Cleavage: On {110}, {011}, indistinct. Fracture: Uneven to conchoidal. Hardness = 2–2.5 D(meas.) = 2.94–3.01 D(calc.) = [3.03] Optical Properties: Transparent to translucent. Color: Sky-blue, bluish green, verdigris-green, emerald-green; pale blue to pale bluish green in transmitted light. Streak: Pale blue to pale green. Luster: Vitreous to resinous. Optical Class: Biaxial (–). Orientation: Y = b; Z ∧ a =25◦. Dispersion: r< v,moderate. α = 1.612(3) β = 1.652(3) γ = 1.675(3) 2V(meas.) = n.d. 2V(calc.) = 72(5)◦ Cell Data: Space Group: I2/a. a = 12.664(2) b = 7.563(2) c = 9.914(3) β =91.32(2)◦ Z=4 X-ray Powder Pattern: Cornwall, England. 6.46 (10), 3.01 (10), 5.95 (9), 2.69 (6), 3.92 (5), 2.79 (5), 2.21 (5) Chemistry: (1) (2) P2O5 3.73 As2O5 23.05 26.54 Al2O3 10.85 11.77 Fe2O3 0.98 CuO 36.38 36.73 H2O 25.01 24.96 Total 100.00 100.00 • (1) Cornwall, England. (2) Cu2Al(AsO4)(OH)4 4H2O. Occurrence: A rare secondary mineral in the oxidized zone of some copper deposits. Association: Olivenite, chalcophyllite, clinoclase, cornwallite, strashimirite, malachite, cuprite, “limonite”. -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
New Mineral Names*
American Mineralogist, Volume 62, pages 173-176, 1977 NEW MINERAL NAMES* MrcHlrI- Fr-BlscHrnAND J. A. MeNnn'ntNo and Institute Agrellite* Museum of Canada, Geological Survey of Canada, for the Mineralogy, Geochemistryand Crystal Chemistry of the J. GrrrrNs, M. G. BowN .qNoB. D. Srunlt.ltt (1976)Agrellite, a Rare Elements(Moscow). J. A. M. new rock-forming mineral in regionally metamorphosed agpaitic alkafic rocks Can. Mineral. 14, 120-126. Fedorovskite+ The mineral occurs as lensesand pods in mafic gneissescom- posed of albite, microcline, alkalic amphibole, aegirine-augite, S. V. MeltNro, D P SsrsurlN and K V. YunrtN'l (1976) eudialyte,and nepheline.Other mineralspresent are: hiortdahlite, Fedorovskite,a new boron mineral,and the isomorphousseries other members of the w<ihleritegroup, mosandrite, miserite, brith- roweite-fedorovskite olite, vlasovite, calcite, fluorite, clinohumite, norbergite, zircon, Zap. Vses Mineral- O'uo 105,71-85 (in Russian)' biotite, phlogopite, galena, and a new unnamed mineral, CaZr- SirO, [seeabstract in Am. Mineral 61, 178-179 (1976)]. The local- ity is on the Kipawa River, Villedieu Township, T6miscamingue County, Quebei, Canada, at about Lat.46" 4'7' 49" N, and Long 78" 29'3l" W (Note by J.A.M.: The Lat. and Long. figuresare interchangedin the paper,and the figurefor the latitudeshould be 46" not 45" ) Agrellite occurs as crystals up to 100 mm in length. They are HCI elongatedparallel to [001] and are flattened on either {010} or X-ray powder data are given for the first 3 samplesanalyzed For { I l0} The color is white to greyishor greenishwhite The lusteron sample(Mg*Mn.u), the strongestlines (41 given) are 3'92 cleavagesis pearly. -
Chapter 4 Minerals (Quiz Free)
Minerals Chapter 4 Section 4.1 What is a mineral? Define a mineral. Describe how minerals form. Identify the most common elements in Earth’s crust. Potash Liroconite Sphalerite Gold Earth’s Crust There are at least 3,000 known minerals in Earth’s crust. Define a mineral. A Mineral – (characteristics)is •naturally occurring •inorganic solid •has a crystal structure •definite chemical composition. Potash Liroconite Gold Sphalerite (Native Element) Solid Minerals always exist in a solid form. Salt Diamond Composition Although a few minerals are composed of single elements, most are made from compounds. Gold Sphalerite Liroconite Potash Composition (continued) Solids with a specific chemical composition Quartz’s chemical ratio (recipe) is always: SiO2 Composition may vary slightly Quartz within a well-defined range. The recipe is still the same. Olivine (Mg,Fe) SiO 100% 2 4 100% Mg Fe Olivine Forsterite Fayalite Magma Magma - Molten material found beneath Earth’s crust Minerals formation Minerals can form when differences in density force magma upward into cooler layers of Earth’s interior. Minerals from solution Minerals form from cooled magma and from elements in solutions. Minerals from solution (Continued) Mineral crystals may begin to precipitate out of a solution that has become saturated. Most abundant elements The most abundant elements in Earth’s crust are oxygen and silicon . Most common minerals The most common minerals, feldspar and quartz, are silicates. (SiO ) tetrahedron XAl(1-2) Si(3-2) O8 4 X may = Sodium, potassium, calcium Silicates Silicate - Mineral that contains silicon and oxygen (SiO4) tetrahedron 4.1 – What is a Mineral? Quiz 1.Although a few minerals are composed of single elements most are made from ____________. -
C:\Documents and Settings\Alan Smithee\My Documents\MOTM
Itkx1//7Lhmdq`knesgdLnmsg9Rshbgshsd Our ongoing search for new minerals to feature finds us scouring the more than forty separate shows that comprise the Tucson Gem & Mineral show every year, looking for large lots of interesting and attractive minerals. The search is rewarded when we make a new contact and find something especially vibrant like this month’s combination of lavender stichtite in green serpentinite! OGXRHB@K OQNODQSHDR Chemistry: Mg6Cr2(CO3)(OH)16A4H2O Basic Hydrous Magnesium Chromium Carbonate (Hydrous Magnesium Chromium Carbonate Hydroxide) Class: Carbonates Subclass: Carbonates with hydroxyl or halogen radicals Group: Hydrotalcite Crystal System: Trigonal Crystal Habits: Crystals rarely macroscopic; usually as crust-like aggregates in matrix; sometimes radiating, micaceous with flexible plates, and nodular with tuberous, irregular surface projections; also massive and fibrous. Color: Lavender, lilac, light violet, pink, or purplish. Luster: Waxy, greasy, sometimes pearly. Transparency: Transparent to translucent Streak: White to pale lilac Refractive Index: 1.516-1.542 Cleavage: Perfect in one direction Fracture: Uneven, brittle. Hardness: 1.5-2.0 Specific Gravity: 2.2 Luminescence: None Distinctive Features and Tests: Softness, color, crystal habits, occurrence in chromium-rich metamorphic environments, and frequent association with serpentinite (a greenish metamorphic rock). Stichtite can be confused with similarly colored sugilite [potassium sodium iron manganese aluminum lithium silicate, KNa2(Fe,Mn,Al)2Li2Si12O30]. -
Journal of the Russell Society, Vol 4 No 2
JOURNAL OF THE RUSSELL SOCIETY The journal of British Isles topographical mineralogy EDITOR: George Ryba.:k. 42 Bell Road. Sitlingbourn.:. Kent ME 10 4EB. L.K. JOURNAL MANAGER: Rex Cook. '13 Halifax Road . Nelson, Lancashire BB9 OEQ , U.K. EDITORrAL BOARD: F.B. Atkins. Oxford, U. K. R.J. King, Tewkesbury. U.K. R.E. Bevins. Cardiff, U. K. A. Livingstone, Edinburgh, U.K. R.S.W. Brai thwaite. Manchester. U.K. I.R. Plimer, Parkvill.:. Australia T.F. Bridges. Ovington. U.K. R.E. Starkey, Brom,grove, U.K S.c. Chamberlain. Syracuse. U. S.A. R.F. Symes. London, U.K. N.J. Forley. Keyworth. U.K. P.A. Williams. Kingswood. Australia R.A. Howie. Matlock. U.K. B. Young. Newcastle, U.K. Aims and Scope: The lournal publishes articles and reviews by both amateur and profe,sional mineralogists dealing with all a,pecI, of mineralogy. Contributions concerning the topographical mineralogy of the British Isles arc particularly welcome. Not~s for contributors can be found at the back of the Journal. Subscription rates: The Journal is free to members of the Russell Society. Subsc ription rates for two issues tiS. Enquiries should be made to the Journal Manager at the above address. Back copies of the Journal may also be ordered through the Journal Ma nager. Advertising: Details of advertising rates may be obtained from the Journal Manager. Published by The Russell Society. Registered charity No. 803308. Copyright The Russell Society 1993 . ISSN 0263 7839 FRONT COVER: Strontianite, Strontian mines, Highland Region, Scotland. 100 mm x 55 mm. -
Mottramite, Descloizite, and Vanadinite) in the Caldbeck Area of Cumberland
289 New occurrences of vanadium minerals (mottramite, descloizite, and vanadinite) in the Caldbeck area of Cumberland. By ART~VR W. G. KINGSBURu F.G.S., Dept. of Geology and Mineralogy, University Museum, Oxford, and J. HARTLnY, B.Sc., F.G.S., Dept. of Geology, University of Leeds. [Taken as read 10 June 1954.] Summary.--Four new occurrences of vanadium minerals are described. New X-ray powder data are given for descloizite and mottramite, and show appreciable differences. Evidence is brought that the original occurrence of mottramite was not at Mottram St. Andrew, Cheshire, but Pim Hill, Shropshire, and that most if not all specimens labelled Mottram St. Andrew or Cheshire really came from Pim Hill. ANADIUM minerals are rare in the British Isles, and only two V species, mottramite (Cu, Zn)PbV0tOH and vanadinite Pbs(VO4)aC1, have so far been recorded from a limited number of localities. We do not include the vanadiferous nodules from Budleigh Salterton in Devon, as the vanadiferous mineral has not been identified. Mottramite, supposedly from Mottram St. Andrew in Cheshire, was first described in 1876,1 but we have evidence (below, p. 293) that the locality was in fact Pim Hill in Shropshire. ~ Vanadinite has so far only been found at Leadhills and Wanlockhead in Scotland. Vauquelinite has been de- scribed from Leadhills and Wanlockhead,a but the specimens have since been shown to be mottramite. 4 As a result of our investigations in the Lake District, we have found several new localities in the Caldbeck area for raottramite, deseloizite, and vanadinite. Higher part of Brandy Gill, Carroek Fell. -
The Minerals of Tasmania
THE MINERALS OF TASMANIA. By W. F. Petterd, CM Z.S. To the geologist, the fascinating science of mineralogy must always be of the utmost importance, as it defines with remarkable exactitude the chemical constituents and com- binations of rock masses, and, thus interpreting their optical and physical characters assumed, it plays an important part part in the elucidation of the mysteries of the earth's crust. Moreover, in addition, the minerals of a country are invari- ably intimately associated with its industrial progress, in addition to being an important factor in its igneous and metamorphic geology. In this dual aspect this State affords a most prolific field, perhaps unequalled in the Common- wealth, for serious consideration. In this short article, I propose to review the subject of the mineralogy of this Island in an extremely concise manner, the object being, chiefly, to afford the members of the Australasian Association for the Advancement of Science a cursory glimpse into Nature's hidden objects of wealth, beauty, and scientific interest. It will be readily understood that the restricted space at the disposal of the writer effectually prevents full justice being done to an absorbing subject, which is of almost universal interest, viewed from the one or the other aspect. The economic result of practical mining operations, as carried on in this State, has been of a most satisfactory character, and has, without doubt, added greatly to the national wealth ; but, for detailed information under this head, reference must be made to the voluminous statistical information, and the general progress, and other reports, issued by the Mines Department of the local Government. -
Rongibbsite, Pb2(Si4al)O11(OH), a New Zeolitic Aluminosilicate Mineral with an Interrupted Framework from Maricopa County, Arizona, U.S.A
American Mineralogist, Volume 98, pages 236–241, 2013 Rongibbsite, Pb2(Si4Al)O11(OH), a new zeolitic aluminosilicate mineral with an interrupted framework from Maricopa County, Arizona, U.S.A. HEXIONG YANG,* ROBERT T. DOWNS, STANLEY H. EVANS, ROBERT A. JENKINS, AND ELIAS M. BLOCH Department of Geosciences, University of Arizona, 1040 East 4th Street, Tucson, Arizona 85721-0077, U.S.A. ABSTRACT A new zeolitic aluminosilicate mineral species, rongibbsite, ideally Pb2(Si4Al)O11(OH), has been found in a quartz vein in the Proterozoic gneiss of the Big Horn Mountains, Maricopa County, Arizona, U.S.A. The mineral is of secondary origin and is associated with wickenburgite, fornacite, mimetite, murdochite, and creaseyite. Rongibbsite crystals are bladed (elongated along the c axis, up to 0.70 × 0.20 × 0.05 mm), often in tufts. Dominant forms are {100}, {010}, {001}, and {101}. Twinning is common across (100). The mineral is colorless, transparent with white streak and vitreous luster. It is brittle and has a Mohs hardness of ∼5; cleavage is perfect on {100} and no parting was observed. 3 The calculated density is 4.43 g/cm . Optically, rongibbsite is biaxial (+), with nα = 1.690, nβ = 1.694, Z nγ = 1.700, c = 26°, 2Vmeas = 65(2)°. It is insoluble in water, acetone, or hydrochloric acid. Electron microprobe analysis yielded an empirical formula Pb2.05(Si3.89Al1.11)O11(OH). Rongibbsite is monoclinic, with space group I2/m and unit-cell parameters a = 7.8356(6), b = 13.913(1), c = 10.278(1) Å, β = 92.925(4)°, and V = 1119.0(2) Å3. -
NO. 7. RESTORMELITE. I Have Obtained on Various Ocasions, from the Restormel Iron Mine, a Mineral Which Might Easilybe Mistaken for One Or Other View Article Online
View Article Online / Journal Homepage / Table of Contents for this issue CHURCH’S CHEMICAL RESEARCHES, ETC. 165 Published on 01 January 1870. Downloaded by University of Lancaster 30/10/2014 18:23:36. XXK- C7iemicaI Researches on hTew or Rare Cornish Minerals. By A. H. CHURCH,M.A., Oxon., Professor of Chemistry, Royal Agricultural College, Cirencester. NO. 7. RESTORMELITE. I have obtained on various ocasions, from the Restormel Iron Mine, a mineral which might easilybe mistaken for one or other View Article Online 166 CHURCH’S CHEMICAL RESEARCHES of the Chinese stones, which are grouped under the vague term agalmatolite. But on comparing the physical and chemical characters of these oriental pinites and pyrophyllites with my Cornish specimeiis, I found such marked differences as to induce me to make a more extended study of the subject. The mate- rial being amorphous, and evidently incompletely altered, was far from promising, but the hope of throwing some light upon the chemical history and formation of similar products, induced me to make several analyses of my specimens. The constancy of their characters and composition was distinctly proved by a physical examination, and by the experimental cheniical results given below. I do not, however, think that I should be in the least degree warranted in assigning specific rank to the Restor- me1 mineral, and though I propose for it the definite name of restorinelite, its proper place appears to me that of a new variety of kaolinite. If we look at the various hydrated aluminium silicates, which have been separately recognized, we shall find that restormelite is near halloysite, but differs from that species by containing 7 per cent. -
Kernowite, Cu2fe(Aso4)(OH)4⋅4H2O, the Fe -Analogue of Liroconite from Cornwall, UK
Mineralogical Magazine (2021), 85, 283–290 doi:10.1180/mgm.2021.40 Article 3+ Kernowite, Cu2Fe(AsO4)(OH)4⋅4H2O, the Fe -analogue of liroconite from Cornwall, UK Michael S. Rumsey1* , Mark D. Welch1, John Spratt2, Annette K. Kleppe3 and Martin Števko4,5 1Department of Earth Sciences, Natural History Museum, London SW7 5BD, UK; 2Core Research Laboratories, Natural History Museum, London SW7 5BD, UK; 3Diamond Lightsource UK, Harwell Science Park, Chilton, Oxfordshire OX11 0DE, UK; 4Earth Science Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 840 05 Bratislava, Slovak Republic; and 5Department of Mineralogy and Petrology, National Museum, Cirkusová 1740, 193 00 Praha, Horní Počernice, Czech Republic Abstract ⋅ The occurrence, chemical composition and structural characterisation of the new mineral kernowite, ideally Cu2Fe(AsO4)(OH)4 4H2O, 3+ ⋅ the Fe -analogue of liroconite, Cu2Al(AsO4)(OH)4 4H2O, are described. Kernowite (IMA2020-053) occurs on specimens probably sourced from the Wheal Gorland mine, St Day, Cornwall, UK, in the cavities of a quartz-gossan rich in undifferentiated micro-crystalline grey sulfides and poorly crystalline arsenic phases including both pharmacosiderite and olivenite-group minerals. The average compos- ition of kernowite determined from several holotype fragments by electron microprobe analysis is Cu1.88(Fe0.79Al0.09)Σ0.88(As1.12O4) ⋅ (OH)4 3.65H2O. The structure of kernowite has been determined in monoclinic space group I2/a (a non-standard setting of C2/c) by single-crystal X-ray diffraction (SCXRD) to R1 = 0.025, wR2 = 0.051 and Goodness-of-fit = 1.112. Unit-cell parameters from SCXRD are a = 12.9243(4) Å, b=7.5401(3) Å, c=10.0271(3) Å, β = 91.267(3)°, V=976.91(6) Å3 and Z = 4.