minerals Article REE Enrichment during Magmatic–Hydrothermal Processes in Carbonatite-Related REE Deposits: A Case Study of the Weishan REE Deposit, China Yu-heng Jia 1,2 and Yan Liu 2,3,* 1 Earth Science Institute, Guilin University of Technology, Guilin 541004, China;
[email protected] 2 Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources, Institute of Geology, Chinese Academy of Geological Science, Beijing 100037, China 3 Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou 511458, China * Correspondence:
[email protected] Received: 22 August 2019; Accepted: 20 December 2019; Published: 27 December 2019 Abstract: The Weishan carbonatite-related rare earth element (REE) deposit in China contains both high- and low-grade REE mineralization and is an informative case study for the investigation of magmatic–hydrothermal REE enrichment processes in such deposits. The main REE-bearing mineral is bastnäsite, with lesser parisite and monazite. REE mineralization occurred at a late stage of hydrothermal evolution and was followed by a sulfide stage. Barite, calcite, and strontianite appear homogeneous in back-scattered electron images and have high REE contents of 103–217, 146–13,120, and 194–16,412 ppm in their mineral lattices, respectively. Two enrichment processes were necessary for the formation of the Weishan deposit: Production of mineralized carbonatite and subsequent enrichment by magmatic–hydrothermal processes. The geological setting and petrographic characteristics of the Weishan deposit indicate that two main factors facilitated REE enrichment: (1) fractures that facilitated circulation of ore-forming fluids and provided space for REE precipitation and (2) high ore fluorite 2 and barite contents resulting in high F− and SO4 − concentrations in the ore-forming fluids that promoted REE transport and deposition.