Meaning of the Wave Function
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Unit 1 Old Quantum Theory
UNIT 1 OLD QUANTUM THEORY Structure Introduction Objectives li;,:overy of Sub-atomic Particles Earlier Atom Models Light as clectromagnetic Wave Failures of Classical Physics Black Body Radiation '1 Heat Capacity Variation Photoelectric Effect Atomic Spectra Planck's Quantum Theory, Black Body ~diation. and Heat Capacity Variation Einstein's Theory of Photoelectric Effect Bohr Atom Model Calculation of Radius of Orbits Energy of an Electron in an Orbit Atomic Spectra and Bohr's Theory Critical Analysis of Bohr's Theory Refinements in the Atomic Spectra The61-y Summary Terminal Questions Answers 1.1 INTRODUCTION The ideas of classical mechanics developed by Galileo, Kepler and Newton, when applied to atomic and molecular systems were found to be inadequate. Need was felt for a theory to describe, correlate and predict the behaviour of the sub-atomic particles. The quantum theory, proposed by Max Planck and applied by Einstein and Bohr to explain different aspects of behaviour of matter, is an important milestone in the formulation of the modern concept of atom. In this unit, we will study how black body radiation, heat capacity variation, photoelectric effect and atomic spectra of hydrogen can be explained on the basis of theories proposed by Max Planck, Einstein and Bohr. They based their theories on the postulate that all interactions between matter and radiation occur in terms of definite packets of energy, known as quanta. Their ideas, when extended further, led to the evolution of wave mechanics, which shows the dual nature of matter -
Arxiv:1206.1084V3 [Quant-Ph] 3 May 2019
Overview of Bohmian Mechanics Xavier Oriolsa and Jordi Mompartb∗ aDepartament d'Enginyeria Electr`onica, Universitat Aut`onomade Barcelona, 08193, Bellaterra, SPAIN bDepartament de F´ısica, Universitat Aut`onomade Barcelona, 08193 Bellaterra, SPAIN This chapter provides a fully comprehensive overview of the Bohmian formulation of quantum phenomena. It starts with a historical review of the difficulties found by Louis de Broglie, David Bohm and John Bell to convince the scientific community about the validity and utility of Bohmian mechanics. Then, a formal explanation of Bohmian mechanics for non-relativistic single-particle quantum systems is presented. The generalization to many-particle systems, where correlations play an important role, is also explained. After that, the measurement process in Bohmian mechanics is discussed. It is emphasized that Bohmian mechanics exactly reproduces the mean value and temporal and spatial correlations obtained from the standard, i.e., `orthodox', formulation. The ontological characteristics of the Bohmian theory provide a description of measurements in a natural way, without the need of introducing stochastic operators for the wavefunction collapse. Several solved problems are presented at the end of the chapter giving additional mathematical support to some particular issues. A detailed description of computational algorithms to obtain Bohmian trajectories from the numerical solution of the Schr¨odingeror the Hamilton{Jacobi equations are presented in an appendix. The motivation of this chapter is twofold. -
The Concept of Quantum State : New Views on Old Phenomena Michel Paty
The concept of quantum state : new views on old phenomena Michel Paty To cite this version: Michel Paty. The concept of quantum state : new views on old phenomena. Ashtekar, Abhay, Cohen, Robert S., Howard, Don, Renn, Jürgen, Sarkar, Sahotra & Shimony, Abner. Revisiting the Founda- tions of Relativistic Physics : Festschrift in Honor of John Stachel, Boston Studies in the Philosophy and History of Science, Dordrecht: Kluwer Academic Publishers, p. 451-478, 2003. halshs-00189410 HAL Id: halshs-00189410 https://halshs.archives-ouvertes.fr/halshs-00189410 Submitted on 20 Nov 2007 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. « The concept of quantum state: new views on old phenomena », in Ashtekar, Abhay, Cohen, Robert S., Howard, Don, Renn, Jürgen, Sarkar, Sahotra & Shimony, Abner (eds.), Revisiting the Foundations of Relativistic Physics : Festschrift in Honor of John Stachel, Boston Studies in the Philosophy and History of Science, Dordrecht: Kluwer Academic Publishers, 451-478. , 2003 The concept of quantum state : new views on old phenomena par Michel PATY* ABSTRACT. Recent developments in the area of the knowledge of quantum systems have led to consider as physical facts statements that appeared formerly to be more related to interpretation, with free options. -
Walther Nernst, Albert Einstein, Otto Stern, Adriaan Fokker
Walther Nernst, Albert Einstein, Otto Stern, Adriaan Fokker, and the Rotational Specific Heat of Hydrogen Clayton Gearhart St. John’s University (Minnesota) Max-Planck-Institut für Wissenschaftsgeschichte Berlin July 2007 1 Rotational Specific Heat of Hydrogen: Widely investigated in the old quantum theory Nernst Lorentz Eucken Einstein Ehrenfest Bohr Planck Reiche Kemble Tolman Schrödinger Van Vleck Some of the more prominent physicists and physical chemists who worked on the specific heat of hydrogen through the mid-1920s. See “The Rotational Specific Heat of Molecular Hydrogen in the Old Quantum Theory” http://faculty.csbsju.edu/cgearhart/pubs/sel_pubs.htm (slide show) 2 Rigid Rotator (Rotating dumbbell) •The rigid rotator was among the earliest problems taken up in the old (pre-1925) quantum theory. • Applications: Molecular spectra, and rotational contri- bution to the specific heat of molecular hydrogen • The problem should have been simple Molecular • relatively uncomplicated theory spectra • only one adjustable parameter (moment of inertia) • Nevertheless, no satisfactory theoretical description of the specific heat of hydrogen emerged in the old quantum theory Our story begins with 3 Nernst’s Heat Theorem Walther Nernst 1864 – 1941 • physical chemist • studied with Boltzmann • 1889: lecturer, then professor at Göttingen • 1905: professor at Berlin Nernst formulated his heat theorem (Third Law) in 1906, shortly after appointment as professor in Berlin. 4 Nernst’s Heat Theorem and Quantum Theory • Initially, had nothing to do with quantum theory. • Understand the equilibrium point of chemical reactions. • Nernst’s theorem had implications for specific heats at low temperatures. • 1906–1910: Nernst and his students undertook extensive measurements of specific heats of solids at low (down to liquid hydrogen) temperatures. -
Entanglement of the Uncertainty Principle
Open Journal of Mathematics and Physics | Volume 2, Article 127, 2020 | ISSN: 2674-5747 https://doi.org/10.31219/osf.io/9jhwx | published: 26 Jul 2020 | https://ojmp.org EX [original insight] Diamond Open Access Entanglement of the Uncertainty Principle Open Quantum Collaboration∗† August 15, 2020 Abstract We propose that position and momentum in the uncertainty principle are quantum entangled states. keywords: entanglement, uncertainty principle, quantum gravity The most updated version of this paper is available at https://osf.io/9jhwx/download Introduction 1. [1] 2. Logic leads us to conclude that quantum gravity–the theory of quan- tum spacetime–is the description of entanglement of the quantum states of spacetime and of the extra dimensions (if they really ex- ist) [2–7]. ∗All authors with their affiliations appear at the end of this paper. †Corresponding author: [email protected] | Join the Open Quantum Collaboration 1 Quantum Gravity 3. quantum gravity quantum spacetime entanglement of spacetime 4. Quantum spaceti=me might be in a sup=erposition of the extra dimen- sions [8]. Notation 5. UP Uncertainty Principle 6. UP= the quantum state of the uncertainty principle ∣ ⟩ = Discussion on the notation 7. The universe is mathematical. 8. The uncertainty principle is part of our universe, thus, it is described by mathematics. 9. A physical theory must itself be described within its own notation. 10. Thereupon, we introduce UP . ∣ ⟩ Entanglement 11. UP α1 x1p1 α2 x2p2 α3 x3p3 ... 12. ∣xi ⟩u=ncer∣tainty⟩ +in po∣ sitio⟩n+ ∣ ⟩ + 13. pi = uncertainty in momentum 14. xi=pi xi pi xi pi ∣ ⟩ = ∣ ⟩ ∣ ⟩ = ∣ ⟩ ⊗ ∣ ⟩ 2 Final Remarks 15. -
Path Integral for the Hydrogen Atom
Path Integral for the Hydrogen Atom Solutions in two and three dimensions Vägintegral för Väteatomen Lösningar i två och tre dimensioner Anders Svensson Faculty of Health, Science and Technology Physics, Bachelor Degree Project 15 ECTS Credits Supervisor: Jürgen Fuchs Examiner: Marcus Berg June 2016 Abstract The path integral formulation of quantum mechanics generalizes the action principle of classical mechanics. The Feynman path integral is, roughly speaking, a sum over all possible paths that a particle can take between fixed endpoints, where each path contributes to the sum by a phase factor involving the action for the path. The resulting sum gives the probability amplitude of propagation between the two endpoints, a quantity called the propagator. Solutions of the Feynman path integral formula exist, however, only for a small number of simple systems, and modifications need to be made when dealing with more complicated systems involving singular potentials, including the Coulomb potential. We derive a generalized path integral formula, that can be used in these cases, for a quantity called the pseudo-propagator from which we obtain the fixed-energy amplitude, related to the propagator by a Fourier transform. The new path integral formula is then successfully solved for the Hydrogen atom in two and three dimensions, and we obtain integral representations for the fixed-energy amplitude. Sammanfattning V¨agintegral-formuleringen av kvantmekanik generaliserar minsta-verkanprincipen fr˚anklassisk meka- nik. Feynmans v¨agintegral kan ses som en summa ¨over alla m¨ojligav¨agaren partikel kan ta mellan tv˚a givna ¨andpunkterA och B, d¨arvarje v¨agbidrar till summan med en fasfaktor inneh˚allandeden klas- siska verkan f¨orv¨agen.Den resulterande summan ger propagatorn, sannolikhetsamplituden att partikeln g˚arfr˚anA till B. -
Two-State Systems
1 TWO-STATE SYSTEMS Introduction. Relative to some/any discretely indexed orthonormal basis |n) | ∂ | the abstract Schr¨odinger equation H ψ)=i ∂t ψ) can be represented | | | ∂ | (m H n)(n ψ)=i ∂t(m ψ) n ∂ which can be notated Hmnψn = i ∂tψm n H | ∂ | or again ψ = i ∂t ψ We found it to be the fundamental commutation relation [x, p]=i I which forced the matrices/vectors thus encountered to be ∞-dimensional. If we are willing • to live without continuous spectra (therefore without x) • to live without analogs/implications of the fundamental commutator then it becomes possible to contemplate “toy quantum theories” in which all matrices/vectors are finite-dimensional. One loses some physics, it need hardly be said, but surprisingly much of genuine physical interest does survive. And one gains the advantage of sharpened analytical power: “finite-dimensional quantum mechanics” provides a methodological laboratory in which, not infrequently, the essentials of complicated computational procedures can be exposed with closed-form transparency. Finally, the toy theory serves to identify some unanticipated formal links—permitting ideas to flow back and forth— between quantum mechanics and other branches of physics. Here we will carry the technique to the limit: we will look to “2-dimensional quantum mechanics.” The theory preserves the linearity that dominates the full-blown theory, and is of the least-possible size in which it is possible for the effects of non-commutivity to become manifest. 2 Quantum theory of 2-state systems We have seen that quantum mechanics can be portrayed as a theory in which • states are represented by self-adjoint linear operators ρ ; • motion is generated by self-adjoint linear operators H; • measurement devices are represented by self-adjoint linear operators A. -
Analysis of Nonlinear Dynamics in a Classical Transmon Circuit
Analysis of Nonlinear Dynamics in a Classical Transmon Circuit Sasu Tuohino B. Sc. Thesis Department of Physical Sciences Theoretical Physics University of Oulu 2017 Contents 1 Introduction2 2 Classical network theory4 2.1 From electromagnetic fields to circuit elements.........4 2.2 Generalized flux and charge....................6 2.3 Node variables as degrees of freedom...............7 3 Hamiltonians for electric circuits8 3.1 LC Circuit and DC voltage source................8 3.2 Cooper-Pair Box.......................... 10 3.2.1 Josephson junction.................... 10 3.2.2 Dynamics of the Cooper-pair box............. 11 3.3 Transmon qubit.......................... 12 3.3.1 Cavity resonator...................... 12 3.3.2 Shunt capacitance CB .................. 12 3.3.3 Transmon Lagrangian................... 13 3.3.4 Matrix notation in the Legendre transformation..... 14 3.3.5 Hamiltonian of transmon................. 15 4 Classical dynamics of transmon qubit 16 4.1 Equations of motion for transmon................ 16 4.1.1 Relations with voltages.................. 17 4.1.2 Shunt resistances..................... 17 4.1.3 Linearized Josephson inductance............. 18 4.1.4 Relation with currents................... 18 4.2 Control and read-out signals................... 18 4.2.1 Transmission line model.................. 18 4.2.2 Equations of motion for coupled transmission line.... 20 4.3 Quantum notation......................... 22 5 Numerical solutions for equations of motion 23 5.1 Design parameters of the transmon................ 23 5.2 Resonance shift at nonlinear regime............... 24 6 Conclusions 27 1 Abstract The focus of this thesis is on classical dynamics of a transmon qubit. First we introduce the basic concepts of the classical circuit analysis and use this knowledge to derive the Lagrangians and Hamiltonians of an LC circuit, a Cooper-pair box, and ultimately we derive Hamiltonian for a transmon qubit. -
Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Emma Wikberg Project work, 4p Department of Physics Stockholm University 23rd March 2006 Abstract The method of Path Integrals (PI’s) was developed by Richard Feynman in the 1940’s. It offers an alternate way to look at quantum mechanics (QM), which is equivalent to the Schrödinger formulation. As will be seen in this project work, many "elementary" problems are much more difficult to solve using path integrals than ordinary quantum mechanics. The benefits of path integrals tend to appear more clearly while using quantum field theory (QFT) and perturbation theory. However, one big advantage of Feynman’s formulation is a more intuitive way to interpret the basic equations than in ordinary quantum mechanics. Here we give a basic introduction to the path integral formulation, start- ing from the well known quantum mechanics as formulated by Schrödinger. We show that the two formulations are equivalent and discuss the quantum mechanical interpretations of the theory, as well as the classical limit. We also perform some explicit calculations by solving the free particle and the harmonic oscillator problems using path integrals. The energy eigenvalues of the harmonic oscillator is found by exploiting the connection between path integrals, statistical mechanics and imaginary time. Contents 1 Introduction and Outline 2 1.1 Introduction . 2 1.2 Outline . 2 2 Path Integrals from ordinary Quantum Mechanics 4 2.1 The Schrödinger equation and time evolution . 4 2.2 The propagator . 6 3 Equivalence to the Schrödinger Equation 8 3.1 From the Schrödinger equation to PI’s . 8 3.2 From PI’s to the Schrödinger equation . -
Structure of a Spin ½ B
Structure of a spin ½ B. C. Sanctuary Department of Chemistry, McGill University Montreal Quebec H3H 1N3 Canada Abstract. The non-hermitian states that lead to separation of the four Bell states are examined. In the absence of interactions, a new quantum state of spin magnitude 1/√2 is predicted. Properties of these states show that an isolated spin is a resonance state with zero net angular momentum, consistent with a point particle, and each resonance corresponds to a degenerate but well defined structure. By averaging and de-coherence these structures are shown to form ensembles which are consistent with the usual quantum description of a spin. Keywords: Bell states, Bell’s Inequalities, spin theory, quantum theory, statistical interpretation, entanglement, non-hermitian states. PACS: Quantum statistical mechanics, 05.30. Quantum Mechanics, 03.65. Entanglement and quantum non-locality, 03.65.Ud 1. INTRODUCTION In spite of its tremendous success in describing the properties of microscopic systems, the debate over whether quantum mechanics is the most fundamental theory has been going on since its inception1. The basic property of quantum mechanics that belies it as the most fundamental theory is its statistical nature2. The history is well known: EPR3 showed that two non-commuting operators are simultaneously elements of physical reality, thereby concluding that quantum mechanics is incomplete, albeit they assumed locality. Bohr4 replied with complementarity, arguing for completeness; thirty years later Bell5, questioned the locality assumption6, and the conclusion drawn that any deeper theory than quantum mechanics must be non-local. In subsequent years the idea that entangled states can persist to space-like separations became well accepted7. -
Hamilton Equations, Commutator, and Energy Conservation †
quantum reports Article Hamilton Equations, Commutator, and Energy Conservation † Weng Cho Chew 1,* , Aiyin Y. Liu 2 , Carlos Salazar-Lazaro 3 , Dong-Yeop Na 1 and Wei E. I. Sha 4 1 College of Engineering, Purdue University, West Lafayette, IN 47907, USA; [email protected] 2 College of Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61820, USA; [email protected] 3 Physics Department, University of Illinois at Urbana-Champaign, Urbana, IL 61820, USA; [email protected] 4 College of Information Science and Electronic Engineering, Zhejiang University, Hangzhou 310058, China; [email protected] * Correspondence: [email protected] † Based on the talk presented at the 40th Progress In Electromagnetics Research Symposium (PIERS, Toyama, Japan, 1–4 August 2018). Received: 12 September 2019; Accepted: 3 December 2019; Published: 9 December 2019 Abstract: We show that the classical Hamilton equations of motion can be derived from the energy conservation condition. A similar argument is shown to carry to the quantum formulation of Hamiltonian dynamics. Hence, showing a striking similarity between the quantum formulation and the classical formulation. Furthermore, it is shown that the fundamental commutator can be derived from the Heisenberg equations of motion and the quantum Hamilton equations of motion. Also, that the Heisenberg equations of motion can be derived from the Schrödinger equation for the quantum state, which is the fundamental postulate. These results are shown to have important bearing for deriving the quantum Maxwell’s equations. Keywords: quantum mechanics; commutator relations; Heisenberg picture 1. Introduction In quantum theory, a classical observable, which is modeled by a real scalar variable, is replaced by a quantum operator, which is analogous to an infinite-dimensional matrix operator. -
Revisiting Online Quantum State Learning
The Thirty-Fourth AAAI Conference on Artificial Intelligence (AAAI-20) Revisiting Online Quantum State Learning Feidiao Yang, Jiaqing Jiang, Jialin Zhang, Xiaoming Sun Institute of Computing Technology, Chinese Academy of Sciences, Bejing, China University of Chinese Academy of Sciences, Beijing, China {yangfeidiao, jiangjiaqing, zhangjialin, sunxiaoming}@ict.ac.cn Abstract theories may also help solve some interesting problems in quantum computation and quantum information (Carleo and In this paper, we study the online quantum state learn- Troyer 2017). In this paper, we apply the online learning the- ing problem which is recently proposed by Aaronson et al. (2018). In this problem, the learning algorithm sequentially ory to solve an interesting problem of learning an unknown predicts quantum states based on observed measurements and quantum state. losses and the goal is to minimize the regret. In the previ- Learning an unknown quantum state is a fundamental ous work, the existing algorithms may output mixed quan- problem in quantum computation and quantum information. tum states. However, in many scenarios, the prediction of a The basic version is the quantum state tomography prob- pure quantum state is required. In this paper, we first pro- lem (Vogel and Risken 1989), which aims to fully recover pose a Follow-the-Perturbed-Leader (FTPL) algorithm that the classical description of an unknown quantum state. Al- can guarantee to predict pure quantum states. Theoretical√ O( T ) though quantum state tomography gives a complete char- analysis shows that our algorithm can achieve an ex- acterization of the target state, it is quite costly. Recent pected regret under some reasonable settings.