Mineralogy of Eudialyte Group Minerals from the East Hill Suite Of
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University of New Orleans ScholarWorks@UNO University of New Orleans Theses and Dissertations Dissertations and Theses 5-15-2009 Mineralogy of Eudialyte Group Minerals From the East Hill Suite Of the Mont Saint-Hilaire Alkaline Plutonic Complex, Including an Alternative Site-Assignment Algorithm & A Proposed Classification System Peter Tice University of New Orleans Follow this and additional works at: https://scholarworks.uno.edu/td Recommended Citation Tice, Peter, "Mineralogy of Eudialyte Group Minerals From the East Hill Suite Of the Mont Saint-Hilaire Alkaline Plutonic Complex, Including an Alternative Site-Assignment Algorithm & A Proposed Classification System" (2009). University of New Orleans Theses and Dissertations. 965. https://scholarworks.uno.edu/td/965 This Thesis is protected by copyright and/or related rights. It has been brought to you by ScholarWorks@UNO with permission from the rights-holder(s). You are free to use this Thesis in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights- holder(s) directly, unless additional rights are indicated by a Creative Commons license in the record and/or on the work itself. This Thesis has been accepted for inclusion in University of New Orleans Theses and Dissertations by an authorized administrator of ScholarWorks@UNO. For more information, please contact [email protected]. Mineralogy of Eudialyte Group Minerals From the East Hill Suite Of the Mont Saint-Hilaire Alkaline Plutonic Complex, Including an Alternative Site-Assignment Algorithm & A Proposed Classification System A Thesis Submitted to the Graduate Faculty of the University of New Orleans in partial fulfillment of the requirements for the degree of Master of Science in The Department of Earth and Environmental Sciences by Peter E. Tice B.Sc. McGill University, 1995 May, 2009 Copyright 2009, Peter E. Tice ii ACKNOWLEDGEMENTS This work greatly benefited from the guidance and assistance of a number of people; to them should be conveyed deep gratitude. Dr. Wm. B. Simmons, Jr. is to be thanked first and foremost for his thoughtful commentary on research methodology, analytical procedures, and petrological and mineralogical interpretations. He deserves a great deal of further appreciation for his dedication and patience. Dr. Simmons was gracious and accommodating in allowing the author to choose and direct the subject of his research; he was tolerant of changes in the direction of research, while still providing guidance and leadership; and he was unwavering in his support of the completion of this study. Dr. Simmons and Mr. Alexander U. Falster, as joint operators of the analytical facilities in the Department of Geology and Geophysics at the University of New Orleans, deserve many collective thanks for providing a laboratory at which students are able, instrumentally and financially, to carry out analyses of both a broad scope and a deep extent. This work required a variety of instruments and a number of instrument-hours that would have made its proper development and completion financially unattainable at virtually any other institution. Dr. Matthew W. Totten lent a valuable alternative perspective to this work and gave constant encouragement to the author in all his endeavours. He helped to develop the author’s breadth of expertise by giving the author the opportunity to collaborate on mineralogical projects in the realm of sedimentary petrology. He was an inspiration and role model throughout their relationship at the University of New Orleans. Dr. Karen L. Webber helped to develop the author’s understanding of mineralogical research in a petrological context, assisted the author in preliminary literature searches, gave iii insightful editorial commentary, and served as an example by whom to measure the standards that characterize research of high quality. Dr. Christopher D. Parkinson provided constructive criticism on the organization of this paper. Dr. Robert F. Martin, of McGill University, first inspired the interest of the author in pegmatites, alkaline igneous rocks, and Mont Saint-Hilaire. As advisor for the author’s undergraduate thesis on the mineralogy and crystallization dynamics of a pegmatite dike at Mont Saint-Hilaire, he accompanied the author on several excursions to the locality, provided expert instruction in scientific writing, and participated in numerous discussions on alkaline melts and mineralogy that shaped that thesis and led to this current work. Monsieur J.G. Poudrette of the Poudrette quarry graciously allows limited access to his property for the collection of aesthetic and research specimens. This beneficence is instrumental in the continuing efforts by all researchers to understand Mont Saint-Hilaire and is deeply appreciated. The author’s Mother and Father nurtured the author’s education and interest in the sciences in school and museums and through talks, both formal and informal. They provided the financial means for the author’s undergraduate education and were unconditionally loving and supportive through challenging and trying times. They were always there; they were true parents. The author’s wife, Sherri, was wonderfully understanding of the author’s needs for private, quiet writing time, spending many hours watching their children and looking after the author’s usual chores so that this work could be completed; although, the children did sometimes get to have a look at what daddy was doing—“Look at all the numbers!” In addition to taking iv care of this practical issue, she was unfaltering in her encouragement to bring this research to its written conclusion. Mr. Alexander U. Falster, although a major contributor to this work, is saved until the end to make more conspicuous his inclusion in this section. Through the entire course of his relationship with the author, he has been as a brother, always ready to offer advice, assistance, laughter, or consolation. Mr. Falster operated the electron microprobe for a total of approximately 150 hours to generate the chemical analyses for this work. He, along with Dr. Simmons, instructed the author on the theoretical and practical aspects of operating the electron microprobe, scanning electron microscope, X-ray diffractometer, and direct-coupled plasma spectrometer. Mr. Falster further assisted, when needed, in the author’s operation of the latter three instruments. Also, Mr. Falster is responsible for maintenance, repairs, and upkeep of all of the instruments used by the author at the University of New Orleans. Without his tremendous efforts, a work of this scope would have been impossible. To any family and friends who gave of themselves but who were not mentioned by name, many thanks. This thesis is dedicated to my chemistry teacher from Wyomissing Area High School, Mr. William C. Dowling, who first showed me the magic of chemistry. v TABLE OF CONTENTS LIST OF TABLES ...........................................................................................................................IX LIST OF FIGURES .......................................................................................................................... X ABSTRACT.................................................................................................................................... XII INTRODUCTION.............................................................................................................................. 1 PREVIOUS WORK........................................................................................................................... 3 HISTORICAL PERSPECTIVE................................................................................................................. 3 EUDIALYTE GROUP MINERALS AT MONT SAINT-HILAIRE ................................................................. 4 GEOLOGIC SETTING..................................................................................................................... 5 REGIONAL GEOLOGY......................................................................................................................... 5 GEOLOGY OF MONT SAINT-HILAIRE ................................................................................................. 7 OCCURRENCE OF EUDIALYTE GROUP MINERALS AT MONT SAINT-HILAIRE ...................................... 9 Introduction ................................................................................................................................. 9 Eudialyte Syenite ......................................................................................................................... 9 Descriptive Mineralogy of Eudialyte Group Minerals.............................................................. 10 ANALYTICAL METHODS ........................................................................................................... 11 SCANNING ELECTRON MICROSCOPY ............................................................................................... 11 Background................................................................................................................................ 11 Sample Preparation................................................................................................................... 11 Operating Conditions ................................................................................................................ 11 X-RAY DIFFRACTOMETRY ..............................................................................................................