Quality of Surface Waters of the United States 1956

Parts 7 and 8. Lower Mississippi River Basin and Western Gulf of Mexico Basins

Prepared under the direction of S. K. LOVE, Chief, Quality of Water Branch

GEOLOGICAL SURVEY WATER-SUPPLY PAPER 1452

Prepared in cooperation with the States of Arkansas, Louisiana, New Mexico, Oklahoma, and Texas, and with other agencies

UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1960 UNITED STATES DEPARTMENT OF THE INTERIOR

FRED A. SEATON, Secretary

GEOLOGICAL SURVEY

Thomas B. Nolan, Director

For sale by the Superintendent of Documents, U. S. Government Printing Office Washington 25, D. C. - Price $1.50 (paper cover) PREFACE

This report was prepared by the Geological Survey in cooper­ ation with the States of Arkansas, Louisiana, New Mexico, Okla­ homa, and Texas, and with other agencies. The data were collected and computed by personnel of the Water Resources Division under the direction of C. G. Paulsen, chief hydraulic engineer, succeededby L. B. Leopold;S. K. Love, chief, Quality of Water Branch, and supervised by district or regional chemists and engineers: P. C. Benedict ...... Lincoln, Nebr. T. B. Dover ...... Oklahoma City, Okla. J. W. Geurin ...... Fayetteville, Ark. Burdge Irelan ...... Austin, Tex. J. M. Stow ...... Albuquerque, N. Mex. Ill CONTENTS

Page Introduction ...... 1 Collection and examination of samples ...... 3 Chemical quality...... 3 Temperature ...... 4 Sediment...... 4 Expression of results ...... 6 Composition of surface waters ...... 8 Mineral constituents in solution ...... 9 Silica ...... 9 Aluminum...... 9 Manganese...... 9 Iron...... 10 Calcium ...... 10 Magnesium...... 10 Sodium and potassium ...... 11 Carbonate and bicarbonate ...... 11 Sulfate...... 11 Chloride...... 11 Fluoride...... 11 Nitrate ...... 12 Boron ...... 12 Dissolved solids...... 13 Properties and characteristics of water ...... 13 Water temperature ...... 13 Oxygen consumed...... 13 Color...... 13 Hydrogen-ion concentration...... 14 Specific conductance ...... 14 Hardness ...... 14 Total acidity ...... 15 Corrosiveness ...... 15 Percent sodium ...... 15 Sodium-adsorption-ratio ...... 16 Sediment...... 16 Streamflow ...... 17 Publications ...... 17 Cooperation ...... 19 Division of work...... 22 Literature cited...... 22 Chemical analyses, water temperatures, and suspended sediment ...... 24 VI CONTENTS

Chemical analyses, etc. --Continued Page Part 7. Lower Mississippi River basin ...... 24 Mississippi River at St. Louis, Mo. (main stem) ...... 24 St. Francis River basin ...... 28 Miscellaneous analyses of streams in St. Francis River basin in Arkansas ...... 28 White River basin ...... 29 War Eagle Creek near Hindsville, Ark ...... 29 Kings River near Berryville, Ark ...... 30 White River at Bull Shoals Dam, Ark ...... 31 White River at Cotter, Ark ...... 33 Buffalo River near St. Joe, Ark ...... 35 North Fork River at Norfork Dam, near Norfork, Ark. 36 Black River near Corning, Ark ...... 37 Current River near Pocanhontas, Ark ...... 38 Spring River at Imboden, Ark ...... 39 Eleven Point River near Ravenden Springs, Ark ..... 42 Strawberry River near Poughkeepsie, Ark ...... 43 White River at Newport, Ark ...... 44 Little Red River near Heber Springs, Ark ...... 47 Bayou De View near Brasfield, Ark ...... 48 White River at Clarendon, Ark ...... 49 Miscellaneous analyses of strams in White River basin in Arkansas ...... 53 Arkansas River basin...... 54 Arkansas River below John Martin Reservoir, Colo .. 54 Arkansas River at Arkansas City, Kans ...... 57 Chikaskia River near Blackwell, Okla ...... 61 Red Rock Creek near Red Rock, Okla ...... 62 Arkansas River at Ralston, Okla ...... 63 Black Bear Creek at Pawnee, Okla ...... 66 Cimarron River near Kenton, Okla ...... 67 Cimarron River near Mocane, Okla ...... 68 Cottonwood Creek near Guthrie, Okla ...... 70 Cimarron River at Perkins, Okla ...... 71 Arkansas River at Sand Springs Bridge, near Tulsa, Okla ...... 75 Verdigris River near Lenapah, Okla ...... 79 Verdigris River near Inola, Okla ...... 82 Neosho (Grand) River near Langley, Okla ...... 87 Neosho (Grand) River at Fort Gibson Reservoir, near Fort Gibson, Okla ...... 89 Illinois River near Watts, Okla ...... 91 Illinois River at Tenkiller Reservoir near Gore, Okla. 92 Canadian River near Amarillo, Tex ...... 94 Canadian River at Bridgeport, Okla ...... 97 Little River below Hog Creek, near Norman, Okla ... 101 Little River near Sasakwa, Okla ...... 104 CONTENTS VII

Chemical analyses, etc. Continued Part 7. Lower Mississippi River basin--Continued Arkansas River basin--Continued Page North Canadian River near Selling, Okla ...... 108 North Canadian River at Canton Reservoir, near Canton, Okla ...... 109 North Canadian River near El Reno, Okla ...... 110 North Canadian River near Wetumka, Okla ...... 113 Deep Fork near Beggs, Okla ...... 117 Canadian River near Whitefield, Okla ...... 121 Sallisaw Creek near Sallisaw, Okla ...... 125 Fourche Maline near Red Oak, Okla ...... 126 Poteau River at Cauthron, Ark ...... 127 Lee Creek near Van Buren, Ark ...... 128 Arkansas River at Van Buren, Ark ...... 129 Mulberry River near Mulberry, Ark ...... 134 Piney Creek near Dover, Ark ...... 137 Illinois Bayou near Scottsville, Ark ...... 140 Arkansas River at Dardanelle, Ark ...... 143 Cadron Creek near Conway, Ark ...... 148 Arkansas River at Little Rock, Ark ...... 151 Miscellaneous analyses lof streams in Arkansas River basin in Kansas, Oklahoma, and Missouri ...... 155 Miscellaneous analyses of streams in Arkansas River basin in Arkansas ...... 165 Miscellaneous analyses of streams in Arkansas River basin in Texas ...... 166 Red River basin ...... 168 Salt Fork Red River near Hedley, Tex ...... 168 East Cache Creek near Elgin, Okla ...... 170 Little Wichita River near Archer City, Tex ...... 173 Little Wichita River near Henrietta, Tex ...... 174 Beaver Creek near Waurika, Okla ...... 175 Red River near Gainesville, Tex ...... 178 Washita River near Carnegie, Okla ...... 182 Washita River near Pauls Valley, Okla ...... 186 Washita River near Durwood, Okla ...... 187 Red River at Denison Dam, near Denison, Tex ...... 191 North Boggy Creek near Stringtown, Okla ...... 193 Clear Boggy Creek near Caney, Okla ...... 194 Tenmile Creek near Miller, Okla ...... 197 Little River near Horatio, Ark ...... 198 Red River at Fulton, Ark ...... 201 Black Bayou near Gilliam, La ...... 205 Red River at Shreveport, La ...... 206 Bayou Dorcheat near Minden, La ...... 209 Cypress Bayou near Benton, La ...... 210 Loggy Bayou near Minock, La ...... 211 Saline Bayou near Lucky, La ...... 212 VIII CONTENTS

Chemical analyses, etc. Continued Part 7. Lower Mississippi River basin--Continued Red River basin--Continued Page Black Lake Bayou near Castor, La ...... 213 Red River at Alexandria, La ...... 214 Ouachita River at Arkadelphia, Ark ...... 217 Ouachita River near Felsenthal, Ark ...... 221 Cornie Bayou near-Three Creeks, Ark ...... 226 Three Creeks near Three Creeks, Ark ...... 229 Corney Bayou near Lillie, La ...... 232 Ouachita River at Monroe, La ...... 233 Boeuf River near Girard, La ...... 236 Tensas River at Tendal, La ...... 237 Miscellaneous analyses of streams in Red River basin in Arkansas ...... 238 Miscellaneous analyses of streams in Red River basin in Texas ...... 239 Miscellaneous analyses of streams in Red River basin in Oklahoma ...... 241 Miscellaneous analyses of streams in Red River basin in Louisiana . .t ..... t ...... 247 Mississippi River near St. Francisville, La. (main stem)...... 249 Mississippi River Delta ...... 252 Vermilion River at Bancker's Ferry near Abbeville, La ...... 252 Tickfaw River at Holden, La ...... 255 Bayou La Fourche at Raceland, La ...... 256 Old Intracoastal Canal at Lockport, La ...... 257 Old Intracoastal Canal near Bourg, La ...... 258 Old Intracoastal Canal at Gayoso, La ...... 259 Bayou La Fourche at Valentine, La ...... 260 Miscellaneous analyses of streams in Mississippi River Delta in Louisiana ...... 261 Part 8. Western Gulf of Mexico basins ...... 263 Mermentau River basin ...... 263 Mermentau River at Lake Arthur, La ...... 263 Miscellaneous analyses of streams in Mermentau River basin in Louisiana ...... 266 Calcasieu River basin ...... 267 Whiskey Chitto Creek near Oberlin, La ...... 267 Bundick Creek near Dry Creek, La ...... 268 Calcasieu River at Moss Bluff, La ...... 269 Miscellaneous analyses of streams in Calcasieu River basin in Louisiana ...... 272 Sabine River basin ...... 273 Sabine River near Tatum, Tex ...... 273 Bayou San Patricio near Noble, La ...... 276 Sabine River near Ruliff, Tex ...... 277 CONTENTS IX

Chemical analyses, etc. --Continued Part 8. Western Gulf of Mexico basins--Continued Sabine River basin--Continued Page Cow Bayou near Mauriceville, Tex ...... 280 Miscellaneous analyses of streams in Sabine River basin in Louisiana ...... 281 Neches River basin ...... 282 Angelina River near Lufkin, Tex ...... 282 Neches River at Evadale, Tex ...... 285 Trinity River basin...... 288 Clear Fork Trinity River at Fortworth, Tex ...... 288 Trinity River near Rosser, Tex ...... 289 Cedar Creek near Mabank, Tex ...... 292 Richland Creek near Fairfield, Tex ...... 293 Trinity River at Romayor, Tex...... 295 Trinity River near Moss Bluff, Tex ...... 298 Old River near Cove, Tex ...... 300 Trinity River at Anahuac, Tex ...... 302 Trinity Bay near Anahuac, Tex ...... 304 Miscellaneous analyses of streams in Trinity River basin in Texas ...... 307 Brazos River basin...... 308 Hubbard Creek near Breckenridge, Tex ...... 308 Brazos River at Possum Kingdom Dam, near Graford, Tex ...... 311 Brazos River near Whitney, Tex ...... 312 Brazos River at Richmond, Tex ...... 314 Miscellaneous analyses of streams in Brazos River basin in Texas ...... 317 Colorado River basin ...... 318 Colorado River near San Saba, Tex ...... 318 Colorado River at Austin, Tex ...... 324 Waller Creek at 23rd Street, at Austin, Tex ...... 326 Colorado River at Wharton, Tex ...... 327 Miscellaneous analyses of streams in Colorado River basin in Texas ...... 329 Guadalupe River basin ...... 330 Guadalupe River at Victoria, Tex ...... 330 Miscellaneous analyses of streams in Guadalupe River basin in Texas ...... 333 Nueces River basin ...... 334 Nueces River near Mathis, Tex ...... 334 Rio Grande basin ...... 336 Rio Grande above Culebra Creek, near Lobatos, Colo. .336 Rio Grande at Embudo, N. Mex ...... 338 Rio Chama near Abiquiu, N. Mex ...... 342 Rio Chama near Chamita, N. Mex ...... 345 Rio Grande at Otowi Bridge near Sanlldefonso, N. Mex. 349 X CONTENTS

Chemical analyses, etc. --Continued Part 8. Western Gulf of Mexico basins--Continued Rio Grande basin Continued Page Galisteo Creek at Domingo, N. Mex ...... 355 Jemez River below Jemez Canyon Dam, N. Mex .... 358 Rio Grande near Bernalillo, N. Mex ...... 362 Rio Grande near Bernardo, N. Mex ...... 367 Rio Puerco below Cabezon, N. Mex ...... 371 Chico Arroyo near Guadalupe, N. Mex ...... 374 Rio San Jose at Correo, N. Mex ...... 376 Rio Puerco at Rio Puerco, N. Mex ...... 378 Rio Puerco near Bernardo, N. Mex ...... 380 Rio Salado near San Acacia, N. Mex ...... 382 Socorro main canal north at San Acacia, N. Mex ..... 385 Rio Grande at San Acacia, N. Mex ...... 387 Rio Grande conveyance channel below heading near San Marcial, N. Mex ...... 392 Rio Grande conveyance channel at San Marcial, N. Mex ...... 396 Rio Grande floodway at San Marcial, N. Mex ...... 401 Pecos River at Puerto De Luna, N. Mex ...... 402 Pecos River below Alamogordo Dam, N. Mex ...... 407 Pecos River near Acme, N. Mex ...... 409 Rio Hondo at Diamond A Ranch near Roswell, N. Mex 412 Pecos River near Artesia, N. Mex ...... 414 Pecos River seepage investigation ...... 420 Rio Penasco at Dayton, N. Mex ...... 426 Pecos River (Kaiser Channel) near Lakewood, N. Mex. 427 Pecos River at dam site 3, near Carlsbad, N. Mex ... 430 Carlsbad main canal at head near Carlsbad, N. Mex .. 431 Pecos River at Carlsbad, N. Mex ...... 432 Refinery intake canal near Loving, N. Mex ...... 434 Pecos River east of Malaga, N. Mex ...... 435 Pecos River at Pierce Canyon Crossing, near Malaga N. Mex ...... 437 Pecos River near Red Bluff, N. Mex ...... 440 Pecos River below Red Bluff Dam, near Orla, Tex ... 443 Pecos River below Grandfalls, Tex ...... 445 Pecos River near Girvin, Tex ...... 446 Miscellaneous analyses of streams in Rio Grande basin in New Mexico ...... 448 Index ...... 465 CONTENTS XI

ILLUSTRATION

Page Figure 1. Map of the United States showing basins covered by the four water-supply papers on quality of surface waters in 1956 ...... 2 QUALITY OF SURFACE WATERS OF THE UNITED STATES, 1956

PARTS 7 and 8

INTRODUCTION

The quality-of-water investigations of the United States Geo­ logical Survey are concerned with chemical and physical charac­ teristics of the surface and ground water supplies of the Nation. Most of the investigations carried on in cooperation with States and other Federal agencies deal with the amounts of matter in so­ lution and in suspension in streams. The records of chemical analysis, suspended sediment, and temperature for surface waters given in this volume serve as a basis for determining the suitability of the waters examined for industrial, agricultural, and domestic uses insofar as such use is affected by the dissolved or suspended mineral matter in the wa­ ters. The discharge of a stream and, to a lesser extent, the chem­ ical quality are related to variations in rainfall and other forms of precipitation. In general, lower concentrations of dissolved solids may be expected during the periods of high flow than during periods of low flow. The concentration in some streams may change materially with relatively small variations in flow, whereas for other streams the quality may remain relatively uniform through­ out large ranges in discharge. The quantities of suspended sedi­ ment carried by streams are also related to discharge, and during flood periods the sediment concentrations in many streams vary over wide ranges. Publication of annual records of chemical analyses, suspended sediment,and water temperature was begun by the Geological Survey in 1941. The records prior to 1948 were published each year in a single volume for the entire country. Beginning in 1948, the rec­ ords were published in two volumes, and beginning in 1950, in four volumes, covering the drainage basins shown in Figure 1. The samples for which data are given in this volume were collected from October 1, 1955, to September 30, 1956. The records are arranged by drainage basins according to Geological Survey prac­ tice in reporting records of streamflow: Stations on tributary 1 QUALITY OF SURFACE WATERS, 1956

This report Parts 1-4; WSP1450 Parts 5-6; WSP 1451 Parts 9-14;WSP1453

Figure 1. Map of the United States showing basins cov­ ered by the four water-supply papers on quality of surface waters in 1956. The shaded portion represents the section of the country covered by this volume; the unshaded portion represents the section of the country covered by other water- supply papers. streams are listed between stations on the main stem in the order in which those tributaries enter the main stem. Descriptive state­ ments are given for each sampling station for which regular series of chemical analyses, temperature observations, or sediment de­ terminations have been made. These statements include the lo­ cation of the stream-sampling station, drainage area, length of time for which records are available, extremes of mineralization, hardness, water temperature, sediment loads, and other pertinent data. Records of water discharge of the streams at or near the sampling period are included in most tables of analyses. During the year ending September 30,1956, 157 regular samp­ ling stations on 95 streams for the study of the chemical character of surface waters were maintained by the Geological Survey in the area covered by this volume. Samples were collected less fre­ quently during the year at many other points. Water temperatures were measured daily at 82 stations. Not all analyses of samples of surface water collected during the year nave been included. Single analyses of an incomplete nature generally have been omit­ ted. Also, analyses made of the daily samples before composi­ ting have not been reported. The specific conductance of almost all daily samples was determined, and as noted in the table head- COLLECTION AND EXAMINATION OF SAMPLES 3 ings this information is available for reference at the district of­ fices listed under Division of Work, on page 22. Quantities of suspended sediment are reported for 24 stations during the year ending September 30, 1956. The sediment samples were collected one or more times daily at most stations, depending on the rate of flow and changes in stage of the stream. Sediment samples were collected less frequently during the year at many other points. In connection with measurements of sediment dis­ charge, sizes of sediment particles were determined at 21 of the stations. Material which is transported almost in continuous contact with the stream bed and the material that bounces along the bed in short skips or leaps is termed "bed load" and is not considered in this report. All other undissolved fragmental material in transport is termed "suspended sediment" and generally constitutes the major part of the total sediment load. At the present time no reliable routine method has been developed for determining bed load.

COLLECTION AND EXAMINATION OF SAMPLES CHEMICAL QUALITY Samples of chemical analyses were usually collected at or near points on streams where gaging stations are maintained for meas­ urement of water discharge. Two methods of compositing water samples for analysis are used by the Geological Survey: (1) Equal volume method Three composite samples were usually prepared each month by mixing together equal volumes of daily samples col­ lected from the 1st to the 10th, from the llth to the 20th, and from the 21st to the end of the month. Composite samples were pre­ pared for shorter periods if the specific conductance of the daily samples indicated that the mineral content of the water had changed significantly. Conversely, composite samples were occasionally prepared for longer periods if the specific conductance of the daily samples indicated that the mineral content had remained nearly uniform. (2) Discharge method Composite samples were pre­ pared by mixing together a volume from each sample in proportion to the product of the rate of water discharge at the time of sam­ pling and the time interval represented by that sample. Generally, each daily sample is assumed to represent an equal time interval; therefore, the volume from each sample is proportional only to the water discharge at the time of sampling. Compositing samples by the discharge method was limited to some streams west of the Mississippi River. The samples were analyzed according to methods regularly used by the Geological Survey. These methods are essentially the same as, or are modifications of, methods described in recognized au­ thoritative publications for the mineral analysis of water samples (Collins, 1928; Am. Public Health Assoc., 1955). QUALITY OF SURFACE WATERS, 1956

TEMPERATURE

Daily water temperatures were measured at most of the sta­ tions when chemical quality or sediment samples were collected. So far as practicable, the water temperatures were taken at about the same time each day for an individual station in order that the data would be relatively unaffected by diurnal variations in tem­ perature. Most large, swiftly flowing streams probably have a small diurnal variation in water temperature, whereas sluggish or shallow streams may have a daily range of several degrees and may follow closely the changes in air temperature. The thermom­ eters used for determining water temperature were accurate to plus or minus 0.5°F. At stations where thermographs are located, the records con­ sist of maximum and minimum temperatures for each day, and the monthly averages of maximum daily and minimum daily temper­ atures .

SEDIMENT

In general, suspended-sediment samples were collected daily with U. S. depth-integrating cable-suspended samplers (U. S. In- teragency, 1948, p. 70-76 and U. S. Interagency, 1952, p. 86-90) from a fixed sampling point at one vertical in the cross section. The US DH-48 hand sampler was used at many stations during pe­ riods of low flow. Depth-integrated samples were collected peri­ odically at three or more verticals in the cross section to deter­ mine the cross-sectional distribution of the concentration of sus­ pended sediment with respect to that at the daily sampling vertical. In streams where transverse distribution of sediment concentration ranges widely, samples were taken regularly at two or more verti­ cals to determine the average concentration across the section. During periods of high flow, samples were taken two or more times throughout the day at many sampling stations, and during periods of rapidly changing flow samples were taken hourly at some stations. Sediment concentrations were determined by filtration or evap­ oration of the samples as required. At many stations the daily mean concentration for some days was obtained by plotting the in­ stantaneous concentrations on the original or copies of the original gage-height chart. The plotted concentrations, adjusted if neces­ sary for cross-sectional distribution with respect to that at the daily sampling vertical, were connected or averaged by continuous curves COLLECTION AND EXAMINATION OF SAMPLES 5 to obtain a concentration graph. This graph represented the esti­ mated concentration at anytime and, for most periods, daily mean concentrations were determined from the graph. When the con­ centration and water discharge were changing rapidly, the day was often subdivided for this computation. For some periods when the day-to-day variation in the concentration was negligible, the data were not plotted, and the average concentration of the samples was used as the mean concentration for the day. For certain sta­ tions, when the discharge and concentrations were relatively low and varied only slightly from day to day, the samples for a number of days were composited and the mean daily concentrations and mean daily loads are shown. For some periods when no samples were collected, daily loads of suspended sediment were estimated on the basis of water dis­ charge, sediment concentrations observed immediately preceding and following the periods, and suspended-sediment loads for other periods of similar discharge. The estimates were further guided by weather conditions and sediment discharge for other stations. In many instances where there were no observations for sev­ eral days, the suspended-sediment loads for individual days are not estimated, because numerous factors influencing the quantities of transported sediment made it very difficult to make accurate estimates for individual days. However, estimated loads of sus­ pended sediment for missing days in otherwise continuous period of sampling have been included in monthly and annual totals for most streams to provide a complete record. For some streams, samples were collected about weekly, monthly, or less frequently, and only rates of sediment discharge at the time of sampling are shown. In addition to the records of quantities of suspended sediment transported, records of the particle sizes of sediment are included. The particle sizes of the suspended sediments for many of the sta­ tions, and the particle sizes of the bed material for some of the stations were determined periodically. As much of the material carried in suspension is finer than 0.062 mm, the pipet method (Kilmer and Alexander, 1949) or the bottom withdrawal tube method (U. S. Interagency, 1943, R. 82-90) were used in most of the anal­ yses. For most samples, material between 1.0 mm and 0.062 mm was analyzed by the visual accumulation tube method (U. S. Inter- agency 1957). Separation of sand from the silt-clay-colloid frac­ tion was by sieve. For some samples all sediment coarser than 0.062 mm was analyzed by the sieve method. For material finer than 0.062 mm the settling medium used was native water or dis­ tilled water to which a dispersing agent had been added. Because sedimentation diameters of the clay and colloidal fractions are often affected by the chemical character of the settling medium, analyses made with native water may more nearly simulate par­ ticle sizes existing in the stream. Results of analyses with dis-

540653 O -60 -2 6 QUALITY OF SURFACE WATERS, 1956 tilled water containing a dispersing agent approximate ultimate particle sizes of the finer fractions. The concentration of sedi­ ment suspension for analysis was reduced to less than 5,000 parts per million where necessary by means of a sample splitter, in order to stay within limits recommended for the bottom-withdrawal tube or pipet method; therefore, the concentration of sediment for analyses was often different from the concentration in the stream. The concentration at which analyses were made is indicated in the appropriate tables.

EXPRESSION OF RESULTS The dissolved mineral constituents are reported in parts per million. A part per million is a unit weight of a constituent in a million unit weights of water. Equivalents per million are not given in this report although the expression of analyses in equivalents per million is sometimes preferred. An equivalent per million is a unit chemical combining weight of a constituent in a million unit weights of water. Equivalents per million are calculated by di­ viding the concentration in parts per million by the chemical com­ bining weights of the individual constituents. For convenience in making this conversion the reciprocals of chemical combining weights of the most commonly reported constituents (ions) are given in the following table: Constituent Factor Constituent Factor Iron (Fe++)...... 0.0358 Carbonate (CO 3 ~~) ..0.0333 Iron (Fe+++)...... 0537 Bicarbonate (HCO 3 -). . 0164 Calcium (Ca++) ...... 0499 Sulfate (SO4 ~) ...... 0208 Magnesium (Mg++) ... .0822 Chloride (Cl-)...... 0282 Sodium (Na+) ...... 0435 Fluoride (F~) ...... 0526 Potassium (K+) ...... 0256 Nitrate (CO 3 ')...... 0161 Results given in parts per million can be converted to grains per United States gallon by dividingby 17.12. A calculated quan­ tity of sodium and potassium is given in some analyses and is the quantity of sodium needed in addition to the calcium and magne­ sium to balance the acid constituents. The hardness, expressed in terms of an equivalent quantity of calcium carbonate (CaCO 3 ), is calculated from the equivalents of calcium and magnesium, or is determined by direct titration. The hardness caused bycalciumand magnesium (and other ions if sig­ nificant) equivalent to the carbonate and bicarbonate is called car­ bonate hardness; the hardness in excess of this quantity is called noncarbonate hardness. The value usually reported as dissolved solids is the residue EXPRESSION OF RESULTS 7

on evaporation after drying at 180° C for 1 hour. For some waters, particularly those containing moderately large quantities of soluble salts, the value reported is calculated from the quantities of the various determined constituents using the carbonate equivalent of the reported bicarbonate. The calculated sum of the constituents may be given instead of or in addition to the residue. In the anal­ yses of most waters used for irrigation, the quantity of dissolved solids is given in tons per acre-foot as well as in parts per mil­ lion. Percent sodium is computed for those analyses where sodium and potassium are reported separately by dividing the equivalents per million of sodium by the sum of the equivalents per million of calcium, magnesium, sodium, and potassium and multiplying the quotient by 100. In analyses where sodium and potassium were calculated and reported as a combined value, the value reported for percent sodium will include the equivalent quantity of potas­ sium. In most waters of moderate to high concentration the pro­ portion of potassium is much smaller than that of sodium. Specific conductance is given for most analyses and was de­ termined by means of a conductance bridge and using a standard potassium chloride solution as reference. Specific conductance values are expressed in micro mhos per centimeter at 25° C. Spe­ cific conductance in micromhos is 1 million times the reciprocal of specific resistance at 25°C. Specific resistance is the resist­ ance in ohms of a column of water 1 centimeter long and 1 square centimeter in cross section. The discharge of the streams is reported in cubic feet per second (see Streamflow, p. 17 ) and the temperature in degrees Fahrenheit. Color is expressed in units of the platinum-cobalt scale proposed by Hazen (1892, p. 427-428). Hydrogen-ion concentration is expressed in terms of pH units. By definition the pH value of a solution is the negative logarithm of the concentration of gram ions of hydrogen. However, the pH meter that is generally used in Survey laboratories determines the ac­ tivity of the hydrogen ions a§ distinguished from concentration. An average of analyses for the water year is given for most daily sampling stations. Most of these averages are arithmetical or time-weighted; when analyses during a year are all on 10-day composites of daily samples with no missing days, the arithmetical and time-weighted averages are equivalent. A time-weighted av­ erage represents the composition of water that would be contained in a vessel or reservoir that had received equal quantities of water from the river each day for the water year. A discharge-weighted average approximates the composition of water that would be found in a reservoir containing all of the water pass ing a given station dur­ ing the year after thorough mixing in the reservoir. A discharge- weighted average is computed by multiplying the discharge for the samp ling period by the concentrations of the individual constituents for the corresponding period and dividing the sum of the products 8 QUALITY OF SURFACE WATERS, 1956 by the sum of the discharges. Discharge-weighted averages are usually lower than arithmetical averages for most streams be­ cause at times of high discharge the rivers generally have lower concentrations of dissolved solids. The concentration of sediment in parts per million is computed as 1, 000,000 times the ratio of the weight of sediment to the weight of water-sediment mixture. Daily sediment loads are expressed in tons per day and except for subdivided days are usually obtained by multiplying daily mean sediment concentration in parts per million by the daily mean discharge, and the appropriate conversion fac­ tor, normally 0.0027. Particle-size analyses are expressed in percentages of material finer than indicated sizes in millimeters. The size classification used in this report is that recommended by the American Geo­ physical Union subcommittee on Terminology (Lane and others, 1947, p. 937). Other data included as pertinent to the size analy­ ses for many streams are the date of collection, the stream dis­ charge and sediment concentration when sample was collected, the concentration of the suspension during analysis, and the method of analysis.

COMPOSITION OF SURFACE WATERS All natural waters contain dissolved mineral matter. Water in contact with soils or rock, even for only a few hours, will dis­ solve some rock materials. The quantity of dissolved mineral matter in a natural water depends primarily on the type of rocks or soils with which the water has been in contact and the length of time of contact. Some streams are fed by both surface runoff and ground water from springs or seeps. Such streams reflect the chemical character of their concentrated underground sources dur­ ing dry periods and are more dilute during periods of heavy rain­ fall. Ground water is generally more highly mineralized than sur­ face runoff because it remains in contact with the rocks and soils for much longer periods. The concentration of dissolved solids in a river water is frequently increased by drainage from mines or oil fields, by the addition of industrial or municipal wastes, or-- in irrigated regions by drainage from irrigated lands. The mineral constituents and physical properties of natural waters reported in the tables of analyses include those that have a practical bearing on the value of the waters for most purposes. The analyses generally include results for silica, iron, calcium, magnesium, sodium, potassium (or sodium and potassium together as sodium), bicarbonate, sulfate, chloride, fluoride, nitrate, bo­ ron, pH, and dissolved solids. Aluminum, manganese, color, acidity, oxygen consumed, and other dissolved constituents and physical properties are reported for certain streams. Phenolic COMPOSITION OF SURFACE WATERS 9 material and minor elements including strontium, chromium, nick­ el, copper, lead, zinc, cobalt, arsenic, cadmium, and others are occasionally determined for a few streams in connection with speci­ fic problems in local areas and the results are reported when ap­ propriate . The source and significance of the different constituents and properties of natural waters are discussed in the following paragraphs.

MINERAL CONSTITUENTS IN SOLUTION

Silica (SiO2) Silica is dissolved from practically all rocks. Some natural surface waters contain less than 5 parts per million of silica and a few contain more than 50 parts, but most waters contain from 1 to 30 parts per million. Silica affects the usefulness of a water because it contributes to the formation of boiler scale; it usually is removed from feed water for high-pressure boilers. Silica also forms troublesome deposits on the blades of stream turbines.

Aluminum (Al) Aluminum is generally present only in negligible quantities in natural waters except in areas where the waters have been in con­ tact with the more soluble rocks of high aluminum content such as bauxite and certain shales. Acid waters often contain large amounts of aluminum. It maybe troublesome in feed waters where it tends to be deposited as a scale on boiler tubes.

Manganese (Mn) Manganese is dissolved in appreciable quantities from rocks in some sections of the country. Waters impounded in large res­ ervoirs may contain manganese that has been dissolved from the mud on the bottom of the reservoir by action of carbon dioxide produced by anaerobic fermentation of organic matter. Manganese is not regularly determined in areas where it is not present in the waters inappreciable amounts. It is especially objectionable in water used in laundry work and in textile pr bees sing. Concen­ trations as low as 0.2 part per million may cause a dark-brown or black stain on fabrics and porcelain fixtures. Appreciable quan­ tities of manganese are often found in waters containing objection­ able quantities of iron. 10 QUALITY OF SURFACE WATERS, 1956

Iron (Fe)

Iron is dissolved from many rocks and soils. On exposure to the air, normal basic waters that contain more than 1 partper mil­ lion of iron soon become turbid with the insoluble reddish ferric oxide produced by oxidation. Surface waters, therefore, seldom contain as much as 1 part per million of dissolved iron, although some acid waters carry large quantities of iron in solution. Iron causes reddish-brown stains on white porcelain or enameled ware and fixtures and on fabrics washed in the water.

Calcium (Ca) Calcium is dissolved from almost all rocks and soils, but the highest concentrations are usually found in waters that have been in contact with limestone, dolomite, and gypsum. Calcium and magnesium make water hard and are largely responsible for the formation of boiler scale. Most waters associated with granite or silicious sands contain less than 10 parts per million of calcium; waters in areas where rocks are composed of dolomite and lime­ stone contain from 30 to 100 parts per million; and waters that have come in contact with deposits of gypsum may contain several hundred parts per million.

Magnesium (Mg) Magnesium is dissolved from many rocks, particularly from dolomitic rocks. Its effect in water is similar to that of calcium. The magnesium in soft waters may amount to only 1 or 2 parts per million, but water in areas that contain large quantities of dolomite or other magnesium-bear ing rocks may contain from 20 to 100 parts per million or more of magnesium.

Sodium and potassium (Na and K) Sodium and potassium are dissolved from almost all rocks. Sodium is the predominant cation in some of the more highly min­ eralized waters found in the Western United States. Natural waters that contain only 3 or 4 parts per million of the two together are likely to carry almost as much potassium as sodium. As the total quantity of these constituents increases, the proportion of sodium becomes much greater. Moderate quantities of sodium and potas­ sium have little effect on the usefulness of the water for most purposes, but waters that carry more than 50 or 100 parts per million of the two may require careful operation of steam boilers COMPOSITION OF SURFACE WATERS 11 boilers to prevent foaming. More highly mineralized waters that contain a large proportion of sodium salts may be unsatisfactory for irrigation.

Carbonate and bicarbonate (CO3 and HCO3 ) Bicarbonate occurs in waters largely through the action of carbon dioxide, which enables the water to dissolve carbonates of calcium and magnesium. Carbonate as such is not usually pres­ ent in appreciable quantities in natural waters. The bicarbonate in waters that come from relatively insoluble rocks may amount to less than 50 parts per million; many waters from limestone con­ tain from 200 to 400 parts per million. Bicarbonate in moderate concentrations in water has no effect on its value for most uses. Bicarbonate or carbonate is an aid in coagulation for the removal of suspended matter from water.

Sulfate (SO4 ) Sulfate is dissolved from many rocks and soils but in especially large quantities from gypsum and from beds of shale. It is formed also by the oxidation of sulfides of iron and is therefore present in considerable quantities in waters from mines. Sulfate in waters that contain much calcium and magnesium causes the formation of hard scale in steam boilers and may increase the cost of softening the water.

Chloride (Cl) Chloride is dissolved from rock materials in all parts of the country. Surface waters in the humid regions are usually low in chloride content, whereas streams in arid or semiarid regions may contain several hundred parts per million of chloride leached from soils and rocks, especially where the streams receive re­ turn drainage from irrigated lands or are affected by ground-water inflow carrying appreciable quantities of chloride. Large quanti­ ties of chloride may affect the industrial use of water by increasing the corrosiveness of waters that contain large quantities of cal­ cium and magnesium.

Fluoride (F) Fluoride has been reported as being present in some rocks in about the same amount as chloride. However, the quantity of 12 QUALITY OF SURFACE WATERS, 1956 fluoride in natural surface waters is ordinarily very small com­ pared to that of chloride. Recent investigations indicate that the incidence of dental caries is less when there are small amounts of fluoride present in the water supply than when there is none. How­ ever, excess fluoride in water is associated with the dental defect known as mottled enamel if the water is used for drinking by young children during calcification or formation of the teeth (Dean, 1936, p. 1269-1272). This defect becomes increasingly noticeable as the quantity of fluoride in water increases above 1.5 to 2.0 parts per million.

Nitrate (NO 3 ) Nitrate in water is considered a final oxidation product of ni­ trogenous material and may indicate contamination by sewage or other organic matter. The quantities of nitrate present in surface waters are generally less than 5 parts per million (as NO3 ) and have no effect on the value of the water for ordinary uses. It has been reported that as much as 2 parts per million of ni­ trate in boiler water tends to decrease intercrystalline cracking of boiler steel. Studies made in Illinois indicate that nitrates in excess of 70 parts per million (as NO3 ) may contribute to methe- moglobinemia ("blue babies") (Faucett and Miller, 1946, p. 593), and more recent investigations conducted in Ohio show that drink­ ing water containing nitrates in the range of 44 to 88 parts per million or more (as NO3 ) may cause methemoglobinemia (Waring, 1949). In a report published by the National Research Council, Maxcy (1950, p. 271) concludes that a nitrate content in excess of 44 parts per million (as NO 3 ) should be regarded as unsafe for infant feeding.

Boron (B) Boron in small quantities has been found essential for plant growth, but irrigation water containing more than 1 part per mil­ lion of boron is detrimental to citrus and other boron-sensitive crops. Boron is reported in Survey analyses of surface waters in arid and semiarid regions where irrigation is practiced or contem­ plated, but few of the surface waters analyzed have harmful con­ centrations of boron. COMPOSITION OF SURFACE WATERS 13

Dissolved solids

The reported quantity of dissolved solids the residue on evap­ oration--consists mainly of the dissolved mineral constituents in the water. It may also contain some organic matter and water of crystallization. Waters with less than 500 parts per million of dis­ solved solids are usually satisfactory for domestic and some in­ dustrial uses. Water containing several thousand parts per mil­ lion of dissolved solids are sometimes successfully used for irri­ gation where practices permit the removal of soluble salts through the application of large volumes of water on well-drained lands, but generally water containing more than about 2, 000 ppm is con­ sidered to be unsuitable for long-term irrigation under average conditions.

PROPERTIES AND CHARACTERISTICS OF WATER

Water temperature Large quantities of water are used in industrial operation; there­ fore temperature and seasonal fluctuations of that temperature are major considerations in planning the use of water for cooling in industrial plants. Water at high temperature can carry less oxygen in solution than at low temperature. Consequently water temper­ ature can affect or determine the pollution characteristics of a stream. Temperature data are required in studies of water in­ tended for aquatic life. A few degrees rise in temperature may seriously limit the capacity of a stream to support fish life.

Oxygen consumed The amount of oxygen consumed furnishes an approximation of the oxidizable matter in the unfiltered and filtered samples and gives a partial measure of polluting materials such as sewage and oxidizable industrial wastes. Waters of naturally high color may have relatively high values for oxygen consumed, and waters that are not noticeably colored may contain oxidizable material.

Color In water analysis the term "color" refers to the appearance of water that is free from suspended solids. Many turbid waters 14 QUALITY OF SURFACE WATERS, 1956

that appear yellow, red, or brown when viewed in the stream show very little color after the suspended matter has been removed. The yellow-to-brown color of some waters is usually caused by organic matter extracted from leaves, roots, and other organic substances in the ground. In some areas objectionable color in water results from industrial wastes and sewage. Clear deep water may appear blue as the result of a scattering of sunlight by the water molecules. Water for domestic use and some industrial uses should be free from any perceptible color. A color less than 10 units generally passes unnoticed. Some swamp waters have natural color of 200 to 300 units or more.

Hydrogen-ion concentration (pH) The degree of acidity or alkalinity of water, as indicated by the hydrogen-ion concentration, expressed as pH (see p.7 ), is related to the corrosive properties of water and is useful in de­ termining the proper treatment for coagulation that may be neces­ sary at water-treatment plants. A pH of 7.0 indicates that the water is neither acid nor alkaline. pH readings progressively lower than 7.0 denote increasing acidity and those progressively higher than 7.0 denote increasing alkalinity. The pH of most natural sur­ face waters ranges between 6 and 8. Some alkaline surface waters have pH values greater than 8.0, and waters containing free min­ eral acid usually have pH values less than 4.5.

Specific conductance (micromhos per centimeter at 25°C) The specific conductance of a water is a measure of its capac­ ity to conduct a current of electricity (see p.7 ). The conductance varies with the concentration and degree of ionization of the dif­ ferent minerals in solution and with the temperature of the water. When considered in conjunction with results of determinations for other constituents, specific conductance is a useful determination and plays an important part in indicating changes in concentration of the total quantity of dissolved minerals in surface waters.

Hardness Hardness is the characteristic of water that receives the most attention in industrial and domestic use. It is commonly recog­ nized by the increased quantity of soap required to produce lather. The use of hard water is also objectionable because it contributes to the formation of scale in boilers, water heaters, radiators, and COMPOSITION OF SURFACE WATERS 15 pipes, with the resultant decrease in rate of heat transfer, possi­ bility of boiler failure, and loss of flow. Hardness is caused almost entirely by compounds of calcium and magnesium. Other constituents--such as iron, manganese, aluminum, barium, strontium, and free acid also cause hard­ ness, although they usually are not present in quantities large enough to have any appreciable effect. Water that has less than 60 parts per million of hardness is usually rated as soft and suit­ able for many purposes without further softening. Waters with hardness ranging from 61 to 120 parts per million may be con­ sidered moderately hard, but this degree of hardness does not seriously interfere with the use of water for many purposes ex­ cept for use in high-pressure steam boilers and in some industrial processes. Waters with hardness ranging from 121 to 200 parts per million are considered hard, and laundries and industries may profitably soften such supplies. Water with hardness above 200 parts per million generally requires some softening before being used for most purposes.

Acidity The acidity of a natural water represents the content of free carbon dioxide and other uncombined gases, organic acids, min­ eral acids and salts of strong acids and weak bases that hydrolyze to give hydrogen ions. Sulfate of iron and aluminum in mine and industrial wastes are common sources of acidity.

Corrosiveness The corrosiveness of a water is that property which makes the water aggressive to metal surfaces and frequently results in the appearance of the "red-water" caused by solution of iron. The dis­ advantages of iron in water have been discussed previously. Ad­ ditionally, corrosion causes the deterioration of water pipes, steam boilers, and water-heating equipment. Many waters that do not appreciably corrode cold-water lines will aggressively attack hot- water lines. Oxygen, carbon dioxide, free acid, and acid-gener­ ating salts are the principal constituents in water that cause cor­ rosion. In a general way, very soft waters of low mineral content tend to be more corrosive than hard waters containing appreciable quantities of carbonates and bicarbonates of calcium and magne­ sium.

Percent sodium The proportion of sodium to the total cation concentration is termed "percent sodium", and is reported in most of the analyses 16 QUALITY OF SURFACE WATERS, 1956

of waters collected from streams in the western part of the coun­ try where irrigation is practiced extensively. The proportion of sodium to all the constituents in the water is explained on page 10 under "Sodium and potassium*'. Waters in which the percent so­ dium is more than 60 may be injurious when applied to certain types of soils, particularly when adequate drainage is not provided (Magistad and Christiansen, 1944, p. 8-9).

Sodium-adsorption-ratio Of more significance than percent sodium for use as an index of the sodium or alkali hazard to the soil is the sodium-adsorption- ratio because it relates more directly to the adsorption of sodium by the soil. The term, "sodium-adsorption-ratio (SAR)" was in­ troduced by the U. S. Salinity Laboratory Staff (1954), and is a ratio expressing the relative activity of sodium ions in exchange reactions with the soil. It is expressed by the equation:

SAR= Na+ \/ Ca+++Mg+:r' 2 where the concentrations of the ions are expressed in milliequiv- alents per liter (or equivalents per million for most irrigation waters). Waters are divided into four classes with respect to sodium or alkali hazard: low, medium, high, and very high, depending upon the SAR and the specific conductance. At a conductance of lOOmicromhos per centimeter the dividing points are at SAR values of 10, 18, and 26, but at 5,000 micromhos the corresponding di­ viding points are SAR values of approximately 2.5, 6.5, and 11. Waters range in respect to sodium hazard from those which can be used for irrigation on almost all soils to those which are gener­ ally unsatisfactory for irrigation.

SEDIMENT

Fluvial sediment is generally regarded as that sediment which is transported by, suspended in, or deposited by water. Suspended sediment is that part of it which remains in suspension in water owing to the upward components of turbulent currents or by colloi­ dal suspension. Most fluvial sediment results from the normal process of erosion, which in turn is part of the geologic cycle of STREAMFLOW 17

rock transformation. In some instances, this normal process may have been accelerated by agricultural practices. Sediment also results from a number of industrial activities. In certain sections, waste materials from mining, logging, oil-field, and other indus­ trial operations introduce large quantities of suspended as well as dissolved material. The quantity of sediment, transported or available for trans­ portation, is affected by climatic conditions, form or nature of precipitation, plant cover, topography, and land use. An impor­ tant property of fluvial sediment is the tall velocity of the parti­ cles in transport. Particle sizes, as determined by various meth­ ods, represent mechanical diameters, which are related to sedi­ mentation diameters indirectly. Sediment particles in the sand- size (larger than 0.062 mm) range do not appear to be affected by flocculation or dispersion resulting from the mineral constituents in solution. The sedimentation diameter of clay and silt particles in suspension may very considerably from point to point in a stream or reservoir, depending on the mineral matter in solution and in suspension and the degree of turbulence present. The size of sedi­ ment particles in transport at any point depends on the type of ero- dible and soluble material in the drainage area, the degree of floc­ culation present, time in transport, and characteristics of the transporting flow. The flow characteristics include velocity of water, turbulence, and the depth, width, and roughness of the chan­ nel. As a result of these variable characteristics, the size of particles transported, as well as the total sediment load, is in constant adjustment with the characteristics and physical features of the stream and drainage area.

STREAMFLOW

Most of the records of stream discharge, used in conjunction with the chemical analyses and in the computation of sediment loads in this volume, are published in Geological Survey reports on the surface-water supply of the United States. The discharge reported for a composite sample is usually the average of daily mean dis­ charges for the composite period. The discharges reported in the tables of single analyses are either daily mean discharges or dis­ charges for the time at which samples were collected, computed from a stage-discharge relation or from a discharge measure­ ment.

PUBLICATIONS

Reports giving records of chemical quality and temperatures of surface waters and suspended-sediment loads of streams in the 18 QUALITY OF SURFACE WATERS, 1956

area covered by this volume for the water years 1941-56, are listed below: Numbers of water-supply papers containing records for Parts 7-8, 1941-56 Year WSP Year WSP Year WSP Year WSP 1941 942 1945 1030 1949 1163 1953 1292 1942 950 1946 1050 1950 1188 1954 1352 1943 970 1947 1102 1951 1199 1955 1402 1944 1022 1948 1133 1952 1252 1956 1452 Geological Survey reports containing chemical quality, temper­ ature, and sediment data obtained before 1941 are listed below. Publications dealing largely with the quality of ground-water sup­ plies and only incidentally covering the chemical composition of surface waters are not included. Publications that are out of print are preceded by an asterisk.

PROFESSIONAL PAPER *135. Composition of river and lake waters of the United States, 1924.

BULLETINS *479. The geochemical interpretation of water analyses, 1911. 770. The data of geochemistry, 1924.

WATER-SUPPLY PAPERS *108. Quality of water in the Susquehanna River drainage basin, with an introductory chapter on physiographic features, 1904. *161. Quality of water in the upper Ohio River basin and at Erie, Pa., 1906. *193. The quality of surface waters in Minnesota, 1907. *236. The quality of surface waters in the United States, Part 1, Analyses of waters east of the one hundredth meridian, 1909. *237. The quality of the surface waters of California, 1910. *239. The quality of the surface waters of Illinois, 1910. *273. Quality of the water supplies of Kansas, with a prelimi­ nary report on stream pollution by mine waters in south­ eastern Kansas, 1911. COOPERATION 19 *274. Some stream waters of the western United States, with chapters on sediment carried by the Rio Grande and the industrial application of water analyses, 1911. *339. Quality of the surface waters of Washington, 1914. *363. Quality of the surface waters of Oregon, 1914. *418. Mineral springs of Alaska, with a chapter on the chemical character of some surface waters of Alaska, 1917. *596-B. Quality of water of Colorado River in 1925-26, 1928. *596-D. Quality of water of Pecos River in Texas, 1928. *596-E. Quality of the surface waters of New Jersey, 1928. *636-A. Quality of water of the Colorado River in 1926-28, 1930. *636-B. Suspended matter in the Colorado River in 1925-28, 1930. *638-D. Quality of water of the Colorado River in 1928-30, 1932. *839. Quality of water of the Rio Grande basin above Fort Quit- man, Tex., 1938. *889-E. Chemical character of surface water of Georgia, 1944. *998. Suspended sediment in the Colorado River, 1925-41, 1947. 1048. Discharge and sediment loads in the Boise River drainage basin, Idaho, 1939-40, 1948. 1110-C. Quality of water of Conchas Reservoir, New Mexico, 1939--49, 1952. Many of the reports listed are available for consultation in the larger public and institutional libraries. Copies of Geological Survey publications still in print may be purchased at a nominal cost from the Superintendent of Documents, Government Printing Office, Washington 25, D. C., who will, upon request, furnish lists giving prices.

COOPERATION

The table on p. 20 lists State and local agencies that cooper­ ated in quality-of-water investigations in the drainage basins in­ cluded in this volume. The locations of quality-of-water district or regional off Ices responsible for the data collected are also given in this table. Financial assistance was f urnishedby the Bureau of Reclamation of the United States Department of the Interior for some of the in­ vestigations in Oklahoma and New Mexico and by the Corps of En­ gineers, Department of the Arrny, for some investigations in Texas. The Corps also provided financial assistance and made most de­ terminations of sediment concentrations and of particle-size of bed material in connection with the sedimentation investigations of the Mississippi River at St. Louis, Mo. Assistance in collecting data was given by many individuals and by municipal, State, and Federal agencies. to State Cooperating agency Drainage basin District or regional office o

Arkansas Engineering Experiment Station Lower Mississippi River. P. O. Box 32, University of Arkansas, University Station Dean George F. Branigan, 205 Ozark St. director. Fayetteville, Ark. gr Louisiana Louisiana Department of Public Lower Mississippi River, 807 Brazos St. Works, Roy T. Sessums, Western Gulf of Mexico. Austin 14, Tex. director. CO Missouri Corps of Engineers, Department Lower Mississippi River 510 Rudge-Guenzel Bldg. § of Army. (sediment investigations Lincoln, Nebr. at St. Louis). o New Mexico New Mexico Interstate Stream Lower Mississippi River, P. O. Box 4217, Commission, S. E. Reynolds, Western Gulf of Mexico Albuquerque, N. Mex. secretary. CO Pecos River Commission, J. H. Bliss, commissioner for CO New Mexico, J. C. Wilson, en commissioner for Texas. OJ Sherman O. Decker, secretary. State Cooperating agency Drainage basin District or regional office

Oklahoma Oklahoma Water Resources Board, Lower Mississippi River. P.O. Box 4355 Francis J. Borelli, executive Oklahoma City, Okla. director. Texas Texas State Board of Water Engi­ Lower Mississippi River, 807 Brazos St. neers, consisting of R. M. Dixon, Western Gulf of Mexico. Austin, Tex. chairman, H. A. Beckwith, and O. F. Dent; Red Bluff Water o Power Control District, Lower O Colorado River Authority, the O Canadian River Municipal Water Authority, Brazos River Author­ ity, Sabine River Authority, the Lower Neches River Authority, and the West Central Texas g Municipal Water District. The cities of Fort Worth and Wichita Falls; the Chambers- Liberty Counties Navigation District; and the Greenbelt Industrial and Municipal Water Authority. 22 QUALITY OF SURFACE WATERS, 1956 In addition, many of the investigations were supported by funds appropriated directly to the Geological Survey. Studies of suspended- sediment loads in the middle Rio Grande in New Mexico were begun in 1948 as a Federal project.

DIVISION OF WORK

The quality-of-water program was conducted by the Water Re­ sources Division of the Geological Survey, Carl G. Paulsen, chief hydraulic engineer, succeededby L. B. Leopold, and S. K. Love, chief of the Quality of Water Branch. The data were collected and prepared for publication under the supervision of district or re­ gional chemists and engineers as follows: In Missouri--?. C. Benedict; in Oklahoma and in the Arkansas River basin in Kansas T. B. Dover; in Arkansas--J. W. Geurin; in Texas and Louisiana Burdge Irelan; in New Mexico and in the Rio Grande and Arkansas River basins in Colorado--J. M. Stow. Any additional informa­ tion on file can be obtained by writing the responsible Survey dis­ trict office. LITERATURE CITED

American Public Health Association, 1955, Standard methods for the examination of water and sewage, 10th ed., p. 1-217. Collins, W. D., 1928, Notes on practical waters analysis: U. S. Geol. Survey Water-Supply Paper 596-H. Dean, H. T., 1936, Chronic endemic dental fluorosis: Am. Med. Assoc. Jour., v. 107, p. 1269-1272. Faucett, R. L. and Miller, H. C. 1946, Methemoglobinemia oc- curing in infants fed milk diluted with well waters of high nitrate content: Jour. Pediatrics, v. 29, p. 593. Hazen, Alien, 1892, A new color standard for natural waters: Am. Chem. Jour., v. 12, p. 427-428. Kilmer, V. J. and Alexander, L. T., 1949, Methods of making mechanical analyses of soils: SoilSci., v. 68, p. 15-24. Lane, E. W., and others, 1947, Report of the Subcommittee on Terminology: Am. Geophys. Union Trans., v. 28, p, 937. Magistad, O. C., and Christiansen, J. E., 1944, Saline soils,, their nature and management: U. S. Dept. Agriculture Circ. 707, p. 8-9. Maxcy, K. F., 1950, Report on the relation of nitrate concentrations in well waters to the occurrence of methemoglobinemia: Natl. Research Council, Bull. Sanitary engineer, p. 265, app. D. LITERATURE CITED 23 U.S. Interagency Report 6, 1952, A study of methods used in meas­ urements and analysis of sediment Loads in streams, the design of improved types of suspended sediment samplers, p. 86-90, U. S. Engineer Office, St. Paul, Minn. U. S. Interagency Report 7, 1943, A study of methods used in meas­ urement and analysis of sediment loads in streams, a study of new methods for size analysis of suspended sediment samples, p. 82-90; U. S. Engineer Office, St. Paul, Minn. U. S. Interagency Report 8, 1948, A study of methods used in meas­ urement and analysis of sediment loads of streams, meas­ urement of the sediment discharge of streams, p. 70-76; U. S. Engineer Office, St. Paul, Minn. U. S. Interagency Report 11, 1957, A study of methods used in measurement and analysis of sediment loads in streams, the development and calibration of the visual-accumulation tube, p. 1-109. U. S. Salinity Laboratory Staff, 1954, Diagnosis and improvement of saline and alkali soils: U. S. Dept. Agriculture, Agri­ culture Handb. 60, p. 1-160. Waring, F. H., 1949, Significance of nitrates in water supplies: Am. Water Works Assoc. Jour., v. 41, no. 2., p. 147-150. Wilcox, L. V., 1955, Explanation and interpretation of analyses of irrigation waters: U. S. Dept. Agriculture Circ. 969, p. 6. CHEMICAL ANALYSES, WATER TEMPERATURES, AND SUSPENDED SEDIMENT 24 PART 7. LOWER MISSISSIPPI RIVER BASIN MISSISSIPPI RIVER MAIN STEM MISSISSIPPI RIVER AT ST. LOUIS, MO. LOCATION. At McArthur Bridge, 1.1 miles below gaging station, which is 15 miles down­ stream from Missouri River and 180 miles upstream from Ohio River. DRAINAGE AREA. 701,000 square miles, approximately (above gaging station). RECORDS AVAILABLE. Water temperatures: October 1950 to . Sediment records: April 1948 to September 1956. EXTREMES, 1955-56. Water temperatures: Maximum, 85°F Aug. 6; minimum, freezing point Dec. 13. Sediment concentrations: Maximum daily, 1,500 ppm 15; minimum daily, 35 ppm Jan. 23, 25. Sediment loads: Maximum daily, 850,000 tons Oct. 8; minimum daily, 4,250 tons Jan. 25. EXTREMES, 1948-56. Water temperatures (1950-56): Maximum, 89°F Aug. 2, 1955; minimum, freezing point on several days during winter months. Sediment concentrations: Maximum daily, 6,420 ppm June 7, 1951; minimum daily, 35 ppm Jan. 23 25, 1956. Sediment loads: Maximum daily, 7,010,000 tons May 5, 1951; minimum daily, 4,250 tons Jan. 25, 1956. REMARKS. Records of discharge for water year to September 1956 given in WSP 1441. Temperature (°F) of water, water year October 1955 to September 1956 /Once-daily measurement g enerally between 9 a.m. and 2 p.m./ Day Oct. Nov. Dec. Jan. Feb. Mar. Apr. May June July Aug. Sept. 1 68 52 70 82 _ 2 38 ._ 53 83 - 3 .. 46 _ 34 _ _ 56 56 79 4 68 71 __ __ 77 5 48 -- 35 ------79 --

6 67 .. 34 36 48 _ _ 73 80 85 73 7 _ .. _ _ _ 45 71 8 _ 43 _ _ 35 _ _ 75 83 9 _ _ 33 34 _ _ 61 77 81 10 65 - - - 44 47 80 70 11 -- 49 ------46 -- 78 78 " no fji) 12 48 ID 13 13 62 32 _ _ _ _ 78 78 81 73 14 _ .. _ _ 37 _ _. 67 73 15 61 52 65 77 82

16 oiQ1 OUon 17 59 " -- 36 ------81 73 18 42 66 80 71 19 40 Dlfll 80 -_ 71 20 57 -- -- 39 ------81 80 76 21 _ _ _ _ 36 42 _ _. 82 69 22 58 44 _ _ _ _ .. 70 75 - 23 50 69 __ 78 __ __. 24 _ ...... 38 _ 68 .. 76 69 25 55 44 -- " 67 80 "

26 4fiAn 70 27 57 36 -- 42 -- 84 77 28 49 70 80 29 54 _ _ _ 41 _ 82 78 30 _ _. 34 _ _ 48 80 31 53 78 -- MISSISSIPPI RIVER MAIN STEM 25 MISSISSIPPI RIVER MAIN STEM Continued MISSISSIPPI RIVER AT ST. LOUIS, MO. Continued Suspended sediment, water year October 1955 to September 1956 October November December Suspended sediment Suspended sediment Suspended sediment Mean Mean Mean Day dis­ Mean dis­ Mean dis­ Mean concen­ Tons concen­ Tons concen­ Tons charge charge charge tration per tration per tration per (cfs) day (cfs) (cfs) day (ppm) (ppm) day (ppm) 1...... 102, 000 655 180, 000 77,700 240 a 50, 000 49,000 70 a 9, 300 2...... 104, 000 600 a 170, 000 85, 000 210 a 48, 000 49,000 65 8,800 3...... 104, 000 520 a 150, 000 80, 500 198 43,000 53, 500 60 a 8, 700 4...... 94, 400 355 90,500 79, 100 210 a 45, 000 59, 400 60 a 9, 800 5...... 91, 200 420 a 100, 000 78,400 220 46, 600 57, 400 70 a 11, 000 6...... 143,000 440 170, 000 79, 100 220 a 47, 000 52, 200 69 9,720 7...... 199,000 510 a 270, 000 76, 300 220 a 45, 000 49, 000 85 a 11, 000 8...... 225,000 1,400 a 850, 000 74,900 229 46, 300 52, 200 95 a 13, 000 9...... 194, 000 1,200 a 630, 000 75, 600 230 a 47, 000 51, 600 107 14, 900 10...... 171,000 851 393, 000 75, 800 240 a 49, 000 49, 000 110 a 15, 000 11...... 144,000 720 a 280, 000 73, 500 240 47, 800 49, 000 90 a 12, 000 12...... 127, 000 670 a 230, 000 73,500 200 39, 700 50, 900 85 a 12, 000 13...... 112, 000 654 198,000 73,500 190 a 38, 000 52,200 78 10, 700 104,000 630 a 180, 000 72,100 190 a 37, 000 52, 800 75 a 11, 000 15...... 97,600 500 132, 000 89,300 186 31,100 56, 100 70 a 11, 000 16...... 92, 000 430 a 110, 000 70, 700 140 a 27, 000 53, 500 75 a 11, 000 17...... 88,000 398 94,600 63, 900 150 a 26, 000 50, 900 95 a 13, 000 18...... 82, 800 350 a 78, 000 62,600 158 28,700 51, 800 85 a 12, 000 19...... 79, 100 310 a 66, 000 62,000 138 23,100 52, 200 85 a 12, 000 74,900 312 63,100 60,600 120 a 20, 000 52,200 85 a 12, 000 73,500 300 a 60, 000 58,000 110 a 17, 000 50, 900 60 a 8, 200 22...... 72, 100 273 53, 100 58,800 109 18,700 50, 200 55 a 7, 500 23...... 68, 600 250 a 46, 000 58, 000 130 a 20, 000 51, 600 70 a9,800 24...... 70,000 250 a 47 ,000 55,400 120 a 18, 000 57, 400 75 a 12, 000 25...... 67,900 240 44,000 54,200 132 19, 300 58, 700 75 a 12, 000 26...... 66, 500 250 a 45, 000 52,200 94 13,200 56, 100 75 a 11, 000 65, 200 248 43, 700 51,600 75 a 10, 000 57,400 85 13, 200 28...... 72, 100 270 a 53, 000 52,200 75 a 11, 000 57, 400 80 a 12, 000 82, 000 295 65,300 50,900 75 a 10, 000 55, 400 70 a 10, 000 30...... 80, 500 260 a 57, 000 50,200 70 a9,500 55, 400 68 9,870 31...... 82, 000 240 53, 100 54, 800 70 10,000 Total. 3,229,400 -- 5,022,400 2, 003, 400 -- 927,800 1, 649, 000 -- 343, 090 January February March L..... 54,800 65 a 9, 600 54, 200 67 9,800 82, 800 150 a 34, 000 2...... 52, 200 70 a 9, 900 52,800 80 a 8, 600 83, 500 216 48, 700 3...... 54, 200 71 10,400 52, 800 69 9,840 92, 800 200 a 50, 000 4...... 56, 800 75 a 12, 000 52,800 70 a 10, 000 86, 500 170 a 40, 000 5...... 55, 400 82 12, 300 53, 500 80 a 12, 000 88, 000 180 a 38, 000 6...... 54, 800 82 12, 100 55,400 80 12,000 87, 200 148 34, 400 56, 800 75 a 12, 000 56, 100 75 a 11, 000 95, 200 139 35, 700 8...... 56, 100 70 a 11, 000 55, 400 86 9,870 90, 400 160 a 39, 000 9...... 53,500 63 9,100 55, 400 85 a 9, 700 86, 500 170 a 40, 000 10...... 52, 800 55 a 7, 800 55,400 85 a 9, 700 85, 800 177 41,000 11...... 52, 200 55 a 7, 800 56, 800 70 a 11, 000 79, 800 180 a 39, 000 52, 200 48 8,770 58,800 70 all, 000 82, 000 160 a 35, 000 54, 200 53 7,760 58, 100 63 9,540 83, 500 130 a 29, 000 14...... 54, 800 60 a 8, 900 58, 100 64 9,690 81, 000 120 a 26, 000 15...... 53, 500 50 a 7, 200 56, 100 60 a 9, 100 78, 400 130 a 28, 000 52, 200 50 a 7, 000 55,400 85 a 13, 000 79, 100 140 a 30, 000 47, 000 50 a 8, 300 56, 100 75 11,400 77, 700 150 a 31, 000 18...... 44,400 45 a 5, 400 58, 100 85 a9,800 77, 700 140 a 29, 000 45, 700 45 a 5, 800 56, 100 85 a 9, 800 77, 700 122 25, 800 20...... 47,000 40 a 5, 100 56,100 60 9,090 74, 200 110 a 22, 000 49,000 45 a 8, 000 56, 100 59 8,940 88, 600 120 22, 200 22...... 47, 000 40 a 5, 100 57, 400 65 a 10, 000 66, 500 120 a 22, 000 23...... 46, 400 35 a 4, 400 59,400 65 a 10, 000 88, 500 111 19,900 24...... 46, 400 40 a 5, 000 61, 300 78 12,900 74, 200 140 a 28, 000 25...... 45,000 35 4,250 77, 000 150 a 31, 000 77, 700 400 a 84, 000 26...... 44, 400 40 a 4,800 67,900 160 a 29, 000 81, 200 521 114, 000 27...... 45, 000 49 5,950 87,200 149 27, 000 82, 800 470 a 110, 000 28...... 47, 600 60 a7,700 79,800 140 a 30, 000 88, 000 400 95,000 29...... 52, 800 70 a 10,000 85,000 113 25,900 89, 600 420 a 100, 000 30...... 56,800 84 12,900 93, 600 391 98,800 31...... 56.100 120 a 18.000 98.400 380 a 100. 000 Total. 1,587,100 258,130 1,716,800 - 390, 670 2, 557, 100 1,489,300 a Computed from estimated concentration graph and daily turbidity readings. 26 LOWER MISSISSIPPI RIVER BASIN MISSISSIPPI RIVER MAIN STEM--Continued MISSISSIPPI RIVER AT ST. LOUIS, MO.--Continued Suspended sediment, water year October 1955 to September 1956 Continued April May June Suspended sediment Suspended sediment Suspended sediment Mean Mean Mean Day dis­ Mean Mean Mean concen­ Tons dis­ concen­ Tons dis­ concen­ Tons charge charge tration per tration per charge tration per (els) day (cfs) (cfs) day (ppm) (ppm) day (ppm) 1...... 105,000 320 a 91, 000 203, 000 741 406, 000 153, 000 534 221, 000 2...... 109, 000 290 a 85, 000 206, 000 989 550, 000 151, 000 440 a 180, 000 103, 000 293 81,500 184, 000 1,050 522, 000 151, 000 490 a 200, 000 4...... 106, 000 290 a 83, 000 165, 000 741 330, 000 153,000 605 250, 000 5...... 108, 000 360 a 100, 000 157,000 660 a 280, 000 136, 000 630 a 230, 000 6...... 123, 000 340 a 110, 000 151,000 460 a 190, 000 123, 000 504 167, 000 7...... 137, 000 320 a 120, 000 144, 000 306 119, 000 120, 000 470 a 150, 000 8...... 133,000 330 a 120, 000 150,000 330 a 130, 000 114, 000 388 119,000 9...... 139, 000 340 a 130, 000 159,000 401 172, 000 101,000 330 a 90, 000 10...... 153, 000 418 173,000 153, 000 370 a 150, 000 97,600 420 a 110, 000 n...... 151, 000 424 173,000 146, 000 292 115,000 97, 600 470 124, 000 12...... 152,000 500 a 210, 000 146, 000 240 a 95, 000 94, 400 470 a 120, 000 13...... 158,000 453 193, 000 144, 000 250 a 97, 000 96, 800 451 118,000 160, 000 440 a 190, 000 147, 000 351 139, 000 93,600 460 a 120, 000 15...... 160, 000 460 a 200, 000 150, 000 501 203, 000 88, 800 432 104, 000 16...... 162, 000 400 a 170, 000 146, 000 380 a 150, 000 79, 100 390 a83,000 17...... 165, 000 389 173,000 139, 000 330 a 120, 000 79, 100 340 a 7 3, 000 18...... 157, 000 400 a 170, 000 136, 000 292 107, 000 80, 500 400 a87,000 19...... 152, 000 420 a 170, 000 138, 000 300 a 110, 000 88, 000 484 115,000 20...... 158,000 390 a 170, 000 148, 000 310 a 120, 000 102, 000 645 178, 000 21...... 165, 000 360 a 160, 000 154, 000 340 a 140, 000 116,000 419 131,000 22...... 165, 000 360 a 160, 000 143, 000 440 170, 000 120, 000 293 94, 900 169, 000 378 172,000 130, 000 435 153, 000 121, 000 250 a 82, 000 24...... 169, 000 370 a 170, 000 121, 000 702 229, 000 116, 000 280 a 88, 000 25...... 168, 000 380 a 170, 000 116,000 642 201, 000 123, 000 370 a 120, 000 26...... 169, 000 374 171,000 118, 000 550 a 180, 000 125,000 370 a 120, 000 165, 000 419 187,000 116, 000 360 a 110, 000 131, 000 420 a 150, 000 160, 000 350 a 150, 000 115, 000 293 91, 000 125, 000 566 191, 000 29...... 166, 000 330 a 150, 000 116,000 250 a 78, 000 113, 000 309 94, 300 30...... 194, 000 427 224, 000 128, 000 290 a 100, 000 111,000 290 a 87, 000 31...... 139,000 550 a 210, 000 Total. 4,481,000 -- 4,626, 500 4, 508, 000 -- 5,767, 000 3, 400, 500 3, 997, 200 July August September L..... 113,000 270 82, 000 77, 700 343 72, 000 98,400 360 a 96, 000 2...... 108, 000 243 70, 900 87, 200 330 a 78, 000 99, 200 300 a 80, 000 3...... 111,000 270 a 81, 000 107, 000 374 108, 000 97,600 290 a 76, 000 4...... 131,000 270 a 95, 000 117,000 500 a 160, 000 100,000 249 67,200 5...... 162, 000 630 276,000 116,000 600 a 190, 000 76, 300 250 a 52, 000 168,000 786 357,000 108, 000 519 151, 000 78,400 227 48, 100 164, 000 820 a 3 60, 000 124, 000 930 a 310, 000 77,700 221 46, 400 8...... 159, 000 1,100 a 470, 000 130,000 843 296, 000 77, 700 220 a46,000 154, 000 1,020 424, 000 138, 000 588 219, 000 76, 300 210 a43,000 10...... 151, 000 780 a 320, 000 143, 000 542 209, 000 73, 500 216 42, 900 145, 000 1,260 493, 000 132, 000 630 a 220, 000 73, 500 250 a 50, 000 126, 000 1,390 473, 000 128,000 670 a 230, 000 77, 000 238 49, 500 112,000 1,070 324,000 122,000 626 206, 000 83, 500 267 60, 200 14...... 102, 000 1,400 a 390, 000 118,000 480 alSO, 000 77,000 469 97,500 15...... 105, 000 1,500 a 430, 000 132,000 345 123, 000 72,800 800 a 160, 000 108, 000 915 267,000 132, 000 341 122, 000 71,400 710 a 140, 000 111, 000 920 a 280, 000 124,000 388 130,000 70, 000 493 93, 200 124, 000 1,140 382, 000 116,000 470 a 150, 000 69, 300 319 59, 700 131,000 1,080 382, 000 114,000 470 a 140, 000 70, 000 269 50, 800 20...... 125, 000 1,020 344, 000 102, 000 371 102, 000 71,400 220 a 42, 000 91 111,000 1,000 a 300, 000 97, 600 290 a 76, 000 70,000 198 37,400 106, 000 1,000 a 290, 000 103, 000 256 71, 200 67, 900 180 a 33, 000 no 106, 000 826 236, 000 101, 000 230 a 63, 000 67,900 200 a 37, 000 24...... 116,000 770 a 240, 000 92,800 226 56, 600 65, 200 197 34, 700 25...... 112,000 665 201,000 85, 800 230 a 53, 000 62, 000 210 a 35, 000 26...... 103, 000 680 a 19 0,000 86, 500 290 a 68, 000 61, 300 219 36, 200 27...... 94, 400 618 158,000 90, 400 645 157, 000 60, 000 210 a 34, 000 28...... 85, 000 700 a 160, 000 82, 800 720 a 160, 000 60, 000 192 31,100 29...... 85, 000 640 a 150, 000 77, 700 681 143, 000 60, 000 210 a 34, 000 30...... 87,200 473 111,000 75, 600 650 a 130, 000 59,400 230 a 37, 000 31...... 85, 000 410 a 94. 000 80. 500 439 95. 400 Total . 3, 700, 600 8,430,900 3, 341, 600 4, 439, 200 2, 224, 700 - 1,749,900 Total discharge for year (cfs- 4,399,000 Total load for year (tons) .... T. 7,422,090 a Computed from estimated concentration graph and daily turbidity readings. MISSISSIPPI RIVER MAIN STEM 27

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o & t+ IH ^5* h liliii iiifi* p tn ^ ^ § t? ^ 28 LOWER MISSISSIPPI RIVER BASIN ST. FRANCIS RIVER BASIN MISCELLANEOUS ANALYSES OF STREAMS IN ST. FRANCIS RIVER BASIN IN ARKANSAS

Hardness Specific Bicar­ asCaCO, conduct­ Discharge Carbonate Sulfate Chloride Nitrate ance PH Date of collection (cfs) bonate (C03) (S04) (CD (NO,) tWCTl \ Calcium, Non- (micro - mag­ carbon­ mhos at nesium ate 25°C) ST. FRANCIS RIVER AT ST. FRANCIS

NOT. 23, 1955...... 965 116 2 21 2.8 1.1 132 34 170 8.3 June 19, ,1956 ...... 626 220 7 22 10 .5 203 11 394 8.6 June 28 ...... 1,080 86 0 14 3.5 1.8 82 11 165 7.8

ST. FRANCIS RIVER AT LAKE CITY

Nov. 23, 1956 ...... 315 134 5 4.0 4.2 1.6 131 13 198 8.4 June 27, 1956 ...... 1,280 134 4 4.0 4.0 1.3 125 9 246 8.5

RIGHT HAND CHUTE OF LITTLE RIVER AT RIVERVALE

350 207 14 20 12 0.4 234 41 335 8.6 , 1956...... 1,070 190 14 12 14 .9 194 15 388 8.8

ST. FRANCIS RIVER FLOODWAY NEAR MARKED TREE

Nov. 8, 1955 ...... 301 228 10 17 12 0.8 244 34 399 8.5 June 19, 1956 ...... 856 138 6 12 2.5 2.1 125 2 243 8.6

ST. FRANCIS RIVER AT MARKED TREE

Nov. 8, 1955...... 107 166 0 16 6.0 0.4 162 26 310 8.2

ST. FRANCIS BAY NEAR RIVERFRONT

Nov. 22, 1955 ...... 682 188 10 22 8.0 0.3 196 25 295 8.5 June 26, 1956 ...... 1,270 177 0 13 2.5 1.0 158 13 299 8.0 ST. FRANCIS RIVER AT PARKIN

Nov. 22, 1955...... 333 187 5 22 4.5 0.8 187 25 285 8.4 Tune 26, 1956 ...... 1,860 218 6 18 10 .9 202 13 392 8.4 WHITE RIVER BASIN WAR EAGLE CREEK NEAR HINDSVILLE, ARK. LOCATION. At gaging station at bridge on State Highway 45, 4 miles downstream from Poyner Hollow Creek, and 4 miles north of Hindsville, Madison County. DRAINAGE AREA. 262 square miles. RECORDS AVAILABLE.--Chemical analyses: to September 1956. REMARKS. Records of discharge for water year October 1955 to September 1956 given in WSP 1441.

Chemical analyses, in parts per million, water year October 1955 to September 1956 Dissolved Hardness Specific Cal­ Mag­ Potas­ Bicar­ solids as CaCO, conduct­ Silica Iron Sodium Sulfate Chloride Fluor ide Nitrate Date of collection Discharge cium (residue ance (Si02) (Fe) nesium (Na) sium bonate (S04) (Cl) (F) (N03) Calcium, Non- (micro- pH Color (cfs) (Ca) (Mg) (K) (HCO,) on evap­ oration mag­ carbon­ mhos at at 180°C) nesium ate 25°C) 52 32 0.9 1.3 92 3.0 3.0 2.8 110 84 8 173 7.4 22 7.8 40 1.8 2.1 122 1.8 4.0 .9 116 107 7 216 7.3 5 11 44 1.3 2.4 133 5.2 4.0 1.3 134 115 6 236 7.2 5 9.1 45 .8 2.6 138 4.6 4.0 1.5 136 116 2 235 8.2 5 8.4 45 3.8 2.9 140 3.8 4.7 1.1 129 128 14 236 7.2 11 43 3.0 1.4 136 4.4 3.4 1.2 128 120 8 234 7.2

215 18 1.2 2.0 48 7.0 2.6 3.7 77 50 10 110 6.7 Mar . 8 ...... 141 24 1.7 2.1 a74 6.0 3.0 2.2 98 67 6 144 8.3 10 474 14 1.3 2.6 47 5.4 2.2 .8 82 40 2 96.0 7.7 Jfay 4 ...... 444 16 2.6 1.5 51 8.2 2.0 1.5 72 51 9 106 7.5 15 120 20 3.6 1.8 66 4.0 4.5 2.2 90 65 11 140 7.4 15 21 29 2.9 2.0 102 4.0 2.0 .7 104 84 1 176 8.0 5 Sept. 5 ...... 5.0 40 1.4 2.8 123 1.0 4.0 2.0 119 106 5 210 7.6 5 a Includes equivalent of 2 parts per million of carbonate (CO,). LOWER MISSISSIPPI RIVER BASIN

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ofDatecollect S : : :| : : 1 : : : : : WHITE RIVER BASIN Continued WHITE RIVER AT BULL SHOALS DAM, ARK. LOCATION. At dam on White River, 6.3 miles northeast of Flippin, 12| miles downstream from Little North Fork, and at mile 418.6. DRAINAGE AREA.--6,036 square miles. RECORDS AVAILABLE.--Chemical analyses: to September 1956. Water temperatures: to September 1956. REMARKS. Records of specific conductance of daily samples available in district office at Fayetteville, Ark. No discharge records available for this station. Chemical analyses, In parts per million, water year October 1955 to September 1956 Dissolved Hard) less Specific Mean Cal­ Mag­ solids asCaCO, conduct­ discharge (residue ance Date of collection (SiOs) (Fe) cium nesium (Na) slum bonate (S04) (Cl) (F) (NOS) Calcium, Non- (micro- PH Color (cfs) (Ca) (Mg) (K) (HCOJ on evap­ oration mag­ carbon­ mhos at at 180°C) nesium ate 25°C) Oct. 3-7,10-14,17-18, 20-21,24-28,31, 1955. 36 11 2.4 146 9.4 3.0 4.3 155 135 15 256 7.9 15 Nov. 1-4,7-10,14-18, 1 °^ 8 9 Dec. 1-2,5-9,12-16, 19-23, 27-30 ...... 2.5 Jan. 3-6,9-13,16-18,20, 254 Feb. 1-3,6-9,13-17, 20-21,23-24, 27-29... 35 11 2.1 149 8.0 3.5 1.6 159 133 10 253 8.1 5 Mar. 1-2,5-9,12-16, 2 0 Apr. 2-6,9-13, 16-20, May 1-4,7-11,14-15,17- 18,21-24,27-28, 31... 38 10 2.8 156 8.0 2.5 3.3 143 136 8 267 8.1 7 June 1,4-8,11-15,18-22, 25-30 ...... 9.3 156 7.0 2.5 3.0 152 138 10 266 8.0 7 -3,5-6,9-13, 16- 20, 23-27, 30-31 ..... 40 10 2.6 162 8.0 3.0 3.0 160 141 8 274 7.9 7 Aug. 1-3,6-10,13-16, 2.9 146 5 Sept. 4-6, 10-14, 17-21, 24-28 ...... 40 11 2.7 b!70 5.6 3.0 3.0 164 145 6 285 8.3 5 a Includes equivalent of 7 parts per million of carbonate (CO,), b Includes equivalent of 2 parts per million of carbonate (CO,). 32 LOVER MISSISSIPPI RIVER BASIN WHITE RIVER BASIN Continued WHITE RIVER AT BULL SHOALS DAM, ARK.--Continued Temperature (°F) of water, water year October 1955 to September 1956 Day Oct. Nov. Dec. Jan. Feb. Mar. Apr. May June July Aug. Sept. 1 _ 49 49 _ 49 49 _ 50 51 .. 47 .. 2 49 49 _ 49 49 49 50 _ 46 49 3 47 49 49 49 _ 49 50 45 48 4 47 49 .. 49 _ _ 49 50 51 _ 48 5 47 49 49 49 49 - 51 45 48 6 47 _ 49 49 49 49 49 _ 51 45 47 48 7 47 49 49 49 49 50 51 47 8 49 49 49 49 _ 50 51 47 9 49 49 49 49 49 50 50 _ 50 47 10 50 49 49 -- -- 50 50 45 50 48 11 50 .. _ 49 _ _ 50 50 51 45 _ 48 12 48 49 49 49 50 51 49 48 13 48 49 49 49 49 50 _ 51 50 49 48 14 48 49 49 49 49 50 51 -. 48 48 15 49 49 49 49 50 51 - 50 16 .. 50 49 49 49 49 50 _ 46 50 .. 17 48 51 _ 49 49 _ 50 50 47 48 18 49 51 49 _ _ 50 50 51 46 .. 48 19 _ 49 _ _ 50 50 _ 51 47 48 20 49 50 49 49 49 50 51 46 47 48 21 49 50 50 .. 49 49 _ 51 46 .. 47 48 22 50 50 49 51 46 48 23 50 49 49 49 45 50 51 46 48 24 48 49 49 50 51 46 48 25 49 49 ~ 50 51 46 46 48 26 49 _ _ 49 49 50 _ 46 47 ._ 48 27 49 _ 49 49 49 50 50 51 45 47 48 48 28 49 49 49 _ 49 50 _ 51 46 48 48 29 49 49 49 49 46 48 -- 30 _. 49 49 50 _ 49 50 ._ 47 48 -- Q1 u 1. 49 51 47 49 __ Aver­ age WHITE RIVER BASIN Continued WHITE RIVER AT COTTER, ARK. LOCATION. At bridge on U. S. Highway 62 at Cotter, Baxter County, about 5 miles downstream from gaging station near Flippin. DRAINAGE AREA. 6,067 square miles (above gaging station). RECORDS AVAILABLE.--Chemical analyses: October 1947 to September 1956. Water temperatures: October 1947 to Hay 1955, to September 1956. EXTREMES, 1955-56. Dissolved solids: Maximum, 221 ppm Jan. 23; minimum, 146 ppm Jan. 1-9, 11-22, 24-29, 31. Hardness: Maximum, 158 ppm Aug. 14; minimum, 126 ppm Jan. 10. Specific conductance: Maximum daily, 375 micromhos Jan. 23; minimum daily, 225-micromhos Aug. 19. Water temperatures: Maximum, 72°F Aug. 13; minimum, 41°F Jan. 24, Feb. 2. EXTREMES, 1951-56. Dissolved solids: Maximum, 344 ppm Feb. 3, 7, 1954; minimum, 140 ppm May 13-17, 19-21, 23, 25-29, 31, 1955. Hardness: Maximum, 191 ppm Feb. 11-29, Mar. 11-19, 1952; minimum, 118 ppm May 13-17, 19-21, 23, 25-29, 31, 1955. Specific conductance: Maximum daily, 695 micromhos Nov. 23, 1954; minimum daily, 180 micromhos May 28, 1955. Water temperatures (1951-54, 1955-56): Maximum, 79°F Sept. 20, 1954; minimum, 35°F Feb. 11, 1955. REMARKS. Records of specific conductance of daily samples available in district office at Fayetteville, Ark. Records of discharge for gaging station near Flippin for water year October 1955 to September 1956 given in WSP 1441. Flow regulated by Bull Shoals Reservoir since , 1951.

Chemical analyses, In parts per mllllou, December 1955 to September 1956 Dissolved Hardness Specific Cal­ Mag­ Bicar­ Car­ solids asCaCO, conduct­ Mean Silica Iron Sodium Sulfate Chloride Fluor ide Nitrate Date of collection! discharge cium nesium bonate (residue ance (SiOJ (Fe) (Na) bonate (SO,) (Cl) (F) (NO,) on evap­ Calcium, Non- (micro- PH Color (cfs) (Ca) (Mg) (HCO.) (CO,) oration mag­ carbon­ mhos at at 180°C) nesium ate 25°C) Dec. 7-12,14-15, 19, 24-26,28-31, 1955 .. 2,709 36 12 3.0 155 0 5.6 4.0 3.5 157 139 12 264 8.2 7 Jan. 1-9,11-22,24-29, 2,781 36 12 3.2 155 0 8.8 4.0 3.0 146 139 12 263 7.8 7 3,830 131 0 6.0 4.2 2.4 a 21 5 126 19 365 8.0 2,500 153 0 5.0 36 2.6 a 221 153 28 375 8.1 Jan. 30...... 2,460 152 3 7.0 18 2.0 a 187 157 27 318 8.4 Feb. 1-29...... 2,731 32 17 1.1 169 0 5.8 4.7 2.0 152 148 10 280 7.8 3,280 120 7 5.0 3.5 19 a 166 144 34 282 8.6 Mar. 2-10 ...... 3,037 37 12 1.8 155 2 7.4 2.8 2.1 166 142 11 265 8.3 5 Mar. 11-20 ...... 3,121 37 11 1.8. 157 0 3.2 3.2 1.5 162 138 9 263 8.2 5 Mar. 21-25, 27-31.... 3,139 39 11 2.3 160 0 7.4 4.0 1.6 161 143 11 270 8.1 5 2,810 142 8 4.0 10 3.3 a 172 149 19 292 8.6 Apr. 1-30...... 3,182 35 13 5.1 158 0 7.2 8.0 1.6 166 141 11 279 7.2 5

May 1-31 ...... 3,386 36 12 2.9 162 0 7.2 4.0 1.4 156 139 6 266 7.6 5 4,009 37 12 3.8 152 5 8.0 4.0 1.7 161 142 9 266 8.7 5 -31 ...... 4,814 38 11 2.9 163 0 6.8 3.5 3.0 156 140 6 269 8.0 5 Aug. 1-13, 15-31 ..... 3,538 39 11 3.1 162 0 7.2 4.5 3.6 160 143 10 276 7.7 7 Aug. 14 ...... 4,600 174 0 7.0 24 1.0 a 195 158 15 331 8.1 Sept. 1-30 ...... 4,083 38 11 2.8 162 0 7.0 4.0 3.1 160 140 7 271 7.9 7 b3,470 37 12 2.8 155 1 6.4 8.1 3.2 170 142 14 289 -- -- a Estimated from specific conductance. b Mean discharge for water year October 1955 to September 1956 was 3, 317 cfs. 34 LOWER MISSISSIPPI RIVER BASIN WHITE RIVER BASIN Continued WHITE RIVER AT COTTER, ARK. Continued Temperature (°F) of water, December 1955 to September 1956 Day Oct. Nov. Dec. Jan. Feb. Mar. Apr. May June July Aug. Sept. 1 _ _ 42 50 56 54 61 67 64 67 2 41 53 58 58 62 65 65 67 3 -. 43 53 59 60 56 61 67 67 4 43 55 58 66 64 65 67 66 5 44 59 57 64 63 65 68 65 6 .. 46 62 60 64 56 70 67 7 49 .. 48 43 52 61 62 67 71 64 8 48 .. 46 50 58 58 63 67 70 63 9 45 -. 44 53 49 62 62 66 70 63 10 48 52 43 56 48 62 64 61 63 63 11 48 48 44 47 55 64 62 63 67 67 12 46 47 43 59 67 _ 63 69 66 13 50 45 59 62 65 72 65 14 48 46 52 45 62 53 _ 63 67 64 15 45 46 46 48 52 56 68 66 69 70 16 42 49 48 55 59 64 63 68 67 17 43 47 54 57 64 68 62 71 65 18 42 45 52 57 71 61 69 66 19 44 43 46 47 59 66 69 61 70 67 20 46 50 48 57 65 64 63 65 65 21 46 50 46 61 71 65 63 62 66 22 45 49 49 60 63 62 61 66 68 23 _. 42 49 53 54 65 63 60 69 63 24 48 41 58 54 57 56 70 63 67 65 25 46 43 52 55 59 53 61 64 66 65 26 45 44 50 57 59 59 63 64 69 65 27 .. 43 54 59 63 64 63 64 71 65 28 46 56 49 55 62 68 63 64 69 65 29 50 46 54 53 61 67 63 65 67 66 30 46 45 54 55 66 64 65 68 65 31 43 44 50 62 -- 63 65 -- Aver­ -- -- age 48 51 57 62 64 64 68 66 WHITE RIVER BASIN Continued BUFFALO RIVER NEAR ST. JOE, ARK. LOCATION. At gaging station at bridge on U. S. Highway 65, 1J miles downstream from Mill Creek, 4 miles upstream from Bear Creek, and 4i miles southeast of St. Joe, Searcy County. DRAINAGE AREA. 825 square miles. RECORDS AVAILABLE. Chemical analyses: October 1953 to September 1956. REMARKS. Records of discharge for water year October 1955 to September 1956 given in WSP 1441. Chemical analyses. In parts per million, water year October 1955 to September 1956 Dissolved Hardness Specific Cal­ Mag­ Potas­ Bicar- solids as CaCO, conduct­ Discharge Silica Iron Sodium Sulfate Chloride Fluor ide Nitrate cium nesium (residue ance Date of collection (cfs) (SiO2) (Fe) (Na) sium bonate (SO.) (Cl) (F) (NO,) Calcium, Non- (micro- PH Color (Ca) (Mg) (K) (HCOS) on evap­ oration mag­ carbon­ mhos at at 180°C) nesium ate 25°C) Oct. 7, 1955 ...... 138 43 3.5 1.4 a 145 3.6 2.2 0.7 141 122 3 237 8.3 7 66 45 3.6 2.2 147 6.0 2.5 .4 142 127 7 248 7.9 5 Nov. 28 ...... 129 47 3.1 2.2 151 7.0 3.0 .5 142 130 6 254 7.9 5 2,280 24 2.4 1.1 74 5.4 1.0 1.1 77 70 10 138 7.3 Mar. 12 ...... 349 35 2.5 1.9 al!2 5.8 2.2 .6 116 98 6 188 8.3 5 272 36 1.2 2.0 0.7 106 8.8 2.5 .0 106 95 8 186 8.1 5 776 28 2.6 2.0 .7 92 7.8 3.0 .0 92 81 5 161 8.2 5 233 37 2.7 2.1 124 6.2 1.5 .2 120 103 2 208 8.0 5 36 38 3.6 2.1 130 5.4 2.5 .7 123 110 3 215 7.7 5 Sept. 24 ...... 14 42 3.7 2.3 142 5.6 2.5 .8 133 120 4 233 8.0 5 a Includes equivalent of 2 parts per million of carbonate (CO3). WHITE RIVER BASIN Continued NORTH FORK RIVER AT NORFORK DAM, NEAR NORFORK, ARK. LOCATION. At Norfork Dam, 4.3 miles northeast of Norfork, Baxter County. DRAINAGE AREA. 1,806 square miles. RECORDS AVAILABLE. Chemical analyses: October 1946 to September 1956. REMARKS. Records of discharge for water year October 1955 to September 1956 given in WSP 1441. Chemical analyses, In parts per million, to September 1956 Dissolved Hardness Specific Cal­ Mag­ Potas­ Bicar­ solids as CaCO, conduct­ Discharge Silica Iron Sodium Sulfate Chloride Fluor ide Nitrate Date of collection cium nesium sium bonate (residue ance (cfs) (SiOa) (Fe) (Na) (S04) (Cl) (F) (NO,) on evap­ Calcium, Non- PH Color (Ca) (Mg) (K) (HCO,) mag­ carbon­ (micro - oration mhos at at 180°C) nesium ate 25°C) 1,280 38 22 2.0 a 216 6.2 2.8 4.1 190 185 8 342 8.4 5 Nov. 10...... 1,170 2.2 0.00 37 23 1.7 1.8 216 6.8 2.5 0.0 1.6 189 187 10 339 7.6 5 1,990 37 21 2.4 b205 6.8 3.2 2.7 180 179 11 327 8.3 5 Dec. 16...... 1,210 2.8 .00 37 23 1.6 1.4 209 10 2.5 .0 .5 186 187 16 336 7.6 7 1,390 2.8 .00 34 21 1.5 1.7 202 5.6 2.2 .0 1.0 174 171 6 316 7.8 7 Jau. 30, 1956 ...... 1,280 .5 .00 34 22 1.4 1.5 206 6.4 2.0 .1 1.1 175 175 6 329 7.5 5 Feb. 14...... 1,980 .5 .00 34 22 1.9 2.0 204 6.0 3.0 .1 1.3 175 175 8 330 7.4 5 Jfar. 13...... 1,470 35 23 1.6 C214 4.2 2.5 1.1 179 182 6 315 8.7 5 Jfar. 26...... 2,140 .9 .00 34 22 1.5 1.9 206 6.6 2.0 .2 1.7 178 175 6 334 7.6 5 1,980 37 21 2.1 d206 3.8 2.5 1.3 183 179 10 308 8.6 7 1,230 .9 .00 35 22 1.4 l.S 202 5.8 2.5 .1 1.4 180 178 12 328 7.5 5 63 1.9 .00 36 21 2.0 2.6 206 5.0 2.5 .1 2.1 174 176 7 323 7.7 5 220 1.7 .05 37 21 2.1 2.8 205 4.8 4.0 .1 1.6 174 179 11 326 7.8 5 142 1.0 .05 35 22 1.6 2.3 207 3.8 2.5 .1 1.5 173 178 8 323 8.0 5 Sept. 10...... 90S 3.2 .00 36 21 1.1 1.0 208 6.2 2.5 .0 1.8 172 176 6 325 7.6 5 a Includes equivalent of 4 parts per million of carbonate (CO$). b Includes equivalent of 2 parts per million of carbonate (CO$). c Includes equivalent of 7 parts per million of carbonate (CO$). d Includes equivalent of 12 parts per million of carbonate (CO,). WHITE RIVER BASIN Continued BLACK RIVER NEAR CORNING, ARK. LOCATION. At gaging station at bridge on U. S. Highway 62, 24 miles east of Corning, Clay County, 13.9 miles downstream from Cane Creek, and at mile 152.2. DRAINAGE AREA. 1,749 square miles. RECORDS AVAILABLE. Chemical analyses: October 1954 to September 1956. REMARKS. Records of discharge for water year October 1955 to September 1956 given in WSP 1441.

Chemical analyses, in parts per million, water year October 1955 to September 1956 Dissolved Hardness Specific Cal­ Mag­ Potas­ Bicar­ solids as CaCO, conduct­ Discharge Silica Iron Sodium Sulfate Chloride Fluoride Nitrate Date of collection cium nesium sium bonate (residue ance pH (cfs) (Si02) (Fe) (Na) (SO,) (Cl) (F) (NO,) on evap­ Calcium, Non- (micro- Color (Ca) (Mg) (K) (HCO,) mag­ oration carbon­ mhos at at 180°C) nesium ate 25°C) 262 33 15 2.1 168 4.0 2.0 1.0 150 144 6 273 8.0 5 Nov. 3 ...... 292 34 16 2.2 176 4.2 3.2 .8 158 151 6 284 8.0 5 392 35 15 2.2 173 4.2 3.8 .8 155 149 7 285 7.3 5 299 33 16 1.6 172 3.5 2.2 .5 152 148 7 291 7.7 1,450 19 12 1.4 104 6.3 1.8 2.6 105 95 10 184 7.0 Mar. 15 ...... 1,210 20 13 1.6 114 7.8 2.0 2.6 109 103 10 196 7.8 10 755 23 14 3.7 128 10 3.0 2.7 129 115 10 227 7.5 5 890 25 14 2.4 140 7.8 3.0 1.8 132 120 5 235 7.9 5 1,440 20 13 1.2 114 7.0 2.0 1.8 110 103 10 197 7.5 10 620 25 15 2.2 1.3 145 4.6 2.5 .7 126 124 5 236 8.1 301 31 15 2.8 162 5.4 4.0 2.4 141 139 6 267 7.5 5 Seot. 26 ...... 272 32 16 3.4 a 170 5.4 3.5 2.2 145 146 6 273 8.4 5 a Includes equivalent of 4 parts per million of carbonate (CO,). WHITE RIVER BASIN Continued

CURRENT RIVER NEAR POCAHONTAS, ARK.

LOCATION. At bridge on U. S. Highway 67, near Pocahontas, Randolph County. RECORDS AVAILABLE.--Chemical analyses: October 1954 to September 1956. REMARKS. No discharge records available for this station. Chemical analyses, in parts per million, water year October 1955 to September 1956 Dissolved Hardness Specific Cal­ Mag­ Potas­ Bicar­ solids as CaCO, conduct­ Mean Silica Iron Sodium Sulfate Chloride Fluoride Nitrate discharge cium nesium (residue ance Date of collection (Si02) (Fe) (Na) sium bonate (S04) (Cl) (F) (N03) Calcium, Non- (micro- PH Color (cfs) (Ca) (Mg) (K) (HCOS) on evap­ oration mag­ carbon­ mhos at at 180°C) nesium ate 25°C) Oct. 4, 1955...... 38 20 1.2 212 5.4 2.5 0.4 174 177 3 324 8.2 5 40 20 1.8 218 3.8 2.2 .6 182 182 3 338 7.8 5 40 21 1.6 220 3.0 2.8 .4 184 186 6 342 7.8 5 Jan. 17, 1956 ...... 38 29 1.2 236 3.1 3.0 .7 184 204 10 356 7.4 33 20 1.4 184 4.4 2.2 1.9 149 164 13 293 7.3 Mar. 15 ...... 30 16 1.7 a 166 3.4 4.5 1.8 152 141 4 256 8.6 5 34 18 1.8 b!87 2 .8 2.2 1.3 166 159 6 286 8.4 5 30 21 1.7 188 5.0 2.5 .9 162 161 7 293 8.1 5 24 17 1.0 146 5.0 2.0 1.8 134 130 10 239 7.8 5 31 20 2.1 1.1 c!89 2.8 2.0 1.8 154 160 5 f294 8.7 5 36 20 2.3 202 4.6 2.5 1.6 168 172 6 319 8.1 5 Sept. 26 ...... 24 20 1.9 b!67 4.2 3.0 1.1 132 142 5 259 8.4 7 a Includes equivalent of 8 parts per million of carbonate (CO,), b Includes equivalent of 4 parts per million of carbonate (CO,), c Includes equivalent of 2 parts per million of carbonate (CO,). WHITE RIVER BASIN Continued SPRING RIVER AT IMBODEN, ARK. LOCATION. At gaging station at bridge on U. S. Highway 62 at Imboden, Lawrence County, 3.9 miles downstream from Janes Creek, 8.5 miles upstream from Eleven Point River, and 12.1 miles upstream from mouth. DRAINAGE AREA. 1,162 square miles. RECORDS AVAILABLE. Chemical analyses: October 1953 to September 1956. Water temperatures: December 1955 to September 1956. EXTREMES, 1955-56. Dissolved solids: Maximum, 312 ppm Jan. 6; minimum, 98 ppm . Hardness: Maximum, 248 ppm Jan. 21-31; minimum, 96 ppm July 25. Specific conductance: Maximum daily, 557 micromhos Jan. 6; minimum daily, 175 micromhos July 25. Water temperatures: Maximum, "82 *F on several days during July and August; minimum 35*F on several days during December and January. REMARKS. Records of specific conductance of daily samples available in district office at Fayetteville, Ark. Records of discharge for water year October 1955 to September 1956 given in WSP 1441.

Chemical analyses, in parts per million, December 19SS to September 1956

Mag­ Po­ Dissolved Hardness Specific Mean Cal­ So- Bicar­ Car­ Sul- Chlo­ Fluo- Ni­ solids asCaCQ, conduct­ dis­ Silica Iron ne­ tas­ Date of collection cium dluni bonate bonate fate ride ride trate (residue ance charge (SiO.) (Fe) sium sium on evap­ Calcium Non- (micro- PH Color (Ca) (Na) (HCOS) (CO,) (S04) (Cl) (F) (NOS) mag­ carbon­ (cfs) (Mg) (K) oration mhos at at 180°C) nesium ate 25°C) Dec. 1-10, 1955 .... 313 5.6 0.02 39 29 2.2 1.4 257 0 3.8 2.5 0.1 1.0 199 217 6 382 8.2 5 293 6.4 .02 34 29 2.3 1.4 235 0 4.8 3.5 .1 2.7 191 204 12 367 8.2 5 285 6.6 .02 34 29 2.3 1.3 228 6 5.0 3.0 .1 1.0 188 204 7 362 8.4 5 Jan. 1-5,7-10,1956.. 272 5.9 .00 43 31 3.1 1.5 278 0 5.0 4.0 .0 .7 220 235 7 424 8.1 5 289 244 0 1.0 33 1.4 a312 239 39 557 8.2 275 6.4 .00 45 31 2.6 1.5 283 0 4.6 3.5 .0 .4 220 240 8 428 8.1 5 308 6.6 .00 50 30 3.0 1.4 294 0 4.6 4.0 .0 .4 234 248 8 445 8.1 5 532 178 8 3.0 3.0 1.8 a 231 170 11 413 8.5 Feb. 2-5 ...... 2,862 29 16 1.0 156 0 5.6 3.1 2.5 150 140 12 254 7.8 1,548 .0 .02 40 20 2.0 2.0 206 0 6.4 2.8 .1 3.2 200 182 13 342 8.2 17 Feb. 12-17 ...... 1,672 4.5 .00 43 21 2.0 1.6 220 2 3.8 2.2 .1 2.5 202 194 10 353 8.3 10 5,920 26 13 1.4 136 0 4.8 1.8 2.6 139 120 8 227 7.8 Keb 21 1,970 176 8 9.0 2.5 5.7 a 173 172 15 309 8.6 Feb. 22-29 ...... 1,229 4.3 .02 45 21> 2.2 1.6 226 2 5.4 3.5 .1 4.0 225 199 10 364 8.3 10 905 148 3 5.0 3.8 4.4 a 181 143 17 324 8.5 Mar. 2, 7, 10 ...... 755 -- -- 38 24 1.5 -- 221 0 5.8 2.2 3.0 194 194 12 348 8.1 5 830 134 10 2.0 2.5 4.4 a 179 141 34 320 8.5 740 34 24 1.6 212 - 0 5.0 2.2 3.7 190 184 10 336 8.1 10 672 -- -- 40 25 1.4 -- 230 0 5.6 2.5 2.0 199 203 14 360 8.0 5 Mar. 12-13, 15-16, 676 36 24 1.5 213 0 4.8 2.8 2.7 187 188 14 335 8.1 7 705 150 8 5.0 2.5 3.6 a216 147 11 385 8.5 569 2.2 .03 32 25 2.2 1.6 216 0 4.2 3.0 .0 2.8 199 183 6 336 7.9 5 506 166 6 4.0 3.0 2.0 a 222 157 11 396 8.5 Aor. 1-8. 10 ...... 561 38 25 1.9 _ 228 0 4.8 2.8 2.0 202 198 11 351 8.2 10 a Estimated from specific conductance. WHITE RIVER BASIN Continued SPRING RIVER AT IMBODEN. ARK.--Continued Chemical anal yses, in parts per million, December 1955 to September 1956 Continued Mag­ Po- Dissolved Hardness Specific Mean Cal- So- Bicar­ Car­ Sul- Chlo­ Fluo- Ni­ solids as CaCO, conduct­ dis­ Silica Iron ne­ tas- Date of collection cium diun* bonate bonate fate ride ride trate (residue ance charge (SiOJ (Fe) sium slum on evap­ Calcium, Non- (micro- pH Color (Ca) (Mg) (Na) (K) (HCO,) (CO,) (S04) (Cl) (F) (NO,) mag­ carbon­ (cfs) oration mhos at at 180°C) nesium ate 25°C) 483 160 8 2.0 6.5 1.8 a 221 154 10 395 8.6 Apr. 11-13, 15-20.. 972 -- -- 43 24 3.8 -- 241 0 4.2 6.0 1.2 223 206 8 381 8.2 10 524 161 8 5.0 3.0 2.6 a 194 154 9 347 8.7 844 4.4 0.01 42 27 3.1 3.2 250 0 5.4 7.0 0.0 1.9 234 216 11 388 8.2 5 825 4.0 .00 34 25 2.9 3.2 218 0 4.2 4.5 .0 2.3 182 188 9 344 7.8 5 May 11-16, 19-20 . . 1,333 37 24 2.3 227 0 3.8 3.5 1.3 198 191 5 343 7.8 10 2,030 118 8 5.0 1.0 3.0 a 124 120 10 222 8.6 1,430 146 6 4.0 2.5 1.9 a 143 137 7 255 8.6 May 21-26, 28-31 . . 1,196 -- -- 45 21 2.4 -- 216 9 4.4 4.0 1.4 216 199 7 351 8.6 10 May 27 1,490 166 8 4.0 2.0 2 2 a 153 188 39 274 8.7 690 4.8 .00 31 24 3.6 1.5 195 0 7.4 7.5 .0 5.4 209 176 16 337 7.5 8 566 34 25 2.0 222 0 4.6 3.0 .9 192 188 6 338 8.0 5 627 40 25 2.1 242 0 6.2 2.5 1.1 208 203 4 367 7.7 5 471 9.4 .00 22 24 2.8 1.1 180 0 5.4 3.0 .0 2.3 158 154 6 293 8.0 5 418 196 4 2.0 2.0 1.5 a 220 175 8 392 8.4 -12, 14-20 .. 734 " -- 30 20 2.0 -- 186 0 4.8 2.5 3.4 164 157 5 293 8.0 7 405 192 4 1.0 2.5 2.0 a217 170 6 387 8.4 -24, 27-31... 1,074 ~ ~ 34 20 1.9 ~ 196 0 5.6 2.5 3.8 173 167 6 308 7.9 5

3,520 110 0 2.0 .5 2.0 a 98 96 6 175 8.0 1,490 135 0 4.0 1.0 2.4 a!16 125 14 208 8.2 515 9.8 .00 37 28 2.5 1.2 250 0 5.0 2.5 .0 1.9 209 207 3 383 8.0 5 394 29 25 2.2 199 2 4.4 4.0 3.4 171 175 9 315 8.3 7 372 35 24 2.9 217 0 4.0 5.0 3.1 186 186 8 343 8.1 5 328 30 26 1.8 216 0 4.0 2.5 2.3 174 182 5 328 8.0 5 293 33 28 2.1 232 0 4.2 2.5 1.9 190 162'198 7 353 7.9 5 Sept. 21-30...... 280 2.9 .00 27 23 2.1 1.2 190 0 6.2 2.5 .0 2.9 159 6 300 8.2 5 Average ...... 670 - -- 38 24 2.3 -- 202 2 4.5 3.7 -- 2.4 192 194 24 343 ~ 7 a Estimated from specific conductance. WHITE RIVER BASIN 41 WHITE RIVER BASIN--Continued SPRING RIVER AT IMBODEN, ARK.--Continued Temperature (°F) of water, December 1955 to September 1956 Day Oct. Nov. Dec. Jan. Feb. Mar. Apr. May June July Aug. Sept. 1 38 43 40 49 57 82 71 80 80 78 2 39 44 42 50 60 56 69 82 81 78 3 40 43 40 51 63 83 88 81 80 73 4 45 42 40 51 60 85 69 82 81 73 5 -- 42 40 55 60 88 70 82 81 73 6 41 43 42 59 61 70 70 81 82 74 7 42 42 41 60 56 71 71 82 81 70 8 43 40 44 52 54 70 73 80 81 88 9 40 38 44 52 56 70 74 80 82 87 10 40 38 44 53 53 71 74 78 80 68 11 39 39 42 52 52 72 74 77 78 89 12 40 39 43 49 54 73 78 78 78 89 13 _ 38 42 47 56 74 78 79 81 70 14 38 38 45 47 59 75 73 79 81 72 15 37 38 48 45 60 70 74 79 80 89 16 35 36 46 46 87 65 74 80 79 74 17 35 36 48 46 55 64 74 79 80 75 18 38 36 48 59 55 86 76 79 82 71 19 36 35 48 49 56 89 77 78 81 71 20 36 35 47 48 57 89 79 78 79 69 21 35 37 47 48 58 72 80 77 73 88 22 36 38 47 49 60 73 80 78 73 88 23 39 36 48 50 59 73 81 76 73 70 24 42 35 52 52 57 71 81 79 75 87 25 44 35 52 51 60 68 79 78 75 88 26 44 36 53 55 62 66 78 78 75 85 27 43 36 54 58 65 66 78 78 75 68 28 42 41 53 57 87 68 79 77 75 68 29 46 44 50 54 87 71 78 78 76 65 30 45 42 _ 53 64 73 79 79 74 65 31 44 40 55 74 79 78 Aver­ age 40 39 46 52 59 89 75 79 78 70 42 LOWER MISSISSIPPI RIVER BASIN

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