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Chapter 20 Worksheet:

I. Determine what is oxidized and what is reduced in each reaction. Identify the oxidizing agent and the , also.

1. 2Sr + O2 2SrO

2. 2Li + S Li2S

3. 2Cs + Br2 2CsBr

4. 3Mg + N2 Mg3N2

5. 4Fe + 3O2 2Fe2O3

6. Cl2 + 2NaBr 2NaCl + Br2

7. Si + 2F2 SiF4

8. 2Ca + O2 2CaO

9. Mg + 2HCl MgCl2 + H2

10. 2Na + 2H2O 2NaOH + H2 ---

11. Give the oxidation number of each kind of atom or ion.

a. sulfate b. Sn c. S2- d. Fe3+ e. Sn4+ f. nitrate g. ammonium

12. Calculate the oxidation number of in each of the following.

a. Cr2O3 b. Na2Cr2O7 c. CrSO4 d. chromate e. dichromate 13. Use the changes in oxidation numbers to determine which elements are oxidized and which are reduced in these reactions. (Note: it is not necessary to use balanced equations)

a. C + H2SO4 CO2 + SO2 + H2O

b. HNO3 + HI NO + I2 + H2O

c. KMnO4 + HCl MnCl2 + Cl2 + H2O + KCl

d. Sb + HNO3 Sb2O3 + NO + H2O 14. For each reaction in problem 13, identify the oxidizing agent and reducing agent. Chapter 20 Worksheet: Redox ANSWERS

I. Determine what is oxidized and what is reduced in each reaction. Identify the oxidizing agent and the reducing agent, also. 0 2+ 0 2- 1. 2Sr + O2 2SrO Sr to Sr ; oxidized/reducing agent O to O ; reduced/ox. ag.

0 1+ 0 2- 2. 2Li + S Li2S Li to Li ; oxidized/red. ag. S to S ; reduced/ox. ag.

0 1+ 0 1- 3. 2Cs + Br2 2CsBr Cs to Cs ; oxidized/red. ag. Br to Br ; reduced/ox. ag.

0 2+ 0 3- 4. 3Mg + N2 Mg3N2 Mg to Mg ; oxidized/red. ag. N to N ; reduced/ox. ag.

0 3+ 0 1- 5. 4Fe + 3O2 2Fe2O3 Fe to Fe ; oxidized/red. ag. O to O ; reduced/ox. ag.

0 1- 1- 0 6. Cl2 + 2NaBr 2NaCl + Br2 Cl to Cl ; reduced/ox. ag. Br to Br ; oxidized/red. ag.

0 4+ 0 1- 7. Si + 2F2 SiF4 Si to Si ; oxidized/red. ag F to F ; reduced/ox. ag.

0 2+ 1+ 0 9. Mg + 2HCl MgCl2 + H2 Mg to Mg ; oxidized/red. ag. H to H ; reduced/o.a.

0 1+ 1+ 0 10. 2Na + 2H2O 2NaOH + H2 Na to Na ; oxidized/r.a. H to H ; reduced/o.a. --- 11. Give the oxidation number of each kind of atom or ion. a. sulfate b. Sn c. S2- d. Fe3+ e. Sn4+ f. nitrate g. ammonium 2- 0 2- 3+ 4+ 1- 1+

12. Calculate the oxidation number of chromium in each of the following.

a. Cr2O3 b. Na2Cr2O7 c. CrSO4 d. chromate e. dichromate 3+ 6+ 2+ 7+ 6+

13. Use the changes in oxidation numbers to determine which elements are oxidized and which are reduced in these reactions. (Note: it is not necessary to use balanced equations) 0 4+ 6+ 4+ a. C + H2SO4 CO2 + SO2 + H2O C to C ; oxidized S to S ; reduced

5+ 2+ 1- 0 b. HNO3 + HI NO + I2 + H2O N to N ; reduced I to I ; oxidized

7+ 2+ c. KMnO4 + HCl MnCl2 + Cl2 + H2O + KCl Mn to Mn ; reduced Cl1- to Cl0; oxidized 0 3+ 5+ 2+ d. Sb + HNO3 Sb2O3 + NO + H2O Sb to Sb ; oxidized N to N ; red. 14. For each reaction in problem 13, identify the oxidizing agent and reducing agent. a. oxidizing agent: reducing agent: carbon b. oxidizing agent: nitrogen reducing agent: c. oxidizing agent: manganese reducing agent: d. oxidizing agent: nitrogen reducing agent: antimony