Deuteron and Antideuteron Production in Galactic Cosmic-Rays

Total Page:16

File Type:pdf, Size:1020Kb

Deuteron and Antideuteron Production in Galactic Cosmic-Rays UNIVERSIDAD NACIONAL AUTONOMA´ DE MEXICO´ POSGRADO EN CIENCIAS F´ISICAS INSTITUTO DE F´ISICA Deuteron and antideuteron production in galactic cosmic-rays Tesis QUE PARA OPTAR POR EL GRADO DE: DOCTOR EN CIENCIAS (F´ISICA) PRESENTA: Diego Mauricio G´omezCoral TUTOR PRINCIPAL: Dr. Arturo Alejandro Menchaca Rocha Instituto de F´ısica CERN-THESIS-2019-034 26/04/2019 MIEMBROS DEL COMITE´ TUTOR: Dr. Varlen Grabski Instituto de F´ısica Dr. Andr´esSandoval Espinosa Instituto de F´ısica CIUDAD DE MEXICO´ 29 de abril de 2019 Producci´onde deuterio y antideuterio en rayos c´osmicosgal´acticos Diego Mauricio G´omezCoral 29 de abril de 2019 To my beloved family: Glorita, Hernando, Carito, and Mart´ın. Abstract The increasing role of antideuterons in the indirect search for dark matter and new cosmic-ray propagation features from deuterons have generated that the study of the cosmic-ray deuteron and antideuteron receives an increasing interest in current astrophysics investigations. To de- termine such fluxes precisely, it is necessary to consider the contribution from the nuclear in- teractions of primary cosmic rays with the interstellar matter. For that purpose, in this thesis, the production of cosmic-ray deuterons and antideuterons in the Galaxy is calculated using advanced Monte Carlo (MC) generators and an updated database of collider measurements. Deuteron and antideuteron production in hadron interactions is modeled through the coa- lescence model, which has demonstrated to reproduce data successfully. The coalescence mech- anism is simulated with an event-by-event afterburner in tandem with MC generators such as EPOS-LHC, QGSJET-II-04, and FTFP-GEANT4. These estimates depend on a single parame- ter (p0) obtained from a fit to the latest collider data, including ALICE-LHC current results. It was found that p0 for antideuterons is not a constant at all energies as previous works suggested, and as a result, the antideuteron production cross section can be at least 20 times smaller in the low collision energy region than earlier estimations. CR deuterons and antideuterons propagation in the Galaxy is calculated using GALPROP, along with a set of parameters that fit AMS-02 latest observations in proton, Helium and Boron- to-Carbon ratio. The resulting antideuteron flux, employing EPOS-LHC, shows a larger mag- nitude compared to previous studies and a slightly different shape in the energy distribution as a consequence of the coalescence parameter (p0) energy dependence. Deuteron flux evaluation with QGSJET-II-04 shows an improved description of measurements at high energy compared to the result without considering coalescence. A simulation of the antideuteron production in AMS-02 as a consequence of CR collisions with the detector materials was conducted. It was concluded, that it is unlikely an antideuteron generated in the detector can be misidentified as an antideuteron from an external source in the lifetime of AMS-02 operations. iii iv Resumen El creciente inter´esen la b´usquedaindirecta de materia oscura a trav´esde la detecci´onde antideuterones, as´ıcomo la posibilidad de encontrar nuevas caracter´ısticasen la propagaci´onde rayos c´osmicosen la galaxia usando la raz´onentre deuterones y helio, motivan la realizaci´on de este trabajo. En este contexto, se vuelve fundamental entender y calcular con las her- ramientas m´asmodernas y con los conocimientos m´asrecientes la producci´onde deuterones y antideuterones a trav´esde colisiones nucleares entre los rayos c´osmicosprimarios y el medio inter- estelar. Por estos motivos en este trabajo se estima la producci´onde deuterones y antideuterones en la galaxia usando generadores Monte Carlo (MC) y una base de datos actualizada de medidas realizadas en experimentos sobre colisiones de part´ıculas. La producci´onde deuterones y antideuterones en la galaxia se describe con el modelo de coalescencia, el cual a demostrado ser acertado en la predicci´onde los datos experimentales. La implementaci´onde la simulaci´ondel modelo de coalescencia se realiza usando un gratinador o \afterburner", en conjunto con los generadores Monte Carlo (EPOS-LHC, QGSJET-II-04 y FTFP-GEANT4). Las predicciones de la simulaci´ondependen de un solo par´ametro,el momento de coalescencia (p0), el cual se obtiene de los datos sobre colisiones incluyendo los resultados actuales de ALICE-LHC. En este trabajo se encontr´oque para antideuterones p0 no es constante a todas las energ´ıascomo se afirmaba en trabajos previos. Como consecuencia, la secci´oneficaz de producci´onde antideuterones puede llegar a ser 20 veces menor a lo encontrado anteriormente en la regi´onde baja energ´ıa. La propagaci´onde deuterones y antideuterones en la galaxia fue calculada con GALPROP, usando par´ametrosque fueron ajustados a datos recientes del experimento AMS-02. El flujo de antideuterones estimado con EPOS-LHC, muestra una magnitud mayor comparada con c´alculos anteriores, as´ı como tambi´enuna forma ligeramente diferente en la distribuci´onde energ´ıa. Dicha diferencia es consecuencia de p0 y su dependencia con la energ´ıa.Por otro lado, el flujo de deuterones en rayos c´osmicoscalculado con QGSJET-II-04 y el modelo de coalescencia describe apropiadamente los datos a altas energ´ıas. Por ´ultimo,se realiz´ouna simulaci´onde la producci´onde antideuterones en AMS-02 como consecuencia de las colisiones de rayos c´osmicoscon los materiales del detector. Se concluy´o que es muy poco probable que un antideuteron producido en el detector se confunda con un antideuteron proveniente de la Galaxia durante el tiempo de operaci´onde AMS-02. v vi Acknowledgments I want to express my sincere gratitude to my advisor Prof. Arturo Menchaca for his continuous support developing ideas for the construction of this work, as well as his comments, critics and corrections to this manuscript. Furthermore, I thank him for encouraging me to recognize my abilities and to pursue a research career. My sincere thanks also goes to the rest of my advisor committee: Prof. Andr´esSandoval and especially Prof. Varlen Grabski, who helped me many times to solve arising questions during the elaboration of this work. Besides, I want also to thank the thesis evaluation committee: Dra. Irais Bautista, Dra. Catalina Espinoza, Dr. Gustavo Medina Tanco, and Dr. Jos´eVald´es. I am also grateful to the cosmic-ray group at the University of Hawaii at Manoa led by Prof. Philip von Doetinchem, and its members Dr. Amaresh Datta, and Anirvan Shukla. A special mention to the computation department of the Institute of Physics, UNAM in particular to Carlos Ernesto L´opez Natar´en.I also thank T. Pierog, C. Baus, and R. Ulrich for providing the Cosmic Ray Monte Carlo package and for answering my questions about the program. The GALPROP team for allowing me to use and to edit the propagation code. Vladimir Uzhinskii and Dennis Wright who observed and commented on some of the results from this work and made suggestions about the afterburner implementation in GEANT4. I gratefully acknowledge the financial support by CONACyT through a Ph.D. fellowship and PNPC project, and by UNAM projects: PAPIIT-DGAPA IN109617 and PAEP. A special men- tion to the institutions involved and their people: Instituto de F´ısica(IFUNAM) and Posgrado en Ciencias F´ısicasUNAM (PCF). My gratitude goes to the ALICE and AMS-02 collabora- tions for allowing me to participate in such amazing experiments and to show me a universe of knowledge and exciting open questions in particle physics and astrophysics from which I am still learning. Last but by no means the least, I would like to thank my family: Glorita, Hernando, Carito y Mart´ınfor their unconditional love and support during my studies and in my life. Special gratitude to my Colombian friends: Tatiana, Juano and Myriam. To all my friends and col- leagues who made my stay in Mexico a wonderful experience. Among them, los lovers: Guerito, Gusi, Cesar, Vladis, R2, Yorch, Peter, Jefe, Miguelover, Javier, Richi y Sult´an.Los del ciruelo: Francisco, Richard, Rafa, and Chava. My friends from the institute: Karina, David, Mario, Mariana, To~no,Javi, Zu~niga,Bora, and Sa´ul. Diego G´omez Mexico City, April 2019 vii viii Agradecimientos Agradezco profundamente a mi asesor el Dr. Arturo Menchaca por su constante apoyo en el desarrollo de ideas para la construcci´onde este trabajo, as´ıcomo su ayuda en la revisi´ony correcci´ondel mismo en varias etapas de su elaboraci´on.Tambi´enagradezco la motivaci´onque me ha transmitido para continuar un proceso acad´emico y de investigaci´on.Adem´as,agradezco a los dem´asmiembros del comit´etutor Dr. Andr´esSandoval Espinoza y especialmente al Dr. Varlen Grabski con quien acud´ınumerosas veces para consultarle inquietudes que surg´ıandurante el desarrollo del trabajo. Adem´as,quiero agradecer a los miembros del jurado evaluador: Dra. Irais Bautista, Dra. Catalina Espinoza, Dr. Gustavo Medina Tanco, y Dr. Jos´eVald´es. Tambi´enquiero expresar mi gratitud al grupo de rayos c´osmicos de la universidad de Hawaii encabezado por el Dr. Philip von Doetinchem, y sus miembros Dr. Amaresh Datta y Anirvan Shukla. Al grupo de computaci´oncient´ıfica del Instituto de F´ısica, especialmente a Carlos Ernesto L´opez Natar´en. Igualmente agradezco a T. Pierog, C. Baus, and R. Ulrich por facil- itarme el programa CRMC y resolver algunas dudas acerca de su funcionamiento, tambi´enal equipo de GALPROP por suministrar el c´odigoque se utiliz´oen este estudio. A Vladimir Uzhin- skii y Dennis Wright quienes tuvieron la amabilidad de observar y criticar algunos resultados de este trabajo as´ıcomo hacer sugerencias sobre la implementaci´ondel afterburner en GEANT4. Agradezco igualmente el apoyo financiero brindado por CONACyT a trav´esde la beca para doctorado nacional, a la UNAM con el proyecto PAPIIT-DGAPA: IN109617 y los apoyos PAEP y PNPC.
Recommended publications
  • The Primordial Earth: Hadean and Archean Eons
    5th International Symposium on Strong Electromagnetic Fields and Neutron Stars 10 –13 of May, 2017 -Varadero, Cuba HABITABILITY OF THE MILKY WAY REVISITED Rolando Cárdenas and Rosmery Nodarse-Zulueta e-mail: [email protected] Planetary Science Laboratory Universidad Central “Marta Abreu” de Las Villas, Santa Clara, Cuba Abstract • The discoveries of the last three decades on deep sea and deep crust of planet Earth show that life can thrive in many places where solar radiation does not reach, using chemosynthesis instead of photosynthesis for primary production. • Underground life is relatively well protected from hazardous ionizing cosmic radiation, so above mentioned discoveries reopen the habitability budget of the Milky Way, turning potentially habitable even planetary bodies without atmosphere. • Considering this, in this work the habitability potential of the Milky Way is reconsidered. Energy Sources for Primary Habitability: - Photosynthesis: Electromagnetic Waves, mostly in the range 400-700 nm. Dominant in planetary surface. - Chemosynthesis: Energy released by redox chemical reactions. Dominant in deep sea and crust. Circumstellar Habitable Zone https://en.wikipedia.org/wiki/Circumstellar_habitable_zone. Accessed on 2017.04.28 Liquid water at surface: biased towards surface (photosynthetic) life Chemosynthesis: More common than previously thought… - Any redox process giving at least 20 kJ/mol of free energy can support microbial metabolism. The following gives 794 kJ/mol: Pohlman, J.: The biogeochemistry of anchialine caves:
    [Show full text]
  • SIDE GROUP ADDITION to the POLYCYCLIC AROMATIC HYDROCARBON CORONENE by PROTON IRRADIATION in COSMIC ICE ANALOGS Max P
    The Astrophysical Journal, 582:L25–L29, 2003 January 1 ᭧ 2003. The American Astronomical Society. All rights reserved. Printed in U.S.A. SIDE GROUP ADDITION TO THE POLYCYCLIC AROMATIC HYDROCARBON CORONENE BY PROTON IRRADIATION IN COSMIC ICE ANALOGS Max P. Bernstein,1,2 Marla H. Moore,3 Jamie E. Elsila,4 Scott A. Sandford,2 Louis J. Allamandola,2 and Richard N. Zare4 Received 2002 July 23; accepted 2002 November 5; published 2002 December 6 ABSTRACT ∼ Ices at 15 K consisting of the polycyclic aromatic hydrocarbon coronene (C24H12) condensed either with H2O, CO2, or CO in the ratio of 1 : 100 or greater have been subjected to MeV proton bombardment from a Van de Graaff generator. The resulting reaction products have been examined by infrared transmission- reflection-transmission spectroscopy and by microprobe laser-desorption laser-ionization mass spectrometry. Just as in the case of UV photolysis, oxygen atoms are added to coronene, yielding, in the case of H2O ices, the addition of one or more alcohol (i OH) and ketone (1CuO) side chains to the coronene scaffolding. There are, however, significant differences between the products formed by proton irradiation and the products formed by UV photolysis of coronene containing CO and CO2 ices. The formation of a coronene carboxylic i acid ( COOH) by proton irradiation is facile in solid CO but not in CO2, the reverse of what was previously observed for UV photolysis under otherwise identical conditions. This work presents evidence that cosmic- ray irradiation of interstellar or cometary ices should have contributed to the formation of aromatics bearing ketone and carboxylic acid functional groups in primitive meteorites and interplanetary dust particles.
    [Show full text]
  • Deuterium – Tritium Pulse Propulsion with Hydrogen As Propellant and the Entire Space-Craft As a Gigavolt Capacitor for Ignition
    Deuterium – Tritium pulse propulsion with hydrogen as propellant and the entire space-craft as a gigavolt capacitor for ignition. By F. Winterberg University of Nevada, Reno Abstract A deuterium-tritium (DT) nuclear pulse propulsion concept for fast interplanetary transport is proposed utilizing almost all the energy for thrust and without the need for a large radiator: 1. By letting the thermonuclear micro-explosion take place in the center of a liquid hydrogen sphere with the radius of the sphere large enough to slow down and absorb the neutrons of the DT fusion reaction, heating the hydrogen to a fully ionized plasma at a temperature of ~ 105 K. 2. By using the entire spacecraft as a magnetically insulated gigavolt capacitor, igniting the DT micro-explosion with an intense GeV ion beam discharging the gigavolt capacitor, possible if the space craft has the topology of a torus. 1. Introduction The idea to use the 80% of the neutron energy released in the DT fusion reaction for nuclear micro-bomb rocket propulsion, by surrounding the micro-explosion with a thick layer of liquid hydrogen heated up to 105 K thereby becoming part of the exhaust, was first proposed by the author in 1971 [1]. Unlike the Orion pusher plate concept, the fire ball of the fully ionized hydrogen plasma can here be reflected by a magnetic mirror. The 80% of the energy released into 14MeV neutrons cannot be reflected by a magnetic mirror for thermonuclear micro-bomb propulsion. This was the reason why for the Project Daedalus interstellar probe study of the British Interplanetary Society [2], the neutron poor deuterium-helium 3 (DHe3) reaction was chosen.
    [Show full text]
  • Investigation of the Use of Deuterium and Oxygen in Illicit Fentanyl Analysis Author(S): John F
    The author(s) shown below used Federal funding provided by the U.S. Department of Justice to prepare the following resource: Document Title: Investigation of the Use of Deuterium and Oxygen in Illicit Fentanyl Analysis Author(s): John F. Casale, Mike Lott, Jennifer R. Mallette Document Number: 255103 Date Received: August 2020 Award Number: NIJ-ONDCP IAA: 2017 DEA contract research task This resource has not been published by the U.S. Department of Justice. This resource is being made publically available through the Office of Justice Programs’ National Criminal Justice Reference Service. Opinions or points of view expressed are those of the author(s) and do not necessarily reflect the official position or policies of the U.S. Department of Justice. Investigation of the Use of Deuterium and Oxygen in Illicit Fentanyl Analysis John F. Casalea, Mike Lottb, and Jennifer R. Mallettea aU.S. Drug Enforcement Administration Special Testing and Research Laboratory Dulles, VA bIsoForensics, Inc. Salt Lake City, UT 84108 This work was conducted through an Inter-Agency Agreement dated June 28, 2017, between the Office of National Drug Control Policy (ONDCP) and the National Institute of Justice (NIJ), under DEA Contract number 15DDHQ18P00000344 with funding from the NIJ, Office of Justice Programs, U.S. Department of Justice. The opinions, findings, and conclusions or recommendations expressed in this publication/program/exhibition are those of the authors, and do not necessarily reflect those of the Department of Justice or ONDCP. This resource was prepared by the author(s) using Federal funds provided by the U.S. Department of Justice.
    [Show full text]
  • Cosmic-Ray Soil Water Monitoring: the Development, Status & Potential of the COSMOS- India Network Ross Morrison, J
    Cosmic-ray soil water monitoring: the development, status & potential of the COSMOS- India network Ross Morrison, J. G. Evans, S. S. Angadi, L. Ball, T. Chakraborty, H. Cooper, M. Fry, G. Geet, M. Goswami, N. Ganeshi, O. Hitt, S. Jain, M. Krishnan, R. Krishnan, A. Kumar, M. Mujumdar, M. Nema, G. Rees, M. Sekhar, O. Swain, R. Thayyen, S. Tripathi, D. Upadhyaya & A. Jenkins COSMOS-India: outline o Background & rationale o Basics of measurement principle o COSMOS-India network & sites o Selected results o Future work COSMOS-India: objectives o Collaborative development of soil moisture (SM) network in India using cosmic ray (COSMOS) sensors o Deliver high temporal frequency SM observations at the intermediate spatial scale in near real-time o Development of national COSMOS-India data system & near real time data portal o Integrate with Earth Observation datasets for validated SM maps of India o Empower many other applications… Acknowledgment: other COSMOS networks cosmos.hwr.arizona.edu cosmos.ceh.ac.uk Why measure soil moisture (SM)? o Controls exchanges of energy & mass between land surface & atmosphere o Hydrology: controls evapotranspiration, partitioning between runoff & infiltration, groundwater recharge o Meteorology: partitioning solar energy into sensible, latent & soil heat fluxes, surface-boundary layer interactions o Plant growth & soil biogeochemistry https://www2.ucar.edu/atmosnews/people/aiguo-dai https://nevada.usgs.gov/water/et/measured.htm Applications of soil moisture data SM observation techniques o Challenge: SM observations at spatial & temporal resolution relevant Measuringto applications soil (e.g.moisture gridded models, content field scale) o Point scale: high temporal resolution & low cost o Issues - spatial heterogeneity & sensor placement (e.g.
    [Show full text]
  • Cosmic-Ray Studies with Experimental Apparatus at LHC
    S S symmetry Article Cosmic-Ray Studies with Experimental Apparatus at LHC Emma González Hernández 1, Juan Carlos Arteaga 2, Arturo Fernández Tellez 1 and Mario Rodríguez-Cahuantzi 1,* 1 Facultad de Ciencias Físico Matemáticas, Benemérita Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, Edif. EMA3-231, Ciudad Universitaria, 72570 Puebla, Mexico; [email protected] (E.G.H.); [email protected] (A.F.T.) 2 Instituto de Física y Matemáticas, Universidad Michoacana, 58040 Morelia, Mexico; [email protected] * Correspondence: [email protected] Received: 11 September 2020; Accepted: 2 October 2020; Published: 15 October 2020 Abstract: The study of cosmic rays with underground accelerator experiments started with the LEP detectors at CERN. ALEPH, DELPHI and L3 studied some properties of atmospheric muons such as their multiplicity and momentum. In recent years, an extension and improvement of such studies has been carried out by ALICE and CMS experiments. Along with the LHC high luminosity program some experimental setups have been proposed to increase the potential discovery of LHC. An example is the MAssive Timing Hodoscope for Ultra-Stable neutraL pArticles detector (MATHUSLA) designed for searching of Ultra Stable Neutral Particles, predicted by extensions of the Standard Model such as supersymmetric models, which is planned to be a surface detector placed 100 meters above ATLAS or CMS experiments. Hence, MATHUSLA can be suitable as a cosmic ray detector. In this manuscript the main results regarding cosmic ray studies with LHC experimental underground apparatus are summarized. The potential of future MATHUSLA proposal is also discussed. Keywords: cosmic ray physics at CERN; atmospheric muons; trigger detectors; muon bundles 1.
    [Show full text]
  • Isotopic Fractionation of Carbon, Deuterium, and Nitrogen: a Full Chemical Study?
    A&A 576, A99 (2015) Astronomy DOI: 10.1051/0004-6361/201425113 & c ESO 2015 Astrophysics Isotopic fractionation of carbon, deuterium, and nitrogen: a full chemical study? E. Roueff1;2, J. C. Loison3, and K. M. Hickson3 1 LERMA, Observatoire de Paris, PSL Research University, CNRS, UMR8112, Place Janssen, 92190 Meudon Cedex, France e-mail: [email protected] 2 Sorbonne Universités, UPMC Univ. Paris 6, 4 Place Jussieu, 75005 Paris, France 3 ISM, Université de Bordeaux – CNRS, UMR 5255, 351 cours de la Libération, 33405 Talence Cedex, France e-mail: [email protected] Received 6 October 2014 / Accepted 5 January 2015 ABSTRACT Context. The increased sensitivity and high spectral resolution of millimeter telescopes allow the detection of an increasing number of isotopically substituted molecules in the interstellar medium. The 14N/15N ratio is difficult to measure directly for molecules con- taining carbon. Aims. Using a time-dependent gas-phase chemical model, we check the underlying hypothesis that the 13C/12C ratio of nitriles and isonitriles is equal to the elemental value. Methods. We built a chemical network that contains D, 13C, and 15N molecular species after a careful check of the possible fraction- ation reactions at work in the gas phase. Results. Model results obtained for two different physical conditions that correspond to a moderately dense cloud in an early evolu- tionary stage and a dense, depleted prestellar core tend to show that ammonia and its singly deuterated form are somewhat enriched 15 14 15 + in N, which agrees with observations. The N/ N ratio in N2H is found to be close to the elemental value, in contrast to previous 15 + models that obtain a significant enrichment, because we found that the fractionation reaction between N and N2H has a barrier in + 15 + + 15 + the entrance channel.
    [Show full text]
  • Coulomb Explosion of Polycyclic Aromatic Hydrocarbons Induced by Heavy Cosmic Rays: Carbon Chains Production Rates
    Coulomb explosion of polycyclic aromatic hydrocarbons induced by heavy cosmic rays: carbon chains production rates M Chabot1 ∗, K B´eroff2, E Dartois2, and T Pino2 1Institut de Physique Nucl´eaired'Orsay (IPNO), CNRS-IN2P3, Univ. Paris Sud, Universit´eParis-Saclay, F-91406 Orsay, France 2Institut des Sciences Mol´eculairesd'Orsay (ISMO), CNRS, Univ. Paris Sud, Universit´eParis-Saclay, F-91405 Orsay, France Synopsis The interstellar medium contains both polycyclic aromatic hydrocarbons and cosmic rays. The frontal impact of a single heavy cosmic ray strips out many electrons. The highly charged species then relax by multi-fragmentation, potentially feeding the interstellar medium with hydrocarbon chains. We model both ionization(s) and fragmentation processes and compute the fragments production rates of particular interest for astrophysical models. Low energy CRs consist of projectiles from ties of Q fold ionization's for an iron projectile proton to nickel with energy from 10 keV to GeV. at 5MeV/u on a C60 is shown in Fig.1 as an ex- Astrophysical PAHs are carbons structures with ample of such calculation. cycles containing from ten's to few hundred's of To calculate the charge state above which carbon atoms. We report on the coulomb explo- the PAH multi-fragments, we used a statistical sion of highly positively charged PAHs induced model in a microcanonical formalism based on by the interstellar low energy CRs leading to the the experimental work of S. Martin [3]. The in- formation of long carbon chains. ternal energy was compute with the IAE model. To retrieve the figure of fragmentation in the 250 multi fragmentation process of the multi-charged 1 species, we extend a statistical model construct 200 initially for small multi-charged carbon Cn(n=2 150 3 to 10)[2].
    [Show full text]
  • Six Phases of Cosmic Chemistry
    Six Phases of Cosmic Chemistry Lukasz Lamza The Pontifical University of John Paul II Department of Philosophy, Chair of Philosophy of Nature Kanonicza 9, Rm. 203 31-002 Kraków, Poland e-mail: [email protected] 1. Introduction The steady development of astrophysical and cosmological sciences has led to a growing appreciation of the continuity of cosmic history throughout which all known phenomena come to being. This also includes chemical phenomena and there are numerous theoretical attempts to rewrite chemistry as a “historical” science (Haken 1978; Earley 2004). It seems therefore vital to organize the immense volume of chemical data – from astrophysical nuclear chemistry to biochemistry of living cells – in a consistent and quantitative fashion, one that would help to appreciate the unfolding of chemical phenomena throughout cosmic time. Although numerous specialist reviews exist (e.g. Shaw 2006; Herbst 2001; Hazen et al. 2008) that illustrate the growing appreciation for cosmic chemical history, several issues still need to be solved. First of all, such works discuss only a given subset of cosmic chemistry (astrochemistry, chemistry of life etc.) using the usual tools and languages of these particular disciplines which does not facilitate drawing large-scale conclusions. Second, they discuss the history of chemical structures and not chemical processes – which implicitly leaves out half of the totality chemical phenomena as non-historical. While it may now seem obvious that certain chemical structures such as aromatic hydrocarbons or pyrazines have a certain cosmic “history”, it might cause more controversy to argue that chemical processes such as catalysis or polymerization also have their “histories”.
    [Show full text]
  • And Tissue Perfusion Employing 2H20 As a Freely Diffusible Tracer (Rat Liver/Surface Coil/Spin-Lattice Relaxation/Heavy Water) JOSEPH J
    Proc. Natl. Acad. Sci. USA Vol. 84, pp. 4099-4102, June 1987 Biophysics Deuterium nuclear magnetic resonance measurements of blood flow and tissue perfusion employing 2H20 as a freely diffusible tracer (rat liver/surface coil/spin-lattice relaxation/heavy water) JOSEPH J. H. ACKERMAN*t, COLEEN S. EwY*, NANCY N. BECKER*, AND ROBERT A. SHALWITZtt *Department of Pediatrics, Washington University School of Medicine, St. Louis, MO 63110; and *Department of Chemistry, Washington University, St. Louis, MO 63130 Communicated by William D. Phillips, January 28, 1987 ABSTRACT The use of deuterium oxide (21120) is pro- We propose herein the analogous use of 2H20 as a posed as a freely diffusible nuclear magnetic resonance (NMR) diffusible blood-flow and tissue-perfusion tracer where deu- blood flow and tissue perfusion tracer of potential clinical terium NMR is used to monitor label intensity as a function utility. Deuterium is a stable, nonradiative isotope commer- of time. Deuterium is a nonradiative, naturally abundant cially available as 2H20 at enrichment levels of essentially (0.0156%), quadrupole nuclide with only 0.01 the sensitivity 100%-i.e., 110 molar equivalent deuterium. This high con- of 'H. Nevertheless, the combination of an efficient centration, together with the short relaxation time of the spin quadrupole relaxation mechanism and the commercial avail- 1 (quadrupole) deuterium nuclide, provides substantial sensi- ability of 2H20, essentially 100% enriched to ca. 110 molar tivity for NMR spectroscopy. As a result, when 2H20 is equivalent deuterium, can provide substantial NMR signal- administered in a bolus fashion to a specific tissue or organ in to-noise in the intact subject.
    [Show full text]
  • Deuterium Concentration by Chemically-Refluxed Ammonia-Hydrogen Exchange
    MIT-D15 DEUTERIUM CONCENTRATION BY CHEMICALLY-REFLUXED AMMONIA-HYDROGEN EXCHANGE SUPPLEMENTARY REPORTS by M. Benedict, E.A. Mason, E.R. Chow, J.S. Baron June 1969 FOR E.I. DUPONT DE NEMOURS & COMPANY UNDER U.S. ATOMIC ENERGY COMMISSION SUBCONTRACT AX-210280 Department of Nuclear Engineering Massachusetts Institute of Technology Cambridge, Massachusetts 02139 (MITNE-103) AECL PROPRIETARY DOCUMENT Notice: This document contains information obtained from Atomic Energy of Canada Limited, designated AECL PROPRIETARY. Documents so designated are made available to the USAEC pursuant to the Memorandum of Understanding executed June 7, 1960, for distribution restricted to the USAEC or its contractors. No other distribution is to be made without permission of AECL which may be secured by requesting specific clearance from the Scientific Representative, USAEC, Chalk River Liaison Office, Chalk River, Ontario. MIT-Dl5 DEUTERIUM CONCENTRATION BY CHEMICALLY-REFLUXED AMMONIA-HYDROGEN EXCHANGE SUPPLEMENTARY REPORTS by M. Benedict, E.A. Mason, E.R. Chow, J.S. Baron June 1969 for E.I. duPont de Nemours & Company under U.S. Atomic Energy Commission Subcontract AX-210280 (MIT DSR-70672) Department of Nuclear Engineering Massachusetts Institute of Technology Cambridge, Massachusetts 02139 (MITNE-103) Table of Contents Page Introductory Note I-1 Supplement A Liquid-Vapor Equilibrium in the System NH 3-H 2-N2 1. Introduction A-1 2. Results 2.1 Liquid Phase A-1 2.2 Vapor Phase A-2 3. Sources of Data A-3 4. Procedure for Correlating Data 4.1 Henry's Law Constants A-4 4.2 Ammonia Content of Vapor A-5 5. Bibliography A-19 Supplement B Enthalpies of Hydrogen, Nitrogen, and Ammonia to 14000 F and from 0 to 200 Atmospheres 1.
    [Show full text]
  • The Nine Lives of Cosmic Rays in Galaxies
    AA53CH06-Grenier ARI 29 July 2015 12:16 The Nine Lives of Cosmic Rays in Galaxies Isabelle A. Grenier,1 John H. Black,2 and Andrew W. Strong3 1Laboratoire AIM Paris-Saclay, CEA/Irfu, CNRS, Universite´ Paris Diderot, F-91191 Gif-sur-Yvette Cedex, France; email: [email protected] 2Department of Earth & Space Sciences, Chalmers University of Technology, Onsala Space Observatory, SE-439 92 Onsala, Sweden; email: [email protected] 3Max-Planck-Institut fur¨ extraterrestrische Physik, 85741 Garching, Germany; email: [email protected] Annu. Rev. Astron. Astrophys. 2015. 53:199–246 Keywords First published online as a Review in Advance on γ rays, interstellar medium, interstellar chemistry, dust, superbubbles June 18, 2015 The Annual Review of Astronomy and Astrophysics is Abstract online at astro.annualreviews.org Cosmic-ray astrophysics has advanced rapidly in recent years, and its impact This article’s doi: on other astronomical disciplines has broadened. Many new experiments 10.1146/annurev-astro-082214-122457 measuring these particles, both directly in the atmosphere or space and in- Annu. Rev. Astro. Astrophys. 2015.53:199-246. Downloaded from www.annualreviews.org Access provided by University of Maryland - College Park on 08/24/15. For personal use only. Copyright c 2015 by Annual Reviews. directly via γ rays and synchrotron radiation, have widened the range and All rights reserved quality of the information available on their origin, propagation, and inter- actions. The impact of low-energy cosmic rays on interstellar chemistry is a fast-developing topic, including the propagation of these particles into the clouds in which the chemistry occurs.
    [Show full text]