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PL9902258 ISSN 1425-204X INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY (27 no Iff] /a} IT 1998 I 30-44 EDITORS Wiktor Smuiek, Ph.D. Bozena Bursa PRINTING Sylwester Wojtas © Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 1999 All rights reserved CONTENTS GENERAL INFORMATION 9 MANAGEMENT OF THE INSTITUTE 11 MANAGING STAFF OF THE INSTITUTE 11 HEADS OF THE INCT DEPARTMENTS 11 PROFESSORS AND SCIENTIFIC COUNCIL 12 PROFESSORS 12 ASSOCIATE PROFESSORS 13 ASSISTANT PROFFESSORS (Ph.D.) 13 SCIENTIFIC COUNCIL (1995-1999) 15 HONORARY MEMBERS OF THE INCT SCIENTIFIC COUNCIL (1995-1999) 16 RADIATION CHEMISTRY AND PHYSICS, RADIATION TECHNOLOGIES 17 PHOTOOXIDATION OF METHIONINE DERIVATIVES IN AQUEOUS SOLUTIONS K. Bobrowski, G.L. Hug, B. Marciniak 19 HYDROXYL RADICAL INDUCED OXIDATION OF (x-(METHYLTHIO)ACETAMIDE IN AQUEOUS SOLUTIONS P. WiSniowski, K. Bobrowski 20 SILVER CLUSTERS IN ZIC-4 ZEOLITES J. Michalik, Jong-Sung Yu, J. Sadio 21 ESR STUDY OF POLYCRYSTALLINE TRIPEPTIDES G. Strzelczak, K. Bobrowski, J. Michalik 24 EPR STUDY OF PARAMAGNETIC PRODUCTS IN DRUGS FOLLOWING y-STERILISATION H.B. Ambroz, E.M. Kornacka, B. Marciniec, G. Przybytniak 26 MODIFICATION OF DNA RADIOLYSIS BY DTT AT CRYOGENIC TEMPERATURES H.B. Ambroz, E.M. Kornacka, G. Przybytniak 27 THEORETICAL STUDY ON DECOMPOSITION OF ETHYL CHLORIDE IN DRY AIR UNDER INFLUENCE OF ELECTRON BEAM H. Nichipor, E. Dashouk, A.G. Chmielewski, Z. Zimek, S. Buika 28 EFFECT OF SELECTED INORGANIC SCAVENGERS ON RADIOLYTIC DEGRADATION OF 2,4-DICHLOROPHENOL P. Drzewicz, P.P. Panta, W. GJuszewski, M. Trojanowicz 30 RADIATION YIELD OF MULTI-IONIZATION SPURS IN SOLID ALANINE Z.P. Zagorski 33 FREE RADICALS IN EB IRRADIATED BLENDS OF POLYETHYLENE AND BUTADIENE-STYRENE BLOCK COPOLYMER G.K. Przybytnialc, Z.P. Zagorski, D. Zuchowska 34 A PULSE RADIOLYSIS STUDY ON SINGLE CRYSTALS OF a-ALANINE Z.P. Zagorski, K. Sehested 36 RADIATION CHEMISTRY OF SOLID THIOSULFATE. I. OPTICAL ABSORPTION SPECTRA Z.P. Zagorski, A. Rafalski 38 RADIATION CHEMISTRY OF VIRGIN POLYPROPYLENE A. Rafalski 41 EFFECTS OF GAMMA IRRADIATION AND ANNEALING TREATMENTS ON THE PERFORMANCE OF Cr;Tm;Ho:YAG LASERS S.M. Kaczmarek, W. Zendzian, T. Lukasiewicz, K. St^pka, Z. Moroz, S. Warchoi 43 HIGH ENERGY ION IMPLANTATION PROFILES J. Krynicki, J. Puton, J. Oleniak, S. Warchol, H. Rzewuski 45 DRS QUANTIFICATION OF ABSORBED RADIATION DOSE INDICATED BY LABELS Z.P. Zagorski, A. Rafalski 46 A THIN, COMPOSITE SODIUM CHLORIDE DOSIMETER WITH DIFFUSE REFLECTED LIGHT SPECTROPHOTOMETRIC READ OUT Z.P. Zag6rski, A. Rafalski . 47 ION BEAM DOSIMETRY. ABSOLUTE METHOD BASED ON ENERGY AND FLUENCE MEASUREMENTS Z. Stuglik 49 ALAN1NE/POLIMER RODS WITH LOW CONCENTRATION OF DL-oc-ALANINE FOR ROUTINE ELECTRON BEAM DOSIMETRY Z. Stuglik, T. Bryl-Sandelewska 50 RE-INVESTIGATION OF PVC FOILS USED FOR ROUTINE ELECTRON BEAM DOSIMETRY IN INCT Z. Stuglik . 51 MICROCRYSTALLINE L-a- AND DL-a-ALANINE IRRADIATED WITH GAMMA RAY AND HEAVY IONS AND ANALYZED BY MEANS OF INSTRUMENTAL METHODS Z. Stuglik, A. Dindune, M. Burzytiska-Szyszko, L. Actida 52 EVALUATION OF ENERGY OF SCANNED ELECTRON BEAM FROM LINEAR ACCELERATOR BY MEANS OF DEPTH-DOSE DISTRIBUTION MEASUREMENT W. Malicki, Z. Stuglik 53 OPTICAL PROPERTIES OF GAMMA IRRADIATED ARTIFICIAL SAPPHIRE AND YTTRIA STABILIZED ZIRCONIA SPECTROSCOPIC WINDOWS L. Fuks, C. Degueldre 54 PRELIMINARY APPLICATION OF MODULATED DIFFERENTIAL SCANNING CALORIMETRY IN STUDIES OF HEAVY ION IRRADIATED POLYESTER FILMS K. CieSla, M. Ribeiro 56 APPLICATION OF WAXS DIFFRACTION IN STUDIES OF CRYSTALLINITY CHANGES IN HEAVY ION IRRADIATED POLYESTER FILMS K. CieSla 57 DIFFERENTIAL SCANNING CALORIMETRY STUDIES OF ANNEALING AND HEAVY ION IRRADIATION INFLUENCE ON MELTING AND CRYSTALLIZATION PROCESSES IN POLYETHYLENE TEREPHTHALATE) K. Cie^la, E. Ferain, R. Legras, W. Starosta 59 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, CHEMISTRY IN GENERAL 61 DETERMINATION OF TRACE ELEMENTS IN ALABASTER BY NEUTRON ACTIVATION ANALYSIS L. Rowiriska, E. Paiiczyk, L. WalH, M. Lig^za, B. Nalepa 63 ANALYSIS OF TRACE ELEMENTS IN LEAD WHITE OF PAINTINGS OF THE SILESIAN SCHOOL FROM THE XVth CENTURY E. Pariczyk, J. Olszewska, L. Rowinska, L. Walis 64 DETERMINATION OF CHEMICAL HOMOGENEITY OF HISTORICAL GLASSWARE. A CASE STUDY J.J. Kunicki-Goldfinger, J. Kierzek, B. Sartowska 67 A CHEMICAL SEPARATION SCHEME FOR 24Na - A DECAY PRODUCT OF THE CLUSTER RADIOACTIVITY OF 233U B. BartoS, A. Bilewicz 70 FRACTIONAT1ON OF YTTERBIUM ISOTOPES IN THE Yb(III)-ACETATE'Yb-AMALGAM SYSTEM. A SEVEN ISOTOPE TRIAL W. Dembiriski, M. Poninski, R. Fiedler 70 HYDRATION AND SOLVATION OF LEAD(II) ACETYLACETONATE AND THE COORDINATION NUMBER OF LEAD(II) J. Narbutt 71 INCREASE OF THE COORDINATION NUMBER OF TRIVALENT p- AND d-BLOCK METAL IONS IN NEUTRAL TROPOLONATES BY ADDUCT FORMATION WITH TRIOCTYLPHOSPHINE OXIDE. THEORETICAL AND THERMODYNAMIC EVIDENCE J. Narbutt, M. Czerwinski, J. Krejzler 73 IMPLICATIONS OF THE NEW THEORY OF ISOTOPE CHEMISTRY OF THE HEAVY ELEMENTS T. Mioduski 77 AQUATION IN SOLID PHASES OF THE Ln2(S04)j-H2O SYSTEMS T. Mioduski 77 INTERLABORATORY COMPARISON OF THE DETERMINATION OF 226Ra AND a8Ra IN SAMPLES SIMULATING COAL MINE WATER J. Narbutt, L. Fuks 79 + 2+ THERMAL CONVERSION OF Li -Mn ACETATE-ASCORBATE GELS TO LiMn2O4 FOR ELECTROCHEMICAL APPLICATIONS A. Deptula, T. Olczak, W. Lada, F. Croce 80 PREPARATION OF CALCIUM PHOSPHATE BIOMATERIALS (POWDERS, MONOLITHS, COATINGS AND FIBERS) 2+ 3 + FROM Ca -PO4 -NHi -OH-ASCORBIC ACID-H2O BY COMPLEX SOL-GEL PROCESS (CSGP) A. Deptuia, W. Lada, T. Olczak, B. Sartowska, R.Z. LeGeros, J.P. LeGeros 84 THE DYNAMICAL PATTERN OF THE 3-AMINO-2-PYRAZINE ACID MOLECULE BY INELASTIC NEUTRON SCATTERING, RAMAN SPECTROSCOPY AND AB INITIO CALCULATIONS A. Pawlukojc, I. Natkaniec, Z. Malarski, J. Leciejewicz 87 NEUTRON DIFFRACTION STUDY OF ANTIFERROMAGNETIC ORDERING IN HoPtSi, ErPtSi AND ErPtGe S. Baran, M. Hofinann, J. Leciejewicz, B. Penc, A. Szytula 88 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS OF HETEROCYCLIC CARBOXYLIC ACIDS. PART XXIII. THE CRYSTAL STRUCTURE OF NICKEL(II) COMPLEX WITH PYRAZINE-2,3-DICARBOXYLIC ACID H. Ptasiewicz-Ba_k, J. Leciejewicz 89 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS OF HETEROCYCLIC CARBOXYLIC ACIDS. PART XXIV. THE CRYSTAL STRUCTURE OF Cu(II) COMPLEX WITH PYRAZINE-2.3-DICARBOXYLIC ACID H. Ptasiewicz-Ba_k, }. Leciejewicz 90 CRYSTAL CHEMISTRY OF COORDINATION COMPOUDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART XXV. THE CRYSTAL STRUCTURE OF CALCIUM(II) COMPLEX WITH 5-METHYLPYRAZINE-2-CARBOXYLIC ACID H. Ptasiewicz-Bak, J. Leciejewicz 91 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART XXVI. THE CRYSTAL STRUCTURE OF MANGANESE(II) COMPLEX WITH FURAN-3-CARBOXYLATE ANIONS B. Paluchowska, J.K. Maurin, J. Leciejewicz 92 SAXS STUDY OF THE INFLUENCE OF SOLVENTS ON THE STRUCTURE OF POLYURETHANE-BASED MEMBRANES H. Grigoriew, A. Wolinska-Grabczyk, A.G. Chmielewski, J. DomagaJa 93 KINETICS OF STRUCTURAL CHANGES IN POLYMER MEMBRANES H. Grigoriew, A.G. Chmielewski, H. Amenitsch, S. Bernstorff, J. Domagala 94 A STUDY ON ANION EXCHANGE THERMODYNAMICS AND THE EFFECT OF COLUMN TEMPERATURE ON THE QUALITY OF CHROMATOGRAPHIC SEPARATIONS IN ISOCRAT1C ION CHROMATOGRAPHY K. Kulisa, R. Dybczynski 95 SORPTION OF HEAVY METALS ON HYDROXYAPATITES J. Chwastowska, E. Sterlinska, M. Sadowska-Bratek 96 EFFECT OF GASEOUS CHLORINE AND HYDROCHLORIDE ON THE As-Pd AND Sb-Pd COMPOUNDS DURING THEIR ATOMISATION IN A GRAPHITE FURNACE L. Pszonicki, J. Dudek 98 DETERMINATION OF SILICON AND PHOSPHORUS BY FLAME AND ELECTROTHERMAL ATOMIC ABSORPTION SPECTROMETRY W. Skwara, L. Pszonicki 99 INVESTIGATION ON POSSIBILITIES OF DETERMINATION OF SOME PRECIOUS METALS IN GEOLOGICAL AND ENVIRONMENTAL SAMPLES BY NEUTRON ACTIVATION ANALYSIS Z. Samczyriski, B. Danko, R. Dybczyriski 100 RADIOBIOLOGY 103 CERAMIDE IS NOT INVOLVED IN NUCLEAR TRANSLOCATION OF NF-KB IN L5178Y SUBLINES B. Sochanowicz, I. Szumiel 105 INDUCTION OF DNA BREAKAGE IN X-IRRADIATED NUCLEOIDS SELECTIVELY STRIPPED OF NUCLEAR PROTEINS IN TWO MOUSE LYMPHOMA CELL LINES DIFFERING IN RADIOSENSITIVITY M. Kruszewski, T, Iwaneriko . 106 CYTOSOLIC LABILE IRON POOL SIZE CORRESPONDS WITH THE SENSITIVITY OF L5178Y SUBLINES TO OXIDATIVE DAMAGE P. Lipinski, H. Retmariska, B. Sochanowicz, M. Kruszewski 107 DIFFERENTIAL INACTIVATION OF DNA-DEPENDENT PROTEIN KINASE IN IRRADIATED REPAIR-COMPETENT AND REPAIR-DEFICIENT L5178Y SUBLINES B. Sochanowicz, M. Kruszewski, I. Szumiel 108 LACK OF ADVERSE EFFECT OF SMOKING HABIT ON DNA STRAND BREAKAGE AND BASE DAMAGE M. Wojew6dzka, M. Kruszewski, T. Iwanenko, A.R. Collins, I. Szumiel 109 POLY(ADP-RIBOSE) METABOLISM IN TWO L5178Y MURINE LYMPHOMA SUBLINES EXPOSED TO X-RAYS H.E. Kleczkowska, I. Szumiel, F.R. Althaus 110 INHIBITION OF POLY(ADP-RIBOSYLATION) SIMILARLY AFFECTS CAMPTOTHECIN-TREATED L5178Y-R AND -S CELLS I. Gradzka, I. Szumiel 111 TELOMERE SIGNALS IN TWO L5178Y MOUSE LYMPHOMA CELL LINES A. Wojcik, E. Bouzyk, I. Szumiel, Ch. Streffer 113 PREFERENTIAL SEGREGATION OF A MARKER CHROMOSOME 14 IN MOUSE RECOMBINANT INBRED STRAINS DERIVED FROM THE KE AND CBA/Kw STRAINS M. Lenartowicz, A. Wojcik 113 SISTER CHROMATID DIFFERENTIATION WITH BIOTIN-dUTP E. Bruckmann, A. Wojcik, G. Obe 114 OXIDATIVE DAMAGE IN DIFFERENTIALLY HYDROGEN PEROXIDE SENSITIVE L5178Y SUBLINES CULTURED IN SELENIUM-SUPPLEMENTED MEDIUM E. Bouzyk 115 NUCLEAR TECHNOLOGIES AND METHODS 117 PROCESS ENGINEERING 119 INTEGRATED CONTROL MONITORING SYSTEM FOR ELECTRON-BEAM INSTALLATION FOR FLUE GAS PURIFICATION FROM SO2 AND NO* AT THE ELECTRIC POWER STATION "POMORZANY" A.G. Chmielewski, E. Iller,