Fluoborite Mg3(BO3)(F, OH)3 C 2001-2005 Mineral Data Publishing, Version 1
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NOTES and NEWS LUDWIGITE from COLORADOGULCH, NEAR HELENA, MONTANA Aoor,Pn Knorl, Yale Uniaersity, Ivew Haoen, Conn
NOTES AND NEWS LUDWIGITE FROM COLORADOGULCH, NEAR HELENA, MONTANA Aoor,pn KNorl, Yale Uniaersity, IVew Haoen, Conn. The relatively rare magnesium-iron borate ludwigite was found during the past summer to occur abundantly 10 miles west of Helena, at Colo- rado Gulch, Lewis and Clark County, Montana. It occursat two prospect pits on the summit of the high hill northwest of the junction of the forks of Colorado Creek. The prospect openings are in the marbleized dolo- mites and limestones of the Devonian Jefferson formation a few yards from the contact of the Boulder batholith, which here consists of sub- porphyritic quartz monzonite. The prospect pits had been opened up in searchfor iron ore, which consistsof magnetite having a notably perfect octahedral parting, apparently as a result of incipient alteration. Large quantities of black rock are exposed,consisting almost wholly of a radially fi.brousmineral, which becauseof the prevalence of tourmaline in this part of the batholith might at first sight be consideredto be tour- maline. The silky luster of the mineral and its tendency toward ocherous weathering, however, suggestthat the mineral is ludwigite. The identity of the mineral was proved by its boron flame reaction, solubility in HCl, and copious precipitates of iron and magnesium. When crushed and ex- amined in oils, a large number of straight slender fibers are seen,but only the very thinnest of them are translucent. The fibers give sharp, straight extinction, and are pleochroic, from deep olive-green in the transverse position to brown parallel to the length. They have positive elongation, and fibers showing the maximum differencein absorption give flash fig- ures, which show that Z:c. -
Revision #1 the Atomic Arrangement and Electronic Interactions In
This is the peer-reviewed, final accepted version for American Mineralogist, published by the Mineralogical Society of America. The published version is subject to change. Cite as Authors (Year) Title. American Mineralogist, in press. DOI: https://doi.org/10.2138/am-2021-7851. http://www.minsocam.org/ 1 Revision #1 2 3 The atomic arrangement and electronic interactions in vonsenite at 4 295, 100, and 90 K 5 1, 1, 2 3 4 6 MARC MADERAZZO , JOHN M. HUGHES , M. DARBY DYAR , GEORGE R. ROSSMAN , 5 3 6 7 BRANDON J. ACKLEY , ELIZABETH C. SKLUTE , MARIAN V. LUPULESCU , AND 7 8 JEFFREY CHIARENZELLI 9 10 1Department of Geology, University of Vermont, Burlington, Vermont, 05405, U.S.A. 11 2Department of Geology and Environmental Earth Sciences, Miami University, Oxford, Ohio 45056, U.S.A. 12 3Department of Astronomy, Mount Holyoke College, South Hadley, Massachusetts 01075, U.S.A. 13 4Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125- 14 2500, U.S.A. 15 5Department of Chemistry, University of Vermont, Burlington, Vermont, 05405, U.S.A. 16 6New York State Museum, Research and Collections, 3140 CEC, Albany, New York 12230, U.S.A. 17 7Department of Geology, St. Lawrence University, Canton, New York 13617, U.S.A. 18 19 ABSTRACT 2+ 3+ 20 Vonsenite, Fe 2Fe O2BO3, has been the subject of many studies in the materials-science and 21 condensed-matter-physics communities due to interest in the electronic and magnetic properties 22 and ordering behavior of the phase. One such study, undertaken on synthetic material of 23 endmember composition, reports X-ray diffraction structure refinements that indicate a phase 24 transition from Pbam to Pbnm at or just below approximately 283 K, determined subsequently to 25 arise from a Peierls-like instability. -
A Specific Gravity Index for Minerats
A SPECIFICGRAVITY INDEX FOR MINERATS c. A. MURSKyI ern R. M. THOMPSON, Un'fuersityof Bri.ti,sh Col,umb,in,Voncouver, Canad,a This work was undertaken in order to provide a practical, and as far as possible,a complete list of specific gravities of minerals. An accurate speciflc cravity determination can usually be made quickly and this information when combined with other physical properties commonly leads to rapid mineral identification. Early complete but now outdated specific gravity lists are those of Miers given in his mineralogy textbook (1902),and Spencer(M,i,n. Mag.,2!, pp. 382-865,I}ZZ). A more recent list by Hurlbut (Dana's Manuatr of M,i,neral,ogy,LgE2) is incomplete and others are limited to rock forming minerals,Trdger (Tabel,l,enntr-optischen Best'i,mmungd,er geste,i,nsb.ildend,en M,ineral,e, 1952) and Morey (Encycto- ped,iaof Cherni,cal,Technol,ogy, Vol. 12, 19b4). In his mineral identification tables, smith (rd,entifi,cati,onand. qual,itatioe cherai,cal,anal,ys'i,s of mineral,s,second edition, New york, 19bB) groups minerals on the basis of specificgravity but in each of the twelve groups the minerals are listed in order of decreasinghardness. The present work should not be regarded as an index of all known minerals as the specificgravities of many minerals are unknown or known only approximately and are omitted from the current list. The list, in order of increasing specific gravity, includes all minerals without regard to other physical properties or to chemical composition. The designation I or II after the name indicates that the mineral falls in the classesof minerals describedin Dana Systemof M'ineralogyEdition 7, volume I (Native elements, sulphides, oxides, etc.) or II (Halides, carbonates, etc.) (L944 and 1951). -
Co-Conversion Mechanisms of Boron and Iron Components of Ludwigite Ore During Reductive Soda-Ash Roasting
metals Article Co-Conversion Mechanisms of Boron and Iron Components of Ludwigite Ore during Reductive Soda-Ash Roasting Xin Zhang, Guanghui Li , Mingjun Rao * , Zhiwei Peng, Qiang Zhong *, Jun Luo, Jinxiang You and Tao Jiang School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China; [email protected] (X.Z.); [email protected] (G.L.); [email protected] (Z.P.); [email protected] (J.L.); [email protected] (J.Y.); [email protected] (T.J.) * Correspondence: [email protected] (M.R.); [email protected] (Q.Z.); Tel.: +86-731-88877656 (M.R.); +86-731-88830542 (Q.Z.) Received: 23 September 2020; Accepted: 11 November 2020; Published: 14 November 2020 Abstract: Ludwigite ore is a typical intergrown mineral resource found in China. Reductive soda-ash roasting followed by water leaching is an innovative process for the high-efficiency separation and recovery of boron and iron. In this study, the co-conversion mechanism of boron activation and iron reduction during soda-ash reductive roasting for boron-bearing iron concentrate was clarified. When the boron-bearing iron concentrate was reduced in the presence of Na2CO3, szaibelyite (Mg2(OH)(B2O4) (OH)) was activated to sodium metaborate (NaBO2) and, meanwhile, magnetite (Fe3O4) was reduced to metallic iron (MFe). Boron activation promoted iron-oxide reduction effectively, while the latter could only slightly influence the former. The promotion occurred through (1) a facilitated generation of sodium magnesium silicate (Na2MgSiO4) and a hindering of the formation of olivine (MgxFe2-x(SiO4)). (2) The newly generated NaBO2 promoted iron-oxide reduction. -
Bulletin 65, the Minerals of Franklin and Sterling Hill, New Jersey, 1962
THEMINERALSOF FRANKLINAND STERLINGHILL NEWJERSEY BULLETIN 65 NEW JERSEYGEOLOGICALSURVEY DEPARTMENTOF CONSERVATIONAND ECONOMICDEVELOPMENT NEW JERSEY GEOLOGICAL SURVEY BULLETIN 65 THE MINERALS OF FRANKLIN AND STERLING HILL, NEW JERSEY bY ALBERT S. WILKERSON Professor of Geology Rutgers, The State University of New Jersey STATE OF NEw JERSEY Department of Conservation and Economic Development H. MAT ADAMS, Commissioner Division of Resource Development KE_rr_ H. CR_V_LINCDirector, Bureau of Geology and Topography KEMBLEWIDX_, State Geologist TRENTON, NEW JERSEY --1962-- NEW JERSEY GEOLOGICAL SURVEY NEW JERSEY GEOLOGICAL SURVEY CONTENTS PAGE Introduction ......................................... 5 History of Area ................................... 7 General Geology ................................... 9 Origin of the Ore Deposits .......................... 10 The Rowe Collection ................................ 11 List of 42 Mineral Species and Varieties First Found at Franklin or Sterling Hill .......................... 13 Other Mineral Species and Varieties at Franklin or Sterling Hill ............................................ 14 Tabular Summary of Mineral Discoveries ................. 17 The Luminescent Minerals ............................ 22 Corrections to Franklln-Sterling Hill Mineral List of Dis- credited Species, Incorrect Names, Usages, Spelling and Identification .................................... 23 Description of Minerals: Bementite ......................................... 25 Cahnite .......................................... -
Metamorphism and Fluid-Rock Interaction in the Alta, Utah
METAMORPHISM AND FLUID-ROCK INTERACTION IN THE ALTA, UTAH CONTACT AUREOLE: IDENTIFICATION OF FORSTERITE REACTION PATHWAYS, EVALUATION OF REACTION OVERSTEPPING, AND TRACE ELEMENT CHARACTERIZATION by Patrick C. Loury A thesis submitted to the faculty of The University of Utah in partial fulfillment of the requirements for the degree of Master of Science in Geology Department of Geology and Geophysics The University of Utah August 2015 Copyright © Patrick C. Loury 2015 All Rights Reserved The University of Utah Graduate School STATEMENT OF THESIS APPROVAL The thesis of ______________________Patrick C. Loury has been approved by the following supervisory committee members: John R. Bowman , Chair 1/14/2014 Date Approved Erich U. Petersen , Member 6/24/2013 Date Approved Diego P. Fernandez , Member 6/24/2013 Date Approved and by ____________________ John M. Bartley____________________ , Chair/Dean of the Department/College/School o f _____________Geology and Geophysics and by David B. Kieda, Dean of The Graduate School. ABSTRACT Forsterite (Fo) is developed extensively in dolomite marbles in the Alta, Utah contact aureole. Through the Fo zone and much of the periclase (Per) zone, the number of forsterite (Fo) crystals/mol Fo increases and the average Fo grain size decreases as the 18 Alta Stock intrusive contact is approached. Excluding the innermost Per zone, A O (Carbonate-Fo) values increasingly depart from equilibrium values with increased metamorphic grade. These textural and oxygen isotope trends reflect progressively greater reaction affinity (Ar) driven by the combined effects of elevated temperatures, faster heating rates, and decreasing X(CO2) in infiltrating fluids toward the igneous contact. 18 Significant variation exists in the number of Fo crystals/mol Fo, 5 O (carbonate), 18 and A O (Carbonate-Fo) between strata within individual outcrops at several locations. -
Karlite, Mgr(Bor)3 (OH,Cl)S a New Borate Mineral and Associatedludwigite from the Eastern Alps
American Mineralogist, Volume 66, pages 872-877, 1981 Karlite, Mgr(BOr)3 (OH,Cl)s a new borate mineral and associatedludwigite from the Eastern Alps GBRHIRo FRANZ Institut fiir AngewandteGeophysik, Petrolo gie und Lagerstiittenforschung TechnischeUniversitiit Berlin, EB 310,StraBe des 17. Juni 135 D 1000Berlin 12. WestGermanv DTETRTcHAcrnRuaNo I nstitutJilr Mineralogie der Univ ersitiit Kiel Olshausenstr.40-60,D 2300Kiel, WestGermany eNo EporB Kocu Mineralogisch-petrographisches Institut der Universitiit Basel Bernoullistr. 30, CH 4056 Basel, Switzerland Abstract Karlite, a new borate mineral with the idealized formula Mgr(BOr)r(OH,Cl), occurs in a clinohumite-chlorite marble associated with ludwigite at Schlegeistal, Zillertaler Alpen, Austria. The mineral is white to light green and has a silky luster. It occursas aggregatesof minute needlesand prisms elongatedparallel to c, as much as l0 mm long, which sometimes have rosette-likeforms. Karlite is biaxial negativewith a mean 2v of 24o, a: 1.589,F: 1.632,y = 1.634,y - d: 0.045,X: c, Y : b,Z: a; and is colorlessin thin section.The (001) cleavageis perfect. The two most common forms are {ll0} and {100}. Hardnessis 5.5. Streak is colorless. Karliteis orthorhombic,Y2r2,2r, with a: 17.929(5),b: 17.600(5),c: 3.102(l)A,Z:4, G*" : 3.02, G-.* : 2.80 to 2.85. The six strongestlines of the X-ray pattern (4 in A, in- tensity, hkl) are 2.21,100,810,740,441;2.83,92,620;2.25,87,251; 2.7g,92,260,221,540; 12.53,76,11o;an.d2.89,68, 160,221,121. -
First Annual Mineralogy Exhibit of the Franklin Kiwanis Club
FIRST ANNUAL MINERALCGY EXHIBIT CF THE FRANKLIN KIWANIS CLUB - October 26th & 27th, 1957 This exhibit makes available for public view for the first time many of the principal private collections of the unique minerals of the Franklin-Sterling Area. These unusual ore bodies, comprising more minerals than are found anywhere else on earth, have intrigued mineralogists and collectors ever since their discovery. Dutch mining experts first explored the area in 1640. The ore bodies, whose principal metals are zinc, manganese and iron, continued to puzzle experts for the next two centuries. Mining operations were first successfully developed by The New Jersey Zinc Company, which succeeded in building a great industry from its beginnings at Franklin. The deposits at Franklin are now exhausted and its specimens have become collectors items. The 178 minerals found at Franklin-Sterling and the 29 minerals which have never been found elsewhere are listed below. MINERALS OF THE FRANKLIN-STERLING AREA Agurite Calcium, Lar- Halloysite Nasonite Albite senite Hancockite Ne oto c it e Allactite Celestite Hardystonite Niccolite Allanite Cerusite Hedyphane. Norbergite Amphibole Chalcocite Hematite Oligocase Actinolite Chalcophanite Hetacrolite Pararammels- Crocidolite Chalcopyrite Heulandite. ' bergite Cummingtonite Chleanthite Hodgkinsonite Pectolite Edenite Chlorite Holdenite Phlogopite Hastingsite Chlorophoenicite Hortonolite Prehnite Hornblende Magnesium Chl. Hyalophane Psilomelane Pargasite Chondrocite Hydrohans- Pyrite Tremolite Clinohedrite mannite -
A-Type Granite Plutons and Tin Skarns in Southeast Yukon: Mindy Prospect and Surrounding Granites of 105C/9
A-type granite plutons and tin skarns in southeast Yukon: Mindy prospect and surrounding granites of 105C/9 Tim Liverton Watson Lake, Yukon Liverton, T., 2016. A-type granite plutons and tin skarns in southeast Yukon: Mindy prospect and surrounding granite of 105C/9. In: Yukon Exploration and Geology 2015, K.E. MacFarlane and M.G. Nordling (eds.), Yukon Geological Survey, p. 151-164. ABSTRACT In the southeast Yukon, immediately southwest of the mid-Cretaceous Cassiar suite plutons,is a northwest-trending suite of anorogenic one-mica granites called the Seagull suite. This suite is comprised of the Seagull and Hake batholiths, Ork and Thirtymile stocks and an un-named intrusion to the northwest. These B and F enriched granites are associated with various forms of tin mineralization, including skarns. The Mindy prospect in the Thirtymile Range contains a variety of metasomatic silicate and borate and fluoride minerals. Tin (Sn) mineralization is found as cassiterite and borate mineral phases. Mapping has shown that faulting active during metamorphism- metsomatism controlled the distribution of the skarn mineralization. Both mineral chemistry and structural control of mineralization have a significant effect on the economic potential of the Mindy prospect. [email protected] YUKON EXPLORATION AND GEOLOGY 2015 151 YUKON GEOLOGICAL RESEARCH INTRODUCTION Skarn mineralization may have a variety of tin minerals: cassiterite, vonsenite [3(Fe,Mg)O·2Fe2O3·SnO2·3B2O3], A northwest-trending line of mid-Cretaceous granite 2+ 3+ hulsite [(Fe ,Mg)2·(Fe ,Sn)BO5], nordenskiöldine plutons in southeast Yukon (Seagull and Hake batholiths, [CaSn(BO ) ] and malayaite [CaSn(SiO )] associated with Ork stock, Thirtymile stock and one un-named stock) have 3 2 5 fluoborite [Mg3(F,OH)3BO3]. -
Ludwigite Mg2fe3+BO5
3+ Ludwigite Mg2Fe BO5 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. Crystals are unterminated, fibrous, curved, to 20 cm; commonly in fanlike to felted aggregates. Physical Properties: Tenacity: Tough. Hardness = 5–5.5 D(meas.) = 3.80(3) D(calc.) = [3.78] Weakly ferromagnetic, probable. Optical Properties: Opaque, translucent only in thin fragments and rims of crystals. Color: Pitch-black, olive-black. Luster: Submetallic. Streak: Black to greenish black. Luster: Silky. Optical Class: Biaxial (+). Pleochroism: X = Y = dark green; Z = dark reddish brown. Orientation: Z = c. Dispersion: rv, extreme. α = 1.83–1.85 β = 1.83–1.90 γ = 1.97–2.03 2V(meas.) = Small. Anisotropism: Strong; yellowish brown to bluish violet gray. Bireflectance: Pinkish gray to dark greenish gray. R1–R2: (400) 10.1–13.8, (420) 9.7–13.2, (440) 9.3–12.6, (460) 9.0–12.1, (480) 8.7–11.8, (500) 8.5–11.5, (520) 8.2–11.3, (540) 8.1–11.2, (560) 7.9–11.0, (580) 7.8–10.9, (600) 7.6–10.8, (620) 7.5–10.8, (640) 7.4–10.8, (660) 7.3–10.8, (680) 7.2–10.8, (700) 7.2–10.9 Cell Data: Space Group: P bam. a = 9.2411(6) b = 12.2948(9) c = 3.0213(3) Z = 4 X-ray Powder Pattern: Willis quadrangle, Montana, USA. 5.12 (100), 2.547 (70), 2.515 (70), 2.027 (50), 2.167 (35), 2.990 (25), 1.903 (25) Chemistry: (1) (2) (1) (2) (1) (2) SiO2 0.49 Fe2O3 39.00 40.89 CaO 0.11 + TiO2 0.05 FeO 3.17 H2O 0.15 B2O3 17.43 17.83 MnO 0.33 Total 100.47 100.00 Al2O3 0.62 MgO 39.12 41.28 (1) Ocna de Fier, Romania; B2O3 by ICP, H2O by the Penfield method; corresponds to 2+ 3+ (Mg1.91Fe0.09Mn0.01)Σ=1.00(Fe0.98Al0.02)Σ=1.00B1.00O5. -
A Mineralogical Field Guide for a Western Tasmania Minerals and Museums Tour
MINERAL RESOURCES TASMANIA Tasmania DEPARTMENTof INFRASTRUCTURE, ENERGY and RESOURCES Tasmanian Geological Survey Record 2001/08 A mineralogical field guide for a Western Tasmania minerals and museums tour by R. S. Bottrill This guide was originally produced for a seven day excursion held as part of the International Minerals and Museums Conference Number 4 in December 2000. The excursion was centred on the remote and scenically spectacular mineral-rich region of northwestern Tasmania, and left from Devonport. The tour began with a trip to the Cradle Mountain National Park, then took in visits to various mines and mineral localities (including the Dundas, Mt Bischoff, Kara and Lord Brassey mines), the West Coast Pioneers Memorial Museum at Zeehan and a cruise on the Gordon River. A surface tour of the copper deposit at Mt Lyell followed before the tour moved towards Hobart. The last day was spent looking at mineral sites in and around Hobart. Although some of the sites are not accessible to the general public, this report should provide a guide for anyone wishing to include mineral sites in a tour of Tasmania. CONTENTS Tasmania— general information Natural history and climate ………………………………………………… 2 Personal requirements ……………………………………………………… 2 General geology…………………………………………………………… 2 Mining history …………………………………………………………… 4 Fossicking areas — general information ………………………………………… 4 Mineral locations Moina quarry …………………………………………………………… 6 Middlesex Plains ………………………………………………………… 6 Lord Brassey mine ………………………………………………………… 6 Mt Bischoff ……………………………………………………………… -
Torreyite (Mg, Mn )9Zn4(SO4)2(OH)22 • 8H2O C 2001-2005 Mineral Data Publishing, Version 1
2+ Torreyite (Mg, Mn )9Zn4(SO4)2(OH)22 • 8H2O c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Rare blocky crystals, to 1 mm, in parallel growth; foliated, fine-grained granular to massive. Twinning: Ubiquitous microscopic polysynthetic twinning on a twin plane in [010]. Physical Properties: Cleavage: {010}, good. Tenacity: Somewhat brittle. Hardness = 3 D(meas.) = 2.665 D(calc.) = 2.65 Optical Properties: Translucent. Color: Bluish white to colorless; colorless in transmitted light. Luster: Vitreous to almost pearly, dull. Optical Class: Biaxial (–). Orientation: X = b. α = 1.570 β = 1.584 γ = 1.585 2V(meas.) = ∼40◦ ◦ Cell Data: Space Group: P 21/a. a = 10.522 b = 9.433 c = 16.443 β =94.91 Z=2 X-ray Powder Pattern: Sterling Hill, New Jersey, USA. 10.2 (100), 5.16 (50), 1.566 (50), 3.84 (40), 2.729 (40), 6.10 (30), 4.52 (20) Chemistry: (1) SO3 11.64 SiO2 0.08 MnO 17.98 ZnO 26.30 MgO 17.27 H2O 26.39 Total 99.66 (1) Sterling Hill, New Jersey, USA; deducting SiO2, corresponds to (Mg5.60Mn3.31)Σ=8.91 • Zn4.22(SO4)1.90(OH)22.46 7.928H2O. Occurrence: Very rare, in veinlets cutting calcite–franklinite–willemite ore in a metamorphosed stratiform zinc orebody. Association: Mooreite, fluoborite, pyrochroite, sussexite, rhodochrosite, zincite, franklinite, willemite, calcite. Distribution: At Sterling Hill, Ogdensburg, Sussex Co., New Jersey, USA. Name: Honors Dr. John Torrey (1796–1873), American naturalist who early studied Franklin, New Jersey, USA minerals. Type Material: Harvard University, Cambridge, Massachusetts, USA, 113732.