NGL 101- the Basics
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U.S. Energy in the 21St Century: a Primer
U.S. Energy in the 21st Century: A Primer March 16, 2021 Congressional Research Service https://crsreports.congress.gov R46723 SUMMARY R46723 U.S. Energy in the 21st Century: A Primer March 16, 2021 Since the start of the 21st century, the U.S. energy system has changed tremendously. Technological advances in energy production have driven changes in energy consumption, and Melissa N. Diaz, the United States has moved from being a net importer of most forms of energy to a declining Coordinator importer—and a net exporter in 2019. The United States remains the second largest producer and Analyst in Energy Policy consumer of energy in the world, behind China. Overall energy consumption in the United States has held relatively steady since 2000, while the mix of energy sources has changed. Between 2000 and 2019, consumption of natural gas and renewable energy increased, while oil and nuclear power were relatively flat and coal decreased. In the same period, production of oil, natural gas, and renewables increased, while nuclear power was relatively flat and coal decreased. Overall energy production increased by 42% over the same period. Increases in the production of oil and natural gas are due in part to technological improvements in hydraulic fracturing and horizontal drilling that have facilitated access to resources in unconventional formations (e.g., shale). U.S. oil production (including natural gas liquids and crude oil) and natural gas production hit record highs in 2019. The United States is the largest producer of natural gas, a net exporter, and the largest consumer. Oil, natural gas, and other liquid fuels depend on a network of over three million miles of pipeline infrastructure. -
SAFETY DATA SHEET Nonflammable Gas Mixture: Carbon Dioxide / Carbon Monoxide / Nitric Oxide / Nitrogen / Propane Section 1
SAFETY DATA SHEET Nonflammable Gas Mixture: Carbon Dioxide / Carbon Monoxide / Nitric Oxide / Nitrogen / Propane Section 1. Identification GHS product identifier : Nonflammable Gas Mixture: Carbon Dioxide / Carbon Monoxide / Nitric Oxide / Nitrogen / Propane Other means of : Not available. identification Product type : Gas. Product use : Synthetic/Analytical chemistry. SDS # : 002173 Supplier's details : Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 24-hour telephone : 1-866-734-3438 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : GASES UNDER PRESSURE - Compressed gas substance or mixture GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. May increase respiration and heart rate. Precautionary statements General : Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Prevention : Not applicable. Response : Not applicable. Storage : Protect from sunlight. Store in a well-ventilated place. Disposal : Not applicable. Hazards not otherwise : In addition to any other important health or physical hazards, this product may displace classified oxygen and cause rapid suffocation. -
Determination of Parent and Alkylated Polycyclic Aromatic Hydrocarbons (Pahs) in Biota and Sediment
ICES TECHNIQUES IN MARINE ENVIRONMENTAL SCIENCES NO. 45 NOVEMBER 2009 Determination of parent and alkylated polycyclic aromatic hydrocarbons (PAHs) in biota and sediment L. WEBSTER • J. TRONCZYNSKI P. KORYTAR • K. BOOIJ • R. LAW International Council for the Exploration of the Sea Conseil International pour l’Exploration de la Mer H. C. Andersens Boulevard 44 – 46 DK‐1553 Copenhagen V Denmark Telephone (+45) 33 38 67 00 Telefax (+45) 33 93 42 15 www.ices.dk [email protected] Our cover photo was taken by N. Penny Holliday aboard the RRS “Discovery” in rough seas in the Rockall Trough. Recommended format for purposes of citation: Webster, L., Tronczynski, J., Korytar, P., Booij, K., and Law, R. 2010. Determination of parent and alkylated polycyclic aromatic hydrocarbons (PAHs) in biota and sediment. ICES Techniques in Marine Environmental Sciences. No. 45. 26 pp. Series Editor: Paul D. Keizer For permission to reproduce material from this publication, please apply directly to the General Secretary. Correspondence concerning the details of any method or procedure should be directed to the author(s). This series presents detailed descriptions of methods and procedures relating to chemical and biological measurements in the marine environment. Most techniques described have been selected for documentation based on performance in ICES or other intercalibration or intercomparison exercises: they have been carefully evaluated and shown to yield good results when correctly applied. They have also been subject to review by relevant ICES working groups, but this is not to be construed as constituting official recommendation by the Council. ISBN 978-87-7482-074-1 978-87-7482-297-4 https://doi.org/10.17895/ices.pub.5070 ISSN 0903 – 2606 2707-6997 © 2010 International Council for the Exploration of the Sea ICES Techniques in Marine Environmental Sciences No. -
Experimental and Analytical Study of Nitric Oxide Formation During Combustion of Propane in a Jet-Stirred Combustor
NASA Technical Paper 1181 I 1 Experimental and Analytical Study of Nitric Oxide Formation During / Combustion of Propane in a Jet-Stirred Combustor , ' N. T. Wakelyn, Casimir J. Jachimowski, and Charles H. Wilson , TECH LIBRARY KAFB, NM 0134538 NASA Technical Paper 1181 Experimental and Analytical Study of Nitric Oxide Formation During Combustion of Propane in a Jet-Stirred Combustor N. T. Wakelyn, Casimir J. Jachimowski, and Charles H. Wilson Langley Research Center Hampton, Virginia National Aeronautics and Space Administration Scientific and Technical Information Otfice 1978 '8' SUMMARY A jet-stirred combustor, constructed of castable zirconia and with an inconel injector, has been used to study nitric oxide formation in propane-air combustion with residence times in the range from 3.2 to 3.3 msec and equiva lence ratios varying from 0.7 to 1.4. The residence time range was character istic of that found in the primary zones of aircraft turbines. Premixed propane-air formulations were subjected to intense and turbulent backmixed combustion within the cavity formed between the injector and the hemispherical inner walls of the zirconia shell. The volume of the combustor cavity was 12.7 cm3 and the mass loading was maintained in the range from 0.053 to 0.055 g/cm3-sec. Measurements were made of combustor operating tem perature and of nitric oxide concentration. Maximum nitric oxide concentrations of the order of 55 ppm were found in the range of equivalence ratio from 1.0 to 1.1. Nitric oxide concentrations were predicted over the range of equivalence ratio by a computer program which employs a perfectly stirred'reactor (PSR) algorithm with finite-rate kinetics. -
Concept Papers for Changes to Rule 9-1 -- Refinery Fuel Gas Sulfur
Draft: 05‐14‐15 Appendix C: Concept Paper for Changes to Rule 9‐1: Refinery Fuel Gas Sulfur Limits Rules to Be Amended or Drafted Regulation of refinery fuel gas (RFG) requires amendments to Air District Regulation 9, Rule 1, Sulfur Dioxide. Goals The goal of this rulemaking is to achieve technically feasible and cost‐effective sulfur dioxide (SO2) emission reductions from RFG systems at Bay Area refineries. Background The lightest components of crude oil separated by a refinery’s atmospheric fractionator are methane and ethane, which are also the primary components of natural gas. At petroleum refineries, these products are not produced in marketable quantities, but are used as fuel in the numerous onsite steam generators and process heaters. When produced at a refinery, this product is called refinery fuel gas (RFG). Pipeline natural gas may be used as a supplemental fuel when needed to enhance the quality of RFG or when there is not enough RFG available. Unlike, pipeline natural gas, refinery fuel gas often contains significant quantities of sulfur that occur naturally in crude oil. When burned, these sulfur compounds are converted to SO2. Process and Source Description RFG can contain between a few hundred and a few thousand parts per million‐volume (ppmv) sulfur in the form of hydrogen sulfide (H2S), carbonyl sulfide (COS), and organic sulfur compounds, such as mercaptans. During combustion, the sulfur in all of these compounds will oxidize to form SO2, which is a criteria air pollutant and a precursor to particulate matter. Scrubbing with an amine or caustic solution can be effective at removing H2S and some acidic sulfur containing compounds, but is generally ineffective at removing nonacidic sulfur compounds. -
Alternatives to High Propane Prices Interest Expense and the Cost of Utilities Are the Two Largest “Out of Pocket” Expenses Facing Most Broiler Growers
ThePoultry Engineering, Economics & Management NEWSLETTER Critical Information for Improved Bird Performance Through Better House and Ventilation System Design, Operation and Management Auburn University, in cooperation with the U.S. Poultry & Egg Association Issue No 29, May 2004 Alternatives to High Propane Prices Interest expense and the cost of utilities are the two largest “out of pocket” expenses facing most broiler growers. There is little a grower can do to reduce interest costs, short of major mortgage refinancing. However, costs associated with utilities are another matter. The topics we have addressed in most past issues of this newsletter have all dealt with housing and ventilation factors which can result in improved flock performance and in reduced levels of energy being used, which directly reduces costs to the grower. Electricity rates are typically fixed and are highly regulated. However, the price of heating fuel, specifically propane (liquefied petroleum gas or LPG), has varied widely up and down in most recent years, depending on the time of year and numerous supply and demand conditions. Growers can choose What growers should be aware of is that there are ways to reduce the from several good risk that they will have to buy propane at one of those times when the alternatives to paying price is highest. This newsletter explains several alternative methods consistently high prices growers can use to get lower and more stable propane costs over time. for propane. Understanding the Basics of Propane Pricing The most fundamental factor in propane pricing is that propane is basically a fossil fuel, being derived from raw natural gas during the oil refining process. -
The Formation of Butane in the Polymerization of Methyl Methacrylate with Butyllithium
Polymer Journal, Vol. 12, No. 8, pp 535-537 (1980) SHORT COMMUNICATION The Formation of Butane in the Polymerization of Methyl Methacrylate with Butyllithium Koichi HATADA, Tatsuki KITAYAMA, and Heimei YUKI Department of Chemistry, Faculty of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560, Japan. (Received February 28, 1980) KEY WORDS Methyl Methacrylate I Perdeuterated Methyl Methacrylate I Anionic Polymerization I Butyllithium I Toluene I Tetrahydrofuran I Butane Formation I Mass Spectroscopy I Butene I It has been found that a small amount of butane merization reactions in toluene: (1) the poly is formed when the polymerization of methyl merization of MMA terminated by CH30D methacrylate is initiated with butyllithium and (MMA-CH30D system) and (2) that of MMA-d8 terminated with acetic acid. The origin of the butane terminated by CH3 0H (MMA-d8-CH3 0H system). was not clear, although the proton abstraction from The reactions were quenched at 10 min following the monomer is assumed. 1 the initiation. The spectra of butane (BuH) and In this work the polymerizations of undeuterated butane-d-1, CH3 CH2 CH2CH2 D, (BuD) are also (MMA) and perdeuterated (MMA-d8 ) methyl shown for comparison. The BuH and BuD were methacrylates were initiated with undeuterated obtained by the reaction of BuLi with CH30H and butyllithium (BuLi) and terminated by CH3 0D and CH30D, respectively. By inspecting these four CH3 0H, respectively. Deuterium distributions in spectra, it can be seen that the butane from the the butane formed were determined by combined MMA-CH3 0D system mainly consists of BuD and gas-liquid phase chromatography-mass spectrom the butane from the MMA-d8-CH30H system is etry. -
Safety Data Sheet
SAFETY DATA SHEET 1. Identification Product number 1000007900 Product identifier AUTO GLASS QUICK RELEASE AGENT Company information Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States Company phone General Assistance 1-630-628-3000 Emergency telephone US 1-866-836-8855 Emergency telephone outside 1-952-852-4646 US Version # 01 Recommended use Not available. Recommended restrictions None known. 2. Hazard(s) identification Physical hazards Flammable aerosols Category 1 Health hazards Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 narcotic effects Aspiration hazard Category 1 Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Extremely flammable aerosol. May be fatal if swallowed and enters airways. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Response If swallowed: Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. Do NOT induce vomiting. If eye irritation persists: Get medical advice/attention. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. -
Oxidation of Ethane to Ethylene and Acetic Acid by Movnbo Catalysts Martial Roussel, Michel Bouchard, Elisabeth Bordes-Richard, Khalid Karim, Saleh Al-Sayari
Oxidation of ethane to ethylene and acetic acid by MoVNbO catalysts Martial Roussel, Michel Bouchard, Elisabeth Bordes-Richard, Khalid Karim, Saleh Al-Sayari To cite this version: Martial Roussel, Michel Bouchard, Elisabeth Bordes-Richard, Khalid Karim, Saleh Al-Sayari. Oxida- tion of ethane to ethylene and acetic acid by MoVNbO catalysts. Catalysis Today, Elsevier, 2005, 99, pp.77-87. 10.1016/j.cattod.2004.09.026. hal-00103604 HAL Id: hal-00103604 https://hal.archives-ouvertes.fr/hal-00103604 Submitted on 4 Oct 2006 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Oxidation of ethane to ethylene and acetic acid by MoVNbO catalysts M. Roussel 1, M. Bouchard 1, E. Bordes-Richard 1*, K. Karim 2, S. Al-Sayari 2 1: Laboratoire de Catalyse de Lille, UMR CNRS 8010, USTL-ENSCL, 59655 Villeneuve d'Ascq Cedex, France 2: SABIC R&T, P.O. Box 42503, Riyadh, Saoudi Arabia ABSTRACT The influence of niobium on the physicochemical properties of the Mo-V-O system and on its catalytic properties in the oxidation of ethane to ethylene and acetic acid is examined. Solids based on MoV 0.4 Ox and MoV 0.4 Nb 0.12 Oy composition and calcined at 350 or 400°C were studied by X-ray diffraction, and by laser Raman and X-ray photoelectron spectroscopies. -
Liquefied Petroleum Gas (LPG)
Liquefied Petroleum Gas (LPG) Demand, Supply and Future Perspectives for Sudan Synthesis report of a workshop held in Khartoum, 12-13 December 2010 The workshop was funded by UKaid from the Department for International Development Cover image: © UNAMID / Albert Gonzalez Farran This report is available online at: www.unep.org/sudan Disclaimer The material in this report does not necessarily represent the views of any of the organisations involved in the preparation and hosting of the workshop. It must be noted that some time has passed between the workshop and the dissemination of this report, during which some important changes have taken place, not least of which is the independence of South Sudan, a fact which greatly affects the national energy context. Critically, following the independence, the rate of deforestation in the Republic of Sudan has risen from 0.7% per year to 2.2% per year, making many of the discussions within this document all the more relevant. Whilst not directly affecting the production of LPG, which is largely derived from oil supplies north of the border with South Sudan, the wider context of the economics of the energy sector, and the economy as a whole, have changed. These changes are not reflected in this document. This being said, it is strongly asserted that this document still represents a useful contribution to the energy sector, particularly given its contribution to charting the breadth of perspectives on LPG in the Republic of Sudan. Liquefied Petroleum Gas (LPG) Demand, Supply and Future Perspectives for Sudan Synthesis report of a workshop held in Khartoum, 12-13 December 2010 A joint publication by: Ministry of Environment, Forestry and Physical Development – Sudan, Ministry of Petroleum – Sudan, United Kingdom Department for International Development, United Nations Development Programme and United Nations Environment Programme Table of contents Acronyms and abbreviations . -
Chapter 2: Alkanes Alkanes from Carbon and Hydrogen
Chapter 2: Alkanes Alkanes from Carbon and Hydrogen •Alkanes are carbon compounds that contain only single bonds. •The simplest alkanes are hydrocarbons – compounds that contain only carbon and hydrogen. •Hydrocarbons are used mainly as fuels, solvents and lubricants: H H H H H H H H H H H H C H C C H C C C C H H C C C C C H H H C C H H H H H H CH2 H CH3 H H H H CH3 # of carbons boiling point range Use 1-4 <20 °C fuel (gasses such as methane, propane, butane) 5-6 30-60 solvents (petroleum ether) 6-7 60-90 solvents (ligroin) 6-12 85-200 fuel (gasoline) 12-15 200-300 fuel (kerosene) 15-18 300-400 fuel (heating oil) 16-24 >400 lubricating oil, asphalt Hydrocarbons Formula Prefix Suffix Name Structure H CH4 meth- -ane methane H C H H C H eth- -ane ethane 2 6 H3C CH3 C3H8 prop- -ane propane C4H10 but- -ane butane C5H12 pent- -ane pentane C6H14 hex- -ane hexane C7H16 hept- -ane heptane C8H18 oct- -ane octane C9H20 non- -ane nonane C10H22 dec- -ane decane Hydrocarbons Formula Prefix Suffix Name Structure H CH4 meth- -ane methane H C H H H H C2H6 eth- -ane ethane H C C H H H H C H prop- -ane propane 3 8 H3C C CH3 or H H H C H 4 10 but- -ane butane H3C C C CH3 or H H H C H 4 10 but- -ane butane? H3C C CH3 or CH3 HydHrydorcocaarrbobnos ns Formula Prefix Suffix Name Structure H CH4 meth- -ane methane H C H H H H C2H6 eth- -ane ethane H C C H H H H C3H8 prop- -ane propane H3C C CH3 or H H H C H 4 10 but- -ane butane H3C C C CH3 or H H H C H 4 10 but- -ane iso-butane H3C C CH3 or CH3 HydHrydoroccarbrobnsons Formula Prefix Suffix Name Structure H H -
Enabling Ethane As a Primary Gas Turbine Fuel: an Economic Benefit from the Growth of Shale Gas
GE Power GEA32198 November 2015 Enabling ethane as a primary gas turbine fuel: an economic benefit from the growth of shale gas Dr. Jeffrey Goldmeer GE Power, Gas Power Systems Schenectady, NY, USA John Bartle GE Power, Power Services Atlanta, GA, USA Scott Peever GE Power Toronto, ON, CAN © 2015 General Electric Company. All Rights Reserved. This material may not be copied or distributed in whole or in part, without prior permission of the copyright owner. GEA32198 Enabling ethane as a primary gas turbine fuel: an economic benefit from the growth of shale gas Contents Abstract ............................................................................3 Introduction ........................................................................3 Fuel Supply Dynamics ...............................................................3 Hydrocarbon Sources and Characteristics ...........................................5 Combustion System Considerations .................................................6 Evaluating Fuels .....................................................................6 GE’s Gas Turbine Combustion Systems ..............................................8 Non-Methane Hydrocarbon Capability ...............................................9 Economic Value of Alternative Fuels .................................................9 Conclusions ........................................................................10 References ........................................................................11 2 © 2015 General Electric Company. All Rights