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Safety Data Sheet SAFETY DATA SHEET 1. Product and Company Identification Product identifier Calcium Bromide Dihydrate Solid Other means of identification Not available Recommended use Additive Recommended restrictions None known. Manufacturer information Irving Blending & Packaging PO Box 1169 Saint John, NB E2L 4E6 CA Phone: 1.800.574.5823 Emergency Phone: 1.506.648.3060 Supplier See above. 2. Hazards Identification Physical hazards Not classified. Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Environmental hazards Not classified. WHMIS 2015 defined hazards Not classified Label elements Signal word Danger Hazard statement Causes serious eye damage. Causes skin irritation. May cause respiratory irritation. Precautionary statement Prevention Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Avoid breathing dust. Use only outdoors or in a well-ventilated area. Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. IF ON SKIN: Wash with plenty of water. Specific treatment (see information on this label). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. WHMIS 2015: Health Hazard(s) None known not otherwise classified (HHNOC) WHMIS 2015: Physical None known Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/Information on Ingredients Mixture Chemical name Common name and synonyms CAS number % Calcium bromide (CaBr2) 7789-41-5 100 All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. #27130 Page: 1 of 6 Issue date 05-April-2016 4. First Aid Measures Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact IF ON SKIN: Wash with plenty of water. Specific treatment (see information on this label). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Ingestion Rinse mouth. Do not induce vomiting. Get medical attention if symptoms occur. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Most important Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred symptoms/effects, acute and vision. Permanent eye damage including blindness could result. May cause respiratory irritation. delayed Skin irritation. May cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. Treat patient symptomatically. treatment needed General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire-fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. Hazardous combustion May include and are not limited to: Hydrogen bromide. Bromine. products 6. Accidental Release Measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers emergency procedures or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect containment and cleaning up material for proper disposal without raising dust. Rinse area with water. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Environmental precautions Do not discharge into lakes, streams, ponds or public waters. 7. Handling and Storage Precautions for safe handling Do not get this material in contact with eyes. Avoid breathing dust. Avoid contact with eyes, skin, and clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Wash thoroughly after handling. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Conditions for safe storage, Store locked up. Store in original tightly closed container. Store away from incompatible materials including any incompatibilities (see Section 10 of the SDS). Keep out of reach of children. 8. Exposure Controls/Personal Protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. #27130 Page: 2 of 6 Issue date 05-April-2016 Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Skin protection Hand protection Impervious gloves. Confirm with reputable supplier first. Other Wear appropriate chemical resistant clothing. As required by employer code. Respiratory protection Avoid inhalation of dust. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Respirator should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA's respirator standard (29 CFR 1910.134), CAN/CSA-Z94.4 and ANSI's standard for respiratory protection (Z88.2). Thermal hazards Not applicable. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. When using do not eat or drink. 9. Physical and Chemical Properties Appearance Crystalline. Powder. Physical state Solid. Form Powder Color White Odor Odorless Odor threshold Not available. pH Not available. Melting point/freezing point 1400 °F (760 °C) (Decomposes) Initial boiling point and boiling 1490 °F (810 °C) range Pour point Not available. Specific gravity 3.35 Partition coefficient Not available. (n-octanol/water) Flash point None Evaporation rate Not available. Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) 312 g/100 mL @ 100°C 142 g/100 mL @ 30°C Auto-ignition temperature Not available. Decomposition temperature > 1292 °F (> 700 °C) Viscosity Not available. Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. 10. Stability and Reactivity Reactivity This product may react with strong oxidizing agents. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Chemical stability Material is stable under normal conditions. #27130 Page: 3 of 6 Issue date 05-April-2016 Conditions to avoid Avoid temperatures exceeding the decomposition temperature. Do not mix with other chemicals. Incompatible materials Strong oxidizing agents. Acids. Hazardous decomposition May include and are not limited to: Hydrogen
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